Tin Containing Patents (Class 420/419)
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Patent number: 11946118Abstract: A titanium-based alloy composition consisting in weight percent, of: 3.0 to 7.0% aluminium, 3.0 to 10.0% vanadium, 3.0 to 10.0% molybdenum, 2.0 to 7.0% tin, 0.0 to 6.0% zirconium, 0.0 to 5.0% niobium, 0.0 to 0.5% iron, 0.0 to 4.0% chromium, 0.0 to 2.0 tungsten, 0.0 to 0.5 % nickel, 0.0 to 0.5% tantalum, or between 0.0 to 2. tantalum when the sum of niobium and tantalum is 5.0% or less, 0.0 to 0.5% cobalt, 0.0 to 0.75% silicon, 0.0 to 0.5% boron, 0.0 to 0.5% carbon, 0.0 to 0.5% oxygen, 0.0 to 0.5% hydrogen, 0.0 to 0.5% nitrogen, 0.0 to 0.5% palladium, 0.0 to 0.5% lanthanum, 0.0 to 0.5% manganese or 0.0 to 2.5% manganese when the sum of chromium and manganese is 4.0 wt. % or less, 0.0 to 1.0% hafnium, the balance being titanium and incidental impurities which satisfies the following relationship: 0.027V+0.178Fe+0.055(Mo+0.5W)+0.016Zr+0.044Cr+0.033(Nb+Ta)+0.053Sn>1.Type: GrantFiled: September 24, 2019Date of Patent: April 2, 2024Assignee: ALLOYED LIMITEDInventor: Enrique Alabort Martinez
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Patent number: 11920231Abstract: A non-limiting embodiment of a titanium alloy comprises, in weight percentages based on total alloy weight: 5.5 to 6.5 aluminum; 1.5 to 2.5 tin; 1.3 to 2.3 molybdenum; 0.1 to 10.0 zirconium; 0.01 to 0.30 silicon; 0.1 to 2.0 germanium; titanium; and impurities. A non-limiting embodiment of the titanium alloy comprises a zirconium-silicon-germanium intermetallic precipitate, and exhibits a steady-state creep rate less than 8×10?4 (24 hrs)?1 at a temperature of at least 890° F. under a load of 52 ksi.Type: GrantFiled: January 28, 2022Date of Patent: March 5, 2024Assignee: ATI PROPERTIES LLCInventors: John V. Mantione, David J. Bryan, Matias Garcia-Avila
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Patent number: 11920219Abstract: The present invention provides a TiAl-based alloy, including: Al: 41 to 43 at %; Fe: 0 to 2.5 at %; Ni: 0 to 2.5 at %; Mo: 0 to 2.0 at %; W: 0 to 2.0 at %; Cr: 0 to 4.5 at %; Mn: 0 to 5.5 at %; V: 0 to 10 at %; Nb: 0 to 10 at %; C: 0.3 to 0.7 at %; and a remainder consisting of Ti and inevitable impurities, in which an alloy element parameter “P=(41.5?Al)/3+Fe+Ni+Mo+W+0.5 Cr+0.4 Mn+0.2 V+0.2 Nb—C” is in a composition range of 1.1 to 1.9, and the TiAl-based alloy has a microstructure consisting of a ? phase of 5 to 30 area %, a ? phase of 0.5 to 5 area %, and a lamellar structure occupying a remaining part.Type: GrantFiled: December 13, 2019Date of Patent: March 5, 2024Assignee: National Institute for Materials ScienceInventor: Toshimitsu Tetsui
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Patent number: 11041402Abstract: A titanium alloy may be characterized by a good oxidation resistance, high strength and creep resistance at elevated temperatures up to 750° C., and good cold/hot forming ability, good superplastic forming performance, and good weldability. The alloy may contain, in weight percent, aluminum 4.5 to 7.5, tin 2.0 to 8.0, niobium 1.5 to 6.5, molybdenum 0.1 to 2.5, silicon 0.1 to 0.6, oxygen up to 0.20, carbon up to 0.10, and balance titanium with incidental impurities.Type: GrantFiled: February 23, 2018Date of Patent: June 22, 2021Assignee: HOWMET AEROSPACE INC.Inventors: Fusheng Sun, Ernest M. Crist, Kuang-O Yu
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Patent number: 10119178Abstract: A titanium alloy having high strength, fine grain size, and low cost and a method of manufacturing the same is disclosed. In particular, the inventive alloy offers a strength increase of about 100 MPa over Ti 6-4, with a comparable density and near equivalent ductility. The inventive alloy is particularly useful for a multitude of applications including components of aircraft engines. The Ti alloy comprises, in weight percent, about 6.0 to about 6.7% aluminum, about 1.4 to about 2.0% vanadium, about 1.4 to about 2.0% molybdenum, about 0.20 to about 0.42% silicon, about 0.17 to about 0.23% oxygen, maximum about 0.24% iron, maximum about 0.08% carbon and balance titanium with incidental impurities.Type: GrantFiled: January 12, 2012Date of Patent: November 6, 2018Assignee: Titanium Metals CorporationInventors: Roger Thomas, Paul Garratt, John Fanning
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Patent number: 9700766Abstract: A golf club head with an improved striking face is disclosed herein. More specifically, the present invention utilizes an innovative die quenching method that can alter the Young's modulus of the material of the striking face. The striking face portion of the present invention generally created from an ?+? titanium alloy such as SP 700 that contains a ? rich alloy composition to create more phase change in the alloying elements. In a preferred embodiment, the die quenching process could create a localized change in the material's Young's modulus throughout different regions of the striking face, resulting in a change in the Young's modulus of the material within the same striking face.Type: GrantFiled: July 30, 2015Date of Patent: July 11, 2017Assignee: Acushnet CompanyInventors: Ryuichi Sugimae, Uday V. Deshmukh, Heng-Jui Henry Yeh
