Abstract: A process for producing a three-dimensional model is provided. The process includes (a) a layer formation step of forming a layer of a powder material having a refractive index n1 above a support, (b) a shape formation step of bonding the powder material layer into a predetermined shape by a binder that gives a refractive index n2, and (c) sequentially repeating the above steps. The absolute value of the difference between the refractive index n1 of the powder material and the refractive index n2 given by the binder is 0.1 or less, and the binder includes two or more types of binders selected from the group consisting of at least one type of colored binder, a white binder, and a colorless transparent binder.

Abstract: Electrically conductive, thermoset molding compositions are disclosed which comprise an unsaturated thermosetting resin, an olefinically unsaturated monomer which is copolymerizable with the thermosetting resin, a thermoplastic additive and carbon black. The carbon black is incorporated in a conductive additive which comprises the thermoplastic additive, the carbon black and, preferably, a lubricant. The electrical resistance of articles molded from the disclosed molding compositions is typically less than about 108 ohms/cm2.

Abstract: A radially inner surface of a sealing lip of an oil seal, is irradiated to induce a chemical reaction in the material of the sealing lip, to form hard helical portions. The hard helical portions act like a helical groove or rib to pump oil back to an oil-side for excellent sealing properties when there is a relative rotational movement between the sealing lip and a shaft to sealed, as well as a static sealing ability at the time there is no relative rotation movement.

Abstract: A method of producing a plastic product having a microstructured surface (3a), utilizing an arrangement for moulding plastic products. Said arrangement has at least two mould parts (2, 3) movable towards and away from each other, a predetermined volume of a viscous polymerizable plastic material (9) being supplied to a cavity formed between the mould parts, after which polymerization of the plastic material occurs. After said polymerization of the plastic material (9′), the mould parts are caused to move apart from each other thereby allowing removal of a finished plastic product the outer shape of which conforms to the shape of the cavity produced by the mould parts. Said viscous polymerizable plastic material (9) is supplied to the cavity (6) around a hole (10a) pertaining to the finished plastic product, and said viscous plastic material is distributed in a direction from said hole (10a) towards the peripheral edge area of the plastic product.

Abstract: The wavefront aberrator of the present invention includes a pair of transparent windows, or plates, separated by a layer of monomers and polymerization initiator, including a broad class of epoxies. This monomer exhibits a variable index of refraction across the layer, resulting from controlling the extent of its curing. Curing of the epoxy may be made by exposure to light, such as ultraviolet light. The exposure to light may be varied across the surface of the epoxy to create a particular and unique refractive index profile.

Abstract: An optical structure and method for forming same includes a plurality of first cured portions and a plurality of second cured portions that are formed from a same light-curable material. The first plurality of cured portions is cured to a first amount. The plurality of second cured portions is cured to a second amount. The first amount is sufficiently different than the second amount to result with discontinuities on the surface of the structure. The lenticular layer can include a prism layer having random discontinuities on the peaks. The discontinuities can also be formed on a window side of the prisms.

Abstract: A cost effective manufacturing process encapsulates a light emitting polymer (LEP) device between two flexible sheet materials, where one sheet may act as the substrate for the LEP device and the other sheet may act as a cover for the LEP device, and at least one of the sheets is transparent. Both encapsulating sheets and, as required, an adhesive system binding the sheets together provide sufficient environmental barriers with low moisture vapor transmission rates (MVTR) and oxygen transmission rates (OTR). The encapsulating sheets may, for example, be laminated together, sandwiching the LEP device in a vacuum, or oxygen/moisture free, and inert gas environment. Prior to encapsulation the LEP device may be heated and placed in a vacuum to remove moisture, air and residual solvents.

Abstract: A method of manufacturing a water-absorbing shaped body that is produced easily without using a thickening agent. Light is radiated onto an aqueous solution including a photo polymerization initiator and a water-soluble ethylenically unsaturated monomer. When a desired viscosity is attained, radiation of the light is stopped temporarily. Then, the aqueous solution, which is thickened, is shaped into a desired shape. Thereafter, polymerization is completed by radiating light again.

Abstract: The present invention relates to a tough, wear resistant Ultra High Molecular Weight Polyethylene (UHMWPE) prepared by the cross linking of a UHMWPE shaped article with irradiation doses higher than 4 Mrads, preferably higher than 5 Mrads, and most preferably less than 10 Mrads. The invention particularly provides total joint replacement devices and methods of making them for the hip, knee, elbow and shoulder.

