Cellulosic Coating Patents (Class 427/339)
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Publication number: 20150140219Abstract: A disinfectant textile composition having antimicrobial, wash durable, optionally enhanced with multifunctional properties, comprising, substrate, disinfecting agents, antiviral agents, antifungal agents, emulsifying agents, vehicle,Type: ApplicationFiled: March 12, 2014Publication date: May 21, 2015Inventors: Rohini Swamy, Sanjeev Swamy
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Patent number: 8834970Abstract: Preliminary cure of an aqueous acrylic weatherproofing emulsion coating is accelerated by contacting the coating with urea hydrochloride dissolved in water or an organic solvent at least partially miscible with water.Type: GrantFiled: October 26, 2006Date of Patent: September 16, 2014Assignee: Tremco Barrier Solutions, Inc.Inventors: James R. Wells, Michael J. Mettille
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Patent number: 8683798Abstract: Embodiments of a product such as a stimuli-responsive product can comprise a shape memory component and a nanofiber component that forms a fibrous microstructure or network. The resulting product can be responsive to stimuli, such as electrical stimuli, in a manner that cause the product to deform, deflect, and rebound. In one embodiment, the product can comprise an epoxy and a continuous non-woven nanofiber, the combination of which provides a product with enhanced actuation speed.Type: GrantFiled: January 13, 2011Date of Patent: April 1, 2014Assignee: Syracuse UniversityInventors: Patrick Mather, Xiaofan Luo
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Patent number: 8664152Abstract: The present invention provides a porous cellulose gel having a high mechanical strength capable of being operated at a higher flow rate, and a method for producing the same. To a suspension liquid of cellulose particles, a crosslinking agent in an amount of from 4 to 12 times the amount of the cellulose monomer in terms of moles and an alkali in an amount of from 0.1 to 1.5 times the amount of the crosslinking agent in terms of moles are added continuously dropwise or added dividedly over a prescribed period of time, whereby flow rate characteristics of a resulting porous cellulose gel can be enhanced. According to the invention, the production efficiency of a polymer substance, such as a nucleic acid and a protein can be enhanced.Type: GrantFiled: August 27, 2008Date of Patent: March 4, 2014Assignee: JNC CorporationInventors: Yasuto Umeda, Yasuo Matsumoto, Masami Shiina, Masami Todokoro, Yoshihiro Matsumoto
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Publication number: 20130295151Abstract: The present invention relates to a process for the treatment of a cellulosic molded body, wherein the molded body is contacted with an acid solution of a chitosan. The process according to the invention is characterized in that the chitosan has a deacetylation degree of at least 80%, a nitrogen content of at least 7 w %, preferably at least 7.5 w %, a weight average molecular weight Mw (D) of 10 kDa to 1000 kDa, preferably 10 kDa to 160 kDa, and a viscosity in 1 w % solution in 1 w % acetic acid at 25° C. of 1000 mPas or less, preferably 400 mPas or less, in particular preferably 200 mPas or less.Type: ApplicationFiled: August 27, 2009Publication date: November 7, 2013Applicant: Lenzing AktiengesellschaftInventors: Sigrid Redlinger, Werner Richardt, Heinrich Firgo
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Publication number: 20130196068Abstract: A film containing alginate membrane and a manufacturing method of the same are revealed. A film carrier is used to absorb liquid and is treated by two separate and continuous coating processes. At least one surface of the film carrier is coated with a layer of alginate solution containing a certain percent of sodium alginate or potassium alginate by weight and then is coated with a layer of salt water solution containing a certain percent of divalent metal ions. Then crosslinking occurs between the alginate in the alginate solution and the divalent metal ions in the salt solution on the surface of the film carrier or infiltrating into the film carrier so as to form a hydrogel complex membrane having a network structure. Thus the continuous and fast mass-production of the film is achieved.Type: ApplicationFiled: March 14, 2013Publication date: August 1, 2013Applicant: BIOSOL TECH CORPORATION LIMITEDInventor: Biosol Tech Corporation Limited
