Reactant Or Catalyst On Support Patents (Class 423/244.02)
  • Patent number: 11912575
    Abstract: The present disclosure provides compositions including method of producing H2, variable volume reactors, methods of using variable volume reactors, and the like.
    Type: Grant
    Filed: March 9, 2021
    Date of Patent: February 27, 2024
    Assignee: Georgia Tech Research Corporation
    Inventors: Andrei G. Fedorov, David M. Anderson
  • Patent number: 11890576
    Abstract: Disclosed herein is a method of regenerating a sorbent of gas in a capture process of said gas, wherein the capture process comprises recirculating the sorbent between a gas capturing system and regenerating reactor system, the method comprising the regenerating reactor system performing the steps of: receiving a solid sorbent to be regenerated, wherein the sorbent is a sorbent of carbon dioxide gas; generating heat by combusting a fuel with an oxidising agent in the presence of a catalyst; regenerating the sorbent by using the generated heat to indirectly heat the sorbent so that the sorbent releases carbon dioxide gas; outputting the regenerated sorbent; and outputting the released carbon dioxide gas. Advantages of the gas capture system include a higher efficiency than known techniques.
    Type: Grant
    Filed: March 8, 2018
    Date of Patent: February 6, 2024
    Assignee: FJELL BIODRY AS
    Inventors: De Chen, Kumar Ranjan Rout, Asbjørn Strand
  • Patent number: 10513441
    Abstract: A process for producing a magnesium aluminate spinel comprising the steps of: i) preparing a magnesium suspension containing a magnesium compound; ii) preparing an aluminum suspension containing an aluminum compound; iii) feeding the magnesium suspension and aluminum suspension independently into a spray dryer nozzle to form a mixed magnesium, aluminum suspension; iv) feeding the mixed magnesium, aluminium suspension from the spray dryer nozzle into a spray dryer to form a mixed magnesium and aluminum compound; and v) calcining the mixed magnesium and aluminum compound to generate a magnesium aluminate spinel.
    Type: Grant
    Filed: September 6, 2016
    Date of Patent: December 24, 2019
    Assignee: Sasol (USA) Corporation
    Inventors: Brian Peoples, Allison Hann
  • Patent number: 10512880
    Abstract: A system for removing carbon dioxide from a carbon dioxide laden gas mixture, the system comprising two groups of carbon dioxide removal structures, each removal structure within each group comprising a porous solid mass substrate supported on the structure; and a sorbent that is capable of adsorbing or binding to carbon dioxide, to remove carbon dioxide from a gas mixture, the sorbent being supported upon the surfaces of the porous mass substrate solid; an endless loop support for each of the groups of the removal structures, the endless loop support being so arranged as to move the support structures of each group along a closed curve while being exposed to a stream of the gas mixture; and a sealable regeneration box at one location along each of the endless loop supports, in which, when a porous solid mass substrate is sealed in place therein, carbon dioxide adsorbed upon the sorbent is stripped from the sorbent and the sorbent regenerated; each removal structural supporting a porous substrate in a positio
    Type: Grant
    Filed: February 17, 2018
    Date of Patent: December 24, 2019
    Inventors: Peter Eisenberger, Graciela Chichilnisky
  • Patent number: 10399404
    Abstract: A machine including a frame, a traction assembly and an actuator disposed between the frame and the traction assembly is disclosed. The actuator is configured to raise the frame to a serviceable height relative to the traction assembly. The machine further includes a support rod configured to be disposed between the frame and the traction assembly when the frame is at the serviceable height such that the support rod is magnetically held on one of the frame and the traction assembly and the support rod defines a gap with other of the frame and the traction assembly. The support rod is configured to abut the other of the frame and the traction assembly when a height of the frame relative to the traction assembly decreases to a height less than the serviceable height.
    Type: Grant
    Filed: October 30, 2017
    Date of Patent: September 3, 2019
    Assignee: Caterpillar Paving Products Inc.
    Inventors: Roger Allen Hedlund, Brad Green
  • Patent number: 9925488
    Abstract: A system for removing carbon dioxide from a carbon dioxide laden gas mixture, the system comprising two groups of carbon dioxide removal structures, each removal structure within each group comprising a porous solid mass substrate supported on the structure and a sorbent that is capable of adsorbing or binding to carbon dioxide, to remove carbon dioxide from a gas mixture, the sorbent being supported upon the surfaces of the porous mass substrate solid; an endless loop support for each of the groups of the removal structures, the endless loop support being so arranged as to move the support structures of each group along a closed curve while being exposed to a stream of the gas mixture; and a sealable regeneration box at one location along each of the endless loop supports, in which, when a porous solid mass substrate is sealed in place therein, carbon dioxide adsorbed upon the sorbent is stripped from the sorbent and the sorbent regenerated; each removal structural supporting a porous substrate in a position
    Type: Grant
    Filed: December 31, 2014
    Date of Patent: March 27, 2018
    Inventors: Peter Eisenberger, Graciela Chichilnisky
  • Patent number: 9266062
    Abstract: The present invention discloses a method of removing sulfur oxides and/or nitrogen oxides in a regeneration flue gas emitted from a regenerator of a catalytic cracking plant and recovering the elemental sulfur and an apparatus therefor.
