Diamond-like Carbon Coating (i.e., Dlc) Patents (Class 427/249.7)
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Patent number: 12226044Abstract: An exterior material for cooking appliance capable of improving visibility, Vickers hardness, and scratch resistance by forming laser holes in a surface of an exterior material including a Diamond like carbon (DLC) coating layer, and a method for manufacturing the exterior material. The cooking appliance exterior material includes a base material, a Diamond like carbon (DLC) coating layer provided on the base material, an adhesive layer provided between the base material and the DLC coating layer to attach the DLS coating layer to the base material to incase an adhesion force between the base material and the DLC coating layer, and a plurality of laser holes provided in a surface of the exterior material.Type: GrantFiled: July 8, 2022Date of Patent: February 18, 2025Assignee: SAMSUNG ELECTRONICS CO., LTD.Inventors: Jiyoung Song, Hyunseok Shin, Youngdeog Koh, Kwangjoo Kim, Taegyeong Kim, Nohcheol Park
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Patent number: 12166066Abstract: A thin film laminate structure, an integrated device including the same, and a method of manufacturing the thin film laminate structure are provided. The thin film laminate structure includes two or more dielectric layers, wherein at least one of the dielectric layers of the thin film laminate structure includes a compound represented by Formula 1 and having a perovskite-type crystal structure having a B/B? composition ratio different from that of a remainder of the dielectric layers: AB1-xB?xO3??<Formula 1> wherein, in Formula 1, A, B, B?, and x are the same as defined in the specification.Type: GrantFiled: July 8, 2021Date of Patent: December 10, 2024Assignees: Samsung Electronics Co., Ltd., Seoul National University R&DB FoundationInventors: Kiyoung Lee, Kookrin Char, Byunghoon Na, Hahoon Lee, Dowon Song
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Patent number: 11746665Abstract: A method of operating a variable vane for a gas turbine includes the step of locating a first bushing at least partially surrounding a first trunnion that extends from a first end of the variable vane. The first trunnion includes an outer surface that has a plurality of troughs. The first bushing includes a plurality of peaks that extend inward from an inner surface. Relative movement is produced between the first bushing and the first trunnion to form a carbon transfer film between the first bushing and the first trunnion.Type: GrantFiled: May 27, 2022Date of Patent: September 5, 2023Assignee: RTX CorporationInventors: Pantcho P. Stoyanov, Mary E. Makowiec
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Component, in particular for a valve train system, and method for producing a component of this type
Patent number: 11739426Abstract: A component (100), in particular for a valve train system, having a substrate (3) and a layer system (1) applied at least in parts to the substrate (3), wherein the layer system (1) includes a friction-reducing and wear-reducing protective layer (2) for forming a component surface, wherein the protective layer (2) has at least one first sub-layer (4, 4a) made of doped tetrahedral amorphous carbon, which includes sp3-hybridized carbon having a mole fraction of at least 50%, wherein the first sub-layer (4, 4a) contains oxygen in a concentration in the range from 0.1 at % to 3.0 at % and hydrogen in a concentration in the range from 0.1 at % to 15 at %, and wherein the first sub-layer (4, 4a) has one or more of the following dopants in a concentration in the range from 0.03 at % to 15 at %: chromium, molybdenum, tungsten, silicon, copper, niobium, zirconium, vanadium, nickel, iron, silver, hafnium, fluorine, boron and nitrogen. A method for producing such a component (100) is also provided.Type: GrantFiled: September 2, 2019Date of Patent: August 29, 2023Assignee: Schaeffler Technologies AG & Co. KGInventors: Ricardo Henrique Brugnara, Nazlim Bagcivan, Edgar Schulz -
Patent number: 11661647Abstract: Artificial lift pump components such as couplings are disclosed, all having a body formed from a selected material, the body having an inner diameter and an outer diameter, a first surface treatment introducing carbon, nitrogen, boron into the material to form a first and hard layer, and a second layer defined as an deposited coating to the first layer that is also made of a carbon, nitrogen, or boron and is further characterized as being ceramic like (hard) and having a low-friction.Type: GrantFiled: September 10, 2019Date of Patent: May 30, 2023Assignee: SCHLUMBERGER TECHNOLOGY CORPORATIONInventors: Bing Han, Manuel Marya, Yuteng Liang
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Patent number: 11565971Abstract: The present application discloses compositions and methods for improving or enhancing the paving or re-paving of asphalt to road surfaces comprising the addition of the composition to the asphalt.Type: GrantFiled: January 24, 2019Date of Patent: January 31, 2023Assignee: COLLABORATIVE AGGREGATES, LLCInventors: John C. Warner, Laura Rose Muollo, Rowan Lewis Walker, Jason R. Bianchini
