Abstract: A reactor for catalytic gas reactions such as synthesis of methanol or ammonia comprises at least one cylindrical catalyst bed having a height not greater than half its over-all diameter and defined on its underside by a grid supported by a dished plate having peripheral mechanical connection to a downward extension of the bed wall. Preferably there are several such beds and an indirect heat exchanger upsteam of the downstream-most bed. The reactor is suitably 5-10 m in diameter and is especially for use at under 120 bar abs in an integrated process for producing methanol and ammonia.

Abstract: Control of the synthesis loop pressure of an ammonia plant is accomplished by automatically changing the purge rate of the recycle gas to maintain optimum synthesis loop pressure. The control logic of this invention allows compressor speed to be set at a constant value and suction pressure to the first stage of the synthesis loop compressor to be maintained by changing the purge rate of the recycle gas. This allows the synthesis loop pressure to seek the highest possible value at the given feed rates of the synthesis gas and compressor speed assuring optimum compressor loading.If the feed rate of synthesis gas is low, additional control is achieved by using the synthesis loop pressure signal or the concentration of inerts signal to vary the compressor speed.

Abstract: The present invention is directed to an improved synthesis process and system for the production of ammonia. More specifically, the present invention involves the use of a split axial flow converter in the low pressure synthesis of ammonia.

Abstract: A chemical plant, wherein gaseous reactants are converted in an exothermic chemical reaction to a reaction product, is combined with a semi-closed Brayton-cycle power plant to utilize the heat of reaction to generate power. Specifically, in one embodiment, an ammonia synthesis plant, wherein gaseous nitrogen and hydrogen are catalytically converted to ammonia, is combined with a semi-closed Brayton-cycle power plant to utilize the heat of reaction of the ammonia synthesis reaction to generate power.

Abstract: Control of the temperature of an ammonia synthesis reactor is accomplished so as to reduce temperature oscillations throughout the reactor. This allows the ammonia synthesis reactor to be operated close to the lowest stable operating temperature which results in optimal reactor performance. The temperature of the effluent flowing from the ammonia synthesis reactor is monitored to detect the presence of thermal waves. The temperature of the effluent flowing from the synthesis reactor is utilized to generate a correction term which is utilized in temperature control for the ammonia synthesis reactor to stabilize the operation of the ammonia synthesis reactor.

Abstract: To reduce the consumption of electricity, a portion of the deuterium-enriched water is stored during the winter while the remainder is used to produce hydrogen in the heavy water preparation plant. The stored deuterium-enriched water is then used in the summer with fresh water to produce hydrogen in the electrolyzer for delivery to the ammonia synthesizing plant. Surplus hydrogen is stored during the summer for subsequent use in the synthesizing plant during the next winter.

Abstract: An apparatus for reducing hydrocarbon fuel requirements for Haber Ammonia Synthesis by the supply of selected gases to the second reformer of such system, comprising a first cylindrical conduit, a second smaller coaxial cylinder inside of the first conduit, forming a first annular space therebetween, the downstream end of said second conduit closed, and a plurality of circumferentially-spaced orifices in the wall of said conduit upstream of the closed end. Means to supply air at selected pressure P1, temperature and flow rate to the first annular space, means to supply at least methane at a pressure P2 greater than P1, to said second conduit, so that the concentration of methane in the air will be less than the lower explosive limit, and means to shield the jets of gas from the orifices in the second conduit, as they flow radially outwardly across the annular space.

Abstract: A radial ammonia converter system including first and second heat interchangers and first, second and third catalyst beds. The synthesis gas is heated in said first and second interchangers by catalyst bed effluent prior to full flow through each of the catalyst beds. In one embodiment, two of the catalyst beds are mounted with the first and second interchangers in one vessel; and in another embodiment, the first interchanger and second catalyst bed are mounted in one vessel and the second interchanger and first catalyst bed are mounted in a separate vessel. In both embodiments, the radial ammonia converter system is completed by a third catalyst bed in a separate vessel.

