Abstract: A variety of redox catalysts, methods of making, and methods of using thereof are provided. Surface modified redox catalysts are provided having an oxygen carrier core with an outer surface that has been modified to enhance the selectivity of the redox catalyst for oxidative dehydrogenation. The surface modification can include forming a redox catalyst outer layer on the outer surface and/or suppressing sites that form nonselective electrophilic oxygen sites on the outer surface of the oxygen carrier. A variety of methods are provided for making the surface modified redox catalysts, e.g. modified Pechini methods. A variety of methods are provided for using the catalysts for oxidative cracking of light paraffins. Methods are provided for oxidative cracking of light paraffins by contacting the paraffin with a core-shell redox catalyst described herein to convert the paraffins to water and olefins, diolefins, or a combination thereof.
Type:
Grant
Filed:
September 12, 2017
Date of Patent:
January 30, 2024
Assignee:
North Carolina State University
Inventors:
Fanxing Li, Luke Michael Neal, Junshe Zhang
Abstract: A composition of matter consisting primarily of a stabilizing element and a transition metal oxide, wherein the transition metal oxide is an anti-ferromagnetic Mott insulator with strong spin orbit interactions, and the composition of matter has a canted crystal structure.
Type:
Grant
Filed:
October 11, 2019
Date of Patent:
September 19, 2023
Assignee:
The Regents of the University of Colorado
Abstract: A method for crystallization of ?-ammonium tetramolybdate includes: performing a stepwise pH-adjusting treatment of an ammonium molybdate solution via zoning to obtain the ?-ammonium tetramolybdate. When feeding the ammonium molybdate solution into a reaction system from a first zone and then into second to sixth zones successively, pH1 of a resultant solution in the first zone is 7.0-6.0; pH2 of a resultant solution in the second zone is less than 6 and greater than or equal to 4; pH3 of a resultant solution in the third zone is less than 4 and greater than or equal to 2.5; pH4 of a crystallized slurry in the fourth zone is less than 2.5 and greater than or equal to 1; pH5 of a crystallized slurry in the fifth zone is 2.5-4.0; and pH6 of a crystallized slurry in the sixth zone is less than 2.5 and greater than or equal to 2.0.
Abstract: A method of producing an organic pigment composition including at least organic pigment microparticles, wherein a diffuse reflectance of the organic pigment microparticles is controlled for the purpose of improving a luminance of a color filter. The luminance of the color filter is controlled to be high, by controlling a ratio of an area of the diffuse reflectance in a target wavelength range to a total area of the diffuse reflectance in the entire measurement wavelength range in a diffuse reflection spectrum of the organic pigment microparticles in the wavelength range of 380 to 780 nm, to be high. The luminance of the color filter is controlled to be high, by coating at least a part of the surface of the organic pigment microparticles with an oxide.
Abstract: A positive electrode active material for lithium secondary batteries includes a lithium composite metal compound containing secondary particles that are aggregates of primary particles which are capable of being doped or dedoped with lithium ions and satisfies all of specific requirements (1) to (4).
Type:
Grant
Filed:
December 21, 2017
Date of Patent:
December 20, 2022
Assignees:
SUMITOMO CHEMICAL COMPANY, LIMITED, TANAKA CHEMICAL CORPORATION
Abstract: A nanoparticle containing monoclinic lutetium oxide. A method of: dispersing a lutetium salt solution in a stream of oxygen gas to form droplets, and combusting the droplets to form nanoparticles containing lutetium oxide. The combustion occurs at a temperature sufficient to form monoclinic lutetium oxide in the nanoparticles. An article containing lutetium oxide and having an average grain size of at most 10 microns.
Type:
Grant
Filed:
August 15, 2012
Date of Patent:
September 28, 2021
Assignee:
The Government of the United States of America, as represented by the Secretary of the Navy
Inventors:
Colin C. Baker, Woohong Kim, Guillermo R. Villalobos, Jasbinder S. Sanghera, Ishwar D. Aggarwal
Abstract: The present disclosure is directed to methods for producing metal oxynitrides using flame synthesis. Embodiments of the disclosure may provide advantages over prior synthesis techniques by reducing synthesis time. Additionally, methods and systems disclosed herein may achieve better incorporation of nitrogen atoms into the oxide structure due in part to the higher homogeneity of flame made particles and ability to control the reaction environment.
