Including Solid Reactant And Means Charging Solids Into, Or Dischanging Solids From, Reaction Chamber Patents (Class 422/232)
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Patent number: 11826749Abstract: A pyrolysis reactor (12) and method for the pyrolysis of hydrocarbon gases (e.g., methane) utilizes a pyrolysis reactor (12) having a unique burner assembly (44) and pyrolysis feed assembly (56) that creates an inwardly spiraling fluid flow pattern of the feed gases to form a swirling gas mixture that passes through a burner conduit (46) with a constricted neck portion or nozzle (52). At least a portion of the swirling gas mixture forms a thin, annular mixed gas flow layer immediately adjacent to the burner conduit (46). A portion of the swirling gas mixture is combusted as the swirling gas mixture passes through the burner conduit (46) and a portion of combustion products circulates in the burner assembly (44). This provides conditions suitable for pyrolysis of hydrocarbons or light alkane gas, such as methane or natural gas.Type: GrantFiled: April 28, 2021Date of Patent: November 28, 2023Assignee: SABIC Global Technologies B.V.Inventors: Sreekanth Pannala, Vladimir Shtern, Lei Chen, David West
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Patent number: 11697100Abstract: A device for cooling a fine-grained solid includes a fluidized bed cooler/heater in which the solid is fluidized with a fluidizing gas and thereby releases energy in the form of heat within the cooler/heater at least two cyclones which are connected in parallel. The cyclones are arranged such that after the fluidization of the solid the fluidizing gas passes through the cyclones so contained particles are removed.Type: GrantFiled: July 1, 2019Date of Patent: July 11, 2023Assignee: METSO OUTOTEC FINLAND OYInventors: Günter Schneider, Robert Maduta, Linus Perander, Eugen Weissenburger, Timo Hensler
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Patent number: 10611634Abstract: Provided are processes for production of hydrogen to be used in various industrial processes, including in processes for production of ammonia and urea. Included are polygeneration processes that result in ultra-low emissions.Type: GrantFiled: March 29, 2018Date of Patent: April 7, 2020Assignee: GRANNUS, LLCInventor: James Kelly Merritt, Jr.
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Patent number: 9809771Abstract: A carbonaceous substance dry powder gasification device and method, the device comprising from bottom to top a lower cooling and purification section (1), a gasification reaction section (2), a cooling reaction section (3) and an upper cooling and purification section (4); an initial cooling device is disposed at the connection between the cooling reaction section and the gasification reaction section; and a plurality of nozzles are circumferentially arranged in the gasification reaction section.Type: GrantFiled: November 21, 2014Date of Patent: November 7, 2017Assignee: ChangZheng Engineering Co., Ltd.Inventors: Congbin Jiang, Wei Xin, Honghai Li, Ruiheng Gao, Yongjin Chen, Xiaofei Li, Yan Zhang, Li Zhang
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Patent number: 9777263Abstract: The present invention relates to an apparatus for preparing enzyme-immobilized beads used for preparation of tagatose, and a method for preparing enzyme-immobilized beads using the same. More specifically, the present invention relates to an apparatus for preparing enzyme-immobilized beads, comprising a nozzle with an inside diameter of 0.1-1 mm having a cylindrical lower end and comprising a cut-type liquid outlet (cut perpendicularly to the vertical axis of the nozzle) formed at the lower end, and a method for preparing enzyme-immobilized beads using the same.Type: GrantFiled: May 18, 2017Date of Patent: October 3, 2017Assignee: CH CHEILJEDANG CORPORATIONInventors: Soon Chul Kim, Seong Bo Kim, Jae Youn Lim, Kwang Jin An, Jin Ha Kim
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Patent number: 9144807Abstract: A centrifuge for separating solids from a liquid including a centrifuge rotor with a rotor shaft, partially formed as a hollow shaft, and a centrifuging drum, being rotatable with the rotor shaft, wherein the liquid to be separated can be supplied via the cavity of the hollow shaft. To ease emptying of the drum, the centrifuging drum includes a drum lower part and a drum upper part, which bears loosely against the drum lower part. The upper part is guided in an axially movable manner on the shaft and is movable by means of a disengagement mechanism parallel to the rotor axis into an open position in which, for self-emptying of the interior space, the drum parts are spaced apart from one another while they still rotate with the rotor shaft.Type: GrantFiled: August 17, 2009Date of Patent: September 29, 2015Assignee: BOLL & KIRCH FILTERBAU GMBHInventors: Carsten Tietze, Gerd Stahl
