Abstract: Disclosed is a positive active material for a lithium secondary battery and a preparation method of the same that can improve cycle-life characteristics and storage characteristics at a high temperature by improving structural safety characteristics and electrochemical characteristics, by forming an overlayer comprising an oxide glass phase on the surface of the positive active material, and a lithium secondary battery comprising the positive active material.

Abstract: This invention relates to complex lithium metal oxides, which are cathode active materials of a lithium or lithium ion secondary battery with enhanced cycle life and safety, and a process for preparation thereof. The core particles are complex lithium metal oxides capable of absorbing, storing and emitting lithium ions, and a coating layer comprised of amorphous complex lithium cobalt oxides that are formed on the surface of the core particle, which is structurally stable and inactive with electrolytes. Because the amorphous complex lithium cobalt oxides are inactive with electrolytes, the oxides stabilize the surface structure of the complex lithium metal oxide and improve on high temperature storage properties, as well as safety and cycle life.

Abstract: A metal film made of a metal material (e.g., NiFe, CoFeNi, or FeCo) including an iron atom is formed on a substrate (S101). Subsequently, the metal film formed on the substrate is plasma-processed in an environment including a gas (e.g., an oxygen gas having a tetrafluoromethane or trifluoromethane gas added thereto) containing oxygen and fluorine atoms (S103). Then, a resist material (e.g., a chemically amplified positive resist material) is applied onto the plasma-processed metal film, so as to form a resist film (S105). Thereafter, the resist film is partly removed, so as to expose a part of the surface of metal film in conformity to a desirable pattern, thereby forming a resist frame (S107).

Abstract: A metal oxide coating and a method of forming the metal oxide coating are disclosed, wherein the metal oxide coating composition includes a metal oxide precursor of the metal oxide, the metal oxide, or a combination thereof, and a solvent of secondary or tertiary C4–C8 alcohol.

Abstract: Low-cost, mechanically strong, highly electronically conductive porous substrates and associated structures for solid-state electrochemical devices, techniques for forming these structures, and devices incorporating the structures provide solid state electrochemical device substrates of novel composition and techniques for forming thin electrode/membrane/electrolyte coatings on the novel or more conventional substrates. In particular, in one aspect the invention provides techniques for co-firing of device substrate (often an electrode) with an electrolyte or membrane layer to form densified electrolyte/membrane films 5 to 20 microns thick. In another aspect, densified electrolyte/membrane films 5 to 20 microns thick may be formed on a pre-sintered substrate by a constrained sintering process. In some cases, the substrate may be a porous metal, alloy, or non-nickel cermet incorporating one or more of the transition metals Cr, Fe and Cu, or alloys thereof.

Abstract: An integral plated resistor having an improved range of resistance is produced by uniformly dispersing an effective amount of various particles in an electroless nickel phosphorus plating composition so that the particles are codeposited with the electroless nickel phosphorus plating composition. Preferred particles include, polytetrafluoroethylene, silicon carbide, tungsten carbide, and other particles that fully sinter at a temperature of less than about 170° C. The improved nickel phosphorus plated resistors of the invention demonstrate increased stability during manufacturing press cycles and a greater range of resistance values than have previously been achieved.

Abstract: An inert anode 50, for use in an electrolytic cell 12 for producing metals such as aluminum, is made by providing chemical source materials 100 such as at least two of metal salts, metal particles, or metal oxides and dissolving them to form a solution or a slurry 110, followed by adding a base 120 and adjusting the pH so that a gel 130 is formed which is dried and calcined 150, 160, 190 to provide a blend of metal oxide powder 200 which can be pressed and sintered 220 to form an inert anode 50.

