Ion Exchanging Or Liquid-liquid Extracting Patents (Class 423/112)
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Patent number: 11787974Abstract: The present disclosure provides chemical-mechanical polishing (CMP) particles exhibiting a high polishing rate and a high polishing quality of generating few defects or scratches due to their modified surface thereof. The present disclosure also provides a polishing slurry composition including the polishing particles.Type: GrantFiled: June 30, 2021Date of Patent: October 17, 2023Assignee: Dongjin Semichem Co., Ltd.Inventors: Weoun Gyuen Moon, Jae Hyun Kim, Kyu Soon Shin, Jong Dai Park, Min Gun Lee, Sung Hoon Jin, Goo Hwa Lee, Gyeong Sook Cho, Jae Hong Yoo
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Patent number: 11661348Abstract: The invention discloses a sound-absorbing material particle and a preparation method thereof. The method for preparing the sound-absorbing material particle comprises: mixing a sound-absorbing raw material with a solvent to form a sound-absorbing slurry; filling the sound-absorbing slurry into a mechanical compression die, and performing compression molding on the sound-absorbing slurry to form a particle; performing a hydrothermal crystallization reaction on the particle to crystallize the sound-absorbing raw material in the particle; and drying the particle to produce the sound-absorbing material particle.Type: GrantFiled: May 18, 2016Date of Patent: May 30, 2023Assignee: GOERTEK INC.Inventor: Xiaodong Cao
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Patent number: 11643481Abstract: The present invention provides polymer compositions having improved corrosivity, color stability and clarity. Also disclosed is a process of preparing the polymers. The process may comprise incorporating into the polymer an acid neutralizing amount of an amorphous aluminum silicate. The amorphous aluminum silicate may be present in the polymer in an amount such that the polymer composition having a Corrosivity Index of less than 6. A refractive index of the amorphous aluminum silicate may be the same or substantially the same as a refractive index of the polymer.Type: GrantFiled: February 1, 2019Date of Patent: May 9, 2023Assignee: W.R. Grace & Co.-Conn.Inventors: Amaia Montoya-Goni, John Kaarto, Michelle Ni Paine, Jose Manuel Rego, Feng Gu, Demetrius Michos, James Neil Pryor
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Patent number: 11505847Abstract: The present invention encompasses a method of selectively separating Ga from wastewaters with the aid of a dialysis method. This exploits the particular complexation behaviour of Ga, which forms an unstable tetrahalo complex. This forms only in the case of a sufficiently high halide concentration. Since the halide concentration becomes lower across the membrane, the Ga-tetrahalo complex breaks down in the membrane, as a result of which the Ga is retained. Other metals such as In and Fe do not show this behaviour, and therefore the tetrahalo complexes of these metals can pass through the membrane and hence can be selectively separated off.Type: GrantFiled: June 13, 2017Date of Patent: November 22, 2022Assignee: FREIBERGER COMPOUND MATERIALS GMBHInventors: Thomas Reinhold, Stefan Eichler, Berndt Weinert, Oliver Zeidler, Michael Stelter
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Patent number: 11225725Abstract: A method for producing aluminum includes: a dissolution step of dissolving a hydrate containing Al in water to prepare an aqueous solution that contains Al ions; an extraction step of bringing an organic phase that is composed of an extractant into contact with an aqueous phase that is composed of the aqueous solution to extract the Al ions in the aqueous phase into the organic phase; and an electrodeposition step of electrolyzing the organic phase as an electrolytic solution to electrodeposit metallic Al onto a surface of a cathode from the Al ions in the electrolytic solution.Type: GrantFiled: July 9, 2019Date of Patent: January 18, 2022Assignee: UACJ CORPORATIONInventors: Junji Nunomura, Yukio Honkawa, Yoichi Kojima, Mikito Ueda
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Patent number: 10632701Abstract: A manufacturing method of a honeycomb structure includes a forming step of preparing a forming raw material containing a cordierite forming material and an inorganic binder, and kneading and forming the prepared forming raw material to have a honeycomb shape; and a firing step of firing the prepared formed body. In the forming step, as the inorganic binder, smectite is used in which at least parts of interlayer metal cations are ion-exchanged with non-metal cations. In the smectite, a total amount of sodium to be contained in the smectite is 1.6 mass % or less in terms of oxides to 100 mass % of the smectite. A content ratio of the smectite in the forming raw material is 0.5 parts by mass or more and 4.0 parts by mass or less to 100 parts by mass of the cordierite forming material.Type: GrantFiled: July 11, 2018Date of Patent: April 28, 2020Assignee: NGK Insulators, Ltd.Inventors: Takayoshi Shibayama, Hideki Oka, Shuji Ueda, Hiroyuki Suenobu
