Reaction Stages Located Within Single Reaction Chamber Patents (Class 422/644)
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Publication number: 20150137041Abstract: A fixed bed gasification system to convert solid organic matter (also called biomass), into synthesis gas. This gas can be burned in an engine, turbine, oven or boiler, which makes it possible to valorize the thermal energy that it harbors.Type: ApplicationFiled: December 27, 2012Publication date: May 21, 2015Inventors: Louis Rousseau, Etienne Lebas, Christian Bedrossian, Bruno Da Silva
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Patent number: 9028766Abstract: A radial-flow plate heat exchanger (5) embedded in the catalytic bed of an isothermal chemical reactor (1) has heat exchange plates (10) comprising fluid passages (13) between a first metal sheet (20) and a second metal sheet (21) joined by perimeter weld seams (23) on a first surface (A) of the plate, a feeding channel (14) and a collecting channel (15) for the heat exchange fluid are formed with suitable metal sheets which are seam welded (25) directly to the opposite surface (B) of the plate, this structure allows the manufacturing of the plate (10) with an automated seam welding process, such as laser beam welding.Type: GrantFiled: July 7, 2010Date of Patent: May 12, 2015Assignee: Casale SAInventors: Enrico Rizzi, Ermanno Filippi, Mirco Tarozzo
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Publication number: 20150126628Abstract: An apparatus and a method for producing chemicals from a methane-containing gas are provided. More specifically, the method and an apparatus make use of heterogeneous catalysis, beginning with the partial oxidation of methane to produce synthesis gas followed by a reaction, such as a Fischer-Tropsch reaction, to produce the chemicals.Type: ApplicationFiled: November 4, 2014Publication date: May 7, 2015Inventors: GREGORY PATIENCE, DARIA CAMILLA BOFFITO
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Patent number: 9023299Abstract: A liquid/gas reactor includes a bulk catalyst bed and means for supplying fresh feed and recycled at least partially converted liquid product stream to the bulk catalyst bed. The reactor also includes means for collecting an at least partially converted liquid product stream from the bulk catalyst bed and recycling at least a portion thereto. A minor catalyst bed extends substantially vertically through the bulk catalyst bed. Means for supplying recycled at least partially converted product stream only to the minor catalyst bed is also provided. A separating wall is disposed between the bulk catalyst bed and the minor catalyst bed.Type: GrantFiled: January 12, 2012Date of Patent: May 5, 2015Assignee: Davy Process Technology LimitedInventors: Edward Adrian Lord, Arthur James Reason
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Patent number: 9023297Abstract: A plant for preparing monosilane (SiH4) by catalytic disproportionation of trichlorosilane (SiHCl3) includes a reaction column having a feed line for trichlorosilane and a discharge line for silicon tetrachloride (SiCl4) formed, and at least one condenser via which monosilane produced can be discharged from the reaction column, wherein the reaction column has at least two reactive/distillative reaction regions operated at different temperatures and containing different catalytically active solids, at least one of the reaction regions containing a catalytically active solid based on vinylpyridine, and at least one of the reaction regions containing a catalytically active solid based on styrene.Type: GrantFiled: July 7, 2010Date of Patent: May 5, 2015Assignee: Schmid Silicon Technology GmbHInventors: Adolf Petrik, Christian Schmid, Jochem Hahn
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Patent number: 9011790Abstract: A reactor for carrying out a three-phase reaction of a liquid phase, a gaseous phase, and a catalyst over a fixed catalyst bed is disclosed. The liquid and gaseous phases are passed through the reactor via a mixing and distribution device positioned over the fixed catalyst bed. The mixing and distribution device includes a trough distributor for the liquid phase, having trough-shaped channels, outlet tubes in the trough-shaped channels for the liquid phase, a distributor plate below the trough distributor, and vertical nozzles, having one or more openings for the gaseous phase and one or more openings, arranged below the openings for the gaseous phase. For entry of the liquid phase, the nozzles are installed so that, at a predetermined liquid feed rate, the surface of the liquid on the distributor plate is below the openings for the gaseous phase and above the openings for the liquid phase.Type: GrantFiled: June 20, 2008Date of Patent: April 21, 2015Assignee: BASF SEInventors: Stefan Iselborn, Andreas Daiss, Reiner Geier, Marcus Bechtel, Michael Wille, Benjamin Hepfer, John Sauter
