Abstract: A method for manufacturing a cobalt based hydroxide carbonate compound having a malachite-rosasite mineral structure, comprising the steps of: providing an first aqueous solution comprising a source of Co, providing a second aqueous solution comprising Na2CO3, mixing both solutions in a precipitation reactor at a temperature above 70° C., thereby precipitating a cobalt based hydroxide carbonate compound whilst evacuating from the reactor any CO2 formed by the precipitation reaction, wherein the residence time of the compound in the reactor is between 1 and 4 hours, and recovering the cobalt based hydroxide carbonate compound. The cobalt based hydroxide carbonate compound is used as a precursor of a lithium cobalt based oxide usable as an active positive electrode material in lithium ion batteries.

Abstract: A method for separating metal components from a treatment material containing a silicate and metal elements includes: a reaction step of reacting the treatment material and a molten alkali hydroxide in which bubbles due to water vapor derived from water are generated by heating a hydroxide of an alkali metal or an alkaline-earth metal and the water in a state where the hydroxide and the water coexist, to obtain a reaction product; and a first precipitation step of dissolving the reaction product of the treatment material and the molten alkali hydroxide after the reaction step in water, thereby generating a precipitate containing the metal elements.

Abstract: A method for recovering ammoniacal nitrogen, in the form of ammonium carbonate and/or ammonium bicarbonate, from an ammoniacal nitrogen-containing vapor that comprises introducing said vapor into at least one pressurizable ammonia scrubbing vessel containing water, simultaneously introducing a carbon dioxide-containing vapor into at least one pressurizable carbon dioxide scrubbing vessel containing water, and simultaneously pumping the solutions created in said scrubbers via hydrologic connections between said scrubbers to mix the solution to create an ammonium carbonate and/or ammonium bicarbonate containing mixture, all while maintaining independent and unmixed vapor streams throughout the entire process. The method further involves recovering ammonium carbonate and/or ammonium bicarbonate from the mixture for further use.

Abstract: A low migration energy curable ink composition may include, based upon total composition weight: a) from about 10% to about 80% of a solvent system comprising the following: i) from about 35% to about 80% of one or more mono-functional acrylate monomers, ii) from about 10% to about 35% of one or more di-functional acrylate monomers, and iii) from about 10% to about 30% of one or more tri-functional or greater acrylate monomers; b) from about 3% to about 30% of an acrylate oligomer, and c) from about 1% to about 15% of a colorant. The low migration energy curable ink may be incorporated into an absorbent article.

Abstract: The present invention provides a method for producing lithium carbonate, that can shorten the time required in the production of lithium carbonate and has excellent maintenance property and production efficiency without forming fixed matters that require complicated procedures to remove in a reaction apparatus.

Abstract: A method for producing metal carbonate is disclosed. The method includes the following steps of providing a first mixture of metal and a catalyst containing iron, NO groups, and N-containing ligands first; then introducing carbon dioxide to the first mixture to form a second mixture and obtaining a product. The method described here can improve the yield and decrease the cost of metal carbonate production.

Abstract: A method for selectively precipitating basic zinc carbonates (BZC) from basic copper carbonates (BCC) from an aqueous ammoniacal solution prepared using a mixture of copper- and zinc-containing materials.

Abstract: A method of selecting or determining a candidate compound suitable for use as a phosphate binder is disclosed. The candidate compound includes ferric compounds, ferric compound complexes, and their derivatives, salts, analogs, and metabolites. The effectiveness of the candidate compound as a phosphate binder is evaluated by a method, comprising measuring and correlating reduction of phosphate concentration in solution and reduction of phosphate absorption in cells.

Abstract: The present invention relates to a method for producing lithium carbonate, the method including: mixing ammonia and carbon dioxide gas (carbonate gas) with an aqueous solution containing lithium chloride to conduct a carbonation reaction; and thereafter, recovering a produced solid by solid-liquid separation, and also relates to a method for producing high purity lithium carbonate.

Abstract: The invention is a process involving membrane-based gas separation for separating and recovering carbon dioxide emissions from combustion processes in partially concentrated form, and then transporting the carbon dioxide and using or storing it in a confined manner without concentrating it to high purity. The process of the invention involves building up the concentration of carbon dioxide in a gas flow loop between the combustion step and a membrane separation step. A portion of the carbon dioxide-enriched gas can then be withdrawn from this loop and transported, without the need to liquefy the gas or otherwise create a high-purity stream, to a destination where it is used or confined, preferably in an environmentally benign manner.

