Special Atmosphere Patents (Class 419/57)
  • Patent number: 5041159
    Abstract: An improved method of forming a nickel plaque wherein an assemblage of particles of a nickel alloy are oxidized and sintered in a preselected atmosphere such that the alloying material is exclusively substantially internally oxidized and the resultant product sintered to provide a sintered porous plaque containing nickel metal and oxidized alloying material.
    Type: Grant
    Filed: February 13, 1989
    Date of Patent: August 20, 1991
    Assignee: Energy Research Corporation
    Inventors: Joel D. Doyon, Lawrence M. Paetsch, Mark Benedict, D. Lynn Johnson
  • Patent number: 5039476
    Abstract: A method for the production of a metallic powder molding material is disclosed which comprises a step of imparting mechanical energy due to at least one of such physical actions as vibration, pulverization, attrition, rolling, shocks, agitation, and mixing a metallic particles in a vessel whose interior is held under vacuumized atmosphere or an atmosphere of inert gas thereby enabling the metallic particles to contact each other and acquire improvement in surface quality and a step of hot molding the metallic particles thereby producing a molding material.
    Type: Grant
    Filed: July 19, 1990
    Date of Patent: August 13, 1991
    Assignee: Ube Industries, Ltd.
    Inventors: Mitsuru Adachi, Akio Okamoto, Hideki Iwai, Yoshiharu Waku
  • Patent number: 5034187
    Abstract: A composition containing 30 to 70% chromium carbide, 5 to 20% soft noble metal, 5 to 20% metal fluorides, and 20 to 60% metal binder is used in a powdered metallurgy process for the production of self-lubricating components, such as bearings. The use of the material allows the self-lubricating bearing to maintain its low friction properties over an extended range of operating temperatures.
    Type: Grant
    Filed: August 23, 1990
    Date of Patent: July 23, 1991
    Assignee: The United States of America as represented by the Administrator of the National Aeronautics and Space Administration
    Inventors: Harold E. Sliney, Christopher Dellacorte
  • Patent number: 5034186
    Abstract: A titanium or titanium alloy composite having a porous surface layer, which comprises a titanium or titanium alloy substrate and a porous titanium or titanium alloy layer that adheres strongly to said substrate, said porous layer being formed by first providing said substrate with a firmly adhering sinter of a mixture of a titanium or titanium alloy powder and a magnesium powder, and then removing magnesium from the sinter. A process for producing a titanium or titanium alloy composite having a porous surface layer, comprising: providing a coating composition comprising a binder added to a mixture of a titanium or titanium alloy powder and a magnesium powder; applying said composition to the surface of a titanium or titanium alloy substrate; heating the substrate at a temperature of from 650.degree. to 800.degree. C. in vacuo or an inert atmosphere so as to form a sinter of the powders of titanium or titanium alloy and magnesium which firmly adheres to said substrate; and removing magnesium from said sinter.
    Type: Grant
    Filed: November 20, 1986
    Date of Patent: July 23, 1991
    Assignee: Permelec Electrode Ltd.
    Inventors: Takayuki Shimamune, Hideo Sato, Masashi Hosonuma
  • Patent number: 5019156
    Abstract: A sintered electric contact material for use in vacuum switch tubes comprises about 50 to 70% by volume of a Cr powder, about 0.1 to 1.15% by volume of a Ti powder, and the remainder of a Cu powder. The sintered material can be obtained advantageously by heating a mixture of the Cr powder, the Ti powder and the Cu powder in a non-oxidizing atmosphere under pressure, at a temperature below the melting point of Cu (the melting point is 1083.degree. C. at normal pressure).
    Type: Grant
    Filed: May 17, 1990
    Date of Patent: May 28, 1991
    Assignee: Mitsubishi Denki Kabushiki Kaisha
    Inventors: Eizo Naya, Mitsuhiro Okumura
  • Patent number: 5011655
    Abstract: The invention provides a method of manufacturing a thin metallic body composite structure. First, an inner layer of a first metal is cleaned to remove oxides and promote metallurgical bonding. The inner layer has a plurality of penetrating holes piercing the thickness of the inner layer. The penetrating holes are filled with metal powder of a second metal. Two outer layers of the second metal are placed on opposite sides of the cleaned and filled inner layer to form a sandwich structure. The sandwich structure is heated to a temperature at which recrystallization will occur in a non-oxidizing atmosphere. The sandwich structure is then hot worked to reduce thickness of the sandwich structure forming the thin metallic body composite structure.
    Type: Grant
    Filed: December 22, 1989
    Date of Patent: April 30, 1991
    Assignee: INCO Alloys International, Inc.
    Inventor: William L. Mankins
  • Patent number: 5009842
    Abstract: High strength steel parts or articles are made from a powder alloy by compacting the powder into a preform, sintering the preform in a sintering furnace or the like under a highly-reducing atmosphere and at a temperature of at least 1150.degree. C., cooling the preform, preheating the sintered preform in a highly-reducing atmosphere, such as an inert gas-based atmosphere containing hydrogen or pure hydrogen, to a temperature of at least 1000.degree. C. and transferring the preheated preform to an impact forging device and impacting the preform at a peak averaging forging pressure of at least about 1000 MPa to obtain a forged part or article. The time period between removal of the preheated preform from the preheater and the first forging impact is no more than about 8 seconds. The sintering and preheating steps can be combined with the sintered preform being cooled to the preheating temperature in the sintering furnace and transferred directly from the sintering furnace to the impact forging device.