Abstract: In a composite magnetic body comprising soft magnetic powder dispersed in an organic binding agent and having an electromagnetic interference suppressing effect, powder excellent in thermal conductivity is further dispersed into the organic binding agent so as to provide a composite magnetic body excellent in thermal conductivity. This composite magnetic body may also be used as a heat dissipation sheet for an electronic device. Further, it may also constitute a heat sink having an electromagnetic interference suppressing effect. As the organic binding agent, thermoplastic polyimide or liquid crystal polymer can be cited. As the powder excellent in thermal conductivity, Al2O3, AlN, cubic BN, insulating SiC or a heat conductive reinforcement (capton) can be cited.

Abstract: A composition of matter comprising a mixture of an oxide powder or powders and a Reactive Organic Medium (ROM) which can be used to create electronic components on a suitable. The materials are applied to conventional polymer-based circuit substrates by any convenient printing process and thermally cured to well-consolidated oxide components at a temperature, which the substrate can withstand. Mixtures for various components, including resistors, capacitor dielectrics and magnetic cores and processes to apply them are disclosed.

Abstract: The invention relates generally to processes for producing electrically conductive noble metal thin films on a substrate by atomic layer deposition. According to one embodiment of the invention a substrate with a surface is provided in a reaction chamber and a vaporised precursor of a noble metal is pulsed into the reaction chamber. By contacting the vaporised precursor with the surface of the substrate, no more than about a molecular layer of the metal precursor is formed on the substrate. In a next step, a pulse of molecular oxygen-containing gas is provided in the reaction chamber, where the oxygen reacts with the precursor on the substrate. Thus, high-quality metal thin films can be deposited by utilising reactions between the metal precursor and oxygen. In one embodiment, electrically conductive layers are deposited in structures that have high aspect ratio vias and trenches, local high elevation areas or other similar surface structures that make the surface rough.

Abstract: A method of making cermet inert anodes for the electrolytic production of metals such as aluminum is disclosed. The method includes the step of spray drying a slurry comprising ceramic phase particles and metal phase particles. The resultant spray dried powder, which comprises agglomerates of both the ceramic phase and metal phase particles, may then be consolidated by techniques such as pressing and sintering to produce a cermet inert anode material. The ceramic phase may comprise oxides of Ni, Fe and at least one additional metal selected from Zn, Co, Al, Li, Cu, Ti, V, Cr, Zr, Nb, Ta, W, Mo, Hf and rare earths. The metal phase may comprise Cu, Ag, Pd, Pt, Au, Rh, Ru, Ir and/or Os. The consolidated cermet inert anode material exhibits improved properties such as reduced porosity. The cermet inert anodes may be used in electrolytic reduction cells for the production of commercial purity aluminum as well as other metals.

Abstract: There is provided a method for fabricating electrical wirings capable of being manufactured with low cost and easily applied to large-scale substrates. A photosensitive ground resin film is formed on an insulating substrate by coating process. The ground resin film is subjected to exposure and development processes, by which a ground resin film patterned into a wiring pattern is obtained. Then, on the patterned ground resin film, a low-resistance metal film made of Cu is formed by electroless plating.

Abstract: Disclosed is a positive active material for a rechargeable lithium battery.

Abstract: A structure and method of fabricating a magnetic read head, comprises forming a fill layer for a magnetic read head gap using atomic layer deposition (ALD). The fill layer comprises an insulator, preferably aluminum oxide, aluminum nitride, mixtures thereof and layered structures thereof. Materials having higher thermal conductivity than aluminum oxide, such as berylium oxide and boron nitride, can also be employed in layers within an aluminum oxide structure. The thickness of the ALD-formed head gap fill layer is between approximately 5 nm and 100 nm, preferably between approximately 10 nm and 40 nm.

