Abstract: A method is disclosed providing temporary protection of a glass surface from staining and scratches by coating the exposed surface with a soluble polymer film incorporating spacer particles of an inert material.

Abstract: A composition which can be applied to old asbestos before it is removed from old plant, apparatus of buildings is provided. The composition, which is in the form of a concentrate to be diluted with water, consists of:(a) from 1 to 20% by weight of a C.sub.12 to C.sub.20 secondary alcohol alkoxylate having a molecular weight in the range 500 to 700.(b) from 0.1 to 20% by weight of a polyoxyethylene-oxypropylene block copolymer having an average molecular weight in the range 1800 to 2000 and an ethylene oxide content of between 8 and 12% by weight.(c) from 10 to 60% by weight of a random polyoxyethylene oxypropylene glycol ether having an average molecular weight in the range 1500 to 3500 and an ethylene oxide content of between 40 and 75% by weight.(d) the balance, if required, being water.

Abstract: A process for facilitating the removal of undesired contamination from a surface, comprising the steps:(a) applying a solution containing a polysaccharide and a solvent therefor onto said surface before it is subjected to contamination, said polysaccharide being capable of forming a redissolvable or swelling solid film upon drying;(b) allowing the applied solution to dry to form a solid film on said surface;(c) treating the coated surface with a liquid capable of redissolving the film or providing for swelling thereof; and(d) removing the undesired contamination by removing the dissolved or swelled surface layer of the film.

Abstract: Asbestos containing materials which have become friable and thus hazardous to health can be rendered non-friable by treatment with a lipophilic material, such as a triglyceride oil having non-polar or slightly polar characteristics. The method of the invention is particularly applicable to the treatment of asbestos-containing roofs which are friable and which, without treatment, would be required to be removed using the stringent, expensive protocol which is specified under the Federal Asbestos Abatement Guidelines for removal of friable asbestos roofs.

Abstract: An improved process for the preparation of backing layers with improved coating qualities is described. These layers are designed to transmit antistatic properties from antistatic layers coated under the backing layers and provide antihalation or anticurl effects in addition thereto. The process of this invention includes in-line addition of a pre-stabilized crosslinking solution to a gelatino-conductive polymer solution just prior to the coating thereof. Smooth, skip-free coatings are obtained and the solutions are stable and can be maintained for long periods of time.

Abstract: A process for producing a silicon-containing polyamic acid affording a silicon-containing polyimide having a low thermal expansion coefficient and a process for producing the silicon-containing polyimide are provided, the former process comprising reacting pyromellitic acid dianhydride (A.sup.1 mols) and 3,3',4,4'-biphenyltetracarboxylic acid dianhydride (A.sup.2 mols) with a diamine of the following formula (I) (B mols) and an aminosilicon compound of the formula (II) so as to satisfy the following expressions (III) and (IV): ##STR1## wherein R.sup.1 is methyl, ethyl, methoxy, ethoxy or halogen; R.sup.2 is alkyl or alkyl-substituted phenyl; X is a hydrolyzable alkoxy, acetoxy or halogen; m is 0, 1 or 2; n is 1 or 2; and k is 1, 2 or 3; andthe latter process comprising baking a solution of the above silicon-containing polyamic acid at 50.degree. to 500.degree. C.

Abstract: A process for applying a permanent filled engraved identification to the surface of an object such as a paving brick which is made of porous material.

Abstract: A flexible decorative sheet material for use in surfacing automobile body panels and the like is disclosed. The sheet material is characterized by having the appearance of a glossy base coat/clear coat automotive paint finish. The material comprises a substantially transparent outer layer, and a pigmented coating on the undersurface of the outer layer which is visible therethrough. The pigmented coating preferably has reflective flakes uniformly distributed therein to impart to the sheet material the appearance of a base coat/clear coat paint finish. Also disclosed are shaped articles which have such sheet materials adhered to one side thereof, and a method for making such sheet materials.

