And Means Upstream Of Extended Surface, Fluid Contact Means Removing Particulate Impurities From Reactant Stream Patents (Class 422/217)
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Patent number: 11452965Abstract: A device for producing and treating a gas stream is provided that includes an enclosure, of which the lower part is submerged in a liquid supply open at the top and includes at least one liquid intake opening. The submerged lower part of the enclosure contains a volume of this liquid and at least one opening for discharging a gas stream, positioned above the surface of the volume of liquid contained in the enclosure. The device further provides for injecting a gas stream including at least one injection conduit and extends in the upper part inside the enclosure outside the volume of liquid. During operation of the device an incoming gas stream is introduced to create an outgoing gas stream, treated by direct contact with said volume of liquid that is discharged outside the enclosure. A facility inclusive of the device and method of operation are also provided.Type: GrantFiled: February 22, 2021Date of Patent: September 27, 2022Assignee: STARKLABInventor: Jaouad Zemmouri
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Patent number: 10946326Abstract: A device for producing and treating a gas stream is provided that includes an enclosure, of which the lower part is submerged in a liquid supply open at the top and includes at least one liquid intake opening. The submerged lower part of the enclosure contains a volume of this liquid and at least one opening for discharging a gas stream, positioned above the surface of the volume of liquid contained in the enclosure. The device further provides for injecting a gas stream including at least one injection conduit and extends in the upper part inside the enclosure outside the volume of liquid. During operation of the device an incoming gas stream is introduced to create an outgoing gas stream, treated by direct contact with said volume of liquid that is discharged outside the enclosure. A facility inclusive of the device and method of operation are also provided.Type: GrantFiled: November 6, 2015Date of Patent: March 16, 2021Assignee: STARKLABInventor: Jaouad Zemmouri
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Patent number: 10799830Abstract: A hydrocarbon burner for an enclosed environment includes a heat exchanger having a first heat exchanger inlet connected to an inlet of the hydrocarbon burner and a first heat exchanger outlet connected to a heater, and a second heat exchanger inlet connected to a reactor outlet and a second heat exchanger outlet connected to an outlet of the hydrocarbon burner. A reactor includes a reactor inlet, the reactor outlet, and a catalyst mixture disposed in a reactor bed between the reactor inlet and the reactor outlet. The heater connects the first heat exchanger outlet to the reactor inlet. The reactor is a low temperature reactor configured to convert at least one hydrocarbon to at least one of H2O and CO2.Type: GrantFiled: January 8, 2018Date of Patent: October 13, 2020Assignee: Hamilton Sundstrand CorporationInventors: Ping Yu, Benjamin Elmer Bishop
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Patent number: 9255520Abstract: A compressed air energy storage module including an integrated thermal energy storage and recovery apparatus is provided. The compressed air energy storage module contains no moving parts and is constructed onsite, underground and out-of-sight. The compressed air energy storage module comprises a first regenerative heat exchanger including a first tank filled with a first particulate material that stores thermal energy and adsorbs air, and a second regenerative heat exchanger including a second tank filled with a second particulate material that stores thermal energy. A first end of the first tank is connected to a first end of the second tank via a first piping system. A second end of the first tank is connected to a second end of the second tank via a second piping system. The first piping system and the second piping system form a circular path for the air to circulate through the first and second regenerative heat exchangers.Type: GrantFiled: February 27, 2013Date of Patent: February 9, 2016Assignee: Energy Compression Inc.Inventor: Timothy F. Havel
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Patent number: 8802020Abstract: A reactor for preparing hydrogen cyanide by the Andrussow process is provided. The reactor comprises at least one gas inlet which opens into a gas inlet region, an outlet for the reaction products and a catalyst, wherein at least one mixing element and at least one gas-permeable intermediate layer are within the reactor between the gas inlet region and the catalyst. The mixing element is arranged between the gas inlet region and the gas-permeable intermediate layer. A process for preparing HCN, in the reactor is also provided.Type: GrantFiled: May 9, 2008Date of Patent: August 12, 2014Assignee: Evonik Röhm GmbHInventors: Thomas Schaefer, Robert Weber, Udo Gropp, Thomas Mertz
