Abstract: The present invention is directed to a method for improving the adhesion of epoxy resins to steel substrates which comprises first removing the oxide surface layer, preferably by chemical means, and then pretreating the substrate with a solution of at least one coupling agent selected from the group consisting of .beta.-diketones and mercaptoesters. The invention also provides a method for improving the adhesion of epoxy resins to steel substrates by pretreating with citric acid or a salt thereof.

Abstract: A method of curing an anaerobic resin, which primarily contains acrylic resin, includes externally catalyzing the cure of the resin with a metal-beta keto ester complex having the structural formula: ##STR1## where M is a transition metal; R.sub.1 is selected from the group consisting of alkyl groups having from 1 to 20 carbon atoms, benzene, naphthalene, anthracene, and hydrocarbon substituted aromatic; R.sub.2 and R.sub.3 are selected from hydrogen, alkyl groups having from 1 to 20 carbon atoms, benzene, naphthalene, anthracene and hydrocarbon substituted aromatic; R.sub.4 is selected from alkyl groups having from 1 to 20 carbon atoms; and n is equal to the valence of the metal M.

Abstract: A method is disclosed for preparing an oleophilic drafting film and related light-sensitive reprographic member. An aqueous drafting composition is disclosed which is both compatible with hydrophobic material and diazo light-sensitive compositions which provides for an expedient method of fabricating drafting film. The drafting composition comprises an acrylic resin emulsion containing an aziridine hardening agent.

Abstract: Heat-sealable films are described which are constituted by a polyolefin film, particularly polypropylene, having on one surface thereof a layer of primer, applied in aqueous or aqueous-alcoholic solution, and chosen from: polyethylenimines, products of the condensation of urea or melamine with formaldehyde, particularly the etherified compounds; alkoxyalkyl melamine polyhydroxylates; or mixtures of the said compounds; and, on the other surface thereof, a layer of the said primer or one similar to the first, followed by a layer of vinyl, vinylidene or acrylic polymer or copolymer.

Abstract: Various substrates can be coated with cured liquid epoxy resin compositions using a modified two-package system by first painting the substrates with a catalyst having the formula Sn(CF.sub.3 SO.sub.3).sub.2 and then contacting the painted substrates with the resin composition. In this scheme considerable time can elapse between preparation of the painted substrates and their contacting of the resin composition.

Abstract: The invention relates to a new process for the shatterproof coating of glass surfaces by coating the surfaces with a coating composition based on a two-component system reacting fully to form a polyurethane, the glass surfaces to be coated being coated before application of the coating composition with a physically drying priming lacquer containing a silane adhesion promoter and a catalyst which accelerates hardening of the coating composition and, as binder, a polyurethane polyurea which has a linear molecular structure and which is soluble in lacquer solvents.

Abstract: Novel, improved adhesive compositions curable at ambient temperature to form adhesive bonds between opaque, impervious, substrates without external application of heat, light or other radiation. The adhesive compositions of this invention comprise one or more ethylenically unsaturated monomers, a source of free radicals, and an activator comprising an azine dye material or the reaction product of an azine dye material with a reducing agent.

Abstract: A method for bonding unvulcanized fluorinated elastomers to vulcanized non-fluorinated elastomers comprising exposing the vulcanized elastomer to a fluorinating agent; applying a conventional fluorinate elastomer adhesive to the treated vulcanized elastomer; contacting the adhesive-coated portion of the vulcanized elastomer with the unvulcanized fluorinated elastomer; and curing in situ the fluorinated elastomer. Sulfur tetrafluoride is a preferred fluorinating agent.

Abstract: A decorative simulated ceramic tile comprises a substrate having a surface coated with an under-coat effective to provide a colored, printable base; an inked layer comprising a layer of colored ink lines of a silicone-containing drying ink forming a printed pattern on said printable base, said printed pattern being clearly visible; and a coloring pigment-containing top coat of a hard resinous, film-forming material; said top coat having a variable height thickness defining a contour of valleys, hills and plains, wherein the intensity of color in the top coat varies with the variation in the contour, the said valleys occurring over said ink lines such that the color of the ink is not obscured, and the hills lying adjacent said ink lines, said color in the top coat providing a contrast with the color in the under-coat and with the color in the printed pattern.