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Patent number: 11549033Abstract: A coating agent is capable of forming a coating film that has enhanced adhesion and adherence to a substrate, and enhanced water resistance as well and composed mainly of an aqueous material. A process of forming a coating agent uses the coating agent, a primer treatment process uses the coating agent, a process of doing repairs to concretes uses the coating agent, and a process of laying down roads uses the coating agent. The coating agent is composed mainly of a polyphenol derivative and containing a polymerizing agent, and has a pH of 9 or less. The polymerizing agent contains a compound having two or more functional groups selected from the group of an amino group and a mercapto group per molecule. In the process of forming a coating film, the coating agent is applied onto a substrate in an alkaline environment having a pH of greater than 9.Type: GrantFiled: August 21, 2018Date of Patent: January 10, 2023Assignee: NATIONAL INSTITUTE FOR MATERIALS SCIENCEInventor: Masanobu Naito
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Patent number: 11538653Abstract: The present invention discloses an ion beam lithography method based on an ion beam lithography system. The ion beam lithography system includes a roll-roll printer placed in a vacuum, and a medium-high-energy wide-range ion source, a medium-low-energy wide-range ion source and a low-energy ion source installed on the roll-roll printer. The ion beam lithography method includes: first coating a polyimide (PI) substrate with a dry film, etching the dry film according to a preset circuit pattern, then using the ion beam lithography system to deposit a wide-energy-range metal ion on the circuit pattern to form a film substrate, and finally stripping the dry film off the film substrate to obtain a printed circuit board (PCB).Type: GrantFiled: May 26, 2020Date of Patent: December 27, 2022Assignee: Beijing Normal UniversityInventors: Bin Liao, Xiaoping Ouyang, Jun Luo, Xu Zhang, Lin Chen, Pan Pang, Xianying Wu, Minju Ying
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Patent number: 10968518Abstract: Systems and methods for treating a carbon overcoat surface are described. In one embodiment, the method may include depositing a magnetic recording layer over a substrate, depositing a carbon overcoat layer over the magnetic recording layer, and exposing a carbon overcoat layer to water in gas phase after the carbon overcoat layer is deposited on the magnetic recording layer. In some cases, the method may include depositing a lubricant over the outer surface of the carbon overcoat after exposing the carbon overcoat layer to the water in gas phase.Type: GrantFiled: December 28, 2018Date of Patent: April 6, 2021Assignee: SEAGATE TECHNOLOGY LLCInventor: Paul M. Jones
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Patent number: 10458548Abstract: Provided is a piston ring having excellent low-friction properties and abrasion resistance manufactured without the need for precision control using an ordinary film formation device that does not have a special function.Type: GrantFiled: August 10, 2015Date of Patent: October 29, 2019Assignees: NIPPON ITF, INC., Honda Motor Co., Ltd.Inventors: Takehiko Ooshiro, Koji Miyake, Masanori Tsujioka, Satoshi Yoshida
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Patent number: 10406500Abstract: This invention relates to a production method for non-detonation synthesis nanodiamond by exposing carbonaceous feedstock to a dense plasma focus. The nucleated nanodiamond particles have characteristics that differentiate them from known forms of nanodiamond. For instance, the nucleated nanodiamond particles are substantially spherical and have a substantially smooth surface, as may be demonstrated by TEM. The nucleated nanodiamond particles are also free of graphite and detonation carbon contaminants. The identity of the nanodiamond particles has been confirmed through raman spectra, for example. The nanodiamond particles have also been found to be effective as a lubricant composition when combined with a carrier oil.Type: GrantFiled: August 15, 2017Date of Patent: September 10, 2019Inventor: Christopher J. Arnold
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Patent number: 9972490Abstract: A plasma stabilization method and a deposition method using the same are disclosed. The plasma stabilization method includes (a) supplying a source gas and (b) supplying a purge gas. The method may also include (c) supplying a reactive gas and (d) supplying plasma. The purge gas and the reactive gas are continuously supplied into a reactor during (a) through (d), and the plasma stabilization method is performed in a state where no substrate exists in the reactor.Type: GrantFiled: March 6, 2017Date of Patent: May 15, 2018Assignee: ASM IP Holding B.V.Inventors: Dong Seok Kang, Yo Chul Jang
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Patent number: 9957456Abstract: Provided is a carbon layer derived from carbide ceramics, wherein metal or non-metal atoms are extracted selectively from the surface of carbide ceramics to form voids, which, in turn, are filled with carbon synthesized by a carbon compound, thereby providing improved roughness and hardness, as well as to a method for preparing the same.Type: GrantFiled: November 19, 2013Date of Patent: May 1, 2018Assignee: KSM Co., Ltd.Inventors: Dae Soon Lim, Min-gun Jeong, Seo-hyun Yoon