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Publication number: 20150051367Abstract: Disclosed are processes and systems for manufacturing polyethylene terephthalate (PET) and pre-polymer. The processes and systems use a variable pressure drop up-flow-pre-polymerizer configuration. The pressure profile in the UFPP can be selected to beneficially change the relative reaction rates of the polymerization and esterification reactions. This design maximizes the esterification carried out in the UFPP, while still producing a pre-polymer with the optimum carboxyl end groups concentration (e.g., about 30? equiv./g to 60? equiv./g) to maximize finisher productivity. This can result in a reduction of the size and cost of the esterifier required for a given plant throughput.Type: ApplicationFiled: June 4, 2012Publication date: February 19, 2015Inventor: Clive Alexander Hamilton
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Publication number: 20140163260Abstract: Method and a reactor for performing exothermic catalytic reactions. The method comprises the steps of providing a feed gas stream comprising reactants for the exothermic catalytic reaction to a fixed bed catalytic reactor comprising one or more catalyst beds each with catalyst particles filled sections with a catalyst volume; providing a feed gas bypass inside the reactor by arranging within at least one of the catalyst beds a number of bypass passageways without catalytic active particles inside the passageways and having a cooling surface area; passing a part of the feed gas stream through the bypass passageways and reminder of the stream through the catalyst particles filled sections; and removing heat from the feed gas stream being passed through the catalyst filled sections by indirect heat transfer to the part of the feed gas stream being passed through the bypass passageways.Type: ApplicationFiled: June 15, 2012Publication date: June 12, 2014Applicant: Haldor Topso A/SInventor: Max Thorhauge
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Publication number: 20140148623Abstract: The invention provides for methods, compositions and systems using bioisoprene derived from renewable carbon for production of a variety of hydrocarbon fuels and fuel additives.Type: ApplicationFiled: April 26, 2013Publication date: May 29, 2014Applicant: DANISCO US INC.Inventor: Danisco US Inc.
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Patent number: 8696773Abstract: In a reforming apparatus, for use in a fuel cell, for reforming a raw fuel into a hydrogen-rich reformed gas, a reformer generates the reformed gas from the raw fuel. A shift reactor reduces carbon monoxide contained in the reformed gas through a shift reaction. A selective oxidation unit reduces the carbon monoxide contained in the reformed gas that has passed through the shift reactor by performing selective oxidation on the carbon monoxide. A reforming reaction tube houses linearly the reformer, the shift reactor and the selective oxidation unit in this order.Type: GrantFiled: March 27, 2012Date of Patent: April 15, 2014Assignee: JX Nippon Oil & Energy CorporationInventors: Akira Fuju, Masataka Kadowaki, Kazumi Kobayashi, Kazuaki Nakajima, Yasushi Sato, Ken Samura
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Patent number: 8697016Abstract: A reactor in the form of an essentially horizontal cylinder for carrying out an autothermal gas-phase dehydrogenation of a hydrocarbon-comprising gas stream by means of an oxygen-comprising gas stream to give a reaction gas mixture over a heterogeneous catalyst configured as monolith is disclosed herein. The interior of the reactor is divided by a detachable, cylindrical or prismatic housing which is arranged in the longitudinal direction of the reactor, gastight in the circumferential direction and open at two end faces of the housing into an inner region, having one or more catalytically active zones. In each case, a packing composed of monoliths may be stacked on top of one another, next to one another, and above one another and before each catalytically active zone. Also in each case, a mixing zone having solid internals and an outer region arranged coaxially to the inner region are provided.Type: GrantFiled: December 1, 2010Date of Patent: April 15, 2014Assignee: BASF SEInventors: Grigorios Kolios, Wilhelm Ruppel, Ulrike Wegerle, Jasmina Kessel, Wolfgang Gerlinger, Godwind Tafara Peter Mabande, Goetz-Peter Schindler, Albena Kostova, Gerhard Olbert, Peter Pfab
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Patent number: 8691156Abstract: A preferential oxidation reactor for removing carbon monoxide in a hydrogen mixture gas is disclosed. The preferential oxidation reactor may include a housing having a catalytic layer provided therein, a mixture gas supply portion inserted into the interior of the housing and penetrating the catalytic layer, a condensate receiving portion contained within the housing and in fluid communication with a gas outlet port of the mixture gas supply portion and condensate control tubes arranged in the catalytic layer of the housing and in fluid communication with the condensate receiving portion. The condensate control tubes may have a capillary structure. A fuel cell system including the preferential oxidation reactor is also disclosed.Type: GrantFiled: December 1, 2010Date of Patent: April 8, 2014Assignee: Samsung SDI Co., Ltd.Inventors: Jong-Rock Choi, In-Hyuk Son, Jin-Goo Ahn, Woo-Cheol Shin, In-Seob Song
