From Carbon Monoxide Patents (Class 423/437.2)
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Publication number: 20100200811Abstract: The present invention relates to a method for oxidizing CO, comprising: passing a first feed comprising CO and a second feed comprising oxygen, in an oxidation zone, over a catalyst comprising highly dispersed gold on sulfated zirconia, at oxidation conditions, to produce an effluent comprising a lower level of CO than in the first feed.Type: ApplicationFiled: February 5, 2010Publication date: August 12, 2010Inventors: Alexander E. Kuperman, Michael E. Moir
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Patent number: 7727931Abstract: Use of physical vapor deposition methodologies to deposit nanoscale gold on activating support media makes the use of catalytically active gold dramatically easier and opens the door to significant improvements associated with developing, making, and using gold-based, catalytic systems. The present invention, therefore, relates to novel features, ingredients, and formulations of gold-based, heterogeneous catalyst systems generally comprising nanoscale gold deposited onto a nanoporous support.Type: GrantFiled: September 23, 2004Date of Patent: June 1, 2010Assignee: 3M Innovative Properties CompanyInventors: Larry A. Brey, Thomas E. Wood, Gina M. Buccellato, Marvin E. Jones, Craig S. Chamberlain, Allen R. Siedle
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Publication number: 20100119433Abstract: The invention provides a method for oxidizing carbon monoxide present in an oxygen-containing gas phase to carbon dioxide which comprises: adsorbing the carbon monoxide onto porous silica; and irradiating the porous silica with ultraviolet ray. In the invention, mesoporous silica or amorphous silica is used as the porous silica. In particular, silica gel that is amorphous silica is preferably used.Type: ApplicationFiled: April 28, 2008Publication date: May 13, 2010Applicant: THE HONJO CHEMICAL CORPORATIONInventors: Gohei Yoshida, Yuuichi Hayashi
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Patent number: 7700512Abstract: A carbon monoxide selective oxidizing catalyst includes a carrier of ferrierite or ZSM-5 that supports a metal component of platinum (Pt) alone or platinum and at least one type of transition metal. Alternatively, a carbon monoxide selective oxidizing catalyst includes a carrier whose maximum pore diameter ranges from 0.55 to 0.65 nanometers (nm) that supports a metal component of platinum (Pt) alone or platinum and at least one type of transition metal.Type: GrantFiled: February 24, 2006Date of Patent: April 20, 2010Assignee: Toyota Jidosha Kabushiki KaishaInventor: Saeko Kurachi
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Publication number: 20100089796Abstract: A layered composition which can be used in various processes has been developed. The composition comprises an inner core such as a cordierite core and an outer layer comprising a refractory inorganic oxide, a fibrous component and an inorganic binder. The refractory inorganic oxide layer can be alumina, zirconia, titania, etc. while the fibrous component can be titania fibers, silica fibers, carbon fibers, etc. The inorganic oxide binder can be alumina, silica, zirconia, etc. The layer can also contain catalytic metals such as gold and platinum plus other modifiers. The layered composition is prepared by coating the inner core with a slurry comprising the refractory inorganic oxide, fibrous component, an inorganic binder precursor and an organic binding agent such as polyvinyl alcohol. The composition can be used in various hydrocarbon conversion processes.Type: ApplicationFiled: December 15, 2009Publication date: April 15, 2010Applicant: UOP LLCInventors: Dean E. Rende, James E. Rekoske, Jeffery C. Bricker, Jeffrey L. Boike, Masao Takayama, Kouji Hara, Nobuyuki Aoi
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Patent number: 7687051Abstract: A method and catalysts for producing a hydrogen-rich syngas are disclosed. According to the method a CO-containing gas contacts a water gas shift (WGS) catalyst, in the presence of water, preferably at a temperature of less than about 450° C. to produce a hydrogen-rich syngas. Also disclosed is a water gas shift catalyst formulated from: a) Pt, its oxides or mixtures thereof, b) at least one of Fe and Rh, their oxides and mixtures thereof, and c) at least one member selected from the group consisting of Sc, Y, Ti, Zr, V, Nb, Ta, Mo, Re, Co, Ni, Pd, Ge, Sn, Sb, La, Ce, Pr, Nd, Sm, and Eu, their oxides and mixtures thereof. The WGS catalyst may be supported on a carrier, such as any one member or a combination of alumina, zirconia, titania, ceria, magnesia, lanthania, niobia, yttria and iron oxide. Fuel processors containing such water gas shift catalysts are also disclosed.Type: GrantFiled: December 18, 2003Date of Patent: March 30, 2010Assignees: Honda Giken Koygo Kabushiki Kaisha, Symyx Technologies, Inc.Inventors: Alfred Hagemeyer, Christopher James Brooks, Raymond E. Carhart, Karin Yaccato, Cory Bernard Phillips, Peter Strasser, Robert K. Grasselli
