Abstract: A composite material for use as a lead replacement, comprising a high density metal such as tungsten (W), a lower density metal such as tin (Sn) and an organic additive is disclosed. Also disclosed are processes for forming such composites. The composite is particularly useful in ammunition.

Abstract: The tungsten/heavy metal alloy is suitable for tools such as extrusion dies and extrusion mandrels for the hot-forming of copper and copper alloys. The novel alloy consists of 80 to 89.9% by weight of tungsten, 2 to 7% by weight of chromium, and a remainder of binder metal. The use of the novel alloy primarily results in a considerably reduced formation of grooves on the surface of the forming tools.

Abstract: A barrier coating is disclosed, containing about 15 atom % to about 95 atom % chromium; and about 5 atom % to about 60 atom % of at least one of rhenium, tungsten, and ruthenium. Nickel, cobalt, iron, and aluminum may also be present. The barrier coating can be disposed between a metal substrate (e.g., a superalloy) and an oxidation-resistant coating, preventing the substantial diffusion of various elements at elevated service temperatures. A ceramic overcoat (e.g., based on zirconia) can be applied over the oxidation-resistant coating. Related methods for applying protective coatings to metal substrates are also described.

Abstract: Disclosed are a tungsten material for a penetrating splinter shell and forming method thereof enabling a penetrator to perforate a hard target on high-speed impact as well as having the following splinter cause a severe damage on an inner component by changing a breakage characteristic of the material into brittle fracture from ductile fracture in a manner that a mechanical characteristic of the material is adjusted by controlling a sintering condition and a composition ratio of a tungsten heavy alloy material having Mo added thereto. The present invention includes the steps of mixing 90˜95 wt % W powder, 3.0˜8.0 wt % Mo powder, 0.5˜3.0 wt % Ni powder, and 1.0˜4.0 wt % Fe powder with each other, molding the mixed powders, and sintering the molded powders.

Abstract: Sputter target, method of manufacture of same and sputter coating process using the target as a sputtering source are disclosed. The sputter target comprises an Me/Si multi-phase, consolidated blend wherein the Si component is present in a very small amount of about trace—0.99 mole Si:1 mole Me. Preferably, Me comprises one or more of Ta, Ti, Mo, or W. The targets are made from the requisite powders via HIP consolidation to provide densities of greater than 98 % of the theoretical density. The targets are especially useful in reactive cathodic sputtering systems employing N2 as the reactive gas to form amorphous Me/Si/N layers.

Abstract: Medium- and high-density articles are formed from melting and casting alloys containing tungsten, iron, nickel and optionally manganese and/or steel. In some embodiments, the articles have densities in the range of 8-10.5 g/cm3, and in other embodiments, the articles have densities in the range of 10.5-15 g/cm3. In some embodiments, the articles are ferromagnetic, and in others the articles are not ferromagnetic. In some embodiments, tungsten forms the largest weight percent of the alloy, and in other embodiments the alloy contains no more than 50 wt % tungsten. In some embodiments, the articles are shell shot.

Abstract: Methods for producing medium-density articles from recovered high-density tungsten alloy (WHA) material, and especially from recovered WHA scrap. In one embodiment of the invention, the method includes forming a medium-density alloy from WHA material and one or more medium- to low-density metals or metal alloys. In another embodiment, medium-density grinding media, such as formed from the above method, is used to mill WHA scrap and one or more matrix metals into particulate that may be pressed and, in some embodiments, sintered to form medium-density articles therefrom.

Abstract: Medium- and high-density articles are formed from melting and casting alloys containing tungsten, iron, nickel and optionally manganese and/or steel. In some embodiments, the articles have densities in the range of 8-10.5 g/cm3, and in other embodiments, the articles have densities in the range of 10.5-15 g/cm3. In some embodiments, the articles are ferromagnetic, and in others the articles are not ferromagnetic. In some embodiments, tungsten forms the largest weight percent of the alloy, and in other embodiments the alloy contains no more than 50 wt % tungsten. In some embodiments, the articles are shell shot.