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Patent number: 9433835Abstract: A golf club head with an improved striking face is disclosed herein. More specifically, the present invention utilizes an innovative die quenching method that can alter the Young's modulus of the material of the striking face. The striking face portion of the present invention generally created from an ?+? titanium alloy such as SP 700 that contains a ? rich alloy composition to create more phase change in the alloying elements. In a preferred embodiment, the die quenching process could create a localized change in the material's Young's modulus throughout different regions of the striking face, resulting in a change in the Young's modulus of the material within the same striking face.Type: GrantFiled: April 1, 2013Date of Patent: September 6, 2016Assignee: Acushnet CompanyInventors: Ryuichi Sugimae, Uday V. Deshmukh, Heng-Jui Henry Yeh
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Publication number: 20150056006Abstract: A welding wire formed of a trace boron titanium base alloy is provided, along with welds formed from the wire and articles comprising one or more of such welds. A method may include forming such a weld or welds from such a welding wire, and may also include non-destructively inspecting titanium alloy articles comprising one or more of such welds using ultrasonic waves to detect internal flaws.Type: ApplicationFiled: November 5, 2014Publication date: February 26, 2015Inventors: Jeffrey J. Bernath, Sesh A. Tamirisakandala
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Publication number: 20140356221Abstract: Titanium alloy that is formed by subjecting titanium alloy to a treatment containing a hydrogen storing step for making the titanium alloy store hydrogen therein, a solution-treatment step for heating the titanium alloy having the hydrogen stored therein in the hydrogen storage step to apply a solution treatment to the hydrogen-stored titanium alloy, a cooling step for cooling the heated hydrogen-stored titanium alloy to develop martensitic transformation in the hydrogen-stored titanium alloy, a hot rolling step for heating the martensitic-transformed titanium alloy to a temperature which is not more than a predetermined transformation point and hot-rolling the martensitic-transformed titanium, and a dehydrogenation step for dehydrogenating the hot-rolled titanium alloy, thereby bringing the titanium alloy with the superplastic property.Type: ApplicationFiled: May 22, 2014Publication date: December 4, 2014Applicants: THE JAPAN RESEARCH INSTITUTE OF INDUSTRIAL SCIENCE, HONDA MOTOR CO., LTD.Inventors: Jun NAKAHIGASHI, Kyo TAKAHASHI
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Patent number: 8894738Abstract: A titanium base alloy powder having lesser amounts of aluminum and vanadium with an alkali or alkaline earth metal being present in an amount of less than about 200 ppm. The alloy powder is neither spherical nor angular and flake shaped. 6/4 alloy is specifically disclosed having a packing fraction or tap density between 4 and 11%, as is a method for making the various alloys.Type: GrantFiled: September 10, 2010Date of Patent: November 25, 2014Assignee: Cristal Metals Inc.Inventors: Lance E. Jacobsen, Adam John Benish
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Patent number: 8741217Abstract: There is provided a titanium alloy for corrosion-resistant materials, which contains 0.01-0.12% by mass in total of at least one of platinum group elements; at least Si and one of, or both of, Sn and Mn, selected from the group consisting of Al, Cr, Zr, Nb, Si, Sn and Mn, wherein the total content of Al, Cr, Zr, Nb, Si, Sn and Mn is 5% by mass or less; and the residue comprising Ti and impurities.Type: GrantFiled: June 15, 2010Date of Patent: June 3, 2014Assignee: Nippon Steel & Sumitomo Metal CorporationInventors: Satoshi Matsumoto, Keisuke Nagashima, Takashi Maeda
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Publication number: 20130336835Abstract: A titanium alloy product according to the present invention: has a strength level higher than that of an existing titanium alloy product; can be successfully cold rolled (coil rolled); and is also provided with workability. In the titanium alloy product according to the invention, expensive alloy elements are not essentially required, and hence cost can be suppressed. The titanium alloy product according to the invention includes Al equivalent represented by (Al+10O (oxygen)): 3.5 to 7.2% (% by mass, the same hereinafter), Al: more than 1.0% and 4.5% or less, O: 0.60% or less, Fe equivalent represented by (Fe+0.5Cr+0.5Ni+0.67Co+0.67Mn): 0.8% or more and less than 2.0%, and one or more elements selected from the group consisting of Cu: 0.4 to 3.0% and Sn: 0.4 to 10%, in which the balance is Ti and unavoidable impurities.Type: ApplicationFiled: April 24, 2013Publication date: December 19, 2013Applicant: Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.)Inventor: Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.)
