Abstract: A method of treating a painted vehicle or glass to form a film which protects the surface and can be easily cleaned. A treatment solution including a surfactant mixed with water is rubbed into sections of the surface being protected until a tacky residue forms on the surface. The tacky residue is then rubbed into the surface until the surface is wiped free of any streaks.

Abstract: Method and apparatus for improving the surface quality of a resin molding by treating it with a plasma gas, measuring and integrating ion density and stopping the treatment when the integration reaches a predetermined value.

Abstract: A method of forming a pseudo-diamond film on a base body, the method comprising a first step of irradiating carbon ions onto a surface of a base body from an assisting ion gun to form a mixture layer comprising base body material atoms and carbon atoms; a second step of simultaneously vapor-depositing the carbon atoms from a vapor deposition source and irradiating hydrogen ions from the assisting ion gun onto the mixture layer to form pseudo-diamond cores on the mixtures layer; and a third step of vapor-depositing carbon atoms from the vapor deposition source and irradiating hydrogen ions from the assisting ion gun onto the pseudo-diamond cores to form a pseudo-diamond film on the pseudo-diamond cores.

Abstract: An item of footwear which has become scuffed or worn, or which is to be protected against wear, on its leather or leather-like external surfaces, is subjected to a preliminary cleaning. Thereafter, a coating of polyurethane elastomer dissolved in a solvent (preferably half toluene and half isopropyl alcohol), further including a colorant, a thickener and a gloss-lowering agent, is brushed or swabbed onto the surface. The solvent evaporates, leaving a thin, flexible, scuff-resistant coating the color of which covers and hides discoloration and scuffs on the original surface.

Abstract: A shaped body formed of a synthetic organic polymer is surface-treated for increasing the surface energy by a spark discharge treatment which is preceded and/or followed by a treatment with a UV ray-absorbing organic liquid and/or a UV irradiation treatment.

Abstract: A support sheet for photographic printing paper having an undercoat layer on which a photographic emulsion layer is to be formed, and which is free from foaming, contamination by foreign substances, and putrefaction and does not effect the photographic emulsion, by the steps of coating front and back surfaces of a substrate sheet with polyolefin resins; surface-activating the front coating layer; and extrusion coating the activated surface of the front coating layer with a coating liquid comprising gelatin, through a slit-shaped orifice, to form the undercoat layer.

Abstract: A reclaimable polyester film is disclosed which comprises an oriented polyester film which has been coated with an adhesion-promoting coating. The coating is applied to the film as an aqueous dispersion and is dried and crosslinked by the application of heat. The coating is prepared by the free-radical emulsion polymerizable of the following components:A) 1 to 99% by weight of a polymer having carboxy and epoxy groups in the form of an aqueous system with,B) 1 to 99% by weight of at least one copolymerizable .alpha.-.beta.-olefinic unsaturated monomer, each with reference to the total solids content of the components, andC) 0.01 to 10% by weight of at least one polymerization initiator, based upon the monomer proportion of the components B), andD) 0 to 20% by weight of anionic or nonionic emulsifiers or a mixture of both, or also of protective colloids, with reference to the proportion of component B).

Abstract: Method and apparatus for treating ultrahigh molecular weight, high strength polyolefin to improve its adhesive bonding to a resin such as epoxy, vinyl ester, polyester, polyurethane, polyolefin or thermoplastic rubber are provided. The method includes the steps of soaking the polyolefin in a first solution comprising (i) an aromatic ketone photosensitizer, and (ii) a first solvent selected from the group consisting of a benzene derivative, an alkyl halide, and a cyclic alkane; removing any excess first solvent; coating the surface of the polyolefin with a second solution comprising (i) about 15 to 70 weight percent of a monomer independently selected from the aforementioned group, (ii) about 0.25 to 5 weight percent of an aromatic ketone photosensitizer, and (iii) about 25 to 84.

Abstract: Method for the electroless metallizing of fibrous materials, consisting of coating such fibrous materials, before subjecting them to a chemical metallizing treatment, with a uniform film of a polymer which is capable of adhering to the fibrous material, is resistant to the chemical metallizing treatment, and is suitable for receiving metal coatings.

Abstract: An in-mold sulfonation system for sulfonating the surface of plastic articles such as plastic containers during molding. Sulfur trioxide is introduced into a pre-mold chamber, converted to a relatively high pressure gaseous sulfur trioxide, and then injected into a mold such as a blow mold immediately before or immediately following full expansion of the formed plastic article in the mold cavity. Neutralization with a gaseous neutralizing agent follows. By controlling the timing and temperature of the in-mold sulfonation step it is possible to produce a plastic article having an effective barrier layer but containing a minimum of undesirable rinseable salts.

