Abstract: The present invention suppresses leakage of combustion gas from a contact surface. A cylinder head (20) is attached to a cylinder block. The surface (26) of the side of the cylinder head (20) that is attached to the cylinder block includes a first region (AH1) and a second region (AH2) that has higher hardness than the first region (AH1).

Abstract: A method of decorating a metal can body and comprising printing a fine pattern onto the can body using a non-varnishable ink, and applying a varnish over the printed fine pattern while the printed non-varnishable ink remains wet. The pattern is configured to give rise to a textured pattern in the varnish once the varnish has dried.

Abstract: A chemical resistant composite glove that includes a first polymeric layer in the shape of a glove; and a second polymeric layer disposed on the first polymeric layer, and wherein the first polymeric layer is specified for one class of chemical resistance and the second polymeric layer is specified for a second class of chemical resistance, and optionally a third polymeric layer, which may be a thin coating, disposed on at least one of first polymeric layer or the second polymeric layer and is optionally specified for a third class of chemical resistance.

Abstract: A molded article containing a crystal of a fluoropolymer. The fluoropolymer contains at least one selected from vinylidene fluoride/tetrafluoroethylene copolymer, polychlorotrifluoroethylene, an ethylene/tetrafluoroethylene copolymer, a tetrafluoroethylene/perfluoro(alkyl vinyl ether) copolymer and a tetrafluoroethylene/hexafluoropropylene copolymer. Further, the crystal is a nano-oriented crystal having a size of 300 nm or smaller.

Abstract: An adhesion promoter comprises a reaction product of: a) a polyepoxide; b) an aminosilane represented by the formula HNR1R2. R1 and R2 independently represent —Z—SiL3. Each Z independently represents a divalent linking group having from 1 to 12 carbon atoms, and each L independently represents a hydrolyzable group; and c) an isocyanatosilane represented by the formula O?C?N—Z—SiL3, wherein Z and L are as previously defined. The adhesion promoter may be used to treat a surface of a substrate such as an abrasive particle, which may be included in a resin-bond abrasive article.

Abstract: A method of producing a film-attached resin base may include supplying a surface treatment gas including at least fluorine gas to a resin base including reinforcing fibers so that embrittled regions are formed in a surface of the resin base and the reinforcing fiber present near the surface of the resin base is modified at least partially; removing at least the embrittled regions so that an uneven surface is formed on the resin base and the reinforcing fiber is at least partially exposed in the uneven surface; and forming a film onto the uneven surface of the resin base.

Abstract: A method of preparing a coated article includes providing an article and coating a surface of the article with a polymeric composition comprising poly(glycerol sebacate). In some embodiments, the composition is a poly(glycerol sebacate) copolymer.

Abstract: Disclosed is a manufacturing method of a liquid crystal display device which is a manufacturing method of a liquid crystal display device including a liquid crystal alignment film to which an alignment regulating force is imparted by a photo-alignment treatment, including: a film forming step of forming a film containing a polymer whose main chain is cleaved by irradiation with light; a photo-alignment step of imparting an alignment regulating force to the film formed in the film forming step by irradiation of the film with light in an atmosphere of a temperature lower than 100° C.; and a removing step of removing a low-molecular weight component generated by cleaving the main chain of the polymer through the light irradiation after the light irradiation. Also disclosed is a liquid crystal display device manufactured by the manufacturing method.

Abstract: A chemical resistant composite glove that includes a first polymeric layer in the shape of a glove; and a second polymeric layer disposed on the first polymeric layer, and wherein the first polymeric layer is specified for one class of chemical resistance and the second polymeric layer is specified for a second class of chemical resistance, and optionally a third polymeric layer, which may be a thin coating, disposed on at least one of first polymeric layer or the second polymeric layer and is optionally specified for a third class of chemical resistance.

