Plural Chemical Reaction Stages Patents (Class 422/170)
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Patent number: 12006580Abstract: Processes and apparatus for electrocatalytically converting carbon dioxide emissions and/or ambient carbon dioxide into useful chemicals are described. The process may include: removing carbon dioxide from ambient air through a carbon capture technique, supplying a carbonate or bicarbonate aqueous solution as cathode feed to a cathode of an electrolytic cell comprising a membrane electrode assembly which includes a bipolar membrane separating an anode from the cathode, and applying an electrical potential difference between the cathode and the anode of the membrane electrode assembly to electrocatalytically reduce the carbonate or bicarbonate aqueous solution to carbon monoxide or another useful chemical.Type: GrantFiled: April 25, 2019Date of Patent: June 11, 2024Assignee: THE UNIVERSITY OF BRITISH COLUMBIAInventors: Curtis Berlinguette, Danielle Salvatore, Tengfei Li, Maxwell Goldman, Eric Lees
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Patent number: 11873269Abstract: A methanol production system of the present disclosure includes: a reformer including a reaction furnace configured to reform methane in a raw material gas to produce a reformed gas containing CO and H2; a reduced-gas generator configured to reduce CO2 to produce a reduced gas containing CO; and a methanol-containing gas generator configured to produce a methanol-containing gas which contains methanol from a reformed gas produced in the reaction furnace and a reduced gas produced in the reduced-gas generator.Type: GrantFiled: November 30, 2021Date of Patent: January 16, 2024Assignee: MITSUBISHI HEAVY INDUSTRIES, LTD.Inventors: Shoichi Furukawa, Hidehiko Tajima
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Patent number: 11517854Abstract: The present invention relates to a diesel oxidation catalyst comprising a substrate and a wash-coat comprising a first layer and a second layer, wherein the substrate has a substrate length, a front end and a rear end, the washcoat comprising the first layer comprising a first metal oxide and comprising a platinum group metal supported on a metal oxide support material; the second layer comprising a second metal oxide and comprising one or more of an oxidic compound of vanadium, an oxidic compound of tungsten and a zeolitic material comprising one or more of Fe and Cu; wherein the first layer is at least partially disposed directly on the substrate, or is at least partially disposed directly on an intermediate layer which is disposed directly on the substrate over the entire length of the substrate, on x % of the length of the substrate from the front end of the substrate, and wherein the second layer is at least partially disposed directly on the substrate, or is at least partially disposed directly on the iType: GrantFiled: February 13, 2018Date of Patent: December 6, 2022Assignee: BASF CorporationInventors: Robert Dorner, Martin Kalwei
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Patent number: 11519669Abstract: A condenser and semiconductor processing machine, relating to the art of semiconductor equipment. The condenser 100 includes a sealed cavity; wherein, a gas passage is provided in the sealed cavity; cooling liquid is filled around the gas passage; a gas inlet, a gas outlet, and a liquid outlet are provided on the sealed cavity, the gas inlet is communicated with the inlet of the gas passage, the gas outlet is communicated with the outlet of the gas passage, and the liquid outlet is communicated with the gas passage; the gas passage is a Tesla valve structure passage.Type: GrantFiled: June 30, 2021Date of Patent: December 6, 2022Assignee: CHANGXIN MEMORY TECHNOLOGIES, INC.Inventor: Tianlong Li
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Patent number: 11185819Abstract: Catalyzed particulate filters comprise three-way conversion (TWC) catalytic material, which comprises rhodium as the only platinum group metal, that permeates walls of a particulate filter. Such catalyzed particulate filters may be located downstream of close-coupled three-way conversion (TWC) composites in an emission treatment system downstream of a gasoline direct injection engine for treatment of an exhaust stream comprising hydrocarbons, carbon monoxide, nitrogen oxides, and particulates.Type: GrantFiled: July 25, 2017Date of Patent: November 30, 2021Assignee: BASF CorporationInventors: Janosch Cravillon, Stephan Siemund, Attilio Siani, Thomas Schmitz, Markus Kinne
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Patent number: 11173435Abstract: An in situ system of filter rejuvenation has a fluid inlet on a first side of a reaction chamber, a fluid outlet disposed on a second side of the reaction chamber, a filtration chamber with a first wall comprising a ceramic glass material with a pass-band in the infrared spectrum. The filtration chamber is in fluid communication with the fluid inlet and the fluid outlet so that a fluid introduced into the inlet passes through the filtration chamber and exits through the fluid outlet. The system has at least one infrared heating element configured to transmit infrared energy within the pass-band of the ceramic glass material to heat the filter medium disposed within the filtration chamber to a temperature of at least 260° C., which can gasify contaminants without combustion.Type: GrantFiled: April 16, 2021Date of Patent: November 16, 2021Inventor: James W. Masten, Jr.
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Patent number: 11045755Abstract: An in situ system of filter rejuvenation can be applied to a mechanical filter passing fluid contaminated by chemical and particulate materials such that the filter removes the contaminants from the flow by trapping the contaminants in a filter medium. A non-combustive infrared heating system gasifies the trapped contaminants without combustion and without emissions to the atmosphere, restoring the efficacy of the filtration medium.Type: GrantFiled: August 26, 2020Date of Patent: June 29, 2021Inventor: James W. Masten, Jr.
