Hydrogen Sulfide Patents (Class 423/563)
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Patent number: 11987510Abstract: Method and apparatus pertaining to the production of hydrogen sulfide using sodium salts recycle. Sodium sulfate is reacted with a carbon containing stream to produce sodium sulfide and carbon dioxide. The sodium sulfide is blended with elemental sulfur and water. The blend is subjected to elevated temperatures and pressures to result in the production of hydrogen sulfide and sodium sulfate. A mixing apparatus, such as a bubble column reactor, has been found to be especially useful. The hydrogen sulfide can be used for removing metal from effluents.Type: GrantFiled: April 23, 2021Date of Patent: May 21, 2024Assignee: 1983 LLCInventor: Dania Valenzuela
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Patent number: 11981613Abstract: Disclosed are methods and systems for hydrogen isotope exchange of organic molecules that can be carried out with no alteration in the chemical structure of the organic molecules. Methods can be utilized to incorporate a particular hydrogen isotope on an organic molecule (e.g., deuteration or tritiation) or to remove a particular hydrogen isotope from an organic molecule (e.g., detritiation).Type: GrantFiled: January 20, 2023Date of Patent: May 14, 2024Assignee: Battelle Savannah River Alliance, LLCInventors: George K. Larsen, III, Tyler C. Guin, Joseph E. Meany, Jay B. Gaillard, Mark C. Elvington
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Patent number: 11801498Abstract: The present invention relates to the catalytic processes for rendering harmless the flue gases of the power stations or more precisely to the catalysts for sulfur oxides reduction to elemental sulfur. The novel catalyst presents the binary polycations of copper and zinc or copper and manganese incorporated into the low silica faujasite X (LSX) having transition metals ratio Cu:Zn or Cu:Mn in the range of 2:1 to 4:1.Type: GrantFiled: June 6, 2022Date of Patent: October 31, 2023Assignees: M Chemical Company, Inc., N.D. Zelinsky Institute of Organic Chemistry RAS (IOKh)Inventors: Albert M. Tsybulevski, Eduardo Bolivar, Alexander Avraamovich Greish, Leonid Modestovich Kustov
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Patent number: 11634552Abstract: Disclosed is an organic amine salt foaming agent, that is, a composite polyurethane foaming agent, comprising: 1) hexafluorobutene; and 2) an alkanolamine salt mixture (MAA), the alkanolamine salt mixture (MAA) contains an organic amine salt compound having the following general formula (I): An?[Bm+]p (I); wherein An? is one or two or three selected from the following anions: (b) carbonate: CO32?; (c) formate: HCOO?; (d) bicarbonate: HO—COO?. A polyurethane foaming method using carbon dioxide and an organic amine in combination is also disclosed, in which carbon dioxide is added to a polyurethane composition for foaming. A method for preparing an alkanolamine carbonate salt with low water content from ammonium carbonate and an epoxide is additionally disclosed, in which a liquid alkanolamine salt mixture is used as a dispersion medium or as a solvent for reaction raw material.Type: GrantFiled: December 5, 2017Date of Patent: April 25, 2023Assignee: Shandong University of TechnologyInventors: Gehua Bi, Yusui Bi
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Patent number: 11530232Abstract: Disclosed herein are lignin valorization strategies that integrate thermochemical pretreatment strategies. Using methods disclosed herein, yields of greater than 40% of usable monomers are obtained from lignin in biomass. The monomers can be assimilated by strains of Pseudomonas putida.Type: GrantFiled: November 16, 2020Date of Patent: December 20, 2022Assignee: Alliance for Sustainable Energy, LLCInventors: Jacob S. Kruger, Gregg Tyler Beckham, David Gregory Brandner
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Patent number: 11014808Abstract: Method of producing hydrogen sulfide in an alkaline environment. A mixture having a sodium salt, elemental sulfur (S) and water is added to a reactor for the purpose of generating hydrogen sulfide (H2S) gas as the main product and sodium sulfate (Na2SO4) as a byproduct.Type: GrantFiled: December 23, 2016Date of Patent: May 25, 2021Assignee: CLEAN RESOURCES PTE. LTDInventor: Abraham Fouad Jalbout
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Patent number: 10625204Abstract: This invention is directed to a method used to remove gases from industrial exhaust streams, and in particular, to a method for removing sulfur dioxide from flue gases, with molten carbonate and treating the resulting molten mixture with a natural gas and optionally with an oxidant.Type: GrantFiled: June 19, 2017Date of Patent: April 21, 2020Assignee: YEDA RESEARCH AND DEVELOPMENT CO. LTD.Inventors: Igor Lubomirsky, Valery Kaplan, Nurlan Dosmukhamedov
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Patent number: 10336614Abstract: The present invention discloses a hydrogen sulfide reactor vessel with an external heating system that is conductively and removably attached to an exterior portion of the reactor vessel. Also disclosed are processes for producing hydrogen sulfide utilizing the reactor vessel.Type: GrantFiled: July 9, 2018Date of Patent: July 2, 2019Assignee: Chevron Phillips Chemical Company, LPInventors: Daniel M. Hasenberg, Alex Pauwels, Ives Mertens