Abstract: Disclosed herein is a process for producing a film, coating or powder employing a metallocene or metallocene-like precursor having the general formula CpMCp′, where M is a metal selected from the group consisting of Ru, Os and Fe; Cp is a first substituted cyclopentadienyl or cyclopentadienyl-like, e.g., indenyl, moiety that includes at least one substituent group D1, where D1 is X; Ca1Hb1Xc1; Ca2Hb2Xc2(C═O)Ca1Hb1Xc1; Ca2Hb2Xc2OCa1Hb1Xc1; Ca2Hb2Xc2(C═O)OCa1Hb1Xc1; or Ca2Hb2Xc2O(C═O)Ca1Hb1Xc1; and Cp′ is a second substituted cyclopentadienyl or cyclopentadienyl-like, e.g., indenyl, moiety that includes at least one substituent group D1′, where D1′ is X; Ca1Hb1Xc1; Ca2Hb2Xc2(C═O)Ca1Hb1Xc1; Ca2Hb2Xc2OCa1Hb1Xc1; Ca2Hb2Xc2(C═O)OCa1Hb1X1; or Ca2Hb2Xc2O(C═O)Ca1Hb1Xc1. D1 and D1′ are different from one another.

Abstract: Disclosed is a positive active material for a rechargeable lithium battery. The active material includes a cobalt-based compound selected from the group consisting of the compounds represented by the formulas 1 to 4. The active material has a structure of secondary particles with a size of 10 to 30 &mgr;m and the secondary particle is gathered with primary particles with a size of 1 to 5 &mgr;m. The active material includes a metallic oxide coated on the cobalt-based compound. LiCoA2  (1) LiCoO2-xBx  (2) LiCo1-xMxA2  (3) LiCo1-xMxO2-yBy  (4) where A is selected from the group consisting of O, S, F and P, B is selected from the group consisting of S, F and P, M is a transition metal selected from Al, Mg, Cr or Mn; Sr; or lanthanide metal selected from La or Ce; 0<x<1 and 0<y<1.

Abstract: Ceramic inert anodes useful for the electrolytic production of aluminum are disclosed. The inert anodes comprise oxides of Ni, Fe and Al. The Ni—Fe—Al oxide inert anode materials have sufficient electrical conductivity at operation temperatures of aluminum production cells, and also possess good mechanical stability. The Ni—Fe—Al oxide inert anodes may be used to produce commercial purity aluminum.

Abstract: A metal oxide electrode coated with a porous metal film, a metal oxide film or a carbon film, its fabrication method and a lithium-ion secondary battery using it are disclosed. The porous thin film of Li, Al, Sn, Bi, Si, Sb, Ni, Cu, Ti, V, Cr, Mn, Fe, Co, Zn, Mo, W, Ag, Au, Pt, Ir, Ru, carbon or their alloys are coated to a few Řa few &mgr;m, so as to remarkably improve the capacity of a battery, high rate charging and discharging characteristics and a durability characteristic. The method can be applied to a fabrication of every secondary battery.

Abstract: The present invention relates to composite polymers containing nanometer-sized metal particles and manufacturing method thereof, which can be uniformly dispersed nanometer-sized metal particles into polymers, thereby allowing the use thereof as optically, electrically and magnetically functional materials. The method for manufacturing composite polymers containing nanometer-sized metal particles includes the steps of: dispersing at least one metal precursor into a matrix made of polymers in a molecule level; and irradiating rays of light on the matrix containing the metal precursors dispersed in the molecule level and reducing the metal precursors into metals and fixing nanometer sized metal particles inside of matrix.

Abstract: A solid oxide fuel cell comprises a dense electrolyte disposed between a porous anode and a porous cathode wherein the dense electrolyte comprises doped lanthanum gallate or yttria stabilized zirconia, the porous anode comprises yttrium-doped strontium titanate, yttrium-doped strontium titanate and nickel, lanthanum-doped ceria and nickel or yttria stabilized zirconia and nickel and the porous cathode comprises doped lanthanum ferrite or strontium-doped lanthanum manganite. The fuel cell may further comprise an interlayer(s) comprising lanthanum-doped ceria disposed between an electrode (anode, cathode or both) and the electrolyte. An interconnect layer comprising doped lanthanum chromate may be disposed between the anode of a first single fuel cell and the cathode of a second single fuel cell. The anode, cathode, electrolyte and optional interlayer(s) are produced by thermal spray.