Abstract: The present invention relates to a liquid (meth)acrylic syrup for impregnating a fibrous substrate. The present invention relates in particular to a viscous liquid syrup mainly containing methacrylic or acrylic components. The invention also relates to a process for manufacturing such a syrup. The invention also relates to a process for impregnating a fibrous substrate or long fibers with said viscous liquid syrup. The invention also relates to a fibrous substrate preimpregnated with said syrup, which is useful for manufacturing mechanical or structured parts or products. The present invention also relates to a manufacturing process for manufacturing mechanical or structured parts or articles and to three-dimensional mechanical or structured parts obtained by this process. The invention applies to the preparation of mechanical parts or structural elements made of fire-resistant thermoplastic composite material.

Abstract: A polymeric carrier composition including a polymer synthesized from monomers selected from acrylic acids, methylacrylates and urethanes and at least one metal having an oxidation state of +1 or +2, including salts and coordination complexes thereof. The composition may be a suspension having 0.5 to 10% by weight of the polymer prepared from monomers selected from a group consisting of acrylic acids, methylacrylates and urethanes, and a viscosity less than 1,000 cps. The composition is applied to substrates, such as woven fabrics, to create metal-infused articles.

Abstract: Polyhemiaminal (PHA) and polyhexahydrotriazine (PHT) materials are modified by 1,4 conjugate addition chemical reactions to produce a variety of molecular architectures comprising pendant groups and bridging segments. The materials are formed by a method that includes heating a mixture comprising solvent(s), paraformaldehyde, aromatic amine groups, aliphatic amine Michael donors, and Michael acceptors, such as acrylates. The reaction mixtures may be used to prepare polymer pre-impregnated materials and composites containing PHT matrix resin.

Abstract: A printed circuit board includes a laminate substrate. The laminate substrate includes catalytic material that resists metal plating except where a surface of the catalytic material is ablated. Metal traces are formed within in trace channels within the laminate substrate. The channels extend below the surface of the catalytic material.

Abstract: Disclosed is an antifogging film-forming material obtained by reacting, in the presence of a quaternary ammonium salt or quaternary phosphonium salt, a copolymer represented by a certain general formula with a multifunctional epoxy compound having a solubility of 40-100 mass % in 25° C. water. The antifogging film-forming material is characterized by having a weight average molecular weight of 100,000-5,000,000. With this material, it becomes possible to obtain an antifogging article excellent in antifogging property, heat resistance, chemical resistance and abrasion resistance.

Abstract: In one aspect, the present invention is directed to methods for modification of functionalized substrates. In another aspect, the invention relates to systems and methods for fabricating multilayer polymer compositions. In certain embodiments, the multilayer polymer compositions described herein can comprise heterobifunctional polymers and heterotrifunctional molecules.

Abstract: Diamine is used to enhance adhesion between polyurethane and polyolefinic material or ionomeric material.

Abstract: A multi-layered film, a backsheet for photovoltaic modules, a method of manufacturing the same, and a photovoltaic module are provided. The multi-layered film can be configured so that a resin layer including a fluorine-based polymer and an oxazoline group-containing polymer is formed on a substrate. As a result, the resin layer including the fluorine-based polymer can have excellent durability and weather resistance, and show high interfacial adhesive strength to the substrate. During the preparation of the multi-layered film, a drying process can also be performed at a relatively low temperature, so that the manufacturing costs can be reduced and the quality of the product can be prevented from being deteriorated by thermal deformation or thermal shock. The multi-layered film may be effectively used as the backsheet in a variety of photovoltaic modules.

Abstract: Some embodiments described herein relate to a substrate with a surface comprising a silane or a silane derivative covalently attached to optionally substituted cycloalkene or optionally substituted heterocycloalkene for direct conjugation with a functionalized molecule of interest, such as a polymer, a hydrogel, an amino acid, a nucleoside, a nucleotide, a peptide, a polynucleotide, or a protein. In some embodiments, the silane or silane derivative contains optionally substituted norbornene or norbornene derivatives. Method for preparing a functionalized surface and the use in DNA sequencing and other diagnostic applications are also disclosed.