Abstract: An aqueous system for treating a film or coating containing water-dispersible polymeric material having water solubilizing sulfonate groups in its molecular structure, the system being effective for insolubilizing the sulfonate groups and enhancing the water resistance of the film, and having dispersed therein per 100 grams of water, from about 0.002 to about 0.5 gram-ion equivalents of a multivalent cation, and from about 0.1 to about 25.0 grams of water-dispersible polyurethane material, and preferably having a No. 2 Zahn cup viscosity of from about 15 to about 50 seconds.

Abstract: An aqueous process is described for preparing water-resistant coatings of hydrophobic copolymers of a predetermined composition. The hydrophobic copolymers are made from hydrophilic comonomers such as a vinyl lactam and a polymerizable carboxylic acid. The hydrophobic copolymers are rendered water soluble with a volatile neutralizing agent, such as ammonium hydroxide, then coated onto a substrate and heated to provide the water-resistant coating, and, if desired, redissolved in an aqueous alkaline solution.

Abstract: A pressure-sensitive adhesive tape for masking selected areas of an article such as a printed circuit board during high temperature operations such as wave soldering comprises a polymeric film coated with a layer of pressure-sensitive adhesive, both film and adhesive being resistant to temperatures up to 250.degree. C. for up to 5 seconds and being soluble in a fluorocarbon solvent such as a trichlorotrifluoroethane solvent. More particularly the film and adhesive are resistant to temperatures up to 260.degree. C. for up to 25 seconds.The polymeric film, which is a novel self-supporting film, may suitably comprise a polymethacrylate other than poly(methyl methacrylate) e.g. poly(butyl methacrylate), or ethyl cellulose or polyvinylpyrrolidone.

Abstract: A composition for the pre-treatment in aqueous form of a surface, preferably of an oven, which is subjected to heat and is liable to soiling by baked-on organic food deposits. A food-safe, inorganic thickening agent, in an amount sufficient so that the composition is capable of forming a continuous coating adhered to all desired portions of the preferably cleaned surface, which coating also remains continuous as the coating dries, preferably by heating, is combined with an alkaline, water-soluble inorganic salt in an amount sufficient so that the composition is readily removable with water or an aqueous solution after the composition has been dried and soiled. The composition forms a continuous film after drying. After the film becomes soiled, it can be readily removed by contact with water or an aqueous solution.

Abstract: The liquid mixtures according to the invention comprise at least one ethylene polymer (A) and at least one solvent (B), and are characterized in that:(a) the ethylene polymer (A) comprises at least one terpolymer having a fluidity index comprised between 2 and 500 dg/min and comprising:from 83 to 95.7 moles % of units derived from ethylene,from 4 to 15 moles % of units derived from at least one alkyl acrylate or methacrylate, the alkyl group having from 1 to 6 atoms of carbon, andfrom 0.3 to 2 moles % of units derived from maleic anhydride,(b) the solvent (B) is selected from amongst aliphatic, cycloaliphatic and aromatic hydrocarbons having from 5 to 12 atoms of carbon, dechlorinated solvents and esters.The process comprises in a first step the dissolution of polymer (A), by stirring, in the solvent (B) at a temperature T (expressed in Celcius degrees) such that: 35.ltoreq.T.ltoreq..theta., .theta. being the boiling temperature of the solvent (B).

Abstract: An oxidation-resistant silicon nitride material possessing a surface layer of a phase of closely packed crystals is produced by a procedure which comprises covering the surface of a silicon nitride substrate with a layer of an alkali metal compound, firing the coated substrate at a temperature of between 800.degree. C. and 1,300.degree. C., thereby forming an alkali metal-containing vitreous coating layer on the surface of the silicon nitride substrate, and thereafter removing the coating layer.

Abstract: An oxidation-resistant sialon material and an oxidation-resistant silicon carbide material each containing a phase of closely packed crystals in the surface region are produced by coating a sialon substrate and a silicon carbide substrate with a layer of an alkali metal compound and a layer of a mixture of an alkali metal compound and a carbonaceous substance respectively, firing the resultant coated substrate at a temperature in the range of 800.degree. to 1,300.degree. C. thereby forming an alkali metal-containing vitreous coating layer on each substrate, and thereafter removing the each coating layer.