Type:
Grant
Filed:
April 17, 2020
Date of Patent:
January 26, 2021
Assignee:
University of South Carolina
Inventors:
Erdem Sasmaz, Nicole Cordonnier, Benjamin Meekins, Jennifer Naglic
Abstract: A method for forming a light extraction layer including nanostructures, the method including: providing a substrate, the substrate being at least partially transparent to UV light; forming a non-aqueous precursor solution comprising fluorine and an alkaline earth metal to form alkaline earth metal difluoride particles; applying the precursor solution on at least a first side of the substrate; drying the substrate at a first temperature for a first period of time; and baking the substrate at a second temperature, higher than the first temperature, for a second period of time, thereby forming a light extraction nanostructure layer comprising alkaline earth metal difluoride nanostructures on the substrate. Also, a light extraction structure and to a UV lamp including such an extraction structure.
Abstract: Iron-containing mixed-phase metal oxides are described. The mixed-phase metal oxides can exhibit electrocatalytic and/or photo-electrocatalytic activity towards reducing reactions, such as the reduction of carbon dioxide.
Abstract: An iron-based powder for powder metallurgy includes an iron-based powder and a composite oxide powder, and the composite oxide contains, by mass, from 15% to 30% Si, from 9% to 18% Al, from 3% to 6% B, from 0.5% to 3% Mg, from 2% to 6% Ca, from 0.01% to 1% Sr, and from 45% to 55% O.
Type:
Grant
Filed:
February 2, 2017
Date of Patent:
May 7, 2019
Assignees:
Sumitomo Electric Industries, Ltd., Sumitomo Electric Sintered Alloy, Ltd.
Abstract: An iron-based powder for powder metallurgy includes an iron-based powder and a composite oxide powder, and the composite oxide contains, by mass, from 15% to 30% Si, from 9% to 18% Al, from 3% to 6% B, from 0.5% to 3% Mg, from 2% to 6% Ca, from 0.01% to 1% Sr, and from 45% to 55% O.
Type:
Grant
Filed:
February 2, 2017
Date of Patent:
February 5, 2019
Assignees:
Sumitomo Electric Industries, Ltd, Sumitomo Electric Sintered Alloy, Ltd.
Abstract: The present invention relates to vanadium oxide and methods of controlling reaction processes for making such materials (e.g., powders). In particular embodiments, the method includes control of oxygen partial pressure in order to kinetically control the oxidation species of the crystalline vanadium oxide material. Other methods, uses, systems, protocols, and coatings are also described.
Type:
Grant
Filed:
May 27, 2015
Date of Patent:
December 25, 2018
Assignee:
National Technology & Engineering Solutions of Sandia, LLC
Inventors:
Mark A. Rodriguez, Nelson S. Bell, Paul G. Clem, Cynthia Edney, James Griego
Abstract: Provided axe porous titanate compound particles capable of giving excellent fade resistance when used in a friction material, a resin compound and a friction material each containing the porous titanate compound particles, and a method for producing the porous titanate compound particles. Porous titanate compound particles are each formed of titanate compound crystal grains bonded together and have a cumulative pore volume of 5% or more within a pore diameter range of 0.01 to 1.0 ?m.
Abstract: Zirconia dental ceramics exhibiting opalescence and having a grain size in the range of 10 nm to 300 nm, a density of at least 99.5% of theoretical density, a visible light transmittance at or higher than 45% at 560 nm, and a strength of at least 800 MPa.
Type:
Grant
Filed:
June 12, 2014
Date of Patent:
June 26, 2018
Assignee:
Ivoclar Vivadent, Inc.