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Publication number: 20150132201Abstract: When processing cellulosic biomass, it may be desirable for a digestion unit to operate without being fully depressurized for process efficiency purposes. Methods for processing cellulosic biomass may comprise providing a biomass conversion system comprising a pressurization zone and a digestion unit that are operatively connected to one another; providing cellulosic biomass at a first pressure; introducing at least a portion of the cellulosic biomass into the pressurization zone and pressurizing the pressurization zone to a second pressure higher than the first pressure; after pressurizing the pressurization zone, transferring at least a portion of the cellulosic biomass from the pressurization zone to the digestion unit, which is at a third pressure that is less than or equal to the second pressure but higher than the first pressure; and digesting at least a portion of the cellulosic biomass in the digestion unit to produce a hydrolysate comprising soluble carbohydrates.Type: ApplicationFiled: January 14, 2015Publication date: May 14, 2015Inventors: Juben Nemchand CHHEDA, Thomas Lamar FLOWERS, Joseph Broun POWELL
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Publication number: 20150125359Abstract: The present invention discloses a fuel supply for a fuel cell, the fuel cell including a liquid storage area that includes a liquid reactant, a reaction area that includes a solid reactant, wherein the liquid reactant is pumped into the reaction area such that the liquid reactant reacts with the solid reactant to produce reaction components, a product collection area that receives the reaction components, a barrier, and a container with an interior volume that substantially encloses the reaction area, liquid storage area, product collection area. The barrier separates and defines several of the aforementioned areas, and moves to simultaneously increase the product collector area and decrease the liquid storage area as the liquid reactant is pumped from the liquid storage area and the reaction components are transferred into the product collection area.Type: ApplicationFiled: December 11, 2014Publication date: May 7, 2015Inventors: Daniel Braithwaite, Jesse Thomas, Adam Rodriguez, Tobin Fisher, Tibor Fabian
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Patent number: 8974763Abstract: A system for the production of ammonium sulfate granules including a pipe cross reactor (PCR) configured to contact concentrated sulfuric acid with anhydrous ammonia to produce a PCR product comprising ammonium sulfate; and a granulator fluidly connected to the PCR, whereby PCR product extracted from the PCR can be introduced into the granulator, an inlet for ammonium sulfate seed material, an ammonia sparger configured to spray liquid anhydrous ammonia directly onto a bed of ammonium sulfate granules within the granulator, a granulator vent configured for extraction of a vapor comprising unreacted ammonia from the granulator, and a granulator product outlet configured for extraction of granulator product comprising ammonium sulfate granules from the granulator. A method of producing ammonium sulfate granules is also provided.Type: GrantFiled: December 18, 2013Date of Patent: March 10, 2015Assignee: Rentech, Inc.Inventors: Praveen Jain, Santiago Gomez, Mark D. Ibsen
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Patent number: 8956573Abstract: The present invention relates to an apparatus and process for polymerizing olefins. One embodiment comprises polymerizing at least one monomer in a first loop reactor in the presence of a catalyst to produce a first polyolefin fraction. A portion of the first polyolefin fraction is transferred to a second loop reactor, connected in series with the first loop reactor. The process further comprises polymerizing in the second loop reactor at least one monomer in the presence of a catalyst to produce a second polyolefin fraction in addition to the first polyolefin fraction. The combination of the first and second polyolefin fractions can produce a polymer resin fluff having bimodal molecular weight distribution.Type: GrantFiled: May 21, 2014Date of Patent: February 17, 2015Assignee: Total Research & Technology FeluyInventors: Louis Fouarge, Eric Damme, Olivier Miserque, Daniel Siraux, Philippe Bodart, Andre Lewalle, Marc Van der Auwera, Frans Van den Brande, Giacomo Conti, Hugo Vandaele, Mark Verleysen, Carl Van Camp, Etienne Laurent, Philippe Marechal, Marc Moers, Leopold D'Hooghe, Marjan Sillis, Kai Hortman, Pascal Folie, Renaud Oreins
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Patent number: 8920736Abstract: A loop seal for a fluidized bed reactor comprising a vertical downcomer segment connected to a dipleg for receiving solids particles from the dipleg, a horizontal segment downstream of the downcomer, a riser segment downstream of the horizontal segment, and a downwardly inclined segment downstream of the riser, whereby the solids are entrained to the fluidized bed reactor. An eductor is added to the angled leg to induce the underflow gas from the cyclone; one of the preferred motive fluids to the eductor is the fines from fuel preparation and the carrying gas for the fines. Also provided are a fluidized bed reactor comprising the loop seal, and a method for producing syngas from coal and steam using the same.Type: GrantFiled: June 5, 2010Date of Patent: December 30, 2014Assignee: Synthesis Energy Systems, Inc.Inventor: Guohai Liu