    Type: Grant
    Filed: June 8, 1990
    Date of Patent: April 23, 1991
    Assignee: Board of Control of Michigan Technological University
    Inventors: Alfred A. Hendrickson, Darrell W. Smith
  • Patent number: 5010050
    Abstract: In a process of producing composite materials consisting of sheet metal plates, metal strips and foils and provided with a skeleton surface structure, a layer of a metal powder which is difficultly flowable and consists of irregularly shaped particles is applied to a continuously moved metallic carrier layer and is bonded to said carrier layer by cold roll cladding and is sintered in a reducing atmosphere at temperatures of 600.degree. to 1000.degree. C. In order to produce composite materials in which the skeleton structure constitutes a layer that is of uniform thickness throughout the surface and is firmly bonded to the carrier layer, the metal powder is uniformly distributed and applied as regards its bulk volume using a distributing roller, which rotates opposite to the main direction of movement of the carrier layer, whereby a uniform thickness is obtained.
    Type: Grant
    Filed: April 18, 1989
    Date of Patent: April 23, 1991
    Assignee: Metallgesellschaft AG
    Inventors: Heinz Wullenweber, Peter Kohl, Herbert Jung, Jurgen Borchardt, Wolfgang Bickle, Jurgen Braus
  • Patent number: 5009706
    Abstract: Rare-earth alloy anisotropic powders consist of, in atomic percent, over 12 percent and not more than 20 percent of R (R is at least one on neodymium and praseodymium or at least one of them and or more rare-earth elements), not less than 4 percent and not more than 10 percent of boron, not less than 0.05 percent and not more than 5 percent of copper and the rest that consists of iron and unavoidable impurities. Up to 20 percent of the iron contained is replaceable with cobalt. The alloy powders are made up of flat crystal grains having mean thickness h (the shortest measure), d not smaller than 0.01 .mu.m and not larger than 0.5 .mu.m and ratio d/h not smaller than 2, where d is the means measure of the grains taken at right angles to the widthwide direction thereof, and the alloy powders are magnetically anisotropic.
    Type: Grant
    Filed: July 18, 1990
    Date of Patent: April 23, 1991
    Assignee: Nippon Steel Corporation
    Inventors: Hiroaki Sakamoto, Masahiro Fujikura, Toshio Mukai
  • Patent number: 5008071
    Abstract: A consolidated tungsten alloy body consisting essentially of from about 70% to about 98% by weight of tungsten, balance nickel and iron in essentially an 8:2 weight ratio. A process for producing the consolidated bodies where the tungsten content is greater than about 88% by weight comprises forming a relative uniform blend of the described metal powders, compacting the powders to form a green body then liquid phase sintering the green body to full density. For alloys containing less than about 90% tungsten solid state sintering can be used.
    Type: Grant
    Filed: November 25, 1988
    Date of Patent: April 16, 1991
    Assignee: GTE Products Corporation
    Inventors: James R. Spencer, James A. Mullendore
  • Patent number: 5000910
    Abstract: At least two kinds of element metal or half-metal powders are mechanically alloyed in a non-oxidizing atmosphere in a blending machine. Then, the resultant mechanically alloyed powdered blend is heated and pressurized in the non-oxidizing atmosphere at a temperature higher than a minimum temperature required for generating the intermetallic compound from the element powders.
    Type: Grant
    Filed: January 24, 1990
    Date of Patent: March 19, 1991
    Assignees: Masaharu Tokizane, Siro Hagishita
    Inventors: Masaharu Tokizane, Kei Ameyama, Haruhiko Sugimoto
  • Patent number: 4996022
    Abstract: A sintered body is produced by a process comprising the steps of mixing one or more metal powder particles with an organic binder, injection-molding the mixture to form a green body of a predetermined shape, removing the binder from the green body to form a porous body substantially made of the metal powder, and heating the porous body to a sintering temperature and holding it at that temperature to produce a sintered body, in which process the binder is removed through the sequence of the following steps: preheating the green body in an inert gas atmosphere in a temperature range that creates open pores in it; placing the green body, in which open pores have started to form, in a hydrogen gas atmosphere optionally mixed with an inert gas; holding the green body in a temperature range where the metal powder is not carburized and where the open pores will be maintained, so that the greater part of the binder is removed to form a porous body that is substantially made of the metal powder alone; and further hold
    Type: Grant
    Filed: July 10, 1990
    Date of Patent: February 26, 1991
    Assignees: Juki Corporation, Nippon Piston Ring Co., Ltd.
