Group Ib Metal (cu, Ag, Or Au) Patents (Class 423/604)
  • Publication number: 20090298699
    Abstract: The invention offers a production method of a material powder of an oxide superconductor. The production method is provided with both a step of producing a dry powder by removing solvent from a solution containing elements for constituting the oxide superconductor and a step of producing oxides of the elements for constituting the oxide superconductor by scattering the dry powder in a high-temperature furnace. Provided with the above steps, the production method not only can achieve the uniform presence of the elements for constituting the oxide superconductor but also enables the mass production of the material powder.
    Type: Application
    Filed: March 13, 2008
    Publication date: December 3, 2009
    Applicant: SUMITOMO ELECTRIC INDUSTRIES ,LTD.
    Inventor: Naoki Ayai
  • Patent number: 7618561
    Abstract: The present invention is to manufacture the organic silver solution by dissolving silver oxide in an organic solvent, and further provide an ink enabling a conductive circuit to be formed by applying it to an inkjet printer. Also, it is to provide a method for forming a conductive circuit on various substrates by printing it through the inkjet printer using the manufactured ink and further heat-treating it. The organic silver solution, a composition according to the present invention, can be manufactured by dissolving silver oxide in an amine-based compound and a lactone-based compound (or a lactam-based compound, a carbonate-based compound, a cyclic acid anhydride-based compound) by reacting the former an the latter, and in order to ensure the appropriate liquid fluidity for the inkjet printer, the ink was manufactured by adding an organic solvent, such as alcohol, a surfactant and the like thereto.
    Type: Grant
    Filed: March 26, 2004
    Date of Patent: November 17, 2009
    Assignee: Haeun Chemtec Co. Ltd.
    Inventors: Kwang Choon Chung, Myoung Seon Gong, Jae Joon Shim
  • Publication number: 20090202427
    Abstract: Process for preparing mixed metal oxide powders Abstract Process for preparing a mixed metal oxide powder, in which oxidizable starting materials are evaporated in an evaporation zone of a reactor and oxidized in the vaporous state in an oxidation zone of this reactor, the reaction mixture is cooled after the reaction and the pulverulent solids are removed from gaseous substances, wherein at least one pulverulent metal, together with one or more combustion gases, is fed to the evaporation zone, the metal is evaporated completely in the evaporation zone under nonoxidizing conditions, an oxygen-containing gas and at least one metal compound are fed, separately or together, in the oxidation zone to the mixture flowing out of the evaporation zone, the oxygen content of the oxygen-containing gas being at least sufficient to oxidize the metal, the metal compound and the combustion gas completely.
    Type: Application
    Filed: May 16, 2007
    Publication date: August 13, 2009
    Applicant: EVONIK DEGUSSA GMBH
    Inventors: Stipan Katusic, Guido Zimmermann, Michael Krämer, Horst Miess, Edwin Staab
  • Patent number: 7566436
    Abstract: A mixing reactor for mixing efficiently streams of fluids of differing densities. In a preferred embodiment, one of the fluids is supercritical water, and the other is an aqueous salt solution. Thus, the reactor enables the production of metal oxide nanoparticles as a continuous process, without any risk of the reactor blocking due to the inefficient mixing inherent in existing reactor designs.
    Type: Grant
    Filed: February 11, 2005
    Date of Patent: July 28, 2009
    Assignee: The University of Nottingham
    Inventors: Edward Henry Lester, Barry James Azzopardi
  • Patent number: 7566437
    Abstract: The present invention relates to a method for manufacture of silver-based composite powders for electrical contact materials. The invention relates also to electrical contact materials made from such composite powders. The process comprises a high energy dispersing process of wet silver oxide (Ag2O) with additional second oxide components in aqueous suspension. The high energy dispersing process can be conducted by high shear mixing or by high energy milling. Preferably high speed dispersing units working at rotating speeds in the range of 5,000 to 30,000 rpm or high energy mills such as attritor mills are used. The new process is versatile, economical and offers access to a broad spectrum of contact materials. The silver-based composite powders made according to the new process yield contact materials with a highly dispersed microstructures and superior material characteristics.
    Type: Grant
    Filed: March 31, 2006
    Date of Patent: July 28, 2009
    Assignee: Umicore AG & Co. KG
    Inventors: Dan Goia, Bernd Kempf, Inge Fallheier, Roger Wolmer, Andreas Koffler
  • Patent number: 7547431
    Abstract: A method of producing high purity nanoscale powders in which the purity of powders produced by the method exceeds 99.99%. Fine powders produced are of size preferably less than 1 micron, and more preferably less than 100 nanometers. Methods for producing such powders in high volume, low-cost, and reproducible quality are also outlined. The fine powders are envisioned to be useful in various applications such as biomedical, sensor, electronic, electrical, photonic, thermal, piezo, magnetic, catalytic and electrochemical products.
