Using Inorganic Silicon Or Phosphorus Compound Patents (Class 422/18)
  • Patent number: 4389371
    Abstract: Corrosion inhibited alcohol compositions can be prepared which are suitable for use as anti-freeze compositions in the cooling systems of internal combustion engines. The alcohol is selected from at least one of the group consisting of methanol, ethanol, propanol, ethylene glycol, diethylene glycol, triethylene glycol, propylene glycol and glycerol. The corrosion inhibitor comprises an effective amount of a conventional corrosion inhibitor selected from the group consisting of the alkali metal carbonates, borax, the alkali metal dichromates, the alkali metal silicates, phosphorous acid, phosphoric acid, an alkali metal tungstate, benzotriazole, tolyltriazole, an alkali metal salt of benzoic or toluic acid, an alkali metal salt of a phenol, an alkanolamine and an organo-silicone compound in addition to an alkanolamine phosphate and a heterocyclic nitrogen-containing compound. The phosphate is the reaction product of an alkanolamine and phosphoric acid.
    Type: Grant
    Filed: July 8, 1981
    Date of Patent: June 21, 1983
    Assignee: BASF Wyandotte Corporation
    Inventors: Joe C. Wilson, Stephen E. Eisenstein, Jerrold F. Maxwell, Stanley T. Hirozawa
  • Patent number: 4384979
    Abstract: The waters used for cooling generally contain hard ions of the group consisting of calcium and magnesium ions concentration of from about 10 to 600 parts per million. Such waters also contain bicarbonate ions. When cooling waters are recirculated through a cooling tower, they are saturated with oxygen and tend to be corrosive and tend to promote formation of calciferous scale. Such propensities are inhibited by the injection of appropriate chemicals so that the inhibited water contains dispersants effective in dispersing incipient calcium compounds and inhibiting calciferous scale, so that the inhibited water contains a plurality of components forming a dynamic layer on metal surfaces protecting such metal from oxidation.
    Type: Grant
    Filed: November 4, 1981
    Date of Patent: May 24, 1983
    Assignee: Atlantic Richfield Company
    Inventor: Gerald D. Hansen
  • Patent number: 4351796
    Abstract: A method of inhibiting the deposition of calcium phosphate scale from an aqueous system treated with a corrosion inhibitor formulation containing a phosphono-carboxylic acid and a polyphosphate comprises adding to the aqueous system a minor amount of hydrolyzed polymaleic anhydride having a molecular weight in the range of from 300 to 5000 as determined by calculation following osmometric measurement on the polymaleic anhydride before hydrolysis, or a water-soluble salt or a hydrolyzed copolymer of polymaleic anhydride.
    Type: Grant
    Filed: December 4, 1980
    Date of Patent: September 28, 1982
    Assignee: Ciba-Geigy Corporation
    Inventor: Alan Marshall
  • Patent number: 4333850
    Abstract: A filled insoluble polymer containing one or more corrosion inhibitors and a slightly water soluble polymer is utilized to automatically and continuously add a corrosion inhibitor to a coolant solution passing through a heat exchanger. The corrosion inhibitor is gradually leached from the filled polymer supplying inhibitor to the coolant to protect the metallic parts of the coolant system that are subject to corrosive conditions.
    Type: Grant
    Filed: June 15, 1979
    Date of Patent: June 8, 1982
    Assignee: Borg-Warner Corporation
    Inventor: Robert H. Krueger
  • Patent number: 4328180
    Abstract: The waters used for cooling generally contain hard ions of the group consisting of calcium and magnesium ions concentration of from about 10 to 600 parts per million. Such waters also contain bicarbonate ions. When cooling waters are recirculated through a cooling tower, they are saturated with oxygen and tend to be corrosive and tend to promote formation of calciferous scale. Such propensities are inhibited by the injection of appropriate chemicals so that the inhibited water contains dispersants effective in dispersing incipient calcium compounds and inhibiting calciferous scale, so that the inhibited water contains a plurality of components forming a dynamic layer on metal surfaces protecting such metal from oxidation.
    Type: Grant
    Filed: October 31, 1980
    Date of Patent: May 4, 1982
    Assignee: Atlantic Richfield Company
    Inventor: Gerald D. Hansen
  • Patent number: 4324684
    Abstract: A composition is disclosed comprising a stable aqueous solution of (i) water-soluble zinc compound, (ii) water-soluble chromate compound and (iii) a particular type of water-soluble polymer composed essentially of moieties derived from acrylic acid and hydroxylated lower alkyl acrylates. The composition could additionally comprise (iiii) orthophosphate.
    Type: Grant
    Filed: March 19, 1980
    Date of Patent: April 13, 1982
    Assignee: Betz Laboratories, Inc.
    Inventors: Gary E. Geiger, Roger C. May
  • Patent number: 4297237
    Abstract: A method of inhibiting corrosion in an aqueous system comprising treating said system with 1.0 to 300 parts per million by weight of the total aqueous content of said system, of a composition comprising polyphosphate and polymaleic anhydride or amine adducts thereof in a weight ratio of from 10:1 to 1:10.
    Type: Grant
    Filed: March 6, 1980
    Date of Patent: October 27, 1981
    Assignee: Calgon Corporation
    Inventor: Bennett P. Boffardi
  • Patent number: 4284599
    Abstract: A sterilization system preferably utilizing two baths in which articles to be sterilized are immersed into a first bath where the articles are conditioned and then into a second bath containing a sterilizing solution where they are sterilized. The ingredients for the sterilization system are stored in hermetically sealed, multicompartment pouches which are opened just prior to use to release and activate the system. The sterilization system utilizes a solution comprising 0.02 to 1% of hypochlorite, 1.4 to 20% of di(alkali metal) phosphate, 0.08% to 21% mono(alkali metal) phosphate, and 0.1 to 0.5% of nonionic surfactant with the proviso that the lower limit of di(alkali metal) phosphate is 4% when the amount of said hypochlorite is from 0.5 to 1%, said percentages being based on weight (in grams) per 100 ml. of solution. The sterilizing solution is highly efficacious while being non-corrosive and having a reduced toxicity and prolonged shelf life, and may be utilized by relatively untrained personnel.