    Inventors: Norikazu Shindo, Tomoyuki Sekine, Yoshikatsu Nakamura, Takashi Kawamoto
  • Patent number: 4992415
    Abstract: A method for fabricating a ceramic superconductor comprising the following steps: mixing a copper or copper alloy metal, a first metal oxide or carbonate which includes one element selected from group IIA of the Chemical Periodic Table, and a second metal oxide or carbonate which includes one element selected from group IIIB of the Chemical Periodic Table to form a copper/ceramic mixture; heting a copper/ceramic mixture to a temperature in the range between 900.degree.-1100.degree. C.; and cooling the heated copper/ceramic mixture slowly, thereby forming a superconductive material. The copper/ceramic mixture may be extruded through a die prior to the heating step, thereby forming a superconductor of desired shape.
    Type: Grant
    Filed: July 31, 1987
    Date of Patent: February 12, 1991
    Assignee: Olin Corporation
    Inventors: Sankaranarayanan Ashok, Bruce M. Guenin
  • Patent number: 4992237
    Abstract: A process is provided for igniting a mixed powder material compact containing sufficient fuel to support an exothermic reaction between ingredients contained in the compact. The ignition is achieved in an inert atmosphere with an electric arc produced by an electrode without contacting the compact and thereby initiating the reaction.
    Type: Grant
    Filed: January 24, 1990
    Date of Patent: February 12, 1991
    Assignee: Amax Inc.
    Inventor: William A. May
  • Patent number: 4992233
    Abstract: Sintering metal powder in inert and/or reducing atmosphere has been found to result in a hard porous metal structure without the use of sintering aids. The oxidation resistance of the structure can be enhanced by the firing process comprised of the following steps: oxidation, reduction, and then inert gas sintering.
    Type: Grant
    Filed: July 15, 1988
    Date of Patent: February 12, 1991
    Assignee: Corning Incorporated
    Inventors: Srinivas H. Swaroop, Raja R. Wusirika
  • Patent number: 4992235
    Abstract: Thermoelectric elements with excellent thermoelectric characteristics such as Seebeck coefficient thermoelectromotive force and thermal conductivity can be produced by molding a powder of metal or metal alloy as the raw material and then sintering; by using as such raw material, ultra fine powders containing Fe and Si as main components and having a mean particle diameter of 50 to 5,000 .ANG..
    Type: Grant
    Filed: March 23, 1989
    Date of Patent: February 12, 1991
    Assignee: Idemitsu Petrochemical Co., Ltd.
    Inventors: Takeo Tokiai, Takashi Uesugi
  • Patent number: 4990410
    Abstract: A surface refined sintered alloy with a burnt surface, comprising 75 to 95% by weight of a hard phase containing Ti, C and N as the essential components and otherwise comprising at least one of Zr, Hf, V, Nb, Ta, Cr, Mo and W and the balance of the alloy comprising a binder phase composed mainly of Co and/or Ni and inevitable impurities, wherein the sintered alloy satisfies at least two conditions selected from the group consisting of the following (1) to (3):(1) the average grain size of the hard phase in a surface layer to the inner portion of 0.05 mm from the burnt surface of the sintered alloy is 0.8 to 1.2-fold of the average grain size of the hard phase in the inner portion of the sintered alloy excluding the surface layer;(2) the average content of the binder phase in the surface layer to the inner portion of 0.05 mm from the burnt surface of the sintered alloy is 0.7 to 1.
    Type: Grant
    Filed: March 7, 1989
    Date of Patent: February 5, 1991
    Assignee: Toshiba Tungaloy Co., Ltd.
    Inventors: Takeshi Saitoh, Tuyoshi Saito, Mitsuo Ueki, Hisashi Suzuki, Keiichi Kobori
  • Patent number: 4990181
    Abstract: The present invention is directed to porous sintered aluminide structures of aluminum, nickel, titanium, and/or rare earth metal. A process is disclosed for forming and sintering aluminides. Other components are optionally added to the aluminide compositions to vary the physical properties of the resultant structure.
    Type: Grant
    Filed: March 14, 1989
    Date of Patent: February 5, 1991
    Assignee: Corning Incorporated
    Inventors: Kim D. Pierotti, Srinivas H. Swaroop, Raja R. Wusirika
  • Patent number: 4986961
    Abstract: A consolidated tungsten heavy alloy body consisting essentially of from about 88% to about 98% by weight of tungsten, from about 0.25% to about 1.5% by weight of a grain size reducing additive selected from the group consisting of ruthenium, rhenium and mixtures thereof, balance iron and nickel in a weight ratio of nickel to iron of from about 1:1 to about 9:1 wherein the consolidated body has greater than about 2500 grains per square millimeter as determined from the microstructure of the body. A process for producing the consolidated body comprises forming a relative uniform blend of the described metal powders, compacting the powders to form a green body then solid state sintering to remove binders followed by liquid phase sintering the green body to full density.
    Type: Grant
    Filed: October 2, 1989
    Date of Patent: January 22, 1991
    Assignee: GTE Products Corporation
    Inventors: James R. Spencer, James A. Mullendore
  • Patent number: 4985071
    Abstract: A process for producing a thin film of a base metal on a substrate which comprises thermally decomposing in oxidative atmosphere an organic or inorganic compound containing a base metal compound formed on a substrate to form the oxide of the metal and then reducing the oxide by heat-treating it in reductive atmosphere. A temperature sensor, magnetic sensor, and ceramic wiring substrate utilizing the base metal thin film.