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Publication number: 20140360919Abstract: The invention concerns a fluid distribution device (1) comprising: at least one inlet tube (2) comprising openings (7) and having a first and a second end (3, 4); a cap (5) comprising a principal body (6) with a lenticular shape and with a circular section elongated by a skirt (8) extending in the direction of the second end (4) towards the first end (3) of the inlet tube (2), said cap (5) having an outer surface and an inner surface, the cap being integral with the second end (4) of the tube via the inner surface and the principal body (6) being provided with a plurality of holes (10); and in which the cap (5) comprises at least one deflection means (14) disposed on its outer surface and configured to direct or maintain the gas towards or at the periphery of said cap (5).Type: ApplicationFiled: June 10, 2014Publication date: December 11, 2014Applicant: AXENSInventors: Jean Francois LE COZ, Daniel FERRE, Cyril COLLADO
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Publication number: 20140357917Abstract: A riser includes a housing in communication with a entry conduit and an exit conduit. The housing is defined by a holdup chamber having a volume of between about 1133 liters and about 45307 liters. The riser is designed to receive a hydrocarbon feed and a catalyst. An apparatus for fluid catalytic cracking includes a riser in fluid communication with a reactor vessel. A hydrocarbon feed stream and a catalyst travel through a first section of the riser at a first velocity of between about 1.5 m/sec to about 10 m/sec and through a second section of the riser at a second velocity of more than about 15 m/sec. A process for fluid catalytic cracking uses a riser with a holdup chamber. A hydrocarbon feed and a catalyst decrease in velocity in the holdup chamber to between 1.5 m/sec and 10 m/sec.Type: ApplicationFiled: May 31, 2013Publication date: December 4, 2014Applicant: UOP LLCInventors: Patrick D. Walker, Matthew Lippmann, Mark Schnaith
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Publication number: 20140326925Abstract: Gasification reactor and process for the production of synthesis gas by partial combustion of a carbonaceous feed. The reactor comprises a reactor chamber with one or more burners and at least one oil lance extending into the reactor chamber. The oil lances can for instance be located at a level 1.5 meters or less below or above the burners.Type: ApplicationFiled: October 17, 2012Publication date: November 6, 2014Inventors: Johannes Cornelis De Jong, Chengming Gao
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Publication number: 20140319418Abstract: The invention relates to a process for producing a hydrogel, which is performed in a reactor which has a body A which rotates about an axis of rotation and a metering system. A component comprising at least i) a soluble salt of an acidic or amphoteric oxygen-containing molecular anion and ii) a component comprising a precipitant are applied with the aid of the metering system to the surface of the rotating body A, such that a mixture of components i) and ii) flows over the surface of the rotating body A to an outer region of the surface of the rotating body A, the mixture leaves the surface and the pH of the mixture after leaving the surface of the body A is between 2 and 12. Additionally disclosed is the use of the resulting hydrogels for production of aerogels.Type: ApplicationFiled: April 13, 2012Publication date: October 30, 2014Applicant: CONSTRUCTION RESEARCH AND TECHNOLOGY GmbHInventors: Zhizhong Cai, Shane Mc Donnell, Burkhard Walther
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Publication number: 20140294695Abstract: An injector mixer for a gasification reactor system that utilizes reactants includes an injector body that extends between a first face and a second face. The injector body includes a first passage that extends between the first face and the second face and has a first central axis. At least one second, impinging passage extends between the first face and second face and has an associated second central axis that has an angle with the first axis. The angle satisfies mixing efficiency Equation (I) disclosed herein.Type: ApplicationFiled: May 31, 2011Publication date: October 2, 2014Applicant: Aerojet Rocketdyne of DE, Inc.Inventors: Chandrashekhar Sonwane, Kenneth M. Sprouse
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Publication number: 20140294694Abstract: One exemplary embodiment can be a process for transferring catalyst in a fluid catalytic cracking apparatus. The process can include passing the catalyst through a conveyor wherein the conveyor contains a screw for transporting the catalyst.Type: ApplicationFiled: March 26, 2013Publication date: October 2, 2014Applicant: UOP, LLCInventors: Sathit Kulprathipanja, Paolo Palmas
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Patent number: 8834819Abstract: A powder lime calcining process comprises: transporting fine granules of limestones having a water content less than 4%, and a granule size less than 15 mm, from a raw material storing bin to a small material bin, transporting the materials from the small material bin into an airflow pipe by a belt conveyer, heating and drying the materials, sieving the materials by a sieving device, transporting granules into a cyclone cylinder deduster and a clothbag deduster in turn by airflow pipes, the fine powders of limestones after dedusted are transported into an intermediate bin; the materials within the intermediate bin are transported to four preheating cyclone cylinders by a pneumatic lift pump and airflow pipes, and are preheated and separated; the materials after separated are transported into three cooling cyclone cylinders for cooling and separating the materials, finally transported into a finished product bin by a finished product transporting system.Type: GrantFiled: October 13, 2010Date of Patent: September 16, 2014Assignee: Baoshan Iron & Steel Co., Ltd.Inventors: Jun Wei, Hua Gao, Bin Zhang, Guoqiang Liu