Abstract: The invention relates to thermoplastic polyolefin compositions having enhanced surface durability and products thereof which include a thermoplastic polyolefin base component at least one radiation-crosslinkable component present in an amount sufficient to enhance the surface durability of the thermoplastic polyolefin component when radiation-cured and at least one photoinitiator present in an amount sufficient to initiate crosslinking of the radiation-crosslinkable component upon exposure of the thermoplastic polyolefin composition to radiation.

Abstract: A freeform fabrication method for fabricating a 3-D multi-material or multi-color object from successive layers of a primary body-building powder, at least a modifier material and a binder powder in accordance with a computer-aided design of the object.

Abstract: A process for producing scratch-resistant coatings, encompassing the following steps: applying at least one UV-curable coating composition to at least one surface of an article to be coated, said coating composition comprising at least one polymer and/or oligomer P1 containing on average at least one ethylenically unsaturated double bond per molecule, and curing the coating composition by exposure to UV radiation, which comprises conducting the curing of the coating composition under an oxygen-containing protective gas which has an oxygen partial pressure in the range from 0.2 to 18 kPa.

Abstract: Pore-free rubber articles are prepared by dip-molding in a dipping medium that includes a vulcanizing agent, then by immersing the dip former in a heated liquid bath that is chemically inert. A particularly effective liquid bath is molten inorganic salt. In addition, the tensile properties of an article of vulcanized rubber can be improved to an unusually effective degree by immersing the already vulcanized article in a solution of a vulcanizing agent to cause the rubber of the article to absorb or imbibe the vulcanizing agent from the solution, and then immersing the rubber and the imbibed vulcanizing agent in a heated liquid bath to increase the degree of vulcanization.

Abstract: A slush-moulding method combined with cross-linking, including the filling of a tank with a suitable quantity of ground polymer blend and the coupling of said tank with a heated mold is provided. The closed system thus obtained is moved in order to transfer the powder onto the mold, so as to carry out on the latter a layer of completely or partially melted powder. Before and after a stage of stripping of the leather off the mold, said leather is cross-linked by means of radiations.

Abstract: Disclosed herein is a method for making fibrous web materials which may be used in or as absorbent core materials for absorbent products. The method involves providing loose fibers, entraining the fibers in a moving airstream, treating the fibers with an energy-activatable pre-polymer composition and subjecting the fibers to activation energy to initiate cross-linking of the composition. The fibers are collected on forming surface to form a fibrous web. The fibers may be treated with the composition while entrained in the moving air or after being collected on the forming surface, or in an alternate embodiment by treating with the composition a mat of fibers from which the loose fibers are provided. The fibrous web material may comprise cellulosic fibers such as pulp, and/or synthetic fibers such as staple fibers, and/or super absorbent materials.

Abstract: In a method of manufacturing a replica, a bondable resin composition is provided between a mold and a substrate or a blank, the resin is cured and the replica thus manufactured is removed from the mold. The replica includes the substrate and the reproduction of the mold on the substrate. The curing includes a UV light-initiated cationic polymerization.

Abstract: A method for forming a non-rubbing alignment film is provided. A polymer film is formed on a substrate. A plurality of microgroove structure is then formed on the surface of the polymer film by the molecular imprint method to prevent electrostatic damage and micro particle contamination produced by the conventional rubbing method.

Abstract: A curable resin composition comprises a poly(arylene ether), an acryloyl monomer, an allylic monomer, and an abrasive filler. The composition tolerates high filler contents, cures rapidly, and exhibits excellent toughness after curing. Useful articles prepared from the composition include grinding wheels and cut-off wheels having good wear characteristics.

Abstract: Disclosed is a film provided with a hardcoat which has high surface hardness and improved apparent scratch resistance. This film provided with a hardcoat comprises: a transparent substrate film; and, stacked on the transparent substrate film in the following order, a hardcoat and a slip layer. The hardcoat is formed of a cured product of a material comprising an ultraviolet-curable resin and a photopolymerization initiator which initiates the photopolymerization of the ultraviolet-curable resin upon exposure to ultraviolet light in its wavelength region other than the wavelength region absorbable by the transparent substrate film. The slip layer contains a slip agent.