Abstract: A device and a method for producing impregnated reinforcements, in particular for composite materials such as drive belts. The method for producing the reinforcements includes: introducing the reinforcement into an applicator device; introducing at least one substance for impregnating the reinforcement into the applicator device; and, embodying the impregnated reinforcement. The device comprises at least one applicator through which the reinforcement is guided and at least one intake for a substance for impregnation.

Abstract: A method for creating a formed-in-place seal on a fuel cell plate is disclosed. The method includes first dispensing a flowable seal material along a first sealing area of a fuel cell plate requiring the seal material. Next, a preformed template is located adjacent to at least a portion of the fuel cell plate, the template including predetermined apertures corresponding with a second sealing area of the plate, such that the apertures are coextensive with at least a portion of the first sealing area. Flowable seal material is applied into the apertures, and is then cured to a non-flowable state.

Abstract: A mold release treatment method of the present invention includes: the step of providing a mold releasing agent and a mold which has a porous alumina layer over its surface, the mold releasing agent containing a fluoric compound which has mold releasability and a solvent; the step of applying over the surface of the mold a solvent that is capable of dissolving the fluoric compound; and thereafter, the step of applying the mold releasing agent over the surface of the mold according to a spray coating method. According to the present invention, a mold release treatment can be performed over a surface of the mold which has the porous alumina layer over its surface, without causing uneven application.

Abstract: A method for enabling D2T2 printing onto non-D2T2 printable substrates uses a diffusible primer material provided on a dye-sheet or ribbon. The primer comprises a polymer, a release agent and a plasticizer. The release agent and the plasticizer are diffused into the substrate, while the polymer remains on the dye-sheet or ribbon. Printing of the primer onto the PC substrate is controlled via a computer image program corresponding to a colored image. This computer image program also controls the printing of the colored image at the primed locations. Accordingly, image-wise treatment of a plastic material via the primer selectively renders the PC substrate surface D2T2 printable at the point of personalization, providing for a 100% PC full card body having the colored image.

Abstract: A method of forming a seal includes preparing a froth from a one component polyurethane precursor, applying the froth to a surface of an article, and simultaneously applying water with the froth, the froth curing to form a gasket having a density not greater than 350 kg/m3 bonded to the article.

Abstract: The purpose of the present invention is to provide composite particulates and a method for manufacturing the composite particulates, the particulates including an organic substance and a metal having exceptional adhesiveness to a substrate, allowing easier control over metallic particle dispersion, facilitating control over electrical conductivity, and exhibiting high electroconductivity. The metallic particulates are characterized in that they have a thiol compound coordinated on the surfaces thereof, they are adsorbed onto a substrate with a silane compound interposed therebetween, and the thiol compound on the surfaces is subjected to oxidative polymerization, thereby yielding a structure in which an electroconductive polymer is coordinate-bonded to the surface of the metallic particulates.

Abstract: The invention relates to an aqueous sizing composition for reinforcing charges, preferably glass fibers, comprising a silane coupling agent, an epoxy film forming polymer comprising 2-8 reactive epoxy groups per chain and compatible with thermoplastic polyester matrix resin selected from PET and PBT, and a hypophosphite in an amount of 5 to 30 w % of the composition, preferably 7 to 25 w %, more preferably 10 to 20 w % and most preferably 12 to 18 w % of the composition. A thermoplastic polyester resin reinforced with glass fibers coated with a sizing composition of the invention shows improved resistance to staining and improved tensile elongation at break. The sizing composition further improves processability of the sized fibres.

Abstract: Compositions useful for improving the adhesion of coating compositions, such as dielectric film-forming compositions, include a hydrolyzed poly(alkoxysilane). These compositions are useful in methods of improving the adhesion of coating compositions to a substrate.

Abstract: Compositions useful for improving the adhesion of coating compositions, such as dielectric film-forming compositions, to a substrate are provided. Also provided are methods of improving the adhesion of coating compositions to a substrate.

Abstract: A method for forming a polymerized film on a surface of a non-conductive material and subsequently forming an electroless metal plating film on the surface is described. The method includes the step of contacting the surface of the material with a solution including (A) an amine compound having at least two functional groups, where at least one of the functional groups is an amino group, and (B) an aromatic compound having at least one hydroxyl group on the aromatic ring.