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Patent number: 10487027Abstract: The invention relates to zeolitic absorbents based on at least one zeolite with hierarchical porosity, containing barium or barium and potassium, to the uses thereof for separating para-xylene from aromatic fractions containing 8 carbon atoms, and to the method for separating para-xylene from aromatic fractions containing 8 carbon atoms.Type: GrantFiled: August 4, 2015Date of Patent: November 26, 2019Assignee: Arkema FranceInventors: Catherine Laroche, Ludivine Bouvier, Cecile Lutz, Arnaud Baudot
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Patent number: 10422021Abstract: This method for producing a vanadium compound has an alkaline leaching step for immersing incineration ash in an alkaline solution to cause vanadium to leach from the incineration ash into the alkaline solution and obtain a leachate slurry, a solid-liquid separation step for separating the leachate slurry obtained in the alkaline leaching step into a solid and liquid followed by removing insoluble matter to obtain a leachate, a pH adjustment step for adding acid to the leachate following solid-liquid separation to make the leachate acidic, an aging step for aging the leachate following pH adjustment until a precipitate forms in the leachate, and a separation step for separating the precipitate from the leachate following the aging step.Type: GrantFiled: January 5, 2018Date of Patent: September 24, 2019Assignee: SHOWA DENKO K.K.Inventors: Gaku Oriji, Kenzo Hanawa
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Patent number: 10059658Abstract: Method for preparation of 5-alkylsalicylaldoximes with formula 1, where R is a C6-C16 alkyl group, consisting in that into a water-alcohol solvent system, p-alkylphenol, sodium hydroxide, chloroform and hydroxylamine are introduced, while in relation to the alkylphenol used, sodium hydroxide and chloroform are used in amounts from the stoichiometric amount to a 100% excess, and hydroxylamine is used in amounts from the stoichiometric amount to a 60% excess, and the reaction is carried out at a temperature of 60-75° C. for 1.5-4 h, and then, at a temperature of 20-30° C., the post-reaction mixture is acidified till the pH of the aqueous phase <7.0 is obtained, and next, an alcohol-water azeotrope is distilled off with an admixture of unreacted chloroform, the residue is mixed with a neutral C5-C10 hydrocarbon solvent, the layers are separated, and the solvent is distilled off from the organic phase.Type: GrantFiled: September 1, 2017Date of Patent: August 28, 2018Assignee: POLITECHNIKA WARSZAWSKAInventors: Krzysztof Bujnowski, Ludwik Synoradzki, Jerzy Wisialski, Agnieszka Krolikowska, Jacek Bordzilowski, Marcin Koziorowski, Roman Zadrozny, Anna Jerzak, Krzysztof Dzienis
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Patent number: 10040746Abstract: The invention is directed to a method for recovering carboyxlic acid from an magnesium carboxylate containing aqueous mixture, including the steps of: contacting the aqueous mixture with an acidic ion exchanger, thereby forming a carboxylic acid mixture and an ion exchanger loaded with magnesium ions; contacting the ion exchanger loaded with magnesium ions with a hydrochloric acid solution, thereby forming a magnesium chloride solution; and thermally decomposing the magnesium chloride solution at a temperature of at least 300° C., thereby forming magnesium oxide (MgO) and hydrogen chloride (HCl).Type: GrantFiled: July 14, 2016Date of Patent: August 7, 2018Assignee: PURAC BIOCHEM B.V.Inventors: Adriaan Dirk Kon, André Banier De Haan, Paulus Loduvicus Johannes Van Der Weide, Tanja Ðekic {hacek over (Z)}ivkovic, Lucien Henri Leander Jozef De Koninck
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Patent number: 9776885Abstract: Provided is a production method for refining iron oxide (hematite), which has such a low sulfur content as to be used as an iron-making raw material, from a leach residue containing iron oxide produced by a high pressure acid leach (HPAL) process. In the method for refining iron oxide for ironmaking by a process of adding sulfuric acid to nickel oxide ore and then leaching nickel from the nickel oxide ore using a pressure vessel, an amount of the sulfuric acid added is 150 kg or more and 220 kg or less per ton of nickel oxide ore.Type: GrantFiled: February 13, 2013Date of Patent: October 3, 2017Assignee: SUMITOMO METAL MINING CO., LTD.Inventors: Yoshitomo Ozaki, Manabu Enomoto, Hirofumi Shouji, Tatsuya Higaki
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Patent number: 9441285Abstract: New compounds which meet general formula (I): where: m=0, 1 or 2; R1 and R2=a C6 to C12, straight-chain or branched, hydrocarbon group; R3=H, a C1 to C12, straight-chain or branched, hydrocarbon group, optionally comprising one or more heteroatoms; a C3 to C8 monocyclic hydrocarbon group, optionally comprising one or more heteroatoms, or a monocyclic (hetero)aryl group; or else R2 and R3 together form a —(CH2)n— group where n=1 to 4; R4=a C2 to C8, straight-chain or branched, hydrocarbon group, or a monocyclic aromatic group; R5=H, or a C1 to C12, straight-chain or branched, hydrocarbon group.Type: GrantFiled: May 6, 2013Date of Patent: September 13, 2016Assignee: Areva MinesInventors: Guilhem Arrachart, Nicolas Aychet, Gilles Bernier, Fabien Burdet, Antoine Leydier, Manuel Miguirditchian, Stephane Pellet-Rostaing, Gabriel Plancque, Raphael Turgis, Elisabeth Zekri