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Patent number: 11000805Abstract: The present invention solves the existing problem of using very expensive oxidation reagents, such as H2O2 and ozone, in removal of NOx and SOx from flue gases, by performing simultaneous oxidation of NOx and SOx with atmospheric oxygen in a combined system for catalytic oxidation and wet-scrubbing of both NOx and SOx from a flue gas and manufacturing fertilisers. Two major configurations of the oxidation system are disclosed in the present invention. The first configuration operates on oxygen-enriched air to increase efficiency of the oxidation reaction and requires an additional oxygen concentrator unit. The second configuration operates on atmospheric air at ambient conditions and requires an additional catalyst activation unit. In the second configuration, the efficient oxidation process is carried out at low temperatures of about 30-90° C. in the presence of recovered and re-activated catalyst.Type: GrantFiled: May 27, 2020Date of Patent: May 11, 2021Assignee: ARIEL SCIENTIFIC INNOVATIONS LTD.Inventors: Gad A. Pinhasi, Tomer Zidki, Haim Cohen
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Patent number: 10995643Abstract: A mixer assembly comprises a tubular housing including a reductant inlet, an exhaust gas inlet and an exhaust gas outlet. The tubular housing defines a longitudinal axis along which exhaust enters the housing. The reductant inlet is positioned on a first side of the tubular housing. An upstream element covers approximately one-half of the cross sectional area of the enhaust gas inlet and is positioned upstream of the reductant inlet. An upstream surface of the upstream mixing element directs exhaust gas flow transversly toward the reductant inlet. A downstream mixing element along with the upstream mixing element at least partially defines a reductant receiving duct in which injected reductant and exhaust gas mix.Type: GrantFiled: March 19, 2019Date of Patent: May 4, 2021Inventors: Sascha Haverkamp, Joachim Gehrlein, Stefan Kohrs, Eric A. Hein, Attila Kovacs
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Patent number: 10954186Abstract: The invention relates to a process for the production of urea ammonium nitrate, a system and a method of modifying a plant. The process comprises subjecting ammonia-containing off-gas resulting from the production of ammonium nitrate (AN off-gas) to condensation under acidic conditions so as to form an acidic condensate, and using at least part of the acidic condensate as an acidic scrubbing liquid in a finishing treatment section having a gas inlet in fluid communication with a gas outlet of a finishing section of a urea production unit, wherein the finishing section is adapted to solidify urea liquid, and wherein said finishing treatment section is adapted to subject ammonia-containing off-gas of the finishing section to treatment with an acidic scrubbing liquid.Type: GrantFiled: May 28, 2019Date of Patent: March 23, 2021Assignee: Stamicarbon B.V.Inventors: Giusy Elisa Puci, Joey Dobree
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Patent number: 10677160Abstract: Systems and methods are provided for combined cycle power generation while reducing or mitigating emissions during power generation. Recycled exhaust gas from a power generation combustion reaction can be separated using a swing adsorption process so as to generate a high purity CO2 stream while reducing/minimizing the energy required for the separation and without having to reduce the temperature of the exhaust gas. This can allow for improved energy recovery while also generating high purity streams of carbon dioxide and nitrogen.Type: GrantFiled: September 23, 2016Date of Patent: June 9, 2020Assignee: ExxonMobil Research and Engineering CompanyInventors: Narasimhan Sundaram, Ramesh Gupta, Hans Thomann, Hugo S. Caram, Loren K. Starcher, Franklin F. Mittricker, Simon C. Weston, Scott J. Weigel
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Patent number: 10662843Abstract: Exhaust after-treatment systems and methods are disclosed. An example system includes a selective catalytic reduction on filter (SCRF) and a selective catalytic reduction (SCR) catalyst positioned downstream of the SCRF. The system also includes a first reductant doser positioned upstream of the SCRF and a second reductant doser positioned downstream of the SCRF and upstream of the SCR catalyst. The system further includes first and second nitrogen oxide (NOx) sensors positioned upstream of the first reductant doser, a third NOx sensor positioned downstream of the SCRF and upstream of the second reductant doser, and a catalyst positioned upstream of the first reductant doser.Type: GrantFiled: July 18, 2014Date of Patent: May 26, 2020Assignee: Cummins Emission Solutions, Inc.Inventor: Behnam Bahrami
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Patent number: 10415448Abstract: An exhaust gas cleaning system for an internal combustion engine is provided with, in an exhaust passage of an internal combustion engine and in order from an upstream side: a hydrocarbon supply unit; an upstream side catalyst unit of an oxidation catalyst, a NOx reduction catalyst, or the like; and a catalyst-equipped fine particle collection filter having a hydrocarbon adsorption function, wherein when a vehicle on which the engine is mounted accelerates after driving for a preset set time period at a temperature of exhaust gas equal to or less than a preset set exhaust gas temperature, the supply of hydrocarbon into the exhaust gas is started when an exhaust gas temperature becomes equal to or more than a preset first set temperature, and the supply of hydrocarbon is terminated when a preset termination condition is satisfied.Type: GrantFiled: June 4, 2015Date of Patent: September 17, 2019Assignee: ISUZU MOTORS LIMITEDInventors: Daiji Nagaoka, Masashi Gabe