Abstract: Coated Fibrous Substrates The present invention provides a method of improving the adhesion of coatings to fibrous base materials. The method comprises treating a fibrous base material with one or more salt(s) of receptor species to provide a pre-coated fibrous base material comprising specific inorganic receptor sites within the fibrous base material. The one or more salt(s) of receptor species is selected from the groups comprising: (a) aluminium salts; (b) titanium salts; (c) zirconium salts; (d) iron salts; (e) soluble alkali silicates; or a combination thereof. The method further comprises coating the treated fibrous base material with a coating formulation comprising one or more compound(s) containing epoxy and alkoxysilane groups. The coating formulation acts as an adhesion promoter and cross-linker.

Abstract: The present disclosure is directed to systems and methods for adjusting adhesion strength between materials during semiconductor sensor processing. One or more embodiments are directed to using various surface treatments to a substrate to adjust adhesion strength between the substrate and a polymer. In one embodiment, the surface of the substrate is roughened to decrease the adhesive strength between the substrate and the polymer. In another embodiment, the surface of the substrate is smoothed to increase the adhesive strength between the substrate and the polymer.

Abstract: The present invention provides a surface-independent surface-modifying multifunctional biocoating and methods of application thereof. The method comprises contacting at least a portion of a substrate with an alkaline solution comprising a surface-modifying agent (SMA) such as dopamine so as to modify the substrate surface to include at least one reactive moiety. In another version of the invention, a secondary reactive moiety is applied to the SMA-treated substrate to yield a surface-modified substrate having a specific functionality.

Abstract: A thermal interface material (TIM) includes a modified release layer having an organosilane-coated surface covalently bound to a TIM formulation layer. The modified release layer may be formed by applying an organosilane (e.g., vinyltriethoxysilane) to the surface of a thermally conductive release layer (e.g., aluminum foil). The organosilane reacts with hydroxyl groups on the surface of the thermally conductive release layer. The TIM formulation layer may be formed by applying a TIM formulation (e.g., a graphite TIM formulation) containing an unsaturated monomer (e.g., methyl acrylate) to the organosilane-coated surface of the modified release layer, and then curing the TIM formulation so that the unsaturated monomer of the TIM formulation reacts with the organosilane-coated surface of the modified release layer.

Abstract: A multi-layered film, a backsheet for photovoltaic modules, a method of manufacturing the same, and a photovoltaic module are provided. The multi-layered film having excellent reliability and adhesive strength under high heat/moisture conditions and also showing excellent weather resistance and durability may be provided by forming a primer layer including an oxazoline group-containing polymer on a substrate and forming a resin layer including a fluorine-based polymer on the primer layer. The primer layer and resin layer of the multi-layered film may be manufactured at a low cost under a low drying temperature using a solvent having a low boiling point, so that the manufacturing costs can be reduced and the quality of the product can be prevented from being deteriorated by thermal deformation or thermal shock.

Abstract: An encapsulated particle includes a core particle, a polyurethane layer, and a wax. The polyurethane layer is disposed about the core particle and the wax is disposed about the polyurethane layer. The polyurethane layer includes the reaction product of an isocyanate and a polyol component. The polyol component includes a catalytic polyol derived from an aromatic amine-based initiator and a polyether polyol that is different from the catalytic polyol in a weight ratio of from about 1:2 to about 10:1. A method of encapsulating the core particle includes the steps of providing the core particle, the isocyanate, the polyol component, and the wax. The method also includes the steps of mixing and reacting the isocyanate and the polyol component to form a polyurethane, encapsulating the core particle with the polyurethane layer which comprises the polyurethane, and encapsulating the polyurethane layer with the wax.