    Type: Grant
    Filed: December 10, 2002
    Date of Patent: June 16, 2009
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Tapesh Yadav, Karl Pfaffenbach
  • Publication number: 20090142411
    Abstract: A device or composition comprising an agent for the coagulation of protein-containing fluids, wherein the agent comprises an inorganic component which is soluble in protein-containing fluids. Use of such a device or composition for the coagulation of protein-containing fluids. A coagulum of protein-containing fluid produced using such a device or composition.
    Type: Application
    Filed: January 17, 2006
    Publication date: June 4, 2009
    Applicant: SMITH & NEPHEW, PLC
    Inventors: Joanna Buckley, Bryan Greener, Emma Woodmansey
  • Publication number: 20090123354
    Abstract: A solid material is presented for the partial oxidation of natural gas. The solid material includes a solid oxygen carrying agent and a hydrocarbon activation agent. The material precludes the need for gaseous oxygen for the partial oxidation and provides better control over the reaction.
    Type: Application
    Filed: November 14, 2007
    Publication date: May 14, 2009
    Inventors: Deng-Yang Jan, Joel T. Walenga, Kurt M. Vanden Bussche, Joseph A. Kocal, Lisa M. King
  • Publication number: 20090068089
    Abstract: We disclose a method of manufacture of silver oxide nano metal particles of 2-10 mm size with specific phase and geometry in their exterior and interior making them suitable for use as potent antimicrobial and styptic agents.
    Type: Application
    Filed: September 8, 2007
    Publication date: March 12, 2009
    Applicant: Quaid-e-Azam University
    Inventors: Syed Tajammul Hussain, Mohammed Mazhar
  • Patent number: 7488464
    Abstract: Methods and systems for processing metal oxides from metal containing solutions. Metal containing solutions are mixed with heated aqueous oxidizing solutions and processed in a continuous process reactor or batch processing system. Combinations of temperature, pressure, molarity, Eh value, and pH value of the mixed solution are monitored and adjusted so as to maintain solution conditions within a desired stability area during processing. This results in metal oxides having high or increased pollutant loading capacities and/or oxidation states. These metal oxides may be processed according to the invention to produce co-precipitated oxides of two or more metals, metal oxides incorporating foreign cations, metal oxides precipitated on active and inactive substrates, or combinations of any or all of these forms.
    Type: Grant
    Filed: July 28, 2004
    Date of Patent: February 10, 2009
    Assignee: EnviroScrub Technologies Corporation
    Inventors: Charles F. Hammel, Richard M. Boren
  • Publication number: 20090033200
    Abstract: The invention relates to a barrier layer provided on the electrode assembly of a discharge lamp comprising at least a layer of nanoclusters of a non-oxidizing material. Further, the invention relates to an electrode assembly for a discharge lamp comprising an electrode having a foil attached thereto to create an electrode assembly, the assembly being coated with a multi-layer coating comprising at least a layer of non-oxidizing material in the form of nanoclusters, and at least another layer of non-oxidizing material, such that the total coating thickness is up to 1500 nm.
    Type: Application
    Filed: August 1, 2007
    Publication date: February 5, 2009
    Inventor: Deeder M. Aurongzeb
  • Patent number: 7482382
    Abstract: The present invention is directed to novel sol-gel methods in which metal oxide precursor and an alcohol-based solution are mixed to form a reaction mixture that is then allowed to react to produce nanosized metal oxide particles. The methods of the present invention are more suitable for preparing nanosized metal oxide than are previously-described sol-gel methods. The present invention can provide for nanosized metal oxide particles more efficiently than the previously-described sol-gel methods by permitting higher concentrations of metal oxide precursor to be employed in the reaction mixture. The foregoing is provided by careful control of the pH conditions during synthesis and by ensuring that the pH is maintained at a value of about 7 or higher.
    Type: Grant
    Filed: May 19, 2004
    Date of Patent: January 27, 2009
    Assignees: The Texas A&M University System, Kaneka Corporation
    Inventors: Yuntao Li, Hung-Jue Sue, Riichi Nishimura, Nobuo Miyatake
  • Publication number: 20080311031
    Abstract: The invention provides a method for the formation of small-size metal oxide particles, comprising the steps of a) preparing a starting aqueous solution comprising at least one of metallic ions and complexes thereof, at a concentration of at least 0.1 % w/w of the metal component; b) maintaining the solution at a temperature lower than 50° C. for a retention time in which hydrolysis takes place, the extent of the hydrolysis being sufficient to produce O.1 mmol protons per mmol of metal present in solution, wherein the time does not exceed 14 days, to form a system containing a retained solution; and c) adjusting the conditions in the system by at least one of the steps of: i) heating the retained solution to elevate the temperature thereof by at least 1° C.; ii) changing the pH of the retained solution by at least 0.1 units; and iii) diluting the retained solution by at least 20% whereby there are formed particles, wherein the majority of the particles formed are between about 2 nm and about 500 nm in size.