    Type: Grant
    Filed: July 27, 2012
    Date of Patent: February 23, 2016
    Assignee: China Petroleum & Chemical Corporation
    Inventors: Dawei Guo, Jiushun Zhang, Anguo Mao, Chaogang Xie, Jun Fu, Wei Wang, Jingchuan Yu
  • Patent number: 9006508
    Abstract: A method of removing mercury and/or sulfur from a fluid stream comprising contacting the fluid stream with a sorbent comprising a core and a porous shell formed to include a plurality of pores extending therethrough and communicating with the core. The core comprises a copper compound selected from the group consisting of a basic copper oxysalt, a copper oxide, and a copper sulfide.
    Type: Grant
    Filed: February 6, 2012
    Date of Patent: April 14, 2015
    Assignee: UOP LLC
    Inventors: Vladislav Ivanov Kanazirev, Dante A. Simonetti, Peter Rumfola, III
  • Patent number: 8974577
    Abstract: Articles for capturing or separating a target gas from a gas stream may include a porous substrate such as a flexible sheet or mat, or a rigid ceramic monolith impregnated or coated with a sorbent composition. The sorbent composition may include a polyamine and a coexistent polymer chemically bonded to the polyamine. The polyamine may include a polyethylenimine. The coexistent polymer may include a polyurethane, a polyolefin-acrylic acid copolymer, or a combination thereof. The sorbent composition may be substantially less water-insoluble than compositions containing only a polyamine and may have high durability and good adsorption capacity for acidic target gases such as carbon dioxide. Methods for preparing the articles using aqueous polymer solutions are provided. Methods for capturing or separating target gases using the articles are provided.
    Type: Grant
    Filed: April 23, 2013
    Date of Patent: March 10, 2015
    Assignee: Corning Incorporated
    Inventors: Dayue David Jiang, Steven Bolaji Ogunwumi
  • Patent number: 8951491
    Abstract: The preparation of nano-oxide coated adsorbent, which is useful for treatment of toxic gases, by coating of composite materials containing hydrotalcite over ceramic monolithic substrates. Oxides and salts of metals are reacted in a known manner to prepare hydrotalcites or mixed metal layered hydroxides such as Mg—Al, Ca—Al, Zn—Al, Zn—Cr type possessing positive layer charge, from which a stable gel is prepared by adding swellable clay, e.g., montmorillonite etc. in different hydrotalcite:clay ratio in an aqueous medium and homogenizing the same with high speed homogenizer and ultrasonicator in a high intensity ultrasonic processor. The gel is dip-coated over cordierite/mulite honey-comb monolithic supports. The dip-coated monoliths are dried and calcined to develop the alumino-silicate supported nano-oxide coats over honey-comb ceramic substrates for carrying out adsorption of H2S and SO2 gas in a He flow in various flow rates at 400 to 1000° C. temperature in a cylindrical quartz tube.
    Type: Grant
    Filed: January 3, 2014
    Date of Patent: February 10, 2015
    Assignee: Council of Scientific & Industrial Research
    Inventors: Mridusmita Mishra, Rajib Lochan Goswamee
  • Patent number: 8894956
    Abstract: Disclosed is an sorbent for removing sulfur dioxide (SO2) contained in combustion flue gases or in the atmosphere by using a diamine-based ionic liquid or a diamine compound supported by a polymer resin. To be specific, the present invention relates to a method of using a tertiary diamine compound immobilized on a polymer surface as a SO2 sorbent and also relates to a novel sorbent for absorbing or adsorbing a sulfur dioxide hydrate (SO2.H2O) formed by a bond between SO2 and water.
    Type: Grant
    Filed: November 22, 2013
    Date of Patent: November 25, 2014
    Assignee: Korea Institute of Science and Technology
    Inventors: Hyun Joo Lee, Seung Rok Lim, Kean Im Lee, Chang Soo Kim, Hoon Sik Kim, Ji Sik Choi, Sang Deuk Lee
  • Patent number: 8883108
    Abstract: This invention relates to a catalyst material, and its method of making and manufacture, useful for a diversity of chemical production processes as well as various emission control processes. More specifically, it relates to a catalyst composition, preferably comprising a metal oxide felt substrate, with one or more functional surface active constituents integrated on and/or in the substrate surface, which can be used in the removal of sulfur and sulfur compounds from hot gases as well as acting to trap solid particulates and trace metals within these hot gases.