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Publication number: 20100074829Abstract: In a process for obtaining CO2, desulfurized natural gas or gas which accompanies mineral oil is reformed autothermally with addition of oxygenous gas at a temperature of from 900 to 1200° C. and a pressure of from 40 to 100 bar (a) by partial catalytic oxidation to give a crude synthesis gas, and then converted catalytically to H2 and CO2 at a temperature of from 75 to 110 DEG C. and a pressure of from 50 to 75 bar (a) of CO, CO2 is scrubbed out of the synthesis gas obtained with methanol at a pressure of from 15 to 100 bar (a) and a temperature of from +10 to ?80° C., and the absorbed CO2 is recovered by decompression. A further possible use of the process consists in converting the recovered CO2 to the supercritical state.Type: ApplicationFiled: October 31, 2007Publication date: March 25, 2010Applicant: LURGI GMBHInventor: Ulrich Koss
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Publication number: 20100068120Abstract: CuO—ZnO—CeO2 catalyst and aged CuO—ZnO catalyst catalytically active for low temperature oxidation of carbon monoxide. The catalysts are co-precipitated, filtered, washed, dried, and calcined. The catalysts can be incorporated into a component of a cigarette or can be used to reduce the concentration of carbon monoxide from a vehicle exhaust emission, a gas used in a laser, a gas used in a fuel cell and/or ambient air undergoing air filtration.Type: ApplicationFiled: October 19, 2009Publication date: March 18, 2010Inventors: Sarojini Deevi, Unnikrishnan Pillai
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Patent number: 7665328Abstract: A method for rendering a contaminated biomass inert includes providing a first composition, providing a second composition, reacting the first and second compositions together to form an alkaline hydroxide, providing a contaminated biomass feedstock and reacting the alkaline hydroxide with the contaminated biomass feedstock to render the contaminated biomass feedstock inert and further producing hydrogen gas, and a byproduct that includes the first composition.Type: GrantFiled: June 19, 2006Date of Patent: February 23, 2010Assignee: Battelle Energy Alliance, LLCInventors: Dennis N. Bingham, Kerry M. Klingler, Bruce M. Wilding
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Publication number: 20090269269Abstract: The disclosed subject matter provides a copper oxide nanoparticle, a catalyst that includes the copper oxide nanoparticle, and methods of manufacturing and using the same. The catalyst can be used to catalyze a chemical reaction (e.g., oxidizing carbon monoxide (CO) to carbon dioxide (CO2)).Type: ApplicationFiled: October 14, 2008Publication date: October 29, 2009Applicant: The Trustees of Columbia University in City of New YorkInventors: Brian Edward White, Stephen O'Brien
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Publication number: 20090226357Abstract: The invention concerns a process for preparing metallic nanoparticles with an anisotropic nature by using two different reducing agents, preferably with different reducing powers, on a source of a metal selected from columns 8, 9 or 10 of the periodic table of the elements.Type: ApplicationFiled: November 14, 2006Publication date: September 10, 2009Inventors: Denis Uzio, Catherine Verdon, Cecile Thomazeau, Bogdan Harbuzaru, Gilles Berhault
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Publication number: 20090214410Abstract: Systems and methods for contacting a liquid, gas, and/or a multi-phase mixture with particulate solids. The system can include a body having a first head and a second head disposed thereon. Two or more discrete fixed beds can be disposed across a cross-section of the body. One or more unobstructed fluid flow paths can bypass each fixed bed, and one or more baffles can be disposed between the fixed beds.Type: ApplicationFiled: February 27, 2008Publication date: August 27, 2009Inventors: Kenneth L. Blanchard, David P. Mann
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Patent number: 7572422Abstract: An exhaust gas purifying method for a fuel cell vehicle comprises preparing an exhaust gas purifying system for the fuel cell vehicle, the exhaust gas purifying system including a methane removal catalyst for accelerating the conversion of methane into hydrogen and carbon monoxide. The methane removal catalyst comprises a catalytic ingredient including at least one of rhodium, platinum and palladium.Type: GrantFiled: October 29, 2007Date of Patent: August 11, 2009Assignee: Nissan Motor Co., Ltd.Inventors: Toru Sekiba, Hiroshi Akama
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Patent number: 7557063Abstract: The invention relates to noble metal-free nickel catalysts that exhibit both high activity and selectivity to hydrogen generation and carbon monoxide oxidation. The noble metal-free water gas shift catalyst of the invention comprises Ni in either a supported or a bulk state and at least one of Ge, Cd, In, Sn, Sb, Te, Pb, their oxides and mixtures thereof.Type: GrantFiled: September 17, 2007Date of Patent: July 7, 2009Assignees: Honda Giken Kogyo Kabushiki Kaisha, Symyx Technologies, Inc.Inventors: Alfred Hagemeyer, Christopher James Brooks, Raymond E. Carhart, Karin Yaccato, Michael Herrmann