Abstract: A method which improves the combustion efficiency of fuel in the internal combustion engine is disclosed. The method is substantially characterized in that a small amount of ammonia gas is incorporated into the hydrocarbon fuel in any position between an air intake port and an intake manifold of the engine. Due to the above addition of ammonia, the combustion of the hydro-carbon fuel in the combustion chamber is enhanced with the improved composition of the discharged gas.

Abstract: An ammonia production process comprising synthesis gas generation and ammonia synthesis with heat recovery in the generation section by steam raising and steam superheating and heat recovery in the synthesis section by steam raising or boiler feed water heating is made more controllable by effecting part of the superheating in the synthesis section, so that a shut-down of the synthesis section results not only in a decrease in steam flow through the superheaters, but also in a decrease in the temperature of the steam fed to them. Thus overheating of the superheaters, a defect of some earlier processes, is avoided. The process is operated with a synthesis pressure under 150, preferably 40-80 bar abs. and preferably synthesis gas generation is based on primary hydrocarbon steam reforming at such a pressure that synthesis gas compression is by under 50%.

Abstract: A catalytic reactor for catalyzed exothermic reactions is disclosed having at least one catalyst layer, characterized in that each individual layer is arranged between two coaxial cylindrical shells, at least two inlets for the reacting gases to the catalyst being provided in one of said shells and at least two outlets in the other shell. The inlets are provided in the external cylindrical shell, and the outlets are provided in the internal cylindrical shell. The inlets and outlets consist of a plurality of openings made in said cylindrical shells and aligned on circumferences that are intersections of the cylindrical shells with equidistant planes perpendicular to the axis of said cylindrical shells.

Abstract: In a reactor suitable for gas-phase catalytic exothermic synthesis, in particular of ammonia or methanol the synthesis gas is reacted in an upstream adiabatic catalytic zone, is cooled in a heat exchanger and then reacted further in a downstream catalytic zone, whereafter preferably it is cooled again, suitably in a boiler or feed water heater, and reacted further in a further catalytic zone. The gas flow through the catalyst is mainly in an axial direction and the pressure drop is kept low by disposing the catalyst in each zone in a plurality of beds fed in parallel from an inlet header and delivered in parallel into an outlet header. The beds may be separately removable from the reactor to facilitate catalyst charging and discharging.

Abstract: An improved air injector for use in feed preparation in the primary reformer of a HABER processor for ammonia synthesis. In the HABER process, process gas is introduced at relatively high velocity downwardly in a process reactor through a vertical conduit. Along the axis of the conduit is an air supply pipe with a fixture which produces a plurality of downwardly and radially outwardly directed pipes attached to a plenum on the bottom of the air pipe. In this invention the number of circumferentially spaced pipes is doubled over the prior art and they are spaced circumferentially into rows directed outwardly at about a 45.degree. angle so as to present, more or less, a continuous plurality of streams of air which block the annular space and force the downflowing process gas to be turbulently mixed with the air and to form a pressurized mass of process gas and air, which is then forced, by the gas pressure, to flow downwardly in, more or less, a uniform manner through a volume of catalyst.

Abstract: An improved synthesis loop for the production of ammonia has a low pressure, i.e. less than 100 atmospheres, a water absorption recovery system which utilizes low level heat recovered from the process for producing the synthesis gas to distill the ammonia-water mixture and an ammonia absorption refrigeration system which utilizes the same distillation column for both the water absorption system and the refrigeration system.

Abstract: An improved synthesis loop for the production of ammonia, has a low pressure, i.e., less than 100 atmospheres, a water absorption recovery system which utilizes low level heat recovered from the process for producing the synthesis gas to distill the ammonia-water mixture and an ammonia absorption refrigeration system which utilizes the same distillation column for both the water absorption system and the refrigeration system.