Special Atmosphere Patents (Class 419/57)
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Patent number: 5338372Abstract: Anisotropic rare-earth permanent magnets characterized in that an aggregate of a plurality of blocks, to each of which anisotropy is imparted, is formed using powders of magnetic material containing rare-earth elements, and the adjoining blocks are powder-metallurgically bonded together under pressure into one piece; a method of making anisotropic rare-earth permanent magnets by molding anisotropic blocks by magnetic-field molding, arranging, aggregating and sealing a plurality of blocks in a bag, and cold hydrostatic pressing the aggregate of blocks in the absence of magnetic field; and a suitable metal mold for magnetic-field molding anisotropic permanent magnets of a relatively large size.Type: GrantFiled: December 3, 1992Date of Patent: August 16, 1994Assignee: Hitachi Metals, Ltd.Inventor: Kazunori Tabaru
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Patent number: 5330703Abstract: A shaped material comprising powders of alloys containing easily oxidizable elements is fired in a hydrogen-based atmosphere containing at least one hydrocarbon gas in a total amount of 0.01-5.0 volume %. Therefore, the amount of oxides formed on the surfaces of material powder particles is reduced, and the sinterability of powder particle surfaces is improved owing to the sticking of atomic carbon thereto and thereby the mutual diffusion of powder particles becomes easy. As a result, there can be obtained a sintered alloy of desired density, superior in oxidation resistance, etc.Type: GrantFiled: January 27, 1993Date of Patent: July 19, 1994Assignee: NGK Insulators, Ltd.Inventors: Tsuneaki Ohashi, Nobuo Tsuno
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Patent number: 5314656Abstract: Transition metal carbonitrides (in particular, titanium carbonitride, TiC.sub.0.5 N.sub.0.5) are synthesized by a self-propagating reaction between the metal (e.g., titanium) and carbon in a nitrogen atmosphere. Complete conversion to the carbonitride phase is achieved with the addition of TiN as diluent and with a nitrogen pressure .gtoreq.0.6 MPa. Thermodynamic phase-stability calculations and experimental characterizations of quenched samples provided revealed that the mechanism of formation of the carbonitride is a two-step process. The first step involves the formation of the nonstoichiometric carbide, TiC.sub.0.5, and is followed by the formation of the product by the incorporation of nitrogen in the defect-structure carbide.Type: GrantFiled: November 20, 1992Date of Patent: May 24, 1994Assignee: The Regents of the University of CaliforniaInventors: Zuhair A. R. Munir, Maryam Eslamloo-Grami
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Patent number: 5312580Abstract: Porous metal components for high temperature fuel cells which are made by integrating the heretofore employed, separate tape casting and pack cementation processes. Particles of a base metal and a master alloy are suspended in a liquid medium in which a binding agent and a halide activator are dispersed. The suspension is cast into the shape wanted in the component, typically by tape casting; and the cast structure is heated to remove the liquid medium, leaving a flexible, green cast structure commonly referred to as a tape. The green tape is so heated as to: (a) burn out the binder in the tape; (b) form an alloy of the base metal and an alloying metal in the master alloy; and (c) sinter the alloy particles into a porous, coherent metal structure.Type: GrantFiled: May 12, 1992Date of Patent: May 17, 1994Inventors: Diane S. Erickson, Estela T. Ong
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Aluminum-alloy powder, sintered aluminum-alloy, and method for producing the sintered aluminum-alloy
Patent number: 5304343Abstract: An aluminum-alloy main-starting powder for producing a sintered aluminum-alloy consists of from 0.1 to 3.0% of Cu, the balance being Al and unavoidable impurities. Mother alloy powder consists of from 4 to 20% of Mg, from 12 to 30% of Si, and Al and unavoidable impurities in balance.Type: GrantFiled: October 19, 1992Date of Patent: April 19, 1994Assignee: Showa Denko K.K.Inventors: Shin Miura, Youichi Hirose, Yoshio Machida, Mitsuaki Sato -
Patent number: 5286441Abstract: A silver-metal oxide composite material comprising a silver matrix, (a) from 1 to 20% by weight, in terms of elemental metal, of an oxide of at least one element selected from the group consisting of Sn, Cd, Zn and In and, optionally, (b) an oxide of Mg, Zr, etc. and/or (c) an oxide of Cd, Sb, etc.; the oxides being dispersed in the form of fine particles with a particle size of not more than about 0.1 .mu.m uniformly and being bound to the silver matrix with no space left, and a process for producing the same. The composite material is excellent in physical and chemical strengths at high temperatures. The process can produce the composite product even with thick walls, within a markedly short time in high productivity. The composite material is useful as electrical contact materials and electrode materials for electric welding.Type: GrantFiled: June 3, 1992Date of Patent: February 15, 1994Assignees: Akira Shibata, Sumico Management Planning Company, Ltd.Inventor: Akira Shibata
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Patent number: 5283031Abstract: A process for producing a precision metal part of a sintered body by powder molding comprises using a metal powder of which the oxygen content and the hydrogen reduction loss are controlled to 0.5-6 wt. % and 1-7 wt. %, respectively. The sintered body has a high density near the theoretical density and is excellent in dimensional accuracy. The molding is facilitated, and the process is simple.Type: GrantFiled: July 23, 1991Date of Patent: February 1, 1994Assignee: Citizen Watch Co., Ltd.Inventors: Naoto Ogasawara, Kenji Kurimura, Ken-ichi Yoshioka, Shigeru Saito, Takao Kasai, Masami Hoshi, Seiichi Nakamura