    Type: Grant
    Filed: January 12, 1989
    Date of Patent: January 15, 1991
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Munehiro Tabata, Chiharu Hayashi, Yasuhito Isozaki, Kazuyuki Okano, Yo Hasegawa
  • Patent number: 4983112
    Abstract: An interlocking device for a HIP equipment that prevents possible damage to the HIP equipment arising from use of a furnace or processing gas in error and can control the oxygen concentration and pressure within the HIP equipment. The device includes a sensor for detecting a concentration of oxygen in the processing gas in a processing gas pipe system. If the sensor detects an excessively high oxygen concentration, a supply side interlocking mechanism closes a valve for the pipe system and disconnects a power source for a furnace in a high pressure vessel. A flow switch is connected to a safety pipe system having a safety device, and a thermocouple is provided for each of the safety and processing gas pipe systems and a relief pipe system.
    Type: Grant
    Filed: July 20, 1989
    Date of Patent: January 8, 1991
    Assignee: Kabushiki Kaisha Kobe Seiko Sho
    Inventors: Katsuhiro Uehara, Takahiko Ishii, Takao Fujikawa, Kuniaki Kanda, Yutaka Narukawa
  • Patent number: 4983572
    Abstract: A superconductive body of an oxidic superconductive material having good mechanical properties is characterized in that the oxidic material forms a matrix through which finely divided particles are mixed at least the surface of which consists of a metal or a metal alloy. Particles in the form of fibres are preferably used and the surface of the particles consists of silver or gold.
    Type: Grant
    Filed: August 25, 1988
    Date of Patent: January 8, 1991
    Assignee: U.S. Philips Corporation
    Inventor: Gijsbertus De With
  • Patent number: 4977034
    Abstract: Coextrusion billets of two or more concentric metallic layers treated by a hot isostatic pressing (HIP) process in order to form a defect-free bondline between the contiguous touching metal layers. The HIP process can also be applied to extruded or further reduced tubes in order to heal bondline defects.
    Type: Grant
    Filed: November 7, 1989
    Date of Patent: December 11, 1990
    Assignee: Teledyne Industries, Inc.
    Inventor: Chun T. Wang
  • Patent number: 4975035
    Abstract: The cathode-forming method involves incorporating cobalt into a nickel plaque so that the exposed surfaces and the pores of the nickel plaque are uniformly covered with cobalt. The plaque is then treated to form nickel hydroxide in the pores and on the surfaces thereof. The cobalt is thus diposed at the interfacial boundary of the nickel plaque and nickel hydroxide so as to reduce the impedance and enhance charge conduction of the cathode. The mode of incorporation can vary. Thus, the sintered nickel plaque can be soaked in an aqueous solution of a water-soluble salt of cobalt, such as cobalt nitrate, then dried and resintered. Another mode involves dispersing a water-soluble cobalt salt in an aqueous slurry of nickel particles and water-soluble binder for the particles. The nickel particles are thus uniformly covered with the dissolved cobalt salt and then are compacted into a plaque. The plaque is dried and finally sintered.
    Type: Grant
    Filed: January 13, 1989
    Date of Patent: December 4, 1990
    Inventors: Jerry Kuklinski, Phillip G. Russell
  • Patent number: 4973355
    Abstract: The invention relates to sintered hard metals having high cutting properties, particularly plastic deformation resistance at high temperatures, crater resistance and the like, suitable for use as cutting tools, wear resistant tools and materials for dies, and the method for producing the same. The invention has for an object to obtain both sintered hard metals having the aforesaid high properties by sintering metallic components comprising IVa group metals, VIa group metals or metals of both groups substituted by Va group metals up to 60 mol % respectively, a B-1 type solid solution hard phase consisting of non-metallic components of C, N and O, and a metallic bonding phase, in a CO gas atmosphere, and to sintered hard metals in which an uniform hardness is imparted to the surface and interior thereof by the method of sintering the said sintered hard metal in a CO gas atmosphere.
    Type: Grant
    Filed: October 31, 1988
    Date of Patent: November 27, 1990
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventors: Kunihiro Takahashi, Toshio Nomura, Takaharu Yamamoto
  • Patent number: 4970050
    Abstract: A method of producing a sintered, very high density dental prosthesis from a suspension containing noble-metal powder mixtures with bi or multimodal particle-size distribution and a mixing liquid. The suspension is molded to the desired shape and then the dental prosthesis is dried. The molded dental prosthesis is then heat-treated 5 to 45 minutes between 100.degree. and 400.degree. C., then heated with an average temperature elevation of 50 to 300 K/min. to 800.degree. C. and then brought to the sintering temperature T at 20 to 200 K/min. The sintering temperature T is between T.sub.solidus - 200) and T.sub.solidus - 70), whereby T.sub.solidus is the solidus temperature of the sintered alloy. The cooling-down of the dental prosthesis takes place under a vacuum or a protective gas.
