Densifying Soda Ash Patents (Class 423/426)
  • Patent number: 9388053
    Abstract: The present invention relates to a highly pure, anhydrous sodium carbonate having a low pore content for use in pharmaceutical formulations and in the foods industry. Furthermore, a novel process for the preparation of this sodium carbonate is provided.
    Type: Grant
    Filed: November 10, 2012
    Date of Patent: July 12, 2016
    Assignee: Merck Patent GmbH
    Inventors: Jens Klatyk, Hans-Kurt Peth, Thorsten Wedel, Guenter Moddelmog
  • Patent number: 9221011
    Abstract: The invention relates to a method adapted for integration with a carbonate absorption/stripping process for removal of carbon dioxide, the method and system including the steps of: converting a source of alkali from a first industry to a non-carbonate alkali; feeding the non-carbonate alkali as makeup to a carbonate absorption system for stripping carbon dioxide from emissions from a second industry; recovering an output from the system for stripping carbon dioxide, and in the process of conversion of the alkali from the first industry, utilising energy from the second industry.
    Type: Grant
    Filed: July 15, 2011
    Date of Patent: December 29, 2015
    Assignee: REDEEM CCS PTY LTD
    Inventor: Barry Neil Hooper
  • Patent number: 7507388
    Abstract: A process related to sodium chemicals production, including the processing of bicarbonate containing solutions obtained by solution mining of trona, nahcolite or wegscheiderite reserves and the lake waters containing bicarbonates, includes the steps of purification, evaporation-decarbonation, crystallization, centrifuging, and drying.
    Type: Grant
    Filed: November 14, 2005
    Date of Patent: March 24, 2009
    Assignee: Eti Soda Uretim Pazarlama Nakliyat VE Elektrik Uretim Sanayi VE Ticaret A.S.
    Inventors: Ismail Ceylan, Ali Ugurelli, Noyan Dilek
  • Patent number: 7410627
    Abstract: A method for solution mining nahcolite, capable of extracting nahcolite from geological formations lean in nahcolite comprising injecting high pressure water (which may include recycled aqueous solution of bicarb and sodium carbonate) at a temperature of at least 250° F. into the formation, dissolving nahcolite in the hot water to form a production solution and recovering the production solution. The invention also includes the processing of the production solution to provide sodium carbonate and, optionally, sodium bicarbonate, comprising: decomposing the sodium bicarbonate portion of the hot aqueous production solution to form a hot aqueous solution of sodium carbonate; evaporating water from the hot aqueous solution comprising sodium carbonate to form a concentrated solution of sodium carbonate; producing sodium carbonate monohydrate from the concentrated solution of sodium carbonate by crystallization; and dewatering and calcining the sodium carbonate monohydrate to produce anhydrous sodium carbonate.
    Type: Grant
    Filed: January 25, 2006
    Date of Patent: August 12, 2008
    Assignee: American Soda, LLP
    Inventors: Max E. Ramey, John S. McEwan, Kevin L. Green, Charles L. Yates, Allan L. Turner, Michael A. Rockendal, Irvin P. Nielsen, Michael P. Hardy, Rex Goodrich
  • Patent number: 7128886
    Abstract: A method for solution mining nahcolite, capable of extracting nahcolite from geological formations lean in nahcolite comprising injecting high pressure water (which may include recycled aqueous solution of bicarb and sodium carbonate) at a temperature of at least 250° F. into the formation, dissolving nahcolite in the hot water to form a production solution and recovering the production solution. The invention also includes the processing of the production solution to provide sodium carbonate and, optionally, sodium bicarbonate, comprising: decomposing the sodium bicarbonate portion of the hot aqueous production solution to form a hot aqueous solution of sodium carbonate; evaporating water from the hot aqueous solution comprising sodium carbonate to form a concentrated solution of sodium carbonate; producing sodium carbonate monohydrate from the concentrated solution of sodium carbonate by crystallization; and dewatering and calcining the sodium carbonate monohydrate to produce anhydrous sodium carbonate.
    Type: Grant
    Filed: July 15, 2003
    Date of Patent: October 31, 2006
    Assignee: Solvay Chemicals, Inc.
