Lubricating Layer Patents (Class 376/415)
  • Patent number: 6574295
    Abstract: In order to provide a boiling water type nuclear reactor use control rod with a guide use roller which improves corrosive environment at a clearance in the guide use roller and suppresses a generation of stress corrosion cracking while maintaining sliding function of the control rod by the guide use roller, at least one of a handle 5, a lower portion supporting plate 2a and a dropping speed limiter 2 is provided with the guide use roller, and a space which causes water flow in a clearance between a pin 9 and a pin hole 12 in the guide use roller is provided adjacent the clearance.
    Type: Grant
    Filed: September 17, 2001
    Date of Patent: June 3, 2003
    Assignees: Hitachi, Ltd., Hitachi Engineering Co., Ltd.
    Inventors: Michio Nakayama, Norio Kawashima, Shinobu Okido
  • Patent number: 5805655
    Abstract: A protective coating to reduce stress corrosion cracking of zirconium alloy sheathing in nuclear reactors. The coating is graphite based and includes ZrO.sub.2 and ethyl cellulose and acts as a sacrificial layer to immobilize fission products by formation of Zr.sub.x I.sub.y C type compounds which do not cause stress corrosion cracking.
    Type: Grant
    Filed: April 10, 1997
    Date of Patent: September 8, 1998
    Assignee: Atomic Energy of Canada Limited
    Inventor: Paul Ka-Hang Chan
  • Patent number: 5581588
    Abstract: A method for mitigating crack initiation and propagation on the surface of metal components in a water-cooled nuclear reactor. An electrically insulating coating doped with a noble metal is applied on the surfaces of IGSCC-susceptible reactor components. The preferred electrically insulating material is yttria-stabilized zirconia doped with palladium or platinum. The presence of an electrically insulating coating on the surface of the metal components shifts the corrosion potential in the negative direction without the addition of hydrogen. Corrosion potentials .ltoreq.-0.5 V.sub.SHE are believed to be achievable even at high oxidant concentrations and in the absence of hydrogen, although the coatings are believed to be particularly suited to applications where a reductant, such as hydrogen, is present.
    Type: Grant
    Filed: June 23, 1995
    Date of Patent: December 3, 1996
    Assignee: General Electric Company
    Inventor: Peter L. Andresen
  • Patent number: 5539791
    Abstract: Zircaloy 2 and zircaloy 4 are zirconium alloys which are permitted and tried and tested in nuclear engineering and which have constituents with fixed concentration ranges. The properties, especially corrosion resistance, mechanical stability and sensitivity to pellet-cladding interaction of those alloys are subject to pronounced spreads of unknown origin. According to the invention, the tin content is between 1.4 and 1.8% by weight, the Fe content between 0.1 and 0.25% by weight, the Cr content between 0.1 and 0.3% by weight, the Si content between 0.05 and 0.02% by weight, the O content between 0.05 and 0.11% by weight, the C content below 0.02% by weight and the Ni content below 0.08% by weight. This restriction of the permissible concentration ranges ensures that the material properties are spread only within a narrow favorable range. A liner made from zirconium with an iron constituent of between 0.2 and 0.8% by weight is proposed for the inner lining of a fuel-rod sheathing tube.
    Type: Grant
    Filed: August 26, 1994
    Date of Patent: July 23, 1996
    Assignee: Siemens Aktiengesellschaft
    Inventors: Friedrich Garzarolli, Eckard Steinberg
  • Patent number: 5533077
    Abstract: An improved method for assembling bundles of nuclear fuel rods which reduces damage to the fuel cladding surface as the fuel rods are passed through an array of spacers. In particular, the invention prevents or greatly reduces the severity of longitudinal scratches on the fuel rods. The method uses thin-walled metallic tubes having a wall thickness of 0.003 to 0.006 inch and a yield strength in excess of 140,000 psi. The predetermined tube thickness ensures that the tube remains elastic. The tube deflects the cell springs when inserted in the spacer cells and reduces the load exerted on the fuel rods.
    Type: Grant
    Filed: February 22, 1995
    Date of Patent: July 2, 1996
    Assignee: General Electric Company
    Inventors: Eric B. Johansson, Edward S. Walker
  • Patent number: 5517541
    Abstract: The present invention provides a cladding having an outer circumferential substrate, a zirconium barrier layer metallurgically bonded to the inside surface of the substrate and an inner circumferential liner metallurgically bonded to the zirconium barrier. The inner circumferential liner is more ductile than conventional Zircaloy. The low ductility of the inner circumferential liner is obtained, for example, by using a zirconium alloy containing a low tin content (e.g. less than 1.2% by weight) and/or a low oxygen content (e.g. less than 1000 ppm). The inner circumferential liner is less than about 25 micrometers thick.
    Type: Grant
    Filed: May 10, 1994
    Date of Patent: May 14, 1996
    Assignee: General Electric Company
    Inventors: Herman S. Rosenbaum, Joseph S. Armijo
  • Patent number: 5493592
    Abstract: A fuel rod has a cladding including a thicker inner layer and a thin outer layer being metallurgically bound thereto. In view of the conditions prevailing on the inside of the cladding tube and the mechanical properties of the entire cladding tube, the inner layer is formed of zircaloy having a comparatively high Sn content and a low Fe and Fe+Cr content. The outer layer also contains virtually only zircaloy constituents, but in view of corrosion, H2 take-up and sensitivity to Li dissolved in the cooling water, the Fe and Fe+Cr content is greater than or at most equal to that of the inner layer, the chosen Sn content is less than 1.3% and the chosen Sn+Fe+Cr content is more than 1.0%. Low failure rates of the cladding tube are thereby achieved even for long service lives.