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Patent number: 8758612Abstract: Process and device for separating liquid from a multiphase mixture contained in a vessel and comprising solid particles and at least one liquid phase forming together at least one suspension, and a gas phase in which at least part of the mixture is circulated through at least one cross-flow filter located outside the vessel, therefore separating said part of the mixture into a filtered liquid and a concentrate.Type: GrantFiled: June 2, 2010Date of Patent: June 24, 2014Assignee: Solvay SAInventors: Jal Rustom Dadabhoy, Massimo Fedeli, Patrick Markus Dhaese, Yvan Frans Van Hoof
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Patent number: 8728403Abstract: The device described in the present invention can trap plugging particles contained in the liquid feed supplying a reactor functioning in gas and liquid co-current down-flow mode using a specific distributor tray comprising a filtration medium. The present device is of particular application to the selective hydrogenation of feeds containing acetylenic and dienic compounds.Type: GrantFiled: September 13, 2012Date of Patent: May 20, 2014Assignee: IFP Energies NouvellesInventors: Abdelhakim Koudil, Christophe Boyer
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Patent number: 8524164Abstract: A method for removing contaminants from an process stream that includes the use of reticulated material to filter the process stream. The reticulated material also facilitate process stream flow distribution in process units. The reticulated material can be packed with a void space between a substantial number of the reticulated material that can be varied to enhance filtration and flow distribution. The method of filtering also provides a method of removing contaminants leaving process equipment. The methods can be used on a variety of process streams and process equipment. The reticulated material can include ceramics, metallic materials, and chemical vapor deposition elements. The reticulated material can be of various shapes and sizes, and can also be catalytically active.Type: GrantFiled: August 15, 2007Date of Patent: September 3, 2013Inventor: John N. Glover
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Patent number: 8500831Abstract: A device for continuously conditioning fed-out natural gas prior to feeding the same to supply lines leading to consumers has a mixing station for producing a burnable gas from natural gas and oxygen, a reactor container for a catalytic combustion of an introduced mixture of burnable gas and natural gas, at least one drying station that is connected downstream of an outlet of the reactor container, at least one separator, particularly for water, and at least one expansion fitting for reducing the pressure. The reactor container and separator chamber of the separator are disposed in an enclosed housing. The mixing chamber, into which a first feed line for fed-out cold natural gas opens, is disposed in the housing between the reactor container and the separator chamber.Type: GrantFiled: May 12, 2009Date of Patent: August 6, 2013Assignee: EWE GASSPEICHER GmbHInventor: Andreas Lenk
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Patent number: 8487151Abstract: The device described in the present invention allows pre-distribution of the gas and liquid feed supplying a reactor functioning in gas and liquid co-current downflow mode to be carried out by means of a pre-distribution plate comprising a filtration medium and an overflow tube in order to regulate the flow of liquid arriving on the distributor plate located downstream of said device. More particularly, the present invention is applicable to the selective hydrogenation treatment of feeds containing acetylenic and dienic compounds.Type: GrantFiled: October 24, 2008Date of Patent: July 16, 2013Assignee: IFP Energies NouvellesInventors: Abdelhakim Koudil, Christophe Boyer
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Patent number: 8434505Abstract: In this disclosure, a reactor system is described. The reaction system comprises (a) a reaction vessel having an inner wall, wherein said reaction vessel is configured to receive reactants and export products and byproducts; (b) a primary quench device (PQD) configured to receive a coolant and disperse said coolant into said reaction vessel; and (c) a secondary quench device (SQD) configured to receive a coolant and disperse said coolant into said reaction vessel; wherein said PQD comprises an array of spray nozzles fixed on the inner wall of said reaction vessel at a first axial position; and wherein said SQD comprises (1) an axially movable pipe having a coolant entry end and a nozzle end, wherein said pipe is configured to be removably fixed inside said reaction vessel; and (2) a spray nozzle that is fluidly connected to said pipe at its nozzle end via a fluid tight seal connection.Type: GrantFiled: February 15, 2012Date of Patent: May 7, 2013Assignee: Synfuels International, Inc.Inventors: Duane Morrow, Joel Cantrell, Edward R. Peterson
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Patent number: 8398931Abstract: The invention provides a recirculating reactor for converting a substrate to a product. The reactor comprises a reaction chamber and a recirculation system, said recirculation system comprising a separator. The reaction chamber contains a catalyst, and comprises a chamber body, a chamber inlet and a chamber outlet. The recirculation system is adapted for recirculating liquid from the chamber outlet to the chamber inlet, and the separator is used for separating a by-product from the liquid.Type: GrantFiled: September 3, 2010Date of Patent: March 19, 2013Assignee: Agency for Science, Technology and ResearchInventors: Jackie Y. Ying, Su Seong Lee, Jaehong Lim, Siti Nurhanna binte Riduan