Abstract: A method for reducing the tendency of a surface of a material to foul when exposed to a potential foulant comprises the step of treating the surface of the material with a plasma of a compound containing or generating hydroxyl groups to render the surface hydrophylic but substantially uncharged.The materials may be inorganic, e.g. glass, or organic, e.g. polyamide, and may be in the form of fibers, woven fabrics, membranes or plates. Suitable compounds containing hydroxyl groups include ethylene glycol and water.

Abstract: A protective material comprising a layer of vinylidene chloride or copolymer of vinylidene chloride between two layers of polyethylene to provide protection against both permeation and breakthrough. A cloth backing or inner layer can be added to this material for comfort. The material can be modified with a reinforcing material such as fiberglass or scrim cloth. Inclusion of an indicator substance between layers, or impregnated in a layer, provides further protection by warning the user of permeation and breakthrough. This material can be utilized in protective clothing such as gloves, as enclosures for instruments and equipment, as a container, and in other applications.

Abstract: Method for water vapor plasma treating the surface of a polymer body to enhance the adhesion of a first and second polymer surface. The method is particularly useful for polyimide surfaces.

Abstract: A method for treating permeable plastics and other porous materials to provide solid barriers within the materials that reduce permeability. One method involves migrating a first gas reactant into the material and migrating a second reactant into the material wherein the first and second reactants react at a reaction interface to form a solid reaction product which provides reduced gas permeability for the material. Embodiments are disclosed in which gaseous reactants are migrated from opposite sides of the material to form an internal gas impermeable barrier. Embodiments are also disclosed where the reactants are sequentially migrated into the material to produce gas impermeable barriers. Swelling of the materials prior to treatment with reactants is also disclosed in order to maximize permeation and reactant migration.

Abstract: The method for applying an adhesive to a hologram film includes the steps of: treating one side surface of a hologram film for enhancing the adhesive of an adhesive material thereto; extruding a hot melt of thermoplastic adhesive material onto said one side surface of the hologram film; and, allowing the thermoplastic adhesive material to dry.

Abstract: In a method of forming a transparent conductive film, an arc discharge type plasma produced by arc discharging is generated in an atmosphere wherein the pressure of an atmospheric gas is 3.0 .times. 10.sup.-4 Torr or higher; the plasma is converged onto a vapor deposition material for forming a transparent conductive film to thereby evaporate the vapor deposition material, whereby said transparent conductive film is formed on a substrate located above said vapor deposition material.

Abstract: A novel primer composition containing a partial hydrolyzate of an aminoalkyl-substituted trialkoxysilane, a carboxylic acid salt of tin and a solvent is applied to a moisture-cured silicone substrate and dried to improve the adhesion of a subsequently applied coating. The composition and method are of particular value for painting a moisture-cured silicone substrate disposed on a support, such as a building sealant used on a window assembly or an encapsulant used on an electrical device.

Abstract: A curative for a two part structural primerless urethane adhesive for fiberglass reinforced polyester substrates curable at 240.degree. F. (116.degree. C.).

Abstract: A metallized high specular gloss polyethylene plexifilamentary film-fibril sheet with very low emissivity is made by a process of calendering a polyethylene film-fibril sheet between a smooth metal roll and a soft, resilient roll to form a sheet of high specular gloss, followed by vacuum metallization of the smooth high specular gloss surface. Such metallized sheets are useful as radiant barriers or roof liners for energy savings purposes.

Abstract: The invention concerns a method for forming a coating with excellent adhesion, water resistance and appearance which comprises the combination of steps of applying on the hydrophobic surfaces having a surface tension of 35 dyne/cm or less of a substrate a dry surface treatment selected from vacuum plasma treatment, corona discharge treatment and ozonization treatment, coating thus treated surfaces with a dispersion type aqueous coating composition comprising an aqueous varnish of at least one aqueous resin whose 1 wt % deionized water solution has a surface tension of 51 dyne/cm or less and which has a water tolerance of 4 or more, and water insoluble resin uniformly dispersed in fine particles in said varnish, the water insoluble resin having a SP value which is 1.0 to 2.2 lower than that of said aqueous resin, and baking the coating. The present method is specifically useful in the coating of automobile bodies, appliances and other high-quality products.