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Patent number: 8673245Abstract: A fixed-bed reactor containing a first catalyst layer filled with a first catalyst for producing acrolein from propylene; a second catalyst layer filled with a second catalyst for producing acrylic acid from acrolein; and an inert substance layer provided between the first catalyst layer and the second catalyst layer, and filled with an inert substance of a cylindrical shape having a surrounding wall in which an opening is formed. A process for producing acrylic acid containing the step of producing acrylic acid from propylene by using the aforementioned fixed-bed reactor.Type: GrantFiled: September 9, 2009Date of Patent: March 18, 2014Assignee: Nippon Shokubai Co., Ltd.Inventors: Michio Tanimoto, Nobuyuki Hakozaki
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Patent number: 8617265Abstract: A method and apparatus for generation of hydrogen. The apparatus includes a hydrogen reactor chamber (99) and a plurality of catalysts within the chamber (99) forming distinct zones or portions (200, 202, and 204), each zone or portion comprising a distinct catalyst or combination thereof. The plurality of catalysts include at least one of a high-activity steam reformation catalyst, coke resistant steam reformation catalyst and steam reformation catalyst that promotes a water gas shift reaction.Type: GrantFiled: April 12, 2005Date of Patent: December 31, 2013Assignee: Intelligent Energy, Inc.Inventor: Anand Chellappa
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Patent number: 8609913Abstract: An axial flow staged zone oligomerization reaction process includes the steps of passing a hydrocarbon feedstock into the lower portion of the axial flow staged zone reactor which includes axial circulation of the hydrocarbon reaction fluid serially in each of the reaction zones, passing catalyst through a constriction zone located between successive upper and lower catalytic reaction zones which includes heat exchanging of the fluids being the constriction zone within the reactor and further includes withdrawing the oligomerized product from the top of the reactor.Type: GrantFiled: October 2, 2009Date of Patent: December 17, 2013Assignee: IFP Energies NouvellesInventors: Sylvain Louret, Patrice Font, Sylvie Lacombe, Eric Sanchez, Laurent Simon
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Patent number: 8586252Abstract: A reactor system is integrated internally within an anode-side cavity of a fuel cell. The reactor system is configured to convert higher hydrocarbons to smaller species while mitigating the lower production of solid carbon. The reactor system may incorporate one or more of a pre-reforming section, an anode exhaust gas recirculation device, and a reforming section.Type: GrantFiled: November 18, 2010Date of Patent: November 19, 2013Assignee: Acumentrics CorporationInventors: Neil Edward Fernandes, Michael S. Brown, Praveen Cheekatamarla, Thomas Deng, James Dimitrakopoulos, Anthony F. Litka
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Patent number: 8574329Abstract: A method of operating a gasifier is provided that envisions dividing the gasifier into multiple zones. A high-calorific-value feedstock with an oxidant is injected in the first zone. The gasifier is operated to substantially consume the oxidant within the first gasification zone. The method of operating the gasifier further includes injecting a low-calorific-value, high-oxygen-content feedstock in a second gasification zone. The low-calorific-value, high-oxygen-content feedstock is devolatilized and gasified in second zone. A method of operation provides for a synergistic co-gasification of the high-calorific-value feedstock and the low-calorific-value, high oxidant content feedstock. The method provides for specific control actions that enable operation of multi-fuel, multizone gasifier.Type: GrantFiled: December 18, 2008Date of Patent: November 5, 2013Assignee: General Electric CompanyInventors: Vladimir Zamansky, Vitali Lissianski, Boris Nikolaevich Eiteneer, Wei Wei, Ravichandra Srinivasa Jupudi, Ramanathan Subramanian
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Patent number: 8568669Abstract: This invention relates to a device for cooling and distributing mixed charges on fixed catalyst beds for use in the cooling zone of descending flow reactors which comprises a flat tray fitted with collector and distributor tubes for liquid superimposed upon and connected to another flat tray of similar design to the upper tray. The device, which is of smaller size in comparison with other commercially available devices, is extremely simple to install industrially and compact, and has as its main characteristic the efficiency with which it promotes reduction of the temperature of the reaction medium when it receives the cooling fluid within the catalytic reactor.Type: GrantFiled: October 29, 2010Date of Patent: October 29, 2013Assignee: Petroleo Brasileiro S.A.—PetrobrasInventors: Wilson Kenzo Huziwara, Donizeti Aurelio Silva Belato, Jorge Roberto Duncan Lima, Rogério Michelan, William Victor Carlos Candido, Angelo Jose Gugelmin, Paulo Sérgio Freire, Nelson Patrício, Jr.