    Type: Application
    Filed: December 21, 2006
    Publication date: December 18, 2008
    Applicant: JOMA INTERNATIONAL AS
    Inventors: Asher Vitner, Aharon Eyal
  • Publication number: 20080305025
    Abstract: The invention provides a method for the formation of small-size metal oxide particles, comprising the steps of: a) preparing a starting aqueous solution comprising at least one of metallic ion and complexes thereof, at a concentration of at least 0.1% w/w of the metal component; b) preparing a modifying aqueous solution having a temperature greater than 50° C.; c) contacting the modifying aqueous solution with the starting aqueous solution in a continuous mode in a mixing chamber to form a-modified system; d) removing the modified system from the mixing chamber in a plug-flow mode; wherein the method is characterized in that: i) the residence time in the mixing chamber is less than about 5 minutes; and iii) there are formed particles or aggregates thereof, wherein the majority of the particles formed are between about 2 nm and about 500 nm in size.
    Type: Application
    Filed: December 21, 2006
    Publication date: December 11, 2008
    Applicant: Joma International AS
    Inventors: Asher Vitner, Aharon Eyal
  • Patent number: 7455823
    Abstract: The invention discloses methods for making micron/nano meter sized particles of various inorganic materials such as minerals/oxides/sulphides/metals/ceramics at a steadily expanding liquid-liquid interface populated by suitable surfactant molecules that spontaneously organize themselves into superstructures varying over large length-scales. This experiment is realized in a radial Hele-Shaw cell where the liquid-liquid interfacial growth rate and consequently time scales such as arrival of surfactant molecules to the interface, the hydrodynamic flow effect to modulate the material organization into super structures at the dynamic charged interface.
    Type: Grant
    Filed: February 23, 2006
    Date of Patent: November 25, 2008
    Assignee: Council of Scientific & Industrial Research
    Inventors: Sastry Murali, Rautaray Debabrata
  • Publication number: 20080267852
    Abstract: Process for preparing pulverulent solids, in which one or more oxidizable and/or hydrolysable metal compounds are reacted in a high-temperature zone in the presence of oxygen and/or steam, the reaction mixture is cooled after the reaction, and the pulverulent solid is removed from gaseous substances, wherein at least one metal compound is introduced into the high-temperature zone in solid form and the evaporation temperature of the metal compound is below the temperature of the high-temperature zone.
    Type: Application
    Filed: November 29, 2006
    Publication date: October 30, 2008
    Applicant: EVONIK DEGUSSA GmbH
    Inventors: Kai Schumacher, Stefan Fiedler, Roland Schilling, Ronald Ihmig, Stipan Katusic
  • Publication number: 20080260612
    Abstract: Multi-step metal compound oxidation process to produce compounds and enhanced metal oxides from various source materials, e.g. metal sulfides, carbides, nitrides and other metal containing materials with metal oxides from secondary reaction steps being utilized as an oxidation agent in the first reactions.
    Type: Application
    Filed: April 18, 2008
    Publication date: October 23, 2008
    Applicant: Orchard Material Technology, LLC
    Inventor: Lawrence F. McHugh
  • Publication number: 20080233030
    Abstract: Process for manufacturing an electrochemical device including a cathode, an anode and at least one electrolyte membrane disposed between the anode and the cathode, wherein at least one of the cathode, the anode and the electrolyte membrane, contains at least a ceramic material.
    Type: Application
    Filed: March 30, 2004
    Publication date: September 25, 2008
    Applicant: PIRELLI & C.S.P.A.
    Inventors: Agustin Sin Xicola, A. Yuri Dubitsky, Enrico Albizzati, Evgeny Kopnin, Elena Roda
  • Publication number: 20080218940
    Abstract: Methods of producing polycrystalline and single crystal dielectrics are disclosed, including dielectrics comprising CaCu3Ti4O12 or La3Ga5SiO4. Superior single crystals are manufactured with improved crystallinity by atomic lattice constant adjustments to the dielectric and to the substrate on which it is grown. Dielectric materials made according to the disclosed methods are useful for manufacture of energy storage devices, e.g. capacitors.
    Type: Application
    Filed: March 5, 2007
    Publication date: September 11, 2008
    Applicant: Northrop Grumman Systems Corporation
    Inventors: Narsingh B. Singh, John J. Talvacchio, Marc Sherwin, Andre Berghmans, David J. Knuteson, David Kahler, Brian Wagner, John D. Adam
  • Publication number: 20080206124
    Abstract: Disclosed is a method of exfoliating a layered material (e.g., graphite and graphite oxide) to produce nano-scaled platelets having a thickness smaller than 100 nm, typically smaller than 10 nm, and often between 0.34 nm and 1.02 nm. The method comprises: (a) subjecting the layered material in a powder form to a halogen vapor at a first temperature above the melting point or sublimation point of the halogen at a sufficient vapor pressure and for a duration of time sufficient to cause the halogen molecules to penetrate an interlayer space of the layered material, forming a stable halogen-intercalated compound; and (b) heating the halogen-intercalated compound at a second temperature above the boiling point of the halogen, allowing halogen atoms or molecules residing in the interlayer space to exfoliate the layered material to produce the platelets.