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Patent number: 10040684Abstract: The present invention discloses a hydrogen sulfide reactor vessel with an external heating system that is conductively and removably attached to an exterior portion of the reactor vessel. Also disclosed are processes for producing hydrogen sulfide utilizing the reactor vessel.Type: GrantFiled: August 23, 2016Date of Patent: August 7, 2018Assignee: Chevron Phillips Chemical Company LPInventors: Daniel M Hasenberg, Alex Pauwels, Ives Mertens
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Patent number: 9421511Abstract: The present invention relates to a reactor and to a process for synthesis of hydrogen sulphide from elemental sulphur and hydrogen at elevated pressure and elevated temperature. The invention further relates to the use of the reactor for preparation of hydrogen sulphide in high yield and with a low H2Sx content.Type: GrantFiled: May 31, 2013Date of Patent: August 23, 2016Assignee: Evonik Degussa GmbHInventors: Caspar-Heinrich Finkeldei, Chiu Kee Cheung, Ralf Maassen, Stefan Wenner, Martin Koerfer
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Patent number: 9278314Abstract: The objective of this invention is to develop a method to reclaim functional sites on a CO2 sorbent that have reacted with an acid gas (other than CO2) to form heat stable salts (HSS). HSS are a significant concern for dry sorbent based CO2 capture because over time the buildup of HSS will reduce the overall functionality of the CO2 sorbent. A chemical treatment can remove the non-CO2 acid gas and reclaim functional sites that can then be used for further CO2 adsorption.Type: GrantFiled: September 19, 2013Date of Patent: March 8, 2016Assignee: ADA-ES, Inc.Inventors: Holly Krutka, Sharon Sjostrom, William J. Morris
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Patent number: 9192888Abstract: Embodiments of apparatuses and methods for removing acid gas from sour gas are provided. In one example, an apparatus comprises an absorption zone. The absorption zone is configured for contacting the sour gas with an absorbent solvent that is at a first predetermined temperature of less than about 0° C. to remove the acid gas and form a treated gas stream that includes entrained absorbent solvent. A heat exchanger or heater is configured to heat the treated gas stream to a second predetermined temperature of greater than about 0° C. to form a partially heated treated gas stream. A water wash zone is configured for contacting the partially heated treated gas stream with water to remove the entrained absorbent solvent and form a solvent-depleted treated gas stream.Type: GrantFiled: June 26, 2013Date of Patent: November 24, 2015Assignee: UOP LLCInventors: Keyur Y. Pandya, David A. Wegerer, Clayton Colin Sadler
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HYDROGEN SULFIDE GAS PRODUCTION PLANT AND METHOD FOR RECOVERING AND USING WASTE HYDROGEN SULFIDE GAS
Publication number: 20150044126Abstract: An object is to provide a hydrogen sulfide gas production plant that can recover discharged waste hydrogen sulfide gas and efficiently supply the gas to a process plant where processing is conducted by using hydrogen sulfide gas, and also provide a method for recovering and using the waste hydrogen sulfide gas by the hydrogen sulfide gas production plant. In the present invention, the hydrogen sulfide gas production plant is provided with a pipe that recovers the waste hydrogen sulfide gas discharged from the hydrogen sulfide gas production plant and that has one end connected to the process plant where the hydrogen sulfide gas is used, and the discharged waste hydrogen sulfide gas is recovered and the recovered waste hydrogen sulfide gas is supplied to the process plant through the pipe.Type: ApplicationFiled: January 7, 2013Publication date: February 12, 2015Inventors: Osamu Nakai, Satoshi Matsubara, Tomoyuki Hirose, Masafumi Nakamura -
Publication number: 20150034500Abstract: A metal organic framework (MOF) includes a coordination product of a metal ion and an at least bidentate organic ligand, where the metal ion and the organic ligand are selected to provide a deliverable adsorption capacity of at least 70 g/l for an electronic gas. A porous organic polymer (POP) includes polymerization product from at least a plurality of organic monomers, where the organic monomers are selected to provide a deliverable adsorption capacity of at least 70 g/l for an electronic gas.Type: ApplicationFiled: August 4, 2014Publication date: February 5, 2015Inventors: Han Sung KIM, Mitchell Hugh WESTON, Patrick FULLER, Paul Wai-Man SIU