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Patent number: 5283030Abstract: A coated cemented carbide alloy, excellent in toughness as well as wear resistance and which is used for cutting tools and wear resistance tools is provided herein. This coated cemented carbide alloy is composed of a cemented carbide substrate consisting of a hard phase of at least one member selected from carbides, nitrides and carbonitrides of the Group IVb, Vb and VIb metals of Periodic Table and a binder phase consisting of at least one member selected from the iron group metals, and a monolayer or multilayer provided on the substrate consisting of at least one member selected from the carbides, nitrides, oxides and borides of Group IVb, Vb and VIb metals of Periodic Table, solid solutions thereof and aluminum oxide, and wherein a binder phase-enriched layer is provided in a space 0.01 mm and 2 mm below the surface of the substrate with A-type and/or B-type pores inside the binder phase-enriched layer.Type: GrantFiled: October 7, 1992Date of Patent: February 1, 1994Assignee: Sumitomo Electric Industries, Ltd.Inventors: Minoru Nakano, Toshio Nomura
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Patent number: 5269830Abstract: A process for synthesizing intermetallic compounds from elemental powders. The elemental powders are initially combined in a ratio which approximates the stoichiometric composition of the intermetallic compound. The mixed powders are then formed into a compact which is heat treated at a controlled rate of heating such that an exothermic reaction between the elements is initiated. The heat treatment may be performed under controlled conditions ranging from a vacuum (pressureless sintering) to compression (hot pressing) to produce a desired densification of the intermetallic compound. In a preferred form of the invention, elemental powders of Fe and Al are combined to form aluminide compounds of Fe.sub.3 Al and FeAl.Type: GrantFiled: October 26, 1990Date of Patent: December 14, 1993Assignee: The United States of America as represented by the United States Department of EnergyInventors: Barry H. Rabin, Richard N. Wright
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Patent number: 5266263Abstract: The invention relates to the reprocessing of used evaporation boats. This is done by a method which comprises comminuting used, aluminum-contaminated evaporation boats and roasting them in a nitrogen-containing atmosphere.Type: GrantFiled: October 28, 1992Date of Patent: November 30, 1993Assignee: Elektroschmelzwerk Kempten GmbHInventors: Klaus Hunold, Peter Matje
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Patent number: 5266264Abstract: The present invention relates to a process for producing sinters, including a steps of mixing a powder material with a binder, injection molding the mixture, and then dewaxing and sintering the resulting injection molded article, wherein the binder comprises at least one of: copolymer, a mixture of copolymer, paraffine wax, carnauba wax, a mixture of the paraffine wax and the carnauba wax, a plasticizer, and a lubricant. According to the present invention, the dewaxing step comprises heating the injection molded article to a temperature of 250.degree.-500.degree. C. in a heating rate of 5.degree.-100.degree. C./hour under the pressure not higher than 1 Torr in order to remove 40%-95 % by weight of the binder components. Further, the temperature elevation in the sintering step is started in a vacuum atmosphere and replacing the atmosphere with an inert gas atmosphere in the process of temperature elevation.Type: GrantFiled: December 31, 1991Date of Patent: November 30, 1993Assignee: The Japan Steel Works Ltd.Inventors: Ritsu Miura, Hirokazu Madarame, Masahiro Uchida, Yasushi Owaki
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Patent number: 5252255Abstract: A conductive metal-filled substrate is formed by intermingling copper or nickel particles into the substrate, contacting the metal particles with a specified developing agent, and heating the metal particles and the developing agent. The filled substrates are electrically conductive and are useful for a variety of uses such as EMI shielding.Type: GrantFiled: June 11, 1990Date of Patent: October 12, 1993Assignee: Akzo America Inc.Inventors: Paul Y. Y. Moy, William J. E. Parr, Dieter Frank, Ronald E. Hutton
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Patent number: 5250254Abstract: A compound for producing sintered parts in an injection molding process and the molding process used to form the parts. The compound contains materials that allow the parts to be formed at lower temperatures and higher production rates when compared to more conventional processes.Type: GrantFiled: December 20, 1991Date of Patent: October 5, 1993Assignee: Sumitomo Metal Mining Co., Ltd.Inventors: Masakazu Achikita, Akihito Ohtsuka
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Patent number: 5242654Abstract: A process for producing strip products which comprises forming an aqueous slurry of a suspension of metallic particles in a film forming cellulose derivative, depositing a quantity of the slurry onto a support surface, drying the slurry to form a self supporting flat product, removing the dried product from the support surface and roll compacting the same to produce a green strip. The green strip is supported on a moving surface as it travels to and enters a heater in which it is heated in an oxidising atmosphere to a temperature at which substantially all traces of the cellulose derivative are removed. The heated strip is fed while still on the moving support surface to and through a sinter furnace to form a coherent strip of the required composition.Type: GrantFiled: January 27, 1992Date of Patent: September 7, 1993Assignee: Mixalloy LimitedInventors: Robert F. Ward, Nigel J. Brooks