Abstract: Easily removable conformable coatings having a controlled thickness with a predetermined minimum value are obtained by the application of a composition comprising a mixture of a viscous carrier material and small particles of a second material by any known method. When both the carrier material and the particulate material mixed therewith are selected to have high dielectric constants, the mixture may be used to obtain coatings suitable for protection of circuit boards supporting high impedance electrical circuits. A mixture of a commercially available grease, e.g., Amoco RYKON (TM), with glass microspheres comprising up to 50% of the volume and preferably in the size range 3-5 mils, provides excellent dielectric conformal coatings for high impedance circuit boards. By contrast, by selecting both the viscous carrier material and the particulate matter mixed therein to have high conductivity, electrically conductive coatings for particularized users may likewise be obtained according to this invention.

Abstract: A process for thermoforming a decorative glossy film to a relatively rigid substrate includes the steps of: providing a carrier film having a heat absorption limit or a plurality of heat absorption limits above which decorative degradation occurs during direct exposure to heat sources of thermoforming apparatus; thermally protecting the surface of the carrier film with a layer of material with a heat absorption rate which will shield the carrier film against excessive heat buildup while softening the carrier film for drawing against a substrate; drawing the carrier film and the protective layer thereon into bonded engagement with the relatively rigid substrate; and thereafter removing the thermal protection layer without degrading the appearance of the decorative carrier film.

Abstract: Barriers used for separating silicone pressurizing medium from articles during curing, thereby protecting the article from silicone contamination. A composite precursor is substantially encapsulated by a barrier coating that is capable of substantially separating the composite precursor from silicone polymers at elevated temperatures during curing. The barrier coating is also capable of being chemically removed from the composite precursor subsequent to its cure without substantially damaging the composite. Composites are molded by protecting a composite precursor from a silicone pressurizing medium during curing utilizing a barrier coating. The method comprises encapsulating a composite precursor with a coating that is substantially capable of separating the composite precursor from silicone polymers at elevated temperatures. The coating is also capable of being chemically removed from the composite without damaging the composite.

Abstract: An improved process for the production of microcapsules by the use of hydrogen transfer polymerization in the presence of a mixture of emulsifiers including either an aqueous solution of a sodium salt of naphthalene-sulfonic acid-formaldehyde condensate or diphenyloxide disulfonate with a polyvinyl alcohol. The process is particularly useful for the production of microcapsules containing a colorless dye intermediate used in carbonless copy paper (CCP) applications.

Abstract: Hot melt pressure sensitive prepared from (a) a rubbery block copolymer containing a rubbery polyisoprene midblock portion and a plurality of crystalline poly(vinylarene) endblocks; (b) a tackfying resin compatible with the midblock portion and (c) poly(alkyloxazoline); and (d) an antioxidant. These adhesives are characterized by exceptional elastic memory, high tensile strength and excellent peel adhesion and, as such, are especially suited for use in elasticized bands for disposable items.

Abstract: Temporary corrosion protection for fresh metal surfaces may be obtained by depositing a thin film of a protective organic compound, particularly a fatty acid ester, from a solvent, preferably a fluorocarbon on the surface to be protected. The film-forming esters are chosen to be self-removing by evaporation so that no cleaning is needed before carrying out processes which require a clean metal surface.

Abstract: A crystal clear paint spray booth barrier coating comprising an aqueous solution of polyvinyl alcohol is disclosed. The polyvinyl alcohol may include a foam depressor for spray application of said coating. Fluorocarbon and non-ionic surfactants are disclosed for providing a smooth coating surface and improving the transparency of said coating. A polyacrylate thickener may be included to facilitate applying the coating to vertical surfaces. Methylparaben is disclosed for preventing the formation of mold on said coating and improving shelf life of the coating. The method disclosed includes mixing an aqueous solution of polyvinyl alcohol, at least one surfactant and a foam depressor, applying said mixture to the surfaces of the paint spray booth to be protected and equipment located in the paint spray booth, and allowing the coating to dry to a crystal clear coating. Methods of removing the coating include peeling the coating off as a film and water washing the coating.