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Publication number: 20150132539Abstract: A coated device comprising a body, a coating on at least a portion of a surface of the body, wherein the coating comprises, a terminal layer, and at least one underlayer positioned between the terminal layer and the body, the underlayer comprising a hardness of greater than 61 HRc, wherein prior to the addition of the terminal layer, at least one of the body and the underlayer is polished to a surface roughness of less than or equal to 1.0 micrometer Ra.Type: ApplicationFiled: August 28, 2014Publication date: May 14, 2015Inventors: Jeffrey R. Bailey, Srinivasan Rajagopalan, Mehmet Deniz Ertas, Adnan Ozekcin, Bo Zhao
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Patent number: 9004465Abstract: A helical compression spring, preferably of steel, in particular CrSi steel or CrNi steel, comprises a coating which has at least one a-C: H: Me coating or a plurality of layers of CrN (16) and a-C: H: Me coatings (14) alternately. In a method for coating a helical compression spring, preferably of steel, a plurality of layers of CrN and a-C: H: Me coatings are applied alternately.Type: GrantFiled: February 17, 2011Date of Patent: April 14, 2015Assignee: Federal-Mogul Burscheid GmbHInventors: Marcus Kennedy, Han-Rainer Brillert, Michael Zinnabold
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Patent number: 8993375Abstract: Method for synthesizing a material by chemical vapor deposition (CVD), according to which a plasma is created in a vacuum chamber in the vicinity of a substrate, and according to which a carbon-carrying substance and H2 are introduced into the chamber in order to produce in the chamber a gas comprising substances carrying reactive-carbon atoms in the form of unsaturated molecules or radicals from which the synthesis of said material will be performed, and in that the electromagnetic absorption and inelastic diffusion spectra of the solid material to be synthesized are used to take from these spectra the absorption frequencies that contribute to the reactions that lead to the formation of the solid material to be synthesized, and in that energetic rays are produced in the form of a photon beam carrying quantities of energy determined by each of the frequencies corresponding to said absorption and inelastic diffusion frequencies, said photon beam being injected into the plasma where, for energy states of the soType: GrantFiled: August 1, 2011Date of Patent: March 31, 2015Assignee: DiarotechInventor: Horacio Tellez Oliva
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Patent number: 8956510Abstract: The present invention relates generally to methods for producing metallic products comprising a substrate and a metallic, external coating. In preferred embodiments, the metallic products are jewelry articles.Type: GrantFiled: June 1, 2012Date of Patent: February 17, 2015Assignee: Frederick Goldman, Inc.Inventor: Andrew Derrig
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Publication number: 20150014569Abstract: A coated valve assembly includes a sleeve having a sleeve outer surface and a sleeve inner surface. Also included is a spool having a spool outer surface. Further included is a hardened surface formed on the sleeve inner surface and the spool outer surface. Yet further included is a coating disposed on the hardened surface of at least one of the spool outer surface and the sleeve inner surface, the second coating comprising a diamond-like carbon coating.Type: ApplicationFiled: February 28, 2014Publication date: January 15, 2015Applicant: Hamilton Sundstrand CorporationInventors: Kevin M. Rankin, Peter M. Ballard
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Publication number: 20150017468Abstract: An example of the coated tool disclosed herein includes a substrate, a metal layer established on the substrate, a continuous metal carbide layer established on the metal layer, and a smooth, continuous, terminated diamond like carbon (DLC) layer established on the metal carbide layer. The DLC layer is to prevent metal, from a workpiece upon which the tool is to act, from adhering to the tool.Type: ApplicationFiled: July 15, 2014Publication date: January 15, 2015Inventor: Michael J. Lukitsch
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Patent number: 8911867Abstract: The invention relates to a protective coating, having the chemical composition CaSibBdNeOgHlMem, wherein Me is at least one metal of the group consisting of {Al, Ti, V, Cr, Zr, Nb, Mo, Hf, Ta, W, Y, Sc, La, Ce, Nd, Pm, Sm, Pr, Mg, Ni, Co, Fe, Mn}, with a+b+d+e+g+l+m=1. According to the invention, the following conditions are satisfied: 0.45?a?0.98, 0.01?b?0.40, 0.01?d?0.30, 0?e?0.35, 0?g?0.20, 0?l?0.35, 0?m?0.20. The invention relates also to a coated member having a protective coating, as well as to a method for producing a protective coating, in particular a multilayer film for a member.Type: GrantFiled: June 18, 2009Date of Patent: December 16, 2014Assignee: Oerlikon Metaplas GmbHInventor: Jörg Vetter