    Type: Application
    Filed: February 22, 2007
    Publication date: August 28, 2008
    Inventors: Bor Z. Jang, Aruna Zhamu
  • Publication number: 20080193760
    Abstract: Disclosed is a method of manufacturing a metal oxide nano powder comprising preparing a first dispersed solution by adding a nano-sized metal powder to water and dispersing the metal powder within the water, performing a hydration reaction of the first dispersed solution at a temperature of about 30 to about 70° C. to generate a precipitation, and filtering and drying the precipitation to prepare a metal oxide powder. Also, disclosed is a metal oxide nano powder manufactured by the method described above, and having any one of a bar-form, a cube-form, and a fiber-form.
    Type: Application
    Filed: November 6, 2007
    Publication date: August 14, 2008
    Inventors: Chang Kyu Rhee, Min Ku Lee, Young Rang Uhm, Jin Ju Park, Byung Sun Han, Hi Min Lee, Seung-Hee Woo
  • Patent number: 7402296
    Abstract: Disclosed is a method of stabilizing copper(II) hydroxide, the method comprising the sequential steps of: (a) combining copper(II) hydroxide, a water-soluble phosphate and water to form a mixture; and (b) drying the mixture. Also disclosed is stabilized copper(II) hydroxide prepared according to said method and a composition comprising stabilized copper(II) hydroxide prepared according to said method and at least one of a surfactant, a solid diluent or a liquid diluent.
    Type: Grant
    Filed: August 30, 2005
    Date of Patent: July 22, 2008
    Assignee: E.I. du Pont de Nemours and Company
    Inventor: Matthew Richard Oberholzer
  • Publication number: 20080138707
    Abstract: The current invention relates to the preparation of an improved cathode active material for non-aqueous lithium electrochemical cell. In particular, the cathode active material comprised ?-phase silver vanadium oxide prepared by using silver- and vanadium-containing starting materials in a stoichiometric molar proportion to give a Ag:V ratio of about 1:2. The reactants are homogenized and then added to an aqueous solution followed by heating in a pressurized vessel. The resulting ?-phase SVO possesses a higher surface area than ?-phase SVO produced by other prior art techniques. Consequently, the ?-phase SVO material provides an advantage in greater discharge capacity in pulse dischargeable cells.
    Type: Application
    Filed: July 19, 2004
    Publication date: June 12, 2008
    Inventors: Esther S. Takeuchi, Veronica Lamothe, Randolph Leising
  • Publication number: 20080121584
    Abstract: Methods of making unique water treatment compositions are provided. In one embodiment, a method of making a doped metal oxide or hydroxide for treating water comprises: disposing a metal precursor solution and a dopant precursor solution in a reaction vessel comprising water to form a slurry; and precipitating the doped metal oxide or hydroxide from the slurry.
    Type: Application
    Filed: June 14, 2007
    Publication date: May 29, 2008
    Applicants: INFRAMAT CORPORATION, UNIVERSITY OF HOUSTON
    Inventors: Huimin Chen, Dennis A. Clifford
  • Patent number: 7357910
    Abstract: Method for producing metal oxide nanoparticles. The method includes generating an aerosol of solid metallic microparticles, generating plasma with a plasma hot zone at a temperature sufficiently high to vaporize the microparticles into metal vapor, and directing the aerosol into the hot zone of the plasma. The microparticles vaporize in the hot zone into metal vapor. The metal vapor is directed away from the hot zone and into the cooler plasma afterglow where it oxidizes, cools and condenses to form solid metal oxide nanoparticles.
    Type: Grant
    Filed: July 15, 2002
    Date of Patent: April 15, 2008
    Assignee: Los Alamos National Security, LLC
    Inventors: Jonathan Phillips, Daniel Mendoza, Chun-Ku Chen
  • Patent number: 7297321
    Abstract: A new class of supermicroporous mixed oxides, with pore sizes in the 10-20 ? range has been prepared utilizing basic metal acetates. The reactions are carried out in non-aqueous solvent media to which an excess of amine is added. Hydrolysis of the reagents is effected by addition of a water-propanol mixture and refluxing. The amine and solvent are removed by thorough washing and/or calcining at temperatures as low as 200° C. Mixtures of transition metal oxides with either ZrO2, TiO2, La2O3, SiO2, Al2O3 or mixtures thereof were prepared. The surface area curves of the pure oxides are Type I with surface areas of 400-600 m2/g and up to 1100 m2/g for the mixed oxides.
    Type: Grant
    Filed: January 11, 2005
    Date of Patent: November 20, 2007
    Assignee: The Texas A&M University System
    Inventors: Boris G. Shpeizer, Abraham Clearfield
  • Patent number: 7276224
    Abstract: Methods of producing nanoporous particles by spray pyrolysis of a precursor composition including a reactive precursor salt and a nonreactive matrix salt are provided, wherein the matrix salt is used as a templating medium. Nanoporous aluminum oxide particles produced by the methods are also provided.