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Patent number: 7550215Abstract: Low-energy, low-capital hydrogen production is disclosed. A reforming exchanger 14 is placed in parallel with an autothermal reformer (ATR) 10 to which are supplied a preheated steam-hydrocarbon mixture. An air-steam mixture is supplied to the burner/mixer of the ATR 10 to obtain a syngas effluent at 650°-1050° C. The effluent from the ATR is used to heat the reforming exchanger, and combined reformer effluent is shift converted and separated into a mixed gas stream and a hydrogen-rich product stream. High capital cost equipment such as steam-methane reformer and air separation plant are not required.Type: GrantFiled: May 21, 2007Date of Patent: June 23, 2009Assignee: Kellogg Brown & Root LLCInventors: Avinash Malhotra, James Hanlan Gosnell
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Patent number: 7501112Abstract: A combination comprising a bed of a particulate copper-containing catalyst and, a guard bed of a particulate composition containing a) lead and/or at least one lead compound that reacts with hydrogen chloride and b) a support therefor. The lead compound is preferably lead nitrate. The combination is of particular utility for the low temperature shift reaction wherein carbon monoxide is reacted with steam to produce hydrogen and carbon dioxide.Type: GrantFiled: March 23, 2006Date of Patent: March 10, 2009Assignee: Johnson Matthey PLCInventor: Michael J. Watson
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Catalysts For Co Oxidation,Voc Combustion And Nox Reduction And Methods Of Making And Using The Same
Publication number: 20080233039Abstract: The present invention is directed to carbon monoxide oxidation reactions in the presence of an O2 containing gas, nitrogen oxide conversion reactions, volatile organic compound conversion reactions in the presence of an O2 containing gas, and combinations thereof, and catalysts for use in those reactions. The catalyst comprises cobalt, its oxides or mixtures thereof and ruthenium, its oxides or mixtures thereof.Type: ApplicationFiled: June 1, 2006Publication date: September 25, 2008Applicant: SYMYX TECHNOLOGIES, INC.Inventors: Alfred Hagemeyer, Anthony F. Volpe, Valery Sokolovskii, Andreas Lesik, Guido Streukens -
Publication number: 20080128656Abstract: Process of depositing nanoparticles of a metal or of an alloy of said metal, said metal being chosen from the metals from columns VIIIB and IB of the Periodic Table, dispersed on a substrate by chemical vapour deposition (CVD), from one or more precursors, in which the deposition is carried out in the presence of a gas comprising more than 50 vol % of a reactive oxidizing gas. Substrate comprising at least one surface, dispersed on which are nanoparticles made of a metal or of an alloy of metals, for example made of silver or a silver alloy. Use of the substrate to catalyse a chemical reaction, for example an NOx elimination reaction.Type: ApplicationFiled: December 23, 2005Publication date: June 5, 2008Applicants: COMMISSARIAT A L'ENERGIE ATOMIQUE, CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE, UNIVERSITE DE POITIERSInventors: Stéphanie Thollon, Fabien Luc, Joel Barrault, Sabine Valange, Erwan Guelou, Marco Daturi, Fabien Can
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Patent number: 7354562Abstract: A process for producing a high temperature COx-lean product gas from a high temperature COx-containing feed gas, includes: providing a sorption enhanced reactor containing a first adsorbent, a shift catalyst and a second adsorbent; feeding into the reactor a feed gas containing H2, H2O, CO and CO2; contacting the feed gas with the first adsorbent to provide a CO2 depleted feed gas; contacting the CO2 depleted feed gas with the shift catalyst to form a product mixture comprising CO2 and H2; and contacting the product mixture with a mixture of second adsorbent and shift catalyst to produce the product gas, which contains at least 50 vol. % H2, and less than 5 combined vol. % of CO2 and CO. The adsorbent is a high temperature adsorbent for a Sorption Enhanced Reaction process, such as K2CO3 promoted hydrotalcites, modified double-layered hydroxides, spinels, modified spinels, and magnesium oxides.Type: GrantFiled: October 25, 2002Date of Patent: April 8, 2008Assignee: Air Products and Chemicals, Inc.Inventors: David Hon Sing Ying, Shankar Nataraj, Jeffrey Raymond Hufton, Jianguo Xu, Rodney John Allam, Sarah Jane Dulley
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Patent number: 7261870Abstract: Carbon monoxide and carbonyl sulfide emissions are reduced in manufacturing processes, including titanium tetrachloride production processes. Gas is contacted with CO, COS, and an oxygen-containing gas with a suitable catalyst. The catalyst may be a metal oxide catalyst containing bismuth, cobalt and nickel, a xerogel or aerogel catalyst containing Au, Rh, Ru and Co in aluminum oxide/oxyhydroxide matrices, or a supported metal catalyst that contains at least one metal from the group Pd, Rh, Ru and Cu. In the latter case, the catalyst support is contains alumina or carbon. A catalyst composite of Au, Rh, Ru and Cr, and cerium oxide and lanthanum oxide may also be used.Type: GrantFiled: June 16, 2003Date of Patent: August 28, 2007Assignee: E.I. du Pont de Nemours and CompanyInventors: Dale Robert Coulson, Norman Herron, Kostantinos Kourtakis, Stephen E. Lyke
