Bismuth Or Antimony Containing (e.g., Bismuthate, Antimonate, Etc.) Patents (Class 423/594.7)
  • Publication number: 20080020236
    Abstract: Provided are an alkaline earth metal silicate-based phosphor which is a compound represented by Formula 1 below, and a white light-emitting device (LED) including the same. (M11-x-yAxBy)aMgbM2cOdZeFormula 1 wherein, M1 is one selected from the group consisting of Ba, Ca, and Sr; M2 is at least one selected from Si or Ge; A and B are each independently one selected from the group consisting of Eu, Ce, Mn, Pr, Nd, Sm, Gd, Tb, Dy, Ho, Er, Tm, Yb, Bi, Sn, and Sb; Z is at least one selected from the group consisting of a monovalent or divalent element, H, and N; and 0<x<1, 0?y?1, 6.3<a<7.7, 0.9<b<1.1, 3.6<c<4.4, 14.4<d<17.6, 14.4<d+e<17.6, and 0?e?0.18. The alkaline earth metal silicate-based phosphor has a broad excitation wavelength range, and thus, both a UV-LED and a blue LED can be used as excitation sources for white LEDs.
    Type: Application
    Filed: March 19, 2007
    Publication date: January 24, 2008
    Applicant: SAMSUNG ELECTRONICS CO., LTD.
    Inventors: Kubota Shunichi, Young-sic KIM, Seoung-jae IM
  • Patent number: 7297322
    Abstract: A process for producing powders of metal compound containing oxygen including the steps of: feeding at least one material selected from a liquid material and a solution material obtained by dissolving solid ingredient in organic solvent via a liquid flow controller into a vaporizer; vaporizing the materials in the vaporizer; adding oxygen; heating; cooling; and crystallizing. Also disclosed is the product formed by this process, and apparatus used in performing the process. The process and the apparatus enable easily mass-producing fine powders of metal compound containing oxygen used as materials for optical crystals, nonlinear crystals or magneto-optical crystals with reasonable production cost.
    Type: Grant
    Filed: March 11, 2005
    Date of Patent: November 20, 2007
    Assignee: Japan Pionics Co., Ltd.
    Inventors: Yukichi Takamatsu, Koji Kiriyama, Akira Asano, Takafumi Ishii
  • Patent number: 7241532
    Abstract: A subject for the invention is to provide a positive-electrode material, which has high capacity and high output and is inhibited from suffering a decrease in output with repetitions of charge and use. The invention provides a positive-electrode material for lithium secondary battery, which comprises a secondary particle of a lithium/transition metal composite oxide containing boron and/or bismuth, and wherein the atomic ratio of the sum of boron and bismuth to the sum of the metallic elements other than lithium, boron, and bismuth in a surface part of the secondary particle is from 5 times to 70 times the atomic ratio in the whole secondary particle.
    Type: Grant
    Filed: September 28, 2004
    Date of Patent: July 10, 2007
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Kazuhiro Kikuchi, Koji Shima
  • Patent number: 7232556
    Abstract: Nanoparticles comprising titanium, such as nanoscale doped titanium metal compounds, inorganic titanium compounds, and organic titanium compounds, their methods of manufacture, and methods of preparation of products from nanoparticles comprising titanium are provided.
    Type: Grant
    Filed: September 24, 2004
    Date of Patent: June 19, 2007
    Assignee: NanoProducts Corporation
    Inventor: Tapesh Yadav
  • Patent number: 7208135
    Abstract: Process for preparing mixed oxides by reacting alkoxides of the elements titanium, zirconium, niobium, tantalum or mixtures thereof with metal hydroxides, metal carboxylates, metal hydroxycarbonates, metal carbonates or mixtures thereof of the elements lithium, sodium, potassium, magnesium, calcium, strontium, barium, zinc, cadmium, aluminum, gallium, yttrium, lanthanum, praseodymium, neodymium, samarium, dysprosium, europium, lead, bismuth or mixtures thereof in a C1–C8-alkanol, in a glycol ether or in a mixture thereof at from 50 to 200° C.
    Type: Grant
    Filed: May 18, 2004
    Date of Patent: April 24, 2007
    Assignee: BASF Aktiengesellschaft
    Inventor: Hans-Josef Sterzel
  • Patent number: 7157024
    Abstract: The present invention relates to a metal oxide particle comprising tin atom, zinc atom, antimony atom and oxygen atom, having a molar ratio SnO2:ZnO:Sb2O5 of 0.01–1.00:0.80–1.20:1.00 and having a primary particle diameter of 5 to 500 nm; and a process for producing the metal oxide particle comprising the steps of: mixing a tin compound, a zinc compound and an antimony compound in a molar ratio SnO2:ZnO:Sb2O5 of 0.01–1.00:0.80–1.20:1.00; and calcining the mixture at a temperature of 300 to 900° C. The metal oxide particle is used for several purposes such as antistatic agents, UV light absorbers, heat radiation absorbers or sensors for plastics or glass, etc.