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Patent number: 8361406Abstract: Systems and methods for treating a fluid with a body are disclosed. Various aspects involve treating a fluid with a porous body. In select embodiments, a body comprises ash particles, and the ash particles used to form the body may be selected based on their providing one or more desired properties for a given treatment. Various bodies provide for the reaction and/or removal of a substance in a fluid, often using a porous body comprised of ash particles. Computer-operable methods for matching a source material to an application are disclosed. Certain aspects feature a porous body comprised of ash particles, the ash particles have a particle size distribution and interparticle connectivity that creates a plurality of pores having a pore size distribution and pore connectivity, and the pore size distribution and pore connectivity are such that a first fluid may substantially penetrate the pores.Type: GrantFiled: June 12, 2012Date of Patent: January 29, 2013Assignee: Errcive, Inc.Inventors: Charles E. Ramberg, Stephen A. Dynan, Jack A. Shindle
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Patent number: 8313709Abstract: A method for removing contaminants from a process stream that includes the use of reticulated material to filter the process stream in a vessel located upstream of a process unit. The reticulated material can be used with other conventional filter media within the vessel.Type: GrantFiled: May 21, 2008Date of Patent: November 20, 2012Assignee: Crystaphase International, Inc.Inventors: John N. Glover, William D. Duke, Peter G. Ham
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Patent number: 8313715Abstract: A process for producing metal oxide from metal salts includes cleaning a metal salt in a filter. After cleaning, the metal salt is dried in a drying apparatus. Steam is formed in the drying apparatus. The metal salt is preheated in at least one preheating stage. The metal salt is calcined to metal oxide in a fluidized-bed reactor. The metal oxide is cooled. The steam formed in the drying apparatus is recirculated into the filter.Type: GrantFiled: January 14, 2010Date of Patent: November 20, 2012Assignee: Outotec OyjInventors: Michael Missalla, Guenter Schneider, Jan Jarzembowski, Erwin Schmidbauer
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Patent number: 8282890Abstract: A vessel comprising a bed of randomly oriented ceramic media having fluid distribution channels incorporated in the outer surface of the media is disclosed. The channels capture and redirect the fluid thereby improving distribution of the fluid in the vessel.Type: GrantFiled: February 12, 2010Date of Patent: October 9, 2012Assignee: Saint-Gobain Ceramics & Plastics, Inc.Inventors: Hassan S. Niknafs, Daniel C. Sherman
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Patent number: 8221691Abstract: An apparatus for producing trichlorosilane includes a reaction container in which a supply gas containing silicon tetrachloride and hydrogen is supplied therein and a reaction product gas containing trichlorosilane and hydrogen chloride is produced; a heat transfer body which is filled in the reaction container, which is formed of a material having a melting point of at least higher than 1,400° C., and which has a void part which enables a gas to be passed; and a heating mechanism heating the heat transfer body in the reaction container.Type: GrantFiled: October 25, 2007Date of Patent: July 17, 2012Assignees: Mitsubishi Materials Corporation, Denki Kagaku Kogyo Kabushiki KaishaInventors: Mitsutoshi Narukawa, Yuji Shimizu
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Patent number: 8101131Abstract: Aluminum chloride from a gas containing chlorosilanes produced in a chlorination reactor is effectively removed. A container 1 is filled with sodium chloride and heated by a heating device 17, a gas containing chlorosilanes produced by a reaction between metallurgical grade silicon and hydrogen chloride passes through the sodium chloride layer 16 to generate a double salt of aluminum chloride contained in the gas and the sodium chloride, and the gas from which the double salt is separated is recovered from a gas recovery tube 26.Type: GrantFiled: March 20, 2009Date of Patent: January 24, 2012Assignee: Mitsubishi Materials CorporationInventors: Teruhisa Kitagawa, Mitsutoshi Narukawa, Chikara Inaba
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Patent number: 8043578Abstract: A flexible pressure containment coverplate has been invented for radial flow reactors. The coverplate is for a fixed bed reactor wherein the reactor undergoes significant thermal cycles. The coverplate provides flexibility for axial and radial thermal growth, while providing a sealing capability to prevent leakage of the fluid. The coverplate has a half toroidal structure, with a semi-circular cross-section.Type: GrantFiled: February 18, 2009Date of Patent: October 25, 2011Assignee: UOP LLCInventor: Michael J. Vetter