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Patent number: 8562763Abstract: A high strength ?+?-type titanium alloy, containing, by mass %, 4.4% to less than 5.5% of Al, 1.4% to less than 2.1% of Fe, and 1.5 to less than 5.5% of Mo and including, as impurities, Si suppressed to less than 0.1% and C suppressed to less than 0.01% and a balance of Ti and unavoidable impurities.Type: GrantFiled: April 5, 2005Date of Patent: October 22, 2013Assignee: Nippon Steel & Sumitomo Metal CorporationInventors: Hiroaki Otsuka, Hideki Fujii, Mitsuo Ishii
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Patent number: 8349248Abstract: A metallic material is made from at least one refractory metal or an alloy based on at least one refractory metal. The metallic material has an oxygen content of about 1,000 to about 30,000 ?g/g and the oxygen is interstitial.Type: GrantFiled: April 13, 2006Date of Patent: January 8, 2013Assignee: Heraeus Precious Metals GmbH & Co. KGInventors: Jens Trotzschel, Bernd Spaniol
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Publication number: 20120076611Abstract: An article of manufacture selected from a titanium alloy fastener and a titanium alloy fastener stock including an alpha/beta titanium alloy comprising, in percent by weight: 3.9 to 5.4 aluminum; 2.2 to 3.0 vanadium; 1.2 to 1.8 iron; 0.24 to 0.3 oxygen; up to 0.08 carbon; up to 0.05 nitrogen; titanium; and up to a total of 0.3 of other elements. In certain embodiments, article of manufacture has an ultimate tensile strength of at least 170 ksi (1,172 MPa) and a double shear strength of at least 103 ksi (710.2 MPa). A method of manufacturing a titanium alloy fastener and a titanium alloy fastener stock comprising the alpha/beta alloy is disclosed.Type: ApplicationFiled: September 23, 2010Publication date: March 29, 2012Applicant: ATI Properties, Inc.Inventor: David J. Bryan
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Publication number: 20120076686Abstract: An alpha/beta titanium alloy comprising, in percent by weight based on total alloy weight: 3.9 to 4.5 aluminum; 2.2 to 3.0 vanadium; 1.2 to 1.8 iron; 0.24 to 0.30 oxygen; up to 0.08 carbon; up to 0.05 nitrogen; up to 0.015 hydrogen ; titanium; and up to a total of 0.30 of other elements. A non-limiting embodiment of the alpha/beta titanium alloy comprises an aluminum equivalent value in the range of 6.4 to 7.2, exhibits a yield strength in the range of 120 ksi (827.4 MPa) to 155 ksi (1,069 MPa), exhibits an ultimate tensile strength in the range of 130 ksi (896.3 MPa) to 165 ksi (1,138 MPa), and exhibits a ductility in the range of 12 to 30 percent elongation.Type: ApplicationFiled: May 16, 2011Publication date: March 29, 2012Applicant: ATI Properties, Inc.Inventors: David J. Bryan, John V. Mantione, Thomas D. Bayha
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Publication number: 20110318220Abstract: A cold rolled titanium alloy plate with a sufficient cold workability and excellent superplasticity characteristics is provided. The cold rolled titanium alloy plate consists of, by mass %, Al of 2.0 to 4.0% and V of 4.0 to 9.0%, one element selected from Zr of not more than 2.0% and Sn of not more than 3.0% and the balance being Ti and impurities, a ratio of ?/? is not less than 0.3 and not more than 0.6; where “?” is an area of a phase in the plate and “?” is an area of ? phase in the plate, and the plate has an elongation at break in a tensile test conducted at 800° C. exceeds 200%.Type: ApplicationFiled: July 11, 2011Publication date: December 29, 2011Applicant: SUMITOMO METAL INDUSTRIES, LTD.Inventor: Atsuhiko KURODA
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Publication number: 20110268602Abstract: Provided herein are titanium alloys that can achieve a combination of high strength and high toughness or elongation, and a method to produce the alloys. By tolerating iron, oxygen, and other incidental elements and impurities, the alloys enable the use of lower quality scrap as raw materials. The alloys are castable and can form ?-phase laths in a basketweave morphology by a commercially feasible heat treatment that does not require hot-working or rapid cooling rates. The alloys comprise, by weight, about 3.0% to about 6.0% aluminum, 0% to about 1.5% tin, about 2.0% to about 4.0% vanadium, about 0.5% to about 4.5% molybdenum, about 1.0% to about 2.5% chromium, about 0.20% to about 0.55% iron, 0% to about 0.35% oxygen, 0% to about 0.007% boron, and 0% to about 0.60% other incidental elements and impurities, the balance of weight percent comprising titanium.Type: ApplicationFiled: April 29, 2011Publication date: November 3, 2011Applicant: QuesTek Innovations LLCInventors: James A. Wright, Jason Sebastian, Herng-Jeng Jou
