And Means Downstream Of A Stage For Internally Injecting A Reactant Into A Reaction Stream For Reaction In A Subsequent Stage, Or Injecting An Internal Quench Stream Into A Reaction Stream Passing Between Stages Patents (Class 422/647)
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Patent number: 9939114Abstract: Pipeline transport of hydrocarbons detect the moisture accumulation location along the pipeline and increase effectiveness of the drying process. Drying air moisture content reduction is obtained by the installing additional intermediate air drying devices in by-pass lines at block valve station along the pipeline to be dried. Purging is proceeded until normalized dew point temperature value of the outcoming air being achieved. Purging is interrupted for 12 hours or more, both upstream and downstream ends of pipeline leaving hermetically closed, and resumed with intermediate air drying devices disabled, continuously measuring the moisture content of the outcoming drying air, fixing the moment when the moisture accumulation in the surrounding air.Type: GrantFiled: December 11, 2014Date of Patent: April 10, 2018Assignee: PUBLICHNOE AKTSIONERNOE OBSCHESTVO “GAZPROM”Inventors: Dmitry Igorevich Shiryapov, Sergei Vsevolodovich Karpov, Aleksei Sergeevich Alikhashkin, Aleksandr Vasilyevich Elfimov
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Patent number: 9089826Abstract: A fluidized-bed reactor system with at least two fluidized-bed reactors, each being a circulating fluidized bed, a particle line with a particle separator for transferring fluidized-bed particles from the first to the second reactor, and a particle line exiting at the lower half of the second reactor for transferring fluidized-bed particles back to the first reactor, wherein, at least in the second reactor, two or more reaction zones separated by one or more flow controllers and that the particle line opens into the second reactor above at least one flow controller.Type: GrantFiled: June 8, 2011Date of Patent: July 28, 2015Assignee: TECHNISCHE UNIVERSITAT WIENInventors: Tobias Proell, Johannes Schmid, Christoph Pfeifer, Hermann Hofbauer
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Patent number: 9011790Abstract: A reactor for carrying out a three-phase reaction of a liquid phase, a gaseous phase, and a catalyst over a fixed catalyst bed is disclosed. The liquid and gaseous phases are passed through the reactor via a mixing and distribution device positioned over the fixed catalyst bed. The mixing and distribution device includes a trough distributor for the liquid phase, having trough-shaped channels, outlet tubes in the trough-shaped channels for the liquid phase, a distributor plate below the trough distributor, and vertical nozzles, having one or more openings for the gaseous phase and one or more openings, arranged below the openings for the gaseous phase. For entry of the liquid phase, the nozzles are installed so that, at a predetermined liquid feed rate, the surface of the liquid on the distributor plate is below the openings for the gaseous phase and above the openings for the liquid phase.Type: GrantFiled: June 20, 2008Date of Patent: April 21, 2015Assignee: BASF SEInventors: Stefan Iselborn, Andreas Daiss, Reiner Geier, Marcus Bechtel, Michael Wille, Benjamin Hepfer, John Sauter
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Patent number: 8865086Abstract: A quenching apparatus for a reactor is disclosed. The quenching apparatus includes a quenching unit (31) and a mixing unit (41). The quenching unit includes fluid distribution pipes (33) which branch off from a central portion of the quenching unit in radial directions and eject quenching fluid, and one or more first fluid outlets (35) which are formed through the bottom of the quenching unit. The mixing unit includes inclined baffles (43), one or more partitions (42) and a second fluid outlet (45). The inclined baffles are respectively disposed under the first fluid outlets. The partitions partition a space between inner and outer sidewalls of the mixing unit into a plurality of separated spaces in which the inclined baffles are respectively disposed. Fluid guided by the inclined baffles and the partitions is discharged out of the mixing unit through the second fluid outlet.Type: GrantFiled: December 29, 2009Date of Patent: October 21, 2014Assignee: SK Innovation Co., Ltd.Inventors: Tae Young Jang, Min Ki Ahn, Sun Hyuk Bae, Gyung Rok Kim, Yoon Mang Hwang, Kyoo Sung Park, Sun Choi, Myung Jun Kim