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Patent number: 9422217Abstract: The invention is directed to a method for recovering carboyxlic acid from an magnesium carboxylate containing aqueous mixture, including the steps of: contacting the aqueous mixture with an acidic ion exchanger, thereby forming a carboxylic acid mixture and an ion exchanger loaded with magnesium ions; contacting the ion exchanger loaded with magnesium ions with a hydrochloric acid solution, thereby forming a magnesium chloride solution; and thermally decomposing the magnesium chloride solution at a temperature of at least 300° C., thereby forming magnesium oxide (MgO) and hydrogen chloride (HCl).Type: GrantFiled: May 23, 2013Date of Patent: August 23, 2016Assignee: PURAC BIOCHEM BVInventors: Adriaan Dirk Kon, André Banier De Haan, Paulus Loduvicus Johannes Van Der Weide, Tanja Ðekic Živkovic, Lucien Henri Leander Jozef De Koninck
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Patent number: 9410227Abstract: The present disclosure relates to processes for recovering rare earth elements from various materials. The processes can comprise leaching the at least one material with at least one acid so as to obtain a leachate comprising at least one metal ion and at least one rare earth element, and a solid, and separating the leachate from the solid. The processes can also comprise substantially selectively removing at least one of the at least one metal ion from the leachate and optionally obtaining a precipitate. The processes can also comprise substantially selectively removing the at least one rare earth element from the leachate and/or the precipitate.Type: GrantFiled: May 3, 2012Date of Patent: August 9, 2016Assignee: ORBITE TECHNOLOGIES INC.Inventors: Richard Boudreault, Joël Fournier, Raymond Simoneau, Maria Cristina Garcia, Denis Primeau, Heinz Krivanec, Carsten Dittrich
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Patent number: 9308521Abstract: Process for preparing a modified zeolite Y which process comprises subjecting zeolite Y having a silica to alumina molar ratio of at least 10 to calcination at a temperature of from 700 to 1000° C. wherein (i) the steam partial pressure is at most 0.06 bar at a temperature of from 700 to 800° C., (ii) the steam partial pressure is at most 0.08 bar at a temperature of from 800 to 850° C., (iii) the steam partial pressure is at least 0.03 bar at a temperature of from 850 to 900° C., and (iv) the steam partial pressure is at least 0.05 bar at a temperature of from 900 to 950° C. and (v) the steam partial pressure is at least 0.07 bar at a temperature of from 950 to 1000° C.Type: GrantFiled: January 16, 2014Date of Patent: April 12, 2016Assignee: PQ CORPORATIONInventors: David Allen Cooper, Cornelius Ouwehand, Laszlo Domokos, Lay Hwa Ong
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Patent number: 9234260Abstract: Provided is a method that selectively extracts and, at a low cost, recovers indium from an acidic solution containing indium and gallium. The present invention is a method that is for isolating a valuable metal and that, by means of subjecting an acidic solution containing indium and gallium to a solvent extraction that is by means of an extraction agent comprising an amide derivative represented by a general formula, extracts indium from the acidic solution. In the formula, R1 and R2 each indicate the same or a different alkyl group, R3 indicates a hydrogen atom or an alkyl group, and R4 indicates a hydrogen atom or any given group, other than an amino group, bonded to the ?-carbon as an amino acid. The general formula preferably has a glycine unit, a histidine unit, a lysine unit, an aspartic acid unit, or an N-methylglycine unit.Type: GrantFiled: April 26, 2013Date of Patent: January 12, 2016Assignees: KYUSHU UNIVERSITY, NATIONAL UNIVERSITY CORPORATION, SUMITOMO METAL MINING CO., LTD.Inventors: Masahiro Goto, Fukiko Kubota, Yuzo Baba
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Patent number: 8968698Abstract: Provided herein are processes for recovering molybdenum and/or other value metals (e.g., uranium) present in aqueous solutions from a large range of concentrations: from ppm to grams per liter via a solvent extraction process by extracting the molybdenum and/or other value metal from the aqueous solution by contacting it with an organic phase solution containing a phosphinic acid, stripping the molybdenum and/or other value metal from the organic phase solution by contacting it with an aqueous phase strip solution containing an inorganic compound and having a ?1.0 M concentration of free ammonia, and recovering the molybdenum and/or other value metal by separating it from the aqueous phase strip solution. When the molybdenum and/or other value metal are present only in low concentration, the processes can include an organic phase recycle step and/or an aqueous phase strip recycle step in order to concentrate the metal prior to recover.Type: GrantFiled: November 7, 2012Date of Patent: March 3, 2015Assignee: Cytec Technology Corp.Inventors: Troy Allan Bednarski, Violina Antoneta Cocalia, Matthew Dean Soderstrom, Eduardo Alberto Kamenetzky, Andrew Michael Cameron, Douglas Harris