Abstract: The adhesion of brass plated steel cord to rubber is improved by treating the cord in a dilute acidic alcohol dip followed by treatment with H.sub.2 S gas or by treating the cord in a dilute aqueous ammonia dip, preferably followed by treatment with H.sub.2 S gas, before combining the cord with a vulcanizable rubber compound and vulcanizing the same.

Abstract: A method of treating inorganic materials such as metals to ensure strong adhesion of a subsequently applied coating of another material, such as a paint, comprises the steps of applying to a surface of the material a composition containing a complexing agent comprising both a sulph-hydro and a carboxylic acid group and applying over the complexing agent a film-forming coating which also contains a complexing agent comprising both a sulph-hydro and a carboxylic acid group and/or an anti-oxidant.

Abstract: A primer composition for portland cement concrete comprising the reaction product of polyphosphoric acid and an alcohol.

Abstract: A method of improving the bond between dissimilar synthetic polymeric materials, such as, for example, a vinyl resin material and a polyurethane or acrylated polyurethane resin material which comprises: including in the vinyl resin material a chemical compound possessing hydroxy, carboxy, amido, amino, imino, mercapto, or like functions containing reactive hydrogen; providing free, available isocyanate in the polyurethane or acrylated polyurethane resin material; bringing the vinyl resin material and the polyurethane or acrylated polyurethane resin material into contact; and exposing the vinyl resin material and the polyurethane, or acrylated polyurethane resin material, while in contact, to curing conditions, whereby there is sufficient chemical inter-reaction between these resin materials as to create a strong and permanent primary chemical bond therebetween, in addition to any secondary bonds, such as hydrogen bonds and/or van der Waals forces.

Abstract: A method of repairing damage to a porous refractory material coated with a glass coating (16) comprising applying hydrolyzed tetraethyl orthosilicate to the damaged area, curing said tetraethyl orthosilicate, applying to said damaged area a pliable filler (30) comprised of hydrolyzed tetraethyl orthosilicate and powdered refractory substrate (11) and heating the damaged area to cure filler (30).

Abstract: A method is described for achieving full cure of a peroxide cured polyester resin in the presence of rubber, which method is based on the discovery that there is competition between the uncured resin and the rubber surface for the peroxide curing agent present adjacent to the rubber/resin interface. The method has several embodiments, including: (1) utilizing a low surface activity rubber, (2) deactivating the surface of a high surface activity rubber, (3) utilizing a peroxide material at the interface, (4) utilizing a material with which the rubber surface reacts preferentially, and (5) utilizing a "rapid cure" for the polyester. Also described is a laminate of rubber and polyester resin formed by this method.

Abstract: A decorative simulated ceramic tile comprises a substrate having a surface coated with an under-coat effective to provide a colored, printable base; an inked layer comprising a layer of colored ink lines of a silicone-containing drying ink forming a printed pattern on said printable base, said printed pattern being clearly visible; and a coloring pigment-containing top coat of a hard resinous, film-forming material; said top coat having a variable height thickness defining a contour of valleys, hills and plains, wherein the intensity of color in the top coat varies with the variation in the contour, the said valleys occurring over said ink lines such that the color of the ink is not obscured, and the hills lying adjacent said ink lines, said color in the top coat providing a contrast with the color in the under-coat and with the color in the printed pattern.

Abstract: A method of improving the bond between dissimilar polymeric materials, such as, for example, a vinyl resin material and a polyurethane or acrylated polyurethane resin material, which comprises: including in the vinyl resin material an acrylate or an acrylated urethane; providing in the polyurethane or acrylated polyurethane resin material an organic peroxide or other UV or thermal activated free radical initiators; bringing the vinyl resin material and the polyurethane or acrylated polyurethane resin material into contact; and exposing the vinyl resin material and the polyurethane or acrylated polyurethane resin material, while in contact, to curing conditions in the presence of said organic peroxide or other UV or thermal activated free radical initiators, whereby there is sufficient chemical interreaction between these resin materials as to create a strong and permanent primary chemical bond therebetween, in addition to any secondary bonds, such as hydrogen bonds and/or van der Waals forces.

