Abstract: In an optical waveguide comprising a transparent cladding (1) filled with a transparent liquid core (2) having a higher refractive index than the cladding, a liquid consisting of an oligomer having a phosphazene skeleton, typically phosphazene oil is used as the core (2). The waveguide is well resistant to heat and weathering, ensures stable performance in a wide temperature range over a long period of time, and provides good light transmission in a wide wavelength range covering the UV, visible and IR spectra.

Abstract: A light scattering light guide, which is capable of converting a light flux of a relatively small cross-sectional area into a light flux of a relatively large area with high efficiency and uniformity, manufacturing method thereof, and applied optical apparatuses such as backlight light source apparatuses and light branching/mixing devices which make effective use of the characteristics of said light scattering light guide. Such light scattering light guide is obtained by utilizing various structures with irregular refraction indexes generated in the process of polymerization of organic materials. The values of scattering power (effective scattering irradiation parameter E, etc.) are selected according to applications. The mechanism for forming the structures with irregular refraction indexes by the polymerization process of organic materials is based on, for example, the difference in compatibility, reactivity, density, etc. among the organic materials.

Abstract: A polymer core optical wave-guide which comprises a substrate, a buffer layer formed on the surface of the substrate made of a SiO.sub.x N.sub.y H.sub.z film of desirable thickness having a refractive index of n.sub.b, an approximately rectangle-shaped core formed on the buffer layer made of a polymer material having a refractive index of n.sub.w (n.sub.w >n.sub.b), a cladding layer covering the surface of the core having a refractive index of n.sub.c (n.sub.c <n.sub.w).

Abstract: A copolymer for optical fiber applications is the polymerization product of a mixture comprising a fluorinated itaconate and an alkyl (meth)acrylate.

Abstract: A process for producing a cured composite and flexible light pipe, in which a molten cladding polymer and a crosslinkable core mixture are concurrently and coaxially extruded through a core mixture delivery tube of a coextrusion die, the extruded tubular cladding is filled with the extruded crosslinkable core mixture, and the crosslinkable core mixture is cured within the tubular cladding.

Abstract: There is provided an aromatic polycarbonate copolymer obtained by reacting a dihydric phenol component comprising mainly 2,2-bis(4-hydroxyphenyl)-1,1,1,3,3,3-hexafluoropropane and 9,9-bis(4-hydroxyphenyl)fluorene or 1,1-bis(4-hydroxyphenyl)-1-phenylethane in a prescribed ratio with a carbonate precursor substance. This aromatic polycarbonate copolymer has a specific viscosity in a limited range. The aromatic polycarbonate copolymer is excellent in optical characteristics, transparency, hydrolysis resistance, heat resistance, oxidation resistance, and heat stability and good in moldability, and is suitable for a plastic optical waveguide that is small in transmission loss and excellent in heat resistance.

Abstract: Novel acrylic acid copolymer primer compositions are disclosed for bonding electroconductive metal oxide films to plastic substrates for electrochromic articles.

Abstract: An organic functional thin film is comprised of a polymer of a molecule having two or more identical or different groups selected from the group consisting of a carbonyloxycarbonyl group, a carboxylic acid group, a carboxylic acid halide group, a carboxyl group, a --COCl group, an --NCO group, a --CHO group and an epoxy group and a molecule having two or more identical or different groups selected from the group consisting of an amino group, groups containing at least one amino proton, an alkylamino group, a silylated alkylamino group, a carboxylic acid group and a hydroxyl group, formed by vapor-phase deposition, the polymer-forming molecules having at least partially one or more donor and/or acceptor groups. Similar organic thin films are also disclosed. These organic thin films are useful for various electronic applications.

Abstract: A method of forming optical light guides through silicon is disclosed wherein such light guides extend from a first (or front) surface along a preferred crystallographic direction to a second (or back) surface.

Abstract: A method is provided for forming in a semiconductive conjugated polymer at least first and second legions having different optical properties. The method comprises: forming a layer of a precursor polymer and permitting the first region to come into contact with a reactant, such as an acid, and heat while permitting the second region to come into contact with a lower concentration of the reactant. The reactant affects the conversion conditions of the precursor polymer in such a way as to control the optical properties of at least the first region so that the optical properties of the first region are different from those of the second region. The precursor polymer may comprise a poly(arylene-1, 2-ethanediyl) polymer, at least some of the ethane groups of which include a modifier group whose susceptibility to elimination is increased in the presence of the reactant.