    Type: Grant
    Filed: June 11, 2002
    Date of Patent: October 2, 2007
    Assignee: Regents of the University of Minnesota
    Inventors: Michael R. Zachariah, Benjamin Y. H. Liu
  • Patent number: 7235224
    Abstract: Disclosed is a process for preparing fine metal oxide particles, comprising the following steps of reacting a reactant mixture comprising i) water, ii) at least one water-soluble metal nitrate and iii) ammonia or ammonium salt at 250–700° C. under 180–550 bar for 0.01 sec to 10 min in a reaction zone to synthesize the metal oxide particles, the metal nitrate being contained at an amount of 0.01–20 wt % in the reactant mixture; and separating and recovering the metal oxide particles from the resulting reaction products. According to the present invention, nano-sized metal oxide particles are synthesized, while the harmful by-products generated concurrently therewith are effectively decomposed in the same reactor.
    Type: Grant
    Filed: July 8, 2003
    Date of Patent: June 26, 2007
    Assignee: Han-Wha Chemical Corporation
    Inventors: Wan-Jae Myeong, Jin-Soo Baik, Se-Woong Park, Chang-Mo Chung, Kyu-Ho Song
  • Patent number: 7226573
    Abstract: A silver oxide powder that replaces silver powder as a silver conductive paste filler has a specific surface area measured by the BET method is 1.0–25.0 m2/g, average primary particle diameter is 1–50 nm, and average secondary particle diameter is 1–1000 nm. The silver oxide powder is made by preparing a neutralization medium that is an aqueous solution containing one or both of sodium hydroxide and potassium hydroxide in a total amount of 0.5 mole/L or less, simultaneously adding an aqueous solution containing silver salt in an amount of 6.0 mole/L or less and an aqueous solution of at least one of sodium hydroxide and potassium hydroxide to the liquid medium to conduct a neutralization reaction, thereby obtaining a neutralized precipitate, maintaining the liquid at a pH in the range of 12±1.5 during the reaction, and subjecting the precipitate to filtration, washing, and drying.
    Type: Grant
    Filed: September 9, 2004
    Date of Patent: June 5, 2007
    Assignee: Dowa Mining Co., Ltd.
    Inventors: Kenichi Harigae, Yoshiyuki Shoji
  • Patent number: 7223377
    Abstract: The present invention is the method for preparation of transition metal oxide having micro-mesoporous structure whose average fine pores size is not less than 1 nm and not more than 2 nm comprising, adding and dissolving transition metal salt which is a precursor of transition metal oxide and/or metal alkoxide in the solution prepared by dissolving polymer surfactant in organic solvent, hydrolyzing said transition metal salt and/or metal alkoxide and preparing sol solution which is polymerized and self organized, then obtaining gel whose organization is stabilized from said sol solution and removing said polymer surfactant by using water of room temperature or water to which alkali metal or alkaline earth metal ion is added.
    Type: Grant
    Filed: October 2, 2002
    Date of Patent: May 29, 2007
    Assignee: Japan Science and Technology Agency
    Inventors: Kazunari Domen, Junko Nomura, Byonjin Ri
  • Patent number: 7201888
    Abstract: The present invention provides silver oxide particles having an average diameter of less than or equal to 100 nm that are stable and can be transported in dry powder form. The surface of the silver oxide particles is coated with an extremely thin layer of a surfactant such as fatty acid. Nanosized silver oxide particles according to the invention are preferably formed via the addition of a strong base to a mixture including an aqueous silver salt solution and a surfactant dissolved in an organic solvent that is at least partially water miscible. The strong base causes silver oxide to precipitate from the mixture as nanosized particles, which are immediately encapsulated by the surfactant and thus protected from further crystal growth and Ostwald ripening. The nanosized surfactant coated particles of silver oxide can be washed and dried and then transported in dry form.
    Type: Grant
    Filed: October 7, 2003
    Date of Patent: April 10, 2007
    Assignee: Ferro Corporation
    Inventors: Gregory M. Berube, Gargi Banerjee
  • Patent number: 7163667
    Abstract: A production process for an oxide magnetic material comprising the steps of blending raw material powder so as to take the composition of a hexagonal ferrite including: at least one kind of an element A selected from the group consisting of Ba, Sr and Ca; Co and Cu; Fe; and O; and sintering said blended powder at a temperature lower than 1000° C.
    Type: Grant
    Filed: January 17, 2003
    Date of Patent: January 16, 2007
    Assignee: Sanyo Electric Co., Ltd.