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Patent number: 8815961Abstract: The invention relates to a process for producing a methane-containing gas from synthesis gas, wherein a synthesis gas containing carbon monoxide and hydrogen is fed for methanation to a reactor system (1) having a catalyst material, wherein the process gas stream leaving the reactor system (1) is divided into a product gas stream and a recycle gas stream, and wherein the recycle gas stream, for compensation of the pressure drop, is transported through an ejector (5) and for cooling is passed together with the synthesis gas into the reactor system (1). According to the invention, the product gas stream is compressed to a pressure which is greater than the pressure of the synthesis gas that is fed to the reactor system (1). Either compressed product gas or industrial gas from an industrial gas pipe system (9) is fed as propellant medium to the ejector (5). The invention also relates to a methane production plant for carrying out the process.Type: GrantFiled: July 12, 2011Date of Patent: August 26, 2014Assignee: Thyssenkrupp Uhde GmbHInventors: Johannes Menzel, Holger Thielert
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Patent number: 8609913Abstract: An axial flow staged zone oligomerization reaction process includes the steps of passing a hydrocarbon feedstock into the lower portion of the axial flow staged zone reactor which includes axial circulation of the hydrocarbon reaction fluid serially in each of the reaction zones, passing catalyst through a constriction zone located between successive upper and lower catalytic reaction zones which includes heat exchanging of the fluids being the constriction zone within the reactor and further includes withdrawing the oligomerized product from the top of the reactor.Type: GrantFiled: October 2, 2009Date of Patent: December 17, 2013Assignee: IFP Energies NouvellesInventors: Sylvain Louret, Patrice Font, Sylvie Lacombe, Eric Sanchez, Laurent Simon
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Patent number: 8518366Abstract: The present invention relates to a process and a device for the combustion of sulphur and/or sulphur-containing compounds, via which a sufficient production of SO2-containing gases having a high SO2 concentration is made possible. The combustion preferably proceeds using a combustion gas which has an oxygen fraction at least as high as air, but preferably a higher fraction of oxygen. The process and the device should be suitable, in particular, for providing sulphur dioxide as a source for further production of sulphuric acid or highly concentrated SO3-containing gases. In addition, the device and the process should be suitable for oxidizing hydrogen-sulphide-containing gases, such as occur, for example, in the refinery industry, in high concentrations to SO2.Type: GrantFiled: October 28, 2010Date of Patent: August 27, 2013Assignee: Bayer Intellectual Property GmbHInventors: Dieter Förtsch, Martin Kürten
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Patent number: 8377156Abstract: The present subject matter is directed to a method for operating a fuel reformer. The method may generally include directing a fluid stream around a reactor assembly of the fuel reformer to cool the reactor assembly, and mixing a heated reformate stream produced by the reactor assembly with the fluid stream to cool the heated reformate stream.Type: GrantFiled: August 3, 2012Date of Patent: February 19, 2013Assignee: General Electric CompanyInventors: Jonathan Dwight Berry, Hasan Karim, Abdul Rafey Khan
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Patent number: 8337787Abstract: A compact device for mixing fluids in a downflow reactor comprising at least one substantially horizontal gathering device provided with a vertical gathering line intended to receive the fluids, at least one injection device arranged in the gathering line, an annular mixing chamber located downstream from the gathering means in the direction of circulation of the fluids, the mixing chamber comprising an inlet end directly connected to the gathering line and an outlet end for passage of the fluids, and a horizontal predistribution plate comprising at least one chimney, the plate being located downstream from the mixing chamber at a distance d2, in the direction of circulation of the fluids. The reactor is especially useful for exothermic reactions, e.g. hydrotreatment, hydrodesulfurization, hydrodenitrogenation, hydrocracking, hydrogenation and hydrodearomatization reactions.Type: GrantFiled: November 19, 2010Date of Patent: December 25, 2012Assignee: IFP Energies NouvellesInventors: Frederic Augier, Denis Darmancier, Christophe Boyer