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Patent number: 8795602Abstract: In certain embodiments, a feed injector system includes an inner channel configured to convey at least one of a solid fuel feed or a liquid reactant or moderator to a reaction zone. A first oxidizer channel extends around the inner channel, wherein the first oxidizer channel is configured to convey a first oxidizer stream to the reaction zone. A second oxidizer channel extends around the first oxidizer channel, wherein the second oxidizer channel is configured to convey a second oxidizer stream to the reaction zone. Additionally, a third channel extends around the inner channel and the first and second oxidizer channels, wherein the third channel is configured to convey at least one of the solid fuel feed or the liquid reactant or moderator to the reaction zone.Type: GrantFiled: September 29, 2011Date of Patent: August 5, 2014Assignee: General Electric CompanyInventor: Ali Ergut
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Patent number: 8784744Abstract: The present invention discloses an apparatus for thermally refining phosphorus. The apparatus comprises: a melting furnace for melting rock phosphate into melts, including a feed port and a melt outlet; and a reduction-oxidation furnace including a furnace body which gas a melt inlet, a slag outlet, and a fume outlet, and a blow gun, wherein the melt inlet and the melt outlet are in communication with each other and wherein the blow gun has an end inserted into the furnace body. The content of impurities in fumes containing phosphorus pentaoxide is low, and the phosphorus pentaoxide can be easily extracted with a high purity of the phosphorus pentaoxide and at low cost by means of the apparatus for thermally refining phosphorus according to the present invention.Type: GrantFiled: May 27, 2010Date of Patent: July 22, 2014Assignees: China Enfi Engineering Corp., Sichuan Chuanheng Chemical CorporationInventors: Xiaomei Feng, Jin Li, Dong Li, Guangming Li, Zhenmin Zhang, Jiacai Wang, Jian Zou, Yongqiang Ma, Jun Hou
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Patent number: 8741226Abstract: The present invention discloses a reduction-oxidation furnace for thermally refining phosphorus. The reduction-oxidation furnace comprises a furnace body and a blow gun, wherein the furnace body has a slag outlet, a fume outlet, and a melt inlet for feeding melts formed by melting rock phosphate into the furnace body and wherein the blow gun has an end inserted into the furnace body. The content of impurities in fumes containing phosphorus pentaoxide is low, the phosphorus pentaoxide can be easily extracted with a high purity of the phosphorus pentaoxide and at low cost by means of the reduction-oxidation furnace for thermally refining phosphorus according to the present invention.Type: GrantFiled: May 27, 2010Date of Patent: June 3, 2014Assignees: China Enfi Engineering Corp., Sichuan Chuanheng Chemical CorporationInventors: Xiaomei Feng, Jin Li, Dong Li, Guangming Li, Zhenmin Zhang, Jiacai Wang, Jian Zou, Yongqiang Ma, Jun Hou
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Patent number: 8728400Abstract: Collection enhanced materials, flue gas additives, and methods of making the enhanced materials and flue gas additives are provided. In one embodiment, a down stream addition system configured to control material passing through a metering device from a vessel to a gaseous exhaust path extending between a unit and an exhaust flue of the unit is provided. In alternative embodiments, methods are provided for introducing at least one of a flue gas additive and a collection enhanced material to a gaseous exhaust stream exiting a unit; exposing and removing at least a portion of at least one a of flue gas additive and a collection enhanced material from a gaseous exhaust stream exiting a unit prior to entering an exhaust flue; and recycling at least a portion of material removed a from a gaseous exhaust stream exiting a unit back to the gaseous exhaust stream without passing through the unit.Type: GrantFiled: May 14, 2013Date of Patent: May 20, 2014Assignee: Intercat Equipment, Inc.Inventors: Martin Evans, Raymond Paul Fletcher, Mehdi Allahverdi, Guido Aru, Paul Diddams, Xunhua Mo, William Reagan, Shanthakumar Sithambaram
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Publication number: 20140079594Abstract: An underwater carbon dioxide storage facility including a carbon dioxide deposit stored underwater as a clathrate includes a flexible barrier disposed at least partially over the carbon dioxide deposit. The carbon dioxide deposit may be stored in or at the bottom of a body of water.Type: ApplicationFiled: September 17, 2012Publication date: March 20, 2014Applicant: Elwha LLCInventors: Kenneth G. Caldeira, Philip A. Eckhoff, Muriel Y. Ishikawa, Roderick A. Hyde, Lowell L. Wood, JR.