    Inventors: Max E. Ramey, John S. McEwan, Kevin L. Green, Charles L. Yates, Allan L. Turner, Michael A. Rockendal, Irvin P. Nielsen, Michael P. Hardy, Rex Goodrich
  • Patent number: 6884428
    Abstract: A biocompatible tissue repair stimulating implant or “scaffold” device is used to repair tissue injuries, particularly injuries to ligaments, tendons, and nerves. Such implants are especially useful in methods that involve surgical procedures to repair injuries to ligament, tendon, and nerve tissue in the hand and foot. The repair procedures may be conducted with implants that contain a biological component that assists in healing or tissue repair.
    Type: Grant
    Filed: December 16, 2002
    Date of Patent: April 26, 2005
    Assignee: DePuy Mitek, Inc.
    Inventors: Francois Binette, Steven M. Bowman, Izi Bruker, Julia Hwang, Mora Carolynne Melican, Alireza Rezania
  • Publication number: 20030143149
    Abstract: A process is described for recovering sodium carbonate or other sodium-based chemicals from sodium-bearing streams, including in particular mine water, evaporative pond water and sodium carbonate decahydrate deposits, recycle and purge streams, and other waste streams. In the process selected sodium bicarbonate-bearing streams are decarbonized to reduce the sodium bicarbonate concentration in a combination with other sodium-bearing streams, resulting in a liquor suitable as feed to a sodium carbonate decahydrate or sodium carbonate monohydrate process. The sodium bicarbonate concentration can be reduced using any number of known processes such as reacting said sodium bicarbonate with a neutralizing agent such as calcium oxide, calcium hydroxide, sodium hydroxide, or other alkali. Sodium bicarbonate can also be stripped using steam or air.
    Type: Application
    Filed: January 31, 2002
    Publication date: July 31, 2003
    Inventors: Victor E. Braman, Marco A. Cortes, Falcon A. Price, Stephen T. Gaddis, Todd M. Lessard, James M. Shepard, Derral W. Smith
  • Patent number: 6576209
    Abstract: A process for producing sodium salts, which comprises adding solid sodium carbonate to a first aqueous solution containing sodium carbonate and sodium hydrogencarbonate, to prepare a second aqueous solution, precipitating, separating and recovering from the second aqueous solution sodium sesquicarbonate crystals containing at least 50 mol % of the sodium hydrogencarbonate component contained in the second aqueous solution, and further recovering sodium carbonate from a mother liquor remaining after separating the sodium sesquicarbonate crystals from the second aqueous solution.
    Type: Grant
    Filed: December 28, 2000
    Date of Patent: June 10, 2003
    Assignee: Asahi Glass Company Ltd.
    Inventors: Kunio Tanaka, Shintaro Kikuchi
  • Patent number: 6334989
    Abstract: A process is presented in which anhydrous soda is crystallized and worked up to produce anhydrous soda crystals with a bulk density from 1300 to 1600 kg/m3. The process is characterized in that a solvent is used that allows the crystals to be formed and handled at atmospheric pressure in the presence of water without the monohydrate of soda being formed.
    Type: Grant
    Filed: December 22, 1998
    Date of Patent: January 1, 2002
    Assignee: Technische Universiteit Delft
    Inventors: Johannes Albertus Maria Meijer, Robert Michael Geertman, Harald Oosterhof, Geert-Jan Witkamp, Gerda Maria Van Rosmalen
  • Patent number: 6228335
    Abstract: A process for the production of soda ash by withdrawing an aqueous mining solution containing dissolved sodium carbonate and at least about 1 wt % sodium bicarbonate from an underground alkali source; stripping CO2 gas from the withdrawn aqueous mining solution, to convert sodium bicarbonate dissolved therein to sodium carbonate; co-crystallizing sodium carbonate monohydrate and sodium sesquicarbonate by evaporation of water from the CO2-stripped aqueous mining solution, without co-crystallization of anhydrous sodium carbonate, to form a slurry of crystalline solids in an aqueous liquor; recovering crystalline solids from the slurry; and calcining the recovered crystalline solids to produce soda ash.