    Type: Grant
    Filed: June 14, 2011
    Date of Patent: November 11, 2014
    Assignee: UOP LLC
    Inventors: Manuela Serban, Lisa M. King, Alakananda Bhattacharyya, Tom N. Kalnes, Kurt M. Vanden Bussche
  • Patent number: 8877153
    Abstract: Novel adsorbents and their use in a process for the removal of sulfur compounds from distillate fuels are described herein. The novel adsorbents are comprised of nanocrystals of Ni having adsorbed on their surface phosphorus and/or phosphine species, which nanocrystals can be distributed in a micro-/meso-porous support material.
    Type: Grant
    Filed: June 6, 2012
    Date of Patent: November 4, 2014
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Mordechay Herskowitz, Miron Landau, Iehudit Reizer, Alberto Ravella, James E. Kegerreis
  • Publication number: 20140294710
    Abstract: A method of preparing a catalyst composition suitable for removing sulfur from a catalytic reduction system and the catalyst composition prepared by the method are provided. The method of preparation of a catalyst composition, comprises: combining a metal oxide precursor, a catalyst metal precursor and an alkali metal precursor in the presence of a templating agent; hydrolyzing and condensing to form an intermediate product that comprises metal oxide, alkali metal oxide, and catalyst metal; and calcining to form a templated amorphous metal oxide substrate having a plurality of pores wherein the alkali metal oxide and catalyst metal are dispersed in an intermixed form in the metal oxide substrate.
    Type: Application
    Filed: June 16, 2014
    Publication date: October 2, 2014
    Applicant: General Electric Company
    Inventors: Oltea Puica Siclovan, Daniel George Norton, Larry Neil Lewis, Dan Hancu, Xiaoying Bao, Robert Burch, Hardacre Christopher, Chansai Sarayute
  • Publication number: 20140186248
    Abstract: The preparation of nano-oxide coated adsorbent, which is useful for treatment of toxic gases, by coating of composite materials containing hydrotalcite over ceramic monolithic substrates. Oxides and salts of metals are reacted in a known manner to prepare hydrotalcites or mixed metal layered hydroxides such as Mg—Al, Ca—Al, Zn—Al, Zn—Cr type possessing positive layer charge, from which a stable gel is prepared by adding swellable clay, e.g., montmorillonite etc. in different hydrotalcite:clay ratio in an aqueous medium and homogenising the same with high speed homogeniser and ultrasonicator in a high intensity ultrasonic processor. The gel is dip-coated over cordierite/mulite honey-comb monolithic supports. The dip-coated monoliths are dried and calcined to develop the alumino-silicate supported nano-oxide coats over honey-comb ceramic substrates for carrying out adsorption of H2S and SO2 gas in a He flow in various flow rates at 400 to 1000° C. temperature in a cylindrical quartz tube.
    Type: Application
    Filed: January 3, 2014
    Publication date: July 3, 2014
    Applicant: Council of Scientific & Industrial Research
    Inventors: Mridusmita MISHRA, Rajib Lochan GOSWAMEE
  • Publication number: 20140161701
    Abstract: A particulate desulphurisation material is described including one or more copper compounds supported on a zinc oxide support material, wherein the desulphurisation material has a copper content in the range 0.1 to 5.0% by weight and a tapped bulk density?1.55 kg/l.
    Type: Application
    Filed: April 12, 2012
    Publication date: June 12, 2014
    Applicant: JOHNSON MATTHEY PUBLIC LIMITED COMPANY
    Inventors: Norman Macleod, Gordon Edward Wilson
  • Patent number: 8668894
    Abstract: The present invention relates to a method for processing a sulfur-containing gas and a hydrogenation catalyst used therefor. The method comprises introducing the sulfur-containing gas into the tail gas hydrogenation unit of a sulfur recovery device, processing it with the hydrogenation catalyst of the present invention, and absorbing the hydrogenated tail gas with a solvent. The hydrogenation catalyst comprises from 0.5 to 3 wt. % of an active component nickel oxide, from 1 to 4 wt. % of an active component cobalt oxide, from 8 to 20 wt. % of an active component molybdenum oxide or tungsten oxide, from 1 to 5 wt. % of a deoxidation auxiliary agent, from 10 to 40 wt. % of TiO2, the balance being ?-Al2O3, based on the weight of the catalyst.
    Type: Grant
    Filed: August 4, 2011
    Date of Patent: March 11, 2014
    Assignees: China Petroleum & Chemical Corporation, Research Institute of Petroleum Processing, Sinopec
    Inventors: Aihua Liu, Yiling Zhang, Xingzhong Xu, Jianli Liu, Weidong Tao, Jinshan Xu
  • Publication number: 20130302479
    Abstract: A sulfur dioxide reducing composition includes an adsorber and an absorber on the adsorber. The adsorber attracts and holds sulfur dioxide and the absorber reacts irreversibly with the sulfur dioxide.
    Type: Application
    Filed: May 11, 2012
    Publication date: November 14, 2013
    Applicant: MULTISORB TECHNOLOGIES, INC.
