Rare Earth, Magnesium Or Alkaline Earth Metal Containing Patents (Class 420/443)
  • Patent number: 6375869
    Abstract: Manganese-free rare earth-transition metal AB5-type hydrogen-absorbing alloys having favorable high rate discharge characteristics, suitable for use in rechargeable batteries for electrical vehicles or hybrid electrical vehicles, include compositions of the general formula: R(CouAlvMwNi1−u−v−w)z, where R is at least one element selected from rare earth elements and yttrium (Y), M is at least one refractory metal selected from Groups IVB, VB, and VIB of the periodic table, the value of u is from 0 to about 0.25, v is from 0 to about 0.10, w is from 0 to about 0.05, and z, the ratio of R(CouAlvMwNi1−u−v−w)/R, is from about 4.70 to about 5.50. The unit cell volume is from about 87 to about 88.5 A3 at 25° C., the plateau pressure is from about 3 to about 10 apsi at 25° C., and the composition is essentially free of manganese.
    Type: Grant
    Filed: January 27, 2000
    Date of Patent: April 23, 2002
    Assignee: Santoku Corporation
    Inventors: Tsong P. Perng, Bao-Min Ma, James Landi, Qun Chen
  • Patent number: 6355117
    Abstract: Compositional requirements and processing improvements are disclosed which improve the hydrogen embrittlement resistance and the fatigue resistance in air of nickel base single crystal articles. The compositional requirements enlarge the difference between the &ggr;′ solvus temperature and the incipient melting temperature, thus enabling the solution of &ggr;/&ggr;′ eutectic islands without causing incipient melting, while hot isostatic pressing and careful melt practice eliminate porosity and carbides, borides and nitrides, all of which act as crack initiation sites.
    Type: Grant
    Filed: March 1, 2000
    Date of Patent: March 12, 2002
    Assignee: United Technologies Corporation
    Inventors: Daniel P. DeLuca, Bradford A. Cowles, Maurice L. Gell, David N. Duhl, Alan D. Cetel, Charles M. Biondo
  • Patent number: 6355212
    Abstract: The invention is directed to anti-corrosive alloys and relates in particular to an alloy containing cobalt, chromium, aluminum, yttrium, silicon, a metal from the second main group, together with the corresponding oxide, in the following proportions: chromium (Cr) 26.0-30%; aluminum (Al) 5.5-13.0%; yttrium (Y) 0.3-1.5%; silicon (Si) 1.5-4.5%; metal from the second main group (magnesium, calcium, barium, strontium) 0.1-2.0%; oxide of the corresponding metal from the second main group 0.1-2.0%; cobalt (Co) remaining percentage. Preferably, tantalum (Ta) is also added in a proportion of 0.5-4.0%, and the remaining percentage of cobalt is replaced by a remaining percentage of Me, Me being understood to mean a metal which may be nickel (Ni) or iron (Fe) or cobalt (Co) or a composition comprising Ni—Fe—Co, Ni—Fe, Ni—Co, Co—Fe.
    Type: Grant
    Filed: January 5, 2000
    Date of Patent: March 12, 2002
    Assignee: Turbocoating SpA
    Inventor: Nelso Antolotti
  • Patent number: 6287398
    Abstract: A high strength nickel-base alloy consisting essentially of, by weight percent, 50 to 60 nickel, 19 to 23 chromium, 18 to 22 iron, 3 to 4.4 aluminum, 0 to 0.4 titanium, 0.05 to 0.5 carbon, 0 to 0.1 cerium, 0 to 0.3 yttrium, 0.002 to 0.4 total cerium plus yttrium, 0.0005 to 0.4 zirconium, 0 to 2 niobium, 0 to 2 manganese, 0 to 1.5 silicon, 0 to 0.1 nitrogen, 0 to 0.5 calcium and magnesium, 0 to 0.1 boron and incidental impurities. The alloy forms 1 to 5 mole percent Cr7C3 after 24 hours at a temperature between 950 and 1150° C. for high temperature strength.
    Type: Grant
    Filed: December 9, 1998
    Date of Patent: September 11, 2001
    Assignee: Inco Alloys International, Inc.
    Inventors: Gaylord Darrell Smith, Norman Farr, Brian Allen Baker
  • Patent number: 6280540
    Abstract: The C-type nickel base alloys of the type containing significant amounts of chromium (about 16 to 25%) and molybdenum (about 12 to 18%) may be improved by adding small but critical amounts of copper (about 1 to 3.5%) which their general corrosion resistance to a wide range of both oxidizing and non-oxidizing industrial media.
    Type: Grant
    Filed: July 22, 1994
    Date of Patent: August 28, 2001
    Assignee: Haynes International, Inc.
    Inventor: Paul Crook
  • Patent number: 6130006
    Abstract: There is provided a hydrogen-absorbing alloy which contains an alloy ingot manufactured by means of a casting or sintering method or a pulverized product of the alloy ingot, and the alloy ingot being represented by the following general formula (1),(Mg.sub.1-a-b R1.sub.a M1.sub.b)Ni.sub.z (1)wherein R1 is at least one element selected from rare earth elements (including Y), M1 is at least one element selected from elements having a larger electronegativity than that of Mg (excluding the elements of R1, Cr, Mn, Fe, Co, Cu, Zn and Ni), and a, b and z are respectively a number satisfying conditions 0.1.ltoreq.a.ltoreq.0.8, 0<b.ltoreq.0.9, 1-a-b>0, and 3.ltoreq.z.ltoreq.3.8.