Inventors:
Dmitri G. Brodkin, Yijun Wang, Ling Tang, Ajmal Khan, Anna B. Verano
Abstract: A dielectric ceramic composition contains a first main ingredient of BaTiO3 and a second main ingredient of BaTi2O5, and a base material powder containing the first and second main ingredients is represented by (1?x)BaTiO3?xBaTi2O5 and x satisfies 0.1?x?0.8. The dielectric ceramic composition may include additional accessory ingredients, and may be used to form ceramic sheets having internal electrodes of a multilayer ceramic capacitor disposed thereon.
Type:
Grant
Filed:
October 4, 2016
Date of Patent:
June 5, 2018
Assignee:
SAMSUNG ELECTRO-MECHANICS CO., LTD.
Inventors:
Seok Hyun Yoon, Seung Ho Lee, Jung Wook Seo, Song Je Jeon
Abstract: The invention is directed to a method for producing metal-containing particles, the method comprising subjecting an aqueous solution comprising a metal salt, Eh, lowering reducing agent, pH adjusting agent, and water to conditions that maintain the Eh value of the solution within the bounds of an Eh-pH stability field corresponding to the composition of the metal-containing particles to be produced, and producing said metal-containing particles in said aqueous solution at a selected Eh value within the bounds of said Eh-pH stability field. The invention is also directed to the resulting metal-containing particles as well as devices in which they are incorporated.
Type:
Grant
Filed:
March 12, 2014
Date of Patent:
March 6, 2018
Assignee:
UT-BATTELLE, LLC
Inventors:
Ji-Won Moon, Hyunsung Jung, Tommy Joe Phelps, Chad E. Duty, Ilia N. Ivanov, Pooran Chandra Joshi, Gerald Earle Jellison, Jr., Beth Louise Armstrong, Sean Campbell Smith, Adam Justin Rondinone, Lonnie J. Love
Abstract: Provided are a cathode active material including polycrystalline lithium manganese oxide and a sodium-containing coating layer on a surface of the polycrystalline lithium manganese oxide, and a method preparing the same. Since the cathode active material according to an embodiment of the present invention may prevent direct contact between the polycrystalline lithium manganese oxide and an electrolyte solution by including the sodium-containing coating layer on the surface of the polycrystalline lithium manganese oxide, the cathode active material may prevent side reactions between the cathode active material and the electrolyte solution. In addition, since limitations, such as the Jahn-Teller distortion and the dissolution of Mn2+, may be addressed by structurally stabilizing the polycrystalline lithium manganese oxide, tap density, life characteristics, and charge and discharge capacity characteristics of a secondary battery may be improved.
Abstract: Provided are a cathode active material including polycrystalline lithium manganese oxide and a boron-containing coating layer on a surface of the polycrystalline lithium manganese oxide, and a method preparing the same. Since the cathode active material according to an embodiment of the present invention may prevent direct contact between the polycrystalline lithium manganese oxide and an electrolyte solution by including the boron-containing coating layer on the surface of the polycrystalline lithium manganese oxide, the cathode active material may prevent side reactions between the cathode active material and the electrolyte solution. In addition, since limitations, such as the Jahn-Teller distortion and the dissolution of Mn2+, may be addressed by structurally stabilizing the polycrystalline lithium manganese oxide, tap density, life characteristics, and charge and discharge capacity characteristics of a secondary battery may be improved.
Abstract: The invention id directed to an article which contains a solid ion conductor which has a garnet-like crystal structure and has the stoichiometric composition L7+xAxG3?xZr2O12, where L is in each case independently a monovalent cation, A is in each case independently a divalent cation, G is in each case independently a trivalent cation, 0 ?x?3 and O can be partly or completely replaced by divalent or trivalent anion, wherein the article is a battery, an accumulator, a supercap, a fuel cell, sensor, a thermoelectric converter or an electrochromic device.
Abstract: Described herein are elements comprising a p-type semiconductor comprising mixed valence oxide compounds and an n-type semiconductor having a deeper valence band than the p-type semiconductor valence bands wherein the semiconductor types are in ionic communication with each other. The elements enhance photocatalytic activity.
