Employing Ammonia As Reactant Patents (Class 423/375)
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Patent number: 9123786Abstract: A means for selectively electrically connecting an electrical interconnect line, such as a bit line of a memory cell, with an associated contact stud and electrically isolating the interconnect line from other partially underlying contact studs for other electrical features, such as capacitor bottom electrodes. The interconnect line can be formed partially-connected to all contact studs, thereby allowing the electrical features to be formed in closer proximity to one another for higher levels of integration, and in subsequent steps of fabrication, the contact studs associated with memory cell features other than the interconnect line can be isolated from the interconnect line by the removal of a silicide cap, or the selective etching of a portion of these contact studs, and the formation of an insulating sidewall between the non-selected contact stud and the interconnect line.Type: GrantFiled: June 30, 2014Date of Patent: September 1, 2015Assignee: MICRON TECHNOLOGY, INC.Inventor: John M. Drynan
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Patent number: 8906334Abstract: The invention includes an apparatus and process for the catalytic production of HCN from a feed gas of ammonia and a hydrocarbon gas by means of heat tubes supplying heat to the feed gas stream and heat tubes for removal of heat from the products. The invention further includes a process for N2O abatement comprising transferring heat from an exothermic N2O degradation reaction through a heat pipe.Type: GrantFiled: May 14, 2008Date of Patent: December 9, 2014Assignee: INVISTA North America S.a r.l.Inventor: Colin S. Slaten
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Publication number: 20140147365Abstract: The invention relates to a hydrocyanic acid containing bioresourced carbon, and to a method for producing a raw material mainly containing the same by reacting ammonia with methane or methanol optionally in the presence of air and/or oxygen, characterized in that at least one of the reagents selected from ammonia, methane and methanol is obtained from a biomass. The invention also relates to the uses of the raw material for producing acetone cyanohydrin, adiponitrile, methionine or methionine hydroxyl-analog, and sodium cyanide.Type: ApplicationFiled: January 31, 2014Publication date: May 29, 2014Applicant: ARKEMA FRANCEInventor: JEAN-LUC DUBOIS
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Patent number: 8551430Abstract: A method for the selective catalytic reduction of nitrogen oxides (NOx) in the exhaust gas from an internal combustion engine includes providing an exhaust system having: an SCR catalytic converter, a reagent addition point upstream of the SCR catalytic converter for adding at least one of a reducing agent and a reducing agent precursor, and a structure which the exhaust gas can at least flow around and is disposed immediately downstream of the reagent addition point.Type: GrantFiled: January 16, 2008Date of Patent: October 8, 2013Assignee: EMITEC Gesellschaft fuer Emissionstechnologie mbHInventor: Rolf Brück
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Publication number: 20120252999Abstract: Systems and methods of producing chemical compounds are disclosed. An example chemical production system includes a combustion chamber having intake ports for entry of a gas mixture. An igniter ignites the gas mixture in the intake chamber to facilitate a reaction at a high temperature and high pressure. A nozzle restricts exit of the ignited gas mixture from the combustion chamber. An expansion chamber cools the ignited gas. The expansion chamber has an exhaust where the cooled gas exits the expansion chamber. A chemical compound product is formed in the expansion chamber.Type: ApplicationFiled: April 12, 2012Publication date: October 4, 2012Inventor: Bruce H. Peters
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Patent number: 8178068Abstract: A catalyst charge for ammonia oxidation, including the Andrussow process, comprises a first stage ammonia oxidation catalyst capable of oxidizing 20 to 99% of designed ammonia throughput, to produce a first stage product gas comprising unreacted ammonia, oxygen and nitrogen oxides, and a second stage ammonia oxidation catalyst capable of completing the oxidation of unreacted ammonia. Low levels of nitrous oxide are produced an extended campaign lengths may be seen.Type: GrantFiled: April 27, 2004Date of Patent: May 15, 2012Assignee: Johnson Matthey PLCInventors: Sean Alexander Axon, Duncan Roy Coupland, Brian Thomas Horner, John Ridland, Ian Carmichael Wishart