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Patent number: 8535614Abstract: The present invention provides a reactor and a method for the production of high purity silicon granules. The reactor includes a reactor chamber; and the reaction chamber is equipped with a solid feeding port, auxiliary gas inlet, raw material gas inlet, and exhaust gas export. The reaction chamber is also equipped with an internal gas distributor; a heating unit; an external exhaust gas processing unit connected between a preheating unit and a gas inlet. The reaction chamber is further equipped with a surface finishing unit, a heating unit and a dynamics generating unit. The reaction is through decomposition of silicon containing gas in densely stacked high purity granular silicon layer reaction bed in relative motion, and to use remaining hear of exhaust gas for reheating. The present invention is to achieve a large scale, efficient, energy saving, continuous, low cost production of high purity silicon granules.Type: GrantFiled: March 8, 2011Date of Patent: September 17, 2013Assignee: Sunnyside Technologies, Inc.Inventor: Xi Chu
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Patent number: 8518366Abstract: The present invention relates to a process and a device for the combustion of sulphur and/or sulphur-containing compounds, via which a sufficient production of SO2-containing gases having a high SO2 concentration is made possible. The combustion preferably proceeds using a combustion gas which has an oxygen fraction at least as high as air, but preferably a higher fraction of oxygen. The process and the device should be suitable, in particular, for providing sulphur dioxide as a source for further production of sulphuric acid or highly concentrated SO3-containing gases. In addition, the device and the process should be suitable for oxidizing hydrogen-sulphide-containing gases, such as occur, for example, in the refinery industry, in high concentrations to SO2.Type: GrantFiled: October 28, 2010Date of Patent: August 27, 2013Assignee: Bayer Intellectual Property GmbHInventors: Dieter Förtsch, Martin Kürten
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Publication number: 20130129609Abstract: The present invention relates to a catalytic system comprising at least two catalytic zones of which at least one zone exclusively contains one or more noble metals selected from the group consisting of Rhodium, Ruthenium, Iridium, Palladium and Platinum and at least another zone contains Nickel, said catalytic system characterized in that at least one zone exclusively containing noble metals selected from the group consisting of Rhodium, Ruthenium, Iridium, Palladium and Platinum is always distinct but in contact with at least one zone containing Nickel. One or more metals selected from the group consisting of Rhodium, Ruthenium, Iridium, Palladium and Platinum are possibly added to the catalytic zone or zones comprising Nickel.Type: ApplicationFiled: May 31, 2011Publication date: May 23, 2013Applicant: ENI S.p.A.Inventors: Luca Eugenio Basini, Alessandra Guarinoni, Luciano Cosimo Carluccio
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Patent number: 8419812Abstract: A reactor for the recovery of carbon and hydrocarbons from organic input material through pyrolysis includes a vessel with a chamber that is limited outwardly by an outer jacket and by an upper and a lower end-wall section, and in which chamber input material in fragmented form is to be placed; an inlet which for the introduction of heated inert gas into the chamber for passage through the input material comprises several inlet units arranged in areas in the chamber; and an outlet which for the passage out from the chamber of gas that has passed through the input material that has been placed in the chamber comprises number of outlet units arranged in areas in the chamber.Type: GrantFiled: November 26, 2007Date of Patent: April 16, 2013Assignee: SES IP ABInventor: Bengt-Sture Ershag
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Patent number: 8323591Abstract: One exemplary embodiment can be a method of fabricating a mixing chamber in a hydroprocessing reactor. The method can include providing a first section forming an opening and coupling a second section including a sidewall to the first section. The second section forms a flange for coupling the mixing chamber and facilitating the mixing of one or more fluids.Type: GrantFiled: April 21, 2011Date of Patent: December 4, 2012Assignee: UOP LLCInventors: Sailesh B. Kumar, Robert L. Bunting
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Patent number: 8318100Abstract: Reactor vessels with pressure and heat transfer features for producing hydrogen-based fuels and structural elements, and associated systems and methods. A representative reactor system in accordance with a particular embodiment includes a first reaction zone and a heat path positioned to direct heat into the first reaction zone, a reactant source coupled to the first reaction zone, and a first actuator coupled to cyclically pressurize the first reaction zone. The system can further include a second reaction zone in fluid communication with the first, a valve coupled between the first and second reaction zones to control a flow rate therebetween, and a second actuator coupled in fluid communication with the second reaction zone to cyclically pressurize the second reaction zone.Type: GrantFiled: February 14, 2011Date of Patent: November 27, 2012Assignee: McAlister Technologies, LLCInventor: Roy Edward McAlister