Abstract: A sulfur sorbent composition includes a support structure and a double oxide sulfur scavenger that is supported on the support structure. The support structure may be diatomaceous earth or a zeolitic-type mineral, and the sulfur scavenger a metal and/or a metal oxide and/or a combination of two or more metal and/or oxides. The sulfur sorbent composition can be used either as a stand-alone device or in conjunction with a fuel reformer to provide a sulfur-free stream.
Abstract: A sorbent for capturing CO2 is fabricated. The sorbent is pelletized and used under a medium or high temperature. The sorbent is mainly made of aluminum calcium carbonate (Ca—Al—CO3). The present invention has a controllable ratio for mixing Ca—Al—CO3 with a release agent (magnesium stearate, MgSt) and a binder (activated carbon, cement or bentonite). The sorbent has a good performance for anti-degradation under a high temperature with 100% of CO2. During 10 loops of use, 43.3˜47.5% of CO2 is captured with an initial amount up to 10 milli-moles per gram (mmol/g) and a stability ratio up to 91.2% maintained.
Type:
Grant
Filed:
August 26, 2014
Date of Patent:
March 15, 2016
Assignee:
INSTITUTE OF NUCLEAR ENERGY RESEARCH, ATOMIC ENERGY COUNCIL, Executive Yuan, R.O.C.
Inventors:
Ching-Tsung Yu, Wun-Syong Chen, Huan-Ting Kuo
Abstract: A negative electrode for a lithium secondary battery that includes, as a negative active material, a lithium titanate (Li4Ti5O12) compound containing 0.004 parts by weight or less of phosphorous (P) and 0.007 parts by weight or less of potassium (K) based on 100 parts by weight of lithium titanate, a binder, and a conductive agent, and a lithium secondary battery including the negative electrode.
Abstract: Compositions having electrocatalytic activity and composites having electrocatalytic activity, as well as processes for making compositions and composites are described. Also, processes for using such compositions and/or composites, such as, for example, a machine or equipment are described. Some aspects of embodiments and/or embodiments of the present invention are directed to a nanosize transition metal alloy (such as for example an alloy and/or one or more intermetallics comprising copper, cobalt, nickel, palladium, platinum, ruthenium, the like, and combinations thereof) that is electrocatalytically active. Some other aspects of embodiments and/or embodiments of the present invention are directed to a composite material comprising a nanosize transition metal alloy and a carbonaceous matrix.
Type:
Grant
Filed:
July 20, 2012
Date of Patent:
September 29, 2015
Assignee:
KEMIJSKI INSTITUT
Inventors:
Marjan Bele, Miran Gaber{hacek over (sc)}ek, Gregor Kapun, Nejc Hodnik, Stanko Ho{hacek over (c)}evar
Abstract: A method for the rapid and continuous production of crystalline mixed-metal oxides from a precursor solution comprised of a polymerizing agent, chelated metal ions, and a solvent. The method discharges solution droplets of less than 500 ?m diameter using an atomizing or spray-type process into a reactor having multiple temperature zones. Rapid evaporation occurs in a first zone, followed by mixed-metal organic foam formation in a second zone, followed by amorphous and partially crystalline oxide precursor formation in a third zone, followed by formation of the substantially crystalline mixed-metal oxide in a fourth zone. The method operates in a continuous rather than batch manner and the use of small droplets as the starting material for the temperature-based process allows relatively high temperature processing. In a particular embodiment, the first zone operates at 100-300° C., the second zone operates at 300-700° C., and the third operates at 700-1000° C., and fourth zone operates at at least 700° C.
Type:
Grant
Filed:
June 5, 2014
Date of Patent:
September 8, 2015
Assignee:
U.S. Department of Energy
Inventors:
David A. Berry, Daniel J. Haynes, Dushyant Shekhawat, Mark W. Smith
Abstract: The present invention refers to a nanomaterial synthesis process from the decomposition and subsequent reaction among common and economical insoluble precursors, or precursors which hydrolyze in contact with water, which are incorporated in the internal phase of an emulsion. These insoluble precursors are introduced in the internal phase of an emulsion, then being subject to decomposition and subsequent reaction in the solid state, under shockwave effect during the detonation of the emulsion, the nanomaterial with the intended structure being in the end obtained. The process of the present invention therefore allows obtaining a wide range of nanomaterial as composites or binary, ternary structures or higher structures, with small-sized homogenous primary particles, applicable to several technological fields.