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Publication number: 20150010447Abstract: A method of purification for recycling of gallium-69 isotopes includes processes of proton irradiation and dissolution for a silver alloy plating target with gallium-69. After the proton irradiation and dissolution, a high concentration elution liquid of gallium-69 and germanium-68 is obtained by washing through an ion-exchange resin to filter out gallium-69 solution, followed by neutralizing precipitation, drying, and sintering treatments to obtain a gallium oxide. The gallium oxide can be dissolved to produce a solid target, and the washing processes can be repeated. The solid target after use can be placed in recycling again. This method is not only implemented to reduce the cost of production and comply with recycling notion nowadays, but also enhance efficiency in the practical application of radioisotopes.Type: ApplicationFiled: July 8, 2013Publication date: January 8, 2015Inventors: Ming-Hsin Li, Hsin-Han Hsieh
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Publication number: 20140301919Abstract: A process for the extraction of alumina from an aluminum-bearing ore or concentrate, comprising the steps of leaching the aluminum-bearing ore or concentrate with a lixiviant of hydrochloric acid and magnesium chloride at atmospheric pressure at a temperature of from 90° C. to the boiling point of the solution and at an Eh of at least 200 mV. After a liquid/solids separation step, the solution obtained is subjected to steps for removal of iron and for recovery of alumina.Type: ApplicationFiled: March 13, 2014Publication date: October 9, 2014Inventors: Vaikuntam I. Lakshmanan, Ramamritham Sridhar, Md. Abdul Halim, Dipak Patel, Paul Doherty
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Patent number: 8834818Abstract: There is provided a hydrometallurgical process of recovering indium and gallium values from mixtures thereof with other metal values for example recycled and scrap solar panel cells which comprises subjecting the mixture to strongly oxidizing acid conditions, preferably via the simultaneous addition of sulfuric acid and hydrogen peroxide to the leach vessel, so as to form indium and gallium salt species of at least the major proportion of the indium and gallium values in the mixture, extracting the indium and gallium values with an organic extractant by adjusting the pH so as to extract individually the indium and gallium values with the organic extractant, stripping indium and gallium values from the extractant using an acid and an alkaline solution respectively and recovering the indium and gallium values.Type: GrantFiled: November 22, 2011Date of Patent: September 16, 2014Assignee: Molycorp Minerals Canada ULCInventor: Casare G. Ferron
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Patent number: 8795613Abstract: The aluminum content of neopentasilane is reduced by treatment with organic compounds D which contain N, O, and/or S atoms and which have free electron pairs on these atoms.Type: GrantFiled: February 28, 2012Date of Patent: August 5, 2014Assignee: Wacker Chemie AGInventor: Dennis Troegel
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Patent number: 8721998Abstract: The application of aqueous solution of magnesium bicarbonate and/or calcium bicarbonate in the process of extraction separation and purification of metals is disclosed, wherein the aqueous solution of magnesium bicarbonate and/or calcium bicarbonate is used as an acidity balancing agent, in order to adjust the balancing pH value of the extraction separation process which uses an acidic organic extractant, improve the extraction capacity of organic phase, and increase the concentration of metal ions in the loaded organic phase.Type: GrantFiled: January 14, 2010Date of Patent: May 13, 2014Assignee: Grirem Advanced Materials Co., Ltd.Inventors: Xiaowei Huang, Zhiqi Long, Xinlin Peng, Hongwei Li, Guilin Yang, Dali Cui, Chunmei Wang, Na Zhao, Liangshi Wang, Ying Yu
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Publication number: 20140065037Abstract: There is provided a hydrometallurgical process of recovering indium and gallium values from mixtures thereof with other metal values for example recycled and scrap solar panel cells which comprises subjecting the mixture to strongly oxidizing acid conditions, preferably via the simultaneous addition of sulfuric acid and hydrogen peroxide to the leach vessel, so as to form indium and gallium salt species of at least the major proportion of the indium and gallium values in the mixture, extracting the indium and gallium values with an organic extractant by adjusting the pH so as to extract individually the indium and gallium values with the organic extractant, stripping indium and gallium values from the extractant using an acid and an alkaline solution respectively and recovering the indium and gallium values.Type: ApplicationFiled: November 22, 2011Publication date: March 6, 2014Applicant: MOLYCORP MINERALS CANADA ULCInventor: Cesare G. Ferron