Abstract: A water based slurry for use as backup coat on a wax model has colloidal silica and milled zircon as primary ingredients. The slurry is utilized as a backup coat on a wax model used in a lost wax investment casting technique. The slurry comprises of colloidal silica, a latex glue, ammonium alginate, a wetting agent, milled zircon, tabular alumina, glass rock and an anti-foaming agent.

Abstract: A method for treating the surface of an oxygen permeable hard contact lens, which comprises applying high-frequency glow discharge treatment to an oxygen permeable hard contact lens made of a copolymer consisting essentially of a silicone-containing (meth)acrylate and/or a fluorine-containing (meth)acrylate, in a gas atmosphere of at least one member selected from the group consisting of helium, neon, argon and nitrogen gas, containing substantially no oxygen.

Abstract: A process for modifying the surface characteristics of a preformed polymeric substrate to impart hydrophilicity, hydrophobicity or other desired properties thereto comprises peroxidizing and hydroperoxidizing the surface of said preformed substrate using ozone, directing the subsequent graft polymerization of selected ethylenically unsaturated monomers essentially solely to the surface of said substrate to achieve the desired alteration of substrate surface characteristics while maintaining substrate structural integrity. Substrates so modified are useful in biomedical devices, semipermeable membranes, films, fibers and especially contact lenses.

Abstract: In a method and in an apparatus for the production of a corrosion-resistant coating of high reflectivity on the surface of workpieces, especially reflector inserts formed from plastic, in a vacuum chamber with a glow-discharge cathode and an evaporator, there is deposited on a coating consisting of a protective lacquer a second coating of a polymer, preferably of hexadimethylsilane, then a third coating of a metal, preferably aluminum, and lastly a fourth coating of a polymer, preferably of hexadimethylsilane. Both the metal evaporation and the polymerization of the protective coatings on the reflective coating and on the lacquer coating are performed in the same vacuum chamber.

Abstract: The present invention relates to a process for troublefree, i.e. flaw-free and uniform, coating of a support which can accept a large amount of electrostatic charge, such as, for example, polycarbonate foils, with a solution of fully reacted polyurethane in organic solvents, more precisely after prior coating of the polycarbonate foil with an organic solution of the sodium salt of polystyrenesulphonic acid.

Abstract: A process is provided for improving the surface properties of polyimide articles which contain significant amounts of transimide. The surface of the polyimide containing the transimide is first treated with a base to convert the surface layer of both the polyimides and the transimides to polyamic salt. Thereafter the surface layer of the converted polyamic salt is treated with an acid to convert the layer to a polyamic acid. This is followed by a cure preferably in infrared radiation at a sufficiently rapid rate to prevent the formation of any significant amounts of transimide and provide only polyimide. Following this treatment metallization is applied to the improved surface layer.

Abstract: A significant improvement of stain-resistance is obtained by commercial application of stain-blocker to nylon carpet that is installed, as opposed to immersing or otherwise treating the primary carpet or treating the precursor nylon polymer or fibers earlier during a manufacturing process. There are various methods of application and of increasing stain-resistance of installed carpets.

Abstract: A two-step, sequential coating method is disclosed which permits the use of aqueous precursor solutions to coat water-insoluble compounds onto thermoplastic film. In a preferred embodiment, an aqueous oleic acid/ammonium oleate solution is coated onto amorphous polyester sheet which is subsequently monoaxially oriented by stretching in the machine direction, and coated with an aqueous solution of calcium hydroxide, thereby forming a layer of calcium oleate in situ. The coated film is subsequently biaxially oriented by stretching in the transverse direction, and heat-set.

Abstract: A specific oxidation product layer is formed on the surface of a styrene resin container body, and via the oxidation product layer, a coated layer of a copolymer of vinylidene chloride, vinyl chloride and a (meth)acrylate is provided. This coated container has not only excellent gas-barrier property but also excellent peel resistance, particularly excellent peel resistance at low temperatures in the wet state.

Abstract: Method for producing a gas separation membrane comprising a microporous support having provided thereon a non-porous coating layer. The method comprises melt extruding a thermoplastic crystalline polymer under particular melt-extrusion conditions to form a precursor in the form of a hollow fiber or flat film, coating the precursor as a support with a coating substance composed of a natural or synthetic substance capable of forming a polymeric layer which does not form pinholes upon subsequent drawing after solidification to form a coating layer on the surface of the support, and solidifying the coating layer. The support is annealed either before or after the cooling process, and this is followed by cold drawing and heat setting the support to form the gas separation membrane.