    Type: Grant
    Filed: December 13, 1989
    Date of Patent: November 13, 1990
    Inventors: Werner Groll, Angela Klaus, Thomas Lange
  • Patent number: 4966818
    Abstract: This invention relates to a method to consolidate a metal powder body to a completely dense body, in which a plate capsule consisting of a cylindrical wall and in one end thereof an end plate is charged with said powder so that the powder completely or essentially completely will fill the capsule, whereafter the air optionally is evacuated from the capsule and optionally replaced with a non-oxidizing protective gas, said capsule thereafter being closed also in the opposite end by an end plaate, whereafter the capsule with its content is heated to a forging temperature suitable for the metal powder and is forged so that the powder is consolidated to a completely dense body.
    Type: Grant
    Filed: April 11, 1989
    Date of Patent: October 30, 1990
    Assignee: Uddeholm Tooling Aktiebolag
    Inventors: Bertil Johansson, Per Hasselstrom
  • Patent number: 4966749
    Abstract: This invention relates to the manufacture of Chevrel phase compounds by sintering a mixture of metal sulfides, metallic molybdenum and molybdenum sulfides under reduced pressure or in a stream of an inert gas containing a reductive gas, and by sintering a mixture of metal sulfides and molybdenum sulfides in a stream of an inert gas containing a reductive gas. This process does not need any complicated procedure as in the prior art and enables one to use a reaction container a desired number of times and to prepare Chevrel phase compounds inexpensively in large amounts.
    Type: Grant
    Filed: June 15, 1989
    Date of Patent: October 30, 1990
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Shigeo Kondo, Yasuharu Yamamura
  • Patent number: 4964907
    Abstract: A process is provided for the production of a sintered body. The process includes the following consecutive steps: (i) mixing and kneading one or more metal powders and/or one or more alloy powder with a binder into a compound, said metal and alloy powders having an average particle size not greater than 30 .mu.m, (ii) injection-molding the compound into a green body; (iii) debinding the green body to form a debound body; and (iv) subjecting the debound body to first-stage sintering at 1,050.degree.-1,250.degree. C. in a reducing or reduced-pressure atmosphere and then to second-stage sintering at a temperature in a range of 1,100.degree.-1,400.degree. C. which is higher than that of the first-stage sintering. This process can provide sintered Ti bodies and sintered magnetic bodies of the Fe-Si type, which have a density ratio of at least 95%.
    Type: Grant
    Filed: August 14, 1989
    Date of Patent: October 23, 1990
    Assignee: Kawasaki Steel Corp.
    Inventors: Yoshisato Kiyota, Junichi Ohta, Hiroshi Ohtsubo, Shigeaki Takajo
  • Patent number: 4963321
    Abstract: There are disclosed a surface sintered alloy with a burnt surface, comprising 75 to 95% by weight of a hard phase containing Ti, C and N as the essential components and otherwise comprising at least one of Zr, Hf, V, Nb, Ta, Cr, Mo and W and the balance of the alloy comprising a binder phase composed mainly of Co and/or Ni and inevitable impurities, wherein the sintered alloy satisfies at least one condition selected from the group consisting of the following (1) to (3):(1) the average grain size of the hard phase in a surface layer to the inner portion of 0.05 mm from the burnt surface of the sintered alloy is 0.8 to 1.2-fold of the average grain size of the hard phase in the inner portion of the sintered alloy excluding the surface layer;(2) the average content of the binder phase in the surface layer to the inner portion of 0.05 mm from the burnt surface of the sintered alloy is 0.7 to 1.
    Type: Grant
    Filed: October 19, 1989
    Date of Patent: October 16, 1990
    Assignee: Toshiba Tungaloy Co., Ltd.
    Inventors: Takeshi Saitoh, Tuyoshi Saito, Mitsuo Ueki, Hisashi Suzuki, Keiichi Kobori
  • Patent number: 4961879
    Abstract: A conductive metal-filled substrate is formed by intermingling copper or nickel particles into the substrate, contacting the metal particles with a specified developing agent, and heating the metal particles and the developing agent. The filled substrates are electrically conductive and are useful for a variety of uses such as EMI shielding.
    Type: Grant
    Filed: June 8, 1988
    Date of Patent: October 9, 1990
    Assignee: Akzo America Inc.
    Inventors: Paul Y. Y. Moy, William J. E. Parr, Dieter Frank, Ronald E. Hutton
  • Patent number: 4961901
    Abstract: In a process of manufacturing diaphragms, a layer of a difficulty flowable metal powder is applied to a support, a wire net is rolled onto the powder layer and the latter is compacted at the same time and the metal powder is fired at 800.degree. to 1500.degree. C. in an oxidizing atmosphere. In order to impart to the diaphragms a constant thickness, strength and density, the metal powder is uniformly distributed and applied as regards its bulk volume to the support and the powder layer is moved under a distributing roller rotating opposite to the direction in which the powder is fed.
    Type: Grant
    Filed: April 18, 1989
    Date of Patent: October 9, 1990
    Assignee: Metallgesellschaft AG
    Inventors: Heinz Wullenweber, Peter Kohl, Herbert Jung, Jorgen Borchardt, Wolfgang Bickle, Jurgen Braus, Hans-Joachim Hiedemann
  • Patent number: 4954313
    Abstract: A method for providing void-free low-electrical-resistance conductive cores in vias having an aspect ratio of greater than approximately 6 includes the steps of providing a conductive thixotropic paste on the top surface of a substrate having vias provided therein, applying pressure to the paste and concurrently applying pressure to the paste and bottom surface of the substrate to force the thixotropic paste into the vias. Vibratory motion may also be applied to the substrate and paste concurrently with the application of pressure and vacuum. The paste is then dried in a vacuum, and subsequently sintered in a two-step process including a slow ramp up to temperature to allow the paste to outgas followed by a high temperature treatment.