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Patent number: 7736467Abstract: A pulp digester includes a vessel having an inlet, an outlet and a wall extending between the inlet and the outlet, the wall of the vessel having a curved interior surface. The digester includes a screen assembly positioned inside the vessel adjacent to the curved interior surface of the wall for removing liquid from pulp material. The screen assembly is movable relative to the curved interior surface of the vessel wall. The digester includes at least one support element permanently attached to the vessel wall for limiting movement of the screen assembly relative to the curved interior surface of the vessel wall. In certain embodiments, the at least one support, such as a ledge permanently attached to the vessel wall, supports a portion of the screen assembly. The screen assembly may have an inner face that is concave in a horizontal direction and convex in a vertical direction.Type: GrantFiled: December 14, 2004Date of Patent: June 15, 2010Assignee: Metso Paper Pori OyInventors: Tuomo Nykanen, Lasse Hernesniemi
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Patent number: 7722832Abstract: A method and assembly for utilizing open-cell cellular solid material in a component separation unit to separate one or more process streams into component process streams having desired compositions. A method and assembly for using said open-cell cellular solid material to separate process streams into desired component process streams in a component separation unit, wherein the open-cell cellular solid material can include oxides, carbides, nitrides, borides, ceramics, metals, polymers, and chemical vapor deposition materials.Type: GrantFiled: May 24, 2005Date of Patent: May 25, 2010Assignee: Crystaphase International, Inc.Inventors: John N. Glover, Peter G. Ham, Krishna K. Rao, Stephen J. McGovern
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Patent number: 7632320Abstract: The present invention is a chemical reactor and method for catalytic chemical reactions having gas phase reactants. The chemical reactor has reactor microchannels for flow of at least one reactant and at least one product, and a catalyst material wherein the at least one reactant contacts the catalyst material and reacts to form the at least one product. The improvement, according to the present invention is: the catalyst material is on a porous material having a porosity that resists bulk flow therethrough and permits molecular diffusion therein. The porous material further has a length, a width and a thickness, the porous material defining at least a portion of one wall of a bulk flow path through which the at least one reactant passes.Type: GrantFiled: November 18, 2005Date of Patent: December 15, 2009Assignee: Battelle Memorial InstituteInventors: Anna Lee Y. Tonkovich, Yong Wang, Sean P. Fitzgerald, Jennifer L. Marco, Gary L. Roberts, David P. Vanderwiel, Robert S. Wegeng
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Patent number: 7628965Abstract: A gas generating system comprises a catalytic reactor in fluid communication with a sulfur separator. The catalytic reactor oxidizes a fuel to provide a supply of carbon dioxide. The sulfur separator removes sulfur components from the stream before or after the fuel is oxidized. A portion of the hot exhaust gas from the catalytic reactor can be used to regenerate an adsorption bed of the sulfur separator.Type: GrantFiled: November 3, 2006Date of Patent: December 8, 2009Assignee: Honeywell International IncInventors: Russell Johnson, Stephen F. Yates, Rehan Zaki
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Patent number: 7604781Abstract: Multiphasic reactions, especially those reactions using a phase transfer catalyst, are conducted in microchannel apparatus. Advantageously, these reactions can be conducted with two, planar microlayers of reactants in adjacent laminar flow streams. Microchannel apparatus and methods for conducting unit operations such as reactions and separations in microchannel apparatus is also described. Microchannel apparatus can provide advantages for controlling reactions and separating products, solvents or reactants in multiphase reactions.Type: GrantFiled: July 26, 2006Date of Patent: October 20, 2009Assignee: Battelle Memorial InstituteInventors: John H. Brophy, Bruce F. Monzyk
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Publication number: 20090202874Abstract: Hydrogen-producing fuel processing systems, hydrogen purification membranes, hydrogen purification devices, and fuel processing and fuel cell systems that include hydrogen purification devices. In some embodiments, the fuel processing systems and the hydrogen purification membranes include a metal membrane, which is at least substantially comprised of palladium or a palladium alloy. In some embodiments, the membrane contains trace amounts of carbon, silicon, and/or oxygen. In some embodiments, the membranes form part of a hydrogen purification device that includes an enclosure containing a separation assembly, which is adapted to receive a mixed gas stream containing hydrogen gas and to produce a stream that contains pure or at least substantially pure hydrogen gas therefrom. In some embodiments, the membrane(s) and/or purification device forms a portion of a fuel processor, and in some embodiments, the membrane(s) and/or purification device forms a portion of a fuel processing or fuel cell system.Type: ApplicationFiled: August 11, 2008Publication date: August 13, 2009Applicant: IdaTech, LLCInventors: David J. Edlund, William A. Pledger, R. Todd Studebaker