Abstract: An electrical laminate comprising layers of a polyester resin-impregnated fibrous cellulosic substrate is disclosed. The substrate is preimpregnated with a nitrogen-containing composition having (a) an N-methylol or N-lower alkoxymethyl group attached to said nitrogen atom, and (b) an unsaturated group capable of copolymerizing with a cross-linking monomer present in the polyester resin.

Abstract: The composite material, which is a solid porous carrier, whose pores are filled with a polymer, a polyolefin having the molecular weight not less than 300,000, the degree of pore filling with said polymer being at least 4 percent of the total volume of the pores, in which the ratio of the carrier mass to the mass of the polymer is 50-99.5:50-0.5. The method of producing said composite material consists in precipitation, from the gas phase, of a complex organometallic catalyst consisting of a compound of a transition metal and of an organic compound of a metal in the 2nd or 3rd group of the Periodic Table, inside the pores of a solid porous carrier, and in polymerization of olefins from the gas phase on said catalyst, precipitated in the pores of the solid porous carrier, at a temperature of 50.degree.-165.degree. C. and a pressure of 1-60 atm. The composite material is characterized by high mechanical strength (compression strength reaching 100-200 kg/sq.cm) high frost resistance, and hydrophobic properties.

Abstract: Cotton, or other fabric containing cellulose, is treated with acrylamide and a chemical initiator that promotes reaction of acrylamide with cellulose. The fabric, with bound acrylamide, is then treated with glyoxal and an acidic, metal salt catalyst to produce a fabric containing crosslinked cellulose. Thus, the fabric is given wrinkle resistance and durable-press properties by the treatment without using formaldehyde, free or combined, that could be released during treatment or from the treated fabric.

Abstract: An improvement in the method of preparing a glass-reinforced elastomeric product whereby cord blows may be eliminated. The method includes treating the glass fabric with a dip which improves adhesion to the rubber, and calendering the glass fabric and the rubber compound. The improvement comprises the step, prior to the calendering, of applying to the glass fabric an overdip composition including an effective amount of a material which is a cure accelerator for the rubber, whereby the amount of time required for full cure, and compaction of the rubber compound is reduced.

Abstract: Adhesive composition based on acrylate monomers and a peroxide, together with selected halogenated aliphatic acids, which is storage stable and can be used as an anaerobic adhesive composition and a method of bonding by use of that adhesive to quickly form adhesive bonds to steel, copper, zinc and brass without use of a primer, which bonds do not lead to significant corrosion of the metals.

Abstract: A method of improving the bond between a vinyl resin material and a polyurethane or acrylated polyurethane resin material which comprises coating a fused vinyl resinous layer with an aqueous acetic acid solution, drying the aqueous coating, applying an uncured polyurethane or acrylated polyurethane layer to the coated surface of the vinyl resin material and exposing the vinyl resinous composition layer and the uncured polyurethane or acrylated polyurethane resin layer to curing conditions to develop a strong and permanent bond between the two layers.

Abstract: A method of producing a magnetic recording layer on a support comprising simultaneously depositing a ferromagnetic material and a polymer on a support using a vapor deposition technique such as vacuum deposition, sputtering, etc., thereby to produce thereon a magnetic recording layer of a composite film of the ferromagnetic material and the polymer. A further embodiment for producing a magnetic recording layer comprises simultaneously depositing a ferromagnetic material and a monomer or oligomer on the support using a vapor deposition technique, polymerizing the deposited layer, e.g., using a polymerization catalyst or by applying ionizing or electromagnetic rays thereto, to form a composite film of the ferromagnetic material and the polymer. The magnetic recording layer thus obtained in either embodiment can be used for high density recording.