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Publication number: 20150030524Abstract: Disclosed are systems and methods which provide a process stream comprising a gaseous component, capture the gaseous component from the process stream by an ionic liquid solvent of a separator, and recover a captured gaseous component from the ionic liquid solvent in a regenerator. A second gaseous component from the process stream may be captured by the ionic liquid solvent of the separator, and the second gaseous component may be recovered from the ionic liquid solvent in the regenerator. Alternatively, the second gaseous component from the process stream may be uncaptured by the ionic liquid solvent, and the uncaptured second gaseous component may be recovered from a membrane unit.Type: ApplicationFiled: July 23, 2013Publication date: January 29, 2015Inventors: Lei JI, Ai-Fu CHANG, Michael S. Driver, Hye-Kyung Timken
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Publication number: 20140363361Abstract: The disclosure provides an LS methane hydrate containing a plurality of methane hydrate crystals and lignosulfonate. The disclosure also provides a method of making an LS methane hydrate by combining methane gas, liquid or solid water, and LS at controlled temperature and starting pressure for a time sufficient to form LS methane hydrate. The disclosure further provides a method of producing energy from an LS methane hydrate by providing an LS methane hydrate directly to a combustion chamber, whereby methane in the methane hydrate and LS are converted to energy in the combustion chamber and water in the methane hydrate is converted to steam. The disclosure additionally provides a method of releasing methane from an LS methane hydrate by heating an LS methane hydrate.Type: ApplicationFiled: August 26, 2014Publication date: December 11, 2014Applicant: THE TEXAS STATE UNIVERSITY-SAN MARCOSInventors: Weixing Wang, Luyi Sun
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Patent number: 8765451Abstract: The present invention provides a method of treating an off-gas stream (80) comprising NH3 and H2S to provide a sulphate stream (910), the method comprising the steps of: (i) providing a first off-gas stream (80) comprising NH3, H2S, CO2 and optionally one or more of HCN, COS and CS2; (ii) passing the first off-gas stream (80) to an incinerator (300) to oxidize NH3, H2S, and optionally one or more of HCN, COS and CS2 to provide a second off-gas stream (310) comprising N2, H2O, SO2 and CO2; (iii) scrubbing the second off-gas stream (310) with a first aqueous alkaline stream (380, 876a) in a caustic scrubber (350) to separate SO2 and a part of the CO2 from the second off-gas stream to provide a spent caustic stream (360) comprising carbonate and one or both of sulphite and bisulphite and a caustic scrubber off-gas stream (370) comprising N2 and CO2; and (iv) passing the spent caustic stream (360) to an aerator (900) comprising sulphur-oxidizing bacteria in the presence of oxygen to biologically oxidize sulphiteType: GrantFiled: April 6, 2010Date of Patent: July 1, 2014Assignee: Shell Oil CompanyInventor: Sandra Schreuder
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Patent number: 8598059Abstract: The present invention relates to a process for sulfurizing a hydrocarbon treatment catalyst, comprising: at least a first step of depositing, on the surface of the catalyst, one or more sulfurization auxiliaries of formula (I): and at least a second step, carried out after the first step, of placing the catalyst in contact with a sulfur-containing gaseous mixture containing hydrogen and a sulfur compound. This process does not comprise the deposit of any carbon sources other than the auxiliary of formula (I).Type: GrantFiled: September 10, 2010Date of Patent: December 3, 2013Assignee: Eurecat S.A.Inventors: Pierre Dufresne, Eric Nagy, Pauline Galliou
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Patent number: 8597581Abstract: A system may include a sulfur recovery unit. The sulfur recovery unit may include an acid gas supply, which may supply acid gas, an oxygen supply, which may supply oxygen, a fuel supply, which may supply fuel. The fuel may have a higher heating value than the acid gas. Also, the sulfur recovery unit may include a thermal reaction zone, which may thermally recover sulfur from the acid gas by combustion of the fuel and the acid gas with the oxygen and through reaction of the acid gas with combustion products arising from the combustion.Type: GrantFiled: January 4, 2010Date of Patent: December 3, 2013Assignee: General Electric CompanyInventors: Sachin Suhas Naphad, Ganesh Prasadh Kidambi
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Patent number: 8551442Abstract: A reactor for synthesizing hydrogen sulfide in which sulfur and hydrogen are subjected to gas-phase reaction in the absence of a catalyst to synthesize hydrogen sulfide, the reactor including: a reactor body that retains liquid sulfur in a bottom portion thereof; a heating unit that gasifies part of the liquid sulfur; a hydrogen gas supply unit that supplies hydrogen gas into the liquid sulfur; and a heat-exchanging portion provided in a gas-phase reaction region located above the liquid surface of the liquid sulfur in the reactor body, wherein heat-exchanging portion is configured such that the reaction temperature in the gas-phase reaction region is controlled to be within a predetermined temperature range by changing the heat exchange amount per unit volume in a gas-phase reaction region located farther from the liquid surface from the heat exchange amount per unit volume in a gas-phase reaction region located closer to the liquid surface.Type: GrantFiled: March 1, 2013Date of Patent: October 8, 2013Assignee: JGC CorporationInventors: Hiroshi Umino, Nobuhiro Yamada, Tsutomu Katagiri, Hiromitsu Shibuya, Shuichi Oguro, Naoyoshi Iwasaki