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Publication number: 20120282308Abstract: A film containing alginate membrane and a manufacturing method of the same are revealed. A film carrier is used to absorb liquid and is treated by two separate and continuous coating processes. At least one surface of the film carrier is coated with a layer of alginate solution containing a certain percent of sodium alginate or potassium alginate by weight and then is coated with a layer of salt water solution containing a certain percent of divalent metal ions. Then crosslinking occurs between the alginate in the alginate solution and the divalent metal ions in the salt solution on the surface of the film carrier or infiltrating into the film carrier so as to form a hydrogel complex membrane having a network structure. Thus the continuous and fast mass-production of the film is achieved.Type: ApplicationFiled: September 22, 2011Publication date: November 8, 2012Inventors: Yao-Chung CHIU, Yu-Yueh Lin
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Publication number: 20110281487Abstract: The present invention provides the gas barrier molded article having high permeation barrier properties against oxygen gas, water vapor and the like. A gas barrier material containing cellulose fibers having an average fiber diameter of not more than 200 nm wherein the content of carboxyl group in a cellulose ranges from 0.1 to 2 mmol/g; and further a cross-linking agent having a reactive functional group or the cellulose fibers being dried or heated or a gas barrier molded article containing a molded substrate and a layer composed of the gas barrier material on the surface of the molded substrate.Type: ApplicationFiled: December 25, 2009Publication date: November 17, 2011Applicant: KAO CORPORATIONInventors: Kenta Mukai, Yoshiaki Kumamoto, Akira Isogai, Zenbei Meiwa, Takahiro Maezawa, Toru Ugajin
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Publication number: 20110212150Abstract: The present invention relates to a process for the treatment of a cellulosic molded body, wherein the molded body is contacted with an acid solution of a chitosan. The process according to the invention is characterized in that the chitosan has a deacetylation degree of at least 80%, a nitrogen content of at least 7 w %, preferably at least 7.5 w %, a weight average molecular weight Mw (D) of 10 kDa to 1000 kDa, preferably 10 kDa to 160 kDa, and a viscosity in 1 w % solution in 1 w % acetic acid at 25° C. of 1000 mPas or less, preferably 400 mPas or less, in particular preferably 200 mPas or less.Type: ApplicationFiled: August 27, 2009Publication date: September 1, 2011Applicant: LENZING AKTIENGESELLSCHAFTInventors: Sigrid Redlinger, Werner Richardt, Heinrich Firgo
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Publication number: 20100015299Abstract: The invention relates to a food casing with textile backing material which has been coated with a layer of regenerated or precipitated cellulose. This casing combines the properties of a textile skin with those of a cellulose fiber skin. Besides the surface texture for which textile skins are known and prized, it also has the transparency and the barrier properties, i.e. water-vapor permeability, oxygen permeability and smoke-constituent permeability, of a cellulose fiber skin. At the same time the casing is impervious to fat. It is used preferably as an artificial sausage casing.Type: ApplicationFiled: April 29, 2006Publication date: January 21, 2010Inventors: Ralf Borst, Jens Foegler, Herbert Gord, Michael Seelgen, Peter Wolf
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Patent number: 7244509Abstract: Hydrogenated triglycerides having melting temperature above about 50° C. are substituted for paraffin as a coating material for the surface of paper products and the resulting paper products have improved wet strength and moisture resistance in addition to being repulpable thereby providing a distinct environmental advantage over paraffin coated products.Type: GrantFiled: January 24, 2005Date of Patent: July 17, 2007Inventor: Scott O. Seydel
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Patent number: 6858311Abstract: A surface protective film which can be easily peeled off from an adhesive silicone rubber composition layer, is free of a plasticizer or the like which may have an adverse effect on adhesion of the adhesive silicone rubber composition layer to a semiconductor chip or semiconductor chip attaching portion, and has no adverse effect on thickness uniformity or surface flatness of the adhesive silicone rubber composition layer, and a process for producing the same. More specifically, a surface protective film for protecting an adhesive silicone rubber composition layer (C), comprising a base film (A) coated, at least on one side, with a cellulose-based resin layer (B) having an SP value of 21.0 to 29.0 (MPa)1/2, determined by the Fedors method, and process for producing the same.Type: GrantFiled: May 9, 2003Date of Patent: February 22, 2005Assignee: Daicel Chemical Industries, Ltd.Inventors: Katsuhiko Sumita, Masaya Omura