Abstract: Disclosed is a positive active material for a rechargeable lithium battery. The positive active material includes a core and a surface-treatment layer on the core. The core includes at least one lithiated compound and the surface-treatment layer includes at least one coating material selected from the group consisting of coating element included-hydroxides, oxyhydroxides, oxycarbonates, hydroxycarbonates and any mixture thereof.

Abstract: In order to prevent a rise in resistance due to oxidation of copper wiring and diffusion of copper, a semiconductor device is provided which contains a wire protective film 1 covering the top of the copper wiring 2 formed in the insulation film and a barrier film surrounding the side and bottom of the copper wiring. The wire protective film and/or barrier film is formed with a cobalt alloy film containing (1) cobalt, (2) at least one of chromium, molybdenum, tungsten, rhenium, thallium and phosphorus, and (3) boron.

Abstract: A fast heat rise resistor comprising a substrate, a foil bridge on the surface of the substrate, the foil bridge having an elevated portion and a contact portion, the elevated portion above the substrate, the contact portion in contact with the substrate, a conductive layer attached to the contact portion of said foil bridge. The activation energy and/or response time is reduced as the foil bridge is suspended over the substrate. Another aspect of the invention include a method of manufacturing the foil bridge and application to autoignition vehicle airbags.

Abstract: A non-carbon, metal-based, high temperature resistant, electrically conductive and electrochemically active anode of a cell for the production of aluminum has a metal-based substrate to which an adherent coating is applied prior to its immersion into the electrolyte and start up of the electrolysis by connection to the positive current supply. The coating is obtainable from one or more layers applied from: a liquid solution, a dispersion in a liquid or a paste, a suspension in a liquid or a paste, and a pasty or non-pasty slurry, and combinations thereof with or without one or more further applied layers, with or without heat treatment between two consecutively applied layers when at least two layers are applied.

Abstract: Solid oxide fuel cells made by coating a slurry of an electrolyte having a limited amount of organic material onto a carrier tape, depositing a one or two layer electrode material on the tape sufficient to support the electrolyte layer, removing the tape, screen printing a second electrode layer on the exposed surface of the electrolyte layer, and firing the layers at a temperature of 1100-1300° C. The resultant fired fuel cell can be mounted on an interconnector comprising a base plate, grooves formed in one face of the base plate, a porous conductive ceramic contact layer between the base plate and an overlying blocking layer of a porous conductive layer to provide electrical contact between the base plate and the blocking layer, or an interconnector having a fired green tape stack having conductive via contacts and air and gas flow channels formed therein. A sealing glass bonds the overlying layers to the base plate.

Abstract: A process of manufacturing a positive active material for a lithium secondary battery includes adding a metal source to a doping element-containing coating liquid to surface-treat the metal source, wherein the metal source is selected from the group consisting of cobalt, manganese, nickel, and combination thereof; drying the surface-treated metal source material to prepare a positive active material precursor; mixing the positive active material precursor with a lithium source; and subjecting the mixture to heat-treatment. Alternatively, the above drying step during preparation of the positive active material precursor is substituted by preheat-treatment or drying followed by preheat-treatment.

Abstract: Provided are low-cost, mechanically strong, highly electronically conductive porous substrates and associated structures for solid-state electrochemical devices, techniques for forming these structures, and devices incorporating the structures. The invention provides solid state electrochemical device substrates of novel composition and techniques for forming thin electrode/membrane/electrolyte coatings on the novel or more conventional substrates. In particular, in one embodiment the invention provides techniques for co-firing of device substrate (often an electrode) with an electrolyte or membrane layer to form densified electrolyte/membrane films 5 to 20 microns thick. In another embodiment, densified electrolyte/membrane films 5 to 20 microns thick may be formed on a pre-sintered substrate by a constrained sintering process. In some cases, the substrate may be a porous metal, alloy, or non-nickel cermet incorporating one or more of the transition metals Cr, Fe, Cu and Ag, or alloys thereof.