    Type: Grant
    Filed: May 24, 2004
    Date of Patent: January 2, 2007
    Assignee: Nissan Chemical Industries, Ltd.
    Inventors: Tadayuki Isaji, Osamu Fujimoto
  • Patent number: 7138102
    Abstract: A method for manufacturing a highly-crystallized double oxide powder composed of a single crystal phase which can be used as a phosphor material, a dielectric material, a magnetic material, etc. The method involves forming fine droplets of a raw material solution containing a raw material compound that includes at least one metal element and/or at least one semi-metal element that constitutes a double oxide, and heating these droplets at a high temperature, wherein the raw material solution is a solution which exhibits only one main peak attributable to the decomposition reaction of the raw material compound or a reaction intermediate thereof in a DTA profile when the solution is dried and solidified and subjected to TG-DTA measurement.
    Type: Grant
    Filed: July 1, 2003
    Date of Patent: November 21, 2006
    Assignee: Shoei Chemical Inc.
    Inventors: Yuji Akimoto, Kazuro Nagashima, Yoshikazu Nageno, Hidenori Ieda, Naoko Tanaka
  • Patent number: 7105145
    Abstract: Ferroelectric metal oxide crystalline particles are produced by first producing nanoparticles of a ferroelectric metal oxide and dispersing the nanoparticles in a gas phase. Then, the nanoparticles are processed by heat treatment with the nanoparticles being maintained in the gas phase in a dispersed state. The nanoparticles may be produced by using a laser ablation method. The ferroelectric metal oxide may have a perovskite crystal structure.
    Type: Grant
    Filed: October 30, 2002
    Date of Patent: September 12, 2006
    Assignee: RIKEN
    Inventors: Kwang-Soo Seol, Kazuo Takeuchi, Takeshi Miyagawa, Yoshimichi Ohki
  • Patent number: 7011908
    Abstract: The present invention provides a manganese bismuth mixed metal oxide cathode material through a solid-state reaction between manganese dioxide, and either bismuth or a bismuth compound in a compound having the general formula MnOy(Bi2O3)x, which affords charge transfer catalytic behavior that allows the cathode to be fully reversible at suppressed charge potentials and increased discharge potentials. The MnOy(Bi2O3)x cathode material may be incorporated into an electrochemical cell with either a lithium metal or lithium ion anode and an organic electrolyte. The present invention provides a compound with the general formula MnOy(Bi2O3)x, where subscript x is between 0.05 and 0.25, subscript y is about 2 and the overcharge protection is not needed as the subscript z approaches 0.0. In the preferred embodiment, a cathode material where subscript x is between 0.05 and 0.135 with the formula MnO2(Bi2O3)0.12 provides the much-needed full reversibility, high voltage stability and reduced charge transfer impedance.
    Type: Grant
    Filed: October 8, 2003
    Date of Patent: March 14, 2006
    Assignee: The United States of America as represented by the Secretary of the Army
    Inventors: Terrill B. Atwater, Alvin J. Salkind, Arek Suszko
  • Patent number: 6926999
    Abstract: A cathode active material for alkaline electrochemical cells comprising an Ag—Bi-M-containing oxidation product produced by oxidizing with an oxidizing agent an Ag—Bi-M-containing neutralized precipitate obtained by reacting inorganic acid salts of silver, bismuth and, optionally, M (M representing at least one metal selected from the group comprised of manganese, nickel and cobalt) with an alkali hydroxide in an aqueous medium; or comprising an Ag—Bi-M-containing oxidation product obtained by reacting inorganic acid salts of silver, bismuth and, optionally, M with an alkali hydroxide in an aqueous medium and in the presence of an oxidizer.
    Type: Grant
    Filed: September 10, 2001
    Date of Patent: August 9, 2005
    Assignee: Dowa Mining Co., Ltd.
    Inventors: Koji Tanoue, Yoshikazu Omoto, Yoshiyuki Shoji, Masayuki Nishina, Toshio Ueda
  • Patent number: 6830822
    Abstract: A pigment with modified properties because of the powder size being below 100 nanometers. Blue, yellow and brown pigments are illustrated. Nanoscale coated, un-coated, whisker inorganic fillers are included. Stoichiometric and non-stoichiometric composition are disclosed. The pigment nanopowders taught comprise one or more elements from the group actinium, aluminum, antimony, arsenic, barium, beryllium, bismuth, cadmium, calcium, cerium, cesium, cobalt, copper, chalcogenide, dysprosium, erbium, europium, gadolinium, gallium, gold, hafnium, hydrogen, indium, iridium, iron, lanthanum, lithium, magnesium, manganese, mendelevium, mercury, molybdenum, neodymium, neptunium, nickel, niobium, nitrogen, oxygen, osmium, palladium, platinum, potassium, praseodymium, promethium, protactinium, rhenium, rubidium, scandium, silver, sodium, strontium, tantalum, terbium, thallium, thorium, tin, titanium, tungsten, vanadium, ytterbium, yttrium, zinc, and zirconium.