    Inventors: Thomas H. Powers, George E. McKedy
  • Publication number: 20130302234
    Abstract: A high capacity filtration media, method of preparing the media, and method of treating a fluid stream with the media are provided. The media contain a porous substrate impregnated with high concentrations of a permanganate. Preferably, the media includes a porous substrate impregnated with at least about 8% permanganate by weight. The media can optionally contain sodium bicarbonate. Improved capacity for the removal of undesirable compounds such as ethylene, formaldehyde, hydrogen sulfide and methyl mercaptan are achieved.
    Type: Application
    Filed: July 19, 2013
    Publication date: November 14, 2013
    Inventor: William G. England
  • Patent number: 8568679
    Abstract: Disclosed is a process for the removal of sulfur from a fuel gas stream that additionally contains carbon dioxide and a light olefin as well as an organic sulfur compound. The process includes hydrotreating the fuel gas stream followed by a catalytic reduction of the resulting hydrotreated fuel gas to remove the carbonyl sulfide contained therein that is yielded in the hydrotreating step as a result of the equilibrium reaction of hydrogen disulfide with carbon dioxide to yield carbonyl sulfide and water.
    Type: Grant
    Filed: May 23, 2008
    Date of Patent: October 29, 2013
    Assignee: Shell Oil Company
    Inventor: Gary Lee Ripperger
  • Patent number: 8562930
    Abstract: Hazardous process gases are heated to auto ignition temperatures by rods and cylinders in a heating chamber. The heated gases and oxygen mix in a combustion chamber, and the gases ignite and combust. Air is introduced to cool the hot combustion products. Particles are separated from the cooled gases. Pure non hazardous gases and air are exhausted.
    Type: Grant
    Filed: February 15, 2012
    Date of Patent: October 22, 2013
    Assignee: Innovative Engineering Solutions, Inc.
    Inventor: Samir S. Shiban
  • Publication number: 20130230721
    Abstract: A method for producing a catalyst using an additive layer method includes: (i) forming a layer of a powdered catalyst or catalyst support material, (ii) binding or fusing the powder in said layer according to a predetermined pattern, (iii) repeating (i) and (ii) layer upon layer to form a shaped unit, and (iv) optionally applying a catalytic material to said shaped unit.
    Type: Application
    Filed: August 22, 2011
    Publication date: September 5, 2013
    Applicant: JOHNSON MATTHEY PLC
    Inventor: Duncan Roy Coupland
  • Publication number: 20130224094
    Abstract: Oxidative and reductive methods are described for the cost-effective destruction of an ammonia-bearing gas stream, potentially containing minor but significant quantities of hydrogen sulfide (H2S), in a conventional Claus sulfur recovery tail gas treating unit, using controlled rates and compositions of combustion gases in order to obtain the temperatures necessary for the desired destruction of unwanted combustibles.
    Type: Application
    Filed: February 5, 2013
    Publication date: August 29, 2013
    Applicant: WORLEYPARSONS GROUP, INC.
    Inventor: WorleyParsons Group, Inc.
  • Publication number: 20130216462
    Abstract: The present invention relates to a method for processing a sulfur-containing gas and a hydrogenation catalyst used therefor. Said method comprises introducing the sulfur-containing gas into the tail gas hydrogenation unit of a sulfur recovery device, processing it with the hydrogenation catalyst of the present invention, absorbing the hydrogenated tail gas with a solvent and then regenerating, the regenerated hydrogen sulfide being recycled to the Claus unit to recover sulfur, the clean tail gas being incinerated in an incinerator to be discharged after reaching the standards. Said sulfur-containing gas comprises from 0 to 6 vol. % of sulfur dioxide and from 0 to 3 vol. % of oxygen, and has a temperature of from 100 to 200° C. The hydrogenation catalyst of the present invention comprises from 0.5 to 3 wt. % of an active component nickel oxide, from 1 to 4 wt. % of an active component cobalt oxide, from 8 to 20 wt. % of an active component molybdenum oxide or tungsten oxide, from 1 to 5 wt.
    Type: Application
    Filed: August 4, 2011
    Publication date: August 22, 2013
    Applicant: CHINA PETROLEUM & CHEMICAL CORPORATION
    Inventors: Aihua Liu, Yiling Zhang, Xingzhong Xu, Jianli Liu, Weidong Tao, Jinshan Xu
  • Publication number: 20130202510
    Abstract: A method of removing H2S, a mercaptan, and/or COS from a fluid stream is presented. The method comprises contacting the fluid stream with a sorbent comprising Cu2O.
    Type: Application
    Filed: February 6, 2012
    Publication date: August 8, 2013
  • Publication number: 20130202511
    Abstract: A method of removing mercaptans, heterocyclic sulfur compounds, and/or COS from a fluid stream comprising contacting the fluid stream with a sorbent comprising a mixture of Cu2O and metallic copper.