Abstract: Disclosed is a positive active material for a lithium secondary battery and a preparation method of the same that can improve cycle-life characteristics and storage characteristics at a high temperature by improving structural safety characteristics and electrochemical characteristics, by forming an overlayer comprising an oxide glass phase on the surface of the positive active material, and a lithium secondary battery comprising the positive active material.

Abstract: Nanostructured non-stoichiometric materials are disclosed. Novel magnetic materials and their applications are discussed. More specifically, the specifications teach the use of nanotechnology and nanostructured materials for developing novel magnetic devices and products.

Abstract: An improved cathode material for nonaqueous electrolyte lithium electrochemical cell is described. The preferred active material is silver vanadium oxide (SVO) coated with a protective layer of an inert metal oxide (MxOy) or lithiated metal oxide (LixMyOz). The SVO core provides high capacity and rate capability while the protective coating reduces reactivity of the active particles with electrolyte to improve the long-term stability of the cathode.

Abstract: Disclosed is a positive active material for a lithium secondary battery and a preparation method of the same, in particular a positive active material and preparation method of the same that can improve cycle-life characteristics at a high temperature and room temperature, and storage characteristics at a high temperature.

Abstract: A nickel electrode for alkaline storage battery of the invention comprises an electrically-conductive porous substrate coated with an oxide containing cobalt on the surface thereof and a positive active material coated with nickel and a compound selected from the group consisting of Ca, Sr, Sc, Y, Al, Mn and lanthanoids on the surface thereof. Thus, the coating of the surface of the active material with nickel and a compound containing Ca, Sr, Sc, Y, Al, Mn and lanthanoids causes the enhancement of the effect of increasing oxygen overvoltage at high temperature and hence the charge acceptability. Further, since the gap between the electrically-conductive porous substrate and the positive active material is filled with the oxide containing cobalt, the electrical conductivity thereof can be improved, making it possible to inhibit the deterioration of large current charge properties and large current discharge properties.

Abstract: Disclosed are organometallic compounds derived from Groups VIIb, VIII, IX, and X metals useful as precursors for the formation of metal containing powders and for the chemical deposition of the metals on substrates, particularly for the chemical vapor deposition of metal films suitable for the manufacture of electronic devices. Methods for their use are also disclosed.

Abstract: The following steps are conducted: preparing a metal salt carried-substrate A by soaking a sintered nickel substrate in an acidic solution containing cobalt ions and at least one metal ions of magnesium ions, iron ions and manganese ions, and drying thus soaked substrate; preparing a hydroxide carried-substrate B by soaking the substrate A in an alkaline solution to deposit cobalt hydroxide and at least one metal hydroxide of magnesium hydroxide, iron hydroxide and manganese hydroxide in the pores and on the surface of the substrate A; obtaining an oxide carried-substrate C by oxidizing the cobalt hydroxide to produce cobalt oxide having a mean cobalt valence of over 2; and obtaining an active material carried-substrate D by soaking the substrate C in a solution containing nickel nitrate dissolved therein, drying thus soaked substrate C, and then soaking thus dried substrate C in an alkaline solution, to fill the active material in the substrate C.

Abstract: A lithium secondary cell, in which a water-soluble polymer having a superior resistance to organic solvents is used as a binder, the capacity is high, the charge-discharge cycle is superior, and the increase of the internal resistance is suppressed, is disclosed. The lithium secondary cell according to the invention comprises a positive electrode and an electrolytic solution, wherein the positive electrode includes a positive electrode active material having a LiNiO2 compound expressed as LixNi1−yMyO2 (M is at least one element selected from a group including Co, Mn, Al, B, Ti, Mg and Fe, 0<x≦1.2, 0<y≦0.25) and a binder for binding the positive electrode active material. The BET specific surface area of the LiNiO2 compound is not more than 0.65 m2/g. The binder has a water-soluble polymer not swollen with the electrolytic solution. The surface of the positive electrode active material is covered by the water-soluble polymer. The reduction of the cell capacity is suppressed.