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Patent number: 8822607Abstract: A substrate for biochips which has a high probe loading amounts and a uniform immobilization density, and which further has a high detection sensitivity and a high reproducibility by preventing a non-specific adsorption of proteins, when used as a substrate for biochips for immobilizing probes composed of biologically relevant substances such as proteins and nucleic acids, is disclosed. Amino groups can be bound to the surface of the substrate uniformly, at a high density and stably by covalently immobilizing an amino group-containing polymer on the surface of the substrate. The probe immobilization rate is high and immobilizing density was uniform by immobilizing a probe composed of a biologically relevant substance such as a protein or nucleic acid by utilizing the amino groups. Further, detection sensitivity and reproducibility are high by inhibiting non-specific adsorption of proteins.Type: GrantFiled: June 30, 2009Date of Patent: September 2, 2014Assignees: Hipep Laboratories, Nippon Light Metal Company, Ltd.Inventors: Kiyoshi Nokihara, Akiyoshi Hirata, Yasuo Oka, Yasushi Takebayashi
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Patent number: 8778295Abstract: Disclosed is a combinatorial synthesis of Diamond wherein a first reactive species is produced by catalytic treatment of Acetylene, a second reactive species is produced by decomposition of a hydrocarbon source having a low Hydrogen-to-Carbon ratio using a high energy discharge, and the two reactive species so obtained are combined in the vapor phase to yield Diamond without the need of post-treatments. The reaction is efficient and affords Diamond under mild conditions with high purity such that it may be useful for producing Diamond for semiconductor and microelectronics applications.Type: GrantFiled: August 5, 2011Date of Patent: July 15, 2014Inventor: Daniel Hodes
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Publication number: 20140193594Abstract: A metallic film formation target which is an object on which a diamond-like carbon film is to be formed is placed in a flow channel through which film formation gas containing methane gas flows. The film formation gas is caused to flow at a predetermined flow rate through the flow channel during the process of raising the temperature of the film formation target from room temperature to a predetermined temperature. The film formation gas is thereby reacted with impurities in a film formation target surface for removal of the impurities from the film formation target surface and is further reacted with metallic elements exposed by the removal of impurities, thus forming a diamond-like carbon film on the film formation target surface.Type: ApplicationFiled: June 18, 2012Publication date: July 10, 2014Applicant: The University of Electro-CommunicationsInventors: Katsumi Tanaka, Cheow Keong Choo
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Publication number: 20140178637Abstract: Provided are low friction coatings with improved abrasion, wear resistance and methods of making such coatings. In one form, the coating includes: i) an under layer selected from the group consisting of CrN, TiN, TiAlN, TiAlVN, TiAlVCN, TiSiN, TiSiCN, TiAlSiN and combinations thereof, wherein the under layer ranges in thickness from 0.1 to 100 ?m, ii) an adhesion promoting layer selected from the group consisting of Cr, Ti, Si, W, CrC, TiC, SiC, WC, and combinations thereof, wherein the adhesion promoting layer ranges in thickness from 0.1 to 50 ?m and is contiguous with a surface of the under layer, and iii) a functional layer selected from the group consisting of a fullerene based composite, a diamond based material, diamond-like-carbon and combinations thereof, wherein the functional layer ranges from 0.1 to 50 ?m and is contiguous with a surface of the adhesion promoting layer.Type: ApplicationFiled: December 21, 2012Publication date: June 26, 2014Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANYInventors: Srinivasan Rajagopalan, Tabassumul Haque, Mehmet Deniz Ertas, Adnan Ozekcin, HyunWoo Jin, Bo Zhao
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Patent number: 8747963Abstract: An apparatus and methods for forming a diamond film, are provided. An example of an apparatus for forming a diamond film includes an electrodeless microwave plasma reactor having a microwave plasma chamber configured to contain a substrate and to contain a reactant gas excited by microwaves to generate a microwave plasma discharge. Gas injection ports extend through an outer wall of the plasma chamber at a location upstream of the plasma discharge and above the substrate. Gas jet injection nozzles interface with the gas injection ports and are configured to form a directed gas stream of reactant gas having sufficient kinetic energy to disturb a boundary layer above an operational surface of the substrate to establish a convective transfer of the film material to the operational surface of the substrate.Type: GrantFiled: January 23, 2009Date of Patent: June 10, 2014Assignee: Lockheed Martin CorporationInventors: Mark Phillip D'Evelyn, John Dewey Blouch, Ludwig Christian Haber, Hongying Peng, David Dils, Svetlana Selezneva, Kristi Jean Narang
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Patent number: 8728571Abstract: Provided is a fabrication method for a functional surface that has self-cleaning ability and superhydrophilic anti-reflective property, which includes a) arranging a plurality of beads having a sphere shape on a surface of a transparent substrate; b) forming a predetermined inter-bead gap by etching the plurality of beads; c) forming a surface unevenness on the surface of the substrate by etching the substrate using the plurality of the beads having the predetermined gap as an etching mask; d) removing the plurality of the beads from the surface of the substrate; and e) forming a photocatalytic layer or a compound layer having a surface tension of 18 to 28 N/m on the surface of the substrate formed with the surface unevenness.Type: GrantFiled: July 28, 2010Date of Patent: May 20, 2014Assignee: Korea Institute of Machinery and MaterialsInventors: Hyuneui Lim, Seungmuk Ji, Jun-Hee Lee, Wan-Doo Kim