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Patent number: 5238883Abstract: Self-supporting bodies are produced by reactive infiltration of a parent metal into a boron donor material and a carbon donor material. The reactive infiltration typically results in a composite comprising a boron-containing compound, a carbon-containing compound and residual metal, if desired. The mass to be infiltrated may contain one or more inert fillers admixed with the boron donor material and carbon donor material. The relative amounts of reactants and process conditions may be altered or controlled to yield a body containing a wide ranging varying volume percentage of ceramic, metal, and porosity.Type: GrantFiled: July 12, 1990Date of Patent: August 24, 1993Assignee: Lanxide Technology Company, LPInventors: Marc S. Newkirk, William B. Johnson
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Patent number: 5227235Abstract: The invention provides a composite soft magnetic material which is prepared by coating soft magnetic metal particles with a high resistance soft magnetic substance, preferably by mechano-fusion, applying electricity to the coated particles in a mold cavity between punches serving as electrodes, for example, to thereby create a plasma, and thereafter further conducting electricity to effect plasma activated sintering. There is obtained a composite material which possesses both the high saturation magnetic flux density and high magnetic permeability characteristic of the soft magnetic metal and the high electric resistivity characteristic of the high resistance soft magnetic substance.Type: GrantFiled: May 8, 1991Date of Patent: July 13, 1993Assignee: TDK CorporationInventors: Hideharu Moro, Yasuharu Miyauchi
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Patent number: 5225155Abstract: Methods and apparatus for protecting extruded metal powder green bodies (34) during firing are provided. In certain embodiments, one or more green bodies (34) are housed in a non-gas tight chamber (13) located in the hot zone (24) of a cold-wall vacuum/atmosphere furnace (10). Furnace gas, e.g., hydrogen, is supplied to the interior of the chamber (13). The resulting one-way flow out of the chamber (13) protects the green bodies (34) from the backflow of burn-out products, as well as from contaminants arising from the walls and internal components of the furnace (10). In other embodiments, green bodies (34) are housed in individual non-gas tight containers (36). The containers (36) minimize the amount of furnace gas which comes into contact with the green bodies (34) during sintering and thus minimize the level of exposure of the green bodies (34) to oxidative impurities in the furnace gas. When composed of the same material as the green bodies, the containers (36) also perform a getter function.Type: GrantFiled: July 22, 1991Date of Patent: July 6, 1993Assignee: Corning IncorporatedInventors: Leslie E. Hampton, David S. Weiss
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Patent number: 5217541Abstract: A permanent magnet essentially consisting of in weight percent, 60% to 68% at least one transition element by weight, 30% to 38% at least one rare earth element by weight, 0.1% to 1.5% nitrogen by weight, and 0.8% to 1.5% boron by weight is disclosed. A method for producing the permanent magnet containing at least one rear element, at least one rare earth element, nitrogen and boron includes melting, cooling, milling, magnetizing, and compacting the transition element, the rare earth element and boron to form a green compact, and then sintering the green compact in nitrogen atmosphere having a constant partial pressure for 1 to several hours to form the permanent magnet.Type: GrantFiled: August 26, 1991Date of Patent: June 8, 1993Assignee: High End Metals Corp.Inventors: Tsung-Shune Chin, Shiang-Jiun Heh, Ken-Der Lin
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Patent number: 5167913Abstract: A method of forming an adherent layer of metallurgy on a ceramic substrate which includes the steps of obtaining a ceramic material containing a polymeric binder and copper metallurgy patterns within the ceramic body. In one embodiment of the invention, the ceramic body also contains MgO.Thereafter, a surface layer of metallurgy is formed on the surface of the ceramic body. In one embodiment, the surface layer is nickel and in another embodiment, the surface layer is copper or gold.Then, the ceramic body undergoes a sintering cycle which includes the steps of pyrolysis, binder burnoff and, lastly, densification and, in some cases, crystallization. During densification and crystallization, there is a predetermined steam atmosphere which meets the following requirements: a partial pressure of oxygen less than that necessary to satisfy the equilibrium equation 4Cu+O.sub.2 =2Cu.sub.2 O; and a partial pressure of oxygen less than or equal to that necessary to satisfy the equilibrium equation 2Ni+O.sub.Type: GrantFiled: December 23, 1991Date of Patent: December 1, 1992Assignee: International Business Machines CorporationInventors: John Acocella, Philip L. Flaitz, Raj N. Master, Chandrasekhar Narayan, Sarah H. Knickerbocker, Paul H. Palmateer, Sampath Purushothaman, Srinivasa S. N. Reddy