Abstract: A process for forming a three-dimensional article in sequential layers in accordance with a digital model of the article. The process comprises the steps of defining a layer of powder or liquid material, applying a liquid reagent to the layer in a pattern corresponding to the digital model, and repeating these steps to form successive layers. The powder or liquid material comprises a first reactive component and the applied liquid includes a second active component capable of reacting with the first reactive component so that the article is built up in layers. The characteristics of the layers vary across those layers and/or the properties vary from layer to layer.

Abstract: A polymer Thick Film (“PTF”) laminate, in which selected (and advantageously all) of the layers are deployed using UV-curable inks. In one embodiment of the invention, the UV-curable PTF layers are deployed in an exemplary monolithic and membranous EL structure, in which UV-cured urethane envelope layers encapsulate UV-cured urethane electroluminescent layers. When deployed in layer form during manufacture and subsequently exposed to UV radiation, the inventive inks cure in a few seconds without any appreciable layer height shrinkage. Manufacturing cycle time is significantly optimized over traditional heat curing processes. Flexible circuitry is also disclosed herein. The flexible circuitry may be embodied using the UV-curable urethane inks disclosed herein, although the flexible circuitry is not limited to UV-curable or urethane embodiments. Successive insulating layers are deployed. The insulating layers have conductive pathways deployed thereon.

Abstract: A system and method for forming a polymeric molding. A mold component includes a transmissive portion for passing curing energy such as UV light into the mold cavity. A masking collar is engaged around the transmissive portion to block curing energy from exposing and curing polymeric material outside of the region underlying the transmissive portion.

Abstract: A method of fabricating a mold and a method of fabricating an article with the mold is disclosed that is capable of fabricating a high three-dimensional surface structure and extending the service life of the mold. A mold having a fine surface shape of a height less than an object height is fabricated, then the fine surface shape of the mold is transferred to an intermediate mold by dry-etching, and then the fine surface shape of the intermediate mold is further transferred to a final article material by dry-etching. In each transfer step by dry-etching, the etching selection ratio is appropriately adjusted to increase the height of the fine surface structure step by step, so that the fine surface shape of the final article material has the object height. On the surface of the final article material, a preliminary pattern of the object surface shape may be formed beforehand to reduce the required thickness of the curable resin.

Abstract: A method of manufacturing a heat conductive molded part having determined heat conductivity properties is provided. The method includes providing a polymer composition containing boron nitride powder. A magnetic field is impressed to the polymer composition containing boron nitride powder, field orienting the boron nitride powder in the polymer composition to a fixed direction. The polymer composition is set containing boron nitride powder with the boron nitride powder oriented in the polymer composition to the fixed direction. The polymer composition may also be provided containing a solvent. The solvent is removed after field orienting the boron nitride powder in the polymer composition to the fixed direction The composition is then set with the field oriented boron nitride powder after having removed the solvent.

Abstract: A method of increasing the efficiency of a multiphoton absorption process and apparatus. The method includes: providing a photoreactive composition; providing a source of sufficient light for simultaneous absorption of at least two photons; exposing the photoreactive composition to at least one transit of light from the light source; and directing at least a portion of the first transit of the light back into the photoreactive composition using at least one optical element, wherein a plurality of photons not absorbed in at least one transit are used to expose the photoreactive composition in a subsequent transit.

Abstract: Described are methods for patterning a substrate by imprint lithography. Imprint lithography is a process in which a liquid is dispensed onto a substrate. A template is brought into contact with the liquid and the liquid is cured. The cured liquid includes an imprint of any patterns formed in the template. In one embodiment, the imprint process is designed to imprint only a portion of the substrate. The remainder of the substrate is imprinted by moving the template to a different portion of the template and repeating the imprint lithography process.

Abstract: A decomposable product fabrication method includes the steps of a) preparing a plant powder obtained by crushing plant fibers and a viscous fluid additive containing a bonding agent, (b) mixing the prepared materials into a viscous mixture, c) drying the viscous mixture by baking, d) using a compression molding machine to mold the viscous mixture into a green ware and discharging steamy air out of the mold during compression molding, e) covering the green ware with a layer of waterproof coating, and f) baking the semi-finished product thus obtained from step e) to a dry status, so as to obtain a finished product after cooling.