Abstract: Ductile, high-density, non-toxic W—Ni—Mn—Fe alloy compositions and methods of manufacture by which they may be converted to shot (for use in shotshells) and other useful products traditionally made of lead alloys are presented. Product of the present invention is softer than gun barrel steels and may be hand-loaded (and recycled/reloaded) into shotshells using conventional powders, primers, casings and wads. If desired for game law enforcement, shot of the present invention may be formulated to be ferromagnetic while retaining all other desirable attributes.

Abstract: A Mo—W material for the formation of wirings is discloses which, as viewed integrally, comprises 20 to 95% of tungsten and the balance of molybdenum and inevitable impurities by atomic percentage. The Mo—W material for wirings is a product obtained by compounding and integrating a Mo material and a W material as by the powder metallurgy technique or the smelting technique or a product obtained by arranging these materials in amounts calculated to account for the percentage composition mentioned above. The Mo—W material containing W in a proportion in the range of from 20 to 95% manifests low resistance and, at the same time, excels in workability and tolerance for etchants. The wiring thin film which is formed of the Mo—W alloy of this percentage composition is used as address wirings and others for liquid crystal display devices.

Abstract: The invention relates to non-sag tungsten wire for being used in light sources or heating elements, which tungsten wire is prepared from a tungsten block by powder metallurgy process with thermomechanical technique, and has an overlapped crystal structure after recrystallization and contains a dopant material. The essential feature of the tungsten wire according to the invention is that as the dopant material, it contains at least one of the following additive materials: lanthanum/III/oxide, cerium dioxide.

Abstract: Structural units which come into contact with glass melts and ceramic melts are exposed to strong corrosive attack. Molybdenum is a known material for glass melt electrodes but it is not usable for the majority of highly corrosive glass and ceramic melts. The use of a special molybdenum and/or tungsten alloy as the material for the structural unit reduces corrosion even in the case of contact with highly corrosive glass and ceramic melts.

Abstract: A high density, non-magnetic alloy is described along with a process for manufacturing it. The preferred composition for the alloy is approximately 95% by weight of tungsten and 5% of austenitic stainless steel. The process for manufacturing the alloy begins with blending tungsten and stainless steel powders which are then mixed with an organic binder to form a feedstock. The latter is then molded into the form of compacted items, such as a hard drive counterweight balance, and then sintered in either vacuum or a hydrogen atmosphere. The tungsten heavy alloys of the present invention can be easily manufactured in large volume economically in many intricate shapes with excellent control of weight and dimensions.

Abstract: A novel metal silicide target material is provided which can effectively restrict the occurrence of fine particles. The target material has a structure comprising metal silicide and free silicon, which material has a relative density more than 100% which relative density is defined by a ratio of a true density of the target material to a theoretical density obtained by calculation, and free silicon portions in the structure of the target material which free silicon portions are provided with Vickers hardness less than 1,100 or which free silicon portions are provided with dislocation-undetectable areas each having a diameter not less than 1 .mu.m. Further, it is desirable that a rupture load evaluated by acoustic emission at which rupture load there occurs rupture in a scratching test of the surface of target material by acoustic emission is not less than 50N.

Abstract: Secondary recrystallized grains having a plurality of crystal orientations in a polycrystalline compact of molybdenum or tungsten, which contains at least one element selected from the group consisting of calcium and magnesium in amount of 0.007 to 0.090 atom %, are formed by locally heating an end portion(s) of the polycrystalline compact. Some grains, which have a prescribed crystal orientation, selected from these secondary recrystallized grains are subsequently grown in the whole polycrystalline compact by annealing.

Abstract: A single phase W-Ti sputter target and a method of manufacturing the target are disclosed. The target is produced by mixing powders of tungsten and titanium and subjecting the mixed powders to a pressing operation for a time, temperature and pressure sufficient to achieve a mutual solid solution of W and Ti, forming single .beta.(Ti,W) phase. The single phase sputtering target emits much less particulate during sputtering than conventional multiphase W-Ti targets of comparable density and composition.