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Patent number: 7255845Abstract: This invention relates to a process for conducting an equilibrium limited chemical reaction in a single stage process channel. A process for conducting a water shift reaction is disclosed. A multichannel reactor with cross flow heat exchange is disclosed.Type: GrantFiled: August 11, 2005Date of Patent: August 14, 2007Assignee: Velocys, Inc.Inventors: Anna Lee Tonkovich, Wayne W. Simmons, Kai Tod Paul Jarosch, Terry Mazanec, Eric Daymo, Ying Peng, Jennifer Lynne Marco
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Patent number: 7238333Abstract: A method of reducing an amount of carbon monoxide in process fuel gas in a water gas shift converter with no methane formation. The method includes placing a high activity water gas shift catalyst system into a water gas shift converter; and passing the process fuel gas through the water gas shift converter in effective contact with the high activity water gas shift catalyst system and converting a portion of the carbon monoxide in the process fuel gas into carbon dioxide and hydrogen by a water gas shift reaction with no methane formation at a temperature in a range of about 200° C. to about 425° C.Type: GrantFiled: March 18, 2004Date of Patent: July 3, 2007Assignee: General Motors CorporationInventors: Anca Faur-Ghenciu, Sailesh Mullapudi, Mark R. Feaviour, Nathan E. Trusty, Jessica G. Reinkingh
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Patent number: 7195742Abstract: An apparatus for preferential oxidation of carbon monoxide in a reformate flow includes a reactor defining a flow path for a reformate flow; at least one catalyst bed disposed along the flow path; and a distributor for distributing oxygen from an oxygen source to the at least one catalyst bed, the distributor including a conduit positioned at least one of upstream of and through the at least one catalyst bed, the conduit having a sidewall permeable to flow of oxygen from within the conduit to the at least one catalyst bed.Type: GrantFiled: July 26, 2002Date of Patent: March 27, 2007Assignee: UTC Fuel Cells, LLCInventors: Ke Liu, Sean C. Emerson, Richard James Bellows
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Patent number: 7179442Abstract: A method and catalysts and fuel processing apparatus for producing a hydrogen-rich gas, such as a hydrogen-rich syngas are disclosed. According to the method a CO-containing gas, such as a syngas, contacts a water gas shift (“WGS”) catalyst, in the presence of water, preferably at a temperature of less than about 450° C. to produce a hydrogen-rich gas, such as a hydrogen-rich syngas. Also disclosed is a water gas shift catalyst formulated from: a) at least one of Rh, Ni, Pt, their oxides and mixtures thereof, b) at least one of Cu, Ag, Au, their oxides and mixtures thereof; and c) at least one of K, Cs, Sc, Y, Ti, Zr, V, Mo, Re, Fe, Ru, Co, Ir, Pd, Cd, In, Ge, Sn, Pb, Sb, Te, La, Ce, Pr, Nd, Sm, Eu, their oxides and mixtures thereof. Another disclosed catalyst formulation comprises Rh, its oxides or mixtures thereof, Pt, its oxides or mixtures thereof and Ag, its oxides or mixtures thereof.Type: GrantFiled: December 18, 2003Date of Patent: February 20, 2007Assignees: Honda Giken Kogyo Kabushiki Kaisha, Symyx Technologies, Inc.Inventors: Alfred Hagemeyer, Raymond E. Carhart, Karin Yaccato, Peter Strasser, Michael Herrmann, Robert K. Grasselli, Christopher James Brooks, Cory Bernard Phillips
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Patent number: 7169376Abstract: The present invention relates to a method for making hydrogen comprising contacting in a water-gas shift reaction zone a feed comprising carbon monoxide and water under water-gas shift conditions with an effective catalytic amount of a catalyst comprising highly dispersed gold on a sulfated zirconia, and collecting from the water-gas shift reaction zone an effluent comprising hydrogen and carbon dioxide. The invention also provides a catalyst composition and a method of making the catalyst. In a specific embodiment the invention provides a method for carrying out the water-gas shift reaction in the fuel processor associated with a fuel cell.Type: GrantFiled: June 10, 2004Date of Patent: January 30, 2007Assignee: Chevron U.S.A. Inc.Inventors: Alexander Kuperman, Michael E. Moir
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Patent number: 7160533Abstract: A method and catalysts for producing a hydrogen-rich syngas are disclosed. According to the method a CO-containing gas contacts a water gas shift (WGS) catalyst, optionally in the presence of water, preferably at a temperature of less than about 450° C. to produce a hydrogen-rich gas, such as a hydrogen-rich syngas. Also disclosed is a water gas shift catalyst formulated from: a) Pt, its oxides or mixtures thereof; b) Ru, its oxides or mixtures thereof; and c) at least one of Li, Na, K, Rb, Cs, Mg, Ca, Sr, Ba, Sc, Y, Ti, Zr, V, Mo, Mn, Fe, Co, Rh, Ir, Ge, Sn, Sb, La, Ce, Pr, Sm, and Eu. Another disclosed catalyst formulation comprises Pt, its oxides or mixtures thereof; Ru, its oxides or mixtures thereof; Co, its oxides or mixtures thereof; and at least one of Li, Na, K, Rb, Cs, Mg, Ca, Sr, Ba, Sc, Y, Ti, Zr, V, Mo, Mn, Fe, Rh, Ir, Ge, Sn, Sb, La, Ce, Pr, Sm, and Eu, their oxides and mixtures thereof.Type: GrantFiled: December 18, 2003Date of Patent: January 9, 2007Assignees: Honda Giken Kogyo Kabushiki Kaisha, Symyx Technologies, Inc.Inventors: Alfred Hagemeyer, Raymond E. Carhart, Karin Yaccato, Peter Strasser, Robert K. Grasselli, Christopher James Brooks, Cory Bernard Phillips