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Patent number: 10364722Abstract: A method for regulating an exhaust-gas aftertreatment device for an internal combustion engine, wherein respectively one loading state of a first SCR component and of a second SCR component arranged downstream of the first SCR component is determined. The loading state of the second SCR component is regulated by way of a dosing system for dosing a reducing agent.Type: GrantFiled: October 18, 2017Date of Patent: July 30, 2019Assignee: FEV EUROPE GMBHInventors: Sebastian Petri, Eric Brueckner, Ibrahim Can Ozyalcin
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Patent number: 10119445Abstract: An exhaust system for treating an exhaust gas from an internal combustion engine is disclosed. The system comprises a modified lean NOx trap (LNT), a urea injection system, and an ammonia-selective catalytic reduction (NH3-SCR) catalyst. The modified LNT comprises platinum, palladium, barium, and a ceria-containing material, and has a platinum:palladium molar ratio of at least 3:1. The modified LNT stores NOx at temperatures below about 200° C. and releases the stored NOx at temperatures above about 200° C. The urea injection system injects urea at temperatures above about 180° C.Type: GrantFiled: September 16, 2014Date of Patent: November 6, 2018Assignee: Johnson Matthey Public Limited CompanyInventor: Daniel Swallow
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Patent number: 10105692Abstract: A catalytic article for treating an exhaust gas stream containing one or more of NOx, hydrocarbons, CO, SOx and ammonia from a combustion turbine comprises (a) a substrate having an inlet end and an outlet end defining an axial length; (b) an oxidation layer comprising an oxidation catalyst comprising one or more noble metals, the oxidation layer being positioned on the substrate and covering the axial length of the substrate; and (c) an SCR layer comprising an SCR catalyst, the SCR layer being positioned on the oxidation layer and overlapping a portion of the oxidation layer, wherein the portion is less than 100%.Type: GrantFiled: September 29, 2016Date of Patent: October 23, 2018Assignee: Johnson Matthey Public Limited CompanyInventors: Paul Joseph Andersen, Kevin Doura
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Patent number: 10022666Abstract: The present invention is an apparatus and method having dynamically reconfigurable air flow paths for supporting polishing and non-polishing operations. The invention includes a first baghouse section and a second baghouse section coupled to the first baghouse section via conduit. A set of valves is disposed along the conduit to direct air flow through the baghouse apparatus. A controller configures the baghouse apparatus by actuating at least one valve in the set of valves. The controller automatically configures the baghouse apparatus in either a polishing operation or a non-polishing operation based on a predetermined criteria.Type: GrantFiled: February 6, 2015Date of Patent: July 17, 2018Assignee: GCC of America, Inc.Inventors: Steven Douglas Roark, Gina Nance
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Patent number: 9771844Abstract: A low emissions 2-stroke natural gas fueled engine includes at least one cylinder with an exhaust port in communication with a silencer-catalytic converter unit. The unit has first and second volumes in communication with each other. The first volume damps spurious exhaust pressure excursions and removes particulates in the exhaust. The second volume houses an oxidation catalyst for treating exhaust to reduce exhaust emissions. The engine oil has at most 10 ppm zinc content to reduce metal poisons contained in the exhaust prior to contact with the oxidation catalyst. The engine oil preferably has a very low ash content to minimize sulfur combustion components in the exhaust to reduce masking of the oxidation catalyst. The first volume preferably has a pressure relief valve set to relieve at a pressure greater than the maximum normal operating pressure of the engine to avoid excessive pressure excursions of the engine exhaust from damaging the oxidation catalyst.Type: GrantFiled: February 10, 2014Date of Patent: September 26, 2017Assignee: GE Oil & Gas Compression Systems, LLCInventors: Bruce M. Chrisman, Thomas J. Hurley
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Patent number: 9731246Abstract: In an exhaust gas purification apparatus provided in an exhaust as path of an engine, it is an object of the present invention to shorten a pipe length of a bypass path bypassing a purification catalyst as short as possible, thereby reducing initial costs. The exhaust gas purification apparatus includes a purification casing in which at least the purification catalyst is accommodated. The purification catalyst purifies exhaust gas from the engine. The purification casing is integrally provided with the bypass path separately from the purification path in which the purification catalyst exists. The bypass path makes the exhaust gas bypasses the purification catalyst without passing through the purification catalyst.Type: GrantFiled: October 3, 2013Date of Patent: August 15, 2017Assignee: Yanmar Co., Ltd.Inventors: Tetsuya Yokoyama, Tsuyoshi Inoue