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Patent number: 8323591Abstract: One exemplary embodiment can be a method of fabricating a mixing chamber in a hydroprocessing reactor. The method can include providing a first section forming an opening and coupling a second section including a sidewall to the first section. The second section forms a flange for coupling the mixing chamber and facilitating the mixing of one or more fluids.Type: GrantFiled: April 21, 2011Date of Patent: December 4, 2012Assignee: UOP LLCInventors: Sailesh B. Kumar, Robert L. Bunting
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Patent number: 8302672Abstract: Plate type heat exchanger (20,120) for a isothermal chemical reactor (60), of the type comprising a substantially box-shaped flattened body (22), defining an internal chamber (24) and equipped with an inlet connection (28) and an outlet connection (29) for a first flow of a heat exchanger operative fluid into and from said chamber (24), at least one supplying-distributing device (26, 126) of a second fluid flow, associated with said body (22) and in fluid communication with the internal chamber (24) thereof, in order to regulate the temperature of said operative fluid, said at least one supplying-distributing device (26,126) being supported inside said internal chamber (24) and in fluid communication therewith.Type: GrantFiled: October 31, 2006Date of Patent: November 6, 2012Assignee: Methanol Casale S.A.Inventors: Ermanno Filippi, Enrico Rizzi, Mirco Tarozzo, Luca Zanichelli
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Patent number: 8282891Abstract: The instant application provides apparatus and methods for the generation of gas, preferably chlorine dioxide. The methods and apparatus of the invention use a removable reaction chamber for the reaction of precursor chemicals, e.g., chlorite salt and an acid. The methods and compositions of the invention provide gas for a number of personal and commercial applications.Type: GrantFiled: July 1, 2010Date of Patent: October 9, 2012Assignee: TBS Technologies, LLCInventors: Thomas J. Dee, Paul Sabin, Douglas Sabin
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Patent number: 8257668Abstract: A hydrogen generator according to the invention comprises: a combustion gas passage (5) configured to flow combustion gas coming from a combustor; a preheat-evaporator (6) which is supplied with a material gas and water and configured to evaporate the water and heat the material gas by heat transmitted from the combustion gas passage and a carbon monoxide reducer (10) through partition a wall; a reformer (7) configured to generate reformed gas from the material gas and steam fed from the preheat-evaporator by using a reforming catalyst (8) and heat transmitted from the combustion gas passage through the partition wall; the carbon monoxide reducer (10) configured to remove carbon monoxide from the reformed gas fed from the reformer by a carbon monoxide removing catalyst (9); a cylindrical body (3) closed at both ends thereof having an internal space is divided by the partition walls (1), (2), (30), (47) to form the combustion gas passage, preheat-evaporator, reformer and carbon monoxide reducer within the cyliType: GrantFiled: September 3, 2007Date of Patent: September 4, 2012Assignee: Panasonic CorporationInventors: Yuji Mukai, Akira Maenishi, Kunihiro Ukai, Toru Nakamura
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Patent number: 8252251Abstract: The present subject matter discloses a fluid cooled reformer for gas turbine systems and a method for cooling both a fuel reformer and a heated reformate stream produced by such fuel reformer. The fluid cooled reformer may include a pressure vessel and a reactor assembly disposed within the pressure vessel. The reactor assembly may include a reactor and may be configured to receive and reform an oxygen/fuel mixture to produce a heated reformate stream. Additionally, the fluid cooled reformer may include an inlet configured to direct a fluid stream into the pressure vessel. At least a portion of the fluid stream may be used to cool the reactor assembly. A reformate cooling section may be disposed downstream of the reactor of the reactor assembly and may be configured to cool the heated reformate stream.Type: GrantFiled: March 30, 2010Date of Patent: August 28, 2012Assignee: General Electric CompanyInventors: Jonathan Dwight Berry, Hasan Karim, Abdul Rafey Khan
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Patent number: 8236071Abstract: A quench ring for use with a gasifier system. The quench ring including an annular manifold having a radius, an annular channel coupled in flow communication with said manifold, and at least one inlet coupled in flow communication with said manifold, said at least one inlet having a center line aligned substantially tangentially to said annular manifold.Type: GrantFiled: August 15, 2007Date of Patent: August 7, 2012Assignee: General Electric CompanyInventors: Judeth Helen Brannon Corry, Yulianto Salahuddin Mohsin