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Patent number: 7160534Abstract: A method and catalysts and fuel processing apparatus for producing a hydrogen-rich gas, such as a hydrogen-rich syngas are disclosed. According to the method, a CO-containing gas, such as a syngas, contacts a platinum-free ruthenium-cobalt water gas shift (“WGS”) catalyst, in the presence of water and preferably at a temperature of less than about 450° C., to produce a hydrogen-rich gas, such as a hydrogen-rich syngas. Also disclosed is a platinum-free ruthenium-cobalt water gas shift catalyst formulated from: a) Ru, its oxides or mixtures thereof; b) Co, Mo, their oxides or mixtures thereof; and c) at least one of Li, Na, K, Rb, Cs, Ti, Zr, Cr, Fe, La, Ce, Eu, their oxides and mixtures thereof. The WGS catalyst may be supported on a carrier, such as any one member or a combination of alumina, zirconia, titania, ceria, magnesia, lanthania, niobia, zeolite, perovskite, silica clay, yttria and iron oxide. Fuel processors containing such water gas shift catalysts are also disclosed.Type: GrantFiled: December 18, 2003Date of Patent: January 9, 2007Assignees: Honda Giken Kogyo Kabushiki Kaisha, Symyx Technologies, Inc.Inventors: Alfred Hagemeyer, Raymond E. Carhart, Karin Yaccato, Michael Herrmann, Andreas Lesik, Christopher James Brooks, Cory Bernard Phillips
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Patent number: 7148178Abstract: A catalyst bed combination comprising a bed of a particulate copper-containing catalyst and, upstream of the catalyst bed, a guard bed in the form of shaped units formed from lead oxide particles and a particulate support material. The guard bed extends the life of the copper catalyst by absorbing halide contaminants in the process stream.Type: GrantFiled: July 28, 2003Date of Patent: December 12, 2006Assignee: Johnson Matthey PLCInventor: Gordon James Kelly
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Patent number: 7115236Abstract: An exhaust gas purifying method for a fuel cell vehicle comprises preparing an exhaust gas purifying system for the fuel cell vehicle, the exhaust gas purifying system including a methane removal catalyst for accelerating the conversion of methane into hydrogen and carbon monoxide. The methane removal catalyst comprises a catalytic ingredient including at least one of rhodium, platinum and palladium.Type: GrantFiled: December 25, 2002Date of Patent: October 3, 2006Assignee: Nissan Motor Co., Ltd.Inventors: Toru Sekiba, Hiroshi Akama
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Patent number: 7070758Abstract: A process and apparatus for generating hydrogen from oil shale. Crushed oil shale may be placed in a chamber and combusted with carbon monoxide, oxygen and steam to form a gas stream of hydrogen and carbon monoxide. The hydrogen and carbon monoxide stream may be passed through a mechanism to produce hydrogen. In one embodiment, the hydrogen and carbon monoxide stream may be passed through a catalytic converter to produce hydrogen and carbon dioxide. The hydrogen and carbon dioxide may be cooled further and passed through a scrubber to remove the carbon dioxide such that hydrogen is produced. In another embodiment, the hydrogen and carbon monoxide may be passed through fluidized beds of magnetite to produce metallic iron, carbon dioxide and water. The metallic iron may then be conveyed to another chamber, where it may be treated with steam, producing magnetite and hydrogen.Type: GrantFiled: July 18, 2003Date of Patent: July 4, 2006Inventor: Oren V. Peterson
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Patent number: 7029640Abstract: In a process for oxidizing carbon monoxide with oxygen to carbon dioxide using a composition comprising platinum and iron, a process of at least partially regenerating the composition is disclosed.Type: GrantFiled: June 17, 2003Date of Patent: April 18, 2006Assignee: ConocoPhillips CompanyInventors: Jianhua Yao, James B Kimble
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Patent number: 6953561Abstract: A device for selective oxidation of a substance stream comprises a selectively active catalyst. For improving the cold-starting characteristics, the device also has an oxidation catalyst that possesses high activity at low temperatures. The selectively active catalyst is applied as a coating onto one or more surfaces of interior walls of the device. A layer of oxidation catalyst is provided in at least the inlet region where the substance stream enters the device, between the layer of selectively active catalyst and the interior walls of the device.Type: GrantFiled: July 16, 2002Date of Patent: October 11, 2005Assignee: Ballard Power Systems AGInventor: Matthias Wolfsteiner