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Patent number: 8715789Abstract: A method and apparatus for plasma enhanced chemical vapor deposition to an interior region of a hollow, tubular, high aspect ratio workpiece are disclosed. A plurality of anodes are disposed in axially spaced apart arrangement, to the interior of the workpiece. A process gas is introduced into the region. A respective individualized DC or pulsed DC bias is applied to each of the anodes. The bias excites the process gas into a plasma. The workpiece is biased in a hollow cathode arrangement. Pressure is controlled in the interior region to maintain the plasma. An elongated support tube arranges the anodes, and receives a process gas tube. A current splitter provides a respective selected proportion of a total current to each anode. One or more notch diffusers or chamber diffusers may diffuse the process gas or a plasma moderating gas. Plasma impedance and distribution may be controlled using various means.Type: GrantFiled: December 16, 2010Date of Patent: May 6, 2014Assignee: Sub-One Technology, Inc.Inventors: Deepak Upadhyaya, Karthik Boinapally, William J. Boardman, Matthew MaMoody, Thomas B. Casserly, Pankaj Jyoti Hazarika, Duc Doan
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Patent number: 8715779Abstract: Apparatus, systems and methods for characteristics of glass components through use of one or more coatings are disclosed. The coatings are typically thin coatings, such as thin film coatings. The coatings can serve to increase strength of the glass components and/or provide durable user interfacing surfaces. Accordingly, glass articles that have received coatings are able to be not only thin but also sufficiently strong so as to resist damage from impact events. The coated glass articles are well suited for use in consumer products, such as consumer electronic devices (e.g., electronic devices).Type: GrantFiled: June 24, 2011Date of Patent: May 6, 2014Assignee: Apple Inc.Inventors: Anna-Katrina Shedletsky, Christopher Prest
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Patent number: 8641999Abstract: Plasma assisted chemical vapor deposition is used to form single crystal diamond from a seed and methane. A susceptor is used to support the seed. Under certain conditions, crystalline grit is formed in addition to the diamond. The crystalline grit in one embodiment comprises mono crystals or twin crystals of carbon, each having its own nucleus. The crystals form in columns or tendrils to the side of the monocrystalline diamond or off a side of the susceptor. The crystals may have bonding imperfections which simulate doping, providing conductivity. They may also be directly doped. Many tools may be coated with the grit.Type: GrantFiled: July 11, 2005Date of Patent: February 4, 2014Assignee: SCIO Diamond Technology CorporationInventors: Patrick J. Doering, Alfred Genis, Robert C. Linares, John J. Calabria
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Patent number: 8580336Abstract: A method of making a heat treated coated article includes forming at least one layer comprising diamond-like carbon (DLC) on a glass substrate, and forming a removable protective film on the glass substrate over at least the layer comprising DLC. The removable protective film includes first and second inorganic layers, the first inorganic layer comprising zinc oxide and nitrogen and being located between the layer comprising DLC and the second inorganic layer. The glass substrate may be heat treated so that during the heat treating the protective film prevents significant burnoff of the layer comprising DLC.Type: GrantFiled: December 13, 2012Date of Patent: November 12, 2013Assignees: Guardian Industries Corp., Centre Luxembourg de Recherches pour le Verre et al. Ceramique S.A. (C.R.V.C.)Inventors: Nestor P. Murphy, Maxio Frati, Rudolph H. Petrmichl, Jiangping Wang, Jens-Peter Muller, Herbert Lage
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Patent number: 8568827Abstract: The present disclosure is directed to a method of making a textured coating on a wear surface of a component. The method includes applying a mask on the surface and depositing a tribological coating on the surface. The method further includes removing the mask.Type: GrantFiled: May 17, 2010Date of Patent: October 29, 2013Assignee: Caterpillar Inc.Inventors: Shuangbio Liu, Chuong Quang Dam, Bao Feng, Dongyun Hua
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Patent number: 8518543Abstract: A sliding member is produced by forming hardening layers with two-layered structure on surface of a substrate metal with a Vickers hardness of not more than Hv300, such as aluminum or magnesium alloy for example, and then forming a DLC film having surface roughness defined as maximum height roughness Rz of 1 to 10 ?m further on the hardening layers. The above-described hardening layers are composed of a first hardening layer dispersed with heavy metal particles, preferably made of tungsten and/or tantalum in the substrate metal, and a second hardening layer formed under the first hardening layer.Type: GrantFiled: February 3, 2009Date of Patent: August 27, 2013Assignees: FujiWPC Co., Ltd., Fuji Kihan Co., Ltd.Inventors: Makoto Kano, Takahiro Horiuchi, Shinichi Takagi, Masao Kumagai, Eiji Shimodaira, Yoshio Miyasaka