    Inventors: Takashi Umemoto, Hideki Yoshikawa, Keiichi Kuramoto, Hitoshi Hirano
  • Patent number: 7135161
    Abstract: A method of forming metal oxide powders includes the steps of solid state mixing of at least one metal nitrate salt, such as Fe(NO3)3 or a combination of metal nitrate salts such as Zn(NO3)3,6H2O and Ga(NO3)3, xH2O, and at least one reducing organic acid, such as tartaric or citric acid. The mixture is heated to form a metal oxide powder, such as alpha-iron oxide (?-Fe2O3) or a mixed metal powder such as zinc gallate phosphor (ZnGa2O4). A metal oxide precursor intermediate can be formed and then heated to form the metal oxide powder.
    Type: Grant
    Filed: September 4, 2003
    Date of Patent: November 14, 2006
    Assignee: University of Florida Research Foundation, Inc.
    Inventors: Paul H. Holloway, Mostafa Abboudi
  • Patent number: 7122167
    Abstract: A supercritical oxidation process carried out in water is capable of oxidizing “organics” in precious metal organic compositions such as heterogeneous (Pt/C) or homogeneous precious metal catalysts and producing a precious metal oxide with few by-products and low losses of precious metal.
    Type: Grant
    Filed: April 10, 2001
    Date of Patent: October 17, 2006
    Assignees: Johnson Matthey Public Limited Company, Chematur Engineering AB
    Inventors: Simon Collard, Anders Gidner, Brian Harrison, Lars Stenmark
  • Patent number: 7118727
    Abstract: The present invention provides a process for producing particles, such as oxide nanoparticles, in a substantially water-free environment. The process involves mixing at least one metal compound of the formula MX(m?n) with at least one surfactant and at least one solvent, wherein M is an electropositive element of Groups 1–15; each X is independently selected from the group consisting of O1/2, F, Cl, Br, I, OR, O2CR, NR2, and R; each R is independently a hydrocarbyl group; n is equal to ½ the oxidation state of the metal M in the product particle; and m is equal to the oxidation state of the element M. The components are typically combined to form a mixture which is thermally treated for a time period sufficient to convert the metal compound into particles of the corresponding oxide, having sizes in a range between about 0.5 nanometer and about 1000 nanometers.
    Type: Grant
    Filed: June 16, 2003
    Date of Patent: October 10, 2006
    Assignee: General Electric Company
    Inventor: Darryl Stephen Williams
  • Patent number: 7105136
    Abstract: In a method for preparing copper salts from at least one cupriferous and one additional reactant, the reactants are used to prepare micro-emulsions while employing at least one block polymer, the intermediate products obtained this way are mixed and reacted together so as to form a micro-emulsion. The preparation of the starting micro-emulsion as well as the subsequent joint reaction preferably occur either with ultrasound or in a high-pressure homogenizer. The copper salts obtained this way exhibit a particle size of less than 50 nm, preferably 5 to 20 nm and can be adjusted to specific applications through the appropriate doping of foreign ions.
    Type: Grant
    Filed: September 27, 2002
    Date of Patent: September 12, 2006
    Assignee: Spiess-Urania Chemicals GmbH
    Inventors: Hartmut Ploss, Gerhard Goebel, André Simon
  • Patent number: 7094301
    Abstract: A method of joining at least two sintered bodies to form a composite structure, including providing a first multicomponent metallic oxide having a perovskitic or fluorite crystal structure; providing a second sintered body including a second multicomponent metallic oxide having a crystal structure of the same type as the first; and providing at an interface a joint material containing at least one metal oxide containing at least one metal identically contained in at least one of the first and second multicomponent metallic oxides. The joint material is free of cations of Si, Ge, Sn, Pb, P and Te and has a melting point below the sintering temperatures of both sintered bodies. The joint material is heated to a temperature above the melting point of the metal oxide(s) and below the sintering temperatures of the sintered bodies to form the joint. Structures containing such joints are also disclosed.
    Type: Grant
    Filed: March 21, 2003
    Date of Patent: August 22, 2006
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Darryl Paul Butt, Raymond Ashton Cutler, Steven Walton Rynders, Michael Francis Carolan
  • Patent number: 7087100
    Abstract: The present invention is a process for producing nanosized metal compounds. The preferred product is nanosized copper, nanosized copper (I) oxide, and nanosized copper (II) oxide. The process includes heating a copper metal precursor in a hydrocarbon preferably selected from alkylated benzenes, polyaromatic hydrocarbons, paraffins and/or naphthenic hydrocarbons. The heating is desirably at a temperature and time effective to convert, for example, the copper metal precursor to nanosized copper (II) oxide, nanosized copper (I) oxide and/or nanosized copper metal. Separation of the hydrocarbon is then performed. Recovering the solid product and recycle/reuse of the recovered hydrocarbon in subsequent preparations of nanosized metal and metal oxides may be performed. The nanosized metal oxides of the invention may additionally be converted to nanosized metal salts by reaction with the appropriate acids while dispersed in the hydrocarbons.