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Patent number: 6942846Abstract: A recombination device (1, 1?) for catalytically recombining hydrogen and/or carbon monoxide with oxygen in a gaseous mixture comprises at least one catalyst system (2) in which a housing (4) is mounted through which the gaseous mixture can flow in free convection in the operational phase. According to the invention, said catalyst system (2) is provided with a plurality of sub-areas (T1, T2) in the direction of flow. A first sub-area (T1) comprises in the incoming direction a catalyst body (6) with a surrounding throttle layer (8) for inhibiting the diffusion of the incoming and/or discharged reaction gases. A second sub-area (T2) that adjoins the first sub-area (T1) comprises at least one catalyst body (6) that is directly accessible by the reaction gases.Type: GrantFiled: March 15, 2000Date of Patent: September 13, 2005Assignee: Framatome ANP GmbHInventors: Bernd Eckardt, Axel Hill
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Platinum group metal promoted copper oxidation catalysts and methods for carbon monoxide remediation
Patent number: 6913739Abstract: The invention provides processes for selectively oxidizing carbon monoxide from an input gas stream that contains carbon monoxide, oxygen and hydrogen. The process includes the step of contacting the input gas stream with a preferential oxidation catalyst. The preferential oxidation catalysts are copper-based catalysts containing low concentrations of platinum group metals. In some embodiments, the processes of the invention are conducted using preferential oxidation catalysts having an oxide support on which is dispersed copper or an oxide thereof, a platinum group metal and a reducible metal oxide. In other embodiments, the processes of the invention are conducted with a preferential oxidation catalysts having a cerium oxide support on which is dispersed copper or an oxide thereof and a platinum group metal.Type: GrantFiled: November 9, 2001Date of Patent: July 5, 2005Assignee: Engelhard CorporationInventors: Lawrence Shore, Wolfgang F. Ruettinger, Robert J. Farrauto -
Patent number: 6869580Abstract: The method for generating a hydrogen-rich stream from hydrocarbon fuels, ultimately to produce hydrogen gas, involves the following two steps performed in a cyclic fashion: (1) pyrolysis of the hydrocarbon fuel to obtain a carbon-rich fraction and a hydrogen-rich fraction; and (2) oxidation of the carbon-rich fraction, or a portion of it, for heat generation. The method involves the following optional steps: (3) steam gasification of part of the carbon-rich fraction to produce additional amounts of hydrogen and carbon monoxide; (4) water-gas shift reaction to convert carbon monoxide to carbon dioxide with the simultaneous formation of additional amounts of hydrogen; and (5) steam reforming of light hydrocarbons that may be produced in step (1) to produce more hydrogen and carbon monoxide.Type: GrantFiled: July 6, 2001Date of Patent: March 22, 2005Assignee: Advanced Fuel Research, Inc.Inventors: Marek A. Wojtowicz, Michael A. Serio, Erik Kroo, Eric M. Suuberg
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Patent number: 6855664Abstract: A catalyst for the full oxidation of volatile organic compounds (VOC), particularly hydrocarbons, and of CO to CO2, comprising: a non-stoichiometric crystalline compound conventionally designated by a formula which corresponds to A14Cu24O41 (I), where A is Sr or a solid solution of Sr with alkaline-earth metals, alkaline metals, lanthanides; or a non-stoichiometric crystalline compound conventionally designated by a formula which corresponds to B4Cu5O10 (II), where B is Ca or a solid solution of Ca with alkaline-earth metals, alkaline metals, lanthanides; or mixtures thereof; and in that it is prepared in a form which has a large specific surface area, preferably larger than 25 m2/g; a method for preparing the catalysts; their use in methods for the full oxidation of VOC and of CO to CO2; and the oxidation methods.Type: GrantFiled: August 21, 2003Date of Patent: February 15, 2005Assignees: Consiglio Nazionale Delle Ricerche, Universita 'Degli Studi di ParmaInventors: Francesco Cino Matacotta, Gianluca Calestani, Chiara Dionigi, Petr Nozar
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Patent number: 6852302Abstract: An apparatus of removing carbon monoxide, has: a hydrogen gas supply unit of supplying a hydrogen gas, a catalytic reaction unit provided with a catalyst body carrying a platinum group metal catalyst, a hydrogen gas introducing unit which introduces a hydrogen gas containing carbon monoxide from the hydrogen gas supply unit to the catalytic reaction unit, and an oxidizing gas supply unit of supplying an oxidizing gas containing oxygen to the catalytic reaction unit, wherein the catalyst body is brought into an oxidizing atmosphere for a period of time during operation according to a predetermined condition or when the apparatus is stopped. Thus, carbon monoxide can be eliminated sufficiently.Type: GrantFiled: November 16, 2000Date of Patent: February 8, 2005Assignee: Matsushita Electric Industrial Co., Ltd.Inventors: Kunihiro Ukai, Takeshi Tomizawa, Kiyoshi Taguchi, Akira Maenishi, Tetsuya Ueda