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Patent number: 8518475Abstract: In certain example embodiments, a coated article includes respective layers including hydrogenated diamond-like carbon (DLC) and zirconium nitride before heat treatment (HT). During HT, the hydrogenated DLC acts as a fuel which upon combustion with oxygen produces carbon dioxide and/or water. The high temperature developed during this combustion heats the zirconium nitride to a temperature(s) well above the heat treating temperature, thereby causing the zirconium nitride to be transformed into a new post-HT layer including zirconium oxide that is very scratch resistant and durable.Type: GrantFiled: September 20, 2012Date of Patent: August 27, 2013Assignee: Guardian Industries Corp.Inventor: Vijayen S. Veerasamy
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Patent number: 8512807Abstract: A method of making cutting tool inserts with high demands on dimensional accuracy includes: mixing by milling of powders forming hard constituents and binder phase, forming the powder mixture to bodies of desired shape, sintering the formed bodies, grinding with high accuracy the sintered bodies to inserts with desired shape and dimension, optionally edge rounding of cutting edges, and providing the ground inserts with a wear resistant non-diamond or non-diamond-like coating. According to the method, the ground inserts are heat treated prior to the coating operation in an inert atmosphere or vacuum or other protective atmosphere below the solidus of the binder phase for such a time that the micro structure of the surface region is restructured without causing significant dimensional changes. In this way inserts with unexpected improvement of tool life and dimensional accuracy have been achieved.Type: GrantFiled: December 9, 2009Date of Patent: August 20, 2013Assignee: Seco Tools ABInventors: Bo Jansson, Jacob Sjolen
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Patent number: 8501276Abstract: Disclosed is a carbon film which has optical characteristics of retaining a high transparency and being high in refractive index and low in double refractivity, is excellent in electric insulating performance, can be applied to various base materials with good adhesiveness, and can be formed at low temperature. Also disclosed is a laminate including a carbon film and a method for producing the laminate.Type: GrantFiled: July 15, 2011Date of Patent: August 6, 2013Assignee: National Institute of Advanced Industrial Science and TechnologyInventors: Yoshinori Koga, Masataka Hasegawa, Sumio Iijima, Kazuo Tsugawa, Masatou Ishihara
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Patent number: 8496992Abstract: A method of coating a substrate, with the method comprising: providing a substrate; dispersing nanodiamond powder in a liquid to provide a coating precursor; converting the liquid of the coating precursor to a vapor; introducing the coating precursor to a vapor deposition process; and operating the vapor deposition process to produce a nanocrystalline diamond-containing nanocomposite coating on the substrate, the nanocomposite coating produced using the coating precursor and comprising the nanodiamond particles.Type: GrantFiled: December 10, 2010Date of Patent: July 30, 2013Assignee: Southwest Research InstituteInventors: Ronghua Wei, Christopher Rincon, Kent E. Coulter
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Patent number: 8430097Abstract: A medicinal inhalation device having a non-metal coating coated on at least a portion thereof, and onto which non-metal coating an at least partially fluorinated compound is then covalently bonded.Type: GrantFiled: November 6, 2008Date of Patent: April 30, 2013Assignee: 3M Innovative Properties CompanyInventors: Philip A. Jinks, Moses M. David, Rudolf J. Dams
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Publication number: 20130075977Abstract: Disclosed is a piston ring for an engine and a method of manufacturing the piston ring. The piston ring includes at least a Cr (Chromium) coating layer coated on a surface of a base material, and a Si-DLC (Silicon doped Diamond Like Carbon) coating layer coated on an outermost layer above the Cr layer and the base material. More specifically, the Si-DLC layer includes about 3 to 10 wt. % of Si.Type: ApplicationFiled: December 12, 2011Publication date: March 28, 2013Applicant: HYUNDAI MOTOR COMPANYInventor: Jeong Uk An
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Patent number: 8367207Abstract: The invention relates to a hydrogenated amorphous carbon coating and to a method for the production thereof. It also relates to devices having such a coating. The method of the invention consists in producing a hydrogenated amorphous carbon coating comprising at least two layers of hydrogenated amorphous carbon, each of said layers having chemical compositions and physical and mechanical properties that are identical, and with thicknesses that are identical or different. The coating of the invention finds many applications, in particular in the mechanical field for parts subject to considerable wear and rubbing problems. It may also be applicable, in particular, in the field of surgical implants and in the MEMS (microelectromechanical systems) field.Type: GrantFiled: October 20, 2008Date of Patent: February 5, 2013Assignees: Commissariat a l'Energie Atomique et aux Energies Alternative, Centre National de la Recherche ScientifiqueInventors: Caroline Chouquet, Cédric Ducros, Frédéric Sanchette