    Type: Grant
    Filed: June 16, 1998
    Date of Patent: October 10, 2000
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Tatsuoki Kohno, Isao Sakai, Masaaki Yamamoto, Motoya Kanda, Hideki Yoshida, Fumiyuki Kawashima, Takao Sawa, Takamichi Inaba, Shusuke Inada, Hirotaka Hayashida, Hiroshi Kitayama
  • Patent number: 6127047
    Abstract: High temperature alloys resistant to degradation and oxidation are provided. In accordance with preferred embodiments, alloys comprising from about 0.1 to about 50 atomic percent silicon, from about 10 to about 80 atomic percent aluminum, and at least one metal selected from the group consisting of chromium, iridium, rhenium, palladium, platinum, rhodium, ruthenium, osmium, molybdenum, tungsten, niobium and tantalum are formed. Shaped bodies and structural members comprising such alloys are also described as are methods for their fabrication.
    Type: Grant
    Filed: February 18, 1992
    Date of Patent: October 3, 2000
    Assignee: The Trustees of the University of Pennsylvania
    Inventors: Wayne L. Worrell, Kang N. Lee
  • Patent number: 6103383
    Abstract: A new nickel-chromium alloy having high rigidity, castability, corrosion and oxidation resistance and easy workability is disclosed. The alloy comprises from about 45 to 81% nickel by weight, from about 13 to 25% chromium by weight, from about 3 to 15% tungsten by weight, and silicon and aluminum in the range from about 1 to about 6% by weight each. The new alloy has a high concentration of tungsten.
    Type: Grant
    Filed: January 27, 1998
    Date of Patent: August 15, 2000
    Assignee: Jeneric/Pentron Incorporated
    Inventor: Arun Prasad
  • Patent number: 6093264
    Abstract: A nickel-based alloy composition is disclosed comprising from about 0.05 to about 3 percent by weight beryllium; from about 1 to about 40 percent by weight copper; no greater than about 10 percent by weight chromium, the balance being nickel. The alloy composition may be adjusted to achieve a high, as-cast hardness alloy over a wide range of alloy component contents, or a moderate, as-cast hardness alloy useful for forming articles such as golf clubs which has relatively constant mechanical properties over a wide range of copper contents.
    Type: Grant
    Filed: August 2, 1999
    Date of Patent: July 25, 2000
    Assignee: NGK Metals Corporation
    Inventors: Charles Walter Hershberger, Dennis Hall
  • Patent number: 6093369
    Abstract: An oxidation-resistant alloy for use in a high-temperature or thermal cycling environment. The alloy comprises a nickel-based matrix having a solid solution of 19-23% chromium and 3-6% aluminum. A self-healing, thermodynamically stable oxide layer is formed upon a surface of the alloy which is exposed to an oxidizing atmosphere over a range of temperatures for extended periods of time. The oxide layer protects the alloy from the oxidizing atmosphere. Additions of calcium and yttrium are made to the matrix to substantially remove or stabilize oxygen and sulfur dissolved in the molten alloy. These additions result in retention of about 0.005-0.05% of calcium and 0.01-0.06% yttrium in the cast alloy. The matrix further includes about 2-8% iron to inhibit nucleation and growth of a "gamma prime" nickel aluminum intermetallic compound which would otherwise adversely harden the alloy and cause local disturbance of a uniform distribution of aluminum. The alloy has a VHN below about 350.
    Type: Grant
    Filed: August 24, 1998
    Date of Patent: July 25, 2000
    Assignee: Hoskins Manufacturing Company
    Inventors: Bertie Forrest Hall, Jr., Stanley James Valykeo
  • Patent number: 6074602
    Abstract: The present invention is directed to the achievement of increased gas turbine engine efficiencies through further improvements in nickel-base superalloys used to make parts and components for gas turbine engines. The present invention comprises nickel-base superalloys for producing single crystal articles having a significant increase in temperature capability, based on stress rupture strength and low and high cycle fatigue properties, over single crystal articles made from current production nickel-base superalloys. Further, because of their superior resistance to degradation by cyclic oxidation, and their resistance to hot corrosion, the superalloys of this invention possess a balance in mechanical and environmental properties which is unique and has not heretofore been obtained.
    Type: Grant
    Filed: July 5, 1994
    Date of Patent: June 13, 2000
    Assignee: General Electric Company
    Inventors: Carl Stephen Wukusick, Leo Buchakjian, Jr.
  • Patent number: 6060174
    Abstract: A substrate (12) such as a superalloy turbine component is coated with a basecoat (14) of the type MCrAlY which also contains boron, where the amount of boron in the basecoat is in a concentration gradient where more boron is present near the top (16) than the bottom (20) of the basecoat (14) and boron is present in an average amount of over 0.50 wt. % throughout the basecoat cross-section (14) of the composite (10).
    Type: Grant
    Filed: May 26, 1999
    Date of Patent: May 9, 2000
    Assignee: Siemens Westinghouse Power Corporation
    Inventors: Stephen M. Sabol, John G. Goedjen
  • Patent number: 5998041
    Abstract: A joined article includes a ceramic member, another member, and a joining layer which is formed between the ceramic member and another member and joins both the members together, wherein the joining layer is composed mainly of nickel, and the joining layer contains beryllium as an activating component.
    Type: Grant
    Filed: March 12, 1997
    Date of Patent: December 7, 1999
    Assignee: NGK Insulators, Ltd.