    Type: Application
    Filed: February 6, 2012
    Publication date: August 8, 2013
  • Patent number: 8465712
    Abstract: A method and system for desulfurization comprising first and second metal oxides; a walled enclosure having an inlet and an exhaust for the passage of gas to be treated; the first and second metal oxide being combinable with hydrogen sulfide to produce a reaction comprising a sulfide and water; the first metal oxide forming a first layer and the second metal oxide forming a second layer within the walled surroundings; the first and second layers being positioned so the first layer removes the bulk amount of the hydrogen sulfide from the treated gas prior to passage through the second layer, and the second layer removes substantially all of the remaining hydrogen sulfide from the treated gas; the first metal oxide producing a stoichiometrical capacity in excess of 500 mg sulfur/gram; the second metal oxide reacts with the hydrogen sulfide more favorably but has a stoichometrical capacity which is less than the first reactant; whereby the optimal amount by weight of the first and second metal oxides is achieved
    Type: Grant
    Filed: November 12, 2009
    Date of Patent: June 18, 2013
    Assignee: The United States of America as represented by the Secretary of the Army
    Inventors: Charles Rong, Rongzhong Jiang, Deryn Chu
  • Patent number: 8377173
    Abstract: The present invention generally relates to a process for the formation of a CO2-selective absorption material and/or sulfur-selective absorption material. In one embodiment, the present invention relates to a process for the formation of a CO2-selective absorption material that comprises providing a solid material, providing an amine source, contacting the solid material with the amine source to absorb amine molecules on the surface of the solid material, and contacting the absorbing amine molecules on the solid material surface with a CO2 stream such that upon contact with the amine and the solid material, CO2 binds with the amine functional group of the amine molecule, reducing the potential for the interaction of the amine functional group with the solid surface and increasing amine sites available for CO2 capture.
    Type: Grant
    Filed: November 7, 2008
    Date of Patent: February 19, 2013
    Assignee: The University of Akron
    Inventor: Steven Chuang
  • Publication number: 20120329644
    Abstract: A catalyst composition, a method of preparation of catalyst composition, a catalytic reduction system including the catalyst composition and a system using the catalytic reduction system are provided. The catalyst composition includes a templated amorphous metal oxide substrate, a catalyst material, and a sulfur scavenger material. The catalyst material includes a catalyst metal disposed on the templated metal oxide substrate and the sulfur scavenger includes an alkali metal.
    Type: Application
    Filed: June 21, 2011
    Publication date: December 27, 2012
    Applicant: GENERAL ELECTRIC COMPANY
    Inventors: Oltea Puica Siclovan, Daniel George Norton, Larry Neil Lewis, Dan Hancu, Xiaoying Bao, Robert Burch, Christopher Hardacre, Sarayute Chansai
  • Patent number: 8323603
    Abstract: A method for producing a substantially desulfurized a hydrocarbon fuel stream at temperatures less than 100° C. The method includes providing a nondesulfurized fuel cell hydrocarbon fuel stream that may include water and passing the fuel stream sequentially through a zeolite Y adsorbent and a selective sulfur adsorbent. The zeolite Y adsorbent may be exchanged with copper ions. The method produces a substantially desulfurized hydrocarbon fuel stream containing less than 50 ppb sulfur.
    Type: Grant
    Filed: June 5, 2009
    Date of Patent: December 4, 2012
    Assignee: Sud-Chemie Inc.
    Inventors: Chandra C Ratnasamy, Jon P. Wagner, R. Steve Spivey, Hans-Georg Anfang
  • Patent number: 8314047
    Abstract: A process for the preparation of a desulfurization material includes: (i) forming a zinc/aluminium hydrotalcite composition, and (ii) calcining the composition to form a zinc oxide/alumina material, in which one or more nickel compounds are included in the hydrotalcite formation step, and/or are impregnated onto the hydrotalcite composition and/or the calcined zinc oxide/alumina material, and the resulting composition dried and recovered.
    Type: Grant
    Filed: February 25, 2009
    Date of Patent: November 20, 2012
    Assignee: Johnson Matthey PLC
    Inventors: Norman Macleod, Antonio Chica Lara, Avelino Corma Canos, Yonhy Saavedra Lopez
  • Patent number: 8308848
    Abstract: Gas desulfurization sorbents and methods using them for removal of sulfur from gas streams, particularly at high temperatures ranging from 500 to 1000° C. The sorbents and methods are of particular application to produce a sulfur-clean feed from reformate gas generated from readily available transportation fuels containing sulfur. Sorbents of the invention can reduce the sulfur concentration in reformate gas to parts per billion on volume basis (ppbv) levels over a large range of temperatures. Sorbent materials of this invention comprise a nickel phase dispersed on a particulate support or a monolith support. The support can be a high surface area support with surface area of 100 m2/g or higher. The invention also provides systems for desulfurizing reformate gas and systems for providing a desulfurized gas to a fuel cell, particularly a solid oxide fuel cell.
    Type: Grant
    Filed: November 27, 2009
    Date of Patent: November 13, 2012
    Assignee: TDA Research, Inc.