Abstract: Copper-tungsten alloys used for materials of electrode, electric contacts, package materials for semiconductors, heat sink and their manufacturing methods. The copper-tungsten alloy contains preferably 5 to 30 wt. % of copper, 0.002 to 0.04 wt. % of phosphor, the remaining portion being substantially all tungsten, and it is preferable to contain in these alloys 0.1 to 0.5% of cobalt, nickel or iron or else any combined two out of these three.

Abstract: A high density, high strength and high compressive strain tungsten heavy alloy consists essentially of tungsten in the amount of approximately 90% by weight, and the rest Mn and Ni in an amount sufficient to cause sintering at between 1100.degree. and 1400.degree. C. The W-Ni-Mn alloy exhibits characteristics of intense shear bands (which could indicate failure by adiabatic shear during high strain-rate dynamic testing) thus making it an attractive material for kinetic energy penetrators. Moreover, the alloy provides an inexpensive high density material which can be produced in furnaces for conventional ferrous powder metal part manufacturing and other conventional non-ferrous powder metal part manufacturing by lowering the sintering temperature by 2000.degree. to 300.degree. C.

Abstract: Methods of making high specific gravity shotgun shot and small arms projectiles from melts containing primarily tungsten and iron, and particularly including specific melting temperature depressants and using specific quenching both compositions are described and specific conditions and materials and methods for making high specific gravity shot pellets and projectiles by powder metallurgical techniques are described.

Abstract: A tungsten based sintered alloy has excellent corrosion resistance under high temperatures and high humidities, and has good toughness. The alloy can be employed as such without requiring further corrosion protection such as Ni plating, due to its corrosion resistance, and allows for plastic deformation such as caulking, due to its toughness or good elongation. The tough corrosion-resistant tungsten based sintered alloy consists of 80 to 97 percent by weight of tungsten, and a remainder of Ni, Co, and optionally Fe and unavoidable impurities. The alloy most particularly has a Co content of at least 2 and not more than 60 percent by weight, an Fe content of more than 0 and less than 5 percent by weight, and a remainder of Ni in a Ni--Co--Fe binder phase.

Abstract: Disclosed is a flow-softening tungsten alloy having the general formula:W.sub.100-p T.sub.x M.sub.y B.sub.zwherein W is tungsten; T is one or more elements selected from the group sisting of titanium, zirconium and hafnium; M is one or more elements selected from the group consisting of molybdenum, tantalum. iron, cobalt, nickel,manganese and vanadium; B is one or more of the elements selected from the group consisting of boron, carbon, silicon and aluminum; x is from 5 to 30 weight percent; y is from 1 to 10 weight percent; z is from 0 to 2 weight percent; and p is equal to or less than 30 weight percent. In this alloy p is approximately equal to the sum of x, y and z. A method of preparing this alloy and a kinetic energy penetrator manufactured from it are also disclosed.

Abstract: The present invention discloses an electrode wiring material including at least one main element selected from the group consisting of Mo and W and an additional element selected from the group consisting of Kr and Xe in an amount of 0.0003 atomic % to 3 atomic %. The present invention further discloses an electrode wiring substrate including an electrode wiring formed on a glass substrate, wherein the electrode wiring is formed of at least one metal selected from the group consisting of Mo and W and the lattice constant of the electrode wiring material is almost equal to the lattice constant of the electrode wiring material in a bulk state.

Abstract: A firearm bolt prepared from an alloy of tungsten, nickel and iron having a density of about from 14.1 g/cc to 18.0 g/cc. The alloy preferably also contains at least one of molybdenum, cobalt, rhenium, tantalum and gold. The alloy is preferably manufactured by standard powder metallurgical techniques followed by a liquid phase sinter and vacuum anneal. The bolt can also be manufactured using solid state sintering. The bolt can also be manufactured by mechanically working the material after sintering, after annealing, or after both sintering and annealing.

Abstract: An arc discharge electrode material used for various electrode materials for arc welding, which is excellent in arc ignitability and consumability. The composition is 0.02 to 1.0 wt % lanthanum boride and the rest of tungsten.