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Patent number: 5167914Abstract: An (Fe, Co)-B-R tetragonal type magnet having a high corrosion resistance, which has a boundary phase stabilized by Co and Al against corrosion, and which consists essentially of:0.2-3.0 at % Dy and 12-17 at % of the sum of Nd and Dy;5-10 at % B;0.5-13 at % Co;0.5-4 at % Al; andthe balance being at least 65 at % Fe.0.1-1.0 at % of Ti and/or Nb may be present. Alloy powders therefor can be also stabilized.Type: GrantFiled: May 22, 1991Date of Patent: December 1, 1992Assignee: Sumitomo Special Metals Co., Ltd.Inventors: Setsuo Fujimura, Masato Sagawa, Hitoshi Yamamoto, Satoshi Hirosawa
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Patent number: 5162099Abstract: The process serves for producing a carbon-containing sintered compact from steel powder. In this process, the steel powder is heated to sintering temperature in an atmosphere containing, at least for a time, carbon monoxide, is kept at sintering temperature over a predetermined period of time and the sintered compact formed thereby is subsequently cooled.In this process, the carbon content of the sintered compact to be produced is to be set to a predetermined value in a way which is simple and suitable for mass production.This is achieved by the partial pressure of the carbon monoxide in the atmosphere being changed selectively during the execution of the production process, and by this change being controlled in such a way that the carbon content of the sintered compact is set to the predetermined value after execution of the production process.Type: GrantFiled: March 3, 1992Date of Patent: November 10, 1992Assignee: Asea Brown Boveri Ltd.Inventors: Gundolf Meyer, Christoph Tonnes
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Patent number: 5162098Abstract: This invention relates generally to a novel method of manufacturing a composite body, such as a ZrB.sub.2 -ZrC-Zr (optional) composite body, by utilizing a post-treatment process and to the novel products made thereby. More particularly, the invention relates to a method of modifying a composite body comprising one or more boron-containing compounds (e.g., a boride or a boride and a carbide) which has been made by the reactive infiltration of a molten parent metal into a bed or mass containing boron carbide, and optionally one or more inert fillers, to form the body.Type: GrantFiled: May 7, 1991Date of Patent: November 10, 1992Assignee: Lanxide Technology Company, LPInventors: Terry D. Claar, Gerhard H. Schiroky, William B. Johnson
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Patent number: 5156805Abstract: A ferritic alloy with a wear resistive oxide scale is obtained through the steps of pressing a ferritic alloy powder containing aluminum into a powder compact of a desired configuration, sintering the powder compact in a non-oxidizing atmosphere to provide a resulting sintered product, and heat-treating the sintered product in an oxidizing gas atmosphere in order to precipitate in the surface thereof alumina in the form of an alumina scale as the wear resistive oxide scale which is responsible for improved surface hardness or wear resistance. Due to the inherent porous nature of the sintered product, the oxidizing gas can readily penetrate deep into the surface of sintered product to facilitate the oxidization of the product surface into the alumina scale, in addition to that the oxidization depth can be controlled such as by the density of the product, which makes it possible to readily control the thickness of the alumina scale.Type: GrantFiled: July 25, 1991Date of Patent: October 20, 1992Assignee: Matsushita Electric Works, Ltd.Inventors: Junji Imai, Shuji Yamada, Tadashi Hamada, Hajime Kojima, Masao Tanahashi
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Patent number: 5152847Abstract: A method and apparatus 10 are disclosed for annealing metal powder so at to decrease the carbon content of the powder while also reducing the oxygen content thereof.Type: GrantFiled: February 1, 1991Date of Patent: October 6, 1992Assignee: Phoenix Metals Corp.Inventors: Stephen E. LeBeau, Sydney M. Kaufman
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Patent number: 5151247Abstract: The present invention is a method for densifying powder metallurgical parts to 100% theoretical density. The method comprises applying a high pressure of 0.1-100 MPa during sintering in a high pressure furnace at a temperature before which the liquid phase is formed and maintaining this pressure during the rest of the sintering cycle until the furnace has cooled to almost room temperature. The method achieves rapid, complete closure of the porosity which results in parts with close dimensional tolerances and practically no warpage.Type: GrantFiled: November 1, 1991Date of Patent: September 29, 1992Assignee: Sandvik ABInventors: Bengt O. Haglund, Bengt N. During
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Patent number: 5147601Abstract: A composition comprising a powder of iron and nickel and a binder (e.g. wax) is injection molded. The powder contains 0.5 to 10% by weight of nickel and has an average particle diameter not exceeding 45 microns. The binder is removed from the molded product. The molded product is sintered, and the sintered product is cooled to room temperature slowly at a rate of 2.degree. C. to 50.degree. C. per minute. The sintered product is of an iron-nickel alloy, has a high density and a high level of soft ferromagnetic properties, and may be complicated in shape.Type: GrantFiled: March 30, 1992Date of Patent: September 15, 1992Assignee: Sumitomo Metal Mining Co., Ltd.Inventors: Akihito Ohtsuka, Yoshio Kijima