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Publication number: 20110150743Abstract: The invention relates to a hydrocyanic acid containing bioresource carbon, and to a method for producing a raw material mainly containing the same by reacting ammonia with methane or methanol optionally in the presence of air and/or oxygen, characterized in that at least one of the reagents selected from ammonia, methane and methanol is obtained from a biomass. The invention also relates to the uses of the raw material for producing acetone cyanohydrin, adiponitrile, methionine or methionine hydroxyl-analog, and sodium cyanide.Type: ApplicationFiled: May 19, 2009Publication date: June 23, 2011Applicant: Arkema FranceInventor: Jean-Luc Dubois
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Publication number: 20110020207Abstract: The invention relates to a process for continuously preparing hydrogen cyanide by reacting ammonia with hydrocarbons, the reaction gas mixture being brought to reaction temperature in the fluidized bed by means of indirect heating by contact with a particulate heat transferrer, and which is characterized in that the heat transferrer is conducted cyclically in a transported fluidized bed, the heat transferrer being heated in an ascending transport stream and being contacted with the reaction gas mixture in a descending transport stream.Type: ApplicationFiled: June 5, 2009Publication date: January 27, 2011Applicant: Evonik Roehm GmbHInventor: Hermann Siegert
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Patent number: 7294325Abstract: A process is described for preparing hydrogen cyanide by autothermal noncatalytic oxidation of one or more nitrogenous hydrocarbons or a nitrogenous hydrocarbon mixture in which the nitrogenous hydrocarbons, an oxygen-containing gas, with or without ammonia, with or without water, with or without a gas containing nitrogen oxides and with or without other essentially inert feed gas constituents are introduced into a flame reaction zone, react in the flame reaction zone and a post-reaction zone at a temperature of from 1000 to 1800° C. for a reaction time of 0.03 to 0.3 s to form a cleavage gas which comprises at least the constituents hydrogen cyanide, carbon oxides, hydrogen, water, ammonia, nitrogen, light hydrocarbons with or without other cleavage gas constituents, the atomic C/N ratio in the reaction zones being from 1 to 7 and the atomic air ratio ?ato being <0.6, the cleavage gas being cooled and separated.Type: GrantFiled: July 24, 2003Date of Patent: November 13, 2007Assignee: BASF AktiengesellschaftInventors: Kai Rainer Ehrhardt, Mayke Mueller-Eversbusch, Dieter Stapf
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Patent number: 6716405Abstract: A process for removing unreacted ammonia from an effluent of a catalyst bed used in a hydrocarbon ammoxidation reaction is provided. The process includes a step of providing a fluidized bed reactor. The reactor includes the catalyst bed for reacting ammonia and hydrocarbons therein. The reactor also includes a dilute phase of the catalyst bed disposed above the catalyst bed. The reactor further includes a set of internals disposed at least partially within the dilute phase of the catalyst bed. The reactor additionally includes an inlet of a first-stage cyclone separator disposed above the set of internals. The process also includes a step of removing the unreacted ammonia from the effluent of the catalyst bed by passing the effluent through the set of internals. The ammonia and hydrocarbons present in the effluent contact the dilute phase of the catalyst bed and react therein.Type: GrantFiled: November 15, 1999Date of Patent: April 6, 2004Assignees: China Petro-Chemical Corporation, Shanghai Research Institute of Petrochemical Technology, SINOPECInventors: Xin Chen, Linghua Wu
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Patent number: 6656442Abstract: A catalytic process and apparatus therefor for the manufacture of hydrogen cyanide. In the process an oxygen rich oxidant stream and at least one oxidant-free feed steam containing methane and ammonia are separately preheated and rapidly mixed to form a detonable mixed stream at a temperature which is at least 50° C. below the autoignition temperature of the mixed stream. The mixed stream is then conveyed to a catalyst capable of catalysing the formation of hydrogen cyanide at such a velocity that detonation is avoided. The process is more energy efficient and gives rise to an effluent stream containing more hydrogen than the conventional Andrussow process.Type: GrantFiled: May 28, 2002Date of Patent: December 2, 2003Assignee: Imperial Chemical Industries PLCInventors: Christopher Cowell, Ralph Doy