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Patent number: 9719386Abstract: An exhaust after-treatment system including at least one exhaust treatment component (18); and a particulate matter dispersion device (40) located upstream of the exhaust treatment component (18). The particulate matter dispersion device (40) includes at least one nozzle line (61) having a plurality of nozzles (58) formed therein, and the particulate matter dispersion device (40) is operable to inject compressed gas towards the exhaust treatment component (18) to substantially minimize build-up of particulate matter at the exhaust treatment component (18).Type: GrantFiled: January 31, 2013Date of Patent: August 1, 2017Assignee: Tenneco Automotive Operating Company Inc.Inventors: Gaofeng Fan, Biao Du, Lin Wang, Jianqiang Fan, Anzhou Wu, Jian Wu, Michael Golin
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Patent number: 9700841Abstract: Synergized PGM catalyst converters configured as three-way catalyst (TWC) systems are disclosed. The disclosed SPGM system configurations exhibit high thermal stability, attenuated air to fuel (A/F) perturbations, enhanced TWC activity, and high catalytic conversion efficiency as a result of synergizing a low PGM loading close-coupled catalyst (CCC), with Ce-based oxygen storage, with a front spinel zone of suitable mixed metal oxide compositions acting as pre-catalyst for oxygen storage. The attenuation of A/F perturbations to lower amplitude, before exhaust gas emissions go into the standard PGM CCC, allows the system to work within a range of R values very close to the stoichiometric point for both lean and rich conditions, and high catalytic conversion efficiency in NOX, CO, and HC conversions. The disclosed SPGM system configurations can be utilized in a plurality of TWC applications, such as conventional TWC systems including an optional underfloor catalyst.Type: GrantFiled: March 13, 2015Date of Patent: July 11, 2017Assignee: BYD Company LimitedInventor: Stephen J. Golden
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Patent number: 9702269Abstract: A device for capture of acid gas of combustion fumes of a thermal power plant, including: absorption means (10) of the gas by capture fluid, a regenerator (1) where the capture fluid and a regeneration fluid steam are put in contact, introduction means (11) of the regeneration fluid in the regenerator, condensation means (2, 3, 4), at the head of said regenerator, separation means (6) of liquid phase of the regeneration fluid and gaseous phase rich in acid gas, Wherein: the regeneration fluid steam introduced is superheated, the regenerator (1) includes means limiting the contact time to substantially maintain the flow rate of regeneration fluid steam, the condensation means (2, 3, 4) are in thermal exchange with first evaporation means of working fluid, and first reintroduction means (13) of steam obtained in a turbine (14).Type: GrantFiled: July 22, 2014Date of Patent: July 11, 2017Assignee: ELECTRICITE DE FRANCEInventor: Yann Le Moullec
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Patent number: 9677447Abstract: An aftertreatment module is disclosed for use with an engine. The aftertreatment module may have an inlet housing at least partially defining an inlet passage for exhaust, and at least one mixer disposed in the inlet passage. The aftertreatment module may also have an outlet housing at least partially defining an outlet passage for exhaust, and a catalyst housing removably connected between the inlet housing and the outlet housing. The aftertreatment module may further have a plurality of catalyst substrates configured to be mounted in the catalyst housing, to receive exhaust from the inlet passage in parallel, and to discharge exhaust to the outlet housing in parallel.Type: GrantFiled: December 5, 2014Date of Patent: June 13, 2017Assignee: Caterpillar Inc.Inventors: Raymond Upano Isada, Kurtis Edward Chenoweth, Eric Spaeth, Ping Xiang, Yung T. Bui
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Patent number: 9630144Abstract: Implementations disclosed herein provide a dry chemical scrubber with a pH regulator that adjusts an internal pH value of the dry chemical scrubber by adding high pH elements to the contents of the dry chemical scrubber on a continuous or periodic basis.Type: GrantFiled: June 18, 2014Date of Patent: April 25, 2017Assignee: MTARRI/VARANI EMISSIONS TREATMENT, LLCInventors: John Jenkins, Frederick T. Varani, Thomas A. Jones, Paul Bertram Trost, Aaron F. Primmer, Nathan A. Emsick
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Patent number: 9381462Abstract: A system for reducing emissions includes a gas production source that produces nitrogen oxides, sulfur oxides, hydrogen sulfide, sulfuric acid, nitric acid, formaldehyde, benzene, metal oxides, or volatile organic compound emissions. An exhaust plenum is downstream from the gas production source, and structure for dispersing a solvent is in the exhaust plenum. A collection tank is in fluid communication with the exhaust plenum to receive the solvent from the exhaust plenum, and a heat source is in the exhaust plenum downstream from the structure for dispersing the solvent. A method for reducing emissions from a gas production source includes flowing exhaust gases through an exhaust plenum, dispersing a solvent through a nozzle in the exhaust plenum, collecting the dispersed solvent in a collection tank, and heating the exhaust gases flowing through the exhaust plenum downstream from the nozzle.Type: GrantFiled: July 1, 2013Date of Patent: July 5, 2016Assignee: General Electric CompanyInventors: Robert Thomas Thatcher, Gilbert Otto Kraemer, Andrew Mitchell Rodwell, Brett Matthew Thompson