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Publication number: 20090197979Abstract: The present invention relates to a slurry bed loop reactor comprising a riser and at least one downcomer (3), wherein two ends of the riser are connected to two ends of the downcomer (3) via lines (16) and (7), respectively. The riser comprises a reaction section (1) and a settling section (2) with an increased tube diameter disposed on the reaction section (1). A gas outlet (13) exists at the top of the settling section (2). Each of the downcomers (3) is divided into a filtrate section (5) and a slurry section (6) by filter medium (4), wherein the filtrate section (5) is connected to a liquid outlet (10); two ends of the slurry section (6) are respectively connected to two ends of the riser, and the filtrate region (5) may further be connected to a back purging system.Type: ApplicationFiled: May 31, 2007Publication date: August 6, 2009Applicant: CHINA PETROLEUM & CHEMICAL CORPORATIONInventors: Zhanzhu Zhang, Lifeng Hu, Xiaojin Tang, Shaobing Wang, Shuandi Hou, Junyi Mao, Hongliang Qu
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Publication number: 20090177023Abstract: The device described in the present invention can trap plugging particles contained in the liquid feed supplying a reactor functioning in gas and liquid co-current down-flow mode using a specific distributor tray comprising a filtration medium. The present device is of particular application to the selective hydrogenation of feeds containing acetylenic and dienic compounds.Type: ApplicationFiled: August 24, 2006Publication date: July 9, 2009Inventors: Abdelhakim Koudil, Christophe Boyer
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Publication number: 20090101584Abstract: The present invention pertains to a reverse-flow reactor comprising at least one catalyst bed which is preceded and followed by at least one bed containing selectively adsorbing material, and its application for in a process for the removal of contaminants from a process stream.Type: ApplicationFiled: October 24, 2005Publication date: April 23, 2009Inventors: Alouisius Nicolaas Renee Bos, Girish Rajkumar Kabra, Jean-Paul Lange
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Patent number: 7393510Abstract: A method for removing contaminants from a process stream that includes the use of reticulated material to filter the process stream in a vessel located upstream of a process unit. The reticulated material can be used with other conventional filter media within the vessel.Type: GrantFiled: June 14, 2004Date of Patent: July 1, 2008Assignee: Crystaphase International, Inc.Inventors: John N. Glover, William D. Duke, Peter G. Ham
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Patent number: 7265189Abstract: A method for removing contaminants from an process stream that includes the use of reticulated material to filter the process stream. The reticulated material also facilitate process stream flow distribution in process units. The reticulated material can be packed with a void space between a substantial number of the reticulated material that can be varied to enhance filtration and flow distribution. The method of filtering also provides a method of removing contaminants leaving process equipment. The methods can be used on a variety of process streams and process equipment. The reticulated material can include ceramics, metallic materials, and chemical vapor deposition elements. The reticulated material can be of various shapes and sizes, and can also be catalytically active.Type: GrantFiled: March 25, 2003Date of Patent: September 4, 2007Assignee: Crystaphase Products, Inc.Inventor: John N. Glover
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Patent number: 7244281Abstract: A plasma fuel reformer assembly for producing reformate gas includes a fuel reformer having an air/fuel input assembly, an electrode assembly, and a soot trap positioned downstream of the electrode assembly. The electrode assembly includes a first electrode and a second electrode that is spaced apart from the first electrode. The fuel reformer further includes a reformer controller electrically coupled to the air/fuel input assembly. The reformer controller includes a processing unit electrically connected to a memory unit.Type: GrantFiled: October 24, 2003Date of Patent: July 17, 2007Assignee: Arvin Technologies, Inc.Inventors: Samuel N. Crane, Jr., William Taylor, III
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Patent number: 7128883Abstract: The use of two transalkylation catalysts to react aromatic compounds of carbon number nine (and heavier carbon numbers) with benzene to form carbon number eight aromatics is disclosed. The two catalyst system preserves ethyl-group species on the heavier aromatics that would otherwise de-ethylate over most gas-phase transalkylation catalysts to form undesired ethane gas with benzene or toluene. Thus, by using a transalkylation step to save ethylbenzene, a greater yield of para-xylene or other carbon number eight aromatics may be achieved within an integrated complex. An apparatus and process for the two transalkylation catalyst system is disclosed with a liquid-phase unit and a gas-phase unit.Type: GrantFiled: November 24, 2004Date of Patent: October 31, 2006Assignee: UOP LLCInventor: Robert B. James, Jr.