Abstract: Magnetic composites exhibit distinct flux properties due to gradient interfaces. The composites can be used to improve fuel cells and effect transport and separation of different species of materials. A variety of devices can be made utilizing the composites including a separator, a cell, an electrode for channeling flux of magnetic species, an electrode for effecting electrolysis of magnetic species, a system for channeling electrolyte species, a system for separating particles with different magnetic susceptibilities. Some composites can be used to make a dual sensor for distinguishing between two species of materials and a flux switch to regulate the flow of a redox species and a flux switch to regulate the flow of a chemical species. Some composites can control chemical species transport and distribution.

Abstract: A photocatalyst composite is provided which comprise a substrate having particles of a photocatalyst such as titanium oxide, adhered thereon via a less degradative adhesive such as a fluorinated polymer comprising a copolymer of a vinyl ester and/or vinyl ether and a fluoroolefin, or a silicon based polymer or cement. Furthermore, a process for producing the photocatalyst composite and a coating composition containing the photocatalyst composite are provided.

Abstract: The present invention provides an alkaline storage battery which is superior in the rate of utilization of the active material, cycle life, and discharge characteristic through a more simplified way of preparation of a high-performance positive active material by addition of a smaller quantity of a cobalt compound than conventional methods. The alkaline storage battery is obtained by employing an active material prepared by rendering &agr;-type cobalt hydroxide adhere on the surface of nickel hydroxide particles and then treating with an aqueous solution of sodium hypochlorite in the positive plate.

Abstract: This invention relates to manufacturing of integrated circuits (ICs) and especially conductive layers suitable for use in an IC. According to the preferred method a metal oxide thin film is deposited on a substrate surface and reduced thereafter essentially into a metallic form with an organic reducing agent. The metal oxide is preferably deposited according to the principles of atomic layer deposition (ALD) using a metal source chemical and an oxygen source chemical. The reduction step is preferably carried out in an ALD reactor using one or more vaporized organic compounds that contain at least one functional group selected from the group consisting of —OH, —CHO and —COOH.

Abstract: A positive electrode active material for an alkaline storage battery comprising at least one selected from the group consisting of a nickel hydroxide powder and a nickel oxyhydroxide powder is disclosed, wherein the positive electrode active material has (1) a mean particle circularity from 0.95 to 1, (2) a mean particle size from 5 to 20 &mgr;m on a volume basis, and (3) a specific surface area from 5 to 20 m2/g, and (4) at least the nickel hydroxide powder has an X-ray diffraction pattern where a full width at half maximum of a peak attributed to (101) face is from 0.7 to 1.2 deg/2&thgr; and a peak intensity ratio of a peak attributed to (001) face to a peak attributed to (101) face is not less than 1.1.

Abstract: A method for making a composite positive electrode material for use in electrochemical cells. The composite material comprises a particle of positive electrode material and a nucleating particle at least partially embedded within the interior of the particle of positive electrode material.

Abstract: Disclosed is a method of forming a nickel metal thin film, comprising the steps of coating a substrate with a solution for forming a nickel metal thin film, the solution being formed of an alcohol solution containing nickel ions and a reducible chelate type ligand having a hydrazone unit so as to form a gel film, and subjecting the resultant gel film to a heat treatment under an inert gas atmosphere.