Abstract: The present invention relates to provide a drawn optical transmission medium having excellent heat resistance and a continuous refractive index distribution in a good productivity at a low cost, and the disadvantages in a conventional synthetic resin optical transmission medium can be eliminated, which method is characterized by a step of crosslinking a polymer having a continuous refractive index gradient distributed from the peripheral portion to the central portion in its cross section and having a crosslinkable functional groups, after the step of heating and drawing.

Abstract: A new scintillating optical fiber is used in an array as a scintillator plate for imaging with high energy radiation, particles and the like. The scintillating optical fiber has an inner plastic core fiber which is transparent to visible radiation and has an index of refraction of about 1.45 or greater. The inner plastic core fiber has a plastic cladding material which has an index of refraction less than that of the inner plastic core fiber. The inner plastic core fiber contains a polymeric matrix material; a metal moiety; and an organic fluorescent material. The scintillator plates are useful in producing high efficiency and high resolution radiographic systems for x-ray medical diagnosis or non-destructive inspection as well as non-destructive inspection with thermal neutrons.

Abstract: The use of an ethylenically-terminated urethane oligomer for the provision of a radiation-cured coating material of an optical fiber, the urethane oligomer being derived from reactants which include a hydroxyl-terminated polyester polyol having dimer acid residues in its structure.

Abstract: Novel acceptor-donor-acceptor compounds for use in forming a thermally-stable electro-optic waveguide are disclosed. Also disclosed is a thermally stable waveguide material containing thermally stable acceptor-donor-acceptor or donor-acceptor-donor guest dipole compounds in dissolved form in a polyimide matrix. The waveguide has selected regions in which the net dipoles of the guest molecules are oriented, for electro-optic switching when an electric field is placed across these regions.

Abstract: An illuminator apparatus has a light source and a liquid-core light guide comprising a tubular flexible sheath of a fluorocarbon polymer material which is filled with a lightguiding fluid such as glycol, a salt solution containing a chloride, fluoride or phosophate, phenylmethyl silicone oil (n.apprxeq.1.57), PCTFE oil, polychlorotrifluoroethylene oil (n=approx. 1.40) or also pure water. The tubular sheath is internally coated with a thin film of Teflon AF.RTM., the refractive index of which is lower than that of the sheath material.

Abstract: An organic molecular crystal comprising the compound N-isopropyl-N'-(4-acetylphenyl)-urea is used for preparing an optical wavelength conversion device. Especially, the device may comprise a core and a clad wherein the organic crystal is used as the core.

Abstract: Optical waveguide devices for interconnecting optical fibers and use in integrated optical systems. The invention includes a substantially dry method for making the devices and intermediate elements.

Abstract: A method for manufacturing a molded waveguide (50) is provided. A first cladding layer (20) is provided. Channels (21) are formed in the first cladding layer (20). A second cladding layer (40) is subsequently provided. The channels (21) in the first cladding layer (20) are then filled with an optically transparent polymer. The second cladding layer (40) is subsequently affixed over the channels (21) of the first cladding layer (20), thereby enclosing the channels (21).

Abstract: Lowered cost fabrication including preparation of large bodies of void-free, high-silica glass, depends upon gellation of an aqueous sol of colloidal silica particles, followed by drying and firing of such gel. Freedom from cracks in the dried gel is the consequence of included polymeric material which wets the particles. The polymeric material is removed by thermal decomposition attended upon temperature attained in firing.

Abstract: An optical fiber includes an optical fiber element having a core layer and a cladding layer formed on the core layer, and a coating layer having a refractive index lower than at least the refractive index of the cladding layer, or a coating layer including at least one of a predetermined saturated higher fatty acid and alkylpolysiloxane.

Abstract: An optical waveguide is disclosed with a substantially planar substrate and a waveguide layer applied to the substrate. The invention resides in that the substrate consists of a synthetic resin or of a material having a high organic proportion. This has the advantage that the high index of refraction of the inorganic waveguide layer is combined with the material properties of the synthetic resin substrate, such as, for example, breaking resistance, plastic and thermoplastic moldability, photochemical structuring ability, and others.