Type:
Grant
Filed:
October 14, 2011
Date of Patent:
August 25, 2015
Assignee:
Innovnano—Materiais A vançados, S.A.
Inventors:
Elsa Marisa Dos Santos Antunes, João Manuel Calado Da Silva, Ana Lúcia Costa Lagoa
Abstract: The present invention relates to a copper ion-modified tungsten oxide photocatalyst subjected to chemical etching treatment with a basic aqueous solution in which a rate of change in diffuse reflectance of the photocatalyst as measured at a wavelength of 700 nm between before and after irradiated with an ultraviolet light in atmospheric air is less than 10%; and a process for producing a copper ion-modified tungsten oxide photocatalyst which includes a copper ion modifying step of modifying a tungsten oxide powder with a copper ion; a chemical etching step of subjecting the tungsten oxide powder to chemical etching treatment with a basic aqueous solution, the chemical etching treatment being carried out either before or after the copper ion modifying step; and a drying step of drying the product obtained after the above steps at a temperature of 200° C. or lower.
Abstract: The present invention provides a sputtering target suitable for producing an amorphous transparent conductive film which can be formed without heating a substrate and without feeding water during the sputtering; which is easily crystallized by low-temperature annealing; and which has low resistivity after the crystallization. An oxide sintered compact containing an indium oxide as a main component, while containing tin as a first additive element, and one or more elements selected from germanium, nickel, manganese, and aluminum as a second additive element, with the content of tin which is the first additive element being 2-15 atom % relative to the total content of indium and tin, and the total content of the second additive element being 0.1-2 atom % relative to the total content of indium, tin and the second additive element.
Abstract: A method for allowing production of high-purity perrhenic acid from crude rhenium sulfide by applying a dry process is provided. A method for producing an aqueous solution of perrhenic acid includes 1) a step for roasting rhenium sulfide under an oxygen-containing gas to collect gasified rhenium oxide; 2) a step for cooling and solidifying the gasified rhenium oxide while keeping sulfur oxide entrained in the gasified rhenium oxide a gaseous state, and subsequently performing solid-gas separation, thereby improving purity of rhenium oxide; and 3) a step for dissolving the solidified rhenium oxide into water, or heating and gasifying the solidified rhenium oxide and then dissolving the gasified rhenium oxide into water, to obtain the aqueous solution of perrhenic acid.
Abstract: A method for producing a nanoparticle to separate a diketopyrrolopyrrole pigment includes separating an ?-type diketopyrrolopyrrole pigment nanoparticle having high crystallinity by carrying out separation of the diketopyrrolopyrrole pigment and crystal type transformation to the ?-type with substantially a single step. The ?-type diketopyrrolopyrrole pigment nanoparticle is separated by mixing a diketopyrrolopyrrole pigment solution having the diketopyrrolopyrrole pigment dissolved in a solvent and an alcohol solvent containing an alcohol compound solvent in a thin film fluid formed between at least two processing surfaces 1 and 2 arranged to be opposite to each other so as to be able to approach to and separate from each other, at least one of which rotates relative to the other. An acidic substance is contained in at least any one of the diketopyrrolopyrrole pigment solution and the alcohol solvent at this moment.
Abstract: An electrode material obtained using a polyol process and a synthesis method is provided. The synthesis method includes steps of preparing a mixed solution by mixing a transition metal compound, a polyacid anionic compound and a lithium compound with a polyol solvent; and obtaining a resultant product by reacting the mixed solution in a heating apparatus. There is an advantage in that the electrode material, which has crystallinity due to a structure such as an olivine structure or a nasicon structure, can be synthesized using a polyol process at a low temperature without performing a heat treatment proces. The nanoelectrode material synthesized by the method has a high crystallinity, uniform particles, and a structure having a diameter ranging from several nanometers to several micrometers. Further, the electrode material has a high electrochemical stability.