    Inventors: Takuma Makino, Masayuki Shinkai
  • Patent number: 5997809
    Abstract: An alloy resistant to carburization and high temperature oxidation. The alloy consists essentially of, by weight percent, 27 to 35 chromium, 0 to 7 iron, about 3 to 4.4 aluminum, 0 to 0.4 titanium, 0.2 to 3 niobium, 0.12 to 0.5 carbon, 0 to 0.05 zirconium, 0.002 to 0.05 total cerium and yttrium, 0 to I manganese, 0 to I silicon, 0 to 0.5 calcium plus magnesium, 0 to 0.1 boron and balance nickel plus incidental impurities.
    Type: Grant
    Filed: December 8, 1998
    Date of Patent: December 7, 1999
    Assignee: Inco Alloys International, Inc.
    Inventors: Gaylord Darrell Smith, Norman Farr, Brian Allen Baker
  • Patent number: 5980821
    Abstract: The invention relates to an austenitic-chromium-iron alloy and its use as a material for articles with high resistance to isothermal and cyclic high temperature oxidation, high heat-resistance and high creep rupture strength at temperatures above 1100 to 1200.degree. C. The characterizing feature of the invention is that the austenitic nickel-chromium-iron alloy consists (in % by weight) of:______________________________________ 0.12 to 0.30% carbon 23 to 30% chromium 8 to 11% iron 1.8 to 2.4% aluminium 0.01 to 0.15% yttrium 0.01 to 1.0% titanium 0.01 to 1.0% niobium 0.01 to 0.20% zirconium 0.001 to 0.015% magnesium 0.001 to 0.010% calcium max 0.030% nitrogen max 0.50% silicon max 0.25% manganese max 0.020% phosphorus max 0.010% sulphur ______________________________________residue nickel, including unavoidable impurities caused by melting.
    Type: Grant
    Filed: April 2, 1992
    Date of Patent: November 9, 1999
    Assignee: Krupp-VDM GmbH
    Inventor: Ulrich Brill
  • Patent number: 5980653
    Abstract: A nickel-based alloy composition is disclosed comprising from about 0.05 to about 3 percent by weight beryllium; from about 1 to about 40 percent by weight copper; no greater than about 10 percent by weight chromium, the balance being nickel. The alloy composition may be adjusted to achieve a high, as-cast hardness alloy over a wide range of alloy component contents, or a moderate, as-cast hardness alloy useful for forming articles such as golf clubs which has relatively constant mechanical properties over a wide range of copper contents.
    Type: Grant
    Filed: January 23, 1997
    Date of Patent: November 9, 1999
    Assignee: NGK Metals Corporation
    Inventors: Charles Walter Hershberger, Dennis Hall
  • Patent number: 5939204
    Abstract: An article that is used to transport a hot oxidizing gas, in particular a flue gas in a gas turbine, has a surface acted upon by the gas. This surface is formed by an alloy which has 10 to 40 wt. % chrome, 1 to 20 wt. % gallium and optionally other specific elements in a base including at least one element from the group of iron, cobalt and nickel. In the alloy the gallium replaces aluminum and/or silicon. The alloy is deposited especially as a protective layer on a superalloy substrate and optionally coated with a gas-permeable ceramic layer.
    Type: Grant
    Filed: February 17, 1998
    Date of Patent: August 17, 1999
    Assignee: Siemens Aktiengesellschaft
    Inventor: Norbert Czech
  • Patent number: 5902700
    Abstract: A hydrogen storage alloy electrode for use in electrochemical hydrogen storage cells, the electrode being in the form of a negative electrode fabricated by sintering a mixture of a hydrogen storage alloy containing manganese and an alloy containing a measured amount of manganese.
    Type: Grant
    Filed: January 21, 1998
    Date of Patent: May 11, 1999
    Assignee: Sanyo Electric Co., Ltd.
    Inventors: Takamichi Hirosawa, Takaaki Ikemachi
  • Patent number: 5900334
    Abstract: The present invention provides a hydrogen occluding alloy exhibiting high hydrogen absorption and desorption rates, and excellent initial activation in practical use, and a method of making it. There is provided a hydrogen occluding alloy having a composition comprising, by wt %, 32 to 38% of rare earth elements essentially consisting of La and/or Ce, 0.5 to 3.5% of Al, 0.5 to 10% of Mn, 0.005 to 0.5% of hydrogen, optionally 0.1 to 17% of Co, and the balance being Ni and unavoidable impurities; wherein the alloy has a microstructure characterized in that fine rare earth element hydride is dispersively distributed in a matrix having a CaCu.sub.5 -type crystal structure in a ratio of 0.5 to 20% by area. There are also provided electrodes and batteries containing such alloys, and methods of making and using such electrodes and batteries.
    Type: Grant
    Filed: May 7, 1997
    Date of Patent: May 4, 1999
    Assignee: Mitsubishi Materials Corporation
    Inventors: Masahiro Wada, Yoshio Takizawa
  • Patent number: 5900558
    Abstract: A container packed with a mixture of powders classified respectively into two or at least three particle-size distribution groups which are different in average particle size, the powders comprising a hydrogen absorbing alloy singly or the combination of such an alloy and a substance not absorbing hydrogen. The mixture is at least 0.03 to not greater than 0.50 in the ratio d.sub.2 /d.sub.1 wherein d.sub.1 is the average particle size of the powder having the particle-size distribution of the largest average particle size, and d.sub.2 is the average particle size of the powder having the particle-size distribution of the second largest average particle size. The weight ratio of the powder to the total weight of the powders is greater when that powder has a particle-size distribution of larger average particle size.
    Type: Grant
    Filed: July 28, 1997
    Date of Patent: May 4, 1999
    Assignee: Sanyo Electric Co., Ltd.