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Patent number: 8314276Abstract: A method of hydroprocessing hydrocarbons is provided using a substantially liquid-phase reactor having first and second catalyst beds with a heat transfer section positioned therebetween. The first and second catalyst beds and the heat transfer section are combined within the same reactor vessel. Each catalyst bed having an inlet temperature and an exit temperature and having a hydroprocessing catalyst therein with a maximum operating temperature range.Type: GrantFiled: July 20, 2011Date of Patent: November 20, 2012Assignee: UOP LLCInventors: John A. Petri, Peter Kokayeff
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Publication number: 20120260565Abstract: The present invention relates to a process for catalytically converting material of biological origin into hydrocarbons useful as fuel components. The process includes hydrodeoxygenation and isomerisation of the material. The present invention relates also to a reactor and an apparatus suitable for use in the process.Type: ApplicationFiled: April 18, 2012Publication date: October 18, 2012Applicant: UPM-KYMMENE CORPORATIONInventors: Jaakko NOUSIAINEN, Arto RISSANEN, Andrea GUTIERREZ, Teemu LINDBERG, Heli LAUMOLA, Pekka KNUUTTILA
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Patent number: 8282891Abstract: The instant application provides apparatus and methods for the generation of gas, preferably chlorine dioxide. The methods and apparatus of the invention use a removable reaction chamber for the reaction of precursor chemicals, e.g., chlorite salt and an acid. The methods and compositions of the invention provide gas for a number of personal and commercial applications.Type: GrantFiled: July 1, 2010Date of Patent: October 9, 2012Assignee: TBS Technologies, LLCInventors: Thomas J. Dee, Paul Sabin, Douglas Sabin
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Patent number: 8273314Abstract: The invention concerns an exchanger-reactor (1) comprising: a vessel (2); means for distributing a feed through a fixed bed catalytic zone (10); means (6) for collecting effluent from the catalytic zone (10); means for heating the catalytic zone (10); in which said collection means (6) comprise conduits passing right through the catalytic zone (10), said conduits being distributed in the catalytic zone and interposed between the heating means, and in which the heating means of the catalytic zone are contained in sheaths (8) which are partially immersed in the catalytic zone (10), the sheaths (8) being open at one of their ends and closed at the other, the open end being fixed to an upper tube plate (21) defining the collection chamber (19) which is located above the catalytic zone (10), said heating means comprising at least one combustion zone (13) located close to the catalytic zone, means for supplying said combustion zone (13) with an oxidizing gas mixture (15) and with a gaseous fuel (17), and meansType: GrantFiled: March 16, 2007Date of Patent: September 25, 2012Assignee: IFP Energies NouvellesInventors: Beatrice Fischer, Stephane Bertholin, Fabrice Giroudiere, Jerome Colin
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Patent number: 8206668Abstract: The apparatus of the invention is essentially characterized by the fact that it includes a fluid-flow duct (10) having an inlet (11) and an outlet (12), and mounted in succession in series in the duct (10): a suction fan (20) for sucking in a carrier gas available at the inlet (11) and for discharging it towards the outlet (12); a bubbler (30) suitable for causing the carrier gas to pass through a volatile liquid (31) contained in the bubbler so as to obtain a stream of carrier gas (33) charged with vapor of the liquid; a device (40) for fractioning the charged stream to deliver a charged stream in fractioned form; and a member (50) for treating the fractioned charged stream to impart a determined quality thereto before it is ejected from the outlet (12) of the duct (10). The invention is applicable in particular to producing a gas charged with a volatile compound, in particular for inhalation.Type: GrantFiled: March 19, 2008Date of Patent: June 26, 2012Assignee: Holiste Laboratories et DeveloppmentInventors: Marie-Laure Delanef, Jean-Michel Collaudin
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Patent number: 8197785Abstract: Systems and methods for contacting a liquid, gas, and/or a multi-phase mixture with particulate solids. The system can include a body having a first head and a second head disposed thereon. Two or more discrete fixed beds can be disposed across a cross-section of the body. One or more unobstructed fluid flow paths can bypass each fixed bed, and one or more baffles can be disposed between the fixed beds.Type: GrantFiled: February 27, 2008Date of Patent: June 12, 2012Assignee: Kellogg Brown & Root LLCInventors: Kenneth L. Blanchard, David P. Mann
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Patent number: 8192688Abstract: A thermally diluted exothermic reactor system is comprised of numerous orifices distributed within a combustor by distributed perforated contactor tubes or ducts. The perforated contactors deliver and mix diluent fluid and one or more reactant fluids with an oxidant fluid. Numerous micro-jets about the perforated tubes deliver, mix and control the composition of reactant fluid, oxidant fluid and diluent fluid. The reactor controls one or more of composition profiles, composition ratio profiles and temperature profiles in one or more of the axial direction and one or two transverse directions, reduces temperature gradients and improves power, efficiency and emissions.Type: GrantFiled: March 26, 2009Date of Patent: June 5, 2012Assignee: Vast Power Portfolio LLCInventors: David L. Hagen, Gary Ginter, Bill Goheen, L. Allan McGuire, Janet Rankin