Abstract: A manufacturing method is provided for a roller, by which a roller having low eccentricity and high surface smoothness can be obtained without the need to perform cumbersome processes such as polishing of a foamed layer. The manufacturing method for a roller includes the steps of injecting a foam-layer compound into the space between a core bar, which is disposed at the center of a cylindrical mold, and an electron beam-irradiated tube, which has an outer diameter somewhat smaller than an inside diameter of the cylindrical mold, and which is set inside the cylindrical mold, and heating and foaming the foam-layer compound, so that the outer surface of the electron beam-irradiated tube is pressed against the inner surface of the cylindrical mold.

Abstract: A polyolefin plaque is made by hot compaction of an assembly of fibres of the oriented polymer. It has been found to be beneficial to subject the fibres to a prior crosslinking process. Hot compaction is then less temperature-sensitive and produces plaques with excellent hot strength properties. Preferably the fibres have been subjected to prior stages of irradiation and annealing, both in a non-oxidising environment, for example acetylene.

Abstract: This disclosure describes a processing approach for the rapid and efficient in-situ polymerization of specially prepared precursor mixtures to achieve near-net-shape production of objects/articles with exact dimensions. The process relies on the use of polymerizable compositions comprised of a mixture of a reactive plasticizer and an initiator, optionally also including a dead polymer, which compositions are semi-solid-like and induce little shrinkage upon curing as a result of their partially polymerized nature prior to processing. The articles of the invention have a surface and an interior core, the composition of the surface material being distinct from the composition of the core material while at the same time the surface and the core are an integral, monolithic entity. In addition, the articles are dimensionally stable and exhibit high fidelity replication.

Abstract: A method of forming features on substrates by imprinting is provided. The method comprises: (a) forming a polymer solution comprising at least one polymer dissolved in at least one polymerizable monomer; and (b) depositing the polymer solution on a substrate to form a liquid film thereon; and then either: (c) curing the liquid film by causing the monomer(s) to polymerize and optionally cross-linking the polymer(s) to thereby form a polymer film, the polymer film having a glass transition temperature (Tg); and imprinting the polymer film with a mold having a desired pattern to form a corresponding negative pattern in the polymer film, or (d) imprinting the liquid film with the mold and curing it to form the polymer film. The temperature of imprinting is as little as 10° C. above the Tg, or even less if the film is in the liquid state. The pressure of the imprinting can be within the range of 100 to 500 psi.

Abstract: A gasket integrated with a cover wherein a gasket material composed of a thermoplastic elastomer composition is integrally fixed to the cover having a shape of multistep contraction over at least two contraction steps, a gasket wherein the cover and the gasket are integrally molded and after molding, are subjected to a heating treatment at a temperature not lower than the temperature at which an adhesive component in materials constituting the gasket initiates crystal fusion or glass transition, or a gasket wherein the cover and the gasket are integrally molded and a covering layer composed of a fluoropolymer is formed on the gasket surface on atmospheric side are proposed. According to the present invention, a gasket integrated with a cover for a hard disc device which gasket is excellent in adhesive property and productivity, and is minimized in permeability and penetration of substances is provided.

Abstract: Novel endoprostheses comprising one or more photocurable materials are disclosed. Said endoprostheses may comprise regions wherein said photocurable materials are selectively disposed about said endoprosthesis and are cured according to desired parameters to achieve varying desired properties. Said properties may include but are not limited to cross-linking density, material density, modulus of elasticity, rate of erosion, extensibility, compressibility, mechanical strength, tensile strength, crystallinity, diffusion coefficient, and permeability.

Abstract: A method of molding a decorative product packaging, comprising the steps of: molding a product container or cap; applying a UV curable liquid to surfaces and/or cavities in the container or cap; then exposing the UV curable liquid to UV radiation to form a solid coating adhered to surfaces and/or filling cavities on the container or cap. The present invention provides dramatic effects, particularly where the container or cap are clear or tinted, because the solid coating can be tinted a contrasting color, providing a striking contrast to the container or cap.

Abstract: A thermally conductive molded article is produced by molding a conductive composition into a predetermined shape. The composition includes a polymer matrix and carbon powders. The carbon powders are obtained by graphitizing a polymeric material that has an aromatic ring on its main chain by heating. The carbon powders are aligned in a certain direction in the polymer matrix. Thus, the molded article can be produced easily and effectively that has excellent thermal conductivity in a given direction and that is suitable for use as a heat radiator, heat transfer member, or a component thereof in electronic hardware.