    Type: Grant
    Filed: February 3, 1989
    Date of Patent: September 4, 1990
    Assignee: Amdahl Corporation
    Inventor: John F. Lynch
  • Patent number: 4948426
    Abstract: A sintering metal powder consisting of metal particles having a particle diameter distribution including a plurality of peaks. The larger of the two particle diameters at every adjoining two, respectively, of the peaks has a ratio of between 5 and 10 to the smaller. The height of one of every adjoining two of the peaks has a ratio of between 1 and 5 to that of the other that is not higher than the one peak. The particle diameter at one of every adjoining two of the peaks which is not higher than the other is smaller than that at the other peak. The particle diameter at the highest peak is between 30 and 80 microns. A process for making a sintered product from such a powder is also disclosed.
    Type: Grant
    Filed: January 22, 1990
    Date of Patent: August 14, 1990
    Assignee: Sumitomo Metal Mining Company Limited
    Inventors: Yutaka Kato, Yoshio Kijima
  • Patent number: 4941918
    Abstract: A magnesium-based composite material having improved mechanical strength, and in particular an improved modulus of elasticity, and a relatively low density. The material is provided by pressing and sintering a mixture of magnesium or magnesium-based alloy particles or a particulate combination of magnesium particles and particles of one or more additional metals, with a reinforcement additive of boron, or boron-coated B.sub.4 C, Si.sub.3 N.sub.4, SiC, Al.sub.2 O.sub.3 or MgO particles.
    Type: Grant
    Filed: December 12, 1988
    Date of Patent: July 17, 1990
    Assignee: Fujitsu Limited
    Inventors: Eiji Horikoshi, Tsutomu Iikawa, Takehiko Sato
  • Patent number: 4940679
    Abstract: Self-supporting bodies are produced by reactive infiltration of a parent metal into boron carbide typically resulting in a composite comprising a boron-containing compound and metal. The mass to be infiltrated may contain one or more inert fillers admixed with the boron carbide, or at least one carbon donor material, to produce a composite by reactive infiltration, which composite comprises a matrix of metal and boron-containing compound embedding the filler. In one embodiment of the invention, a parent metal is reactively infiltrated into a mass comprising a boron carbide material mixed with a carbon-containing compound. In this embodiment, a self-supporting composite is formed typically comprising a boron-containing compound, a carbon-containing compound, and metal. The relative amounts of reactants and process conditions may be altered or controlled to yield a body containing varying volume percents of ceramic, metal and/or porosity.
    Type: Grant
    Filed: December 23, 1987
    Date of Patent: July 10, 1990
    Assignee: Lanxide Technology Company, LP
    Inventors: Terry D. Claar, Steven M. Mason, Kevin P. Pochopien, Danny R. White
  • Patent number: 4937042
    Abstract: A mixture of two powdered alloys of the M, Cr, Al type, M being Co and/or Ni, is disclosed, in one form, for use in providing an abradable surface of an article and is characterized by the substantial absence of B. The first alloy has substantially no Si and has a higher melting range than that of the second alloy. The second alloy has substantially no Y and consists essentially of, by weight, 8-12% Si, 1.5-4% Al, 10-30%Cr, with the balance M and incidental impurities. The total mixture composition consists essentially of, by weight, 10-35% Cr, 4-10% Al, from a small but effective amount up to about 0.09% Y, 2-6% Si, with the balance M and incidental impurities.
    Type: Grant
    Filed: March 23, 1989
    Date of Patent: June 26, 1990
    Assignee: General Electric Company
    Inventors: Roger J. Perkins, Murray S. Smith, Jr.
  • Patent number: 4931213
    Abstract: A process for producing a ceramic material which is electrically conductive by reacting titanium dioxide with intercalated graphite under conditions which effect the reduction of the titanium dioxide, said product comprising an electrically conductive, corrosion-resistant, substoichiometric titanium dioxide combined chemically with an intercalant or residue thereof, for example, a metal such as copper or nickel, and the use thereof in thermal, electrical and electro-chemical applications.
    Type: Grant
    Filed: January 23, 1987
    Date of Patent: June 5, 1990
    Inventor: Richard B. Cass
  • Patent number: 4929417
    Abstract: A powder of at least one of TiB.sub.2, ZrB.sub.2 and HfB.sub.2 is mixed with at least one of Ti, Zr, Hf, TiB, ZrB and HfB, or with at least one of Ti, Zr, Hf, TiB, ZrB and HfB and a powder of boron, to prepare a mixed powder which can form a sintered product having a boron content of 65 to 67 atom %. Alternatively, a powder of at least one of Ti, Zr, Hf, TiB, ZrB and HfB is mixed with a powder of boron to prepare the mixed powder. The mixed powder may further contain up to a maximum of 30% by weight of a powder of AlN. Then, the mixed powder is sintered to make metal diboride ceramics. The lower-melting metal or compound which the mixed powder contains melts to form a liquid phase and enables the manufacture of a sintered product of high density by a customary sintering operation employing a low temperature. The sintered product having a boron content of 65 to 67 atom % consists solely of metal diboride crystals having a structure of the hexagonal system.