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Patent number: 5145505Abstract: Disclosed are a high toughness cermet comprising a sintered alloy comprising 75 to 95% by weight of a hard phase of carbide, nitride or carbonitride containing Ti, at least one of W, Mo and Cr, and N and C, and the balance of a binder phase composed mainly of an iron group metal, and inevitable impurities,wherein the content of Ti in said sintered alloy is 35 to 85% by weight calculated on TiN or TiN and TiC, and the contents of W, Mo and Cr are 10 to 40% by weight in total calculated on WC, Mo.sub.2 C and/or Cr.sub.3 C.sub.2,the relative concentration of said binder phase at the 0.01 mm-inner portion from the surface of said sintered alloy is 5 to 50% of the average binder phase concentration of the inner portion, and the relative concentration of said binder phase at the 0.1 mm-inner portion from the surface of said sintered alloy is 70 to 100% of the average binder phase concentration of the inner portion, anda compression stress of 30 kgf/mm.sup.Type: GrantFiled: February 7, 1992Date of Patent: September 8, 1992Assignee: Toshiba Tungaloy Co., Ltd.Inventors: Takeshi Saito, Kozo Kitamura, Mitsuo Ueki
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Patent number: 5132082Abstract: A method for lowering the oxygen potential of an inert processing atmosphere containing a reducing gas such as hydrogen, by introducing a metal catalyst to induce reaction between the reducing gas and oxygen, which may originate from leaks into the system or from other sources. The catalyst, such as a precious metal, increases the rate of reaction between gaseous hydrogen and gaseous oxygen to form water vapor, thereby decreasing the amount of molecular oxygen available to react with oxidizable materials exposed to the inert processing atmosphere.Type: GrantFiled: June 12, 1991Date of Patent: July 21, 1992Assignee: The Pennsylvania Research CorporationInventors: George Simkovich, Ming-Chuan Lee
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Patent number: 5130206Abstract: Extra loss is introduced in coupled cavity and klystron RF circuits by applying a surface coating to selected parts of circuit elements used in the circuits. The coating is applied in the form of a slurry, which is then sintered. The slurry comprises a mixture of an iron-base powder (such as a stainless steel) and a dielectric glass ceramic, suspended in a binder dissolved in a solvent. Circuits with the loss coating are easier to match than by other prior art techniques. The loss coating of the invention reduces the fabrication cost of coupled-cavity traveling wave tubes, while improving the performance by minimizing the gain ripple. Higher average power operation is possible, due to elimination of loss buttons previously employed in the prior art.Type: GrantFiled: July 29, 1991Date of Patent: July 14, 1992Assignee: Hughes Aircraft CompanyInventors: Sunder S. Rajan, Ivo Tammaru, Steve L. Bosma, John W. Eldridge
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Patent number: 5126104Abstract: A method is disclosed for preparing an intimate mixture of powders of nickel-chromium-boron-silicon alloy, molybdenum metal powder, and Cr.sub.3 C.sub.2 /NiCr alloy suitable for thermal spray coatings which comprises milling a starting mixture of the above two alloys with molybdenum powder to produce a milled mixture wherein the average particle size is less than about 10 micrometers in diameter, forming an aqueous slurry of the resulting milled mixture and a binder which can be an ammoniacal molybdate compound or polyvinyl alcohol, and agglomerating the milled mixture and binder. The intimate mixture and binder may be sintered in a reducing atmosphere at a temperature of about 800.degree. C. to 950.degree. C. for a sufficient time to form a sintered partially alloyed mixture wherein the bulk density is greater than about 1.2 g/cc.Type: GrantFiled: June 6, 1991Date of Patent: June 30, 1992Assignee: GTE Products CorporationInventors: Vidhu Anand, Sanjay Sampath, David L. Houck, Jack E. Vanderpool
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Patent number: 5125962Abstract: A sintered material resistant to heat and mechanical strain, particularly to impact and friction, for the production of molded articles, made of a matrix metal powder having approximately 70 to 100% by weight of a copper component and approximately 0 to 30% by weight of an alloy component of cobalt, chromium, iron, manganese, nickel, tungsten and/or carbon. In another embodiment, the sintered material may also include an additional high-alloy metal powder admixed as a hard phase to the matrix metal powder. The additional high-alloy metal powder is present in the amount of a maximum 30% by weight, with respect to the sum of the matrix metal powder and high-alloy metal powder. The sintered material is especially suitable for heat- and wear-resistant molded articles for use in high gas environments, for example, in internal combustion engines. For example, guides, bearings, and valve elements may be made of this material and especially valve seat rings.Type: GrantFiled: November 13, 1989Date of Patent: June 30, 1992Assignee: Sintermetallwerk Krebsoge GmbHInventor: Bernd Krentscher
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Patent number: 5124118Abstract: A method for manufacturing a brake fitting comprising a plurality of studs each surrounded by a less fragile belt, the studs being non-contiguously secured to a metal support. According to the method, the support is provided with a slip-resistant surface by coating with a braze welding suspension which is oxidized and reduced. Stud blanks then are molded and compacted from powdered friction products and belt blanks are molded and compacted from metal powders and given an internal diameter 1.005 to 1.05 times the external diameter of the stud blanks, and the belt blanks are disposed around the stud blanks and sintered, obtaining sheathed stud blanks which are placed on the slip resistant surface of the support, and welded thereto by heat treatment. Finally, the sheathed stud blanks are forged at over 400 degree C., shortening them by at least 15%.Type: GrantFiled: May 17, 1991Date of Patent: June 23, 1992Assignee: Le Carbone LorraineInventors: Hassan Youssef, Yves Bigay