    Inventors: Hiroshi Nakamura, Shin Fujitani, Yumiko Nakamura, Hiroshi Watanabe, Ikuo Yonezu, Takahiro Yonesaki, Kouichi Nishimura
  • Patent number: 5830415
    Abstract: The present invention provides a car exhaust purifying filter member which is high in the capacity to collect solid and liquid contents in exhausts and which has such high heat resistance as to be capable of withstanding heat when burned for cleaning and a method of manufacturing the same. A three-dimensional mesh-like metallic porous member made from Ni--Cr--Al and having a three-dimensional framework is heated at 800-1000 .degree. C. in the atmosphere to form on its surface a densely grown fibrous alumina crystal. This member is used as a filter member. Such a filter member shows excellent collecting capacity and corrosion resistance and can withstand high temperatures. Also, it is possible to firmly carry a catalyst on the fibrous alumina crystal formed on the surface. Because of its increased surface area, it has an increased catalyst carrying capacity.
    Type: Grant
    Filed: February 21, 1995
    Date of Patent: November 3, 1998
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventors: Takao Maeda, Masayuki Ishii, Hiroshi Yoshino, Shunsuke Ban
  • Patent number: 5725693
    Abstract: A filler metal alloy used as a filler for welding east nickel aluminide alloys contains from about 15 to about 17 wt. % chromium, from about 4 to about 5 wt. % aluminum, equal to or less than about 1.5 wt. % molybdenum, from about 1 to about 4.5 wt. % zirconium, equal to or less than about 0.01 wt. % yttrium, equal to or less than about 0.01 wt. % boron and the balance nickel. The filler metal alloy is made by melting and casting techniques such as are melting the components of the filler metal alloy and east in copper chill molds.
    Type: Grant
    Filed: March 6, 1996
    Date of Patent: March 10, 1998
    Assignee: Lockheed Martin Energy Systems, Inc.
    Inventors: Michael L. Santella, Vinod K. Sikka
  • Patent number: 5680896
    Abstract: A method for producing rare earth metal-nickel hydrogen occlusive alloy ingot that contains 90 vol % or more of crystals having a crystal grain size of 1 to 50 .mu.m as measured along a short axis of the crystal and 1 to 100 .mu.m as measured along a long axis of the crystal. The method for producing the rare earth metal-nickel hydrogen occlusive alloy ingot involves melting a rare earth metal-nickel alloy and uniformly solidifying the alloy melt to have a thickness of 0.1 to 20 mm under cooling conditions of a cooling rate of 10.degree. to 1000.degree. C./sec and a sub-cooling degree of 10.degree. to 500.degree. C.
    Type: Grant
    Filed: April 6, 1995
    Date of Patent: October 28, 1997
    Assignee: Santoku Metal Industry Co., Ltd.
    Inventors: Kazuhiko Yamamoto, Yuichi Miyake, Chikara Okada, Nobuyuki Kitazume
  • Patent number: 5660649
    Abstract: Single crystal superalloy castings are described which have excellent oxidation resistance. The oxidation resistance is due to the presence of small but effective amounts of magnesium in the casting. Single crystal castings containing magnesium in the range of 5-200 parts per million, by weight, are described.
    Type: Grant
    Filed: March 18, 1996
    Date of Patent: August 26, 1997
    Assignee: United Technologies Corporation
    Inventors: Norman S. Bornstein, Stephen Chin, David N. Duhl, Donald R. Parille, Dilip M. Shah
  • Patent number: 5628814
    Abstract: A nickel-base superalloy article has a coating having a composition, in weight percent, of from about 10 to about 20 percent cobalt, from about 14 to about 25 percent chromium, from about 2 to about 12 percent aluminum, from 0 to about 0.2 percent yttrium, from about 0.001 to about 3 percent boron, from about 1 to about 10 percent silicon, balance nickel and incidental impurities. The coating is preferably applied by mixing together two powders, one with a higher solidus temperature and one with a lower solidus temperature, whose net composition is that of the coating. The powder mixture is compacted with a binder, applied to a surface of the article, and heated to a temperature above the lower solidus temperature.
    Type: Grant
    Filed: November 22, 1995
    Date of Patent: May 13, 1997
    Assignee: General Electric Company
    Inventors: Jim D. Reeves, David E. Budinger, Robert A. Anderson
  • Patent number: 5603891
    Abstract: The invention relates to a heat resistant hot formable austenitic nickel alloy consisting of (in % by weight)______________________________________ carbon 0.05 to 0.15 silicon 2.5 to 3.0 manganese 0.2 to 0.5 phosphorus max 0.015 sulphur max 0.005 chromium 25 to 30 iron 20 to 27 aluminium 0.05 to 0.15 calcium 0.001 to 0.005 rare earths 0.05 to 0.15 nitrogen 0.05 to 0.20 ______________________________________residue nickel and the usual impurities due to melting.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: February 18, 1997
    Assignee: Krupp VDM GmbH
    Inventor: Ulrich Brill
  • Patent number: 5540789
    Abstract: Single crystal superalloy castings are described which have excellent oxidation resistance. The oxidation resistance is due to the presence of small but effective amounts of magnesium in the casting. Single crystal castings containing magnesium in the range of 5-200 parts per million, by weight, are described.