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Patent number: 8182750Abstract: A carbon monoxide treatment apparatus according to an exemplary embodiment of the present invention includes: a reactor body; a partitioning plate located inside the reactor body for partitioning an internal space of the reactor body into a first section and a second section; a channel member in the first section for transporting an introduced gas including a reformed gas and an oxidant gas to the second section; and a reaction unit around the channel member of the first section for reducing a concentration level of carbon monoxide in the introduced gas moving through the first section by utilizing a preferential oxidation reaction of the carbon monoxide and the oxidant gas of the introduced gas, wherein moisture of the introduced gas that has been partially condensed when passing through the channel member is stored in the second section.Type: GrantFiled: February 20, 2008Date of Patent: May 22, 2012Assignee: Samsung SDI Co., Ltd.Inventors: Man-Seok Han, Seong-Jin An, Ju-Yong Kim, Sung-Chul Lee, Yong-Kul Lee, Chan-Ho Lee, Jun-Sik Kim, Jin-Goo Ahn
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Patent number: 8178062Abstract: In a reforming apparatus, for use in a fuel cell, for reforming a raw fuel into a hydrogen-rich reformed gas, a reformer generates the reformed gas from the raw fuel. A shift reactor reduces carbon monoxide contained in the reformed gas through a shift reaction. A selective oxidation unit reduces the carbon monoxide contained in the reformed gas that has passed through the shift reactor by performing selective oxidation on the carbon monoxide. A reforming reaction tube houses linearly the reformer, the shift reactor and the selective oxidation unit in this order. A combustion means produces combustion exhaust gas by combusting the raw fuel. An outer casing is placed around the reforming reaction tube, and the outer casing has a larger diameter than that of the reforming reaction tube. A heated flow passage through which the combustion exhaust gas passes to heat the reforming reaction tube is formed between the reforming reaction tube and the outer casing.Type: GrantFiled: September 26, 2008Date of Patent: May 15, 2012Assignees: Sanyo Electric Co., Ltd., Nippon Oil CorporationInventors: Akira Fuju, Masataka Kadowaki, Kazumi Kobayashi, Kazuaki Nakajima, Yasushi Sato, Ken Samura
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Patent number: 8168131Abstract: A syngas reforming reactor has a shell-and-tube configuration wherein the shell-side fluid flow path through the tube bundle has a longitudinal configuration. The reactor can include a shell-side inlet fluid distributor plate below the lower end of the tube bundle.Type: GrantFiled: November 9, 2009Date of Patent: May 1, 2012Assignee: Kellog Brown & Root LLCInventors: Robert Stevens Burlingame, Lloyd Edward Cizmar, Larry Gene Hackemesser, Laura Beth Aguilar
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Patent number: 8153070Abstract: A microreactor capable of reducing a pressure drop in an entire system includes a mixer 103 having a mixing channel for mixing two kinds of raw materials 101 and 102, and a reactor 109 having a reaction channel connected to the downstream side of the mixing channel to receive the mixture flowing out from the mixing channel and cause chemical reactions of the mixture inside the reaction channel. The reactor 109 a first reactor unit 107 having a large surface-to-volume (S-V) ratio of the reaction channel at an upstream side, and a second reactor unit 108 having a small S-V ratio of the reaction channel at a downstream.Type: GrantFiled: April 28, 2009Date of Patent: April 10, 2012Assignee: Hitachi, Ltd.Inventors: Yukako Asano, Tetsuro Miyamoto, Hajime Katou, Shigenori Togashi
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Patent number: 8133458Abstract: A reactor for converting methane, ammonia and oxygen and alkaline or alkaline earth hydroxides into alkaline or alkaline earth cyanides by two-stage reactions comprising a first stage with a gas inlet, wherein the first stage is formed by a cone with distribution plates providing an even gas distribution over the catalyst material wherein the distribution plates are located between the gas inlet of the reactor and catalyst material and the distribution plates being perforated with a number of holes, with the distribution plates spaced from each other in the flow direction of the gas, the first distribution plate(s) functioning mainly to distribute the gas, whereas the last distribution plate works as a heat radiation shield and as a distribution plate facing the catalyst material, and wherein the catalyst material is present in the form of catalyst gauze fixed by catalyst weights.Type: GrantFiled: March 3, 2008Date of Patent: March 13, 2012Assignee: EICPROC ASInventor: Erik Fareid
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Patent number: 8124035Abstract: Continuous processes for monoalkylating aromatic compound with an aliphatic feedstock comprising aliphatic olefin of 8 to 18 carbon atoms per molecule are effected using at least 3 reaction zones in series, each containing solid alkylation catalyst with effluent cooling between reaction zones, each of which reaction zones is supplied a portion of the fresh aliphatic feedstock, such that the Reaction Zone Delta T in each reaction zone is less than about 15° C. The overall aromatic compound to olefin molar ratio is less than about 20:1. The alkylation product has desirable linearity and low amounts of dimers, dealkylated compounds and diaryl compounds even though a low aromatic compound to olefin molar ratio is used.Type: GrantFiled: February 5, 2010Date of Patent: February 28, 2012Assignee: UOP LLCInventor: Mark G. Riley