    Type: Grant
    Filed: March 23, 1979
    Date of Patent: August 18, 1981
    Assignee: Anprosol Incorporated
    Inventors: Harold W. Andersen, Shirley R. Andersen, Clifford Zaner, Charles H. Harrison
  • Patent number: 4240925
    Abstract: This invention relates to a process of inhibiting pitting corrosion which is characterized by the use of synergistic mixtures of organic anodic and cathodic corrosion inhibitors. These synergistic mixtures effectively inhibit pitting corrosion in highly oxygenated systems without the conventional use of heavy metals such as zinc (Zn) or chromium (Cr). This invention also relates to the use of alkoxysilyl alkylene polyamines as pitting corrosion inhibitors.
    Type: Grant
    Filed: August 2, 1978
    Date of Patent: December 23, 1980
    Assignee: Petrolite Corporation
    Inventor: William S. Tait
  • Patent number: 4241014
    Abstract: A single-phase antifreeze or coolant concentrate is disclosed comprising a major proportion of at least one alcohol, at least one water-soluble silicate, and an organic basic pH buffer and corrosion inhibitor comprising at least one hydroxybenzoic acid. The concentrates can be used without dilution but are preferably used, upon dilution with water. The concentrates are generally diluted for use in with about 25 to about 90 percent by weight of water based upon the total weight of the concentrate. The alcohol is preferably ethylene glycol. The alcohol-based antifreeze and coolant compositions of the invention are effective in the protection against corrosion of all metals and alloys used in industrial processes and are especially effective when used to inhibit the corrosion of aluminum internal combustion engine and radiator components.
    Type: Grant
    Filed: October 9, 1979
    Date of Patent: December 23, 1980
    Assignee: BASF Wyandotte Corporation
    Inventors: Stanley T. Hirozawa, Edward F. O'Brien, Joe C. Wilson
  • Patent number: 4219433
    Abstract: Metal corrosion inhibitor comprising (a) benzoic acid and/or a benzoate, (b) a trialkanolamine, (c) phosphoric acid and/or a phosphate, and (d) at least one selected from mercaptobenzothiazole, its salts, benzotriazole and tolyltriazole, which can exhibit excellent anti-corrosive property to various metals for a long term and can be diluted with an aqueous liquor and can be employed in combination with usual anti-freezing agents.
    Type: Grant
    Filed: September 19, 1978
    Date of Patent: August 26, 1980
    Assignee: Otsuka Chemical Co., Ltd.
    Inventors: Isao Manabe, Akiyoshi Inubushi
  • Patent number: 4210549
    Abstract: This invention relates to single-phase antifreeze or coolant concentrates comprising a major proportion of at least one alcohol, at least one water-soluble silicate, and an organic basic pH buffer and corrosion inhibitor comprising at least one hydroxybenzoic acid. The concentrates can be used without dilution but are preferably used, upon dilution with water. The concentrates are generally diluted for use in with about 25 to about 90 percent by weight of water based upon the total weight of the concentrate. The alcohol is preferably ethylene glycol. The alcohol-based antifreeze and coolant compositions of the invention are effective in the protection against corrosion of all metals and alloys used in industrial processes and are especially effective when used to inhibit the corrosion of aluminum internal combustion engine and radiator components.
    Type: Grant
    Filed: January 2, 1979
    Date of Patent: July 1, 1980
    Assignee: BASF Wyandotte Corporation
    Inventors: Stanley T. Hirozawa, Edward F. O'Brien, Joe C. Wilson
  • Patent number: 4202796
    Abstract: Composition for prevention of ferrous corrosion consisting essentially of (a) sorbitol, (b) benzotriazole or tolyltriazole, and (c) a water-soluble phosphate.
    Type: Grant
    Filed: July 31, 1978
    Date of Patent: May 13, 1980
    Assignee: Chemed Corporation
    Inventors: Jose T. Jacob, Vincent R. Kuhn
  • Patent number: 4176059
    Abstract: A low toxicity, corrosion and scale inhibiting composition for use in recirculating aqueous systems, e.g. in heat exchangers, comprises from about 3-1,000 parts by weight of molybdate, from about 0.5-1,000 parts by weight of an organic cationic or non-ionic surfactant, from about 0.3-1,000 parts by weight of a water soluble polyphosphate and from about 0.05-500 parts by weight of an azole, for example tolyltriazole. The composition is water soluble or water dispersible, and is effective in very small amounts (3-3,500 ppm) for corrosion control of metals such as carbon steel, copper and aluminum exposed to circulating water.
    Type: Grant
    Filed: June 8, 1978
    Date of Patent: November 27, 1979
    Assignee: Quatic Chemicals Limited
    Inventor: Fumiko Suzuki
  • Patent number: 4134959
    Abstract: The invention disclosed provides a new composition and method for inhibiting corrosion. The present composition is relatively non-toxic, contains no chromates and zinc, and consists essentially of an azole and a water-soluble phosphate in an effective combination. Effective amounts of the corrosion inhibiting composition are used to provide corrosion protection in both ferrous and non-ferrous metals.
    Type: Grant
    Filed: August 19, 1977
    Date of Patent: January 16, 1979
    Assignee: Chemed Corporation
    Inventors: Russell O. Menke, Jose T. Jacob, Chih M. Hwa