    Type: Grant
    Filed: October 9, 2001
    Date of Patent: August 8, 2006
    Assignee: General Electric Company
    Inventors: Kenrick M. Lewis, Hua Yu, Regina Nelson Eng, Sabrina R. Cromer, Chi-Lin O'Young, Abellard T. Mereigh
  • Patent number: 7081234
    Abstract: A process of treating metal oxide nanoparticles that includes mixing metal oxide nanoparticles, a solvent, and a surface treatment agent that is preferably a silane or siloxane is described. The treated metal oxide nanoparticles are rendered hydrophobic by the surface treatment agent being surface attached thereto, and are preferably dispersed in a hydrophobic aromatic polymer binder of a charge transport layer of a photoreceptor, whereby ?—? interactions can be formed between the organic moieties on the surface of the nanoparticles and the aromatic components of the binder polymer to achieve a stable dispersion of the nanoparticles in the polymer that is substantially free of large sized agglomerations.
    Type: Grant
    Filed: April 5, 2004
    Date of Patent: July 25, 2006
    Assignee: Xerox Corporation
    Inventors: Yu Qi, Nan-Xing Hu, Ah-Mee Hor, Cheng-Kuo Hsiao, Yvan Gagnon, John F. Graham
  • Patent number: 7011898
    Abstract: A method of forming a composite structure includes: (1) providing first and second sintered bodies containing first and second multicomponent metallic oxides having first and second identical crystal structures that are perovskitic or fluoritic; (2) providing a joint material containing at least one metal oxide: (a) containing (i) at least one metal of an identical IUPAC Group as at least one sintered body metal in one of the multicomponent metallic oxides, (ii) a first row D-Block transition metal not contained in the multicomponent metallic oxides, and/or (iii) a lanthanide not contained in the multicomponent metallic oxides; (b) free of metals contained in the multicomponent metallic oxides; (c) free of cations of boron, silicon, germanium, tin, lead, arsenic, antimony, phosphorus and tellurium; and (d) having a melting point below the sintering temperatures of the sintered bodies; and (3) heating to a joining temperature above the melting point and below the sintering temperatures.
    Type: Grant
    Filed: March 21, 2003
    Date of Patent: March 14, 2006
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Darryl Paul Butt, Raymond Ashton Cutler, Steven Walton Rynders, Michael Francis Carolan
  • Patent number: 6984369
    Abstract: Disclosed is a process for making surfactant capped nanocrystals of metal oxides which are dispersable in organic solvents. The process comprises decomposing a metal cupferron complex of the formula MXCupX, wherein M is a metal, and Cup is a N-substituted N-Nitroso hydroxylamine, in the presence of a coordinating surfactant, the reaction being conducted at a temperature ranging from about 150 to about 400° C., for a period of time sufficient to complete the reaction. Also disclosed are compounds made by the process.
    Type: Grant
    Filed: November 22, 2000
    Date of Patent: January 10, 2006
    Assignee: The Regents of the University of California
    Inventors: A. Paul Alivisatos, Joerg Rockenberger
  • Patent number: 6951398
    Abstract: The invention relates to a new type of reflective optical element made of a reflective metallic layer comprising reflecting nanoparticles deposited on a liquid surface. Metallic or non-metallic nanometer-sized particles are coated with a ligand. The coated particles are concentrated and deposited on the surface of a liquid where they self-assemble to give optical-quality high-reflectivity optical surfaces. Coating liquid surfaces with reflective layers allows one to make inexpensive and versatile high-quality mirrors. The surfaces of liquids can be shaped by a variety of techniques.
    Type: Grant
    Filed: April 9, 2003
    Date of Patent: October 4, 2005
    Assignee: Université Laval
    Inventors: Ermanno Borra, Anna Ritcey, Hélene Yockel-Lelièvre
  • Patent number: 6926999
    Abstract: A cathode active material for alkaline electrochemical cells comprising an Ag—Bi-M-containing oxidation product produced by oxidizing with an oxidizing agent an Ag—Bi-M-containing neutralized precipitate obtained by reacting inorganic acid salts of silver, bismuth and, optionally, M (M representing at least one metal selected from the group comprised of manganese, nickel and cobalt) with an alkali hydroxide in an aqueous medium; or comprising an Ag—Bi-M-containing oxidation product obtained by reacting inorganic acid salts of silver, bismuth and, optionally, M with an alkali hydroxide in an aqueous medium and in the presence of an oxidizer.
    Type: Grant
    Filed: September 10, 2001
    Date of Patent: August 9, 2005
    Assignee: Dowa Mining Co., Ltd.
    Inventors: Koji Tanoue, Yoshikazu Omoto, Yoshiyuki Shoji, Masayuki Nishina, Toshio Ueda
  • Patent number: 6908600
    Abstract: A method for obtaining pigments for ceramic and glass, particularly for substrates and coatings, including a step of adding a solution of an iron salt to at least one silicon addition agent including silica in gel form.