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Patent number: 8304063Abstract: A diamond-like carbon film for sliding parts which is applied to the sliding surface of sliding parts, the diamond-like carbon film including at least two layers, one being a lower layer of diamond-like carbon (referred to as DLC hereinafter) and the other being an upper layer of DLC placed thereon, wherein the lower layer has a hardness no lower than 20 GPa and no higher than 45 GPa, a Young's modulus no lower than 250 GPa and no higher than 450 GPa, and a thickness no smaller than 0.2 ?m and no larger than 4.0 ?m, and the upper layer has a hardness no lower than 5 GPa and lower than 20 GPa, a Young's modulus no lower than 60 GPa and no higher than 240 GPa, and a thickness no smaller than 1.0 ?m and no larger than 10 ?m. The diamond-like carbon film has both good durability and low frictional coefficient.Type: GrantFiled: December 1, 2008Date of Patent: November 6, 2012Assignee: Kobe Steel, Ltd.Inventors: Hirotaka Ito, Kenji Yamamoto
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Patent number: 8277622Abstract: The present invention relates to diamond material comprising a boron doped single crystal diamond substrate layer having a first surface and a boron doped single crystal diamond conductive layer on said first surface, wherein the distribution of boron in the conductive layer is more uniform than the distribution of boron in the substrate layer.Type: GrantFiled: January 22, 2008Date of Patent: October 2, 2012Assignee: Element Six Ltd.Inventor: Geoffrey Alan Scarsbrook
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Patent number: 8241713Abstract: A process for fabricating an amorphous diamond-like film layer for protection of a moisture or oxygen sensitive electronic device is described. The process includes forming a plasma from silicone oil, depositing an amorphous diamond-like film layer from the plasma, and combining the amorphous diamond-like film layer with a moisture or oxygen sensitive electronic device to form a protected electronic device. Articles including the amorphous diamond-like film layer on an organic electronic device are also disclosed.Type: GrantFiled: February 21, 2007Date of Patent: August 14, 2012Assignee: 3M Innovative Properties CompanyInventors: Moses M. David, Fred B. McCormick, Mark A. Roehrig
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Patent number: 8221832Abstract: A method of making a heat treated (HT) coated article to be used in shower door applications, window applications, or any other suitable applications where transparent coated articles are desired. For example, certain embodiments of this invention relate to a method of making a coated article including a step of heat treating a glass substrate coated with at least a layer of or including carbon and an overlying protective film including a zinc oxide inclusive layer. Following and/or during heat treatment (e.g., thermal tempering, or the like) the protective film may be removed. Other embodiments of this invention relate to the pre-HT coated article, or the post-HT coated article.Type: GrantFiled: October 7, 2010Date of Patent: July 17, 2012Assignees: Guardian Industries Corp., Centre Luxembourgeois de Recherches pour le Verre et la Ceramique S.A. (C.R.V.C.)Inventors: Nestor P. Murphy, Maximo Frati, Rudolph Hugo Petrmichl, Jiangping Wang, Jens-Peter Muller, Herbert Lage
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Publication number: 20120148762Abstract: The present disclosure relates to a method of coating a substrate, with the method comprising: providing a substrate; dispersing nanodiamond powder in a liquid to provide a coating precursor; converting the liquid of the coating precursor to a vapor; introducing the coating precursor to a vapor deposition process; and operating the vapor deposition process to produce a nanocrystalline diamond-containing nanocomposite coating on the substrate, the nanocomposite coating produced using the coating precursor and comprising the nanodiamond particles.Type: ApplicationFiled: December 10, 2010Publication date: June 14, 2012Applicant: SOUTHWEST RESEARCH INSTITUTEInventors: Ronghua Wei, Christopher Rincon, Kent E. Coulter
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Patent number: 8187722Abstract: An object of the present invention is to provide a copper foil with carrier sheet which permits releasing of the carrier sheet from the copper foil layer even when hot pressing at a temperature exceeding 300° C. is applied in the production of a printed wiring board. In order to achieve the object, a copper foil with physically releasable carrier sheet having a copper foil layer on the surface of the carrier sheet through a bonding interface layer, characterized in that the bonding interface layer is composed of a metal layer and a carbon layer. It is preferable for the bonding interface layer to be composed of a metal layer of 1 nm to 50 nm thick and a carbon layer of 1 nm to 20 nm thick.Type: GrantFiled: May 18, 2007Date of Patent: May 29, 2012Assignee: Mitsui Mining & Smelting Co., Ltd.Inventors: Seiji Nagatani, Hiroshi Watanabe, Kazufumi Izumida