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Patent number: 6852303Abstract: A molybdenum carbide compound is formed by reacting a molybdate with a mixture of hydrogen and carbon monoxide. By heating the molybdate powder from a temperature below 300° C. to maximum temperature 850° C., a controlled reaction can be conducted wherein molybdenum carbide is formed. A high surface area, nanograin, metastable molybdenum carbide can be formed when the reaction temperature is below 750° C. The metastable molybdenum carbide is particularly suitable for use as a catalyst for the methane dry reforming reaction and the water gas shift reaction.Type: GrantFiled: September 30, 2003Date of Patent: February 8, 2005Assignee: N.V. Union Miniere S.A. et al.Inventors: Purnesh Seegopaul, Lin Gao
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Patent number: 6838071Abstract: The present invention comprises a method for production of a CO2-rich gas stream and a H2-rich gas stream, the method comprising the following steps: a) natural gas and water are fed to a reforming reactor and are converted to synthesis gas under supply of a O2-containing gas: b) the gas stream from a) is shifted, whereby the content of CO is reduced and the amounts of CO2 and H2 are increased by reaction of H2O; c) the gas stream from b) is separated in a separation unit into a CO2-rich and a H2-rich gas stream, respectively. The invention also concerns the use of a CO2-rich gas stream for injection into marine formations, and the use of a H2-rich gas stream for hydrogenation, as a source of energy/fuel in fuel cells or for production of electricity.Type: GrantFiled: September 14, 1999Date of Patent: January 4, 2005Assignee: Den Norske Stats Oljeselskap A.S.Inventors: Ola Olsvik, Roger Hansen, Arne Grislingås, Erling Rytter
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Patent number: 6824904Abstract: A preferential oxidation reactor is provided including a plurality of reactor sections. The reactor sections are individually optimized for operating at a preferred reaction temperature. In one embodiment, each reactor subsection includes a respective coolant flow for manipulating the operating temperature of the respective subsection. In another embodiment, a first section includes a lower temperature catalyst substrate, a second reactor section includes a higher temperature (i.e. normal) catalyst substrate and a third reactor section includes a lower temperature catalyst substrate. Yet another embodiment includes modifying the catalyst substrates of the respective subsections through the inclusion of promoters. Still another embodiment includes varying a density of the catalyst substrate across the reactor sections. Each of the embodiments enable quick light-off of the reactor, while limiting a reverse water-gas shift reaction.Type: GrantFiled: April 26, 2002Date of Patent: November 30, 2004Assignee: General Motors CorporationInventors: Mark A. Brundage, William H. Pettit, Rodney L. Borup
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Publication number: 20040229091Abstract: Methods and systems for carbon monoxide clean-up are provided. The methods and systems utilize water gas shift reactors having water gas shift catalysts and hydride heat exchangers having metal hydrides. The methods and systems allow hydrogen from a reactant stream to be stored in the metal hydride during carbon-monoxide clean-up and subsequently released into the reactant stream. It is emphasized that this abstract is provided to comply with the rules requiring an abstract which will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure. It is submitted with the understanding that is will not be used to interpret or limit the scope or meaning of the claims. 37 CFR 1.72(b).Type: ApplicationFiled: May 16, 2003Publication date: November 18, 2004Inventors: Julia Margaret Rowe, Beverley Sowerby
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Patent number: 6805850Abstract: A CO-shift device includes a main body having therein a space in which a CO-shift catalyst is accommodated, the space being divided into an inner space and an outer space surrounding the inner space; an inlet portion formed at one end portion of the inner space, the inlet portion being supplied with a reformed gas such that the reformed gas flows through the inner space. An outlet portion is formed at one end portion of the outer space and a redirecting portion is provided between the other end portion of the inner space and the other end portion of the redirecting portion, thereby reversing the reformed gas flown into the other end of the inner space in order that the resulting reformed gas passes through the outer space to be exhausted from the outlet portion, the reformed gas being shifted to reduce CO by the CO-shift catalyst during its movement through the inner and outer spaces.Type: GrantFiled: March 19, 2002Date of Patent: October 19, 2004Assignee: Aisin Seiki Kabushki KaishaInventor: Takashi Ishikawa
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Patent number: 6783749Abstract: Improved method for recovering hydrogen and carbon monoxide from hydrocarbon conversion processes are disclosed. A monolith catalyst reactor means is utilized in treating the waste gas stream from the hydrocarbon conversion process to assist in recovering hydrogen and carbon monoxide from the waste gas stream. The present invention also provides a method for improving the yield of hydrogen and carbon monoxide from a hydrocarbon conversion process utilizing a monolith catalyst reactor means.Type: GrantFiled: May 13, 2002Date of Patent: August 31, 2004Assignee: The BOC Group, Inc.Inventors: Natarajan Narasimhan, Ramakrishnan Ramachandran, Satish S. Tamhankar, Weibin Jiang