Abstract: A non-permanent ornamental paint mixture being water soluble after drying. The mixture consists essentially of: from about 75.0 to about 85.0 parts by weight water; from about 10.0 to about 12.0 parts by weight filler; from about 0.5 to about 1.5 parts by weight aqueous pigment dispersion; from about 2.0 to about 2.5 parts by weight release agent; from about 3.0 to about 4.5 parts by weight acid containing, cross-linked acrylic emulsion copolymer; up to 1.0 parts by weight alkali; up to 0.1 parts by weight defoamer; and up to 0.1 parts by weight antimicrobial agent.

Abstract: Disclosed is a masking tape suitable for use in manufacturing a printed circuit board. The masking tape comprises a water soluble paper as a tape base material, and a water soluble adhesive agent applied to one side of the paper. A method of filling through-holes employing such a water soluble masking tape in a process of manufacturing a printed circuit board is also disclosed.

Abstract: Temporarily insulating frozen surfaces, such as ice rinks, from the ambient air by spreading a metastable liquid foam over the ice surface to remain thereon when the ice surface is not in use, then prior to the next use period, removing the aged, partially frozen foam. Fire fighting foam liquids are preferred embodiment foaming agents.

Abstract: A debilitant composition of water and a homopolymer of ethylene oxide having a molecular weight of from about 100,000 to about 5,000,000 and having a repeating monomeric unit with a molecular weight of 44 is applied to a body of previously installed asbestos insulation in sufficient quantity to thoroughly wet at least the exposed portion thereof. Thereafter, the pre-wet body is mechanically debrided.

Abstract: Asbestos-containing materials can be removed from their substrate by (1) applying a composition containing a cellulosic polymer such as hydroxypropyl cellulose to said asbestos-containing material; (2) allowing the cellulosic polymer containing composition time to penetrate and wet the asbestos-containing material; and (3) removing the resulting wet asbestos-containing material by use of mechanical forces.

Abstract: A method of placing color indicia or tints on a porous surface includes the steps of forming a base layer on a surface, such as a floor, by applying a liquid layer of an unpigmented metal interlock acrylic finish to the surface, and allowing the base layer to dry. A pigmented layer of liquid metal interlock acrylic finish containing an acrylic polymer emulsion and pigment substance is then applied over the base layer in the form of an indicia, such as a decoration, advertisement, or pattern. After the pigmented layer has dried, a protective layer of liquid metal interlock acrylic finish is then applied over the pigmented layer and allowed to dry to protect the design, and the protective layer can be buffed to a shine. The method can be used to quickly and easily apply directional aids, advertisements, tints, or other colored indicia to a floor. Both the pigmented and unpigmented layers are readily removable with common detergents such as ammonia.

Abstract: Homopolymers and copolymers which have an average molecular weight of at least 2000 and which contain at least 5 mole %, relative to the polymer, of at least one structural element of the formula I or II ##STR1## in which and R' are independently alkylene, cycloalkylene, aralkylene or arylene, R.sup.1 is halogen, nitro, alkyl, alkoxy, alkylthio, phenyl or aralkyl, R.sup.2 is a direct bond, --O--, --S--, methylene, carbonyl or alkylidene, R.sup.3 is hydrogen, aroyl or defined as R.sup.1, and as integers a is 0 to 3, b is 0 to 4, c is 0 to 5, d is 0 to 5 and q is 0 or 1The polymers are sensitive to radiation and can be used for the production of protective coatings or photographic relief images.

Abstract: Photographic elements comprising at least one protective hydrophilic colloid layer comprising at least one urethane of polyethylene oxide compounds as antistatic agent in the form of dispersed droplets having an average diameter ranging from 1500 to 12000 nm and method of covering such photographic elements with at least one such protective hydrophilic colloid layer obtained by the steps of dissolving such urethane in a water-immiscible solvent medium, emulsifying the resulting solution in aqueous hydrophilic colloid, removing said water-immiscible solvent medium by evaporation to form the dispersed droplets in the aqueous hydrophilic colloid, and coating the latter as such or after having been mixed with additional hydrophilic colloid to form the protective hydrophilic colloid layer.