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Publication number: 20110027121Abstract: An oxidation resistant, high strength titanium alloy, particularly adapted for use in the manufacture of automotive exhaust system components and other applications requiring oxidation resistance and strength at elevated temperatures. The alloy comprises, in weight percent, iron less than 0.5, or 0.2 to less than 0.5%, oxygen 0.02 to less than 0.15%, silicon 0.15 to 0.6%, and balance titanium. Optional alloying elements are Al, Nb, V, Mo, Sn, Zr, Ni, Cr and Ta, with a total content of less than 1.5.Type: ApplicationFiled: August 2, 2010Publication date: February 3, 2011Inventors: Yoji Kosaka, Stephen P. Fox
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Publication number: 20100329919Abstract: A titanium base alloy powder having lesser amounts of aluminum and vanadium with an alkali or alkaline earth metal being present in an amount of less than about 200 ppm. The alloy powder is neither spherical nor angular and flake shaped. 6/4 alloy is specifically disclosed having a packing fraction or tap density between 4 and 11%, as is a method for making the various alloys.Type: ApplicationFiled: September 10, 2010Publication date: December 30, 2010Inventors: Lance E. Jacobsen, Adam John Benish
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Publication number: 20100310410Abstract: There is provided a titanium alloy for corrosion-resistant materials, which contains 0.01-0.12% by mass in total of at least one of platinum group elements; at least Si and one of, or both of, Sn and Mn, selected from the group consisting of Al, Cr, Zr, Nb, Si, Sn and Mn, wherein the total content of Al, Cr, Zr, Nb, Si, Sn and Mn is 5% by mass or less; and the residue comprising Ti and impurities.Type: ApplicationFiled: June 15, 2010Publication date: December 9, 2010Inventors: Satoshi Matsumoto, Keisuke Nagashima, Takashi Maeda
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Patent number: 7722805Abstract: The patent provides the titanium alloy with extra-low modulus and superelasticity containing 20˜35 wt. % niobium, 2˜15 wt. % zirconium, balanced titanium and other unavoidable impurity elements. The advantages of the invention alloy are shown as follows: The invention titanium alloy has superior cold processing capacity and low work hardening rate; It can be severely deformed by cold rolling and cold drawing; It has superelasticity, shape memory effect, damping capacity, low modulus, high strength, good corrosion resistance and high biocompatibility; The invention titanium alloy can be made into nano-size materials by cold deformation and extra high strength can be achieved by heat treatment.Type: GrantFiled: November 25, 2004Date of Patent: May 25, 2010Assignee: Institute of Metal Research Chinese Academy of SciencesInventors: Yulin Hao, Shujun Li, Rui Yang
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Publication number: 20090180918Abstract: A titanium-aluminum-tin alloy applied to a golf club head includes 89 wt % to 95 wt % titanium (Ti), 3.5 wt % to 6.5 wt % aluminum (Al), and 1.5 wt % to 3.5 wt % tin (Sn), and minor elements such as niobium (Nb), vanadium (V), molybdenum (Mo), zirconium (Zr), chromium (Cr), iron (Fe), silicon (Si), oxygen (O), and nitrogen (N) may be selectively added into the titanium-aluminum-tin alloy, so as to form a material with a high elongation from 11% to 15% and a tensile strength from 700 Mpa to 950 Mpa, which can be applied to a main body and a hitting surface of a golf club head, thereby achieving a golf club head product with good hitting sense, desirable damping capability, expected golf-controlling capability and a customized feature of an adjustable angle at a club portion, together with the internal structural designs of the main body, weighting structure, and rib design.Type: ApplicationFiled: March 12, 2008Publication date: July 16, 2009Applicant: ADVANCED INTERNATIONAL MULTITECH CO., LTD.Inventors: Liang-Ho TSAI, Cheng-Tao LEE
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Patent number: 7479194Abstract: A damage tolerant microstructure for a lamellar alloy, such as a lamellar ?TiAl alloy, is provided in accordance with the present invention. The alloy comprises a matrix and a plurality of grains or lamellar colonies, a portion of which exhibit a nonplanar morphology within said matrix. Each of the lamellar colonies contains a multitude of lamella with irregularly repeating order. The ?TiAl platelets have a triangular (octahedral) unit cell and stack with ? twins. The ?2Ti3Al platelets are irregularly interspersed. The unit cell for ?2Ti3Al is hexagonal. Each of the layers has a curved, nonplanar structure for resisting crack formation and growth.Type: GrantFiled: August 8, 2005Date of Patent: January 20, 2009Assignee: United Technologies CorporationInventor: Daniel P. DeLuca
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Publication number: 20080253922Abstract: A method for surface roughening a metal work piece includes disposing the work piece proximate to a counter electrode. The work piece and the counter electrode are disposed in an electrolyte. An electric potential with current flow is applied between the work piece and the counter electrode to roughen the metal surface to a desired roughness.Type: ApplicationFiled: April 13, 2007Publication date: October 16, 2008Inventors: Andrew Lee Trimmer, Bin Wei, Joshua Leigh Miller, Nicholas Joseph Kray, Michael Scott Lamphere