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Patent number: 9364790Abstract: An exhaust treatment component including a mixing assembly located within a housing. The mixing assembly includes a decomposition tube having a first end and a second end, the first end being configured to receive the exhaust from the inlet and being configured to receive a reagent exhaust treatment fluid; a flow reversing device disposed proximate the second end, the flow reversing device configured to direct a mixture of the exhaust and reagent exhaust treatment fluid as the mixture exits the second end of the decomposition tube in a direction back toward the first end, the flow reversing device including a plurality of deflecting members for swirling and intermixing the exhaust and reagent exhaust treatment fluid; and a swirl arrester device configured to eliminate the swirling of the exhaust and reagent exhaust treatment fluid after exiting the flow reversing device.Type: GrantFiled: September 15, 2014Date of Patent: June 14, 2016Assignee: Tenneco Automotive Operating Company Inc.Inventors: Manoj Sampath, Omkar Champhekar
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Patent number: 9352276Abstract: A swirl device for intermixing a reagent exhaust treatment fluid and an exhaust produced by an engine. The swirl device includes a cylindrical tube defining an inlet for receipt of the reagent exhaust treatment fluid and the exhaust, and a swirl member attached to the cylindrical tube. The swirl member conically expands outward from the cylindrical tube and includes a plurality of tabs separated by elongate slots. The plurality of tabs are configured to swirl and intermingle the reagent exhaust treatment fluid and the exhaust.Type: GrantFiled: September 15, 2014Date of Patent: May 31, 2016Assignee: Tenneco Automotive Operating Company Inc.Inventor: Manoj Sampath
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Patent number: 9334781Abstract: An exhaust treatment component for treating an exhaust produced by an engine. The exhaust treatment component includes a housing, a first exhaust treatment component substrate positioned within the housing, and a dosing module for dosing a reagent exhaust treatment fluid into the exhaust. The dosing module is secured to the housing and positioned upstream of the first exhaust treatment component substrate. An ultrasonic transducer is positioned between the dosing module and the first exhaust treatment component substrate. The ultrasonic transducer is configured to emit a plurality of ultrasonic waves into the exhaust including the reagent exhaust treatment fluid.Type: GrantFiled: September 15, 2014Date of Patent: May 10, 2016Assignee: Tenneco Automotive Operating Company Inc.Inventors: John Stanavich, William Adams, Daniel Alexander, Michael Golin
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Patent number: 9295943Abstract: A filter system and method for capturing and treating HAPs and VOCs. The system has one or more dual pass filters. Each pass filter has a media bed with a plurality of VOC digesting microbes. Fluid from a holding tank containing additional microbes may be used to regenerate the media beds by transferring the fluid from the holding tank to the dual pass filter. Any one of the dual pass filters may be isolated from the flow of HAPs for regeneration of the media bed. Any one of the dual pass filters may also be isolated from fluid communication with the holding tank while in service in capturing HAPs and/or VOCs. The filter system being contained in a highly mobile enclosure.Type: GrantFiled: July 18, 2013Date of Patent: March 29, 2016Assignee: AMERICAN ENVIRONMENTAL FABRICATION & SUPPLY LLCInventors: Scott Manes, Randy Glad
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Patent number: 9040005Abstract: The present invention relates to a method for removal of SO2 from exhaust gas from a marine engine or a marine boiler of a ship. The exhaust gas from said marine engine or marine boiler is cooled and washed with seawater in a first scrubber section, and subsequently, in a second scrubber section, washed with circulating freshwater with an addition of an alkaline chemical. The circulating freshwater used for washing is warmer than the seawater used for cooling in the first scrubber section. The warmer freshwater is indirectly heat exchanged with cold seawater. The exhaust gas washed in the first scrubber section is passed via a demister unit before it is washed with circulating freshwater in the second scrubber section. The invention further relates to a corresponding scrubber system.Type: GrantFiled: September 12, 2012Date of Patent: May 26, 2015Assignee: ALFA LAVAL CORPORATE ABInventor: Jens Peter Hansen
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Publication number: 20150139882Abstract: An integrated sorbent injection, heat recovery, and flue gas desulfurization system is disclosed. A dry sorbent is injected into the flue gas upstream of the air heater. This reduces the acid dew point temperature, permitting additional heat energy to be captured when the flue gas passes through the air heater. The flue gas then passes through a desulfurization unit and through a baghouse, where solids are captured. The capture of additional heat energy permits the overall boiler efficiency to be increased while safely operating at a lower flue gas temperature. The integrated system consumes no greater quantity of sorbent than conventional methods but provides the benefit of improved plant heat rate.Type: ApplicationFiled: July 21, 2014Publication date: May 21, 2015Inventors: Eric M. WARREN, Jeb W. GAYHEART, Anthony A. SILVA