Abstract: A circuit pattern on a circuit board usually has a number of contact areas to which components are soldered. Some of the contact areas have holes extending through the board for insertion of leads of leaded components, the leads then being flow soldered to the contact areas. It often occurs that additional leaded components are to be mounted on the board after a first flow soldering step. However, holes through which the leads are to pass can be closed by solder. These holes are therefore masked mechanically, by a masking member which contacts the board at these holes, or by tape, or other such method. The present invention uses a conventional solder resist layer, usually applied prior to flow soldering, extending the solder resist layer over a part of the contact area to the periphery of the hole, the hole having an unplated bore or wall. The resist layer extends for at least part of the hole periphery.

Abstract: A method and composition for providing, in situ, a polymeric membrane for isolating hazardous materials within an area such as, for example, an asbestos removal job site. The polymer is applied in liquid form to surfaces which are to be protected. Upon cure, a seamless bladder-like membrane is formed which isolates the work area and prevents the spread of airborne, or water-carried particulate. The membrane can then be peeled from the surface and compacted for disposal.

Abstract: Composition for forming on an article a temporary protective covering and applicable in the form of an aqueous solution or dispersion, comprising at least one starch or starch derivative and at least one wetting agent.

Abstract: A composition for protection of the liquid surface from heat- and mass-trfer, for example from evaporation, contains a polymer limitedly swelling in the protected liquid or a mixture of said polymer with a neutral filler having a density lower than the density of the protected liquid.A method for protection of the liquid surface from heat- and mass-transfer comprising application of said composition on the surface of a liquid, for example petroleum, in an amount of from 0.1 to 2 kg per m.sup.2. Upon contacting of the polymer with the liquid the polymer rapidly swells and forms a continuous gel-like covering which hinders the heat- and mass-transfer on the liquid surface.

Abstract: Removable water-borne urethane resin coating composition comprising polyurethane resin containing carboxyl groups and/or carboxylate groups and polyvalent metal complex as a cross-linking agent and method for removing the coating formed by using the removable water-borne urethane resin coating composition which comprises treating said coating with a ligand containing alkaline solution and removing the coating.The coating formed by using the composition is superior in water resistance, recoatability, detergent resistance, black heel mark resistance, abrasion resistance and service life.

Abstract: Liquid, solvent-free, aqueous compositions for the removal of film-forming polymeric protective coatings. The compositions contain a combination of alkanolamines and hydrotropic substances acting as solution promoters. Optionally, pH-regulating acids, thickeners, surfactants, corrosion inhibitors, biocides and/or dyes are added.

Abstract: A solvent-resistant barrier coating is used beneath a polyurethane top coat, for example for coating aircraft. The barrier coating comprises a film-forming addition polymer comprising units of a vinyl aromatic monomer and units of a monomer containing a hydroxy alkyl group and a polyisocyanate containing at least 2 isocyanate groups per molecule. The addition polymer has a hydroxyl content in the range 0.5 to 5 percent by weight due to the presence of the hydroxy alkyl groups and preferably contains at least 30 percent by weight of the vinyl aromatic monomer. The ratio of isocyanate groups to hydroxyl groups is in the range 1:1 to 2:1. The polyurethane top coat can be removed from the substrate by a stripping solvent such as methylene chloride without removing the barrier coating.

Abstract: Disclosed is a maskless metal cladding process for plating an existing metallurgical pattern by utilizing a protective layer to isolate those areas of underlying metallurgy on which additional metal plating is not desired. The layer acts as an isolation barrier to protect the underlying metallurgy from deposition and subsequent diffusion of the heavy metal (e.g., gold) overlay. The composition of the protective layer is selected as one having sufficient mechanical integrity to withstand process handling and support the gold overlay and having the thermal integrity to withstand the high temperatures reached during metal sputtering and diffusion processes. The isolation barrier layer has an organic component as a binder which thermally decomposes, either in a heating step before metal deposition or during the diffusion cycle, leaving no carbonaceous residue but leaving an inert, inorganic standoff to support the metal.