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Publication number: 20080181808Abstract: A method of treating an article including a titanium alloy having 5-6.5% aluminum by weight; 1.5-2.5% tin by weight; 1.5-2.5% chromium by weight; 1.5-2.5% molybdenum by weight; 1.5-2.5% zirconium by weight; and titanium. The method includes heat treating the titanium alloy without exposing the titanium alloy to a beta anneal process. There is also an article that has been subjected to a heat treatment process that does not include a beta anneal.Type: ApplicationFiled: January 31, 2007Publication date: July 31, 2008Inventors: Samuel Vinod Thamboo, Ling Yang
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Publication number: 20080035250Abstract: A process for casting titanium alloy based parts includes the steps of melting a quantity of titanium alloy to form a molten titanium alloy; adding to the molten titanium alloy a quantity of boron in an amount of about 0.2 weight percent to about 1.3 weight percent of the molten titanium alloy to form a molten boron modified titanium alloy; and casting a boron modified titanium alloy based part.Type: ApplicationFiled: August 9, 2006Publication date: February 14, 2008Inventors: Tai-Tsui Aindow, Prabir R. Bhowal
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Patent number: 7261782Abstract: A titanium alloy obtained by a cold-working step, in which 10% or more of cold working is applied to a raw titanium alloy, comprising a Va group element and the balance of titanium substantially, and an aging treatment step, in which a cold-worked member, obtained after the cold-working step, is subjected to an aging treatment so that the parameter “P” falls in a range of from 8.0 to 18.5 at a treatment temperature falling in a range of from 150° C. to 600° C.; and characterized in that its tensile elastic limit strength is 950 MPa or more and its elastic deformation capability is 1.6% or more. This titanium alloy is of high elastic deformation capability as well as high tensile elastic limit strength, and can be utilized in a variety of products extensively.Type: GrantFiled: December 5, 2001Date of Patent: August 28, 2007Assignee: Kabushiki Kaisha Toyota Chuo KenkyushoInventors: JungHwan Hwang, Tadahiko Furuta, Kazuaki Nishino, Takashi Saito
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Patent number: 7008489Abstract: An alpha-beta, titanium-base alloy with improved ductility at high strength levels compared to commercially available alloys, such as Ti-17. The alloy exhibits at least a 20% improvement in ductility at a given strength level compared to Ti-17. The alloy comprises, in weight %, 3.2 to 4.2 Al, 1.7 to 2.3 Sn, 2 to 2.6 Zr, 2.9 to 3.5 Cr, 2.3 to 2.9 Mo, 2 to 2.6 V, 0.25 to 0.75 Fe, 0.01 to 0.8 Si, 0.21 max. Oxygen and balance Ti and incidental impurities.Type: GrantFiled: May 22, 2003Date of Patent: March 7, 2006Assignee: Ti-Pro LLCInventor: Paul J. Bania
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Patent number: 6979375Abstract: A titanium alloy member is characterized in that it comprise 40% by weight or more titanium (Ti), a IVa group element and/or a Va group element other than the titanium, wherein a summed amount including the IVa group element and/or the Va group element as well as the titanium is 90% by weight or more, and one or more members made in an amount of from 0.2 to 2.0% by weight and selected from an interstitial element group consisting of oxygen, nitrogen and carbon, and that its basic structure is a body-centered tetragonal crystal or a body-centered cubic crystal in which a ratio (c/a) of a distance between atoms on the c-axis with respect to a distance between atoms on the a-axis falls in a range of from 0.9 to 1.1. This titanium alloy member has such working properties that conventional titanium alloys do not have, is flexible, exhibits a high strength, and can be utilized in a variety of products.Type: GrantFiled: May 1, 2001Date of Patent: December 27, 2005Assignee: Kabushiki Kaisha Toyota Chuo KenkyushoInventors: Tadahiko Furuta, Yoshiki Seno, JungHwan Hwang, Kazuaki Nishino, Takashi Saito
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Patent number: 6918971Abstract: A sheet, a plate, a bar or wire is made of Ti and has high ductility and low material anistropy in a plane of a sheet or plate, or in a sectional plane of a bar or a wire and contains Fe, in mass, at 0.15-0.5%, N at 0.015-0.041 and 0, with the balance Ti and unavoidable impurities. When the Fe content is defined as [Fe], the N content as [N] and the 0 content as [0], the oxygen equivalent value Q=[0]+2.77[N]+0.1 [Fe] is 0.11-0.28.Type: GrantFiled: August 22, 2002Date of Patent: July 19, 2005Assignee: Nippon Steel CorporationInventors: Hideki Fujii, Isamu Takayama, Yoshito Yamashita, Mitsuo Ishii, Kazuhiro Takahashi