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Patent number: 9034267Abstract: In an internal combustion engine, inside of an engine exhaust passage, a hydrocarbon feed valve (15) and an exhaust purification catalyst (13) are arranged. The exhaust purification catalyst (13) is comprised of a mixture of a first catalyst in which platinum (51) and a basic layer (52) are carried on alumina (50) and a second catalyst in which rhodium (56) is carried on zirconia (55). The concentration of hydrocarbons which flow into the exhaust purification catalyst (13) is made to vibrate by within a predetermined range of amplitude of a 200 ppm or more and within a predetermined range of period of 5 second or less, whereby the NOx which is contained in exhaust gas is reduced at the exhaust purification catalyst (13).Type: GrantFiled: October 4, 2010Date of Patent: May 19, 2015Assignee: Toyota Jidosha Kabushiki KaishaInventors: Masao Watanabe, Koutarou Hayashi, Kohei Yoshida, Yuki Bisaiji, Kazuhiro Umemoto
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Patent number: 9034269Abstract: The present invention relates to a diesel oxidation catalyst comprising a carrier substrate, and a first washcoat layer disposed on the substrate, the first washcoat layer comprising palladium supported on a support material comprising a metal oxide, gold supported on a support material comprising a metal oxide, and a ceria comprising compound, as well as a process for the preparation of such catalyst.Type: GrantFiled: November 27, 2013Date of Patent: May 19, 2015Assignee: BASF SEInventors: Marcus Hilgendorff, Alfred H. Punke, Torsten W. Müller-Stach, Gerd Grubert, Torsten Neubauer, Jeffrey B. Hoke
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Patent number: 9028761Abstract: In an internal combustion engine, inside of an engine exhaust passage, a hydrocarbon feed valve (15) and an exhaust purification catalyst (13) are arranged. The exhaust purification catalyst (13) is comprised of an upstream-side catalyst (14a) and a downstream-side catalyst (14b) arranged in series at an interval from each other. The upstream-side catalyst (14b) has a smaller cross-sectional area than the downstream-side catalyst (14b). The concentration of hydrocarbons which flow into the upstream-side catalyst (14a) is made to vibrate by within a predetermined range of amplitude of a 200 ppm or more and within a predetermined range of period of 5 seconds or less, whereby the NOx which is contained in exhaust gas is reduced at the exhaust purification catalyst (13).Type: GrantFiled: December 24, 2010Date of Patent: May 12, 2015Assignee: Toyota Jidosha Kabushiki KaishaInventors: Kazuhiro Umemoto, Kohei Yoshida, Mikio Inoue
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Publication number: 20150125353Abstract: An air pollution control apparatus includes: a denitration unit that removes nitrogen oxides from a flue gas; a desulfurization unit that is installed on a gas flow downstream side of the denitration unit to remove the sulfur oxides in a flue gas 11B; a finish denitration and desulfurization unit that is installed on the gas flow downstream side of the desulfurization unit to perform finish denitration and desulfurization of NO2 and SO2; and a carbon dioxide recovery unit that is installed on the gas flow downstream side of the finish denitration and desulfurization unit to remove and recover the carbon dioxide in a flue gas.Type: ApplicationFiled: May 17, 2013Publication date: May 7, 2015Applicant: MITSUBISHI HEAVY INDUSTRIES, LTD.Inventors: Tsuyoshi Oishi, Hiroshi Tanaka, Naohiko Ukawa
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Publication number: 20150113966Abstract: Systems, apparatus and methods are disclosed for reducing the amount of nitrous oxide (N2O) produced in a selective catalytic reductant (SCR) catalyst in an exhaust aftertreatment system. The SCR catalysts are arranged to reduce the amount of N2O produced during NOx reduction while not adversely affecting NOx conversion.Type: ApplicationFiled: October 30, 2013Publication date: April 30, 2015Applicant: Cummins Inc.Inventors: Krishna Kamasamudram, Neal W. Currier, Ashok Kumar
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Patent number: 9011569Abstract: A wall flow type particulate filter (24) adapted to be arranged in an exhaust passage of an internal combustion engine in which combustion is performed in an excess of oxygen carries a solid acid. The solid acid has an acid strength which is higher than the acid strength of sulfurous acid and lower than the acid strength of sulfuric acid.Type: GrantFiled: June 29, 2012Date of Patent: April 21, 2015Assignee: Toyota Jidosha Kabushiki KaishaInventors: Hiroshi Otsuki, Shigeki Nakayama, Hiromasa Nishioka, Katsuhiko Oshikawa, Yoshihisa Tsukamoto, Junichi Matsuo, Yuichi Sobue, Daichi Imai, Kou Sugawara
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Patent number: 9011809Abstract: An ammonia oxidation catalyst being superior in heat resistance and capable of suppressing by-production of N2O or NOx. The ammonia oxidation catalyst is made by coating at least two catalyst layers having a catalyst layer (lower layer) including a catalyst supported a noble metal on an inorganic base material including any of a composite oxide (A) having at least titania and silica as main components, alumina, and a composite oxide (B) consisting of alumina and silica; and a catalyst layer (upper layer) including a composite oxide (C) consisting of at least silica, tungsten oxide, ceria and zirconia, at the surface of an integral structure-type substrate, wherein a composition of the composite oxide (C) is silica: 20% by weight or less, tungsten oxide: 1 to 50% by weight, ceria: 1 to 60% by weight, and zirconia: 30 to 90% by weight.Type: GrantFiled: February 24, 2012Date of Patent: April 21, 2015Assignee: N.E. Chemcat CorporationInventors: Tomoaki Ito, Toshinori Okajima, Takashi Hihara, Makoto Nagata