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Patent number: 8119083Abstract: This invention relates to a multiphase reactor which is especially suitable for desulfurization of flue gas. A rotary build-in member comprising a axisymmetric body and an annular axisymmetric body is fixed on the shell of the reactor. The shell is cylindrical, and its surface is smooth or waved. The maximum diameter of the axisymmetric body is no less than the inner diameter of the annular axisymmetric body. The axisymmetric body is installed on the annular axisymmetric body coaxially. One rotary build-in member and its corresponding shell constitute an unit, and the reactor may have one or more such units. The multiphase reactor can effectively improve the flow pattern of the fluid and the contact of gas-liquid-solid three-phase of the reactants, speed up the mass transfer, and prevent deposition of the solid phase. The reactor is simple in structure and convenient for use. It can be used in the fields such as environmental protection, chemical engineering, metallurgy, and architectural industries.Type: GrantFiled: October 16, 2003Date of Patent: February 21, 2012Inventor: Hanxiang Shi
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Patent number: 8114353Abstract: Methods and systems for preparing catalyst, such as chromium catalysts, are provided. The valence of at least a portion of the catalyst sent to an activator is changed from Cr(III) to Cr(VI). The catalyst is prepared or activated continuously using a fluidization bed catalyst activator.Type: GrantFiled: December 20, 2007Date of Patent: February 14, 2012Assignee: Chevron Phillips Chemical Company LPInventors: Elizabeth A. Benham, Max P. McDaniel, Ted H. Cymbaluk, Charles K. Newsome, Charles R. Nease, H. Kenneth Staffin, Thomas R. Parr
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Patent number: 8110149Abstract: The present invention relates to a method for the continuous production of high-molecular polyesters by esterification of dicarboxylic acids and/or transesterification of dicarboxylic acid esters with diols and/or mixtures thereof in the presence of catalysts with formation of a prepolymer in a tower reactor and polycondensation thereof to form a high-molecular polyester in a polycondensation reactor, a prepolymer with >40 to 70 repeat units (DP) being produced in the tower reactor and this prepolymer being polycondensed in only one further reactor to form a polyester with >150 to 205 DP.Type: GrantFiled: May 31, 2007Date of Patent: February 7, 2012Assignee: Uhde Inventa-Fischer GmbHInventor: Eike Schulz Van Endert
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Patent number: 8110161Abstract: The invention relates to a process for the production of alkylated aromatic compounds comprising introducing olefin and aromatic compounds into at least first and second vertically spaced catalytic reaction zones in an alkylation unit under alkylation reaction conditions to provide an alkylated product, wherein the second catalytic reaction zone is positioned above the first catalytic reaction zone; wherein aromatic compound from each of the at least first and second catalytic reaction zones are contacted with a cooling means for re-condensing at least a portion of the aromatic compounds vaporized from the exothermic heat of reaction of the alkylation process; and wherein the olefin is introduced into the at least first and second catalytic reaction zones via respective first and second olefin feed streams at respective olefin feed rates such as to maintain olefin partial pressures at inlets to at least first and second catalytic reaction zones which vary by less than about ten percent.Type: GrantFiled: December 11, 2009Date of Patent: February 7, 2012Assignee: Lummus Technology Inc.Inventor: Kevin John Schwint
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Patent number: 8101141Abstract: A unified fuel processing reactor for a solid oxide fuel cell can reform hydrocarbon-based fuel into hydrogen-rich gas, remove a sulfur component, and convert non-converted fuel and a low carbon (C2˜C5) hydrocarbon compound into hydrogen and methane in a single reactor. The reactor comprises a primary-reformer which reforms a hydrocarbon-base fuel and generates hydrogen-rich reformed gas, a desulfurizer which removes a sulfur component from the reformed gas, and a post-reformer which selectively decomposes a low carbon (C2˜C5) hydrocarbon in the desulfurized reformed gas into hydrogen and methane. The primary-reformer, desulfurizer and post-reformer are in the unified reactor and isolated, except for a fluid passage, from each other by internal partition walls. The primary-reformer is disposed at a center portion of the reactor. The post-reformer and the desulfurizer are concentrically disposed outside of the primary-reformer.Type: GrantFiled: April 24, 2009Date of Patent: January 24, 2012Assignee: Korea Advanced Institute of Science and TechnologyInventors: Joongmyeon Bae, Sangho Yoon, Sunyoung Kim
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Patent number: 8097226Abstract: A catalytic reaction device for fluid-solid heterogeneous catalytic reactions including a distributor, flow controllers, parallel reactors, temperature controllers, coolers and product receivers with reactive fluids flowing into the flow controllers to control the total flow of a fluid is provided.Type: GrantFiled: December 13, 2006Date of Patent: January 17, 2012Assignee: Microvast Power Systems Co., Ltd.Inventors: Jiangping Yi, Li Huang, Wensheng Li, Xio Ping Zhou