Abstract: Non-woven fabrics produced from spunbonded web of the thermally bonded type suitable for use in folding window blinds are disclosed. To provide an opaque fabric with a weave-like finish a metalized blackout film and the spunbonded web substrate are laminated together while simultaneously embossing the substrate. Non-opaque fabrics may be made by using a film without metalization. Binder material is added to provide corrosion protection for the metalized film and additional bonding to the substrate. Difficulties in embossing this type of web are overcome by using steel embossing rollers and narrow widths of web. Using this basic process opaque fabrics may be made without embossing by creating a temporary bond between the layers with the surface tension of water, or non-opaque fabric made by not adding any film in the embossing step.

Abstract: The present invention discloses a process for treating plastic structural sheets with a long lasting surfactant. The process encompasses exposing the surface of the sheet to a saturated solution of long lasting surfactant while the surface of the sheet is still tacky. A series of rollers forces the surfactant into the surface and distribute the surfactant uniformly across the sheet.

Abstract: A process for forming an anti-halation layer on the surface of a polyester photographic film support comprises the steps of (1) subjecting the surface to an activation treatment such as, for example, corona discharge treatment; (2) coating the activated surface with a composition comprising an anti-halation agent, such as carbon black, and an alkali-soluble polymeric binder, such as cellulose acetate hexahydrophthlate, dispersed in a liquid organic medium; and (3) drying the coating to thereby form an anti-halation layer which is strongly adherent to the polyester film suport yet is readily removable by an alkaline photographic processing solution.

Abstract: An inner boot for a ski boot which has wall portions that define the body of the inner boot. The wall portions are made from an open cell foam material. A lower portion of the inner boot includes a sealing coating of polyurethane that seals the foot of a skier against moisture and humidity. A process for manufacturing the inner boot includes degreasing the inner boot, soaking the inner boot in a polyurethane solution, removing excess polyurethane and drying the inner boot.

Abstract: Semicrystalline polymers and copolymers having migratory additives therein can be provided with reduced migration. A surface layer of the polymer of copolymer article is rendered quasi-amorphous and a film less penetrable by said migratory additives than the polymer or copolymer is adhered thereto.

Abstract: The invention relates to a process for the preparation of plastic mouldings, preferably plastic films, antistatically treated with a transparent layer of polypyrrole; the process is characterized by a certain combination of special measures which are coordinated with one another.

Abstract: Thin films (e.g. less than 100 nm thick) of a metal oxide material can be deposited on a variety of hydrophilic substrates by hydrolysis. Deposition is achieved by reacting a vapor of an appropriate metal-containing compound with water at or near the substrate's surface. The resulting deposited film can serve a variety of uses, for example, as a photo-resist in micro-electronics or in any area where protective films are useful, such as the passivation of ternary metal oxide superconductors.

Abstract: Described is a method for imparting a photochromic response to a synthetic plastic article, e.g., an optical lens such as a sunglass lens prepared from an allyl diglycol carbonate monomer. The method described comprises depositing a thin uniform substantially dry film of a photochromic-bearing polymeric resin onto at least one planar surface of the synthetic plastic material, heating the plastic article and resin film substantially uniformly at temperatures near to but below the melting temperature of the photochromic substance for a time sufficient to transfer a photochromic amount of the photochromic material into the subsurface region of the plastic article, and thereafter removing the photochromic-lean resin film from the planar surface(s) of the plastic article.

Abstract: Disclosed is a method of coating a golf ball comprising coating a surface of a golf ball with a solution of ethylene-imine, carbodiimid or the derivatives thereof and then coating it with a paint and a pre-treatment solution comprising ethylene-imine, carbodiimide and the derivatives thereof for coating a golf ball.

Abstract: This invention relates to a new process and group of products that are useful in preventing nylon and wool fibers, including carpeting and upholstery, from being permanently stained. Fibers can be permanently stained by food colors contained in foods spilled on the fiber. This new group of sulfonated phenol-formaldehyde or naphthol-formaldehyde and anionic surfactant compounds not only block the stain from the fiber but also minimizes any yellowing or discoloration of the treated fibers during the application and during the subsequent exposure to sunlight or commonly used lightfastness testing equipment.

Abstract: A method for heparinizing a substrate includes applying a coating of ammonium salt to a substrate by steeping the substrate in a solution of the salt at an alkaline pH and contacting the coated substrate with a solution of a salt of heparin.