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Patent number: 6649137Abstract: A conical reactor head for use in chemical processes or other systems is provided. The reactor head includes a robust internal insulator to boost efficiency while maintaining safety by allowing the reactor head to self-radiate at high temperatures. The reactor head also includes a plurality of support lugs to protect its bottom flange from scratches or other damage when the reactor head is set on the ground. The reactor head is adapted to connect to a catalyst-containing barrel which is specially designed to facilitate easy installation and removal of catalysts or other equipment from outside the barrel.Type: GrantFiled: May 2, 2001Date of Patent: November 18, 2003Assignee: Rohm and Haas CompanyInventors: David Mark Bergeron, Michael Stanley DeCourcy, Aaron Angel Quintanilla, Paul Francis Valerio, James Woodrow Vinson, Jr., David Alec Williams
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Patent number: 6491876Abstract: A catalytic process and apparatus therefor for the manufacture of hydrogen cyanide. In the process an oxygen rich oxidant stream and at least one oxidant-free feed stream containing methane and ammonia are separately preheated and rapidly mixed to form a detonable mixed stream at a temperature which is at least 50° C. below the autoignition temperature of the mixed stream. The mixed stream is then conveyed to a catalyst capable of catalyzing the formation of hydrogen cyanide at such a velocity that detonation is avoided. The process is more energy efficient and gives rise to an effluent stream containing more hydrogen than the conventional Andrussow process.Type: GrantFiled: December 21, 1998Date of Patent: December 10, 2002Assignee: Imperial Chemical Industries PLCInventors: Christopher Cowell, Ralph Doy
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Publication number: 20020001558Abstract: A composition, a process for producing the composition, and a process for producing a nitrile are disclosed. The composition is substantially anhydrous or free of water and comprises ammonia and an anti-foaming agent. The composition can be produced by contacting substantially anhydrous ammonia with an anti-foaming amount of an anti-foaming agent. The process for producing a nitrile comprises contacting a hydrocarbon with the composition disclosed herein.Type: ApplicationFiled: May 15, 2001Publication date: January 3, 2002Inventors: Timothy Park Stauffer, Gregory Park Shankwitz
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Patent number: 6238634Abstract: A process for nondestructive heating and supplying of ammonia feed gas wherein high quality ammonia (typically greater than 90% and as high as 99%) is preserved at temperatures well in excess of the conventional limit of 230° C. (typically from 400 to 700° C.) by controlling the selection of metal surfaces in contact with the hot gas, the bulk temperature of the gas, the wall temperature, the pressure, the contact time, and the spatial surface density. Such hot gases are particularly useful for the manufacture of hydrogen cyanide.Type: GrantFiled: May 5, 1999Date of Patent: May 29, 2001Assignee: E.I. du Pont de Nemours and CompanyInventors: Peter Gideon Gelblum, John J. Barnes, Ioannis V. Bletsos, Norman Herron, Tae Hoon Kim
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Patent number: 6096173Abstract: A method of producing hydrogen cyanide by the gas-phase reaction of methane with ammonia at elevated temperature and an ammonia/methane ratio of 1.001 to 1.1. The conducting of the gaseous reaction mixture through a corona discharge causes the reaction to start at temperatures below 1000.degree. C. without the action of a catalyst. This results in considerable savings of the necessary investment expenses as well as of the running costs for energy.Type: GrantFiled: December 7, 1998Date of Patent: August 1, 2000Assignee: Degussa AktiengesellschaftInventors: Lukas Von Hippel, Andreas Gutsch, Roland Schaffer, Manfred Sauer, Rudolf Vanheertum
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Patent number: 5817286Abstract: Processes for the production of hydrogen cyanide from the reaction of methane with ammonia at temperatures above about 800.degree. C. where the reactor contains a matrix bed of heat resistant materials. The product stream produced within the reactor is preferably routed in a countercurrent fashion to the feed stream entering the reactor to preheat the feed stream and to lower the exit temperature of the product stream. Reactors capable of being used to practice such processes are also provided by the invention.Type: GrantFiled: July 25, 1997Date of Patent: October 6, 1998Assignee: Thermatrix Inc.Inventors: Richard J. Martin, John D. Stilger, John D. Young