Abstract: A permeable paver and paving slab that have water permeability of on average about 1 inch per hour and compressive strength of an average of about 5000 psi to 8000 psi, the paver and paving slab manufactured by forming a mixture comprising blast-furnace slag, sand, gravel and Portland cement into predetermined sizes, shapes and colors as desired utilizing a hydraulic-type or equivalent compacting block forming machine.

Abstract: Hydraulic cement compositions that include a carbonate compound composition, e.g., a salt-water derived carbonate compound composition containing crystalline and/or amorphous carbonate compounds, are provided. Also provided are methods of making and using the hydraulic cements, as well as settable compositions, such as concretes and mortars, prepared therefrom. The cements and compositions produced therefrom find use in a variety of applications, including use in a variety of building materials and building applications.

Abstract: The present invention relates to a process for purifying a gas stream comprising hydrogen sulfide or mercaptans, or mixtures thereof. The gas stream can be a sour natural gas stream, a landfill gas or an industrial gas stream. The process comprises contacting the gas stream at effective absorption conditions including an absorption temperature less than about 300° C. with a solid absorbent effective to absorb the hydrogen sulfide, or mercaptans or mixtures thereof to provide a purified gas stream. Method is useful for treating gas streams having up to 90 vol-% hydrogen sulfide, or treating highly pure hydrogen streams. The invention is useful as a guard bed for fuel cells and sensitive laboratory instruments. The invention can also be employed to treat steam reformer product hydrogen streams without the need for further compression of the product hydrogen streams.

Abstract: Aspects of the invention include methods of removing carbon dioxide (CO2) from a CO2 containing gas. In some instances, the methods include contacting CO2 containing gas with a bicarbonate buffered aqueous medium under conditions sufficient to produce a bicarbonate rich product. Where desired, the resultant bicarbonate rich product or a component thereof may then be stored or further processed, e.g., combined with a divalent alkaline earth metal cation, under conditions sufficient to produce a solid carbonate composition. Aspects of the invention further include systems for practicing the methods, as well as products produced by the methods.

Abstract: The present invention relates to a method of precipitation of metal ions. Mineral(s), oxide(s), hydroxide(s) of magnesium and/or calcium are adopted as raw materials, and the raw material(s) is processed through at least one step of calcination, slaking, or carbonization to produce aqueous solution(s) of magnesium bicarbonate and/or calcium bicarbonate, and then the solution(s) is used as precipitant(s) to deposit rare earth, such as nickel, cobalt, iron, aluminum, gallium, indium, manganese, cadmium, zirconium, hafnium, strontium, barium, copper and zinc ions. And at least one of metal carbonates, hydroxides or basic carbonates is obtained, or furthermore the obtained products are calcined to produce metal oxides. The invention takes the cheap calcium and/or magnesium minerals or their oxides, hydroxides with low purity as raw materials to instead common precipitants such as ammonium bicarbonate and sodium carbonate etc.

Abstract: Described is a method for the production of metal salts, wherein the cationic metal is preferably selected from Group I to IV metals and mixtures thereof and the anionic group is selected from phosphates, silicates, sulfates, carbonates, hydroxides, fluorides and mixtures thereof, and wherein said method comprises forming a mixture of at least one metal source that is a metal carboxylate with a mean carbon value per carboxylate group of at least 3 and at least one anion source into droplets and oxiding said droplets in a high temperature environment, preferably a flame. This method is especially suited for the production of calcium phosphate biomaterials such as hydroxyapatite (HAp,Ca10(PO4)6(OH)2) and tricalcium phosphate (TCP,Ca3(PO4)2) that exhibit excellent biocompatibility and osteoconductivity and therefore are widely used for reparation of bony or periodontal defects, coating of metallic implants and bone space fillers.

Abstract: Disclosed is a method of preparing a nano metal salt, including providing a metal cation solution, and providing hydroxide anions and carbonate anions to the metal cation solution to precipitate a nano metal salt. The nano metal salt has the hydroxide anion and the carbonate anion. The nano metal salt can be used to prepare an absorption layer of a solar cell.