Abstract: There is provided an electroless Ni—B plating liquid for forming, a Ni—B alloy film on at least part of the interconnects of an electronic device having an embedded interconnect structure, the electroless Ni—B plating liquid comprising nickel ions, a complexing agent for nickel ions, a reducing agent for nickel ions, and ammonums (NH4+). The electroless Ni—B plating liquid can lower the boron content of the resulting plated film without increasing the plating rate and form a Ni—B alloy film having an FCC crystalline structure.

Abstract: A method of preparing for a positive active material for a rechargeable lithium battery is provided. In this method, a lithiated compound to be coated and an organic solution or aqueous solution including a coating-element source are putted into a mixer, the mixture is continuously stirred to mix the contents thoroughly, and a hot dry gas is introduced into the mixer to evaporate the solvent while the powder is continuously agitated. The resulting dry coated powdery compound is heat-treated at an elevated temperature to obtain an oxide coating on the lithiated compound.

Abstract: The present invention relates to a method for a surface treatment of a layered structure oxide for a positive electrode in a lithium secondary battery. The method includes coating the surface of the layered structure oxide with a lithium transition metal oxide. The lithium secondary battery where the layered structure oxide is used as an active material of the positive electrode solves the problem of the thermal stability suffered conventionally.

Abstract: Disclosed is a positive active material for a rechargeable lithium battery. The positive active material includes a core and a surface-treatment layer on the core. The core includes at least one lithiated compound and the surface-treatment layer includes at least one coating material selected from the group consisting of coating element included-hydroxides, oxyhydroxides, oxycarbonates, hydroxycarbonates and any mixture thereof.

Abstract: A nickel electrode for an alkaline storage battery employed as a positive electrode of an alkaline storage battery is formed by filling an active material into pore of a porous sintered substrate wherein said active material is formed by adhering niobic acid to a surface of nickel hydroxide particles.

Abstract: A high capacity alkaline storage battery which exhibits a maintained dischargeability and a reduced excess negative electrode capacity by decreasing the content of &ggr;-NiOOH left in higher order positive active material. To an aqueous solution of a mixture of nickel sulfate, zinc sulfate and cobalt sulfate was gradually added an aqueous solution of sodium hydroxide with stirring to cause the crystallization of nickel hydroxide. Nickel hydroxide thus crystallized was washed, dehydrated, and then dried. To nickel hydroxide was then added dropwise a predetermined amount of an oxidizing agent (NaClO) while being stirred in an aqueous solution of sodium hydroxide which had been kept to a predetermined temperature so that nickel hydroxide as a main component was put in higher order (e.g., average valence is raised to 2.8) Subsequently, to the material was added dropwise a predetermined amount of a reducing agent (H2O2) so that the higher order nickel hydroxide as a main component was reduced (e.g.

Abstract: An active material having a composition of LixNiyMzO2 (0.8<x<1.5, 0.8<y+z<1.2, 0≦z<0.35; M is an element selected from Co, Mg, Ca, Sr, Al, Mn and Fe) is preserved in a gas having a moisture dew point of −20° C. or less from immediately after production of said active material till preparation of an active material mixture-coating material, or is subjected to vacuum drying immediately before preparation of said active material mixture-coating material. The prepared mixture-coating material is applied onto a collector.

Abstract: In a solution for forming electron-emitting regions of electron-emitting devices, the solution contains a metal carboxylate expressed by the following general formula (I), an organic solvent and/or , and water; (R(COO)k)mM  (I) where k=numeral from 1 to 4 , m=a numeral from 1 to 4, and R=CnX2n+1−k R=CnX2n+2−k where X=a hydrogen or halogen (total number of hydrogen and halogen atoms is 2n+1) , n=an integer from 0 to 30, and M=a metal, wherein the organic solvent is a carboxylic ester having the same carboxylic group as R(COO)k expressed in the general formula (I). In a manufacture method of electron-emitting devices each provided between electrodes with a conductive film including an electron-emitting region, a process of forming the conductive film includes a step of coating and calcining the above solution. An image-forming apparatus is manufactured by using the electron-emitting devices.