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Patent number: 8642002Abstract: Disclosed are a hydrogen energy production system utilizing silicon wastewater and a method for production of hydrogen energy using the same. More particularly, the disclosed system includes: a UF treatment bath wherein the silicon wastewater is treated through UF film filtration to separate UF treated water and a concentrated silicon waste solution therefrom; a line mixer connected to the UF treatment bath in order to admix the separated silicon waste solution with an alkaline material fed from the outside; and a hydrogen production bath connected to the line mixer, wherein the concentrated silicon waste solution in the mixture reacts with the alkaline material, in order to produce hydrogen gas. Additionally, a hydrogen energy production method using the foregoing system is also disclosed.Type: GrantFiled: January 24, 2011Date of Patent: February 4, 2014Assignee: Woongjin Coway Co., Ltd.Inventors: Chae-Seok Choi, Ji-Hyeon Hwang, Youn-Kook Kim
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Publication number: 20130336851Abstract: A process and apparatus for fluid catalytic cracking feeds catalyst to a chamber of a riser. The catalyst exits the chamber and passes through a plenum and into a reaction zone through a plurality of tubes which distribute the catalyst uniformly over a cross section of the reaction zone of the riser. A hydrocarbon feed is fed to the plenum. The hydrocarbon feed passes from the plenum into the reaction zone through a plate comprising a multiplicity of openings which distribute the hydrocarbon feed uniformly over a cross section of the reaction zone of the riser. The feed is contacted with the catalyst in a reaction zone of the riser.Type: ApplicationFiled: June 14, 2012Publication date: December 19, 2013Applicant: UOP LLCInventor: Sujay R. Krishnamurthy
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Publication number: 20130313163Abstract: The invention concerns a purge/sampling system for vessels, particularly for high temperature, high pressure vessels such as hydroconversion reactors used in refinery processes and operated in severe conditions. Such purge/sampling system comprises a purge/sampling line (16) equipped with a connector designed to be connected to the vessel (10), a first (18 and a second (20) flow regulation systems mounted in series on the purge/sampling line, wherein at least one injection line (22) is connected to the purge/sampling line between the first and the second flow regulation systems, said injection line comprising connecting means to a source of cleaning fluid (24) and at least one flow regulation device to control the flow of cleaning fluid through injection line and purge/sampling line The invention also concerns a vessel equipped with such a purge/sampling system, as well as a cleaning method using said purge/sampling system.Type: ApplicationFiled: December 23, 2011Publication date: November 28, 2013Applicant: TOTAL RAFFINAGE MARKETINGInventors: Katell Le Lannic, Xavier Mourain, Maxime Varin
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Patent number: 8562270Abstract: A dam arrangement is provided for confining catalyst and other particles. The dam can be arranged in a wide variety of configurations. In one embodiment, blocks are provided that are releasably secured to the top tubesheet by means of magnets, and sheets are secured to the blocks to create a dam. In another embodiment, the blocks are releasably secured to the tubesheet by fasteners which project into the tops of some of the tubes and then lock into those tubes.Type: GrantFiled: September 17, 2010Date of Patent: October 22, 2013Assignee: Extundo IncorporatedInventors: Clifford L. Johns, Dennis McAndrews, Douglas K. Cornett
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Patent number: 8535614Abstract: The present invention provides a reactor and a method for the production of high purity silicon granules. The reactor includes a reactor chamber; and the reaction chamber is equipped with a solid feeding port, auxiliary gas inlet, raw material gas inlet, and exhaust gas export. The reaction chamber is also equipped with an internal gas distributor; a heating unit; an external exhaust gas processing unit connected between a preheating unit and a gas inlet. The reaction chamber is further equipped with a surface finishing unit, a heating unit and a dynamics generating unit. The reaction is through decomposition of silicon containing gas in densely stacked high purity granular silicon layer reaction bed in relative motion, and to use remaining hear of exhaust gas for reheating. The present invention is to achieve a large scale, efficient, energy saving, continuous, low cost production of high purity silicon granules.Type: GrantFiled: March 8, 2011Date of Patent: September 17, 2013Assignee: Sunnyside Technologies, Inc.Inventor: Xi Chu
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Patent number: 8519094Abstract: Process for heating a polymer-containing stream being transferred from a polymerization reactor to a separation zone or device, by passing the stream through at least two heaters operating in parallel, each heater having at least one transfer line for the stream and a heater for heating the transfer line. The average particle of the polymer is below 3 mm, the temperature of the polymer-containing stream at the outlet of all heaters is maintained above the dew point of the stream, and no heater has a volumetric flowrate of polymer-containing stream more than three times that of any other heater.Type: GrantFiled: April 15, 2009Date of Patent: August 27, 2013Assignee: Ineos Manufacturing Belgium NVInventors: Daniel Marissal, Marc Parisel, Brent Walworth
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Patent number: 8512643Abstract: A method for controlling volatiles in recycled carbon black, such as from pyrolysis of tires, includes deagglomerating the recycled carbon black to substantially reduce the carbon black particle size and impinging an air current on the carbon black particles, preferably in a countercurrent direction, to increase the processing temperature and thereby enhance the release of volatiles. Associated apparatus is disclosed.Type: GrantFiled: August 11, 2009Date of Patent: August 20, 2013Assignee: Delta Energy Holdings, LLCInventors: Daniel E. Steinmeyer, Alan M. Levine, Duane M. Erickson