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Patent number: 5360603Abstract: The present invention relates to processes and apparatus for mixing oxidizable reactants with oxidant and/or oxidizing oxidizable reactants. Through using particular mixing and/or oxidizing arrangements, the risk of flammable or explosive reactions can be significantly reduced or prevented. When ammonia is used as the reactant, nitric acid can be obtained.Type: GrantFiled: August 23, 1993Date of Patent: November 1, 1994Assignee: Praxair Technology, Inc.Inventors: Raymond F. Drnevich, Douglas R. Dreisinger
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Patent number: 5356603Abstract: This invention is a method for producing hydrocyanic acid by using an element which comprises a foraminous structure fabricated from a material consisting essentially of a metal selected from the group consisting of platinum, rhodium, palladium and alloys of mixtures thereof characterized by (a) a novel configuration whereby the initial product of the formula: curve the flat ratio (C/F) multiplied by mesh size (N) and wire diameter (d.sub.w), for said element is greater than at least about 0.08 and (b) where, for a given methane and ammonia throughput, the conversion efficiency is a function of the curve to flat ratio (C/F), wire diameter (d.sub.w) and mesh size (N) combination and conversion efficiency is improved by increasing the mesh size (N) for a given wire diameter, increasing the wire diameter (d.sub.w) for a given mesh size, and increasing the curve to flat ratio (C/F) to a ratio of above 1.0. Preferably the initial product of the formula is greater than 0.Type: GrantFiled: January 26, 1993Date of Patent: October 18, 1994Assignee: Johnson Matthey Inc.Inventors: William A. Hochella, Steven A. Heffernen
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Patent number: 5266291Abstract: The present invention relates to processes and apparatus for mixing oxidizable reactants with oxidant and oxidizing oxidizable reactants. When ammonia is used as the reactant, nitric acid can be obtained. Through using particular mixing and oxidizing arrangements, the volume of reactant oxidized can be significantly increased.Type: GrantFiled: May 5, 1992Date of Patent: November 30, 1993Assignee: Praxair Technology, Inc.Inventors: Raymond F. Drnevich, Douglas R. Dreisinger
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Patent number: 4853190Abstract: There is obtained an increase in the throughput in the known BMA furnace or a BMA furnace chamber without changing the construction and dimensions already present by changing the lower part of the cooling head into a short tubular heat exchanger while maintaining the necessary temperature profile for the process by arranging the ceramic tubes in the furnace chamber in closer or less close fashion and/or by using ceramic tubes having different inner and outer geometries and/or structure.Type: GrantFiled: May 16, 1988Date of Patent: August 1, 1989Assignee: Degussa AGInventors: Reinhard Manner, Hans Schaefer, Carl Voight, Wolf D. Pfeifer
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Patent number: 4320104Abstract: By introducing the reaction gas mixture of hydrocarbons and ammonia at increased velocity through an inlet tube with one or more openings in a customary reaction tube in the hydrocyanic acid-methane-ammonia (BMA) process the yield of HCN is increased considerably.Type: GrantFiled: September 3, 1980Date of Patent: March 16, 1982Assignee: Degussa AktiengesellschaftInventors: Friedrich Bittner, Carl Voigt, Peter Kleinschmit
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Patent number: 4317808Abstract: For the reduction of the ammonia content in the product gas of the hydrocyanic acid-methane-ammonia (BMA) process and accordingly to increase the yield the reaction gas mixture of this process is brought into contact with zeolite and the ammonia thereafter desorbed from the zeolite preferably again employed in the reaction step. If the desorption is carried out with a flushing gas such as the hydrocarbon used in the reaction then this mixture can be directly supplied again to the BMA reactor. Through this procedure the amount of ammonia previously lost to the process can again be made useful in the process itself.Type: GrantFiled: November 18, 1980Date of Patent: March 2, 1982Assignee: Degussa AktiengesellschaftInventors: Carl Voigt, Hans Strack, Peter Kleinschmit