Abstract: Aspects of the present invention refers to a process for production of nickel carbonate including preparing a magnesium salt solution, contacting the solution with a stream of gaseous CO2, keeping pH between 4 and 10 and temperature between 0 and 100° C., during up to 5 hours to produce a first mixture, contacting the first mixture with a nickel sulphate solution to produce a second mixture, performing a separation of liquid and solid portions of the second mixture, and feeding the magnesium salt solution with the liquid portion. This process recycles the reagent used for producing nickel carbonate and yields a final product that is easy to handle and transport.

Abstract: In a preferred embodiment, the invention relates to a process of sequestering carbon dioxide. The process comprises the steps of: (a) reacting a metal silicate with a caustic alkali-metal hydroxide to produce a hydroxide of the metal formerly contained in the silicate; (b) reacting carbon dioxide with at least one of a caustic alkali-metal hydroxide and an alkali-metal silicate to produce at least one of an alkali-metal carbonate and an alkali-metal bicarbonate; and (c) reacting the metal hydroxide product of step (a) with at least one of the alkali-metal carbonate and the alkali-metal bicarbonate produced in step (b) to produce a carbonate of the metal formerly contained in the metal silicate of step (a).

Abstract: A permeable paver that has water permeability of on average about 1 inch per hour and compressive strength of an average of about 8000 psi, the paver manufactured by forming a mixture comprising blast-furnace slag, sand, gravel and portland cement into predetermined sizes, shapes and colors as desired utilizing a hydraulic-type or equivalent compacting block forming machine.

Abstract: In a preferred embodiment, the invention relates to a process of sequestering carbon dioxide. The process comprises the steps of: (a) reacting a metal silicate with a caustic alkali-metal hydroxide to produce a hydroxide of the metal formerly contained in the silicate; (b) reacting carbon dioxide with at least one of a caustic alkali-metal hydroxide and an alkali-metal silicate to produce at least one of an alkali-metal carbonate and an alkali-metal bicarbonate; and (c) reacting the metal hydroxide product of step (a) with at least one of the alkali-metal carbonate and the alkali-metal bicarbonate produced in step (b) to produce a carbonate of the metal formerly contained in the metal silicate of step (a).

Abstract: The present invention relates to a filler or a filler mixture containing carbonate, as well as to a process for manufacturing the same by precipitating the filler directly into the pulp or, as a separate process without the presence of fibres, particularly from the wire water of the paper or board manufacture. The invention also relates to a fibre product containing this filler, such as a paper or board product, or a plastic, rubber, concrete or paint product.

Abstract: A process for manufacturing a block of material that imitates natural stone. The manufactured stone not only looks and appears like natural stone, but is also consistent with the composition of natural stone. The process comprises forming an aqueous mixture of limestone aggregates, treating the mixture with carbon dioxide under pressure and then highly compressing the treated mixture in a sealed mold. This process recreates the endogenous matrix of the natural stone and its original composition. The block of material is intended for construction and decoration purposes.

Abstract: To provide a method for producing a carbonate, including: growing seed crystals, wherein the seed crystals are grown in a reaction solution containing at least urea. An aspect in which the seed crystals are strontium carbonate particles, an aspect in which the reaction solution contains a metal ion source and the metal ion source is a hydroxide of strontium, and the like are favorable.

Abstract: An exhaust processing assembly for an exhaust generating device, the exhaust processing assembly comprising one or more cartridges, each of the cartridges including a housing and a constituent housed in the housing and capable of at least partially removing carbon dioxide from the exhaust of the exhaust generating device, said constituent being one or more of a solid absorber and any other constituent, wherein the cartridges are one of: removable from the exhaust processing assembly and replaceable with other like cartridges, and refillable with new constituent.

Abstract: CO2-sequestering formed building materials are provided. The building materials of the invention include a composition comprising a carbonate/bicarbonate component. Additional aspects of the invention include methods of making and using the CO2-sequestering formed building material.

Abstract: New photocatalytic product comprising compounds of titanium integrated with limestone. The product is obtained by reacting limestone with a suitable precursor of titanium dioxide in a basic solution, recovering the product in particular conditions, drying it and calcining it. By operating in presence of sodium, a composite is obtained substantially free from titanium dioxide, containing limestone and calcium titanate. The composite thus obtained, used as such or in mixture with other components, has shown an unexpectedly high photocatalytic activity.