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Publication number: 20130177496Abstract: A reactor for synthesizing hydrogen sulfide in which sulfur and hydrogen are subjected to gas-phase reaction in the absence of a catalyst to synthesize hydrogen sulfide, the reactor including: a reactor body that retains liquid sulfur in a bottom portion thereof; a heating unit that gasifies part of the liquid sulfur; a hydrogen gas supply unit that supplies hydrogen gas into the liquid sulfur; and a heat-exchanging portion provided in a gas-phase reaction region located above the liquid surface of the liquid sulfur in the reactor body, wherein heat-exchanging portion is configured such that the reaction temperature in the gas-phase reaction region is controlled to be within a predetermined temperature range by changing the heat exchange amount per unit volume in a gas-phase reaction region located farther from the liquid surface from the heat exchange amount per unit volume in a gas-phase reaction region located closer to the liquid surface.Type: ApplicationFiled: March 1, 2013Publication date: July 11, 2013Applicant: JGC CORPORATIONInventors: HIROSHI UMINO, NOBUHIRO YAMADA, TSUTOMU KATAGIRI, HIROMITSU SHIBUYA, SHUICHI OGURO, NAOYOSHI IWASAKI
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Patent number: 8377310Abstract: Toxic substances such as heavy metals are extracted from a medium using a sorbent composition. The sorbent composition is derived by sulfidation of red mud, which contains hydrated ferric oxides derived from the Bayer processing of bauxite ores. Exemplary sulfidizing compounds are H2S, Na2S, K2S, (NH4)2S, and CaSx. The sulfur content typically is from about 0.2 to about 10% above the residual sulfur in the red mud. Sulfidized red mud is an improved sorbent compared to red mud for most of the heavy metals tested (Hg, Cr, Pb, Cu, Zn, Cd, Se, Th, and U). Unlike red mud, sulfidized red mud does not leach naturally contained metals. Sulfidized red mud also prevents leaching of metals when mixed with red mud. Mixtures of sulfidized red mud and red mud are more effective for sorbing other ions, such as As, Co, Mn, and Sr, than sulfidized red mud alone.Type: GrantFiled: May 11, 2010Date of Patent: February 19, 2013Assignee: J.I. Enterprises, Inc.Inventor: Joseph Iannicelli
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Patent number: 8226986Abstract: The present invention provides novel stable, liquid compositions comprising chalcogenides or salts thereof. These compositions may be used for a variety of purposes, including the treatment and prevention of ischemic or hypoxic injury, as well as in the preservation of biological matter.Type: GrantFiled: March 16, 2011Date of Patent: July 24, 2012Assignee: Ikaria, Inc.Inventors: Kevin J. Tomaselli, Paul A. Hill, Thomas L. Deckwerth, Edward A. Wintner, Csaba Szabo
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Patent number: 8021624Abstract: The invention relates to a reactor (1) and a process for continuously preparing H2S by converting a reactant mixture which comprises essentially gaseous sulfur and hydrogen over a catalyst, comprising a sulfur melt (9) at least in a lower subregion (8) of the reactor (1), into which gaseous hydrogen is introduced. The catalyst is arranged in at least one U-shaped tube (21) which is partly in contact with the sulfur melt (9), the at least one U-shaped tube (21) having at least one entry orifice (23) on a limb (26) above the sulfur melt (9), through which the reactant mixture can enter the U-shaped tube (21) from a reactant region (10) of the reactor (1), having a flow path within the at least one U-shaped tube, along which the reactant mixture can be converted in a reaction region comprising the catalyst (22), and having at least one exit orifice (24) in another limb (27) through which a product can exit into a product region (7).Type: GrantFiled: January 14, 2008Date of Patent: September 20, 2011Assignee: BASF SEInventors: Andreas Wölfert, Herald Jachow, Heinz Drieβ
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Publication number: 20110220551Abstract: Sulfhydryl compounds, including hydrogen sulfide and mercaptans, may be removed from a fluid or gaseous stream or substrate by reacting the hydrogen sulfide and mercaptans in the stream with a scavenger of the structural formula: wherein R1, R2 and R3 are each independently selected from the group consisting of R4 and R5, R4 is a C1-C20 straight or branched chain alkyl group, R5 is —[(CH)m—NH]p—(CH2)nOH, n and m are independently an integer from 2 to about 6, p is from 1 to about 6; and wherein at least one of R1, R2 and R3 is R4 and at least one of R1, R2 and R3 is R5.Type: ApplicationFiled: March 12, 2010Publication date: September 15, 2011Inventor: Grahame N. Taylor