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Patent number: 8088344Abstract: A multi-tubular reactor system for catalytically reacting a fluid reactant mixture to form a fluid product comprising a shell and a plurality of reactor tubes housed therein. The reactor system is adapted to allow heat-exchange fluid to flow between the shell and the external surface of the reactor tubes. A reactor tube comprises a reaction zone, and also a heating zone and/or a cooling zone. The reaction zone is positioned downstream of the heating zone. The cooling zone is positioned downstream of the reaction zone. The reactor tube contains a bed of solid particulate catalyst in the reaction zone. The reactor tube additionally contains a heat-exchanging essentially rod-shaped insert having a length of from 1 to 20%, preferably 1 to 5%, of the total length of the reactor tube in the heating zone and/or the cooling zone.Type: GrantFiled: September 22, 2006Date of Patent: January 3, 2012Assignee: Shell Oil CompanyInventors: Arend Jan Te Raa, Mathias Jozef Paul Slapak, Alouisius Nicolaas Rene Bos
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Patent number: 8075856Abstract: The present invention is a multiple reaction set for the production of chemicals by equilibrium limited reactions utilizing plate-type or extended surface heat exchangers. The heat exchangers effectively cool the reaction products in order to condense the methanol contained within the reaction products for separation, and also to warm incoming feed reactants prior to entrance of the reactants into a reactor utilized for the production of methanol. The various reactors, heat exchangers, and separators can be formed as separated zones within the enclosed vessels, thereby eliminating the need for separately constructed reactors, heat exchangers, and separators. Multi-stream plate-type of extended surface heat exchangers can be utilized to allow efficient cooling and methanol separation.Type: GrantFiled: September 22, 2006Date of Patent: December 13, 2011Inventors: James Andrew Banister, Anthony Matthew Johnston, Brian S. Haynes
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Patent number: 8066954Abstract: A plug flow reactor having an inner shell 27 surrounded by outer shell 21 and having at least one annular flow passage 35 therebetween can be used to prepare compositions, including polymers. The plug flow reactor also includes inlet port 36, an outlet port 37 and a plurality of exchanger tubes 26 wherein the exchanger tubes are in fluid communication to the at least one annular flow passage. Polystyrene and high impact polystyrene can be prepared using the reactor.Type: GrantFiled: December 17, 2008Date of Patent: November 29, 2011Assignee: Fina Technology, Inc.Inventors: Thanh T. Nguyen, Jay L. Reimers
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Patent number: 8057749Abstract: A device for carrying out exothermal chemical reactions wherein a gas phase is guided across a fixed bed and allowed to react, comprising a housing and an exchangeable unit wherein the reaction takes place.Type: GrantFiled: September 18, 2006Date of Patent: November 15, 2011Assignee: Evonik Degussa GmbHInventors: Achim Fischer, Harald Heinzel, Christoph Weckbecker, Klaus Huthmacher
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Patent number: 8057944Abstract: A reformer for a fuel cell system includes a leading segment and a trailing segment. The leading segment includes less reactive catalyst and/or more stabilizing catalyst than the trailing segment. The reformer may be used for reformation of high and low hydrocarbon fuels.Type: GrantFiled: April 22, 2010Date of Patent: November 15, 2011Assignee: Bloom Energy CorporationInventor: Swaminathan Venkataraman
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Patent number: 8052946Abstract: A system and process for upgrading hydrocarbons such as heavy oils includes a high temperature plasma reactor apparatus, in one or more vessels, into which the oils are introduced along with water, such as steam, to produce lighter hydrocarbon fractions, along with carbon monoxide and hydrogen, that flows to an additional stage where more hydrocarbons and water are introduced for further fractionating reactions facilitated by reaction of carbon monoxide and water to produce carbon dioxide and nascent, or prompt, free radicals of hydrogen. Heavy hydrocarbons upgraded can include heavy oils in the form of tar sands, oil shale, and oil residuals. The vessel or vessels can each contain a carbonaceous bed facilitating the described reactions and example embodiments include one vessel with the reactions performed in a single bed and, also, two vessels with the reactions performed in a carbonaceous bed portion in each vessel.Type: GrantFiled: October 27, 2009Date of Patent: November 8, 2011Assignee: Westinghouse Plasma CorporationInventors: Shyam V. Dighe, Mark Anthony Montemurro, Richard Dale Bower, Aleksandr Gorodetsky, Mark F. Darr, Ivan A. Martorell
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Patent number: 8029738Abstract: Methods and devices for removing inflammable gases produced by radiolysis in a closed chamber containing radioactive matters comprising organic compounds and possibly water, or radioactive matters in the presence of organic compounds and possibly water. Inside the chamber there may be placed a catalyst of at least one reaction for oxidizing the inflammable gases by oxygen contained in the chamber atmosphere, supported by an inert solid support; a catalyst of at least the reaction for oxidizing CO to CO2; possibly an oxygen source; and possibly a hygroscopic microporous inert solid support. Also, chambers for radioactive matters containing such devices.Type: GrantFiled: January 6, 2010Date of Patent: October 4, 2011Assignee: TN InternationalInventors: Pascale Abadie, Herve Issard