Abstract: A layer of a liquid composition containing an epoxide resin as the sole photopolymerizable component, a heat-activated curing agent for epoxide resins, and preferably a photopolymerization catalyst, is exposed to actinic radiation until the layer solidifies to form an essentially solid, continuous film due to photopolymerization of the epoxide resin through epoxide groups, the resin remaining, however, still thermosettable by virtue of residual epoxide groups. The film so formed is contacted with fibrous reinforcing material and caused to flow about the fibers, suitably by applying heat and pressure, to form a prepreg. When desired, e.g., after the prepreg has been formed into some desired configuration or layers of prepreg have been stacked, the assembly may be cured by further heating.

Abstract: According to the invention, the method for applying a polymer coating onto the surface of a solid filler comprises deposition of a complex organometallic catalyst, containing a compound of a transition metal and an organic compound of a metal of the second or third groups of the periodic system, on the surface of the solid filler and liquid- or gas-phase polymerization of olefins at a temperature of 50.degree. to 170.degree. C. and a pressure of 1 to 60 atm on said catalyst deposited on the surface of the solid filler. The deposition is carried out in two stages. The first stage is gas-phase deposition of the first component of the catalyst, i.e. a compound of a transition metal, on the surface of the solid filler. The second stage is gas- or liquid-phase deposition of the second component of the catalyst, i.e. an organic compound of a metal of the second or third group of the periodic system.

Abstract: Decorative articles having a three-dimensional patterned surface are formed employing the different surface tension properties of a wet ink printed pattern and a liquid top coat composition; the difference in surface tension is such that the liquid top coat composition retracts from the wet ink pattern; subsequently the ink is dried and the top coat is dried and cured.

Abstract: Reduced odor is achieved in certain reactive fluid adhesive compositions while maintaining adequate adhesive properties by using higher molecular weight (C.sub.10 -C.sub.18) acrylic and methacrylic ester monomers in combination with minor quantities of diacrylate or dimethacrylate monomers, instead of lower molecular weight acrylic and methacrylic ester monomers generally used in such adhesives.

Abstract: A composite antistatic coating film comprising a first layer obtained by condensing a hydrolyzed partial condensate of an alkyltrialkoxysilane on the surface of a substrate and a second layer obtained by condensing a hydrolyzate or a hydrolyzed partial condensate of a tetrafunctional silicon compound, a chloropolysiloxane or an alkoxypolysiloxane on the first layer.

Abstract: A method for the coating of glass surfaces in order to prevent the scattering of glass particles upon bursting, with a transparent, duroplastic protective coat by depositing a paste of hydroxy group-containing 1,2-epoxy compounds with at least one 1,2-epoxide group in the molecule and a lower melting point of more than 40.degree. C. and hardening agents, and hardening the overlay at higher temperatures; which comprises first treating the clean glass surface with an aqueous or alcoholic silane skim coat, drying said surface if necessary and thereafter warming said surface to a temperature up to 120.degree. C.

Abstract: Pipe sections of polyester fiberglass, epoxy fiberglass or of other diverse or same materials are adhesively joined together or to reaction vessels by applying to one mating surface an adhesive composition comprising a solution of non-reactive elastomer as for example, butadieneacrylonitrile rubber dissolved in a mixture of polymerizable acrylic monomers and acrylic acid monomer such as methyl methacrylate and acrylic acid, containing a polymerization catalyst such as benzoyl peroxide, and applying to the other mating surface a tertiary amine activator, bringing the mating surfaces together and allowing the adhesive to cure to a set. In another embodiment the tertiary amine is encapsulated in a rupturable microsphere and dispersed in the adhesive composition. The microspheres may be ruptured before or after the adhesive is applied.

Abstract: An article of clothing, particularly a glove, which is highly resistant to chemical warfare agents, comprising a fabric substrate, normally pre-shaped to form the article, which is coated with an inner layer of a resilient elastomer, such as natural rubber, deposited from a latex, which adheres to but does not penetrate the substrate, and then coated with an outer layer of a butyl rubber which may contain an inorganic filler. The fabric substrate provides wearer comfort while the combination of an inner layer having a high vapor retention capacity and an outer layer which is resistant to toxic chemicals in liquid form and has a low vapor permeability, provides a high resistance to toxic chemicals for periods of time not heretofore possible.