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Patent number: 6814820Abstract: An article is formed of an alpha-beta titanium-base alloy, preferably an alloy having more than about 3.5 weight percent molybdenum. An example of such an article is a gas turbine compressor blade having a nominal composition, in weight percent, of about 4 percent aluminum, about 4 percent molybdenum, about 2 percent tin, about 0.5 percent silicon, balance titanium and impurities. The article is processed to form a martensitic structure therein. The processing, which typically involves forging or weld repairing, includes the steps of first heating the article to a first-heating temperature of greater than about 1600° F., and thereafter first cooling the article to a temperature of less than about 800° F. The article is thereafter second heated to a second-heating temperature of from about 1275° F. to about 1375° F. for a time of from about 1 to about 7 hours, and thereafter second cooled to a temperature of less than about 800° F.Type: GrantFiled: July 6, 2001Date of Patent: November 9, 2004Assignee: General Electric CompanyInventor: Kazim Ozbaysal
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Patent number: 6726784Abstract: A high strength and ductility &agr;+&bgr; type titanium alloy, comprising at least one is isomorphous &bgr; stabilizing element in a Mo equivalence of 2.0-4.5 mass %, at least one eutectic &bgr; stabilizing element in an Fe equivalence of 0.3-2.0 mass %, Si in an amount of 0.1-1.5 mass %, and C in an amount of 0.01-0.15% mass, and has a &bgr; transformation temperature no lower than 940° C.Type: GrantFiled: September 16, 2002Date of Patent: April 27, 2004Inventors: Hideto Oyama, Takayuki Kida, Kazumi Furutani, Masamitsu Fujii
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Titanium alloy, member made of the titanium alloy and method for producing the titanium alloy member
Patent number: 6007923Abstract: A joined tubular body comprises a titanium alloy pipe of which crystal grain is hard to coarsen at the time of welding or hot-extruding, which consists by weight percentage of at least one element selected from 0.01.about.10% of S, 0.01.about.10% of Se and 0.01.about.10% of Te (the total sum does not exceed 10%), one or both of 0.01.about.10% REM and 0.01.about.10% of Ca (the total sum does not exceed 10%), and the above pipe is joined to a titanium alloy pipe consisting of the above elements and also at least one element selected from Al.ltoreq.10%, V.ltoreq.25%, Sn.ltoreq.15%, Co.ltoreq.10%, Cu.ltoreq.10%, Ta.ltoreq.15%, Mn.ltoreq.10%, Hf.ltoreq.10%, W.ltoreq.10%, Si.ltoreq.0.5%, Nb.ltoreq.20%, Zr.ltoreq.10%, Mo.ltoreq.15%, and 0.ltoreq.0.1% (the total sum does not exceed 30%).Type: GrantFiled: June 6, 1996Date of Patent: December 28, 1999Assignee: Daido Tokushuko Kabushiki KaishaInventors: Takao Shimizu, Seiya Asari, Noriyoshi Yokota -
Patent number: 5922274Abstract: A titanium alloy having improved heat resistance in addition to the inherent properties of lightness and corrosion resistance. The alloy consists essentially of, by weight %, Al: 5.0-7.0%, Sn: 3.0-5.0%, Zr: 2.5-6.0%, Mo: 2.0-4.0%, Si: 0.05-0.80%, C: 0.001-0.200%, O: 0.05-0.20%, optionally further one or two of Nb and Ta: 0.3-2.0%, and the balance of Ti and inevitable impurities. A method of producing parts from this alloy comprises subjecting the titanium alloy of the above described alloy composition to heat treatment at a temperature of .beta.-region, combination of rapid cooling and slow cooling or combination of water quenching and annealing, hot processing in .alpha.+.beta. region, solution treatment and aging treatment.Type: GrantFiled: December 22, 1997Date of Patent: July 13, 1999Assignee: Daido Steel Co., Ltd.Inventors: Akihiro Suzuki, Toshiharu Noda, Michio Okabe
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Patent number: 5849112Abstract: The invention is a process for simultaneously improving at least two mechanical properties of mill-processed (.alpha.+.beta.) titanium alloy, which may or may not contain silicon, which includes steps of heat treating the mill-processed titanium alloy such that the (.alpha.+.beta.) microstructure of said alloy is transformed into an (.alpha.+.alpha..sub.2 +.beta.) microstructure, preferably containing no silicides. The heat treating steps involve subjecting the mill-processed titanium alloy to a sequence of thermomechanical process steps, and the mechanical properties which are simultaneously improved include (a) tensile strength at room, cryogenic, and elevated temperatures; (b) fracture toughness; (c) creep resistance; (d) elastic stiffness; (e) thermal stability; (f) hydrogen embrittlement resistance; (g) fatigue; and (h) cryogenic temperature embrittlement resistance. As a consequence of the process, the (.alpha.+.alpha..sub.2 +.beta.) microstructure contains equiaxed alpha phase strengthened with .alpha.Type: GrantFiled: December 16, 1996Date of Patent: December 15, 1998Assignee: Boeing North American, Inc.Inventor: Sami M. El-Soudani