    Type: Grant
    Filed: April 21, 1989
    Date of Patent: May 29, 1990
    Assignee: Agency of Industrial Science and Technology
    Inventors: Tadahiko Watanabe, Kazuhisa Shobu, Yukio Kai, Hideki Yamamoto, Eiichi Sudoh, Osamu Yagishita, Junshiro Hayakawa
  • Patent number: 4927461
    Abstract: The machinability characteristics of P/M ferrous sintered compacts are improved when the compact is prepared from a ferrous powder having a maximum particle size less than about 300 microns, and from at least about 0.01 weight percent of a boron nitride powder comprising agglomerates of irregular-shaped, submicron particles.
    Type: Grant
    Filed: November 2, 1988
    Date of Patent: May 22, 1990
    Assignee: Quebec Metal Powders, Ltd.
    Inventors: Cavit Ciloglu, Martin Gagne, Edy Laraque, Joel Poirier, Sylvain Tremblay, Yves Trudel
  • Patent number: 4923512
    Abstract: Cobalt-bound tungsten carbide metal matrix composites having a unique microstructure are produced by consolidating partially sintered greenware under high pressures, e.g., 120,000 psi, at temperatures less than those used for conventional liquid phase sintering in a relatively short time, e.g., from less than one minute to less than about one hour. The composites have a binder phase which contains less than about 80 weight percent of the tungsten found in a composite prepared from the same or similar compositions via liquid phase sintering. These composites provide cutting tools with both toughness and wear resistance which exceed that of cutting tools made from the same or similar compositions via liquid phase sintering.
    Type: Grant
    Filed: April 7, 1989
    Date of Patent: May 8, 1990
    Assignee: The Dow Chemical Company
    Inventors: Ed E. Timm, Douglas B. Schwarz
  • Patent number: 4917859
    Abstract: The present invention provides a dewaxing process for metal powder compact which comprises the steps of embeding in alumina powder an injection-molded metal powder compact consisting of metal powder and an organic binder including low melting point substances; heating the embeded compact to a temperature of 200.degree. C. in a chemically inert atmosphere in a dewaxing furnace, thereby removing the low melting point substances from the compact without deformation of the compact; placing the compact in a closed sintering vessel so as to keep the surrounding temperature constant and disposing the vessel in a vacuum furnace; evacuating the vacuum furnace; and removing the organic binder by heating to a temperature of 550.degree. to 650.degree. C. at a heating rate of 300.degree. to 600.degree. C./hr while supplying an inert gas into the vacuum furnace.
    Type: Grant
    Filed: September 6, 1989
    Date of Patent: April 17, 1990
    Assignee: Mitsubishi Steel Mfg. Co., Ltd.
    Inventor: Kazunori Hamo
  • Patent number: 4915898
    Abstract: An improved method for the continuous fabrication of metal-hydride, electrochemical, hydrogen storage alloy, negative electrodes for use in rechargeable nickel metal hydride cells. The improved method comprises the steps of reducing the size of a high hardness, metal hydride, hydrogen storage alloy by shattering it along natural fracture line thereof. The process next includes providing measured amounts of powered metal hydride electrochemical hydrogen storage alloy material and disposing said material upon a continuous wire mesh screen substrate. Thereafter, the powdered metal hydride electrochemical hydrogen storage alloy and wire mesh screen are subjected to a compaction process wherein they are rolled and pressed so as to form a single integral electrode web which is subsequently exposed to a high temperature sintering process in a chemically inert environment.
    Type: Grant
    Filed: February 9, 1989
    Date of Patent: April 10, 1990
    Assignee: Energy Conversion Devices, Inc.
    Inventors: Merle Wolff, Mark A. Nuss, Michael A. Fetchenko, Andrea L. Lijoi, Steven P. Sumner, Joseph LaRocca, Thomas Kaatz
  • Patent number: 4915735
    Abstract: A wear-resistant sintered alloy comprising an Cr-C-Fe base alloy in which 0.5 to 3% by weight of CaF.sub.2 and 5 to 20% by weight of hard particles having particle size of 44 to 150 .mu.m and a mean value of Vickers hardness of 800 to 2000 are dispersed. This wear-resistant sintered alloy is produced by a method comprising the steps of adding 1.2 to 2% by weight of carbon powder, 0.5 to 3% by weight of calcium fluoride powder, and 5 to 20% by weight of hard metal powder having the particle size of 44 to 150 .mu.m and a mean value of Vickers hardness of 800 to 2000, to an Fe-Cr-C base alloy powder containing 10 to 20% by weight of Cr and 0.8 to 1.5% by weight of C, mixing them, molding the resultant mixed powder into a desired shaped, and then sintering the compact in the temperature range of from 1180.degree. to 1260.degree. C. in a non-oxidizing atmosphere. The sintered alloy is useful as a material for parts required to have the heat resistance and wear resistance.