Abstract: Nitrogen oxide storage materials and methods of manufacturing nitrogen oxide storage materials are disclosed. The nitrogen oxide storage materials can be used to manufacture catalytic trap disposed in an exhaust passage of an internal combustion engine which is operated periodically between lean and stoichiometric or rich conditions, for abatement of NOx in an exhaust gas stream which is generated by the engine. In one embodiment, the nitrogen oxide storage material comprises alkaline earth material supported on ceria particles having a crystallite size of between about 10 and 20 nm and the alkaline earth oxide having a crystallite size of between about 20-40 nm.

Abstract: The chromium (III) carbonate of the present invention exhibits a light blue color in a solid state. This chromium (III) carbonate has an L* value of 50 to 70, an a* value of ?4 to ?2, and a b* value of ?10 to ?7, which are represented by the L*a*b* color system (JIS Z8729). This chromium (III) carbonate is preferably completely dissolved within 30 minutes when the chromium (III) carbonate is added, in an amount corresponding to a Cr content of 1 g, to 1 liter of an aqueous solution of hydrochloric acid having a pH of 0.2 at a temperature of 25° C. This chromium (III) carbonate is preferably obtained by contacting an aqueous solution of carbonate and an aqueous solution containing trivalent chromium at a pH of 6 to 12 under the condition of a reaction liquid temperature of 0° C. or more and less than 50° C. Also, preferably, after production of the chromium (III) carbonate, filtration is performed, and the chromium (III) carbonate is washed with water until the conductivity of the filtrate is 5 mS/cm or less.

Abstract: The present invention is directed to a method of making metal oxide and mixed metal oxide particles. The method includes treating a mixture formed from a metal source, such as metal alkoxide, a surfactant, and a first alcohol in an aqueous media at a very high metal oxide yield. The mixture is reacted using a catalyst to form metal oxide particles having a desired particle size in said mixture. The method is particularly suitable for forming silica particles. The metal oxide particles can then be heat treated to form synthetic fused metal oxides such as, for example, synthetic fused silica.

Abstract: A method of preparing insoluble transition metal compound particles is described, comprising: providing a transition metal salt solution having the formula (TM)(S) wherein TM is one or more of Mn, Ni, Co, Mg, Zn, Ca, Sr, Cu, Zr, P, Fe, Al, Ga, In, Cr Ge or Sn; providing a source of a carbonate-, hydroxide-, phosphate-, oxyhydroxide- or oxide-based anionic compound wherein the anionic component, represented by S?, is reactive with TM to form the particles; adding the transition metal salt solution and anionic compound to a reaction chamber; and subjecting the chamber to sonication at an intensity of about 0.1 to about 50 W/mL. In an exemplary embodiment, MnCO3 particles are formed from: MnSO4; and Na2CO3 and/or NH4HCO3, wherein the ratio of MnSO4 to Na2CO3 and/or NH4HCO3 is from about 1:1.5 to 1.5:1. The particles may have narrow size distribution and a tap density of about 1.7-2.3 g/mL.

Abstract: In some embodiments, the invention provides systems and methods for removing carbon dioxide and/or additional components of waste gas streams, comprising contacting the waste gas stream with an aqueous solution, removing carbon dioxide and/or additional components from the waste gas stream, and containing the carbon dioxide and/or additional components, in one form or another, in a composition. In some embodiments, the composition is a precipitation material comprising carbonates, bicarbonates, or carbonates and bicarbonates. In some embodiments, the composition further comprises carbonate and/or bicarbonate co-products resulting from co-processing SOx, NOx, particulate matter, and/or certain metals. Additional waste streams such as liquid, solid, or multiphasic waste streams may be processed as well.

Abstract: The present invention relates to a chemical composition and method of generating carbon dioxide for use with an insect monitor and/or capture device comprising: i) an effervescent agent; ii) a solid acid; iii) a deliquescent agent; and optionally iv) an anti-clumping agent.

Abstract: The current invention provides a novel process for the treatment and reclamation of drilling frac flowback and produced wastewater from the drilling industry. The wastewater is delivered to the EMC/F System from a frac tank or other reservoir. The wastewater is pumped into the system and is treated sequentially by passing through a mechanical hydrocavitation unit, an electromagnetic unit, an electrocoagulation unit and/or a hydrocyclone and a flocculation-sedimentation tank. Polishing of the final effluent is accomplished by passing the water through a mixed media tank.