    Type: Grant
    Filed: May 30, 2003
    Date of Patent: December 14, 2004
    Assignee: NanoProducts Corporation
    Inventor: Tapesh Yadav
  • Patent number: 6780394
    Abstract: A perovskite feedstock (powder or preform) is placed in a high-pressure cell of a high pressure/high temperature (HP/HT) apparatus and subjected to pressures in excess of about 2 kbar and temperatures above about 800° C. for a time adequate to increase the density of the preform.
    Type: Grant
    Filed: August 16, 2001
    Date of Patent: August 24, 2004
    Assignee: Diamond Innovations, Inc.
    Inventors: Suresh S. Vagarali, John W. Lucek
  • Patent number: 6770256
    Abstract: Metal oxides having a perovskite or perovskite-like crystal structure are prepared by a process comprising subjecting a mixture of starring powders to a high energy milling sufficient to induce chemical reaction of the components and thereby directly mechanosynthesize said metal oxide in the form of a perovskite or a perovskite-like material having a nanocrystalline structure as determined by X-ray diffractometry. The process according to the present invention is simple, efficient, not expensive and does not require any heating step for producing a perovskite that may easily show a very high specific surface area. Another advantage is that the perovskite obtained according to the present invention also has a high density of lattice defects thereby showing a higher catalytic activity, a characteristic which is highly desirable in their eventual application as catalysts and electronic conductors.
    Type: Grant
    Filed: April 9, 2001
    Date of Patent: August 3, 2004
    Assignee: Universite Laval
    Inventors: Serge Kaliaguine, André Van Neste
  • Publication number: 20040120881
    Abstract: Grain oriented ceramics constituted of a polycrystalline body having a first perovskite-type alkali-pentavalent metal oxide compound as the main phase, in which a specific crystal plane of each grain constituting the polycrystalline body is oriented. The grain oriented ceramics are obtained by molding a mixture of a first anisotropically-shaped powder A of which developed plane has a lattice matching with a specific crystal plane of the first perovskite-type alkali-pentavalent metal oxide compound and a first reaction material capable of reacting with the first anisotropically-shaped powder A thereby forming at least the first perovskite-type alkali-pentavalent metal oxide compound such that the first anisotropically-shaped powder A is oriented, and by heating them.
    Type: Application
    Filed: December 11, 2003
    Publication date: June 24, 2004
    Applicant: KABUSHIKI KAISHA TOYOTA CHUO KENKYUSHO
    Inventors: Hisaaki Takao, Yasuyoshi Saito, Toshihiko Tani
  • Publication number: 20040110641
    Abstract: The present invention provides a Bi2223 based thick film that does not peel off when a thermal or a mechanical shock is applied to a base or an oxide superconductor thick film or the like in the middle of a manufacturing process and a method of manufacturing the same An oxide superconductor paste 1 having a mixing ratio of Bi2212 composition is applied to a base 3, dried, burned, and thereafter burned at a temperature approximate to its melting point to obtain a partially molten layer 4. Next, an oxide superconductor paste 2 having a mixing ratio of Bi2223 composition is applied to the partially molten layer 4, dried, burned, compressed by a CIP, and thereafter repeatedly burned and compressed for a predetermined number of times to obtain the base 3 having a desired superconductor thick film 5 formed thereon.
    Type: Application
    Filed: July 31, 2003
    Publication date: June 10, 2004
    Applicants: DOWA MINING CO., LTD., CENTRAL RESEARCH INSTITUTE OF ELECTRIC POWER INDUSTRY
    Inventors: Masahiro Kojima, Masakazu Kawahara, Michiharu Ichikawa, Hiroyuki Kado, Masatoyo Shibuya
  • Publication number: 20040086452
    Abstract: In a method of producing ferroelectric metal oxide crystalline particles, used is an apparatus including a particle producing device, a heat treatment device and a particle collecting device. The particle producing device produces nanoparticles of a ferroelectric metal oxide from a particle source placed in a vessel by a laser ablation method, in which the particle source is irradiated with a laser beam emitted by a laser device, and the nanoparticles are dispersed in an oxygen atmosphere (gas phase). The nanoparticles produced in the vessel and dispersed in a carrier gas is supplied through a connecting pipe into a vessel included in the heat treatment device. The heat treatment device processes the nanoparticles by a heat treatment that heats the nanoparticles dispersed in the oxygen gas atmosphere at a predetermined temperature for a predetermined time while the nanoparticles flow together with the carrier gas through the vessel.
    Type: Application
    Filed: October 30, 2002
    Publication date: May 6, 2004
    Inventors: Kwang-Soo Seol, Kazuo Takeuchi, Takeshi Miyagawa, Yoshimichi Ohki