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Patent number: 8597600Abstract: There are provided processes for extracting aluminum ions from aluminous ores and for preparing alumina. Such processes can be used with various types of aluminous ores such as aluminous ores comprising, for example, various types of metals such as Fe, K, Mg, Na, Ca, Mn, Ba, Zn, Li, Sr, V, Ni, Cr, Pb, Cu, Co, Sb, As, B, Sn, Be, Mo, or mixtures thereof.Type: GrantFiled: October 29, 2012Date of Patent: December 3, 2013Assignee: Orbite Aluminae Inc.Inventors: Richard Boudreault, Serge Alex, Fabienne Biasotto
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Patent number: 8568671Abstract: Provided a method for preparing metallurgical-grade alumina by using fluidized-bed fly ash, comprising: a) removing iron by wet magnetic separation after crushing the fly ash; b) reacting the fly ash after magnetic separation with hydrochloric acid to obtain a hydrochloric leachate; c) passing the hydrochloric leachate through macro-porous cationic resin to deeply remove iron to obtain a refined aluminum chloride solution; d) concentrating and crystallizing the refined aluminum chloride solution to obtain an aluminum chloride crystal; and e) calcining the aluminum chloride crystal to obtain the metallurgical-grade alumina. The method is simple, the procedure is easy to be controlled, the extraction efficiency of alumina is high, the production coast is low, and the product quality is steady.Type: GrantFiled: April 27, 2011Date of Patent: October 29, 2013Assignee: China Shenhua Energy Company LimitedInventors: Zhaohua Guo, Cundi Wei, Peiping Zhang, Jianguo Han, Junzhou Chi, Yanbin Sun, Yixin Zhao
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Publication number: 20130233130Abstract: There is provided a method for extracting aluminum ions from argillite. The process comprises leaching the argillite with an acid such as HCl so as to obtain a composition comprising the aluminum ions and iron ions; at least partially removing the iron ions from the composition by substantially selectively precipitating the iron ions by adding a base and at least partially removing the precipitated iron ions so as to obtain an Al-rich composition; and optionally purifying the Al-rich composition by adding a base for substantially selectively precipitating the aluminum ions, by means of a hollow fiber membrane, or by a liquid-liquid extraction.Type: ApplicationFiled: November 18, 2011Publication date: September 12, 2013Inventors: Richard Boudreault, Serge Alex, Fabienne Biasotto, Joël Fournier
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Patent number: 8343446Abstract: The oxine ligands 5-chloro-8-hydroxyquiniline and 5-sulfoxyl-8-hydroxyquinoline are covalently bound, using, for example, the Mannich reaction, to a silica gel polyamine composite made from a silanized amorphous silica xerogel and polyallylamine. The resulting modified composites, termed CB-1 (X?Cl) and SB-1 (X?SO3H), respectively, show a clear selectivity for trivalent over divalent ions and selectivity for gallium over aluminum. The compounds of the invention can be applied for the sequestration of metals, such as heavy metals, from contaminated mine tailing leachates.Type: GrantFiled: October 13, 2011Date of Patent: January 1, 2013Assignee: The University of MontanaInventors: Edward Rosenberg, Paul Miranda, Yuen Onn Wong
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Patent number: 8337789Abstract: There are provided processes for extracting aluminum ions from aluminous ores and for preparing alumina. Such processes can be used with various types of aluminous ores such as aluminous ores comprising various types of metals such as Fe, K, Mg, Na, Ca, Mn, Ba, Zn, Li, Sr, V, Ni, Cr, Pb, Cu, Co, Sb, As, B, Sn, Be, Mo, or mixtures thereof.Type: GrantFiled: May 15, 2012Date of Patent: December 25, 2012Assignee: Orsite Aluminae Inc.Inventors: Richard Boudreault, Serge Alex, Fabienne Biasotto
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Patent number: 8241594Abstract: There are provided processes for extracting aluminum ions from aluminous ores. Such processes can be used with various types of aluminous ores such as aluminous ores comprising various types of metals such as Fe, K, Mg, Na, Ca, Mn, Ba, Zn, Li, Sr, V, Ni, Cr, Pb, Cu, Co, Sb, As, B, Sn, Be, Mo, or mixtures thereof.Type: GrantFiled: October 7, 2010Date of Patent: August 14, 2012Assignee: Orbite Aluminae Inc.Inventors: Richard Boudreault, Serge Alex, Fabienne Biasotto
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Publication number: 20110274597Abstract: The application of aqueous solution of magnesium bicarbonate and/or calcium bicarbonate in the process of extraction separation and purification of metals is disclosed, wherein the aqueous solution of magnesium bicarbonate and/or calcium bicarbonate is used as an acidity balancing agent, in order to adjust the balancing pH value of the extraction separation process which uses an acidic organic extractant, improve the extraction capacity of organic phase, and increase the concentration of metal ions in the loaded organic phase.Type: ApplicationFiled: January 14, 2010Publication date: November 10, 2011Inventors: Xiaowei Huang, Zhiqi Long, Xinlin Peng, Hongwei Li, Guilin Yang, Dali Cui, Chunmei Wang, Na Zhao, Liangshi Wang, Ying Yu