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Patent number: 6780386Abstract: Provided is a catalyst for selective oxidation of CO gas in a gas of essentially hydrogen, and a method for producing the catalyst. The catalyst is highly active in a relatively high temperature range. The catalyst is for selectively oxidizing CO gas with hydrogen, and this carries ruthenium held on a carrier of titania and alumina, or carries ruthenium with an alkali metal and/or an alkaline earth metal held thereon. For producing the catalyst, a solution containing ruthenium and an alkali metal and/or an alkaline earth metal is applied to the carrier.Type: GrantFiled: June 19, 2001Date of Patent: August 24, 2004Assignee: Idemitsu Kosan Co., Ltd.Inventors: Tetsuya Fukunaga, Kozo Takatsu, Masatoshi Shibata, Satoshi Hachiya, Hiroyuki Endo
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Patent number: 6777117Abstract: There is provided a catalyst for a water gas shift reaction in a hydrogen gas which is able to effectively remove CO in the hydrogen gas within a broader temperature range. Such a catalyst for the water gas shift reaction is characterized in that a metal oxide carrier supports at least platinum. The catalyst can be used for removing carbon monoxide in the hydrogen gas. Particularly, such a catalyst can be used in the water gas shift reaction for removing carbon monoxide in a reformed gas in a fuel cell generation system.Type: GrantFiled: February 6, 2001Date of Patent: August 17, 2004Assignee: Matsushita Electric Works, Ltd.Inventors: Akira Igarashi, Hirokazu Higashi, Manabu Mizobuchi, Noboru Hashimoto, Kensaku Kinugawa
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Patent number: 6746657Abstract: The invention disclosed is a method for the reduction of carbon monoxide to carbon dioxide in a gas stream comprising carbon monoxide, hydrogen and water vapor, wherein the carbon monoxide and hydrogen have a mole ratio greater than 5:1, with substantially reduced methanation. The invention utilizes a reactor having at least one channel having a catalyst positioned thereon and a flow rate of the gas stream over the catalyst such that a boundary layer having a thickness less than a maximum thickness boundary is created.Type: GrantFiled: March 12, 2002Date of Patent: June 8, 2004Assignee: Precision Combustion, Inc.Inventor: Marco J. Castaldi
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Patent number: 6740303Abstract: A gas generating system for a fuel cell system as well as to a method of operating same. In order to provide hydrogen-containing combustible gas as rapidly as possible and to reduce the exhaust gas emissions, for the start of the operation of the gas generating system, at least one catalytic burner is started and the generated heat is used for evaporating a combustion agent and/or water and for the heating-up of an additionally connected partial reforming unit or partial oxidation stage in order to generate a hydrogen-containing gas for the fuel cell unit by reforming or partial oxidation.Type: GrantFiled: February 4, 2002Date of Patent: May 25, 2004Assignee: Ballard Power Systems AGInventors: Stefan Boneberg, Martin Schaefer, Martin Schuessler, Erik Theis, Ralf Heuser
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Patent number: 6726890Abstract: The present invention provides a catalyst for oxidizing reformed gas, which catalyst can selectively oxidize carbon monoxide—which is contained in the reformed gas used as a fuel of a solid polymer fuel cell and which acts as a catalyst poison of the fuel cell—into carbon dioxide with high performance. The reformed gas is oxidized by use of the catalyst of the present invention, which catalyst is characterized in that M-type mordenite, among different types of zeolite, is used as a carrier and a bimetallic alloy metal system containing platinum and an alloy-forming metal other than platinum is supported by the carrier, wherein the amount of the alloy-forming metal in the alloy is 20-50 at. %.Type: GrantFiled: January 14, 2000Date of Patent: April 27, 2004Assignees: Tanaka Kikinzoku Kogyo K.K.Inventor: Masahiro Watanabe
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Patent number: 6723298Abstract: A method for catalytic conversion of carbon monoxide with water to carbon dioxide and water in a hydrogen-containing gas mixture (carbon monoxide conversion) by passing the gas mixture over a shift catalyst that is at an operating temperature for the carbon monoxide conversion. The method is carried out with a shift catalyst based on noble metals that is applied to an inert support element in the form of a coating.Type: GrantFiled: May 11, 2000Date of Patent: April 20, 2004Assignee: DMC2 Degussa Metals Catalysts Cerdec AGInventors: Frank Baumann, Stefan Wieland
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Publication number: 20040038815Abstract: A catalyst for the full oxidation of volatile organic compounds (VOC), particularly hydrocarbons, and of CO to CO2, comprising:Type: ApplicationFiled: August 21, 2003Publication date: February 26, 2004Inventors: Francesco Cino Matacotta, Gianluca Calestani, Chiara Dionigi, Petr Nozar