Type:
Grant
Filed:
September 23, 2006
Date of Patent:
April 21, 2015
Assignee:
Industry Foundation of Chonnam National University
Inventors:
Jae Kook Kim, Dong Han Kim, Tae Ryang Kim
Abstract: Provided are a composite including a lithium titanium oxide and a bismuth titanium oxide, a method of manufacturing the composite, an anode active material including the composite, an anode including the anode active material, and a lithium secondary battery having improved cell performance by including the anode.
Type:
Grant
Filed:
March 14, 2012
Date of Patent:
April 21, 2015
Assignee:
Samsung SDI Co., Ltd.
Inventors:
Min-sang Song, Kyu-sung Park, Gue-sung Kim, Young-min Choi
Abstract: The invention provides a process for production of powder of perovskite compound which comprises: the first step for obtaining an aggregate of perovskite compound which comprises at least one A group element selected from the group consisting of Mg, Ca, Sr, Ba and Pb and at least one B group element selected from the group consisting of Ti, Zr, Hf and Sn, and which is represented by the general formula ABO3 wherein A is at least one A group element and B is at least one B group element; and the second step for heating the aggregate of perovskite compound obtained in the first step in a solvent at a temperature in a range from 30° C. to 500° C. whereby disintegrating the aggregate.
Abstract: Perovskite materials of the general formula SrCeO3 and BaCeO3 are provided having improved conductivity while maintaining an original ratio of chemical constituents, by altering the microstructure of the material. A process of making Pervoskite materials is also provided in which wet chemical techniques are used to fabricate nanocrystalline ceramic materials which have improved grain size and allow lower temperature densification than is obtainable with conventional solid-state reaction processing.
Type:
Grant
Filed:
April 7, 2011
Date of Patent:
April 14, 2015
Assignees:
Savannah River Nuclear Solutions, LLC, University of South Carolina
Inventors:
Kyle S. Brinkman, Paul S. Korinko, Elise B. Fox, Frank Chen
Abstract: A method for preparing a layered oxide cathode using a two step calcination procedure, wherein the first step includes pre-calcination utilizing a rotary calciner.
Type:
Grant
Filed:
June 24, 2011
Date of Patent:
March 31, 2015
Assignee:
BASF Corporation
Inventors:
Ivan Petrovic, Anthony Thurston, Stephen Sheargold
Abstract: An all-solid-state lithium ion secondary battery containing a novel garnet-type oxide serving as a solid electrolyte. The garnet-type lithium ion-conducting oxide is one represented by the formula Li5+XLa3(ZrX, A2-X)O12, wherein A is at least one selected from the group consisting of Sc, Ti, V, Y, Nb, Hf, Ta, Al, Si, Ga, Ge, and Sn and X satisfies the inequality 1.4?X<2, or is one obtained by substituting an element having an ionic radius different from that of Zr for Zr sites in an garnet-type lithium ion-conducting oxide represented by the formula Li7La3Zr2O12, wherein the normalized intensity of an X-ray diffraction (XRD) pattern with a diffraction peak, as normalized on the basis of the intensity of a diffraction peak, is 9.2 or more.
Abstract: A coating is described. The coating includes a metal oxide layer, which in turn includes a surface having a water contact angle greater than 90 degrees. A metal-oxide coating composition is also described. The composition includes effective amounts of a first type and a second of metals and an effective amount of oxygen to react with the first type and the second type of metals to produce a first type and a second type of metal oxides, both of which produce a structure that is greater than about 50% (by volume) amorphous.
Type:
Application
Filed:
March 21, 2013
Publication date:
March 19, 2015
Inventors:
Mark Allen George, Ching-Lin Chang, Ravi Prasad
Abstract: The present invention provides a composition for collecting a metal component from a metal component-containing material, the composition containing a compound containing at least one element selected from the group consisting of lanthanoid elements and elements in group 2 of the periodic table, and a compound containing at least one element selected from the group consisting of elements in groups 3, 4, 12, and 13 of the periodic table and transition metal elements in the 4th period of the periodic table. The present invention further provides a method for collecting a metal component using this composition. With the use of the composition of the present invention, a metal component can be easily and efficiently collected from a material containing a highly useful metal component such as noble or rare metal.