Abstract: The present invention provides partial and complete shielding approaches to alter the cross-linking characteristics of irradiated polymers, such as polyethylene. Irradiated polymers and fabricated articles, such as medical prosteses, comprising irradiated polymers also are provided.

Abstract: This invention is a rapid low-cost technique for manufacturing thick high-performance carbon and ceramic composites in the form of uniformly densified near-net shaped structures. This is accomplished by impregnating composite preforms with low-viscosity wetting monomers which undergo polymerization followed by pyrolysis reactions in the preform ultimately creating ceramic and/or carbon matrices. Since the monomers possess low-molecular-weight they have low viscosities. Thus, if they wet the fiber and partially-densified preform they can easily impregnate even the smallest pores. Once inside the preforms, polymerization of the monomers is then initiated, resulting in a liquid matrix-precursor of the high molecular weight needed to produce a superior matrix (upon pyrolysis) with high efficiency.

Abstract: In accordance with the invention, features can be directly imprinted into the surface of a solid substrate. Specifically, a substrate is directly imprinted with a desired pattern by the steps of providing a mold having a molding surface to imprint the pattern, disposing the molding surface adjacent or against the substrate surface to be imprinted, and irradiating the substrate surface with radiation to soften or liquefy the surface. The molding surface is pressed into the softened or liquefied surface to directly imprint the substrate. The substrate can be any one of a wide variety of solid materials such as semiconductors, metals, or polymers. In a preferred embodiment the substrate is silicon, the laser is a UV laser, and the mold is transparent to the UV radiation to permit irradiation of the silicon workpiece through the transparent mold. Using this method, applicants have directly imprinted into silicon large area patterns with sub-10 nanometer resolution in sub-250 nanosecond processing time.

Abstract: A process for producing microfluidic articles comprises (a) preparing a photoreactive composition comprising (1) at least one reactive species that is a polymer or a polymer precursor and that is capable of undergoing an acid- or radical-initiated chemical reaction and (2) at least one multiphoton photoinitiator system; (b) exposing a portion of the composition to light sufficient to cause simultaneous absorption of at least two photons, thereby forming exposed and unexposed portions of the composition, and thereby inducing at least one acid- or radical-initiated chemical reaction in the exposed portion; and (c) removing either the exposed or the unexposed portion of the composition, so as to form a microfluidic article comprising a seamless polymer matrix that defines at least one inlet, at least one outlet, and a microfluid processing architecture that is capable of fluidic communication with the inlet and the outlet and that is otherwise fully enclosed within the polymer matrix.

Abstract: A detoxification process for rendering three-dimensional objects formed by solid freeform fabrication techniques biocompatible for use in long-term dermal contact applications. The process nullifies cytotoxins normally present in objects formed by solid freeform fabrication techniques rendering such techniques as viable for the production of biocompatible devices such as stents, artery valve components, bone implant supports, pacemaker shells, surgical tools, and the like. In one embodiment, a custom hearing aid shell is produced by stereolithography from an acrylate photopolymer resin that was detoxified for long-term dermal contact application. The detoxification process makes three-dimensional objects created by solid freeform fabrication techniques available for products requiring biocompatibility.

Abstract: The present invention is directed towards contact planarization methods that can be used to planarize substrate surfaces having a wide range of topographic feature densities for lithography applications. These processes use thermally curable, photo-curable, or thermoplastic materials to provide globally planarized surfaces over topographic substrate surfaces for lithography applications. Additional coating(s) with global planarity and uniform thickness can be obtained on the planarized surfaces. These inventive methods can be utilized with single-layer, bilayer, or multi-layer processing involving bottom anti-reflective coatings, photoresists, hardmasks, and other organic and inorganic polymers in an appropriate coating sequence as required by the particular application. More specifically, this invention produces globally planar surfaces for use in dual damascene and bilayer processes with greatly improved photolithography process latitude.