    Inventors: Gokhan Alptekin, Margarita DuBovik, Ambalavanan Jayaraman
  • Patent number: 8236262
    Abstract: A particulate desulfurization material includes one or more nickel compounds, a zinc oxide support material, and one or more alkali metal compounds wherein the nickel content of the material is in the range 0.3 to 10% by weight and the alkali metal content of the material is in the range 0.2 to 10% by weight. A method of making the desulfurization material includes the steps: (i) contacting a nickel compound with a particulate zinc support material and an alkali metal compound to form an alkali-doped composition, (ii) shaping the alkali-doped composition, and (iii) drying, calcining, and optionally reducing the resulting material. The desulfurization material may be used to desulfurize hydrocarbon gas streams with reduced levels of hydrocarbon hydrogenolysis.
    Type: Grant
    Filed: February 25, 2009
    Date of Patent: August 7, 2012
    Assignee: Johnson Matthey PLC
    Inventors: Gavin Potter, Gordon Edward Wilson, Norman Macleod, Antonio Chica Lara, Avelino Corma Canos, Yonhy Saavedra Lopez
  • Patent number: 8142748
    Abstract: Disclosed is a composition useful in the hydrolysis of sulfur compounds that are contained in a gas stream. The composition comprises alumina, a group VI metal component and a group VIII metal component. The composition has a pore structure such that a large percentage of its total pore volume is contained within the pores having a pore diameter greater than 10,000 angstroms.
    Type: Grant
    Filed: September 11, 2008
    Date of Patent: March 27, 2012
    Assignee: Shell Oil Company
    Inventor: Stephen Neil Massie
  • Patent number: 8083933
    Abstract: A process for removing organic sulfur from a fuel gas stream that further contains light olefins by catalytic hydrodesulfurization to yield a treated fuel gas having an very low concentration of organic sulfur. The effluent of the catalytic hydrodesulfurization reactor may be cooled with a portion thereof being recycled and introduced along with the fuel gas stream that is charged to the hydrodesulfurization reactor. The remaining, unrecycled portion of the effluent may further be treated to remove the hydrogen sulfide that is yielded from by the hydrodesulfurization of the fuel gas stream.
    Type: Grant
    Filed: April 10, 2008
    Date of Patent: December 27, 2011
    Assignee: Shell Oil Company
    Inventor: Gary Lee Ripperger
  • Patent number: 8052935
    Abstract: A system for removing sulfur from a gaseous stream includes (a) a reaction bed for receiving the gaseous stream and for reacting sulfur dioxide and at least some of the hydrogen sulfide of the gaseous stream into elemental sulfur to provide an elemental sulfur stream and a first product stream; and (b) a circulating fluidized bed comprising (i) a first region for receiving the first product stream and using a sulfur adsorption material to adsorb and remove any remaining hydrogen sulfide from the first product stream to generate saturated sulfur adsorption material and a second product stream substantially free of sulfur; and (ii) a second region for receiving a regeneration stream and for using the regeneration stream to regenerate the saturated sulfur adsorption material and to generate the sulfur dioxide.
    Type: Grant
    Filed: April 30, 2009
    Date of Patent: November 8, 2011
    Assignee: General Electric Company
    Inventors: Thomas Frederick Leininger, Ke Liu, Wei Wei, Rizeq George Rizeq
  • Patent number: 8043989
    Abstract: A system is provided for desulfurizing a hydrocarbon fuel containing a light amount of methanol and a slight amount of water. The desulfurization system uses a Y-type zeolite-based desulfurizing agent containing at least copper arranged upstream of the system and an X-type zeolite-based desulfurizing agent containing at least silver arranged downstream of the system and thus can maintain desulfurization effect for a long period of time.
    Type: Grant
    Filed: March 4, 2009
    Date of Patent: October 25, 2011
    Assignee: Nippon Oil Corporation
    Inventors: Yoshiyuki Nagayasu, Atsushi Segawa, Kazunori Miyazawa, Yoshihiro Kobori
  • Publication number: 20110243824
    Abstract: This invention relates to a catalyst material, and its method of making and manufacture, useful for a diversity of chemical production processes as well as various emission control processes. More specifically, it relates to a catalyst composition, preferably comprising a metal oxide felt substrate, with one or more functional surface active constituents integrated on and/or in the substrate surface, which can be used in the removal of sulfur and sulfur compounds from hot gases as well as acting to trap solid particulates and trace metals within these hot gases.
    Type: Application
    Filed: June 14, 2011
    Publication date: October 6, 2011
    Applicant: UOP LLC
    Inventors: Manuela Serban, Lisa M. King, Alakananda Bhattacharyya, Tom N. Kalnes, Kurt M. Vanden Bussche
  • Publication number: 20110200507
    Abstract: A process for removing sulfur compounds from a hydrocarbonaceous gas mixture, which comprises contacting the hydrocarbonaceous gas mixture with an adsorber material comprising copper oxide on magnesium silicate as support material.