    Type: Grant
    Filed: February 15, 1995
    Date of Patent: July 30, 1996
    Assignee: United Technologies Corporation
    Inventors: Norman S. Bornstein, Stephen Chin, David N. Duhl, Donald R. Parille, Dilip M. Shah
  • Patent number: 5529642
    Abstract: A nickel-based alloy which is excellent not only in anti-corrosion properties but also in workability is disclosed. The alloy contains 15 to 35 weight % of chromium; 6 to 24 weight % of molybdenum; wherein the sum of chromium plus molybdenum is no greater than 43 weight %; 1.1 to 8 weight % of tantalum; and balance nickel and unavoidable impurities. The alloy may optionally include no greater than 0.1 weight % of nitrogen; no greater than 0.3 weight % of magnesium, no greater than 3 weight % of manganese, no greater than 0.3 weight % of silicon, no greater than 0.1 weight % of carbon, no greater than 6 weight % of iron, no greater than 0.1 weight % of zirconium, no greater than 0.01 weight % of calcium, no greater than 1 weight % of niobium, no greater than 4 weight % of tungsten, no greater than 4 weight % of copper, no greater than 0.8 weight % of titanium, no greater than 0.8 weight % of aluminum, no greater than 5 weight % of cobalt, no greater than 0.
    Type: Grant
    Filed: September 19, 1994
    Date of Patent: June 25, 1996
    Assignee: Mitsubishi Materials Corporation
    Inventors: Katsuo Sugahara, Hideo Kitamura, Saburo Wakita, Koji Toyokura, Yoshio Takizawa, Tsutomu Takahashi
  • Patent number: 5516381
    Abstract: A rotating blade or stationary vane of a gas turbine which is made of a nickel alloy containing Cr, Co, Mo, W, Ta, Al, Ti, C, B, Zr, and one or both of Mg and Ca. Additionally, the alloy may contain Hf, Pt, Rh and Re.
    Type: Grant
    Filed: January 25, 1995
    Date of Patent: May 14, 1996
    Assignees: Mitsubishi Materials Corporation, Mitsubishi Jukogyo Kabushiki Kaisha
    Inventors: Hisataka Kawai, Ikuo Okada, Ichiro Tsuji, Koji Takahashi, Kensho Sahira, Akira Mitsuhashi
  • Patent number: 5501917
    Abstract: Improved multicomponent alloys for hydrogen storage and rechargeable hydride electrode applications, and in particular for rechargeable hydride battery applications, according to the formula: A.sub.a B.sub.b Ni.sub.c D.sub.y M.sub.x R.sub.z, and the hydride thereof, where A is at least one element selected from the group consisting of Ti, Zr, Hf, Y, V, Nb, Pd, Mg, Be, and Ca; B is at least one element selected from the group consisting of Mg, Al, V, Wb, Ta, Cr, Mn, Si, C, B, and Mo; D is at least one element selected from the group consisting of W, Fe, Co, Cu, Zn, Ag, Sb and Sn; M is at least one element selected from the group consisting of Li, Na, K, Rb, Cs, P, S, Sr, and Ba; R is at least one element selected from the group consisting of Sc, Y, La, Ce, Pr, and Yb; and where a, b, c, x, y and z are defined by: 0.10.ltoreq.a.ltoreq.0.85, 0.02.ltoreq.b.ltoreq.0.85, 0.02.ltoreq.c.ltoreq.0.85, 0.01.ltoreq.x.ltoreq.0.30, 0.ltoreq.y.ltoreq.0.25, 0.ltoreq.z.ltoreq.0.12 and a+b+c+x+y=1.00.
    Type: Grant
    Filed: January 28, 1994
    Date of Patent: March 26, 1996
    Inventor: Kuochih Hong
  • Patent number: 5455120
    Abstract: A nickel base superalloy capable of being made into a single crystal article is provided with high temperature strength and improved stability by limiting the presence of an undesirable SRZ constituent. Significant to the control of formation of such undesirable constituents is the control of the amount of Re in the alloy in combination with elements such as Al, Cr, Ta, Mo, Co and W. A solution heat treatment is provided for additional control.
    Type: Grant
    Filed: July 29, 1993
    Date of Patent: October 3, 1995
    Assignee: General Electric Company
    Inventors: William S. Walston, Earl W. Ross, Tresa M. Pollock, Kevin S. O'Hara, Wendy H. Murphy
  • Patent number: 5455119
    Abstract: A coating composition comprising an alloy having the formula RCrAlR'R" wherein R is nickel, cobalt or the like; R' is yttrium or hafnium and R" is tantalum, rhenium and/or platinum, preferably mixed with an oxide dispersion such as alumina, to provide an improved class of coatings suitable for operating in high temperature oxidizing environments.
    Type: Grant
    Filed: November 8, 1993
    Date of Patent: October 3, 1995
    Assignees: Praxair S.T. Technology, Inc., Rolls-Royce PLC
    Inventors: Thomas A. Taylor, David F. Bettridge, Robert C. Tucker, Jr.
  • Patent number: 5449490
    Abstract: The improved superalloy that possesses all the characteristics required of the high-temperature structural material of high-temperature gas-cooled reactors (i.e., high-temperature strength, corrosion resistance, good producibility, good hot workability and resistance to embrittlement due to thermal aging) consists essentially of 16-28% Cr, 15-24% W (provided that Cr+W=39-44%), 0.01-0.1% Zr, 0.001-0.015% Y, 0.0005-0.01% B, up to 0.05% C, up to 0.1% Si, up to 0.1% Mn (provided that Si+Mn.ltoreq.0.1%), up to 0.1% Ti, up to 0.1% Al and up to 0.1% Nb (provided that Ti+Al.ltoreq.0.1% and Ti+Al+Nb.ltoreq.0.15%), with the balance being Ni and inevitable impurities and all percentages being on a weight basis.