    Type: Grant
    Filed: December 10, 1997
    Date of Patent: May 8, 2001
    Assignee: FMC Wyoming Corporation
    Inventors: William C. Copenhafer, David E. Smith
  • Patent number: 6207123
    Abstract: A process for producing sodium salts, which comprises adding solid sodium carbonate to a first aqueous solution containing sodium carbonate and sodium hydrogencarbonate, to prepare a second aqueous solution, precipitating, separating and recovering from the second aqueous solution sodium sesquicarbonate crystals containing at least 50 mol % of the sodium hydrogencarbonate component contained in the second aqueous solution, and further recovering sodium carbonate from a mother liquor remaining after separating the sodium sesquicarbonate crystals from the second aqueous solution.
    Type: Grant
    Filed: February 24, 1999
    Date of Patent: March 27, 2001
    Assignee: Asahi Glass Company, Ltd.
    Inventors: Kunio Tanaka, Shintaro Kikuchi
  • Patent number: 5759507
    Abstract: This invention provides a method for the production of dense soda ash by reacting sodium carbonate decahydrate with a light soda ash or soda ash fines at an elevated temperature to produce sodium carbonate monohydrate crystals, and drying the sodium carbonate monohydrate to produce dense soda ash.
    Type: Grant
    Filed: December 19, 1996
    Date of Patent: June 2, 1998
    Assignee: Solvay Minerals, Inc.
    Inventors: David R. Delling, Kevin L. Green, James D. Phillip, Donald M. Robertson
  • Patent number: 5198145
    Abstract: Dry-blended detergent formulations are prepared by absorbing liquid surfactant on absorptive soda ash derived from the dehydration of sodium carbonate decahydrate.
    Type: Grant
    Filed: December 6, 1991
    Date of Patent: March 30, 1993
    Assignee: FMC Corporation
    Inventors: Walter Lobunez, David Goldstein
  • Patent number: 4291002
    Abstract: A process for the production of sodium carbonate wherein sodium bicarbonate is recovered from a brine containing sodium carbonate by carbonation of the brine under controlled conditions. The sodium bicarbonate is crystallized from the carbonated brine in a multi-stage carbonating, cooling and crystallization process after which it is filtered to produce wet cake. The wet cake is subjected to predrying to provide a predried wet cake of a specified free moisture content and mixed with recycle light ash to provide a dryer feed of specified moisture content to alleviate problems of product fouling or plugging of the dryer. The light ash from the dryer then is bleached and subjected to recrystallization, screening, centrifuging and drying to provide a dried sodium carbonate possessing, after evaporation of the water of hydration and free moisture, less than 0.10 percent moisture and chemical and physical properties meeting commercial dense ash specifications.
    Type: Grant
    Filed: October 25, 1977
    Date of Patent: September 22, 1981
    Assignee: Kerr-McGee Chemical Corporation
    Inventors: Donald S. Arnold, James L. Fairchild, Donald A. Nichols, Merlin D. Coe
  • Patent number: 4001381
    Abstract: The invention is a heavy sodium carbonate -dense soda- in the form of briquettes, having great density, and includes also the commercial forms of heavy sodium carbonate in the form of powder, grains and briquettes, which products are obtained by grinding - or not as required - the briquettes. The invention also comprises a novel process which produces these briquettes by briquetting of the dry sodium bicarbonate from the SOLVAY or TRONA soda ash fabrication process, which after filtering or centrifuging and drying is briquetted at a pressure between 500 to 1000 kg/cm.sup.2 ; the briquettes with a density of 1.8 kg/dm.sup.3, are then introduced into a heated static space at 700.degree. to 750.degree. C., and maintained there until the bicarbonate briquettes turn into dense sodium carbonate briquettes, with a density of 2.2 - 2.4 kg/dm.sup.3.
    Type: Grant
    Filed: July 20, 1973
    Date of Patent: January 4, 1977
    Assignee: Uzina De Produse Sodice
    Inventors: Aurelian M. Dascalescu, Grigore O. Socolescu