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Patent number: 5124119Abstract: A beryllium metal matrix phase includes up to 70% by volume of beryllium oxide single crystals dispersed therein. The composites are useful for electronics applications because of their light weight, high strength and effective thermal properties.Type: GrantFiled: February 12, 1991Date of Patent: June 23, 1992Assignee: Brush Wellman Inc.Inventor: Fritz C. Grensing
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Patent number: 5124120Abstract: A method for making zinc electrodes for alkaline-zinc batteries comprising the steps of: mixing an amount of a zinc-magnesium binder alloy with an amount of a material chosen from zinc and a second zinc-magnesium alloy to form a mechanical mixture. The melting temperature of the material is at least 15 Celsius degrees higher than the melting temperature of the binder alloy. The mixture is applied to a current collector and the current collector with applied mixture is heated to a temperature at which incipient melting of the binder alloy causes sintering of the mixture with the formation of a coherent layer solidly bonded to the current collector. The compositions and the amount of the binder alloy and the second alloy are selected such that the active material in the layer of the electrode contains no more than about 15% magnesium, preferably no more than about 10% magnesium.Type: GrantFiled: July 16, 1990Date of Patent: June 23, 1992Assignee: Cominco Ltd.Inventors: Jack Sklarchuck, Hans Rensing
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Patent number: 5110541Abstract: A method of manufacturing a porous electrode for a molten carbonate fuel cell comprises the steps of: pulverizing an Al-base intermetallic compound: mixing Ni powders with the pulverized intermetallic compound to form a slurry which contains Ni powders and the pulverized intermetallic compound, the pulverized intermetallic compound serving as a reinforcement; shaping the slurry like a sheet or a tape; and sintering the sheet or tape-like slurry to form the porous electrode.Type: GrantFiled: May 22, 1991Date of Patent: May 5, 1992Assignee: Ishikawajima-Harima Heavy Industries Co., Ltd.Inventors: Yoshikazu Yamamasu, Tetsuyuki Morita, Sadao Nakaniwa, Masami Ichihara
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Patent number: 5110543Abstract: A blade member for cutting-tools includes a cermet substrate which contains, apart from unavoidable impurities, a binder phase and a hard dispersed phase. The binder phase contains 5% to 30% by weight of cobalt and/or nickel. The hard dispersed phase contains a balance composite carbonitride of titanium and one or more of the elements tungsten, molybdenum, tantalum, niobium, hafnium and zirconium. The composite carbo-nitride satisfies the relationship 0.2.ltoreq.b/(a+b).ltoreq.0.7, where a and b denote atomic ratios of carbon and nitrogen, respectively. The substrate includes a hard surface layer in which the maximum hardness is present at a depth between 5 .mu.m and 50 .mu.m from a substrate surface thereof. The substrate surface has a hardness of 20% to 90% of the maximum hardness.Type: GrantFiled: July 19, 1991Date of Patent: May 5, 1992Assignee: Mitsubishi Metal CorporationInventors: Niro Odani, Kazuyoshi Yoshioka, Sinichi Sekiya
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Patent number: 5108492Abstract: It is provided a method for the manufacture of a corrosion-resistant sintered alloy steel, which comprises providing a stainless steel powder; adding a binder to said steel powder; molding the mixture; and carrying out the steps of (1) heating the resultant molding to remove the binder therefrom, (2) sintering the thus debound molding under reduced pressure up to 30 Torr, and (3) further sintering at a higher temperature than those of steps (1) and (2) in a non-oxidative atmosphere under substantially atmospheric pressure. It is also provided a corrosion-resistant sintered alloy steel which comprises a stainless steel, said alloy steel having a density ratio of not less than 92%, a maximum diametric of pore present in the structure of not larger than 20 .mu.m, and a content of Cr at the surface of the steel as being sintered which is not less than 80% of a content of Cr in the inside thereof.Type: GrantFiled: February 22, 1990Date of Patent: April 28, 1992Assignee: Kawasaki Steel CorporationInventors: Yoshisato Kiyota, Hiroshi Ohtsubo, Junichi Ohta, Masakazu Matsushita, Ichio Sakurada
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Patent number: 5098870Abstract: This invention relates generally to a novel method of preparing self-supporting bodies and to the novel products made thereby. In its more specific aspects, this invention relates to a method of producing self-supporting bodies having controlled porosity and graded properties and comprising one or more boron-containing compounds, e.g., a boride or a boride and a carbide. The method comprises, in one embodiment, reacting a powdered parent metal, in molten form, with a bed or mass comprising a boron carbide material and, optionally, one or more inert fillers, to form the body. In another embodiment, both of a powdered parent metal and a body or pool of molten parent metal are induced to react with a bed or mass comprising a boron carbide material and, optionally, one or more inert fillers. in addition, combustible additives (e.g., gelatin, corn starch, wax, etc.) can be mixed with the bed or mass comprising a boron carbide material to aid in the porisity producing process.Type: GrantFiled: July 23, 1990Date of Patent: March 24, 1992Assignee: Lanxide Technology Company, LPInventors: Terry D. Claar, William B. Johnson