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Patent number: 5542992Abstract: A TiAl base alloy containing 46 to 54 mol % of Ti and 46 to 52 mol % of Al in which Sb is added within a range of 0.1 to 1 mol %, at least one element of Hf and/or Zr is further added within a range of 0 to 3 mol %, and three phases of a .gamma. phase, an .alpha..sub.2 phase and Sb-rich phase coexist.Type: GrantFiled: March 2, 1995Date of Patent: August 6, 1996Assignee: National Research Institute For MetalsInventors: Kenki Hashimoto, Minoru Nobuki, Morihiko Nakamura, Haruo Doi
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Patent number: 5366570Abstract: A titanium matrix composite having eutectically formed titanium alloy reinforcement containing at least two of the elements of silicon, aluminum, zirconium, manganese, chromium, molybdenum, carbon, iron, boron, cobalt, nickel, germanium and copper.Type: GrantFiled: March 2, 1993Date of Patent: November 22, 1994Assignee: Cermics Venture InternationalInventors: Vladislav I. Mazur, Yuri N. Taran, Svetlana V. Kapustnikova, Viktor I. Trefilov, Sergey A. Firstov, Leonid D. Kulak
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Patent number: 5358686Abstract: A titanium-base alloy, and weldment made therefrom, consisting essentially of, in weight percent, aluminum 4 to 5.5, preferably 5.0, tin up to 2.5, preferably 0.5 to 1.5 or 1; zirconium up to 2.5, preferably 0.5 to 1.5 or about 1; vanadium 0.5 to 2.5, preferably 0.5 to 1.5 or about 1; molybdenum 0.3 to 1, preferably, 0.66 to 1 or about 0.8; silicon up to 0.15, preferably 0.07 to 0.13 or about 0.1; oxygen 0.04 to 0.12, preferably 0.07 to 0.11 or about 0.09; iron 0.01 to 0.12, preferably 0.01 to 0.09 or about 0.07 and balance titanium and incidental impurities.Type: GrantFiled: February 17, 1993Date of Patent: October 25, 1994Inventors: Warren M. Parris, James A. Hall, Paul J. Bania, Ivan L. Caplan
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Patent number: 5348702Abstract: This invention relates to TiAl based intermetallic compound alloy and process for producing; the object of this invention is to improve high temperature deformability. The alloy comprises basic components: Ti.sub.y AlCr.sub.x, wherein 1%.ltoreq.X.ltoreq.5%, 47.5%.ltoreq.Y.ltoreq.52%, and X+2Y.gtoreq.100%, and comprises a fine-grain structure with a .beta. phase precipitated on a grain boundary of equiaxed .gamma. grain having grain size of less than 30 .mu.m, and possessing a superplasticity such that the strain rate sensitivity factors (m value) is 0.40 or more and tensile elongation is 400% or more tested at 1200.degree. C. and a strain rate of 5.times.10.sup.-4 S.sup.-1.Type: GrantFiled: March 5, 1993Date of Patent: September 20, 1994Assignee: Nippon Steel CorporationInventors: Munetsugu Matsuo, Naoya Masahashi, Keizo Hashimoto, Toshihiro Hanamura, Hideki Fujii, Masao Kimura, Youji Mizuhara, Hiroo Suzuki
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Patent number: 5232661Abstract: This invention relates to TiAl based intermetallic compound alloy and process for producing; the object of this invention is to improve high temperature deformability. The alloy comprises basic components: Ti.sub.y AlCr.sub.x, wherein 1%.ltoreq.X.ltoreq.5%, 47.5%.ltoreq.Y.ltoreq.52%, and X+ 2Y.gtoreq.100%, and comprises a fine-grain structure with a .beta. phase precipitated on a grain boundary of equiaxed .gamma. grain having grain size of less than 30 .mu.m, and possessing a superplasticity such that the strain rate sensitivity factors (m value) is 0.40 or more and tensile elongation is 400% or more tested at 1200.degree. C. and a strain rate of 5.times.10.sup.-4 S.sup.-1.Type: GrantFiled: August 8, 1991Date of Patent: August 3, 1993Assignee: Nippon Steel CorporationInventors: Munetsugu Matsuo, Naoya Masahashi, Keizo Hashimoto, Toshihiro Hanamura, Hideki Fujii, Masao Kimura, Youji Mizuhara, Hiroo Suzuki
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Patent number: 5215600Abstract: A sheet of Ti 6-2-2-2-2 alloy having a starting thickness of between approximately 0.040 inches and 0.187 inches is thermomechanically treated at a temperature of between approximately 1500 degrees F. and 1750 degrees F. at a mechanical strain rate in the range of between approximately 1.times.10.sup.-4 and 1.times.10.sup.-2 inch per inch per second to produce a formed part having a tensile strength which is approximately 33% greater than untreated rolled Ti 6-2-2-2-2 alloy sheet or plate.Type: GrantFiled: July 22, 1991Date of Patent: June 1, 1993Assignee: Rohr, Inc.Inventors: Mark S. Bertolini, Brian Norris, Michael J. Waring
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Patent number: 5209790Abstract: A method of making a Titanium, Vanadium and Chromium alloy substantially free of Titanium-Chromium phases and inclusions of undissolved Vanadium including the steps of alloying preselected amounts of Vanadium and Chromium to produce a stable phase alloy substantially free of unalloyed Chromium or Vanadium and then mixing and melting the stable phase alloy together with a preselected amount of Titanium to produce the final alloy composition.Type: GrantFiled: February 11, 1992Date of Patent: May 11, 1993Assignee: Teledyne Industries, Inc.Inventor: Chester C. Wojcik