Abstract: Molecular adsorption to the microfluidic device surfaces can be passively and actively mitigated by mixing certain hydrophilic polymers (organic polymers with repeating hydrophilic groups—the preferred polymers being amphipathic surfactants—with the sample liquid during or prior to relevant microfluidic operations. Nonionic surfactants such as polyoxyethylene sorbitan monooleate and polyoxyethylene octyl phenyl ether are especially effective. High molecular weight polyethylene polymers are also effective. The hydrophilic polymers appear to prevent binding of the fouling molecules to the microfluidic by occupying the surface sites in place of the fouling molecules or by interacting with the fouling molecules to prevent binding of the fouling molecules the surface. When surface adsorption is thus mitigated, microfluidic devices can readily handle samples containing biomolecules to enable active sample concentration, filtering, washing, transport, mixing and other sample handling operations.

Abstract: Provided among other things is a fabric comprising: a HPPE base fabric; coated thereon a primer polymer; and coated on the primer polymer a liquid-resistant polymer layer. The primer polymer can be a polyurethane. The base fabric can comprise an adhesion promoter that can be a plasticizer. The adhesion promoter can be a sulfonic acid plasticizer. The adhesion promoter can contain an active hydrogen, carboxy, carboxyloxy or acid group. The fabric can comprise, coated on the liquid-resistant polymer layer, an additional polymer layer. The additional polymer layer can comprise carnauba wax in an amount from about 1 to 3% Phr. The liquid-resistant polymer layer can be a NBR layer. In certain embodiments, the fabric shows no delamination of the liquid-resistant polymer layer after an adherence test. The primer layer can be a polyurethane layer. These features can be present in any combination.

Abstract: A composition for use in construction comprising pigment, dry cement and at least 30% powder polymer is provided. The composition has enhanced color retention and abrasion resistance and when applied to a surface the composition produces a smooth or textured, water-shedding properties that are aesthetically-pleasing. The coated surface as well as the method of preparing and applying the composition is also provided.

Abstract: The present invention provides a method of manufacturing a golf ball having a solid core formed of a rubber composition and a cover of at least one layer encasing the core, which method includes the steps of treating a surface of the core with a solution containing a halogenated isocyanuric acid and/or a metal salt thereof, and covering the treated core with a cover material. The invention also provides a golf ball obtained by such a method. Golf balls obtained by this method have a good feel and a good scuff resistance, and also have a high durability to impact.

Abstract: The field of the invention relates to systems and methods for surface treatments, and more particularly to systems and methods for surface treatments, modifications or coatings using micro- and nano-structure particles for both super-hydrophobic and super-oleophobic properties. In one embodiment, a method of treating surfaces to impart both super-hydrophobic and super-oleophobic properties includes the steps of pre-treating a substrate surface; assembling dual-scale nanoparticles onto the surface of the substrate; and treating the dual-scale nanoparticle coated surface with SiCl4 to cross-link the nanoparticles to each other and to the surface of the substrate creating a robust nano-structured topographic surface having both super-hydrophobic and super-oleophobic properties.

Abstract: The flexible sheet-like material comprises a textile layer, which is coated at least on one side with a functional layer which is permeable to gas but impermeable to the matrix material, acting as a barrier layer for the matrix material, and is produced by coating the textile layer directly with a foam or a paste.

Abstract: The invention relates to a process that makes it possible to improve the mechanical strength of bonds between substrates when these bonds are produced by means of an adhesive that comprises a resin that can be cured by chain polymerization, and in particular a resin that can be cured under the effect of ionizing or light radiation. This process is characterized in that it comprises the grafting of groups capable of acting as chain transfer agents during the polymerization of said resin to the surface of the substrates, before the latter are brought into contact with the adhesive. Applications: assembling of structural, engine, passenger compartment or bodywork parts in the aeronautical, space, railway, ship-building and automotive industries.

Abstract: Disclosed herein is an environmentally safe, grease and/or adhesion resistant article comprising an absorbent substrate, a cross-linking agent, and a polymer; wherein the substrate is first coated with the cross-linking agent and is then coated with the polymer.

Abstract: A method of manufacturing a sole according to the present invention includes the steps of obtaining a rubber part by previously crosslinking a polymer mixture containing 50 to 100 mass % of a diene-based polymer and 0 to 40 mass % of an acrylonitrile component in a polymer component of the polymer mixture, halogenating the rubber part, and bonding the rubber part and thermoplastic resin to each other by molding said thermoplastic resin on said rubber part.