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Patent number: 9010097Abstract: In an internal combustion engine, inside of an engine exhaust passage, a hydrocarbon feed valve (16), an exhaust purification catalyst (13), a particulate filter (14), and an NO2 reduction catalyst (15) are arranged. At the time of engine operation, the amplitude of change of the concentration of hydrocarbons which flow into the exhaust purification catalyst (13) is made to become within a predetermined range of amplitude by control of the injection amount of hydrocarbons from the hydrocarbon feed valve (16). When the NO2 which is produced at the particulate filter (14) should be reduced to NO, the injection amount of hydrocarbons is increased whereby the pass through amount of hydrocarbons which pass straight through the exhaust purification catalyst (13) is increased.Type: GrantFiled: March 17, 2011Date of Patent: April 21, 2015Assignee: Toyota Jidosha Kabushiki KaishaInventors: Mikio Inoue, Kohei Yoshida, Yuki Bisaiji, Kazuhiro Umemoto, Masahide Iida
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Patent number: 9011568Abstract: A filter for internal combustion engines, includes a rigid external casing provided with at least an inlet for a fluid to be filtered and an outlet for the fluid when filtered, and a filter cartridge located internally of the external casing, which includes a plurality of tubular filter walls arranged parallel to one another which are destined to be crossed by the fluid flowing from the inlet towards the outlet of the external casing; the external casing being conformed such as to delimit a pouch a transversal section of which, performed along a perpendicular plane to axes of the tubular filter walls, exhibits a prevalent line of development and a small width with respect to the prevalent line of development; the tubular filter walls being arranged internally of the pouch, side by side with one another, forming a single row which follows the prevalent line of development of the pouch.Type: GrantFiled: August 4, 2010Date of Patent: April 21, 2015Assignee: UFI Innovation Center S.R.L.Inventor: Giorgio Girondi
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Patent number: 8999048Abstract: An exhaust gas purifying apparatus for a diesel engine includes a diesel particulate filter (DPF) in an exhaust system in the diesel engine. The exhaust gas purifying apparatus is constructed to execute regeneration of the DPF by raising a temperature of the DPF in a case where a predetermined DPF regeneration condition is fulfilled, interrupt the regeneration of the DPF, execute idling stop, automatically restart the diesel engine and then restart the regeneration of the DPF, and when shifting to the idling operation is carried out during regeneration of the DPF, delay execution of the idling stop until a temperature of the DPF at a time at which the idling stop is started becomes not less than a temperature of the DPF at a time at which shifting to an idling operation is carried out even in a case where the predetermined idling stop condition is fulfilled.Type: GrantFiled: May 20, 2011Date of Patent: April 7, 2015Assignee: Nissan Motor Co., Ltd.Inventors: Toru Nishizawa, Risa Yamamoto
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Patent number: 8999047Abstract: A system for removing Hg contained in flue gas from a boiler, the system includes: a heat exchanger for performing heat exchange of the flue gas from the boiler; a precipitator for removing soot and dust in the flue gas; a wet desulfurization device for removing mercury oxide Hg2+ in the flue gas using an alkali absorbent; and; a removal assistant supply unit for supplying a removal assistant for removing impurities into a limestone and gypsum slurry that circulates through the wet desulfurization device.Type: GrantFiled: October 15, 2010Date of Patent: April 7, 2015Assignee: Mitsubishi Hitachi Power Systems, Ltd.Inventors: Nobuyuki Ukai, Seiji Kagawa, Tatsuto Nagayasu, Takuya Okamoto
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Patent number: 8992652Abstract: A filtering device features a ceramic filter body for filtering a fluid flow, the filter body consisting of a wavy layer and a flat layer and the wavy and flat layer being wound in a spiral-shaped manner. The wave length of the waves increases from the inside to the outside with increasing distance to the longitudinal axis of the filter body such that the wave troughs and the wave peaks of at least two radially adjacent windings each lie on a common radial plane.Type: GrantFiled: December 17, 2012Date of Patent: March 31, 2015Assignee: Mann+Hummel GmbHInventors: Arndt-Udo Rolle, Frank Ehlen, Kathrin Lichtenwalter, Jochen Linhart, Nadine Dietsch
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Patent number: 8992651Abstract: [Problem] To provide a filter whose initial collection efficiency can be increased and whose pressure loss increase can be suppressed. [Means to solve the problem] A ceramic filter includes: numerous crystalline masses bound to one another each formed of aggregation of columnar crystals, wherein a number of large diameter pores are present between the numerous crystalline masses, and small diameter pores are present between the numerous columnar crystals forming the crystalline mass.Type: GrantFiled: March 28, 2012Date of Patent: March 31, 2015Assignee: Kubota CorporationInventors: Atsushi Sugai, Hiroshi Yamaguchi