    Type: Grant
    Filed: September 13, 1994
    Date of Patent: February 20, 1996
    Assignee: Siemens Aktiengesellschaft
    Inventors: Friedrich Garzarolli, Eckard Steinberg
  • Patent number: 5469481
    Abstract: A method is provided for forming a three-layer cladding tube having an outer substrate, a zirconium barrier layer, and an inner liner having alloying elements, in which the zirconium barrier layer (located between an outer substrate and inner liner) is at least partially alloyed with alloying elements that impart resistance to corrosion. The barrier layer has a diffusion layer extending from its inner surface (facing the fuel) to the barrier layer's interior (the interior being defined between the barrier layer's inner and outer surfaces). At the interior edge of the diffusion layer, there will be substantially no alloying elements beyond those normally present in zirconium. The methods of forming such structure include a diffusion anneal of a three-layer cladding in the range of 650.degree.-1000.degree. C. for times between about 1 minute and 20 hours. This anneal drives some of the alloying elements from the inner liner into the zirconium barrier layer to form the diffusion layer.
    Type: Grant
    Filed: March 21, 1994
    Date of Patent: November 21, 1995
    Assignee: General Electric Company
    Inventors: Ronald B. Adamson, Daniel R. Lutz, Joseph S. Armijo
  • Patent number: 5267287
    Abstract: In a method for fabricating an end fitting (12,200) for a nuclear fuel assembly (10), wherein the end fitting includes at least one spring member (24,202) having an active external surface (32,206) for contacting rigid core support structure (100) in the nuclear reactor, the improvement comprising applying a coating to the active surface of the spring member. The coating is selected from the group consisting of nitrides, Cr, TiC, CrC, ZrC and NiTaB. The spring member is preferably Inconel and the coating is one of ZrN or TiN. Each spring member can be formed by nesting a plurality of spring elements (28,34,36 or 208,210) so that the spring elements are in contact with each other and the method includes applying said coating to each of the spring elements at least where they contact each other.
    Type: Grant
    Filed: September 25, 1992
    Date of Patent: November 30, 1993
    Assignee: Combustion Engineering, Inc.
    Inventor: William J. Bryan
  • Patent number: 4822559
    Abstract: A nuclear fuel element for use in power-producing nuclear reactors, comprising a circular metal cladding tube containing sintered cylindrical oxide fuel pellets, the tube being formed internally with a substantially cylindrical inner surface having a plurality of longitudinal ribs forming axially extending channels. The fuel pellets have chamfered endfaces creating toroidal spaces at the adjoining ends of the fuel pellets, the ratio of axial channel to toroidal space volumes including any pellet dishing being at most about one (1);a process for the manufacture of such fuel element.
    Type: Grant
    Filed: September 10, 1987
    Date of Patent: April 18, 1989
    Assignee: Studsvik Energiteknik AB
    Inventor: Hilding Mogard
  • Patent number: 4783311
    Abstract: Nuclear fuel elements are provided that are resistant to pellet-clad interaction. The closed end nuclear fuel elements comprise a zirconium or zirconium alloy tube that has a layer of lubricant, preferably graphite, on the inner surface thereof, and enriched uranium dioxide pellets that have a coating on the outer surface thereof of a thickness sufficient to absorb fission products. The coating on the pellets may be a burnable absorber or a material that has a relatively low neutron absorption compared to a burnable absorber. The combination of the layer on the tube and the coating on the pellets reduces both the stress level and the concentration of damaging fission products that would contact and react with the layer of lubricant about the inside surface of the tubular cladding and thus reduces conditions for pellet-clad interaction.
    Type: Grant
    Filed: July 15, 1987
    Date of Patent: November 8, 1988
    Assignee: Westinghouse Electric Corp.
    Inventor: Harry M. Ferrari
  • Patent number: 4541984
    Abstract: A getter-lubricant coating system between the nuclear fuel and the fuel cladding minimizes the pellet-clad stress concentration and renders fission gases and impurities unreactive to the cladding. The getters are matched to the lubricant matrix such that they are homogeneously dispersed in the matrix and are physically and/or chemically bound in place. A preferred form of the getter is a graphite or boron nitride intercalate of the getter material.
    Type: Grant
    Filed: September 29, 1982
    Date of Patent: September 17, 1985
    Assignee: Combustion Engineering, Inc.
    Inventor: David N. Palmer
  • Patent number: 4316771
    Abstract: Nuclear fuel for use in nuclear reactors is provided in the form of a nuclear fuel element with an interior barrier layer interposed between the sheath and the fuel. The barrier layer incorporates particles of copper in finely divided form to provide by combination with cadmium, which is released during irradiation of the fuel, a stabilized copper-cadmium compound localized intermediate the fuel and the sheath, thus impeding attack on the sheath by the released cadmium. There is further provided a simple, low cost method for applying the barrier layer in a nuclear fuel element.
    Type: Grant
    Filed: September 19, 1979
    Date of Patent: February 23, 1982
    Assignee: Canadian General Electric Company Limited
    Inventor: Harvey R. Lee