    Type: Application
    Filed: August 27, 2009
    Publication date: August 18, 2011
    Applicant: BASF SE
    Inventors: Jochen Steiner, Alexander Schäfer, Annebart Engbert Wentink, Ekkehard Schwab, Helmut Boos, Patrick Amrhein
  • Patent number: 7998447
    Abstract: A method of removing hydrogen sulfide from an emissions stream is disclosed, wherein the method includes directing the emissions stream into a hydrogen sulfide converter having a metal oxide catalyst, adsorbing the hydrogen sulfide in the emissions stream to the metal oxide catalyst in the hydrogen sulfide converter, reacting the hydrogen sulfide with at least one of an oxidant and a reductant in the hydrogen sulfide converter to chemically transform the hydrogen sulfide, and adjusting an air-fuel ratio of the emissions stream based on exhaust temperature of an emission control device, where the adjustment varies a duration of at least one of lean and rich operation to perform the adsorbing and reacting even as exhaust temperature varies.
    Type: Grant
    Filed: January 28, 2004
    Date of Patent: August 16, 2011
    Assignee: Ford Global Technologies, LLC
    Inventors: Shane Elwart, Gopichandra Surnilla, Joseph R. Theis
  • Publication number: 20110117001
    Abstract: A system and method for removing sulfur-containing contaminants from indoor air includes a panel system having a first layer and a second layer. The first layer can include a base media onto which sodium bicarbonate is attached. The second layer can include a base media onto which activated carbon is attached. Indoor air including sulfur-containing contaminants can contact and pass through the first layer. Sulfuric acid can react with the sodium bicarbonate to produce sodium sulfate, which can, in turn, act as a drying agent for organic sulfur-containing contaminants in the indoor air, such as carbon disulfide and carbonyl sulfide. As a result of such drying, the second layer can more effectively trap and/or bind (adsorb) the organic sulfur-containing contaminants so that these contaminants are removed from the contaminated air. The treated air can be returned to an indoor space of the structure.
    Type: Application
    Filed: July 20, 2010
    Publication date: May 19, 2011
    Inventors: Ronald G. HUGGINS, Carl M. SABATELLO, Paul T. SABATELLO
  • Publication number: 20110110836
    Abstract: A method and system for desulfurization comprising first and second metal oxides; a walled enclosure having an inlet and an exhaust for the passage of gas to be treated; the first and second metal oxide being combinable with hydrogen sulfide to produce a reaction comprising a sulfide and water; the first metal oxide forming a first layer and the second metal oxide forming a second layer within the walled surroundings; the first and second layers being positioned so the first layer removes the bulk amount of the hydrogen sulfide from the treated gas prior to passage through the second layer, and the second layer removes substantially all of the remaining hydrogen sulfide from the treated gas; the first metal oxide producing a stoichiometrical capacity in excess of 500 mg sulfur/gram; the second metal oxide reacts with the hydrogen sulfide more favorably but has a stoichiometrical capacity which is less than the first reactant; whereby the optimal amount by weight of the first and second metal oxides is achieve
    Type: Application
    Filed: November 12, 2009
    Publication date: May 12, 2011
    Applicant: U.S. Government as represented by the Secretary of the Army
    Inventors: CHARLES RONG, RONGZHONG JIANG, DERYN CHU
  • Patent number: 7931882
    Abstract: Compositions and associated methods directed to the removal of sulfurous compounds from air are presented herein. The compositions and methods may be able to treat air with H2S concentrations of at least 1000 ppm. The compositions and associated methods are used to remove sulfurous compounds from air associated with wastewater systems in various aspects.
    Type: Grant
    Filed: December 19, 2008
    Date of Patent: April 26, 2011
    Assignee: Syneco Systems Inc
    Inventors: Leigh Falkman, Dennis W. Van Dover
  • Patent number: 7906088
    Abstract: Mixing small amounts of an inorganic halide, such as NaCl, to basic copper carbonate followed by calcination at a temperature sufficient to decompose the carbonate results in a significant improvement in resistance to reduction of the resulting copper oxide. The introduction of the halide can be also achieved during the precipitation of the carbonate precursor. These reduction resistant copper oxides can be in the form of composites with alumina and are especially useful for purification of gas or liquid streams containing hydrogen or other reducing agents. These reduction resistant copper oxides can function at near ambient temperatures.
    Type: Grant
    Filed: August 26, 2009
    Date of Patent: March 15, 2011
    Assignee: UOP LLC
    Inventors: Vladislav I. Kanazirev, Peter Rumfola, III
  • Publication number: 20110014105
    Abstract: A particulate desulphurisation material includes one or more nickel compounds, a zinc oxide support material, and one or more alkali metal compounds wherein the nickel content of the material is in the range 0.3 to 10% by weight and the alkali metal content of the material is in the range 0.2 to 10% by weight. A method of making the desulphurisation material includes the steps: (i) contacting a nickel compound with a particulate zinc support material and an alkali metal compound to form an alkali-doped composition, (ii) shaping the alkali-doped composition, and (iii) drying, calcining, and optionally reducing the resulting material. The desulphurisation material may be used to desulphurise hydrocarbon gas streams with reduced levels of hydrocarbon hydrogenolysis.