Abstract: The invention discloses a method of preparing monodisperse microtablets of calcium carbonate in aqueous solutions containing calcium, gelatin and urea. Calcium carbonate powders of a unique tablet-like morphology were produced by simply ageing the prerefrigerated (at 4° C. for at least 24 hours) CaCI2-gelatin-urea solutions at 70° C. for 24 h in ordinary glass media bottles. Thermal decomposition of dissolved urea was used to supply aqueous carbonate (CO32?) ions to the calcium (Ca2+) ion and gelatin-containing solutions. Monodisperse CaCO3 microtablets have the particle sizes from 1 to 8 microns. CaCO3 microtablets were biphasic in nature and consist of 93 to 98% vaterite and 2 to 7% calcite. Identical solutions used without prerefrigeration yielded only trigonal prismatic calcite crystals upon ageing at 70° C. for 24 h.

Abstract: Reduced-carbon footprint concrete compositions, and methods for making and using the same, are provided. Aspects of the reduced-carbon footprint concrete compositions include CO2-sequestering carbonate compounds, which may be present in the hydraulic cement and/or aggregate components of the concrete. The reduced-carbon footprint concrete compositions find use in a variety of applications, including use in a variety of building materials and building applications.

Abstract: Provided is a catalyst material comprising aggregates of nanoneedles of mainly R-type manganese dioxide and having a mesoporous structure. With this, water can be oxidatively decomposed under visible light at room temperature to produce oxygen gas, proton and electron. Also provided is a catalyst material comprising aggregates of nanoparticles of mainly hydrogenated manganese dioxide. With this, acetic acid or an inorganic substance can be synthesized from carbon dioxide gas.

Abstract: To provide an optical resin composition containing carbonate crystals, which have oriented birefringence, have a needle- or rod-like shape, and are able to negate the birefringence without sacrificing the light transmittance of a transparent polymeric resin where the carbonate crystal exists, and a method for producing the resin composition. To achieve this provided are an optical resin composition containing a resin and carbonate crystals, wherein the carbonate crystals have a specific surface area of 4 m2/g or more, and the carbonate crystals dispersed into the resin have an average dispersion diameter of 500 nm at a maximum, and a method for producing the optical resin composition.

Abstract: CO2-sequestering formed building materials are provided. The building materials of the invention include a composition comprising a carbonate/bicarbonate component. Additional aspects of the invention include methods of making and using the CO2-sequestering formed building material.

Abstract: The object of the present invention is to provide a carbonate crystal, which has oriented birefringence, is needle- or rod-like, and is able to negate the birefringence without sacrificing the light transmittance of a transparent polymeric resin when it exists in the transparent resin; a manufacturing method of the carbonate crystal; and a transparent optical resin composition comprising the carbonate resin. The carbonate crystal has an aspect ratio of two or greater, the average major axis length of 400 nm or shorter, and the variation coefficient expressed in Formula (1) below is 0.40 or less: 1 r × { 1 n - 1 ? ? i = 1 n ? ( r i - r ) 2 } 1 2 Formula ? ? ( 1 ) wherein r denotes an average major axis length, n denotes the number of particles used for the measurement of the major axis length, and n denotes the major axis length of the ith particle measured.

Abstract: Provided herein are methods and systems including contacting an anode electrolyte with an anode; contacting a cathode electrolyte with a cathode where cathode is a fine mesh cathode; and applying voltage across the anode and the cathode. The methods and systems further may include treating hydroxide ions produced at the cathode with carbon from a source of carbon.

Abstract: It is an object of the present invention to provide a mixture for recovery utilization or transfer of carbon dioxide gas. According to the present invention, disclosed is a mixture containing carbon dioxide and an alkyltin alkoxide composition containing carbon dioxide complex of an alkyltin alkoxide, the mixture having a composition with a specified ratio.