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Patent number: 5098649Abstract: A rare earth metal-iron group metal target for a magneto-optical disk is produced by mixing power (a) produced by the rapid quenching treatment of an alloy composed of at least one rare earth metal and at least one iron group metal in a composition range which permits the formation of an eutectic structure, with powder (b) from at least one iron group metal in an amount necessary for meeting the composition requirements of the target; and subjecting the resulting mixture to pressure sintering in vacuum or in an inert gas atmosphere at a temperature lower than a liquid phase-appearing temperature of the mixture to produce a rare earth metal-iron group metal intermetallic bonding layer betwen the particles.Type: GrantFiled: June 26, 1990Date of Patent: March 24, 1992Assignee: Hitachi Metals, Ltd.Inventors: Shunichiro Matsumoto, Tsutomu Inui, Rokuo Ichiyasu, Yoshitaka Chiba
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Patent number: 5098648Abstract: Disclosed herein is an economical process for the production of a sintered Fe-Co type, Fe-Co-V type or Fe-Co-Cr type magnetic material, which comprises preparing an alloy powder of at least Fe and Co metals of a like powder, kneading it with an organic binder, conducting injection molding and debinding, and then conducting a two-stage sintering treatment consisting of low-temperature sintering and high-temperature sintering. Magnetic materials having a specific composition of the Fe-Co, Fe-Co-V or Fe-Co-Cr type and excellent magnetic properties and a low core loss value are also disclosed.Type: GrantFiled: June 13, 1991Date of Patent: March 24, 1992Assignee: Kawasaki Steel CorportionInventors: Yoshisato Kiyota, Osamu Furukimi
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Patent number: 5096661Abstract: A porous intermediate compact is first prepared from metal particles, carbon and a temporary binder. The compact is then heated to remove the binder and then infiltrated with the vapor of a metal having a melting point lower than the compact.Type: GrantFiled: April 2, 1991Date of Patent: March 17, 1992Assignee: Raybestos Products CompanyInventor: Richard D. Lang
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Patent number: 5093039Abstract: Disclosed is an electrically conductive sintered silicon carbide body having an electric resistivity of not higher than 1 .OMEGA..multidot.cm, which is produced by(a) mixing(1) a first silicon carbide powder having a mean grain size of from 0.1 to 10 .mu.m with(2) a second silicon carbide powder having a mean grain size of not greater than 0.1 .mu.m prepared by(2-1) introducing a starting gas composed of a silane compound of silicon halide and a hydrocarbon into a plasma of a non-oxidative atmosphere, and(2-2) conducting gas phase reaction between the silane compound or silicon halide and the hydrocarbon while controlling the pressure of the reaction system within the range of from less than 1 atom to 0.1 torr, and(3) optionally, a carbon powder which is required for reducing oxides contained in both the first and second silicon carbide powders,(b) optionally reducing the oxides with the carbon, and(c) heating the resulting mixture for sintering. Also, processes of producing the same are disclosed.Type: GrantFiled: November 6, 1989Date of Patent: March 3, 1992Assignees: Kazunori Kijima, Sumitomo Cement Co., Ltd.Inventors: Kazunori Kijima, Eiki Arai, Youichi Miyazawa, Mikio Konishi, Ken Kato
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Patent number: 5093076Abstract: This invention describes a practice for the hot pressing and/or hot working of rare earth element-containing alloy powders using open-to-the-air presses. The rare earth-containing powder is pressed into a compact at ambient temperatures using a solid lubricant only on the die wall. This compact is then hot pressed in an open air press utilizing a heated die flooded with argon.Type: GrantFiled: May 15, 1991Date of Patent: March 3, 1992Assignee: General Motors CorporationInventors: Kevin A. Young, Joseph J. Worden, Donald S. Kirk, Larry J. Eshelman
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Patent number: 5089222Abstract: This invention relates to the manufacture of Chevrel compounds by sintering a mixture of metal sulfides, metallic molybdenum and molybdenum sulfides under reduced pressure or in a stream of an inert gas containing a reductive gas, and by sintering a mixture of metal sulfides and molybdenum sulfides in a stream of an inert gas containing a reductive gas. This process does not meet any complicated procedure as in prior art and enables one to use a reaction container a desired number of times and to prepare Chevrel compounds inexpensively in large amounts.Type: GrantFiled: August 20, 1990Date of Patent: February 18, 1992Assignee: Matsushita Electric Industrial Co., Ltd.Inventors: Shigeo Kondo, Yasuharu Yamamura