Abstract: This invention relates to fine-particle powders of the metals Fe, Co, Ni, W and/or Mo which have a defined particle size of 1.0 nm to less than 1 00 nm. Less than 1% of the individual particles of the powder deviate by more than 40% from the average particle size, and no individual particle of the powder deviates by more than 60% from the average particle size.

Abstract: A titanium-tungsten target material capable of limiting the amount of particles generated during sputtering and a method of manufacturing this titanium-tungsten material. The titanium-tungsten target material has a titanium-tungsten alloy phase which occupies 98% or more of the whole area of the material as observed in a micro-structure thereof. In one example of the manufacturing method, an ingot obtained by melting tungsten and titanium is processde by a solution treatment to form a titanium-tungsten target, or a power obtained by melting the ingot is sintered to form a target. Preferably, the melting may be performed under reduced pressure in an electron beam melting manner. In another example of the manufacturing method, a powder is formed from a molten metal by an atomization method and the obtained powder is sintered to form a titanium-tungsten target. For sintering of the powder, it is preferable to apply hot isostatic pressing or hot pressing.

Abstract: A tungsten based heavy alloy having a W--Ni--Fe based composition containing traces of lanthanum or calcium, thereby capable of exhibiting high toughness, irrespective of the content of impurities such as phosphorous and sulfur contained therein, the cooling rate after the sintering treatment and the re-heating treatment. The present invention provides a method for making the high toughness tungsten based heavy alloy. The tungsten based heavy alloy of the present invention is useful to manufacture warheads for breaking armor plates, which require high toughness.

Abstract: A method for heat-treatment of tungsten based alloys, capable of improving impact toughness while keeping tensile strength and elongation. The method comprises maintaining a sintered tungsten based alloy consisting of 86 to 99 weight % tungsten and the balance at least one selected from a group consisting of nickel, iron, copper, cobalt and molybdenum, at a temperature ranged from 950.degree. to 1,350.degree. C. for a maintenance time of one minute to 24 hours, quenching the sintered alloy in water or in oil, and repeating the maintaining and quenching steps.

Abstract: Alloys of tungsten and uranium and a method for making the alloys. The amount of tungsten present in the alloys is from about 55 vol % to about 85 vol %. A porous preform is made by sintering consolidated tungsten powder. The preform is impregnated with molten uranium such that (1) uranium fills the pores of the preform to form uranium in a tungsten matrix or (2) uranium dissolves portions of the preform to form a continuous uranium phase containing tungsten particles.

Abstract: Tungsten-titanium sputter targets of at least 95% theoretical density are provided with little or no .beta.(Ti, W) phase constituent. Such targets will minimize troublesome particulate emissions during sputter coating conditions.

Abstract: A substrate material for a magnetic head, which comprises an oxide composed mainly of WO.sub.3 and has a thermal expansion coefficient of 100 to 130.times.10.sup.-7 /.degree. C., and a magnetic head using the substrate material.

Abstract: A vibration-proof tungsten wire which forms, in cases where the diameter of the wire is D mm and when an electric current corresponding to 90% of the fusion current value is passed therethrough for 5 minutes, a wire havinga crystal grain boundary at which bubbles of 0.3 .mu.m or less in diameter are dispersed in bubble rows with lengths of (0.39/D).sup.2 .times.3 .mu.m or more arrayed in the wire axis direction of said crystal grain boundary, and bubbles of 0.2 .mu.m or less in diameter are randomly dispersed; anda crystal grain in which bubbles of 0.3 .mu.m or less in diameter are dispersed in rows with lengths of (0.39/D).sup.2 .times.30 .mu.m or more arrayed in the wire axis direction within said crystal grain, and bubbles of 0.2 .mu.m or less are randomly dispersed;a process for preparing the same; and a tungsten filament obtained from the above-defined wire. The doped tungsten wire of this invention possesses excellent vibration-proof property on lighting as well as high reliability.