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Patent number: 8202499Abstract: A small cylindrical reformer having at least a combustion reaction unit and a fuel-converting catalytic reaction unit wherein the combustion reaction unit and the fuel-converting catalytic reaction unit are structured as six cylindrical pipes to realize optimal heat exchange efficiently, a route supplying a water gas shift reformate to a preferential oxidation reactor and a route supplying feed and water into reforming reaction parts from the feed/water inlet overlap each other at a lower portion of the reformer so as to increase heat transfer efficiency, and a preferential oxidation reactor provided outside the fuel-converting catalytic reaction unit to decrease the concentration of carbon monoxide in the water gas shift reformate to a predetermined level or lower and increase heat transfer efficiency with an air/fuel preheating passage communicating with the air/fuel inlet.Type: GrantFiled: December 28, 2010Date of Patent: June 19, 2012Assignee: SK Energy Co., Ltd.Inventors: Tae Woo Woo, Young Seek Yoon, Seong Ho Lee, Il Su Kim, Keun Seob Choi
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Patent number: 8192688Abstract: A thermally diluted exothermic reactor system is comprised of numerous orifices distributed within a combustor by distributed perforated contactor tubes or ducts. The perforated contactors deliver and mix diluent fluid and one or more reactant fluids with an oxidant fluid. Numerous micro-jets about the perforated tubes deliver, mix and control the composition of reactant fluid, oxidant fluid and diluent fluid. The reactor controls one or more of composition profiles, composition ratio profiles and temperature profiles in one or more of the axial direction and one or two transverse directions, reduces temperature gradients and improves power, efficiency and emissions.Type: GrantFiled: March 26, 2009Date of Patent: June 5, 2012Assignee: Vast Power Portfolio LLCInventors: David L. Hagen, Gary Ginter, Bill Goheen, L. Allan McGuire, Janet Rankin
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Patent number: 8168131Abstract: A syngas reforming reactor has a shell-and-tube configuration wherein the shell-side fluid flow path through the tube bundle has a longitudinal configuration. The reactor can include a shell-side inlet fluid distributor plate below the lower end of the tube bundle.Type: GrantFiled: November 9, 2009Date of Patent: May 1, 2012Assignee: Kellog Brown & Root LLCInventors: Robert Stevens Burlingame, Lloyd Edward Cizmar, Larry Gene Hackemesser, Laura Beth Aguilar
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Patent number: 8057641Abstract: A method and apparatus for effective pyrolysis of a biomass utilizing rapid heat transfer from a solid heat carrier or catalyst. Particularly, various embodiments of the present invention provide methods and apparatuses which incorporate progressive temperature quenching and rapid disengagement of the heat carrier material and reaction product.Type: GrantFiled: July 19, 2010Date of Patent: November 15, 2011Assignee: Kior Inc.Inventors: Robert Bartek, Ronald Lee Cordle
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Patent number: 8057747Abstract: The invention provides a method and apparatus for integrating the heat transfer zones of plate fin and tube and finned tube exchangers and a catalytic mass transfer zone. The invention also provides a method for in situ regeneration of existing coated surface and augmentation of existing coated surface, or catalyst performance.Type: GrantFiled: October 26, 2009Date of Patent: November 15, 2011Assignee: SME Products, LPInventors: Larry Lewis, Jeff Diaz
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Patent number: 8052946Abstract: A system and process for upgrading hydrocarbons such as heavy oils includes a high temperature plasma reactor apparatus, in one or more vessels, into which the oils are introduced along with water, such as steam, to produce lighter hydrocarbon fractions, along with carbon monoxide and hydrogen, that flows to an additional stage where more hydrocarbons and water are introduced for further fractionating reactions facilitated by reaction of carbon monoxide and water to produce carbon dioxide and nascent, or prompt, free radicals of hydrogen. Heavy hydrocarbons upgraded can include heavy oils in the form of tar sands, oil shale, and oil residuals. The vessel or vessels can each contain a carbonaceous bed facilitating the described reactions and example embodiments include one vessel with the reactions performed in a single bed and, also, two vessels with the reactions performed in a carbonaceous bed portion in each vessel.Type: GrantFiled: October 27, 2009Date of Patent: November 8, 2011Assignee: Westinghouse Plasma CorporationInventors: Shyam V. Dighe, Mark Anthony Montemurro, Richard Dale Bower, Aleksandr Gorodetsky, Mark F. Darr, Ivan A. Martorell