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Patent number: 8012337Abstract: Proposed is a method for collecting valuable metal from an ITO scrap by subjecting the ITO scrap to electrolysis and collecting the result as metallic indium. Specifically, the present invention proposes a method for selectively collecting metallic indium including the steps of subjecting the ITO scrap to electrolysis in an electrolytic bath partitioned with a diaphragm or an ion-exchange membrane, subsequently extracting anolyte temporarily, eliminating tin contained in the anolyte by a neutralization method, a replacement method or other methods, placing a solution from which the tin was eliminated in a cathode side again and performing electrolysis thereto; or a method for collecting valuable metal from an ITO scrap including the steps of obtaining a solution of In or Sn in an ITO electrolytic bath, eliminating the Sn in the solution, and collecting In in the collecting bath.Type: GrantFiled: June 27, 2007Date of Patent: September 6, 2011Assignee: JX Nippon Mining & Metals CorporationInventors: Yuichiro Shindo, Kouichi Takemoto
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Patent number: 8007759Abstract: A static ion-exchange process for the preparation of a polynuclear Al species comprising the treatment of an aqueous aluminum chloride solution with a hydroxide-form ion-exchange resin at a temperature of from 5° C. to 60° C. for a period of at least 30 minutes.Type: GrantFiled: March 22, 2006Date of Patent: August 30, 2011Assignee: Conopco Inc.Inventors: Olivier Deschaume, Carole Celia Perry, Kirill Shafran
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Publication number: 20110044869Abstract: There are provided processes for extracting aluminum ions from aluminous ores. Such processes can be used with various types of aluminous ores such as aluminous ores comprising various types of metals such as Fe, K, Mg, Na, Ca, Mn, Ba, Zn, Li, Sr, V, Ni, Cr, Pb, Cu, Co, Sb, As, B, Sn, Be, Mo, or mixtures thereof.Type: ApplicationFiled: October 7, 2010Publication date: February 24, 2011Inventors: Richard BOUDREAULT, Serge ALEX, Fabienne BIASOTTO
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Patent number: 7837961Abstract: There are provided processes for extracting aluminum ions from aluminous ores. Such processes can be used with various types of aluminous ores such as aluminous ores comprising various types of metals such as Fe, K, Mg, Na, Ca, Mn, Ba, Zn, Li, Sr, V, Ni, Cr, Pb, Cu, Co, Sb, As, B, Sn, Be, Mo, or mixtures thereof.Type: GrantFiled: May 7, 2008Date of Patent: November 23, 2010Assignee: Exploration Orbite VSPA Inc.Inventors: Richard Boudreault, Serge Alex, Fabienne Sotto
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Publication number: 20100226839Abstract: The present invention provides a novel process for the removal and recovery of gallium from a feed solution containing the gallium and copper. The process of the present invention utilizes a combination of a supported liquid membrane (SLM) and a strip dispersion to improve extraction of gallium while increasing membrane stability and decreasing processing costs. This novel process selectively removes gallium from feed solution containing the gallium and copper.Type: ApplicationFiled: November 3, 2009Publication date: September 9, 2010Applicant: SOLAR APPLIED MATERIALS TECHNOLOGY CORP.Inventors: Jian-Jou LIAN, Chung-Ching LEE, I-Wen HUANG, Hai-Jui CHEN
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Publication number: 20100150799Abstract: There are provided processes for extracting aluminum ions from aluminous ores. Such processes can be used with various types of aluminous ores such as aluminous ores comprising various types of metals such as Fe, K, Mg, Na, Ca, Mn, Ba, Zn, Li, Sr, V, Ni, Cr, Pb, Cu, Co, Sb, As, B, Sn, Be, Mo, or mixtures thereof.Type: ApplicationFiled: May 7, 2008Publication date: June 17, 2010Inventors: Richard Boudreault, Serge Alex, Fabienne Sotto
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Patent number: 7736547Abstract: A method of producing a proton conducting material, comprising adding a pyrophosphate salt to a solvent to produce a dissolved pyrophosphate salt; adding an inorganic acid salt to a solvent to produce a dissolved inorganic acid salt; adding the dissolved inorganic acid salt to the dissolved pyrophosphate salt to produce a mixture; substantially evaporating the solvent from the mixture to produce a precipitate; and calcining the precipitate at a temperature of from about 400° C. to about 1200° C.Type: GrantFiled: March 11, 2008Date of Patent: June 15, 2010Assignee: Los Alamos National Security, LLCInventors: Fernando Henry Garzon, Melinda Lou Einsla, Rangachary Mukundan