Abstract: This invention relates to heat and corrosion resistant alloys for structural parts in industrial furnaces and similar installations requiring hot strength, long life and resistance to hot gas corrosion, carburization and thermal fatigue, and to master alloys to aid in the production of these alloys. The alloys consist of additions of less than one percent by weight each of the components tungsten, zirconium, molybdenum, columbium, titanium and one or more rare earth elements to base alloys of the types standardized by the Alloy Castings Institute Division of the Steel Founders Society of America or to similar base alloys. The master alloys consist of all of these components, with the possible exception of Mo, combined together in the desired proportions, possibly along with some combination of iron, nickel or chromium in total content of up to about half of the master alloys by weight as partial diluents. The resultant master alloys are always denser than molten baths of the base heat resistant alloys.

Abstract: A W-Ni-Co penetrator has a composition of 90 to 98 weight percent tungsten, the balance being nickel and cobalt, the weight ration of nickel to cobalt being between 1:1 to 9:1.

Abstract: There are disclosed pharmaceutical compositions containing polyoxoanions, methods of using them alone or in combination with other compounds, such as AZT and Poly-I:C for the treatment of retroviruses. Also disclosed are novel polyoxoanions.

Abstract: An amorphous aluminum-refractory metal alloy with special characteristics such as high corrosion resistance, high wear resistance and considerable toughness, consisting of Al and at least one element selected from refractory metals of Ta, Nb, Mo and W, a portion of the set forth refractory metals being allowed to be substituted with at least one element selected from Ti and Zr.

Abstract: An amorphous aluminum-refractory metal alloy with special characteristics such as high corrosion resistance, high wear resistance and considerable toughness, consisting of Al and at least one element selected from refractory metals of Ta, Nb, Mo and W, a portion of the set forth refractory metals being allowed to be substituted with at least one element selected from Ti and Zr.

Abstract: A tungsten alloy is used as a material of an electrode wire for electric spark cutting. The tungsten alloy comprises one or more elements selected from the group consisted of Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu and oxides thereof. An electrode wire made of such a tungsten alloy handles an improved processing speed and the accuracy of the cut surface is also improved. The number of failures due to breaking of the electrode wire has been reduced and the tensile strength of the electrode wire has been increased. The same effect can be attained when a molybdenum alloy containing one or more oxides of elements selected from the group consisted of Al, Si and K is used as an alloying component in the alloy for making the electrode wire for electric spark cutting.

Abstract: A superconducting material made of tungsten or molybdenum containing a specified amount of silicon, a wiring made of this superconducting material, and a semiconductor device using this wiring.The above-mentioned superconducting material undegoes no damage even in the steps of heat treatments effected after the formation of a wiring therefrom by virtue of its high melting point, and can be very easily patterned by reactive ion etching using SF.sub.6 as an etching gas, which has heretofore been generally employed. These features, in which conventional superconducting materials are lacking, allow the superconducting material of the present invention to exhibit excellent properties particularly when used in the wirings of a semiconductor device.

Abstract: A consolidated tungsten alloy body consisting essentially of from about 60% to about 98% by weight of tungsten, balance, nickel and iron, containing a continuous phase of tungsten and a discontinuous phase of grains of a tungsten, nickel and iron alloy having an aspect ratio of at least 4:1 relatively uniformly distributed throughout the continuous phase and wherein said body has a recrystallization temperature of from about 1000.degree. C. to about 1200.degree. C. A process for producing the consolidated bodies comprises working and annealing at controlled temperatures to achieve the desired properties. The working temperatures are from about 700.degree. C. to about 900.degree. C. and the annealing temperature is preferably 1200.degree. C.

Abstract: Tungsten-rich alloys of formula W.sub.100-P M.sub.X RE.sub.Y ME.sub.Z wherein W is tungsten, M is one or more elements selected from the group consisting of transition elements, RE is an element selected from the group consisting of rare earth and actinide elements, ME is silicon, boron, germanium or aluminum, X is 0 to 25 weight %, Y is 0 to 2 weight %, Z is 0.1 to 3 weight % and P=X+Y+Z where P.ltoreq.26 weight % are disclosed. The alloys possess high strength and ductility. A method for preparing the alloys by rapid solidification processing is also disclosed.

Abstract: A tungsten heavy alloy system is modified by replacing from 2% to 10% of the tungsten by weight with tantalum to increase the strength and hardness characteristics for the alloy. This renders the alloy particularly useful for kinetic energy penetrators.