Abstract: A method and apparatus for light curing of composite materials in which the radiation required to initiate the curing is delivered via one or more lossy fiber optics. The fiber optics are made lossy by methods such as bending the fiber, weaving the fiber into a mat to create periodic micro-bends, tailoring the thickness of the fiber cladding to allow evanescent wave transmission, or simply removing the cladding at intervals along the fiber. Distribution of the light through out the composite material results in dramatic power and time reductions over traditional light curing methods. Unlike thermal curing of composite materials, there is no need for an auto-clave and hence no limit on the size of the part that may be created. Additional benefits include the possibility of curing at operational temperature and so avoiding thermal stresses.

Abstract: Described are methods for patterning a substrate by imprint lithography. An imprint lithography method includes placing a curable liquid on a substrate. A template may be contacted with the curable liquid. Surface forces at the interface of the curable liquid and the template cause the curable liquid to gather in an area defined by a lower surface of the template. Alternately, the curable liquid may fill one or more relatively shallow recesses in the template and the area under the template lower surface. Activating light is applied to the curable liquid to form a patterned layer on the substrate.

Abstract: A stereolithographically fabricated marking for a semiconductor device component, such as a packaged or unpackaged semiconductor device or another substrate. When formed on a semiconductor device with a stereolithographically formed package structure, the marking may be integral with the package. The marking may be formed as apertures through or recesses in one or more stereolithographically fabricated layers of material, or the marking may include one or more stereolithographically fabricated layers that protrude from a surface of a semiconductor device component. Raised markings may also be formed on the surfaces of packaged or bare semiconductor device components. Alternatively, the marking may be fabricated separately from a semiconductor device component, then secured thereto. Methods for stereolithographically marking semiconductor device components are also disclosed.

Abstract: A mill blank assembly for a dental prosthesis includes a milling section and a support section for supporting the assembly in a milling machine. In certain embodiments, the milling section is adhesively bonded to the support section by a direct chemical bond that provides enhanced resistance to unintentional detachment of the milling section from the support section during a subsequent machining operation. Optionally, the support section includes a passageway that receives a quantity of flowable dental restorative material used to make the milling section, such that the restorative material that is located in the passageway provides additional resistance when hardened to unintentional detachment of the milling section from the support section.

Abstract: The invention is a process for radiant curing of a coating on a three-dimensional object.

Abstract: A fluid containment structure that includes a substrate with a gasket surface and a form-in-place gasket disposed on the gasket surface and a method for forming the fluid containment structure are described. The form-in-place gasket is disposed around and marks the perimeter of an interior area on the substrate. The interior area and the form-in-place gasket define a well that is adapted for retaining a fluid. The fluid containment structure may be associated with or form a portion of an analysis site where a sample fluid retained in the fluid containment structure may be analyzed.

Abstract: A substrate having embossed thereon a plurality of shaped recesses of a predetermined precise geometric profile, each recess having a flat bottom surface having a major dimension of about 500 &mgr;m or less, the substrate being capable of undergoing a thermal cycle of about one hour at about 150° C. while maintaining about ±10 &mgr;m or less dimensional stability of the embossed shaped indentations, and wherein the substrate comprises an amorphous thermoplastic material. During the thermal cycle the substrate has an elastic modulus greater than about 1010 dynes/cm2 and a viscoelastic index of less than about 0.1.

Abstract: A method is provided for preparing a novel therapeutic agent-containing reservoir (26, 28) for use in conjunction with an electrotransport drug delivery system (10). A polymeric matrix is foamed in a selected atmosphere and then cross-linked to form a polymeric closed-cell foam matrix reservoir (26, 28). The method enables relatively smaller quantities of therapeutic agent to be loaded into the electrotransport system (10) and is especially useful for the transdermal delivery of more costly drugs, such as peptides and proteins produced from genetically engineered cell lines, and/or highly potent drugs for which a small dosage is efficacious. Reservoirs (26, 28) prepared according to this method and electrotransport devices (10) containing such reservoirs are also provided.

Abstract: A photocuring resin composition comprising a thermoplastic resin (a-1) having a radical polymerizing unsaturated group at its side chain and a photopolymerization initiator (a-2) and substantially not including a crosslinking compound other than (a-1), a photocuring sheet comprising a photocuring resin composition (A) laminated on a substrate sheet (B) and a process of production of the same, a photocuring decorative sheet and photocuring insert molding sheet using the same, and a process of production of a molded article using such a photocuring sheet and an insert molded article obtained by the same.