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Patent number: 8029748Abstract: The invention provides methods, apparatus and chemical systems for making vinyl acetate from ethylene, oxygen, and acetic acid.Type: GrantFiled: November 18, 2008Date of Patent: October 4, 2011Assignees: Velocys, Inc, Celanese International CorporationInventors: Terry Mazanec, Victor J. Johnston, Michael Huckman, Sean P. Fitzgerald, James A. Foster, Daniel Lindley, Anna Lee Tonkovich, Francis P. Daly, Leslie Wade, Tony Hammock, Thomas Yuschak, Bin Yang, Kai Jarosch
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Patent number: 8029738Abstract: Methods and devices for removing inflammable gases produced by radiolysis in a closed chamber containing radioactive matters comprising organic compounds and possibly water, or radioactive matters in the presence of organic compounds and possibly water. Inside the chamber there may be placed a catalyst of at least one reaction for oxidizing the inflammable gases by oxygen contained in the chamber atmosphere, supported by an inert solid support; a catalyst of at least the reaction for oxidizing CO to CO2; possibly an oxygen source; and possibly a hygroscopic microporous inert solid support. Also, chambers for radioactive matters containing such devices.Type: GrantFiled: January 6, 2010Date of Patent: October 4, 2011Assignee: TN InternationalInventors: Pascale Abadie, Herve Issard
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Patent number: 8017095Abstract: The present invention provides a novel means to provide more effective mixing of gas and fluids in a height constrained interbed space of a catalytic reactor without increasing pressure drop. In particular, the device improves the effectiveness of an existing mixing volume in mixing the gas phase and liquid phase of two-phase systems. According to the present invention, the mixing device helps create a highly arcuate flow to incoming effluents and a high degree of mixing within a constrained interbed space of a catalytic reactor.Type: GrantFiled: May 29, 2009Date of Patent: September 13, 2011Assignee: Chevron U.S.A. Inc.Inventors: Abdenour Kemoun, Steven X. Song
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Patent number: 8012436Abstract: A quenching vessel being, in use, vertically elongated and provided with an inlet for gas at its upper end, an outlet for cooled gas at its lower end defining a pathway for a gas flow directed downwardly, the vessel being provided at its upper end with a first internal tubular wall part which wall part has an opening fluidly connected to the inlet for gas and wherein the tubular wall part is connected at its lower end with a divergent conical part having walls which are inclined outwardly in the direction of the pathway for gas, wherein an arrangement of more than one nozzle for atomisation and spraying a liquid quench medium in a downward direction into the pathway for the gas flow are present in the space enclosed by the divergent conical part.Type: GrantFiled: September 4, 2008Date of Patent: September 6, 2011Assignee: Shell Oil CompanyInventors: Robert Van Den Berg, Wouter Koen Harteveld, Hans Joachim Heinen, Thomas Paul Von Kossak-Glowczewski
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Patent number: 7959880Abstract: The present invention includes methods and apparatuses for producing hydrogen peroxide using microchannel technology. An exemplary process for producing hydrogen peroxide comprises flowing feed streams into intimate fluid communication with one another within a process microchannel to form a reactant mixture stream comprising a hydrogen source and an oxygen source such as, without limitation, hydrogen gas and oxygen gas. Thereafter, a catalyst is contacted by the reactant mixture and is operative to convert a majority of the reactant mixture to hydrogen peroxide that is withdrawn via an egressing product stream. During the hydrogen peroxide chemical reaction, exothermic energy is generated and absorbed by the fluid within the microchannel as well as the microchannel itself.Type: GrantFiled: June 11, 2008Date of Patent: June 14, 2011Assignee: Velocys, Inc.Inventors: Anna Lee Y. Tonkovich, Bin Yang, William Allen Rogers, Jr., Paul William Neagle, Sean P. Fitzgerald, Kai Tod Paul Jarosch, Dongming Qiu, David J. Hesse, Micheal Lamont