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Patent number: 5171408Abstract: The titanium alloy T1 17, having a nominal composition of about 5 weight percent aluminum, about 2 weight percent zirconium, about 2 weight percent tin, about 4 weight percent molybdenum, about 4 weight percent chromium, no more than about 1.1 percent of other elements, and balance titanium, is electrochemically machined using an electrolyte comprising an aqueous solution of from about 0.94 to about 1.16 moles per liter of bromide anion and from about 0.09 to about 0.55 moles per liter of sodium nitrate.Type: GrantFiled: November 1, 1991Date of Patent: December 15, 1992Assignee: General Electric CompanyInventor: Roy F. Thornton
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Patent number: 5082506Abstract: A method for providing improved ductility in a castable gamma titanium aluminide is taught. The method involves adding inclusions of boron to the titanium aluminide containing higher concentrations of niobium and thermomechanically working the casting. Boron additions are made in concentrations between 0.5 and 2 atomic percent. Fine grain equiaxed microstructure is found from solidified melt. Property improvements are achieved by the thermomechanical processing.Type: GrantFiled: September 26, 1990Date of Patent: January 21, 1992Assignee: General Electric CompanyInventor: Shyh-Chin Huang
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Patent number: 5041262Abstract: A novel titanium base alloy having a micrograph with alpha plates oriented in three directions with respect to their parent beta grains, but with alpha plates so short that no basketweave pattern is evident. The alloy contains from 0.02 to 2.0 atomic percent boron; 6 to 30 atomic percent aluminum; 0 to 4 atomic percent tin; 0 to 4 atomic percent gallium; and may contain 0 to 6 atomic percent zirconium of hafnium or a mixture of the two; 0 to 12 atomic percent of at least one metal selected from the group consisting of vanadium, columbium, tantalum, chromium, molybdenum, rhenium, tungsten, ruthenium, and the platinum group metals; and from 0 to 2 atomic percent of at least one element selected from the group consisting of yttrium, carbon and the rare earth metals.Type: GrantFiled: October 6, 1989Date of Patent: August 20, 1991Assignee: General Electric CompanyInventor: Michael F. X. Gigliotti, Jr.
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Patent number: 4906436Abstract: Alpha titanium alloys containing aluminum, hafnium and/or tantalum has been found to have improved creep and tensile strengths as well as oxidation resistance at temperature up to about 700.degree. C. without embrittlement.Type: GrantFiled: June 27, 1988Date of Patent: March 6, 1990Assignee: General Electric CompanyInventors: Francis X. Gigliotti, Jr., Raymond G. Rowe, Gerald E. Wasielewski, deceased
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Patent number: 4859415Abstract: A method of improving the resistance of oil-well tubular products made of .alpha.-type or (.alpha.+.beta.)-type Ti-based alloys to corrosion in a deep-well environment at high temperatures is disclosed. The method is characterized by adding, as an alloying element, (A) at least one platinum group metal in an amount of 0.02-0.20% by weight, or (B) at least one platinum group metal in an amount of 0.005-0.12% by weight and optionally at least one of Ni, Co, W, and Mo in an amount of 0.05-2.00% by weight.Type: GrantFiled: October 29, 1987Date of Patent: August 22, 1989Assignee: Sumitomo Metal Industries, Ltd.Inventors: Yoshiaki Shida, Shiro Kitayama, Tomio Nishikawa
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Patent number: 4842820Abstract: A TiAl composition is prepared to have high strength and to have improved ductility by altering the atomic ratio of the titanium and aluminum to have what has been found to be a higly desirable effective aluminum concentration by addition of boron according to the approximate compositions displayed in the shaded area of FIG. 10.Type: GrantFiled: December 28, 1987Date of Patent: June 27, 1989Assignee: General Electric CompanyInventors: Shyh-Chin Huang, Michael F. X. Gigliotti, Jr.
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Patent number: 4810465Abstract: A free-cutting Ti alloy is disclosed. The basic alloy composition of this free-cutting Ti alloy essentially consists of at least one of S: 0.001-10%, Se: 0.001-10% and Te: 0.001-10%; REM: 0.01-10%; and one or both of Ca: 0.001-10% and B: 0.005-5%; and the balance substantially Ti. The Ti alloy includes one or more of Ti-S (Se, Te) compounds, Ca-S (Se, Te) compounds, REM-S (Se, Te) compounds and their complex compounds as inclusions to improve machinability. Some optional elements can be added to above basic composition.Also disclosed are methods of producing the above free-cutting Ti alloy and a specific Ti alloy which is a particularly suitable material for connecting rods.Type: GrantFiled: February 9, 1987Date of Patent: March 7, 1989Assignee: Daido Tokushuko Kabushiki KaishaInventors: Atsuyoshi Kimura, Sadayuki Nakamura