Abstract: The invention relates to a process for antistatic treatment or pretreatment for subsequent surface-coating of materials based on polyamides, polyimides or polyamideimides, where the molded articles of the material are treated with a solution of salt mixtures comprising(a) halides of elements of main groups 1 and/or 2 of the periodic system, in particular CaCl.sub.2, MgCl.sub.2, LiCl, NaCl and/or KCl and(b)(1) salts of weak inorganic bases with strong inorganic acids, in particular AlCl.sub.3, FeCl.sub.3, TiCl.sub.4, SbCl.sub.5, CaCl.sub.2, FeCl.sub.2, CuCl.sub.2, ZnCl.sub.2 and/or MoCl.sub.5(2) and/or the chelate complexes of (b1) with Schiff bases, amines, carboxylic acids, diketones, .alpha.,.beta.-unsaturated ketones and phosphines,(c) in a non-corrosive, organic swelling agent or solvent for the materials mentioned, where appropriate with the addition of water, preferably in an alcohol, at temperatures up to the boiling point of the solvents, preferably at temperatures of from -15.degree. C. to +60.

Abstract: A polyvinylidene difluoride structure with a critical surface energy of at least about 80 dynes/cm and a method of making such a structure comprising the steps of contacting a polyvinylidene difluoride structure with an alkalized solution, such as potassium hydroxide, to form activated sites on the surface of the structure; rinsing the activated structure to remove residual alkali; contacting the rinsed, activated structure with a solution of a polymerization initiator, such as potassium peroxydisulfate, and a polymerizable vinylic monomer, such as acrylic acid; and polymerizing and grafting the monomer to the activated structure to form a polyvinylidene difluoride structure with a critical surface energy of at least about 80 dynes/cm.

Abstract: The surface of a polymer is treated to improve the adherence of paint, ink and glue thereto by contacting its surface with a solution of an ortho-benzoquinone or it substituted derivative together with an organic carboxyic acid or its anhydride or cyanic or thiocyanic acid in an inert organic solvent.

Abstract: A method of and an apparatus for making a magnetic recording tape, which is free from wrinkles formed thereon, by the use of a vapor deposition technique. A length of tape reeled on a supply reel is taken up by a take-up reel after having passed through a deposition station where it is movably turned around a cylindrical drum. In one aspect, the difference in tension between two different portions of the tape moving between the drum and the take-up reel and on respective sides of a tensioning roll forming a part of at least one tension control mechanism is adjusted to a value not greater than 10N/mm.sup.2. In another aspect, a charge eraser is employed and installed in the vicinity of the drum for removing an electrostatic charge built up in the tape being moved from the drum onto the take-up reel. In a further aspect, the cylindrical drum is used having its outer peripheral surface roughened to a ten-point average surface roughness of not smaller than 0.1 .mu.m.

Abstract: A transfer recording medium comprising a substrate and a plurality of image forming elements bonded thereto by a binder is provided. The surface of each image forming element at least partially protrudes out of the binder. Such transfer recording medium may be prepared by applying the binder onto the substrate in a prescribed thickness, disposing the image forming elements in excess on the binder, and then removing the excess of the image forming elements. The thus prepared transfer recording medium provides an image having a high density and a faithfully reproducible color.

Abstract: A method and apparatus for coating a fastener, particularly a fastener with a head portion and shank portion, with a coating material is provided. The invention includes the steps of and apparatus for supporting the fasteners such that the fasteners are positioned for coating. The fasteners are conveyed such that the fasteners are moved through a plurality of operation stations and pass through a heating station where the shank portions of the fasteners are heated. Subsequently, at a material applying station, a coating material is applied to the heated shank portions. A preferred embodiment of the method and apparatus of the present invention includes supporting the fasteners on their head portions with the shank portions projecting upward, conveying the fasteners with their shank portions projecting upward for processing, heating the shank portion to a temperature above the melting point of the applied material and applying the material to the heated shank portion to form a coating thereon.

Abstract: A method for lubricating a low surface energy polymeric surface includes plasma treatment of the surface. A film of a polysiloxane lubricant is applied to the plasma-treated surface to give an even coating of the lubricant which is stable for a protracted period of time.

Abstract: Composite membranes having advantageous combinations of selectivity and permeability are prepared by the coating of a separation layer on a porous support layer containing a controlled amount of liquid in the range of from about 10% to about 90% by weight of the liquid present in the fully wet support layer.

Abstract: An optical waveguide and method of fabricating waveguide structures is disclosed. More specifically, a method of producing an organic waveguide which comprises treating a transparent plastic substrate with a solution in a inert solvent of an organic dopant which is absorbed into the surface of the substrate, under conditions such that a surface layer is formed having a refractive index which is greater than that of the substrate. Said dopant has a higher affinity for the plastic's substrate than for the solvent.