    Type: Grant
    Filed: September 6, 1994
    Date of Patent: September 12, 1995
    Assignee: Japan Atomic Energy Research Institute
    Inventors: Tatsuo Kondo, Hajime Nakajima, Masami Shindo, Hirokazu Tsuji, Ryohei Tanaka, Susumi Isobe, Sadao Ohta, Watanabe Rikizo
  • Patent number: 5443789
    Abstract: An improved nickel-based single crystal superalloy has both an extremely low sulphur content and a very low lanthanum, cerium, or lanthanum plus yttrium, or cerium plus yttrium, or content, whereby the amount while very low, is sufficient to react with the remaining available sulphur in the alloy and with sulphur from the fuel used in engine operation, such that the very thin, protective scale layer of aluminum oxide formed on the surfaces of the nickel-based alloy parts exposed to the very high temperatures incident in high efficiency turbine engines, will afford effective, long-life protection for the surfaces of these engine components, through the virtual elimination of spalling of the aluminum oxide scale during cyclic engine operations.
    Type: Grant
    Filed: November 18, 1992
    Date of Patent: August 22, 1995
    Assignee: Cannon-Muskegon Corporation
    Inventors: Kenneth Harris, John M. Eridon, Steven L. Sikkenga
  • Patent number: 5435861
    Abstract: A nickel-based monocrystalline superalloy suitable for turbine engine blades is obtained by adding to the alloy at least one element chosen from erbium and silicon, at a concentration by weight of 50 to 500 ppm for Er and of 500 to 1000 ppm for Si and, optionally, hafnium at a concentration by weight of 500 to 1000 ppm.
    Type: Grant
    Filed: August 6, 1993
    Date of Patent: July 25, 1995
    Assignee: Office National d'Etudes et de Recherches Aerospatiales
    Inventors: Tasadduq Khan, Pierre Caron
  • Patent number: 5431750
    Abstract: The improved nickel-base heat-resistant alloy consists of 13.1-15.0% Cr (all percentages that follows are by weight), 8.5-10.5% Co, 1.0-3.5% Mo, 3.5-4.5% W, 3.0-5.5% Ta, 3.5-4.5% Al, 2.2-3.2% Ti, 0.06-0.12% C, 0.005-0.025% B, 0.010-0.05% Zr and 1-100 ppm of Mg and/or Ca, in the optional presence of 0-1.5% Hf and/or 0-0.5% of at least one element of Pt, Rh and Re, with the remainder being Ni and incidental impurities. The alloy has high strength and high resistance to oxidation and corrosion at elevated temperatures and, hence, is suitable for use as a constituent material for machine parts that are to be exposed to elevated temperatures.
    Type: Grant
    Filed: June 19, 1992
    Date of Patent: July 11, 1995
    Assignees: Mitsubishi Materials Corporation, Mitsubishi Jukogyo Kabushiki Kaisha
    Inventors: Hisataka Kawai, Ikuo Okada, Ichiro Tsuji, Koji Takahashi, Kensho Sahira, Akira Mitsuhashi
  • Patent number: 5417918
    Abstract: The invention relates to an austenitic nickel-chromium-molybdenum alloy having high resistance to general corrosion, crevice, pitting and stress crack corrosion and also intercrystalline corrosion, consisting of (in % by weight):carbon: up to 0.01%silicon: up to 0.05%manganese: up to 0.50%phosphorus: up to 0.020%sulphur: up to 0.010%chromium: 14.0 to 18.0%molybdenum: 14.0 to 18.0%cobalt: up to 2.0%tungsten: up to 0.5%calcium 0.001 to 0.010%magnesium: 0.001 to 0.020%aluminium: 0.05 to 0.30%nitrogen: up to 0.02%iron: up to 3.0%copper: up to 0.5%titanium: up to 0.01%residue nickel and usual impurities due to melting, the sum of the contents (carbon+silicon+titanium) being limited to 0.05% at the most, and the sum of the elements (calcium+magnesium+aluminium) being adjusted within the limits 0.055 to 0.33%.
    Type: Grant
    Filed: February 2, 1993
    Date of Patent: May 23, 1995
    Assignee: Krupp VDM GmbH
    Inventors: Michael Kohler, Ulrich Heubner
  • Patent number: 5395584
    Abstract: Nickel-base superalloy composition for the repair, coating or rebuilding of the surface of a superalloy substrate, such as a single crystal nickel-base superalloy, to impart thereto surface areas having improved high temperature properties such as hot corrosion resistance. The present compositions are applied by low heat-input welding processes, such as laser welding or plasma arc welding, and are formulated to provide hot corrosion resistance properties and yet to have good weldability properties. The composition contains, by weight percentages, 2-12.5 Cr, 6-17 Cr, 0.5-7 Mo, 0.5-4 Ta, 2.5-9.5 Al, 1-4 Re, 1.5-8.5 W, 0.01-2.5 Nb, 0.5-6 Ti, 0.01-0.7 Yt, 0.02-3.5 Hf, and balance Ni.
    Type: Grant
    Filed: June 17, 1992
    Date of Patent: March 7, 1995
    Assignee: Avco Corporation
    Inventors: Charles Berger, Michael Iovene
  • Patent number: 5366695
    Abstract: This invention relates to a nickel-based superalloy comprising the following elements in percent by weight: from about 5.0 to about 7.0 percent rhenium, from about 1.8 to about 4.0 percent chromium, from about 1.5 to about 9.0 percent cobalt, from about 7.0 to about 10.0 percent tantalum, from about 3.5 to about 7.5 percent tungsten, from about 5.0 to about 7.0 percent aluminum, from about 0.1 to about 1.2 percent titanium, from about 0 to about 0.5 percent columbium, from about 0.25 to about 2.0 percent molybdenum, from about 0 to about 0.15 percent hafnium, and the balance nickel+incidental impurities, the superalloy having a phasial stability number N.sub.v3B less than about 2.10.