Abstract: This invention provides a fiber waveguide with a liquid crystal core. The liquid crystals are aligned in layers with molecular directors approximately parallel to each other. An electric field can be applied to the liquid crystal core to provide linear and nonlinear optical modulation. Alone or in combination with polarizers, reflectors, and birefringent elements, the waveguide of this invention provides phase, polarization and intensity modulation, spectral filtering, and second harmonic generation.

Abstract: An optical wavelength conversion module having a laser light source, a lens system for managing the laser beam, and a conversion element. The laser light source generates a beam of laser light of a substantially circular cross-section having an aspect ratio of 1.3 or less. The substantially circular beam is collimated and condensed by the lenses and directed into the core of the conversion element which then emits converted light. The optical wavelength conversion module is small in size and produces converted light with high efficiency.

Abstract: An optical fiber device comprising an optical fiber comprising a core made of an organic crystal and a cladding made of glass, the device generating second harmonics of a laser light that has been launched into the core, the device further comprising a buffer layer on at least one end faces of the optical fiber, and a water barrier layer on the surface of the buffer layer, the buffer layer being such that the organic crystal of the core is not dissolved therein.

Abstract: An evanescent wave sensor and method for use in analyzing one or more media, the sensor including a waveguide having first and second wave propagating surfaces. The waveguide propagates an input signal along the waveguide between the first and second surfaces. The first surface receives a first radiation signal which indicates the presence of a first analyte, and the second surface receives a second radiation signal representing one or both of a second analyte and a reference. The first and second surfaces can both be contacted with a single medium, or with two separate media, and one or more output signals can be detected.

Abstract: An optical frequency conversion element has a wave-guiding layer which consists of a .chi..sup.(2) -active ferroelectric liquid crystal. The monomeric or polymeric liquid crystal material has a periodic structure which permits the so-called quasi phase matching of a guided laser beam. The period length of the structure is equal to twice the coherence length l.sub.c =.pi./.DELTA..beta. of the material, whereby .DELTA..beta.=.beta..sub.o (2.omega.)-2.beta..sub.o (.omega.), with .omega.=angular frequency of the fundamental wave, 0=zero-order mode and .beta.=propagation constant of the mode.

Abstract: An organic material for non-linear optics, in which the structure of the molecule includes an electron donor group and an electron attractor group connected by means of an electron-transmitting group, the material being characterized by the fact that it satisfies the formula: ##STR1## where R is selected from (CH.sub.3).sub.2 N and CH.sub.3 O, with the first material being dimethylamino 4, cyano 4' biphenyl and the second being methoxy 4, cyano 4' biphenyl.

Abstract: Polyimide optical waveguide structures comprising a core within a cladding wherein at least one of the core and the cladding is a polyimide containing 6FDA, BTDA, an aromatic diamine having bulky methyl groups ortho to the amine, and a co-diamine wherein the polyimides have the properties of low optical loss, low optical absorbance, controllable refractive index, and high thermal stability, and wherein the polyimides are photosensitive and solvent resistant.

Abstract: A waveguide structure is directly extruded onto a surface from a nozzle placed a predetermined distance above the surface and which is moved relative to the surface, preferably by means of a translation table. The predetermined distance is preferably maintained constant and the speed of relative motion regulated to achieve a uniform degree of molecular orientation within the extruded material, thus maintaining a sufficiently uniform refractive index along the axis of the waveguide. Partitions within the nozzle allow the formation of a layered waveguide or the simultaneous formation of concentric cladding or protective layers. The waveguides are advantageously formed as a curtain which is later patterned, by direct writing on the surface or between chips mounted on an electronic module.

Abstract: A new scintillating optical fiber is used in an array as a scintillator plate for imaging with high energy radiation, particles and the like. The scintillating optical fiber has an inner plastic core fiber which is transparent to visible radiation and has an index of refraction of about 1.45 or greater. The inner plastic core fiber has a plastic cladding material which has an index of refraction less than that of the inner plastic core fiber. The inner plastic core fiber contains a polymeric matrix material; a metal moiety; and an organic quench-resistant fluorescent material. The scintillator plates are useful in producing high efficiency and high resolution radiographic systems for x-ray medical diagnosis or non-destructive inspection as well as non-destructive inspection with thermal neutrons.