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Patent number: 8992842Abstract: A system for producing ammonia includes sources of hydrogen and nitrogen gas, a hydrogen gas booster for producing produce pressurized hydrogen gas, a nitrogen gas booster for producing pressurized nitrogen gas, and a synthesis reactor that receives a mixture of the pressurized hydrogen and nitrogen gases. The synthesis reactor includes an inlet for receiving the pressurized gas mixture, a heating zone adjacent the inlet for heating the gas mixture, a catalyst zone downstream from the heating zone for catalyzing a reaction of the mixture to form ammonia and a by-product, and a cooling zone downstream from the catalyst zone for cooling the ammonia and the by-product. The system has a separator for separating the ammonia from the by-product, an ammonia storage tank for collecting the ammonia, and a recycle loop for re-circulating the by-product back to the synthesis reactor.Type: GrantFiled: September 10, 2012Date of Patent: March 31, 2015Inventor: Roger Gordon
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Publication number: 20150086457Abstract: A system for treating mercury in flue gas is provided. The system includes a mercury adsorbent supply device to adsorb the mercury with the mercury adsorbent; a precipitator to collect the mercury adsorbent with adsorbed mercury and soot in the flue gas; a mercury adsorption assistant supply device to remove mercury remaining in the flue gas; and a desulfurization device to remove sulfur oxide (SOx) in the flue gas.Type: ApplicationFiled: May 31, 2012Publication date: March 26, 2015Applicant: MITSUBISHI HITACHI POWER SYSTEMS, LTD.Inventors: Seiji Kagawa, Hideaki Sakurai, Nobuyuki Ukai, Susumu Okino, Tatsuto Nagayasu
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Patent number: 8984863Abstract: Provided is an ammonia injection device (10) installed at an exhaust gas duct through which an exhaust gas generated in a gas turbine flows, and configured to inject ammonia into the exhaust gas at an upstream side of a denitration catalyst configured to perform denitration processing in a flowing direction of the exhaust gas, the device including a plurality of ammonia injection pipes (11) disposed in parallel each other in a surface which traverses the exhaust gas duct. A plurality of nozzle pipes (12) configured to eject the ammonia from the ammonia injection pipes in an arrangement direction of the plurality of ammonia injection pipes are installed at the ammonia injection pipe in a longitudinal direction of the ammonia injection pipes. Diffuser panels (13) extending toward a downstream side in a flowing direction of the exhaust gas at both sides in a longitudinal direction of the ammonia injection pipes with respect to the nozzle pipes are formed at the nozzle pipes.Type: GrantFiled: November 1, 2011Date of Patent: March 24, 2015Assignee: IHI CorporationInventors: Akinori Yukimura, Masafumi Kawai, Yoshiyuki Yamane
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Patent number: 8978363Abstract: A diesel particulate filter (“DPF”) system that is more convenient than a conventional DPF system, including a DPF having a catalyzed soot filter (“CSF”) that is connected to an exhaust pipe of a diesel engine in order to collect particulate matter (“PM”) in exhaust gas, and a diesel oxidation catalyst (“DOC”) provided on an upstream side of the CSF; and temperature sensors provided respectively on an upstream side and a downstream side of the DOC. When a PM accumulation amount in the CSF exceeds a fixed amount, DPF regeneration is performed by setting a temperature detected by the upstream side temperature sensor at or above a first threshold and setting a temperature detected by the downstream side temperature sensor at or above a second threshold. When a breakdown is detected in the upstream side temperature sensor, the second threshold is modified upward.Type: GrantFiled: June 10, 2011Date of Patent: March 17, 2015Assignee: Isuzu Motors LimitedInventors: Takashi Ikeda, Naofumi Ochi, Hitoshi Satou
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Patent number: 8974563Abstract: An exhaust gas purification system includes a diesel particulate filter (“DPF”) which collects particulate matter (“PM”) in exhaust gas, an exhaust pipe injector which performs exhaust pipe injection, and a DPF regeneration control unit which performs temperature rise control of an exhaust gas temperature by the exhaust pipe injection to regenerate the DPF when the PM collected by the DPF exceeds a fixed amount and which, during the regeneration, integrates an amount of time during which the exhaust gas temperature exceeds a PM combustion temperature and completes the regeneration when an integrated value thereof reaches a set regeneration completion value. The DPF regeneration control unit aborts the regeneration when, during regeneration, a total amount of the exhaust pipe injection exceeds an upper limit before the integrated value.Type: GrantFiled: June 10, 2011Date of Patent: March 10, 2015Assignee: Isuzu Motors LimitedInventors: Takashi Haseyama, Shinji Gotou, Hiroyuki Oohira
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Patent number: 8974740Abstract: An exhaust treatment component mounting system including an exhaust treatment component canister that includes a cleat ring, and an exhaust treatment component housing including a radially outwardly extending flange. A torsion rod including a first end that mates with the flange of the housing, and a second end including a coupling that mates with the cleat ring, wherein during connection between the first end and the second end of the torsion rod, the canister is rigidly secured to the housing.Type: GrantFiled: March 12, 2013Date of Patent: March 10, 2015Assignee: Tenneco Automative Operating Company Inc.Inventor: John Stanavich