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Patent number: 8012441Abstract: The invention relates to a method for isolating hydrogen sulphide from coke-oven gas with the subsequent recovery of elemental sulphur in a Claus plant. The hydrogen sulphide is eliminated from the coke-oven gas by gas washing using an absorption liquid. During the regeneration of the loaded absorption liquid, hydrogen sulphide is accumulated in concentrated form and is fed to the Claus plant. Said Claus plant comprises a Claus boiler, a waste-heat boiler, in addition to a reactor, which forms an additional catalyst stage. According to the invention, the Claus plant is operated with a single reactor, which operates at a working temperature of below 250° C. The process gas that exits the reactor is returned after the deposition of elemental sulphur with a non-reacted residual concentration of hydrogen sulphide to the coke-oven gas that is to be cleaned, prior to the gas washing stage.Type: GrantFiled: May 10, 2003Date of Patent: September 6, 2011Assignee: Uhde GmbHInventor: Holger Thielert
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Patent number: 7923037Abstract: The present invention provides novel stable, liquid compositions comprising chalcogenides or salts thereof. These compositions may be used for a variety of purposes, including the treatment and prevention of ischemic or hypoxic injury, as well as in the preservation of biological matter.Type: GrantFiled: January 31, 2008Date of Patent: April 12, 2011Assignee: Ikaria, Inc.Inventors: Kevin J. Tomaselli, Paul A. Hill, Thomas L. Deckwerth, Edward Wintner, Csaba Szabo
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Patent number: 7887777Abstract: Hydrogen sulfide H2S is prepared from a crude gas stream containing H2S and polysulfanes (H2Sx). The crude gas stream is passed at temperatures of from 114 to 165° C. through catalytically active material present in a vessel, and sulfur is collected in the bottom of the vessel and recycled to the preparation of H2S. This process may be accomplished in an apparatus including a reactor for reacting sulfur and hydrogen, a cooler for receiving and cooling an H2S-containing crude gas stream passed out of the reactor to between 114 to 165° C., a vessel coupled to the cooler, the vessel including catalytically active material and a bottom for collecting sulfur obtained from the crude gas stream, and a line which is connected to the bottom of the vessel and opens into the cooler or into the reactor, for recycling sulfur.Type: GrantFiled: January 15, 2008Date of Patent: February 15, 2011Assignee: BASF SEInventors: Andreas Wölfert, Herald Jachow, Heinz Drieβ
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Patent number: 7871594Abstract: The present invention describes a reactor (1) for continuously preparing hydrogen sulfide H2S from hydrogen and sulfur, comprising a distributor device (15) for distributing gaseous hydrogen in a sulfur melt (9) present at least in a lower part of the reactor. The distributor device (15) is arranged in the sulfur melt (9) and comprises a distributor plate (16) which is arranged in the reactor (1) and has an edge (17) extending downward and, if appropriate, has passage orifices (19). The hydrogen from a hydrogen bubble which forms below the distributor plate (16) is (for example through the passage orifices (19)) distributed in the sulfur melt (9) via the distributor plate (16).Type: GrantFiled: January 10, 2008Date of Patent: January 18, 2011Assignee: BASF SEInventors: Andreas Wölfert, Herald Jachow, Heinz Drieβ
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Patent number: 7854915Abstract: The invention relates to a method of producing sulfuric acid wherein an SO2-containing raw gas produced in a sulfuric-acid recovery plant is passed through at least one reactor in which a catalytic reaction of SO2 to SO3 takes place, and the SO3 thereby formed is converted into sulfuric acid. According to the invention, at least a partial stream of the gas stream leaving the sulfuric-acid recovery plant is hydrogenated with an H2-rich gas in a post-treatment stage. The H2S-containing gas stream formed by the hydrogenation is fed into the H2S gas scrubber of a coke oven plant or a petrochemical plant. The invention also relates to an installation for carrying out the method.Type: GrantFiled: March 20, 2008Date of Patent: December 21, 2010Assignee: Uhde GmbHInventor: Holger Thielert
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Patent number: 7833508Abstract: The invention relates to a reaction vessel in which hydrogen sulphide is prepared from sulphur and hydrogen, wherein the reaction vessel consists partly or entirely of a material which is resistant to the reaction mixture, its compounds or elements and retains its resistance even at high temperatures.Type: GrantFiled: July 10, 2009Date of Patent: November 16, 2010Assignee: Evonik Degussa GmbHInventors: Hubert Redlingshöfer, Jan-Olaf Barth, Caspar-Heinrich Finkeldei, Hans Joachim Hasselbach, Stephan Kretz, Harald Heinzel, Christoph Weckbecker
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Patent number: 7833509Abstract: The invention relates to a process and to an apparatus for preparing hydrogen sulfide H2S by converting a reactant mixture which comprises gaseous sulfur and hydrogen over a solid catalyst. The reactant mixture is converted at a pressure of from 0.5 to 10 bar absolute, a temperature of from 300 to 450° C. and a sulfur excess in a reactor (1). The sulfur excess corresponds to a ratio of excess sulfur to H2S prepared of from 0.2 to 3 kg of sulfur per kg of H2S prepared.Type: GrantFiled: January 14, 2008Date of Patent: November 16, 2010Assignee: BASF SEInventors: Andreas Wölfert, Herald Jachow, Heinz Drieβ