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Patent number: 7553474Abstract: It is an object to provide a method for producing stable alkaline metal oxide sols having a uniform particle size distribution. The method comprises the steps of: heating a metal compound at a temperature of 60° C. to 110° C. in an aqueous medium that contains a carbonate of quaternary ammonium; and carrying out hydrothermal processing at a temperature of 110° C. to 250° C. The carbonate of quaternary ammonium is (NR4)2CO3 or NR4HCO3 in which R represents a hydrocarbon group, or a mixture thereof. The metal compound is one, or two or more metal compounds selected from a group of compounds based on a metal having a valence that is bivalent, trivalent, or tetravalent.Type: GrantFiled: August 8, 2005Date of Patent: June 30, 2009Assignee: Nissan Chemical Industries, Ltd.Inventors: Yutaka Ohmori, Hirokazu Kato, Yoshinari Koyama, Kenji Yamaguchi
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Patent number: 7494630Abstract: A new method to strip metals from organic solvents in a manner that allows for the recycle of the stripping agent. The method utilizes carbonate solutions of organic amines with complexants, in low concentrations, to strip metals from organic solvents. The method allows for the distillation and reuse of organic amines. The concentrated metal/complexant fraction from distillation is more amenable to immobilization than solutions resulting from current practice.Type: GrantFiled: June 25, 2003Date of Patent: February 24, 2009Assignee: The United States of America as represented by the United States Department of EnergyInventors: Terry A. Todd, Jack D. Law, R. Scott Herbst, Valeriy N. Romanovskiy, Igor V. Smirnov, Vasily A. Babain, Vyatcheslav M. Esimantovski
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Publication number: 20080107577Abstract: A method for treating an oil shale formation comprising dawsonite includes assessing a dawsonite composition of one or more zones in the formation. Heat from one or more heaters is provided to the formation such that different amounts of heat are provided to zones with different dawsonite compositions. The provided heat is allowed to transfer from the heaters to the formation. Fluids are produced from the formation.Type: ApplicationFiled: October 20, 2006Publication date: May 8, 2008Inventors: Harold J. Vinegar, Xueying Xie, David Scott Miller
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Patent number: 7338589Abstract: The present invention relates to a process for the recovery of gallium from Bayer process liquors. Bayer process liquor is obtained from alumina industries and contains 450 g/L Na2O, 80 g/L Al2O3 and 190±20 ppm of gallium. The present invention utilizes an organic and inorganic phase for a two stage separation process to recover gallium with high purity.Type: GrantFiled: March 20, 2003Date of Patent: March 4, 2008Assignee: Council of Scientific and Industrial ResearchInventors: Patcha Ramachandra Rao, Puvvada George Vijay Kumar, Archana Agrawal, Indranil Chattoraj
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Patent number: 7288184Abstract: Disclosed is a process for removing acids in a system in which aromatic hydrocarbons are separated from a mixture with aliphatic hydrocarbons. The aromatic hydrocarbons are extracted from the mixture using an extracting solvent. The aromatic hydrocarbons are stripped from the extracting solvent with steam and the steam is condensed to form water which is separated from the aromatic hydrocarbons. The separated water is passed through a basic anion exchange column and is then heated to produce the steam.Type: GrantFiled: December 10, 2004Date of Patent: October 30, 2007Assignee: ExxonMobil Chemical Patents Inc.Inventors: Marcus Lambertus Hendricus van Nuland, John Joseph Monson
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Patent number: 6846470Abstract: A method for producing an indium-containing aqueous solution having a reduced amount of metal impurities is provided. A method for producing an indium-containing aqueous solution having a reduced amount of metal impurities which comprises bringing an aqueous solution containing indium and metal impurities whose hydrogen ion concentration is adjusted at 0.5 mol/L to 3 mol/L into contact with a non-chelate ion-exchange resin to remove the metal impurities, and a method for producing an indium-containing aqueous solution having a reduced amount of metal impurities which comprises bringing an aqueous solution containing indium and metal impurities into contact with a chelate ion-exchange resin to remove the metal impurities are provided.Type: GrantFiled: February 5, 2002Date of Patent: January 25, 2005Assignee: Sumitomo Chemical Company, LimitedInventors: Takeshi Hattori, Shinji Fujiwara, Kunio Saegusa
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Patent number: 6838004Abstract: A nanoporous reactive adsorbent incorporates a relatively small number of relatively larger reactant, e.g., metal, enzyme, etc., particles (10) forming a discontinuous or continuous phase interspersed among and surrounded by a continuous phase of smaller adsorbent particles (12) and connected interstitial pores (14) therebetween. The reactive adsorbent can effectively remove inorganic or organic impurities in a liquid by causing the liquid to flow through the adsorbent. For example, silver ions may be adsorbed by the adsorbent particles (12) and reduced to metallic silver by reducing metal, such as ions, as the reactant particles (10). The column can be regenerated by backwashing with the liquid effluent containing, for example, acetic acid.Type: GrantFiled: September 7, 2000Date of Patent: January 4, 2005Assignee: Industrial Science & Technology Network, Inc.Inventors: Arthur Jing-Min Yang, Yuehua Zhang