Type:
Grant
Filed:
June 21, 2013
Date of Patent:
March 17, 2015
Assignee:
National Institute of Advanced Industrial Science and Technology
Abstract: A composition is described that includes a perovskite of the formula LaMO3, where M is at least one element selected from among iron, aluminum or manganese, in the form of particles dispersed on an alumina or aluminum oxyhydroxide substrate, wherein after calcination at 700° C. for 4 hours, the perovskite is in the form of a pure crystallographic phase, and in that the size of the perovskite particles does not exceed 15 nm. The described composition can be used in the field of catalysis.
Type:
Grant
Filed:
February 25, 2010
Date of Patent:
March 10, 2015
Assignee:
Rhodia Operations
Inventors:
Simon Ifrah, Olivier Larcher, Rui Jorge Coelho Marques, Michael Lallemand, Julien Hernandez
Abstract: A method for manufacturing a nanostructured metal oxide calcinate suitable for biosensor through a procedure of redox reaction is disclosed in this invention. The nanostructured metal oxide calcinate is free of impurities and produced with better electrocatalytic activity and better conductivity. Thus, an electrode of biosensor can be modified via the nanostructured metal oxide calcinate. The method for manufacturing the nanostructured metal oxide calcinate includes: disposing a first metal material and a second metal material into a reaction slot and making the first metal material and the second metal material dissolved within a solvent to form a mixture, wherein the pH value of the mixture ranges between 0 to 7, the mixture performs a redox reaction process for obtaining a metal oxide material; and eventually calcining the metal oxide material for obtaining a nanostructured metal oxide calcinate.
Type:
Application
Filed:
December 11, 2013
Publication date:
February 19, 2015
Applicant:
NATIONAL SUN YAT-SEN UNIVERSITY
Inventors:
Chun-Hu Chen, Cheng-Chi Kuo, Wen-Jie Lan
Abstract: Feed material comprising uniform solution precursor droplets is processed in a uniform melt state using microwave generated plasma. The plasma torch employed is capable of generating laminar gas flows and providing a uniform temperature profile within the plasma. Plasma exhaust products are quenched at high rates to yield amorphous products. Products of this process include spherical, highly porous and amorphous oxide ceramic particles such as magnesia-yttria (MgO—Y2O3). The present invention can also be used to produce amorphous non oxide ceramic particles comprised of Boron, Carbon, and Nitrogen which can be subsequently consolidated into super hard materials.
Abstract: Provided are an oxide tablet for vapor deposition (oxide evaporation material), and a vapor-deposited thin film and a solar cell formed using the same. The tablet comprises a sintered body which contains indium oxide as a main component and cerium and which is subjected to no surface grinding after sintering, in which CompS/CompA=0.9 to 1.1, where the content of cerium in a surface layer to a depth of 5 ?m from a surface of the sintered body is represented by a Ce/In atomic ratio (CompS), and an average value of the content of cerium in the entire sintered body is represented by a Ce/In atomic ratio (CompA).
Abstract: A solid scintillator in an embodiment includes a polycrystal body of an oxide having a garnet structure. In the solid scintillator, a linear transmittance at a wavelength of 680 nm is 10% or more. The oxide constituting the solid scintillator has a composition represented by, for Example, General formula: (Gd1??????Tb?Lu?Ce?)3(Al1?xGax)aOb, wherein 0<??0.55, 0<??0.55, 0.0001???0.1, ?+?+?<1, 0<x<1, 4.8?a?5.2, 11.6?b?12.4.
Type:
Application
Filed:
September 4, 2014
Publication date:
January 22, 2015
Inventors:
Makoto HAYASHI, Yukihiro FUKUTA, Takao SAWA
Abstract: Disclosed is a method of making a pyrochlore comprising, obtaining a solution comprising a solvent and a metal precursor or salt thereof capable of forming a pyrochlore, wherein the metal precursor or salt thereof is dissolved in the solvent, subjecting the solution to a drying step to obtain a non-gelled or non-polymerized pyrochlore precursor material in powdered form, and subjecting the pyrochlore precursor material to a calcination step to obtain a pyrochlore.