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Patent number: 7824638Abstract: This disclosure relates generally to processes for efficient incineration and conversion of the tail gas streams from sulfur recovery units containing sulfur compounds such as H2S, CO2, COS, CS2, and other sulfur species and sulfur vapors from S1 to S8 to SO2. The present disclosure describes the use of a combination of catalysts to achieve efficient oxidation of all reduced sulfur compounds as well as oxidation of CO and H2 to meet the industry emission requirements. The catalytic tail gas incineration process described herein can advantageously operate at lower temperatures, which in turn can represent a savings in reduced fuel gas costs.Type: GrantFiled: March 4, 2009Date of Patent: November 2, 2010Assignee: Worleyparsons Group, Inc.Inventors: Mahin Rameshni, Stephen Santo
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Publication number: 20100196245Abstract: A process for substantially removing carbonaceous material from a composition comprising providing the composition having carbonaceous material, reacting the carbonaceous material with a sulfur compound, and forming products having carbon and sulfur, and the resulting composition and system used therefore.Type: ApplicationFiled: April 5, 2010Publication date: August 5, 2010Inventors: Raymond C. Stenger, James A. Wasas
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Publication number: 20100159135Abstract: The present disclosure relates to novel methods and apparatuses for generating hydrogen sulfide or hydrogen selenide gas from decomposition of a solid precursor. In some embodiments, the generated gas is cooled so as to condense a by-product of the decomposition and thereby increasing the purity of the gas. In some embodiments, the generated hydrogen sulfide or hydrogen selenide gas is used to prepare metal sulfide or metal selenide films.Type: ApplicationFiled: December 18, 2009Publication date: June 24, 2010Applicant: The Board of Trustees of the Leland Stanford Junior UniversityInventors: Stacey Bent, Jeffrey S. King, Jonathan R. Bakke
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Patent number: 7736618Abstract: The invention relates to a reaction vessel in which hydrogen sulphide is produced from sulphur and hydrogen, wherein the reaction vessel is partially or completely made up of a material which is resistant to the reaction mixture and its compounds and/or elements and which remains resistant even at high temperatures.Type: GrantFiled: April 2, 2007Date of Patent: June 15, 2010Assignee: Evonik Degussa GmbHInventors: Hubert Redlingshoefer, Karl-Guenther Schuetze, Christoph Weckbecker, Klaus Huthmacher
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Publication number: 20100137595Abstract: Use vaginal odorant compounds for controlling motile cell chemotaxis.Type: ApplicationFiled: June 27, 2008Publication date: June 3, 2010Applicant: Fraunhofer-Gesellshcaft zur Forderung der angewandten Forschung e.V.Inventor: Andrea Büttner
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Publication number: 20100015036Abstract: The present invention describes a reactor (1) for continuously preparing hydrogen sulfide H2S from hydrogen and sulfur, comprising a distributor device (15) for distributing gaseous hydrogen in a sulfur melt (9) present at least in a lower part of the reactor. The distributor device (15) is arranged in the sulfur melt (9) and comprises a distributor plate (16) which is arranged in the reactor (1) and has an edge (17) extending downward and, if appropriate, has passage orifices (19). The hydrogen from a hydrogen bubble which forms below the distributor plate (16) is (for example through the passage orifices (19)) distributed in the sulfur melt (9) via the distributor plate (16).Type: ApplicationFiled: January 10, 2008Publication date: January 21, 2010Applicant: BASF SEInventors: Andreas Wölfert, Herald Jachow, Heinz Driess
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Patent number: 7625539Abstract: A process for producing a purified gas stream from a feed gas stream comprising contaminants, the process comprising the steps of: (a) removing contaminants from the feed gas stream to obtain the purified gas stream and a sour gas stream comprising H2S and RSH; (b) separating the sour gas stream comprising H2S and RSH into a gas stream enriched in H2S and a residual gas stream comprising RSH; (c) converting H2S in the gas stream enriched in H2S to elemental sulphur in a Claus unit, thereby obtaining a first off-gas stream comprising SO2; (d) converting SO2 in the first off-gas stream comprising SO2 to H2S in a Claus off-gas treating reactor to obtain a second off-gas stream comprising H2S; (e) converting RSH from the residual gas stream comprising RSH to H2S in an RSH conversion reactor to obtain a residual gas stream comprising H2S, wherein at least one of the operating conditions of the RSH conversion reactor is different from the corresponding operating condition of the Claus off-gas treating reactor.Type: GrantFiled: November 2, 2006Date of Patent: December 1, 2009Assignee: Shell Oil CompanyInventors: Cornelis Petrus Johannes Maria Van Den Brand, Lydia Singoredjo, Johannes Theodorus Maria Smits