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Patent number: 6673969Abstract: A new oxime mixture used as an extractant for metals, prepared from natural products containing alkylated phenols such as cashew nut shell liquid using mild reaction conditions, is expressed by the formula: The oxime mixture is suitable for extracting gallium from waste effluents from ore processing, such as Bayer liquor.Type: GrantFiled: February 28, 2002Date of Patent: January 6, 2004Assignee: Comselho Nacional de Desenvolvimento Cientifico e Tecnologico CNPQInventors: Peter R. Seidl, Ángelo Da Cunha Pinto, Arthur R. Menzel, Roberto O. Portela Couto
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Publication number: 20010031233Abstract: Compositions and methods for selectively binding metal ions from a source solution comprise using a polyhydroxypyridinone-containing ligand covalently bonded to a particulate solid support through a hydrophilic spacer of the formula SS-A-X-L (HOPO)n where SS is a particulate solid support such as silica or a polymeric bead, A is a covalent linkage mechanism, X is a hydrophilic spacer grouping, L is a ligand carrier, HOPO is a hydroxypyridinone appropriately spaced on the ligand carrier to provide a minimum of six functional coordination metal binding sites, and n is an integer of 3 to 6 with the proviso that when SS is a particulate organic polymer, A-X may be combined as a single covalent linkage.Type: ApplicationFiled: April 6, 2001Publication date: October 18, 2001Inventors: Ronald L. Bruening, Krzysztof E. Krakowiak
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Patent number: 6267936Abstract: Solvent extraction of one or more metal ions from an aqueous solution in the presence of hydrocarbon-soluble aminomethylenephosphonic acid derivatives.Type: GrantFiled: March 29, 1999Date of Patent: July 31, 2001Assignees: BASF Aktiengesellschaft, Instituto National de Engenharia e TecnologiaInventors: Francisco Delmas, Carlos Nogueira, Michael Ehle, Knut Oppenländer
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Patent number: 6241893Abstract: An amorphous potassium aluminosilicate filtration media which may be mixed with activated carbon filters water to remove oxygen, chlorines, hardness, alkalinity, ammonia, hydrogen, hydrogen sulfide, sodium sulfite and other contaminants. The particular sodium aluminosilicate is a porous amorphous material formed under ultraviolet light or sunlight to produce pore sizes of 60 Å to 250 Å at ambient temperatures (20° C.-35° C.) and low relative humidity (5%-20%). The media is initially formed as a microporous primarily amorphous gel containing Na2O, Al2O3, SiO2 and H2O. The sodium therein is displaced by potassium, whereby the filter removes impurities from water without introducing sodium. The potassium aluminosilicate may be a second stage filter to a first stage filter composed of a strong base anion media charged with potassium carbonate and/or bicarbonate.Type: GrantFiled: March 18, 1997Date of Patent: June 5, 2001Inventor: Ehud Levy
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Patent number: 6217622Abstract: A method of forming and classifying a precipitate containing large, coarse and fine particles from a super-saturated precipitating mother slurry, e.g. sodium aluminate from the Bayer process. The method comprises separating the precipitating mother slurry into a plurality of separate streams, introducing each stream into a vessel provided with an agitated lower zone and a quiescent upper zone to form the precipitate, with the large and coarse particles remaining as a slurry in the agitated lower zone and the fine particles migrating to the quiescent zone, removing product slurry from the lower agitated zone, and removing spent liquor containing the fine particles from the quiescent upper zone. The invention also provides apparatus for carrying out the method. The combined precipitation and partial classification (separation of fine particles) makes it possible to deal with high solids charges increasingly encountered in industrial processes.Type: GrantFiled: October 22, 1998Date of Patent: April 17, 2001Assignee: Alcan International LimitedInventor: Bryan Hiscox
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Patent number: RE36990Abstract: A method for the recovery of a metal from an organic complex thereof, said method comprising treating the complex with a weakly acid aqueous solution of an alkali metal, an alkaline earth metal or ammonium chloride having a chloride content of at least 4 molar whereby said complex is decomposed and metal ions are transferred to the aqueous solution.Type: GrantFiled: July 26, 1996Date of Patent: December 19, 2000Assignee: Zeneca LimitedInventors: Domenico C. Cupertino, Peter A. Tasker