Abstract: A transparent thermoplastic molding compound consisting of 40 to 90% by weight of units derived from tetrafluoroethylene, and 60 to 10% by weight of units derived from compounds of formula I or II:CF.sub.2 .dbd.CF--O--(CF.sub.2 --CF(CF.sub.3)--O).sub.m --(CF.sub.2).sub.n --CF.sub.3 (I)CF.sub.2 .dbd.CF--O--(CF.sub.2 --CF(CF.sub.3)--O).sub.p --(CF.sub.2).sub.q --COO--R (II)is particularly suitable for manufacturing the sheath of beam waveguides whose core has a higher transparency than polymethyl methacrylate.

Abstract: A substantially dry method for making an optical waveguide device with at least one buried channel waveguide in a laminated and hardened matrix. The method begins with exposing to light a region of a substantially dry photohardenable film adhered to a support. Then a first substantially dry photohardenable layer which is adhered to a support is laminated to one side of the film. Then the support is removed from the film. Then a second substantially dry photohardenable layer which is adhered to a support is laminated to the other side of the film. Then the layers and film are hardened.

Abstract: An electro-optic waveguide deflector appropriate for use in an optical pickup head uses any film exhibiting high second order susceptibility such as nonlinear optic organic Langmuir-Blodgett films or nonlinear optic organic poled polymer films, or a liquid-crystal overlay cell. The deflector comprises a base support, a planar electrode layer disposed on the base support, a first buffer layer atop the first electrode layer, and an optical waveguide layer overlying the first buffer layer and planar electrode. When nonlinear optic films are used to form the waveguide layer, a second buffer layer is disposed atop the waveguide layer, and a pair of spaced electrodes is disposed atop the second buffer layer. When a nematic-type liquid-crystal overlay cell is used, it is disposed atop a passive dielectric waveguide, and a pair of spaced electrodes is disposed on the under surface of the liquid-crystal cell cover plate.

Abstract: In a method of manufacturing a planar optical waveguide based entirely on polymer materials an active polymer is deposited onto a semiconductor substrate between two layers of buffer polymers chosen so that the difference in refractive index on each side of the active polymer is between 0.005 and 0.5 and preferably between 0.01 and 0.4.

Abstract: The present invention is directed to a fiber optic sensor for analyzing pH which comprises (a) a fluorescence-based fiber optic sensor; and (b) a fluorescent dye-polymeric matrix in contact with the sensor, wherein the fluorescent dye is seminaphthorhodaflor-1-isothiocyanate, the polymer is a hydrogel selected from the group consisting of polyhydroxyethylmethacrylate, polyvinylpyrrolidone, cellulose, dextrans, and polysaccharides, and the dye is chemically bonded to the polymer.

Abstract: A method for manufacturing a molded waveguide (50) is provided. A first cladding layer (20) is provided. Channels (21) are formed in the first cladding layer (20). A second cladding layer (40) is subsequently provided. The channels (21) in the first cladding layer (20) are then filled with an optically transparent polymer. The second cladding layer (40) is subsequently affixed over the channels (21) of the first cladding layer (20), thereby enclosing the channels (21).

Abstract: A method of manufacturing a multimode optical transmission medium from a synthetic resin having the distribution of refractive index varying continuously in a fixed direction. In the method, the polymerization is caused to proceed utilizing the effect of diffusion or exclusion of a monomer in the gel formed at the polymerization initiating terminal. Therefore, this method is free from the defects of methods using conventional polymerization reactions, and has an extremely high productivity.

Abstract: An optical article is disclosed comprised of a support including a portion adjacent one major surface which is transparent to the electromagnetic radiation sought to be propagated, an organic layer unit capable of converting a portion of polarized electromagnetic radiation of a selected wavelength to its second harmonic wavelength, means for optically coupling into said organic layer unit polarized electromagnetic radiation of a selected wavelength in its zero order transverse magnetic mode, and means for receiving from the layer unit a portion of the electromagnetic radiation in the form of a first order transverse magnetic mode. The organic layer unit has a thickness which is at least 70 percent cf the wavelength of the zero order transverse magnetic mode and differs by less than 100 .ANG. from the thickness required for identical propagation constants of the zero and first order transverse magnetic modes.