Abstract: A tungsten heavy alloy system is modified by partial replacement of the tungsten with substantial amounts of molybdenum ranging from 2% to 16% by weight to produce a new alloy with greater strength and hardness and moderate ductility. This new alloy is particularly useful for kinetic energy penetrators. The process involved is liquid phase sintering in an atmosphere of dry hydrogen, then wet hydrogen, then argon, followed by heat treament at 1100.degree. C. with a water quench. The resulting alloy is further hardened by swaging and strain aging which, at certain levels of molybdenum, produces a material having hardness in excess of HRC 45.

Abstract: New alloys highly resistant to corrosion by concentrated acid and having excellent adhering properties when coated on stainless steel are formed of 60 to 90 atomic percent tantalum or tungsten, with the remainder being iron, chromium and nickel in the proportions found in stainless steel, e.g., 304L stainless steel. They may be formed in situ on the surface to be coated by sputter deposition, using a sputter target which is part tungsten or tantalum, and part stainless steel.

Abstract: A low density tungsten alloy article is disclosed and the method for producing the article. The method involves compacting a relatively uniform tungsten alloy powder with the tungsten content comprising no greater than about 90% by weight of the alloy and the balance a matrix phase to produce a preformed article which is then sintered in a reducing atmosphere at a temperature below the melting point of the matrix phase for a sufficient time to form a densified article which is mechanically worked to produce the final article.

Abstract: There is provided a high-purity molybdenum target or high-purity molybdenum silicide target for LSI electrodes which comprises a high-purity metallic molybdenum having an alkali metal content of not more than 100 ppb and a radioactive element content of not more than 10 ppb. Further, a process is provided for producing such target comprising a wet purification processing followed by a series of dry processings.

Abstract: This invention relates to a sintering process. More particularly, this invention relates to a process for preparing a sintered form having a tungsten content which comprises the steps of:(a) sintering a porous form of pressed tungsten alloy powders having a high tungsten content in solid phase, and(b) heat treating the sintered part from step (a) in a liquid phase.

Abstract: Solid solutions of molybdenum and tungsten having molybdenum to tungsten atom ratios between about 1:1 and about 10:1 are produced by heating a mechanically milled mixture of a molybdenum oxide and tungsten oxide to a temperature between about 1000.degree. C. and about 1300.degree. C. at a rate of at least about 20.degree. C. per minute in a hydrogen-containing atmosphere and holding at temperature to reduce the oxides of molybdenum and tungsten and to provide a homogeneous solid solution of molybdenum and tungsten. The homogeneous solid solution is mixed with a stoichiometric excess of carbon and heated to a temperature between about 1200.degree. C. and about 1800.degree. C. under a protective atmosphere to react the carbon with the alloy powder to form a solid solution of hexagonal monocarbides.

Abstract: Tungsten heavy alloys comprising by weight from about 80 to about 100% tuten and from about 0 to about 20% of one or more heavy alloying metals are produced by introducing powders of tungsten and the alloying metals into a thermal spray plasma gun, melting the powders in the hot zone of the gun to form a molten alloy and then spraying the molten alloy in droplet form into a collecting chamber where the droplets are solidified, and the resultant alloy in powdered form is collected. The powdered alloy can be further mixed with powdered copper, iron, nickel, cobalt or tantalum and compacted by dynamic or explosive compaction to form a near full density material. Full density materials are produced by further thermomechanical processing of the compact.

Abstract: Tungsten heavy alloys comprising by weight from about 80 to about 100% tuten and from about 0 to about 20% of one or more heavy alloying metals are produced by introducing powders of tungsten and the alloying metals into a thermal spray plasma gun, melting the powders in the hot zone of the gun to form a molten alloy and then spraying the molten alloy in droplet form into a collecting chamber where the droplets are solidified, and the resultant alloy in powdered form is collected. The powdered alloy can be further mixed with powdered copper, iron, nickel, cobalt or tantalum and compacted by dynamic or explosive compaction to form a near full density material. Full density materials are produced by further thermomechanical processing of the compact.