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Publication number: 20120114964Abstract: Provided is a coated-surface sliding part having excellent adhesion of a hard coating, and a method for producing the same part. The coated-surface sliding part is a sliding part wherein a hard coating is formed by physical deposition on the surface of a base material formed from, by mass percent, C 0.5 to 0.8%, Si 0.1 to 1.5%, Mn 0.2 to 1.0%, Cr 8.0 to 13.5%, Mo and/or W 0.5 to 4.0% in terms of (Mo+ 1/2 W), and N 0.01 to 0.1%, with the remainder being Fe and impurities. The physically deposited coating is a titanium metal coating further covered by a diamond-like carbon coating. The method for producing a coated-surface part involves sputtering in order to apply the physically deposited coating, which consists of the titanium metal coating and then the diamond-like carbon coating which forms the surface layer, to the surface of the base material having the aforementioned composition. The base material is preferably subjected to argon gas bombardment prior to application of the physically deposited coating.Type: ApplicationFiled: July 13, 2010Publication date: May 10, 2012Applicants: HITACHI METALS, LTD., HITACHI TOOL ENGINEERING, LTD.Inventors: Fumiaki Honda, Kenji Yokoyama, Kenichi Inoue, Kunichika Kubota, Toshihiro Uehara, Takehiro Ohno, Katsuhiko Ohishi
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Patent number: 8119199Abstract: A method of making a window unit is provided which may result in improved yields. In certain example embodiments, the method involves coating a substrate with both (i) a solar control/management coating, and (ii) a protective layer (e.g., of or including diamond-like carbon (DLC)) over the solar control/management coating. The protective layer protects the coated substrate from scratches and/or the like during processing prior to heat treatment. Then, during heat treatment, the protective layer(s) is burned off in part or in whole. Following heat treatment, the coated article (substrate with solar control/management coating thereon) is coupled to another substrate in order to form the window unit.Type: GrantFiled: September 2, 2010Date of Patent: February 21, 2012Assignee: Guardian Industries Corp.Inventors: Scott V. Thomsen, Vijayen S. Veerasamy
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Patent number: 8119032Abstract: The invention provides methods functionalizing a planar surface of a graphene layer, a graphite surface, or microelectronic structure. The graphene layer, graphite surface, or planar microelectronic structure surface is exposed to at least one vapor including at least one functionalization species that non-covalently bonds to the graphene layer, a graphite surface, or planar microelectronic surface while providing a functionalization layer of chemically functional groups, to produce a functionalized graphene layer, graphite surface, or planar microelectronic surface.Type: GrantFiled: June 10, 2008Date of Patent: February 21, 2012Assignee: President and Fellows of Harvard CollegeInventors: Roy G. Gordon, Damon B. Farmer, Charles M. Marcus, James R. Williams
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Patent number: 8105660Abstract: A method of forming a diamond-like carbon coating by plasma enhanced chemical vapor deposition on an internal surface of a hollow component having an inner surface. A reduced atmospheric pressure is created within a pipe or other hollow component to be treated. A diamondoid precursor gas is introduced to the interior of the component. A bias voltage is established between a first electrode and one or more second electrodes. The first electrode is or is attached to the component. The second electrode is externally offset from an opening of the component, by a hollow insulator. A plasma region is established adjacent an inner surface of the component and extends through the hollow insulator. The precursor gas comprises at least one diamondoid. The pressure and bias voltage are selected such as to cause the deposition of diamond-like carbon on the inner surface.Type: GrantFiled: May 1, 2008Date of Patent: January 31, 2012Inventors: Andrew W Tudhope, William J Boardman, Steven F Sciamanna, Thomas B Casserly, Robert M Carlson
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Patent number: 8079428Abstract: Hardfacing materials include particles of polycrystalline diamond (PCD) material embedded within a matrix material. The PCD particles comprise a plurality of inter-bonded diamond grains. Material compositions and structures used to apply a hardfacing material to an earth-boring tool (e.g., welding rods) include PCD particles. Earth-boring tools include a hardfacing material comprising PCD particles embedded within a matrix material on at least a portion of a surface of a body of the tools. Methods of forming a hardfacing material include subjecting diamond grains to elevated temperatures and pressures to form diamond-to-diamond bonds between the diamond grains and form a PCD material. The PCD material is broken down to form PCD particles that include a plurality of inter-bonded diamond grains. Methods of hardfacing tools include bonding PCD particles to surfaces of the tools using a metal matrix material.Type: GrantFiled: July 2, 2009Date of Patent: December 20, 2011Assignee: Baker Hughes IncorporatedInventors: Nicholas J. Lyons, Danny E. Scott