Abstract: A process for the manufacture of a multi-layer polymer optical fiber having a graded optical refractive index profile. This fiber is comprised of an inner core layer, one or more intermediate layers and an outer clad layer, each layer being extruded from a polymer material. All layers are arranged in a concentric configuration, with the outer clad layer enclosing all other layers.

Abstract: The present invention provides a resin molded body for optical parts, and comprises a solid solution of a polycarbonate and a polyester carbonate.In the resin molded body of the present invention, when the amount incorporated of the polyester carbonate is increased, the light transmission loss is increased, but the distortion temperature is considerably raised and a high heat resistance is obtained.

Abstract: An optical switch with improved stability which has a flat waveguide including at least two optical waveguides which are made of a glass containing silica and arranged closely each other, at least a core part of each of the optical waveguides consisting of an amorphous material which is prepared by a sol-gel method and contains organic molecules doped and orientated in a direction of electrostatic field by the application of an electrostatic field, and means for changing an optical path through change of a refractive index of the core part by applying an external force to the core part, which means is provided near the core part.

Abstract: An optical waveguide (11) is composed substantially entirely of triazine.

Abstract: A flame retardant plastic optical fiber cord comprising a plastic optical fiber comprising a core and a cladding, and a jacket layer provided on the optical fiber, wherein the jacket layer has an oxygen index of not less than 25 as measured by the method stated in JAPANESE INDUSTRIAL STANDARD K 7201.

Abstract: A nonlinear all-optical switching device including a waveguide of an organic conjugated material which forms a nonlinear optical medium. The nonlinear material has an index of refraction which is a function of the local intensity of light. Light beams passing through the waveguide intersect and interact causing diffraction into secondary beams. The intensity of the diffracted beams is a function of the intensity and frequency of the intersecting light beams. The nonlinear material can respond extremely fast and provide a bandwidth exceeding 500 GHz.

Abstract: Optical fibres, and a process for their production, are described which comprise tubular plastic cladding and a core of a polymer whose refractive index is at least 1% greater than that of the cladding material. The core is obtained from a polymerisable mixture which comprises compounds containing epoxy groups, of which at least 10% by weight are siloxanes containing epoxy groups.

Abstract: Esters of .alpha.-fluoroacrylic acid are accessible by hydrolysis of an .alpha.-hydroxymethyl-.alpha.-fluoromalonic acid ester, decarboxylation and dehydration of the hydrolysis product and subsequent esterification of the resulting .alpha.-fluoroacrylic acid with an alcohol. The esters are polymerizable and are suitable for use as a starting material for preparing fluoropolymers which in turn are usable as materials for manufacturing transparent articles. The polymers are high-molecular and non-crystalline and have softening temperatures of above 100.degree. C.

Abstract: 4'-Dimethylamino-4-methylstilbazolium methanesulfonate is prepared by the reaction of methyl methanesulfonate with 4-picoline followed by condensation with p-dimethylaminobenzaldehyde. Its hydrated form has second harmonic generation optical properties, but this is not true of the anhydrous form. Thus, the hydrated form is useful in the production of optical waveguides, spatial light modulators and the like.

Abstract: Transparent thermoplastic molding composition of a polymer containinga) 10 to 95% by weight of units which are derived from a compound of the formula (I)R.sub.2.sup.1 C.dbd.CF--COO--C(CF.sub.3).sub.2 R.sup.2 (I)b) 90 to 5% by weight of units which are derived from one or more compounds of the formula (II) ##STR1## and c) 0 to 85% by weight of units which are derived from a compound of the formula (III)R.sub.2.sup.7 C.dbd.CF--COO--CR.sub.3.sup.8 (III)The molding composition is used for the production of optical objects, in particular for the production of optical fibers.

Abstract: An optical waveguide having a core/sheath structure whose sheath comprises a terpolymer based on vinylidene fluoride, tetrafluoroethylene and hexafluorpropylene, is suitable for transmission paths of ca. 10 to 100 m an can also be used at a temperature of above 100.degree. C. without significant reduction of the transmission path.