Abstract: A golf ball including a thermoplastic core having an outer diameter of 1.51 inches to 1.59 inches; an outer cover layer; and an inner cover layer between the core and the outer cover layer. The thermoplastic core has been exposed to a gradient-initiating solution comprising a solvent, free radical initiator, and a reactive co-agent comprising a metal salt of an acrylic or methacrylic acid, a mono- or multi-functional acrylate or methacrylate, or having the chemical structure where R=linear, branched, or aromatic C1-C14 and n=1-5, such that the hardness of the outer surface is different than the hardness of the geometric center to define a positive or negative hardness gradient of 5 Shore C or greater.

Abstract: The present invention relates to an adhesion promoting cleaner solution for producing and adherent coating on a resinous substrate. The adhesion promoting cleaning solution comprises a telechelic diol in a carrier liquid such as an organic solvent. Also disclosed is a process of using the adhesion promoting cleaner solution to produce an adherent coating on a resinous substrate.

Abstract: A solid support for maintaining a uniform spot shape while improving the capacity for immobilization of nucleic acids upon spotting of nucleic acids onto a solid support is provided. A substrate has a base material, an electrostatic layer formed on the base material in order to electrostatically attract nucleic acids, and carboxyl groups formed on the electrostatic layer, wherein the ratio, (COO peak intensity)/(C—C peak intensity) in the C1s spectra obtained by X-ray photoelectron spectrometry (XPS) performed for the surface of the substrate ranges from 0.10 to 0.20. The solid support for immobilizing nucleic acids is produced by active esterification of carboxyl groups of the substrate.

Abstract: The present invention relates to “grafting to” methods of modifying materials surfaces with high-density polymer brushes. A method of the present invention comprises contacting in succession or simultaneously an activated material surface, a solution of a polymeric material having a polymeric backbone with pendant reactive moieties, and a melt of brush-forming terminally-functionalized polymer chains, in order to allow a covalent bonding reaction to occur between surface and polymers, wherein upon completion of the reaction, the polymeric material forms a layer between the material surface and the brush polymer chains.

Abstract: The invention relates to a method for preparing a foam composite element, including the steps of preparing a top layer, applying an adhesion promoter layer to the top layer, wherein the adhesion promoter layer includes a modified isocyanate, and applying a foam layer including polyurethane and/or polyisocyanurate to the adhesion promoter layer. On application, the modified isocyanate in the adhesion promoter layer has a content of free isocyanate groups of from ?10% to ?29%. The invention further relates to the use of a modified isocyanate having a content of free isocyanate groups of ?10% to ?29% as an adhesion promoter in the preparation of foam composite elements and foam composite elements obtained by the method according to the invention.

Abstract: The invention relates to a method for producing a coated aluminium strip, in which the aluminium strip is unwound from a coil and fed into a unilateral or bilateral extrusion coating arrangement, the aluminium strip is extrusion coated with a thermoplastic polymer and after being extrusion coated, the aluminium strip is reheated to a metal temperature above the melting point of the thermoplastic polymer. The object of providing a method for producing an aluminium strip by which an extrusion-coated aluminium strip can be produced which can be processed at high processing speeds in follow-on composite tools is achieved in that the unilateral or bilateral plastics material coating of the aluminium strip is textured, after being reheated, using rolls which have a superficial structure.

Abstract: The invention discloses an adhesion agent composition comprising at least one C3-C200 olefin compound having at least one metathesis active double bond, wherein the olefin is substituted or unsubstituted; and at least one compatibilizing functionality for interacting with a substrate surface. The substrate surface can be any surface, for example, silicate glasses, silicate minerals, metals, metal alloys, ceramics, natural stones, plastics, carbon, silicon, and semiconductors. The invention also discloses articles of manufacture utilizing these adhesion agents as well as methods for adhering a polyolefin to a substrate surface.