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Patent number: 7125528Abstract: An apparatus for separating oxygen from an oxygen-containing gas and facilitating a chemical reaction with the separated oxygen includes a mixed conducting membrane, a porous body, and a material for catalyzing the reaction. The mixed conducting membrane has respective oxidation and reduction surfaces and is made of a non-porous, gas-impermeable, solid material capable of simultaneously conducting oxygen ions and electrons. At least the membrane and the catalyzing material are non-reactive with each other or are physically separated from each other during oxygen separation and the chemical reaction. The apparatus can be embodied by tubes, and a plurality of such tubes can form part of a reaction vessel in which various chemical reactions can occur benefiting from the apparatus design.Type: GrantFiled: May 24, 2002Date of Patent: October 24, 2006Assignee: BP Corporation North America Inc.Inventors: Charles J. Besecker, Terry J. Mazanec, Sherman J. Xu, Erling Rytter
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Patent number: 7115148Abstract: Hydrogen is produced in a compact methanol-steam reformer, which integrates an inner cylindrical heating chamber; and a reactant vaporizer and heating zone, and an outer Cu/ZnO/Al2O3 catalyst bed in concentric annuli around the heating chamber. Tubular, palladium-silver alloy membranes in the catalyst bed separate hydrogen from retentate gas, which is separately discharged from the apparatus through a manifold.Type: GrantFiled: May 13, 2003Date of Patent: October 3, 2006Assignee: Her Majesty the Queen in right of Canada, as respresented by the Minister of Defence of Her Majesty's Canadian GovernmentInventors: Ian R. Wheeldon, Brant A. Peppley, Helmut Wieland
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Patent number: 6972119Abstract: A hydrogen producing apparatus comprising: a reforming section having a reforming catalyst which causes a reaction between a carbon-containing organic compound as a feedstock and water; a feedstock supply section for supplying the feedstock to the reforming section; a water supply section for supplying water to the reforming section; a heating section for heating the reforming catalyst; a shifting section having a shift catalyst which causes a shift reaction between carbon monoxide and water contained in a reformed gas supplied from the reforming section; and a purifying section having a purifying catalyst which causes oxidation or methanation of carbon monoxide contained in a gas supplied from the shifting section, wherein the shift catalyst comprises a platinum group metal and a metal oxide.Type: GrantFiled: December 27, 2000Date of Patent: December 6, 2005Assignee: Matsushita Electric Industrial Co., Ltd.Inventors: Kiyoshi Taguchi, Takeshi Tomizawa, Kunihiro Ukai, Toshiyuki Shono, Koichiro Kitagawa, Tetsuya Ueda, Seiji Fujihara, Yutaka Yoshida
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Patent number: 6846469Abstract: A method for extending the operating life of a fixed bed reactor for reacting a feedstock in which a feedstock is contacted with a fixed bed of catalytic material contained in the reactor.Type: GrantFiled: November 14, 2000Date of Patent: January 25, 2005Assignee: ExxonMobil Research and Engineering CompanyInventors: Ramesh Gupta, Salvatore Joseph Rossetti, David Charles Dankworth, Jeffrey L. Kaufman, David Lee Vannauker, James Philip Bailor
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Patent number: 6767389Abstract: Membrane modules that contain one or more hydrogen-selective membranes, methods for preparing the same, and hydrogen purification systems, fuel processors and devices containing the same. In some embodiments, the membrane modules include one or more hydrogen-selective membranes supported on a support or screen structure, of which a variety of embodiments are disclosed. In some embodiments, the membrane or membranes are adhesively mounted on the screen structure during assembly. In some embodiments, the screen structure includes a plurality of screen members adhesively mounted together during assembly. In some embodiments, the screen structure includes a coating. The present invention is also directed to methods for reducing the thickness of hydrogen-selective membranes.Type: GrantFiled: July 21, 2003Date of Patent: July 27, 2004Assignee: IdaTech, LLCInventors: David J. Edlund, William A. Pledger, R. Todd Studebaker
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Patent number: 6746651Abstract: A stack of very thin metal plates provides high surface area for catalytic decomposition of a fluid flowing axially from upstream to downstream through the stack. Each plate has flow-through passages of selected size and location to promote uniform flow and good surface contact with a catalyst surface on the plates. The downstream surface of each plate is etched to provide gaps between plates for lateral fluid flow. The plates are divided into groups separated by metering plates that promote more uniform flow from group to group.Type: GrantFiled: August 10, 1999Date of Patent: June 8, 2004Assignee: Aerojet-General CorporationInventors: James B. Ponzo, Robert C. Schindler, Hans Harry Mueggenburg