Abstract: The present invention addresses the problem of providing producing processes for garnet precursor microparticles (a precursor for microparticles of garnet structure) and microparticles of garnet structure. One of the processing processes comprises mixing ions of at least two elements with a basic substances that contain the at least two elements. The thin-film fluid is formed between at least two processing surfaces which are approachably and separably arranged facing each other with at least one of the processing surfaces rotating relative to the other. In the processing process, the precipitated microparticles are garnet precursor microparticles, and the molar ratio between the at least two elements in the garnet precursor microparticles is regulated by controlling the pH of the thin-film fluid after the mixing. Microparticles of garnet structure can be obtained by subjecting the garnet precursor microparticles to heat treatment.
Abstract: Disclosed are a silicon-containing cerium composite oxide which is capable of maintaining a large specific surface area even used in a high temperature environment, and which has excellent heat resistance and reducibility, as well as a method for producing the composite oxide and a catalyst for exhaust gas purification employing the composite oxide. The composite oxide contains 2 to 20 mass % silicon in terms of SiO2, has properties of exhibiting a specific surface area of not less than 40 m2/g as measured by the BET method after calcination at 1000° C. for 5 hours, and a reducibility of not lower than 30% as calculated from measurement of temperature-programmed reduction from 50° C. to 900° C. after calcination at 1000° C. for 5 hours, and is suitable for a co-catalyst for a catalyst for exhaust gas purification.
Abstract: A method for the rapid and continuous production of crystalline mixed-metal oxides from a precursor solution comprised of a polymerizing agent, chelated metal ions, and a solvent. The method discharges solution droplets of less than 500 ?m diameter using an atomizing or spray-type process into a reactor having multiple temperature zones. Rapid evaporation occurs in a first zone, followed by mixed-metal organic foam formation in a second zone, followed by amorphous and partially crystalline oxide precursor formation in a third zone, followed by formation of the substantially crystalline mixed-metal oxide in a fourth zone. The method operates in a continuous rather than batch manner and the use of small droplets as the starting material for the temperature-based process allows relatively high temperature processing. In a particular embodiment, the first zone operates at 100-300° C., the second zone operates at 300-700° C., and the third operates at 700-1000° C., and fourth zone operates at at least 700° C.
Type:
Application
Filed:
June 5, 2014
Publication date:
December 11, 2014
Inventors:
David A. Berry, Daniel J. Haynes, Dushyant Shekhawat, Mark W. Smith
Abstract: [Problem] The present invention relates to: a heat ray shielding adhesive which is used in bonding to a windowpane and the like and shields neat rays; a heat ray shielding transparent adhesive sheet; and a method for producing the heat ray shielding adhesive. The present invention provides a heat ray shielding transparent adhesive sheet which has nigh transmittance in the visible light region, low haze and more excellent transparency. [Solution] Transparency and heat ray shielding properties can be imparted in a simpler manner by using a heat ray shielding adhesive composition which contains fine heat ray shielding particles that have a half-value width of the first main peak of from. 0.01° to 0.80° (inclusive) as determined by X-ray diffraction pattern, and a heat ray shielding transparent adhesive sheet is therefore able to be produced at low cost.
Abstract: A system and method thereof are provided for multi-stage processing of one more precursor compounds into a battery material. The system includes a mist generator, a drying chamber, one or more gas-solid separators, and one or more in-line reaction modules comprised of one or more gas-solid feeders, one or more gas-solid separators, and one or more reactors. Various gas-solid mixtures are formed within the internal plenums of the drying chamber, the gas-solid feeders, and the reactors. In addition, heated air or gas is served as the energy source within the processing system and as the gas source for forming the gas-solid mixtures to facilitate reaction rate and uniformity of the reactions therein. Precursor compounds are continuously delivered into the processing system and processed in-line through the internal plenums of the drying chamber and the reaction modules into final reaction particles useful as a battery material.