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Patent number: 8512656Abstract: Regenerator and process for regenerative thermal oxidation of offgases comprising halooganosilocon compounds in which offgases are heated in the regenerator, fed to an oxidation zone present in the regenerator to oxidize the haloorganosilicon compounds to SiO2 and hydrogen halides which form a flue gas which is then cooled in the generator to a temperature below its acid dew point and is discharged.Type: GrantFiled: August 2, 2012Date of Patent: August 20, 2013Assignee: Bayer Intellectual Property GmbHInventors: Ulrich Westphal, Thomas Leyendecker, Michaela Maria Schütz, Mischa Theis, Dieter Förtsch
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Patent number: 8491857Abstract: Processes and apparatus produce economically feasible biodiesel without subsidies. Toward that end, integrated small plants process materials containing lipids with anhydrous bioethanol as solvent and reactant, and sulfuric acid and potassium hydroxide mainly as catalysts to produce up to 3 million gallons of biodiesel per plant per year. The product is predominantly fatty acids ethyl esters (FAEE) and a chemically-enhanced organic fertilizer as byproduct. The raw material may include a wide variety of non-edible solid matter that contains lipids, which normally have from 0.5% to 80% by weight of free fatty acids in total oils. Multiple apparatus makes this process feasible. In addition to not competing with food production, since they supply fertilizer for small scale farmers, the processes and apparatus allow sustainable liquid fuel production.Type: GrantFiled: September 5, 2012Date of Patent: July 23, 2013Inventor: Antonio Cantizani
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Patent number: 8475726Abstract: A reactor (6) for pyrolysing waste, in particular rubber tires, said reactor comprising a pyrolysis space (68), an inlet port (63) and an outlet port (64) enabling a flow across the pyrolysis space (68) of a heating medium for transferring heat required for the pyrolysis, and a lower discharge port (62) for discharging solid residues of the pyrolysis. The invention is, characterized in that—it comprises a baffle means (65) made of a plate material and enabling a gravitational slipping of the solid residues towards the discharge port (62), which baffle means (65) has openings (66) allowing the flow of the heating medium and is arranged to divide the inner space of the reactor (6) to form an upper pyrolysis space (68) and a lower space and—one of the inlet and outlet ports (63, 64) is in connection with the pyrolysis space (68) and the other one with the lower space. The invention is also an apparatus comprising the above reactor (6).Type: GrantFiled: August 16, 2007Date of Patent: July 2, 2013Assignee: Pirolisis Project Kft.Inventors: András Bence Balint, Péter Varga, László Nagy, Sándor Demeter, Iván Pál Fodor
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Patent number: 8475552Abstract: In accordance with one embodiment, a system includes a posimetric pump configured to increase pressure of a feedstock to provide a pressurized feedstock. The system also includes a fixed bed gasifier configured to gasify the pressurized feedstock, wherein the fixed bed gasifier comprises an enclosure, a feedstock inlet configured to receive the pressurized feedstock, at least one agent inlet configured to receive at least one gasification agent, a syngas outlet configured to output a syngas, an ash outlet configured to output ash, and a fixed bed configured to support the pressurized feedstock while allowing flow of the at least one gasification agent through the pressurized feedstock.Type: GrantFiled: September 15, 2010Date of Patent: July 2, 2013Assignee: General Electric CompanyInventors: Richard Anthony DePuy, Derek Leslie Aldred
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Patent number: 8465705Abstract: Process for the removal/reduction of the hydrogen sulfide contained in natural gas which comprises: a) feeding natural gas and water to a reaction vessel maintained under thermodynamic conditions favorable for the formation of H2S hydrates and substantially at the production pressure of natural gas; b) discharging the H2S hydrates, from the bottom of the reaction vessel; c) optionally melting the hydrates and re-injecting water and/or gas comprising hydrogen sulfide and/or the hydrates as such into the same production field or into a geologically equivalent structure; and d) optionally feeding the remaining natural gas to a conventional softening process.Type: GrantFiled: June 15, 2005Date of Patent: June 18, 2013Assignee: ENI S.p.A.Inventors: Liberato Giampaolo Ciccarelli, Gian Paolo Borghi
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Patent number: 8454355Abstract: A burning device is provided for fuel cell to be run under high temperature. The burning device uses a specific-designed fuel spraying device having porous medium. The burning device can be used under different statuses of flow in the fuel cell. With the burning device, the fuel cell has improved efficiency by enhancing recycling of system heat and pollution of discharged waste gas is reduced.Type: GrantFiled: March 9, 2010Date of Patent: June 4, 2013Assignee: Atomic Energy Council—Institute of Nuclear Energy ResearchInventors: Yu-Ching Tsai, Tzu-Hsiang Yen, Wen-Tang Hong, Cheng-Nan Huang, Hung-Yu Wang, Wei-Ping Huang, Chien-Hsiung Lee
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Publication number: 20130129569Abstract: A reactor for the gasification of biomass having a reactor vessel that defines a gasification chamber with an oxidation zone, to which oxidation zone an oxygen containing gasification agent, in particular air, may be supplied from outside of the reactor vessel, wherein biomass may be continuously transported to the oxidation zone in the gasification chamber, wherein air supply elements having exit openings in the area of the oxidation zone are arranged in the reactor vessel, which extend in the transport direction of the biomass. The air supply elements are each configured in lance form and provided along at least one insulation section with an external insulation layer.Type: ApplicationFiled: July 5, 2010Publication date: May 23, 2013Inventor: Erwin Schiefer