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Patent number: 7560409Abstract: Photo-oxidation catalysts and methods for cleaning a metal-based catalyst are disclosed. An exemplary catalyst system implementing a photo-oxidation catalyst may comprise a metal-based catalyst, and a photo-oxidation catalyst for cleaning the metal-based catalyst in the presence of light. The exposure to light enables the photo-oxidation catalyst to substantially oxidize absorbed contaminants and reduce accumulation of the contaminants on the metal-based catalyst. Applications are also disclosed.Type: GrantFiled: August 19, 2005Date of Patent: July 14, 2009Assignee: Alliance for Sustainable Energy, LLCInventors: J. Roland Pitts, Ping Liu, R. Davis Smith
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Publication number: 20090175774Abstract: The detecting and monitoring of solid structure or phase transformation, such as those used for testing the formation of gas hydrates and their inhibition by chemical additives may be conducted in a multi-test assembly of laboratory bench scale loops. The test loop contains a fluid that includes water and hydrate-forming guest molecules such as methane, ethane, carbon dioxide and the like at hydrate-forming conditions of low temperature and high pressure. A small bit or “pig” may be circulated through the test loop at variable speeds. The pig may be moved or impelled through the test loop remotely. The formation of hydrates may be monitored with consistent and reproducible results.Type: ApplicationFiled: January 3, 2008Publication date: July 9, 2009Applicant: BAKER HUGHES INCORPORATEDInventor: Jun TIAN
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Publication number: 20090053130Abstract: The invention relates to a reaction vessel in which hydrogen sulphide is produced from sulphur and hydrogen, wherein the reaction vessel is partially or completely made up of a material which is resistant to the reaction mixture and its compounds and/or elements and which remains resistant even at high temperatures.Type: ApplicationFiled: April 2, 2007Publication date: February 26, 2009Applicant: EVONIK DEGUSSA GMBHInventors: Hubert Redlingshoefer, Karl-Guenther Schuetze, Christoph Weckbecker, Klaus Huthmacher
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Patent number: 7485281Abstract: The reduction of gas streams containing sulfur dioxide to elemental sulfur is carried out by contacting a reducing gas, such as natural gas, methanol or a mixture of hydrogen and carbon monoxide, with recycled sulfur to produce a stream containing hydrogen sulfide that may be reacted with the gas stream that contains sulfur dioxide. Gas streams with a molar concentration of sulfur dioxide from 1 to 100% may be processed to achieve nearly 100% sulfur recovery efficiency.Type: GrantFiled: June 13, 2006Date of Patent: February 3, 2009Assignee: Worleyparsons Group, Inc.Inventor: Mahin Rameshni
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Publication number: 20080187485Abstract: The invention provides a method of extracting the hydrogen sulfide contained in a gas comprising aromatic hydrocarbons, wherein the following stages are carried out: a) contacting said gas with an absorbent solution so as to obtain a gas depleted in hydrogen sulfide and an absorbent solution laden with hydrogen sulfide, b) heating and expanding the hydrogen sulfide-laden absorbent solution to a predetermined temperature and pressure so as to release a gaseous fraction comprising aromatic hydrocarbons and to obtain an absorbent solution depleted in aromatic hydrocarbons, said temperature and pressure being so selected that said gaseous fraction comprises at least 50% of the aromatic hydrocarbons and at most 35% hydrogen sulfide contained in said hydrogen sulfide-laden absorbent solution, c) thermally regenerating the absorbent solution depleted in aromatic hydrocarbon compounds so as to release a hydrogen sulfide-rich gaseous effluent and to obtain a regenerated absorbent solution.Type: ApplicationFiled: February 6, 2007Publication date: August 7, 2008Inventors: Julia Magne-Drisch, Anne-Claire Lucquin, Christina Streicher, Jean Elgue, Jean-Paul Cousin, Gauthier Perdu, Damien Roquet, Viep Hoang Dinh
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Publication number: 20080019899Abstract: Hydrogen sulfide is selectively enriched from an acid gas (1) that comprises relatively large quantities of carbon dioxide using a configuration in which a portion of an isolated hydrogen sulfide stream is introduced into an absorber (51) operating as a carbon dioxide rejecter. The resulting concentrated hydrogen sulfide enriched solvent (4) is then further used (directly or indirectly) to absorb hydrogen sulfide from an acid feed gas.Type: ApplicationFiled: August 18, 2004Publication date: January 24, 2008Inventors: John Mak, Richard B. Nielsen, Thomas King Chow, Oliver Margan, Vincent Wai Wong