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Patent number: 6777100Abstract: A surface protective film which can be easily peeled off from an adhesive resin layer it protects, is free of any component which may have an adverse effect on adhesion of the adhesive resin layer to an object to which it is bonded, and has no adverse effect on thickness uniformity or surface flatness of the adhesive resin layer, and a process for producing the same. More specifically, a surface protective film for protecting an adhesive resin layer, comprising a base film (A) coated, at least on one side, with a cellulose-based resin layer (B) having an SP value of 21.0 to 29.0(MPa)1/2, determined by the Fedors method, and process for producing the same.Type: GrantFiled: May 16, 2003Date of Patent: August 17, 2004Assignee: Daicel Chemical Industries, Ltd.Inventors: Katsuhiko Sumita, Masaya Omura
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Patent number: 6669981Abstract: Methods of enhancing the photostabilizing of silver in medical materials are described. More particularly, the methods increase the photostabilization of silver in certain materials comprising hydrophilic, amphoteric and anionic polymers by subjecting the polymers to solutions containing an organic solvent and silver, during or after which one or more agents are added which facilitate the photostablization of the material.Type: GrantFiled: November 29, 2001Date of Patent: December 30, 2003Assignee: Bristol-Myers Squibb CompanyInventors: David Parsons, Elizabeth Jacques, Philip Bowler
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Patent number: 6599575Abstract: The present invention is directed to a method for the production of a durably hydrophilic, non-leaching coating. A carbohydrate-salt mixture is formed by at least partially dissolving a water insoluble carbohydrate in an aqueous salt solution to form a carbohydrate-salt complex. The carbohydrate-salt mixture is applied to a substrate, and the substrate is rinsed with a solvent to form a coating.Type: GrantFiled: December 31, 2001Date of Patent: July 29, 2003Assignee: Kimberly-Clark Worldwide, Inc.Inventors: William G. Reeves, Li-fu Chen
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Patent number: 6547832Abstract: Process for the yellowing-inhibiting finishing of textile, indigo-dyed, washed and/or stonewashed and/or bleached denim articles, characterized in that the finishing is carried out from aqueous medium with protonated fatty acid ester-aminoamides and/or hydroxyaminoamides of N-(&bgr;-hydroxyethyl)ethylenediamine, in which the fatty acid radicals each contain from 12 to 22 carbon atoms and which have been protonated with at least 1.5 equivalents of ortho-phosphoric acid per equivalent of basic amino groups.Type: GrantFiled: July 10, 2000Date of Patent: April 15, 2003Assignee: Clariant Finance (BVI) LimitedInventors: Fred Freudemann, Kurt Poppenwimmer
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Patent number: 6444134Abstract: A method of finishing a wood floor comprising a first step of applying an aqueous polar solvent for a sufficient period of time to allow removal of a portion of any existing stains and soils and to at least partially etch the surface of an existing finish. A second step of applying an aqueous rinse to flush at least a substantial portion of any residue formed in the first steps and a third step of applying a water based finish and allowing it to dry.Type: GrantFiled: February 22, 2000Date of Patent: September 3, 2002Assignee: The Flecto Company, Inc.Inventors: Ronnie Gene Holman, Roy Edward Blackburn, Jr., Timothy G. Specht
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Patent number: 5820934Abstract: The present invention relates to a method for the production of a fiber-reinforced cellulose tube by continuous coating of a fibrous non-woven fabric with an alkaline viscose solution which is neutralized by means of an acid-containing precipitating liquid and is converted into regenerated cellulose, wherein on the path between viscose coating and immersion in the precipitating bath, aqueous, acid-containing precipitating agents are caused to act upon the fresh viscose tube within the tube for the purpose of stiffening and regeneration to form regenerated cellulose, the process being begun with the application of the precipitating liquid directly after conclusion of the embedding of fiber in viscose and the precipitating liquid being guided together with the tube with the aid of optionally fixed internal devices which are designed in such a way that they support the tube that has had precipitating bath applied to it and in the process maintain it in rounded shape, that the length of the inner preliminary precType: GrantFiled: May 9, 1997Date of Patent: October 13, 1998Assignee: Wolff Walsrode AGInventor: Klaus Basfeld