Abstract: A disc-shaped information carrier for high-density storage, in particular for video signals, has the information provided on both sides of the carrier and stored in the form of a beam-relfecting surface structure which is covered by a layer of translucent material. A disc-shaped base element is formed by injection molding, pressing, stamping or the like to exhibit a surface structure corresponding to the information to be stored on both sides thereof. Each side has a thin metallic coating applied thereto which maintains the same surface profile and the information structure is protected on each side with a layer of transparent material.

Abstract: A decorative simulated ceramic tile is produced in a method which comprises applying to a flat surface of a non-metallic, porous substrate, an under-coat effective to seal the surface and provide a colored, printable base; printing on the printable base a pattern composed of ink lines of a colored drying ink containing 0.75 to 5% by weight of an organic silicone oil, and allowing the ink to dry; applying to the printable base, a coloring pigment-containing liquid top coat containing from 0.75% to 2.

Abstract: Disclosed is a method of bonding two fluoropolymer membrane sheets. According to the disclosed method, a third sheet is contacted with a base and then interposed between the two membrane sheets. The two membrane sheets may also be contacted with a strong base. The resulting sandwich of three sheets is heated and pressed to effect the bond.

Abstract: A method for coloring inorganic substrates such as glass beads, glass fibers, mineral wool, rock wool, mineral fiber boards and cloths, concrete molded materials, inorganic pigments and metallic powders, which comprises treating the inorganic substrate with (1) a cationic component comprising(a) a water soluble cationic resin or an aqueous solution of a water soluble cationic resin,(b) an aqueous solution of a water soluble cationic resin and a water soluble cationic dye, or(c) an aqueous dispersion of a water soluble cationic resin, a cationic dispersing agent plus a water insoluble dye or pigment and, optionally, a cationic water soluble dye; andWith (2) an anionic component comprising(d) an aqueous solution of a water soluble anionic dye,(e) an anionic dispersing agent or an aqueous solution of an anionic dispersing agent,(f) an aqueous solution of an anionic dispersing agent and a water soluble anionic dye, or(g) an aqueous dispersion of an anionic dispersing agent plus a water insoluble dye or pigment an

Abstract: This invention relates to the production of composites of organic polyisocyanate plastics and metals. The metals are pretreated with certain adhesion promoters in order to increase adhesion between the metal and the plastic. The pretreated metal sheet or foil is brought into contact with the reaction mixture during the chemical reaction while the plastic is being formed.

Abstract: A coagulation process for coating various substrates with organic resins which may be admixed with reactive or nonreactive particles. The process comprises (A) providing the substrate to be coated with a dry coagulating compound surface and (B) exposing said substrate to an aqueous bath comprising an organic film forming material, at least fifty (50) weight percent of which is a chemically ionizable organic film-former which (i) has at least 12 carbon atoms per molecule; (ii) is at least partially ionized such that it is substantially soluble in said aqueous bath; and (iii) coagulates in the presence of said coagulating compound.

Abstract: Perfluorinated functionalized materials are disclosed which are prepared by simultaneous perfluorination and functionalization. A wide variety of materials can be used including polymers and other branched or straight chain hydrocarbons. The material to be perfluorinated is placed in a direct fluorination apparatus and a mixture of fluorine and oxygen is passed over the material using La-Mar direct fluorination techniques. With materials such as polyethylene or polypropylene, pendant alkyl groups are converted to either acid fluoride groups or perfluoroalkyl groups, with the exact ratio of each being dependent upon the specific fluorine-to-oxygen ratio used.

Abstract: A process for producing a strong and water-resistant bond between aluminum or an aluminum-based alloy and a polysulphide material by means of a primer which is applied to the metal, characterized in that the primer is a solution of a strongly basic alkali metal compound such as alkali metal hydroxides, phosphates and carbonates. The present invention also includes articles treated by the aforementioned process.