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Patent number: 7014833Abstract: A process for reacting a first component with itself or a second component to produce a third component in which a first material comprising a first component or said first component and a second component is fed to divided wall column having a catalytic distillation structure in at least one of the separate vertical sections of the divided wall column where concurrently: (1) a first component alone or with a second component is contacted with a catalytic distillation structure in a distillation reaction zone thereby catalytically reacting at least a portion of the first component with itself or with the second component to form a product and (2) a first mixture comprising the first component and the product or the first component, the second component and the product; and withdrawing the product from the distillation column reactor; while within the column concurrently with the catalytic reaction and fractionation a second mixture is fractionated, which contains the first component and the product or first aType: GrantFiled: May 5, 2004Date of Patent: March 21, 2006Assignee: Catalytic Distillation TechnologiesInventors: Willibrord A. Groten, Mario J. Maraschino
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Patent number: 6852305Abstract: A process is provided for the production of hydrogen sulphide from the bacterial reduction of a mixture of a liquid and elemental sulfur with an electron donor, such as hydrogen gas, carbon monoxide or organic compounds. The bacteria may be Desulforomonas sp. (mesophilic), Desulfotomaculum KT7 (thermophilic), etc. The liquid/sulfur mixture is at a pH ranging from 5 to 9, and the liquid/sulfur mixture contacts the bacteria at a hydraulic retention time of at least 1 day. The hydrogen sulphide is stripped from the liquid medium to produce a gas containing at least 1 volume percent hydrogen sulphide.Type: GrantFiled: November 25, 2003Date of Patent: February 8, 2005Assignee: Paques Bio Systems B.V.Inventors: Cees Jan Nico Buisman, Henk Dijkman
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Patent number: 6676918Abstract: A method for removing hydrogen sulfide from liquid sulfur, comprising introducing liquid sulfur containing hydrogen sulfide in an upstream portion of a conduit. The conduit has a fluid outlet in a downstream portion thereof located within a lower portion of a first vessel. The method further includes causing the liquid sulfur to flow through the conduit outlet into the first vessel, up an annulus formed between the conduit and the first vessel and overflow through an outlet positioned at an upper portion of the first vessel into a second vessel which is connected to a liquid sulfur pit operating at atmospheric pressure. Air is introduced into the liquid sulfur located in the annulus at a point between the conduit outlet and said first vessel outlet. The flows concurrently to the direction of flow of the liquid sulfur in the annulus and out of the first vessel outlet into the second vessel thereby removing hydrogen sulfide from the liquid sulfur in the annulus.Type: GrantFiled: March 21, 2003Date of Patent: January 13, 2004Assignee: ExxonMobil Research and Engineering CompanyInventors: Francis Sui Lun Wu, Michael Allen Capone, Raymond Paul Shapka, David Ian Devenny
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Publication number: 20020068034Abstract: The present invention provides a method for inhibiting the evolution of H2S from sulfhydryl compounds in molten sulfur by using scavenging agents such as anhydrides and polymers thereof, conjugated ketones, carbonates, epoxides, monoesters and diesters of unsaturated dicarboxylic acids and polymers of these esters, and the like and mixtures thereof. In one embodiment, it is preferred that the scavenging agent is in liquid form at contact temperature with the molten sulfur. In another embodiment, the scavenging agent may be atomized into the vapor space over the molten sulfur to contact the sulfur with the agent.Type: ApplicationFiled: October 9, 2001Publication date: June 6, 2002Inventors: John A. Schield, Weldon J. Cappel, Jerry J. Weers, Glenn L. Roof
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Methods of chemically converting first materials to second materials utilizing hybrid-plasma systems
Patent number: 6372156Abstract: In one aspect, the invention encompasses a method of chemically converting a first material to a second material. A first plasma and a second plasma are formed, and the first plasma is in fluid communication with the second plasma. The second plasma comprises activated hydrogen and oxygen, and is formed from a water vapor. A first material is flowed into the first plasma to at least partially ionize at least a portion of the first material. The at least partially ionized first material is flowed into the second plasma to react at least some components of the first material with at least one of the activated hydrogen and activated oxygen. Such converts at least some of the first material to a second material. In another aspect, the invention encompasses a method of forming a synthetic gas by flowing a hydrocarbon-containing material into a hybrid-plasma system.Type: GrantFiled: August 19, 1999Date of Patent: April 16, 2002Assignee: Bechtel BWXT Idaho, LLCInventors: Peter C. Kong, Jon D. Grandy