Abstract: A partial painting method suitable for partially painting a workpiece or article of a complex surface shape. A surface of the workpiece is coated with strippable paint. The coated strippable paint is dried into a strippable film on the workpiece surface. A laser beam is applied to the strippable film along a prescribed cutting line so as to cut the strippable film. A portion of the strippable film corresponding to a first area of the workpiece surface to be painted is peeled off, while the remaining portion of the strippable film is left adhering on a second area of the workpiece surface to remain unpainted, and thereby masking of the workpiece is completed. The first area is then painted with a paint to form a final paint coating.

Abstract: A paint spray booth masking composition comprising:______________________________________ Ingredients % by weight ______________________________________ Water 30-50 Polyvinylpyrrolidone 2-30 Saccharide 16-60 Water-soluble surfactant 0.07-0.13 Preservative 0.05-0.

Abstract: An absorbent floor cleaning and waxing composition is disclosed comprising shreds of a hydrophilic, open-celled, solids-loaded polyurethane foam having an aqueous wax emulsion releasably incorporated therein. The composition is effective to replace soiled coatings of floor wax with fresh floor wax.

Abstract: A process for treating the interior surface area of a glass nozzle for use in an ink jet printer device. The process includes cleaning of the surface area with a hydrofluoric acid solution under controlled conditions, rinsing and then protecting the cleaned area with a blocking agent to prevent contamination by the atmosphere prior to use of the nozzle in a printer device. The disclosed process is useful in minimizing air bubble formation and lock within the nozzle during use, and in facilitating ejection or purging of such air bubbles as may become ingested by the nozzle during service.

Abstract: This invention is to a process for sizing textile materials by treatment with copolymers, and/or multipolymers, of acrylamide, the products thereby obtained and the sizing compositions used.

Abstract: An alkaline liquid composition is disclosed which is useful for restoring grout. The composition consists essentially of an aqueous dispersion of a film-forming polymeric resin, a compatible surfactant, a basic alkali metal salt, sodium hypochlorite, pigment, and an amount of zinc oxide effective to set the composition when it is coated onto and absorbed by the porous grout.

Abstract: A method is disclosed for protecting glass surfaces in a stack of glass sheets by treating the surfaces with a stain-inhibiting organic hydroxy acid and separating adjacent surfaces with an interleaving material.

Abstract: A method is disclosed for protecting glass surfaces in a stack of glass sheets by treating the surfaces with a mixture of stain-inhibiting organic acids which crystallize on the glass, and separating adjacent surfaces with an interleaving material.

Abstract: Method for preparation of metal-free strips in the metal vapor deposition of an insulating tape intended for use in electric capacitors, in which the insulating tape is covered, in the region of the metal-free strips to be prepared, by an endless cover tape which rests against the insulating tape and travels along with the same velocity as the former and is coated with oil on the side facing the metal evaporator before entering the vapor deposition zone. The invention is characterized by the features that first, the insulating tape and the cover tape are brought into contact with each other; that then by vapor deposition of oil, a film is prepared which also covers the lateral surfaces of the cover tape as well as slightly adjacent areas, and whereupon the metal vapor deposition takes place.

Abstract: Differential release coating compositions for use on liners of the type employed in the manufacture of pressure sensitive adhesive backed label transfer tape in roll form. The compositions in their preferred form comprise a binder, an aqueous solution of an organopolysiloxane, a catalyst, and an acrylic acid-acrylonitrile terpolymer.

Abstract: A method is disclosed for protecting glass surfaces in a stack of glass sheets by treating the surfaces with an organotin compound and separating adjacent surfaces with an interleaving material.

Abstract: A method for sealing a rim-like opening in a glass container is described. The surface of the opening is treated with tin and/or titanium oxide precursors and with or without one or more of the groups consisting of fluorides, sulfur oxides and sulfur oxide precursors and then overcoated with a chromium III organic metallic complex. A membrane comprising a thermoplastic film is pressed onto the coated opening surface and heated to cause glass-plastic adhesion, forming a closure. The coating steps may be applied to glass containers immediately after forming and annealing as appropriate, or may be applied to glass containers taken from storage.