    Type: Grant
    Filed: November 25, 2002
    Date of Patent: June 21, 2005
    Inventors: Franco Ambri, Filippo Ranuzzi
  • Patent number: 6849798
    Abstract: The present invention relates to the use of a nanocrystalline layer of Cu2O in the construction of photovoltaic cells to increase the ability of the photovoltaic cells to utilize UV radiations for photocurrent generation.
    Type: Grant
    Filed: December 17, 2002
    Date of Patent: February 1, 2005
    Assignee: General Electric Company
    Inventors: Chayan Mitra, Danielle Walker Merfeld, Gunasekaran Somasundaram
  • Patent number: 6849574
    Abstract: A multimetal oxide of the formula I Aga?bMbV2Ox*c H2O,??I where M is a metal selected from the group consisting of Li, Na, K, Rb, Cs, Tl, Mg, Ca, Sr, Ba, Cu, Zn, Cd, Pb, Cr, Au, Al, Fe, Co, Ni and/or Mo, a is from 0.3 to 1.9 and b is from 0 to 0.5, with the proviso that the difference (a?b)?0.1 and c is from 0 to 20 and x is a number determined by the valence and amount of elements different from oxygen in the formula I, has a crystal structure giving an X-ray powder diffraction pattern which displays reflections at the lattice spacings d of 15.23±0.6, 12.16±0.4, 10.68±0.3, 3.41±0.04, 3.09±0.04, 3.02±0.04, 2.36±0.04 and 1.80±0.04 ?. Precatalysts and catalysts produced therefrom for the partial oxidation of aromatic hydrocarbons are also provided.
    Type: Grant
    Filed: November 10, 1999
    Date of Patent: February 1, 2005
    Assignee: BASF Aktiengesellschaft
    Inventors: Thomas Heidemann, Hartmut Hibst, Stefan Bauer, Ulf Dietrich
  • Patent number: 6797017
    Abstract: The current invention relates to the preparation of an improved cathode active material for non-aqueous lithium electrochemical cell. In particular, the cathode active material comprises &egr;-phase silver vanadium oxide prepared by using a &ggr;-phase silver vanadium oxide starting material. The reaction of &ggr;-phase SVO with a silver salt produces the novel &egr;-phase SVO possessing a lower surface area than &egr;-phase SVO produced from vanadium oxide (V2O5) and a similar silver salt as starting materials. Consequently, the low surface area &egr;-phase SVO material provides an advantage in greater long term stability in pulse dischargeable cells.
    Type: Grant
    Filed: December 5, 2001
    Date of Patent: September 28, 2004
    Assignee: Wilson Greatbatch Ltd.
    Inventors: Randolph A. Leising, Esther S. Takeuchi
  • Patent number: 6719924
    Abstract: There is provided a superconducting device including a substrate, a first superconductor layer supported by the substrate and containing Ln, AE, M and O, and a second superconductor layer containing a material represented by a formula of (Yb1−yLn′y)AE′2M′3Oz, the first and second superconductor layers forming a junction, and atomic planes each including M and O in the first superconductor layer and atomic planes each including M′ and O in the second superconductor layer being discontinuous to each other in a position of the junction, wherein each of Ln and Ln′ represents at least one metal of Y and lanthanoids, each of AE and AE′ represents at least one of alkaline earth metals, each of M and M′ represents a metal which contains 80 atomic % or more of Cu, y represents a value between 0 and 0.9, and z represents a value between 6.0 and 8.0.
    Type: Grant
    Filed: October 30, 2001
    Date of Patent: April 13, 2004
    Assignees: Kabushiki Kaisha Toshiba, International Superconductivity Technology Center
    Inventors: Toshihiko Nagano, Jiro Yoshida
  • Patent number: 6596246
    Abstract: Stable copper hydroxide is prepared by removing ferrous ion from the beginning cupric solution. The ferrous ion is oxidized to ferric ion, and the ferric ion is precipitated by raising the pH of the solution to 3-4. The utilization of phosphate ion both increases the efficiency of oxidation and simultaneously precipitates ferric ion. A second raising the pH of the purified solution precipitates highly pure copper hydroxide that can be harvested.
    Type: Grant
    Filed: March 20, 2001
    Date of Patent: July 22, 2003
    Assignee: Dermet SA de CV
    Inventors: Julio Huato, Tetsuya Ogura
  • Publication number: 20030077219
    Abstract: In a method for preparing copper salts from at least one cupriferous and one additional reactant, the reactants are used to prepare micro-emulsions while employing at least one block polymer, the intermediate products obtained this way are mixed and reacted together so as to form a micro-emulsion. The preparation of the starting micro-emulsion as well as the subsequent joint reaction preferably occur either with ultrasound or in a high-pressure homogenizer. The copper salts obtained this way exhibit a particle size of less than 50 nm, preferably 5 to 20 nm and can be adjusted to specific applications through the appropriate doping of foreign ions.
    Type: Application
    Filed: September 27, 2002
    Publication date: April 24, 2003
    Inventors: Hartmut Ploss, Gerhard Goebel, Andre Simon