    Type: Grant
    Filed: May 10, 1988
    Date of Patent: April 10, 1990
    Assignee: Sumotomo Electric Industries, Ltd.
    Inventor: Naoki Motooka
  • Patent number: 4915736
    Abstract: The present invention relates to a novel method of manufacturing a composite body, such as a ZrB.sub.2 -ZrC-Zr composite body, by utilizing a carburization technique. Moreover, the invention relates to novel products made according to the process. The novel process modifies the residual parent metal which remains in a composite body, by exposing said residual metal to a carburizing environment. Thus, by modifying the composition of residual parent metal, the properties of the resultant composite body can also be modified. Parent metals such as zirconium, titanium, and hafnium are well suited to be treated by the carburizing process according to the present invention.
    Type: Grant
    Filed: December 23, 1987
    Date of Patent: April 10, 1990
    Assignee: Lanxide Technology Company, LP
    Inventors: Terry D. Claar, Gerhard H. Schiroky
  • Patent number: 4913739
    Abstract: A process for the powder metallurgical production of structural parts of high strength and hardness from silicon-manganese or silicon-manganese-carbon alloyed steels. The alloying elements Si and Mn or Si, Mn and C are mixed, in powder form, by way of the alloy carriers ferrosilicon, ferromanganese or a silicon-manganese-iron master alloy containing silicon and manganese in the ranges from 10 to 30 weight percent Si, 20 to 70 weight percent Mn, remainder Fe, with an iron powder and when carbon is present with graphite, to form a powder mixture. The powder mixture is compressed and sintered at a temperature in a range from 1150.degree. C. to 1250.degree. C. and then cooled.
    Type: Grant
    Filed: March 8, 1985
    Date of Patent: April 3, 1990
    Assignee: Kernforschungszentrum Karlsruhe GmbH
    Inventors: Fritz Thummler, Aloisio N. Klein, Rainer Oberacker
  • Patent number: 4911989
    Abstract: A coated cemented carbide alloy having jointly a high toughness and high wear resistance is produced by specifying the cooling rate during sintering in efficient manner, which alloy comprises a cemented carbide substrate consisting of a hard phase of at least one member selected from the group consisting of carbides, nitrides and carbonitrides of Group IVa, Va and VIa metals of Periodic Table and a binder phase consisting of at least one member selected from the iron group metals, and a monolayer or multilayer, provided thereon, consisting of at least one member selected from the group consisting of carbides, nitrides, oxides and borides of Group IVa, Va and VIa metals of Periodic Table, solid solutions thereof and aluminum oxide, in which the hardness of the cemented carbide substrate in the range of 2 to 5 .mu.m from the interface between the coating layer and substrate is 800 to 1300 kg/mm.sup.
    Type: Grant
    Filed: April 10, 1989
    Date of Patent: March 27, 1990
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventors: Nakano Minoru, Tobioka Masaaki, Nomura Toshio
  • Patent number: 4911882
    Abstract: The present invention relates to the preparation of permanent magnet materials of the Iron-Boron-Rare Earth type.
    Type: Grant
    Filed: February 8, 1989
    Date of Patent: March 27, 1990
    Assignee: SPS Technologies, Inc.
    Inventor: Frank S. Greenwald
  • Patent number: 4906529
    Abstract: A method is provided for producing an erosion-resistant layer or coating on the surface of a metallic workpiece. The method includes providing a thermally sprayable alloy of Ni-Cr-Fe-B-Si and thermally spraying the alloy on the workpiece to a specified thickness, following which the sprayed-on layer is heated in vacuum to a temperature between 250.degree. C. to 400.degree. C. for a time at the stated temperature of about 5 to 30 minutes sufficient to effect degassing of the layer. The temperature of the layer is thereafter raised to a range of about 800.degree. C. to 950.degree. C. and maintained at that temperature in vacuum for between 5 to 30 minutes. The temperature at the layer is then raised to between 900.degree. C. and 1100.degree. C. under a protctive atmoshpere at a pressure of between 200 to 600 mm Hg to effect fursion of the layer at above its melting point, following which the coated metallic workpiece is finally cooled to room temperature under the protective atmosphere.
    Type: Grant
    Filed: February 4, 1987
    Date of Patent: March 6, 1990
    Assignee: Castolin S.A.
    Inventors: Niels Brundbjerg, Wolfgang Simm
  • Patent number: RE33243
    Abstract: The invention relates to a process for the treatment of a metal oxide powder, particularly a UO.sub.2 or PuO.sub.2 powder, with a view to its fritting.This process consists of oxidizing the powder, so as to form on its surface a hydrated oxide layer of the same metal. When the oxide is UO.sub.2 or PuO.sub.2 and mixtures thereof, as well as those prepared with ThO.sub.2, the treated powder can be used for producing nuclear fuel pellets by cold compression, followed by fritting.
    Type: Grant
    Filed: January 13, 1989
    Date of Patent: June 26, 1990
    Assignee: Commissariat a l'Energie Atomique
    Inventors: Camille Braun, Joel Danroc, Bernard Francois, Jean Michel