Abstract: Compositions that may be used as primers for bonding silicone elastomers to porous substrates which are obtained from the reaction of an acrylate and an acryloxyalkylakoxysilane in the presence of a free radical initiator and an organic solvent.

Abstract: The discoloration of finishes derived from coating compositions containing polyarylene sulfide resin can be significantly reduced by applying to the substrate a citrate, carbonate, sulfate or hydroxide of an alkali metal prior to applying the polyarylene sulfide resin composition.

Abstract: A method of imparting flame retardant character to cellulosic containing material by applying an effective fire retarding imparting amount of a phosphorous composition to the material and curing the phosphorous composition, the improvement comprising pretreating the material with an aqueous caustic solution prior to applying the phosphorous composition, wherein the material contains at least 20% polyester.

Abstract: A coating composition consisting essentially of certain heat-stable polymers, colorants, oxidation catalysts, and liquid carrier useful for coating an article to produce a finish which is capable of having a decorative pattern produced within it is provided.

Abstract: This invention is concerned with a process for bonding a durable low surface energy polymeric coating to a metal or oxide surface. The metal or oxide surface is first treated with an alkali, thereby maximizing the hydroxide ion concentration on the surface, and then in a rigorously dry state with a rigorously dry fluorinated material to form the polymeric coating. The fluorinated material has the formulaRf -- O -- (CH.sub.2).sub.n -- SiX.sub.3wherein Rf is a fluorinated lower alkyl group, n is an integer from 2 to 10, and X is a halogen, cyanide or alkoxy group.

Abstract: A coating composition consisting essentially of certain heat-stable polymers, colorants, antioxidants, and liquid carrier useful for coating an article to produce a finish which is capable of maintaining its hue and having a decorative pattern produced within it is provided.

Abstract: Multi-layer automotive glazing units that include, in their structures, transparent substrates with protective covers or shields over surfaces of the substrates and that combine penetration resistant body portions with exposed abrasion resistant surfaces; and methods of producing such units.

Abstract: This invention is directed to a process for forming a wettable battery separator comprising a non-woven mat of polyolefin fiber by forming a non-woven mat of polyolefin fiber having a thickness in the range 10 to 40 mils and pore sizes less than 40 microns, contacting the mat with an aqueous solution of a water soluble peroxy compound, e.g. hydrogen peroxide or potassium persulfate at a temperature below 70.degree. C., rinsing the mat in water and thereafter immersing the thus treated mat in an aqueous solution of a hydrophilic vinyl monomer such as acrylic, methacrylic, vinyl sulfonic acid, said solution containing a redox catalyst, e.g. an ion of a transition metal, e.g. ferrous, cerous, cobaltous, or an organic amine, thereby causing a graft polymerization of said hydrophilic vinyl monomer on said polyolefin mat to give a wettable polyolefin battery separator.

Abstract: Solutions of chlorosulfonated polyethylene or mixtures of sulfonyl chlorides and chlorinated polymers in polymerizable vinyl monomers having a Brookfield viscosity of up to about 1 million form excellent adhesive compositions which cure to high bond strengths. Acrylic monomers are preferred.

Abstract: A method is disclosed for protecting aluminum and aluminum alloys by the chemical bonding of a polymerized coating to the aluminum oxide on the aluminum surface. The protective coating is graft polymerized from a solution onto the aluminum in the presence of a small amount of silver ion as an initiator. A peroxide is present during the graft polymerization to regenerate silver ions and to catalyze polymerization of monomers and prepolymers which attach to the aluminum surface. The monomers are vinyl monomers containing one or more hydroxy, carboxy, glycidyl and aziridinyl groups. The prepolymers are polyurethane resins and aliphatic, cycloaliphatic and aromatic epoxy resins. The vinyl monomers and prepolymers are cross-linked to provide a transparent, impervious protective coating on the aluminum. The coated aluminum article made by the above method is also disclosed.