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Patent number: 5082433Abstract: Molded articles, particularly cams for camshafts of internal combustion engines, are subjected to high wear conditions. In order to make them resistant to wear, they are produced from a sintered alloy, which has been fabricated by powder metallurgical means. The alloy has a hardened matrix with interstitial copper and consists of 0.5 to 16% by weight of molybdenum, 1 to 20% by weight of copper, 0.1 to 1.5% by weight of carbon and, optionally, of admixtures of chromium, manganese, silicon and nickel totalling, at most, 5% by weight, the remainder being iron.Type: GrantFiled: December 17, 1990Date of Patent: January 21, 1992Assignee: Etablissement SupervisInventor: Karl Leithner
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Patent number: 5080712Abstract: Methods for preparing sintered components from iron-containing and alloy steel powder are provided. The methods includes compacting a powder mixture in a die set at a pressure of at least about 25 tsi to produce a green compact which is then presintered at a temperature of about 1100.degree.-1600.degree. F. (593.degree.-870.degree. C.) for at least about 5 minutes to produce a presintered preform. The presintered preform is then compacted at a pressure of at least about 25 tsi to produce a double-pressed presintered preform, which is, in turn, sintered at a temperature of at least about 1000.degree. C. for at least about 5 minutes to produce a sintered component having improved transverse rupture strength and a higher density.Type: GrantFiled: May 16, 1990Date of Patent: January 14, 1992Assignee: Hoeganaes CorporationInventors: William B. James, Robert J. Causton, John J. Fulmer
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Patent number: 5067979Abstract: A process is provided for the production of a sintered body. The process includes the following consecutive steps: i) mixing and kneading one or more metal powders and/or one or more alloy powder with a binder into a compound, said metal and alloy powders having an average particle size not greater than 30 .mu.m, ii) injection-molding the compound into a green body; iii) debinding the green body to form a debound body; and iv) subjecting the debound body to a first-stage sintering at 1,050.degree.-1,250.degree. C. in a reduced-pressure atmosphere and then to second-stage sintering at a temperature in a range of 1,100.degree.-400.degree. C. which is higher than that of the first-stage sintering. This process can provide sintered Ti bodies and sintered magnetic bodies of the Fe-Si type, which have a density ratio of at least 95%.Type: GrantFiled: July 6, 1990Date of Patent: November 26, 1991Assignee: Kawasaki Steel CorporationInventors: Yoshisato Kiyota, Junichi Ohta, Hiroshi Ohtsubo, Shigeaki Takajo
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Patent number: 5063021Abstract: A method is disclosed for preparing an intimate mixture of powders of nickel-boron-silicon alloy and molybdenum metal powder suitable for thermal spray coatings which comprises milling a starting mixture of the alloy and molybdenum powder to produce a milled mixture wherein the average particle size is less than about 10 micrometers in diameter, forming an aqueous slurry of the resulting milled mixture and a binder which can be an ammoniacal molybdate compound or polyvinyl alcohol, and agglomerating the milled mixture and binder. The intimate mixture and binder are preferably sintered in a reducing atmosphere at a temperature of about 800.degree. C. to about 950.degree. C. for a sufficient time to form a sintered partially alloyed mixture wherein the bulk density is greater than about 1.2 g/cc.Type: GrantFiled: May 23, 1990Date of Patent: November 5, 1991Assignee: GTE Products CorporationInventors: Vidhu Anand, Sanjay Sampath, Clarke D. Davis, David L. Houck
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Patent number: 5063001Abstract: A method of compacting radioactive metal wastes comprising enclosing the radioactive metal waste in vacuo in a capsule, placing the capsule into a pressure container, and subjecting the capsule to an increased pressure at a high temperature to compact the waste. The compacting treatment is conducted in a state in which the atmosphere within the pressure container contains water molecules in an amount, in terms of the total weight W (g) thereof, the amount being preferably in the range of:1.3.times.10.sup.-6 .times.V.ltoreq.Wwherein V (cm.sup.3) is the volume of the compacting space in the pressure container. Alternatively, an oxide coating is formed on the outer surface of the capsule before the capsule is placed into the pressure container, or the formation of the oxide coating is followed by the compacting treatment conducted in the above-mentioned state.Type: GrantFiled: August 20, 1990Date of Patent: November 5, 1991Assignees: Kabushiki Kaisha Kobe Seiko Sho, Doryokuro Kakunenryo Kaihatsu JigyodanInventors: Hidehiko Miyao, Satoshi Ikeda, Masao Shiotsuki, Shigeyoshi Kawamura, Fumiaki Komatsu, Ikuji Takagi, Tadamiti Sakai
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Patent number: 5041414Abstract: Continuous malleable superconductive material which can be machined, rolled and soldered, being the product of sintering at an elevated temperature and pressure of a metal plated powder of a compound QBa.sub.2 Cu.sub.3 O.sub.7-x wherein Q is yttrium or europium, where x is smaller than one. The metal is advantageously silver and the plating process is one without the use of electricity. A preferred range of silver content is about 5 to 32 weight per cent, and the silver forms an essentially continuous phase in the superconductive material. Sintering can be done at from about 350.degree. and 950.degree. C., with a preferred range of 400.degree. to 900.degree. C. The superconductive material of the invention exhibits transition to zero-resisitivity state and the Meissner effect.Type: GrantFiled: February 13, 1989Date of Patent: August 20, 1991Assignee: Yeda Research and Development Company LimitedInventor: Shymon Reich