    Type: Application
    Filed: February 25, 2009
    Publication date: January 20, 2011
    Applicant: JOHNSON MATTHEY PLC
    Inventors: Gavin Potter, Gordon Edward Wilson, Norman Macleod, Antonio Chica Lara, Avelino Corma Canos, Yonhy Saavedra Lopez
  • Patent number: 7851401
    Abstract: The invention concerns solids comprising a single tungsten oxide layer on a zirconia support and/or titanium dioxide support, characterized in that the tungsten exhibits tetrahedral co-ordination, before and after calcining. The invention also concerns the method for preparing the solids, and their uses as acid catalysis reactions catalyst.
    Type: Grant
    Filed: July 1, 2003
    Date of Patent: December 14, 2010
    Assignee: Centre National de la Recherche Scientifique (C.N.R.S.)
    Inventors: Francois Figueras, Nadine Essayem, Cyril Feche, Stephane Loridant, Jorge Palomeque, Georges Gelbard
  • Publication number: 20100296990
    Abstract: A solid air filtration medium includes an impregnate with an organic amine and an inorganic metal salt. The medium has from about 0.1 to about 25% by weight of impregnate. The impregnate contains from about 0.1 to about 5% by weight organic amine, and the organic amine includes aqueous urea, solid urea, melamine or mixtures thereof. The impregnate contains from about 0.1 to about 5% by weight metal salt, and the metal salt includes magnesium oxide, calcium oxide or mixtures thereof. The impregnate optionally further includes a surfactant such as polyacrylic acid. Methods for forming a solid air filtration medium having an impregnate containing an organic amine and an inorganic metal salt and methods for removing contaminants from a fluid stream are also provided.
    Type: Application
    Filed: March 18, 2010
    Publication date: November 25, 2010
    Applicant: Purafil, Inc.
    Inventor: William G. England
  • Publication number: 20100284879
    Abstract: For the conversion of sulphur-containing compounds present in a gas comprising H2S and sulphur-containing compounds into additional H2S, a step A for bringing said gas into contact with a reducing gas in the presence of a hydrogenation catalyst comprising at least cobalt, molybdenum and an alumina support, the sum of the quantities of cobalt and molybdenum, calculated in the oxide form, being in the range of 3% to 25% by weight, the surface area of said alumina being more than 140 m2/g. In step B at least a fraction of effluent gas from step A is contacted with a catalyst comprising at least one alkaline-earth element, at least one dopant being iron, cobalt or molybdenum and at least one compound of the group constituted by titanium oxide and zirconium oxide, said catalyst for step B) being either in the form of a bulk oxide comprising only said oxides or in the form of a supported oxide.
    Type: Application
    Filed: October 29, 2008
    Publication date: November 11, 2010
    Applicant: IFP
    Inventors: Christophe Nedez, Eric Roisin
  • Publication number: 20100233054
    Abstract: The invention relates to a catalyst for the desulfurization of hydrocarbon-comprising gases, which comprises a support material, with the exception of activated carbons and zeolites, and a silver-comprising active composition, wherein the catalyst has a pore structure having a maximum number of the pores in a pore diameter range from 6 to 11 nm. The invention further provides processes for producing such a catalyst, its use for the desulfurization of hydrocarbon-comprising gases, in particular in fuel cell applications, and a process for the desulfurization of hydrocarbon-comprising gases.
    Type: Application
    Filed: August 4, 2008
    Publication date: September 16, 2010
    Applicant: BASF SE
    Inventors: Jochen Steiner, Markus Hoelzle, Heiko Urtel
  • Patent number: 7771685
    Abstract: A flue gas desulfurization process and system that utilize ammonia as a reactant, and in which any hydrogen sulfide and/or mercaptans within the ammonia are separated during the desulfurization process so as to prevent their release into the atmosphere. The process and system entail absorbing acidic gases from a flue gas with a scrubbing media containing ammonium sulfate to produce a stream of scrubbed flue gas, collecting the scrubbing media containing the absorbed acidic gases, injecting into the collected scrubbing media a source of ammonia that is laden with hydrogen sulfide and/or mercaptans so that the injected ammonia is absorbed into and reacted with the collected scrubbing media, stripping the hydrogen sulfide and/or mercaptans from the collected scrubbing media by causing the hydrogen sulfide and/or mercaptans to exit the collected scrubbing media as stripped gases, and collecting the stripped gases without allowing the stripped gases to enter the stream of scrubbed flue gas.
    Type: Grant
    Filed: April 25, 2008
    Date of Patent: August 10, 2010
    Assignee: Marsulex Environmental Technologies, Corp
    Inventor: Eli Gal