Abstract: The gaseous effluent to be treated is contacted in column C1 with an absorbent solution selected for its property of forming two separable phases when it is heated. The regenerated absorbent solution is separated into two phases in drum B1; a fraction rich in water and a fraction rich in reactive compounds. Separation allows to optimize the operations performed on the regenerated absorbent solution. On the one hand, separation allows to carry out vaporization, through reboiler R1, of a fraction of the absorbent solution, preferably containing a limited reactive compound concentration in relation to the absorbent solution, thus limiting their degradation. On the other hand, separation of the phases allows to reduce the amount of solution to be treated in order to remove the non-regeneratable salts and thus to reduce the costs linked with their elimination. Finally, separation allows to eliminate the degradation products by carrying out a specific and suitable purification for each phase.

Abstract: A method of preparing basic metal carbonate selected from the group consisting of zinc carbonate, nickel carbonate, silver carbonate, cobalt carbonate, tin carbonate, lead carbonate, manganese carbonate, lithium carbonate, sodium carbonate, and potassium carbonate from metals comprising: contacting the metal with an aqueous solution comprising an amine, carbonic acid, and oxygen under conditions where the metal is converted into basic metal carbonate; and recovering the basic metal carbonate.

Abstract: Provided are methods for sequestering carbon dioxide from a synthesis gas to provide a gaseous and an aqueous product. A recovery method and system for combusting the gaseous product and utilizing the aqueous product is provided. Methods and systems are described for utilizing the aqueous product in an electrochemical or a precipitation reaction. Compositions of sequestered carbon dioxide are provided.

Abstract: Aspects of the present invention refers to a process for production of nickel carbonate including preparing a magnesium salt solution, contacting the solution with a stream of gaseous CO2, keeping pH between 4 and 10 and temperature between 0 and 100° C., during up to 5 hours to produce a first mixture, contacting the first mixture with a nickel sulphate solution to produce a second mixture, performing a separation of liquid and solid portions of the second mixture, and feeding the magnesium salt solution with the liquid portion. This process recycles the reagent used for producing nickel carbonate and yields a final product that is easy to handle and transport.

Abstract: As population density increases, the transportation of hazardous chemicals, including acids and disinfectants, lead to an increased incidence of spills while the consequences of spills become more serious. While solutions of halide acids, hypohalites and halites are safer disinfectants for transportation, handling, storage and use than traditional gaseous chlorine, the manufacturing cost of these disinfectants has here-to-fore limited their use. Economical processes are presented for the manufacture of O2, halogen oxides, halide acids, hypohalites, and halates; as well as polynucleate metal compounds, metal hydroxides and calcium sulfate hydrate (gypsum). The instant invention presents methods and processes that incorporate the use of sulfur. This is while environmental regulators, such as the US EPA, require an increased removal of sulfur from hydrocarbon fuels, thereby creating an abundance of sulfur, such that the refining industry is in need of a way to dispose of said abundance of sulfur.

Abstract: Methods of sequestering carbon dioxide (CO2) are provided. Aspects of the methods include precipitating a storage stable carbon dioxide sequestering product from an alkaline-earth-metal-containing water and then disposing of the product, e.g., by placing the product in a disposal location or using the product as a component of a manufactured composition. Also provided are systems for practicing methods of the invention.

Abstract: A process for producing sodium hydrogencarbonate crystal particles having a low caking property, which entails subjecting sodium hydrogencarbonate crystal particles having an average particle size of from 50 to 500 ?m based on the mass to heat treatment at a temperature of from 70 to 95° C. by a heating gas having a carbon dioxide gas concentration of at most the concentration calculated by the formula: Carbon dioxide gas concentration=0.071×e(0.1×T)×R(?0.0005×T?0.9574), where T (° C.) is the temperature of sodium hydrogencarbonate crystals, and R (%) is the relative humidity around the crystals at the temperature of the crystals, provided that the upper limit of the carbon dioxide gas concentration is 100 vol % to form anhydrous sodium carbonate on the surface of the sodium hydrogencarbonate crystal particles with a content of anhydrous sodium carbonate of from 0.03 to 0.4 mass % in the sodium hydrogencarbonate crystals.

Abstract: Dielectric materials comprising nanocrystalline or nanoparticulate metal oxides or metal carbonates having enhanced dielectric constant values are provided. Specifically, the dielectric materials exhibit high dielectric constant values at low frequencies approaching the DC limit. The dielectric materials also exhibit low dielectric loss factors and high voltage breakdown limits making them well suited for use in capacitors, particularly high energy density capacitors.