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Patent number: 6733552Abstract: A hydrogen generating apparatus having a fuel feeding part, a water feeding part for fuel reforming, an oxidant gas feeding part, a reforming catalyst body, a heating part for the reforming catalyst, a CO shifting catalyst body and a CO purification catalyst body is provided wherein the reforming catalyst body, the CO shifting catalyst body and the CO purification catalyst body are sequentially ordered from the fuel feeding part toward the downstream side, and wherein a shifting catalyst of the shifting catalyst body contains as one component at least a platinum group-type catalyst.Type: GrantFiled: March 13, 2000Date of Patent: May 11, 2004Assignee: Matsushita Electric Industrial Co., Ltd.Inventors: Kiyoshi Taguchi, Takeshi Tomizawa, Kunihiro Ukai, Toshiyuki Shono, Kouichiro Kitagawa
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Patent number: 6692705Abstract: The invention is directed to a multi-tier bypass apparatus for extending the operating life of fixed bed reactors. The multi-tier bypass may be disposed within a fixed catalyst bed to allow any fluid feedstock to bypass successive layers of the fixed catalyst bed as they foul. The invention also relates to an improved fixed bed reactor comprising the inventive multi-tier bypass and a method for extending the operating life of a fixed bed reactor.Type: GrantFiled: August 22, 2001Date of Patent: February 17, 2004Assignee: ExxonMobil Research and Engineering CompanyInventors: Ramesh Gupta, Salvatore Joseph Rossetti
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Patent number: 6689329Abstract: The invention is directed to a bypass device for extending the operating life of fixed bed reactors. The device may be placed within a fixed catalyst bed to partition the bed into a first top bed and a second virtual bed. The bypass device allows any fluid feedstock to bypass the first top bed of the fixed catalyst bed as it fouls and enter the second virtual bed under conditions that promote depositing any foulants contained in the bypass flow on the top surface of the second virtual bed rather than in the interstices of the second virtual bed. The invention also relates to an improved fixed bed reactor comprising the inventive bypass device and a method for extending the operating life of a fixed bed reactor that employs the inventive bypass device.Type: GrantFiled: October 10, 2001Date of Patent: February 10, 2004Assignee: ExxonMobil Research and Engineering CompanyInventors: Ramesh Gupta, Salvatore Joseph Rossetti
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Patent number: 6632406Abstract: The device for removing pollution from the exhaust gases of an internal combustion engine includes an exhaust box (12) containing, in series, a catalytic purification unit (18) and a particle filter (20). The exhaust box (12) includes means (36; 60) providing access to the upstream face of the particle filter (20). Application to removing pollution from automobile vehicle diesel engines in particular.Type: GrantFiled: December 13, 1999Date of Patent: October 14, 2003Assignee: Ecia IndustrieInventors: Joël Michelin, Jean-Pierre Barnabé
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Publication number: 20030095901Abstract: An arrangement for mounting a screen (20) in a continuous digester used for making chemical pulp or paper pulp. Such a digester includes a substantially cylindrical pressure vessel arranged in an upright position, the pressure vessel having a smaller diameter at the top end of the digester than at the bottom end of the digester, the diameter of the digester being changed at regionally defined areas by one or more conical sections (4). The screens are mounted at these conical sections to remove liquid from chips or pulp in the digester. In the present arrangement an upper edge (21) of the screen (20), which, in the operating position, is located higher, is arranged in the region of the conical section (4). In particular, the screen extends substantially to the section of the conical section, which has the smallest diameter.Type: ApplicationFiled: November 5, 2002Publication date: May 22, 2003Inventor: Antti Isola
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Publication number: 20020188155Abstract: A description is given here of a novel process for the production of monocarboxylic and polycarboxylic aromatic acids by the catalytic oxidation in homogeneous phase of aromatic compounds carrying at least one oxidizable substituent group attached directly to the carbon atom of the corresponding aromatic nucleus. The novel process according to the present invention comprises the steps of: a) catalytically oxidizing the corresponding aromatic precursors in liquid phase in the presence of gaseous oxygen; b) filtering the end product; c) recycling into the oxidation reactor at least part of the mother liquors resulting from the filtration stage, and is characterized by the fact that said steps from (a) to (c) are carried out in a closed and continuous cycle operating substantially under the same pressure and temperature conditions, preferably at 2-10 barg and 100-140° C.Type: ApplicationFiled: June 3, 2002Publication date: December 12, 2002Inventors: Franco Codignola, Antonio Moro