    Type: Grant
    Filed: June 29, 1992
    Date of Patent: November 22, 1994
    Assignee: Cannon-Muskegon Corporation
    Inventor: Gary L. Erickson
  • Patent number: 5330710
    Abstract: A nickel-base alloy for a glass-contacting member used in an unenergized state and having a composition comprising by weight 25 to 40% of chromium, 10 to 45% of cobalt, optionally 0.1 to 3.0% of titanium and optionally 0.01 to 0.05% of at least one element selected from among rare earth metals with the balance consisting of nickel and unavoidable impurities.
    Type: Grant
    Filed: March 6, 1992
    Date of Patent: July 19, 1994
    Assignee: Doryokuro Kakunenryo Kaihatsu Jigyodan
    Inventors: Toshio Masaki, Noriaki Sasaki, Shin-ichiro Torata, Hiroshi Igarashi, Tetsuya Shimizu, Tomohito Iikubo
  • Patent number: 5316866
    Abstract: A superalloy component includes a substrate article of a superalloy, and a strengthenable, adherent coating on the substrate. The coating is preferably a nickel-base superalloy that is strengthened by the formation of gamma and gamma-prime phases. The coating is stronger than conventional MCrAlX coatings, and, therefore, more resistant to thermal fatigue. One operable coating has a composition, in weight percent, of about 7.5 percent cobalt, about 9 percent chromium, about 6 percent aluminum, about 1 percent titanium, about 1.5 percent molybdenum, about 4 percent tantalum, about 3 percent tungsten, about 3 percent rhenium, about 0.5 percent hafnium, about 0.3 percent yttrium, about 0.5 percent columbium, about 0.05 percent carbon, about 0.015 percent boron, about 0.015 percent zirconium, and balance nickel.
    Type: Grant
    Filed: September 9, 1991
    Date of Patent: May 31, 1994
    Assignee: General Electric Company
    Inventors: Edward H. Goldman, Ramgopal Darolia
  • Patent number: 5273712
    Abstract: A method of protecting and a protective coating for metal components formed of nickel or cobalt-based superalloys are disclosed. The protective coating essentially consists of the following constituents (in percent by weight):1 to 20% rhenium,15 to 50% chromium,0 to 15% aluminum, the share of chromium and aluminum taken together being at least 25% and at most 53%,0.3 to 2% in total of at least one reactive element from the group consisting of the rare earths, and0 to 3% silicon, impurities, as well as the following elective components:0 to 5% hafnium,0 to 12% tungsten,0 to 10% manganese,0 to 15% tantalum,0 to 5% titanium,0 to 4% niobium, and0 to 2% zirconium,the total share of the elective components being from 0 to a maximum of 15%, and a remainder primarily being at least one of the elements iron, nickel, and cobalt. The protective coating is primarily suited for use with metal components in gas turbines and aircraft engines.
    Type: Grant
    Filed: February 26, 1992
    Date of Patent: December 28, 1993
    Assignee: Siemens Aktiengesellschaft
    Inventors: Norbert Czech, Friedhelm Schmitz
  • Patent number: 5270123
    Abstract: A nickel base superalloy capable of being made into a single crystal article is provided with high temperature strength and improved stability by limiting the Presence of an undesirable SRZ constituent. Significant to the control of formation of such undesirable constituents is the control of the amount of Re in the alloy in combination with elements such as Al, Cr, Ta, Mo, Co and W. A solution heat treatment is provided for additional control.
    Type: Grant
    Filed: March 5, 1992
    Date of Patent: December 14, 1993
    Assignee: General Electric Company
    Inventors: William S. Walston, Earl W. Ross, Kevin S. O'Hara, Tresa M. Pollock
  • Patent number: 5242656
    Abstract: This invention relates to an active material of hydrogen storage alloy electrode. The composition of the active material has a formula: Mm Ni.sub.5-x-y-z-u A.sub.x B.sub.y C.sub.z D.sub.u ; wherein Mm is mischmetal; A=Mn, Sn, or V; B=Cr, Co, Ti, Nb, Zr, or Si; C=Al, Mg, or Ca; D=Li, Na, or K; 0.ltoreq..times..ltoreq.0.95; 0.ltoreq. y.ltoreq. 1; 0.ltoreq. z.ltoreq. 0.7; and 0.1.ltoreq. u.ltoreq. 0.9. Alternatively, the composition may be of the formula: Ti.sub.2 Ni.sub.1-u Du; wherein D=Li, Na, or K; and 0.04.ltoreq. u.ltoreq. 0.9. This active material can relieve the alkali metal ions M.sup.+ continuously in charge-discharge process of the alkali batteries, increase the concentration of MOH within the battery, take effect in protecting the cathode and the anode validly, and improve the cycle life and the discharge capacity of the battery.
    Type: Grant
    Filed: April 2, 1992
    Date of Patent: September 7, 1993
    Inventors: Yunshi Zhang, Deying Song, Youxiao Chen, Jun Chen, Genshi Wang, Huatang Yuan, Zuoxiang Zhou, Xuejun Cao, Taoshi Zang, Daxin Zhang
  • Patent number: 5217684
    Abstract: A precipitation-hardening-type Ni-base alloy exhibiting improved resistance to stress corrosion cracking in a sour gas atmosphere containing elemental sulfur at high temperatures is disclosed. The alloy consists essentially of, by weight %;______________________________________ Cr: 12-25%, Mo: over 9.0 and up to 15%, Nb: 4.0-6.0%, Fe: 5.0-25%, Ni: 45-60%, C: 0.050% or less, Si: 0.50% or less, Mn: 1.0% or less, P: 0.025% or less, S: 0.0050% or less, N: 0.050% or less, Ti: 0.46-1.0%, Al: 0-2.0%.