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Patent number: 8420703Abstract: The purpose of the present invention is to provide a method for collecting effective components from polyester fiber waste containing polyalkylene telephthalate as the main component, more specifically to provide a method for separating and removing foreign matters (mainly cotton) contained in polyester fiber waste. The purpose of the invention can be achieved by a method for separating and removing foreign matters from polyester waste, which includes throwing polyester fiber waste that contains polyalkylene telephthalate as the main component and foreign matters other than the polyalkylene telephthalate into a depolymerization reaction tank, subjecting a part or all of the polyester fiber to a depolymerization reaction with alkylene glycol to give a depolymerization reaction liquid, and then continuously or intermittently feeding the liquid to a foreign matter-separating and removing apparatus having specified characteristics.Type: GrantFiled: February 19, 2008Date of Patent: April 16, 2013Assignee: Teijin Fibers LimitedInventors: Kouji Mukai, Minoru Nakashima
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Patent number: 8388902Abstract: A method for regenerating activated coke used for treating wastewater or sewage is provided. The method includes loading the activated coke to an environment under 150 to 250° C., heating the activated coke to a temperature of 700 to 850° C. for about 40 to 90 minutes; and providing a steam to the activated coke with a rate of 0.1 to 0.5 m3/(ton of activated coke). When the activated coke is being heated at the temperature, it generates a gas mixture including a steam portion and at least a paraffine gas. The gas mixture flows along a reverse direction relative to a flow of cooling water, so that the steam portion is converted into a part of the cooling water for recycling. The paraffine gas is used as a fuel. An apparatus for regenerating the activated coke used for treating wastewater or sewage is also provided.Type: GrantFiled: December 16, 2008Date of Patent: March 5, 2013Assignees: Dawei Zhang, Mississippi International Water, Inc.Inventor: Dawei Zhang
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Patent number: 8377387Abstract: A system includes a fluidization device including a flow passage configured to convey a flow of solid fuel particles in a downstream direction, and a body disposed within the flow passage. The body is configured to direct the flow of solid fuel particles between the body and an outer wall of the flow passage. The fluidization device also includes a carrier gas injection port positioned radially outward from the body. The carrier gas injection port is configured to provide a flow of carrier gas in the downstream direction to break up agglomerations within the flow of solid fuel particles.Type: GrantFiled: June 23, 2010Date of Patent: February 19, 2013Assignee: General Electric CompanyInventors: Constantin Dinu, Steven Craig Russell, Yichuan Fang
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Patent number: 8362160Abstract: The present invention relates to methods for delivering granulated material to a reactor for use in the polymerization of alpha-olefin comprising the steps of: providing a first conduit having a granulated material inlet, the conduit being operably connected to a pocket ball valve comprising at least one pocket, said pocket ball valve being operably connected to a second conduit, said second conduit being operably connected to a polymerization reactor; introducing a granulated material to the first conduit through said inlet; metering the granulated material through the pocket ball valve; and passing said material through the second conduit to the polymerization reactor. The present invention also relates to polyolefin production processes and polyolefin producing units.Type: GrantFiled: September 26, 2008Date of Patent: January 29, 2013Assignee: Total Petrochemicals Research FeluyInventors: Yahya Bouquoyoue, Claude Queyrel
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Publication number: 20120322649Abstract: Processes and apparatuses for regenerating catalyst particles are provided. The processes include introducing spent catalyst particles to a burn zone in a continuous catalyst regenerator. When introduced, the catalyst particles, which contain a platinum group metal, carry coke deposits. In the process, a combustion gas at a temperature of at least 490° C. with an oxygen content of at least 0.5 mol % is fed to the burn zone. There, the coke deposits on the catalyst particles are combusted with the combustion gas. The catalyst particles are passed from the burn zone to a halogenation zone in the continuous catalyst regenerator and the catalyst particles are oxyhalogenated to redisperse the platinum group metal to form regenerated catalyst particles.Type: ApplicationFiled: June 17, 2011Publication date: December 20, 2012Applicant: UOP LLCInventors: Michael A. Moore, Paul A. Sechrist, Bryan K. Glover
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Patent number: 8313715Abstract: A process for producing metal oxide from metal salts includes cleaning a metal salt in a filter. After cleaning, the metal salt is dried in a drying apparatus. Steam is formed in the drying apparatus. The metal salt is preheated in at least one preheating stage. The metal salt is calcined to metal oxide in a fluidized-bed reactor. The metal oxide is cooled. The steam formed in the drying apparatus is recirculated into the filter.Type: GrantFiled: January 14, 2010Date of Patent: November 20, 2012Assignee: Outotec OyjInventors: Michael Missalla, Guenter Schneider, Jan Jarzembowski, Erwin Schmidbauer