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Patent number: 6464949Abstract: A steam-cracking unit comprises at least one multitube quenching exchanger, equipped with a non-obstructive impact separator for preventing the erosion of the tubular input plate. The impact separator is at least 50% opaque when viewed from transfer pipe. It is arranged inside of an input cone in such a way that there is free passage of at least 40 mm between the periphery of the impact separator and the cone.Type: GrantFiled: March 8, 1999Date of Patent: October 15, 2002Assignee: Institut Francais du PetroleInventors: Eric Lenglet, Jean-Pierre Burzynski, Gérard Courteheuse, Roland Huin, Yves Gougne
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Publication number: 20020141920Abstract: An improved metal gas separation membrane for separating hydrogen from a gas steam includes a quantity of metal particles that are bonded together to form a porous body. The porous body may have a porosity that increases from a first surface to an opposite second surface and may additionally include a coating of ceramic particles on the first surface. The metal gas separation membrane may include a coating of a dense precious metal applied thereto that is permeable by hydrogen via chemisorption-dissociation-diffusion. The porous body may include a catalytic enhancement. Also disclosed are three gas separation modules that employ the metal gas separation membrane disposed within a core of the gas separation module for separating hydrogen from a gas stream. The gas separation membranes are each supported on a first mounting member and a second mounting member. The gas separation modules may also include a catalytic enhancement.Type: ApplicationFiled: September 13, 2001Publication date: October 3, 2002Inventors: Mary Anne Alvin, Gerald J. Bruck
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Publication number: 20020098136Abstract: Many useful chemical conversion processes result in the production or removal of thermal energy as the result of such processes. A device for permitting staged addition of heat into a steam reforming, carbon dioxide reforming, water-gas-shift, or preferential reactor using an inline system built to accomplish multiple reactant injection and gas mixing along the flow path of a chemical reactor. This integrates a uniform reaction injection device, a gas mixing component, and a catalytic initiator within a section designed to be installed between compartments used to promote an endothermic process. The intent is to provide heat through an endothermic process that uniformly increases temperature for convection heat transport into the subsequent compartment.Type: ApplicationFiled: January 23, 2001Publication date: July 25, 2002Inventor: Nicholas Vanderborgh
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Publication number: 20020094313Abstract: A stripper and a stripping process for removing the flue gas carried by regenerated catalyst. A cylindrical stripper mainly comprises a degassing pipe at the longitudinal axis, a horizontal pipe connected with the lower end of the degassing pipe, several sets of inner annular baffles and outer annular baffles arranged in alternative arrangement along the vertical direction. Inner annular baffles are fixed on the degassing pipe, outer annular baffles are fixed on the inner wall of the cylinder. The degassing pipe has holes below each set of the inner annular baffles. The regenerated catalyst enters the stripper from the upper part, comes into a countercurrent and crosscurrent contact with steam from the annular steam conduit, and the stripped regenerated catalyst leaves the stripper from the bottom.Type: ApplicationFiled: March 1, 2001Publication date: July 18, 2002Applicant: CHINA PETROLEUM AND CHEMICAL CORP.Inventors: Weimin Lu, Xieqing Wang, Xiaoxiang Zhong, Songnian Li
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Publication number: 20020068027Abstract: The invention is directed to a multi-tier bypass apparatus for extending the operating life of fixed bed reactors. The multi-tier bypass may be disposed within a fixed catalyst bed to allow any fluid feedstock to bypass successive layers of the fixed catalyst bed as they foul. The invention also relates to an improved fixed bed reactor comprising the inventive multi-tier bypass and a method for extending the operating life of a fixed bed reactor.Type: ApplicationFiled: August 22, 2001Publication date: June 6, 2002Inventors: Ramesh Gupta, Salvatore Joseph Rossetti
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Publication number: 20020031459Abstract: The invention is directed to a reactor for reacting a feedstock, said reactor comprising, a fixed catalyst bed for reaction of said feedstock said reactor containing a bypass apparatus disposed within said fixed catalyst bed, said bypass apparatus being aligned with the direction of flow of said feedstock, and wherein said bypass apparatus comprise a cage member comprising a first elongated hollow member having a top wall, sidewalls and a bottom wall, said cage member having openings therein, and a second hollow elongated member for passing said feedstock therethrough, said second hollow elongated member being disposed within and protruding through said top wall of said cage member and wherein said second elongated member extends above said catalyst bed through said cage member.Type: ApplicationFiled: July 13, 1999Publication date: March 14, 2002Inventors: RAMESH GUPTA, SALVATORE JOSEPH ROSSETTI, DAVID CHARLES DANKWORTH, JEFFREY L. KAUFMAN, DAVID LEE VANNAUKER, JAMES PHILIP BAILOR