    Type: Grant
    Filed: November 30, 1990
    Date of Patent: June 8, 1993
    Assignee: Sumitomo Metal Industries, Ltd.
    Inventors: Masaaki Igarashi, Shiro Mukai, Yasutaka Okada, Akio Ikeda
  • Patent number: 5194222
    Abstract: An alloy exhibiting corrosion resistance in a combustion environment where V, Na, S and Cl are present comprises, in weight percent, not more than 0.05% C, 0.02-0.5% Si, 0.02-0.5% Mn, 15-35% Cr, 0.5-4% Mo, 10-40% Co, 5-15% Fe, 0.5-5% W, 0.0003-0.005% Ca and the remainder of Ni at a content of not less than 4% and unavoidable impurities, provided that Cr (%)+0.5Ni (%)+3Mo (%).gtoreq.30 (%) and Ni (%)+0.5Co (%).gtoreq.Cr (%)+Mo (%)+W (%). A composite steel tube exhibiting corrosion resistance in a combustion environment where V, Na, S and Cl are present comprises an inner tube constituted of Cr-containing boiler tube and an outer tube constituted of the alloy.
    Type: Grant
    Filed: December 20, 1991
    Date of Patent: March 16, 1993
    Assignee: Nippon Steel Corporation
    Inventors: Hiroyuki Ogawa, Tetsuo Ishitsuka, Kozo Denpo, Akihiro Miyasaka, Michihisa Ito, Mizuo Sakakibara
  • Patent number: 5154885
    Abstract: A protective coating for metal components formed of nickel or cobalt-based superalloys essentially consists of the following constituents (in percentages by weight):1 to 20% rhenium,22 to 50% chromium,0 to 15% aluminum, the share of chromium and aluminum taken together being at least 25% and at most 53%,0.3 to 2% in total of at least one reactive element from the group consisting of the rare earths, and0 to 3% silicon,impurities, as well as the following elective components:0 to 5% hafnium,0 to 12% tungsten,0 to 10% manganese,0 to 15% tantalum,0 to 5% titanium,0 to 4% niobium, and0 to 2% zirconium,the total share of the elective components being from 0 to a maximum of 15%, and a remainder primarily being at least one of the elements iron, nickel, and cobalt.
    Type: Grant
    Filed: August 10, 1990
    Date of Patent: October 13, 1992
    Assignee: Siemens Aktiengesellschaft
    Inventors: Norbert Czech, Friedhelm Schmitz
  • Patent number: 5151249
    Abstract: A nickel-based superalloy consisting essentially of, in weight percent, from about 4 to about 5 percent chromium, from about 11 to about 14 percent cobalt, from about 4 to about 8 percent tungsten, from about 6 to about 10 percent tantalum, from about 5 to about 7 percent aluminum, from about 5.5 to about 8 percent rhenium, from about 0 to about 0.50 percent hafnium, from about 0 to about 0.07 percent carbon, from 0 to about 0.01 percent boron, from 0 to about 0.030 percent yttrium, from 0 to about 6 percent ruthenium, from 0 to about 1 percent molybdenum, from 0 to about 1 percent niobium, and the balance essentially nickel. Articles made from the superalloy of the invention are especially useful when cast as single crystal airfoils for use in advanced gas turbine engines.
    Type: Grant
    Filed: December 29, 1989
    Date of Patent: September 29, 1992
    Assignee: General Electric Company
    Inventors: Curtiss M. Austin, Ramgopal Darolia, Kevin S. O'Hara, Earl W. Ross
  • Patent number: 5141704
    Abstract: The improved superalloy that possesses all the characteristics required of the high-temperature structural material of high-temperature gas-cooled reactors (i.e., high-temperature strength, corrosion resistance, good productibility, good hot workability and resistance to embrittlement due to thermal aging) consists essentially of 16-28% Cr. 15-24% W (provided that Cr+W=39-44%), 0.01-0.1% Zr, 0.001-0.015% Y, 0.0005-0.01% B, up to 0.05% C, up to 0.1% Si, up to 0.1% Mn (provided that Si+Mn.gtoreq.0.1%), up to 0.1% Ti, up to 0.1% Al and up to 0.1% Nb (provided that Ti+Al.gtoreq.0.1% and Ti+Al+Nb.gtoreq.0.15%), with the balance being Ni and inevitable impurities and all percentages being on a weight basis.
    Type: Grant
    Filed: July 26, 1991
    Date of Patent: August 25, 1992
    Assignee: Japan Atomic Energy Res. Institute
    Inventors: Tatsuo Kondo, Hajime Nakajima, Masami Shindo, Hirokazu Tsuji, Ryohei Tanaka, Susumu Isobe, Sadao Ohta, Rikizo Watanabe
  • Patent number: 5129968
    Abstract: The present invention provides an alloy having improved crack growth inhibition and having high strength at high temperatures. The composition of the alloy is essentially as follows:______________________________________ Ingredient Concentration in Weight % ______________________________________ Ni balance Co 15 Cr 10 Mo 3 Al 4.9 Ti 2.0 Ta 4.7 Nb 2.3 Zr 0.06 V 1 C 0.05 B 0.
    Type: Grant
    Filed: September 28, 1988
    Date of Patent: July 14, 1992
    Assignee: General Electric Company
    Inventor: Michael F. Henry