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Publication number: 20120251408Abstract: A system to provide a particulate solid material to a pressurised gasification reactor includes a low pressure storage vessel fluidly connected to the inlet of a bulk materials pump, a first part of a transport conduit directly connecting the outlet of the bulk materials pump to an inlet of a diverter valve, a second part of the transport conduit connecting an outlet of the diverter valve to a burner as present in a reactor vessel, wherein said diverter valve is provided with a second outlet connecting a recycle conduit with the low pressure storage vessel and which diverter valve is adjustable to either fluidly connect the bulk materials pump to the burner or alternatively fluidly connect the bulk materials pump to the low pressure storage vessel.Type: ApplicationFiled: April 18, 2012Publication date: October 4, 2012Applicant: SHELL OIL COMPANYInventor: Govert Gerardus Pieter VAN DER PLOEG
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Patent number: 8263014Abstract: In an apparatus and method of generating a carbon nanotube (CNT), a process chamber is heated to a target temperature and a catalyst powder is supplied into the heated process chamber. The catalyst powder moves in a first direction in the process chamber. A source gas is supplied into the process chamber in a second direction opposite to the first direction, so that the source gas delays the movement of the catalyst powder in the first direction and is reacted with the catalyst powder in the process chamber to thereby produce the CNT in the process chamber. Accordingly, the flow of the source gas against the flow of the catalyst powder reduces the drop velocity of the catalyst powder. Therefore, the source gas and the catalyst powder may be reacted with each other for a sufficiently long time.Type: GrantFiled: November 30, 2010Date of Patent: September 11, 2012Assignee: Korea Kumho Petrochemical Co., Ltd.Inventors: Suk-Won Jang, Byung-Yun Kong, Chung-Heon Jeong
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Publication number: 20120213691Abstract: According to one embodiment, there is provided a graphite nano-carbon fiber provided by using an apparatus having a reactor capable of keeping a reducing atmosphere inside thereof, a metal substrate arranged as a catalyst in the reactor, a heater heating the metal substrate, a pyrolysis gas source supplying pyrolysis gas obtained by thermally decomposing a wood material in a reducing atmosphere to the reactor, a scraper scraping carbon fibers produced on the metal substrate, a recovery container recovering the scraped carbon fibers, and an exhaust pump discharging exhaust gas from the reactor. The carbon fibers are linear carbon fibers with a diameter of 25 to 250 nm formed with layers of graphenes stacked in a longitudinal direction.Type: ApplicationFiled: August 5, 2011Publication date: August 23, 2012Applicant: KABUSHIKI KAISHA TOSHIBAInventors: Katsuki Ide, Tetsuya Mine, Jun Yoshikawa, Tsuyoshi Noma, Masao Kon, Kazutaka Kojo
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Patent number: 8241583Abstract: A process for cracking a hydrocarbon feed in a reactor assembly comprising: a reactor vessel; a solid catalyst inlet by which catalyst is introduced and a solid catalyst outlet by which catalyst is removed from the reactor vessel; a plurality of feed nozzles by which feed is introduced at the bottom of the vessel; a product outlet for removing a product mixture of gas and solid catalyst at the upper part of the reactor; at least one partition plate, that divides the interior of the reactor vessel into two or more compartments, wherein the partition plate intersects the solid catalyst inlet.Type: GrantFiled: March 5, 2009Date of Patent: August 14, 2012Assignee: Shell Oil CompanyInventors: Hubertus Wilhelmus Albertus Dries, Rene Samson
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Patent number: 8236247Abstract: Material withdrawal apparatus, methods, and systems of regulating material inventory in one or more units are provided. A material withdrawal apparatus includes a heat exchanger and transport medium junction configured to provide transport medium to transport the withdrawn material from the unit to the heat exchanger. Another material withdrawal apparatus includes a heat exchanger and shock coolant junction configured to provide shock coolant to the material withdrawn from the unit. Another material withdrawal apparatus includes a heat exchanger, shock coolant junction, and transport medium junction. Another embodiment of a material withdrawal apparatus includes a vessel and shock coolant junction. Another material withdrawal apparatus includes a vessel and transport medium junction. The vessel includes a wall, liner with heat insulating refractory material, fill port, and a discharge port.Type: GrantFiled: December 23, 2009Date of Patent: August 7, 2012Assignee: Intercat Equipment, Inc.Inventors: Martin Evans, Ronald Butterfield
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Patent number: 8221695Abstract: A catalytically activated vacuum distillation system, several novel component parts of said system, a process for producing carbon based products and novel carbon black that is produced from such a system and process.Type: GrantFiled: September 16, 2010Date of Patent: July 17, 2012Inventors: Michael P Maskarinec, Bart M. Taylor
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Patent number: 8202485Abstract: Process for providing a flow of particulate matter to a reactor, by intermittently adding the particulate matter and a diluent to a mixing tank, and continuously withdrawing a slurry of particulate matter in diluent from the mixing tank for introduction into the reactor. Prior to each addition of particulate matter and diluent to the mixing tank, the concentration of particulate matter in the diluent already in the mixing tank is measured or calculated, and the amount of particulate matter and diluent subsequently added is measured so as to achieve the same concentration at the end of the addition as that measured or calculated prior to the addition.Type: GrantFiled: December 22, 2009Date of Patent: June 19, 2012Assignee: Ineos Manufacturing Belgium NVInventor: Brent Walworth