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Patent number: 5690996Abstract: A cross-linked flexible sponge absorbent medium containing substantially uniformly distributed fibrous reinforcement is prepared under such conditions that swelling of the sponge is controlled to a water retention value of 2 to 6; and simultaneously or subsequently, the cross-linked sponge is reacted with a reagent which introduces functional groups into the modified cross-linked sponge. There is also provided apparatus having an inlet for liquid, an outlet for liquid so as to define a path for liquid flow between the inlet and the outlet, an adsorbent medium, obtainable by the above method, being positioned across the liquid flow path in the apparatus.Type: GrantFiled: October 19, 1995Date of Patent: November 25, 1997Assignee: SepragenInventors: Alan Sanderson, Rod Dove, Fang Ming, John Howell
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Patent number: 5668193Abstract: A solid substrate, the surface of which has been modified to introduce reactive groups of a hydrophilic nature thereon, the modification being provided by a primer comprising a first polysaccharide containing as reactive groups amino and hydroxyl groups; and a process for the preparation of such solid substrate.Type: GrantFiled: December 5, 1995Date of Patent: September 16, 1997Assignee: Medicarb ABInventors: Ibrahim Gouda, Olle Larm
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Patent number: 5536573Abstract: A thin-film heterostructure bilayer is formed on a substrate by a molecular self-assembly process based on the alternating deposition of a p-type doped electrically conductive polycationic polymer and a conjugated or nonconjugated polyanion or water soluble, non-ionic polymer has been developed. In this process, monolayers of electrically conductive polymers are spontaneously adsorbed onto a substrate from dilute solutions and subsequently built-up into multilayer thin films by alternating deposition with a soluble polyanion or water soluble, non-ionic polymer. In contrast to a deposition process involving the alternate self-assembly of polycations and polyanions, this process is driven by non-covalent bonded attractions (for example, ionic and hydrogen bonds) developed between a p-type doped conducting polymer and a polymer capable of forming strong secondary bonds. The net positive charge of the conducting polymer can be systematically adjusted by simply varying its doping level.Type: GrantFiled: July 6, 1994Date of Patent: July 16, 1996Assignee: Massachusetts Institute of TechnologyInventors: Michael F. Rubner, Josephine Ho-Wah Cheung
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Patent number: 5492723Abstract: A cross-linked flexible sponge absorbent medium containing substantially uniformly distributed fibrous reinforcement is prepared under such conditions that swelling of the sponge is controlled to a water retention value of 2 to 6; and simultaneously or subsequently, the cross-linked sponge is reacted with a reagent which introduces functional groups into the modified cross-linked sponge. There is also provided apparatus having an inlet for liquid, an outlet for liquid so as to define a path for liquid flow between the inlet and the outlet, an adsorbent medium, obtainable by the above method, being positioned across the liquid flow path in the apparatus.Type: GrantFiled: November 2, 1992Date of Patent: February 20, 1996Assignee: Sepragen CorporationInventors: Alan Sanderson, Rod Dove, Fang Ming, John Howell
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Patent number: 5387383Abstract: Rayon/nylon and other sheath/core composite fibers or other materials, with good adhesion between sheath and core resulting from an adhesion promoter. The adhesion promoter is difunctional and sterically hindered. Fumaric acid and terephthalic acid are preferred adhesion promoters for the composite fibers or other materials, because each compound has both difunctionality and steric hinderance, allowing either to form covalent bonds to both the sheath and the core. Fibers produced in accordance with this invention may be used to produce fabrics which have the strength and wrinkle resistance shown by a number of synthetic fibers, but with the water absorption characteristics of natural fibers such as cotton.Type: GrantFiled: December 13, 1993Date of Patent: February 7, 1995Assignee: Board of Supervisors of Louisiana State University and Agricultural and Mechanical CollegeInventors: John R. Collier, Billie J. Collier
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Patent number: 5367040Abstract: A process for the production of modified phenol-formaldehyde resins includes the use of a difunctional phenolic compound as the phenolic component of the resins. The inventive resins resist pre-curing and are useful in the production of molded wood composites produced, for example, by wet-dry forming processes.Type: GrantFiled: December 29, 1992Date of Patent: November 22, 1994Assignee: Masonite CorporationInventor: Zygmunt Teodorczyk
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Patent number: 5360636Abstract: A process for improving the biocompatibility of cellulosic film membranes is characterized by the fact that the film membranes are coated during or after their preparation with cellulose ethers and/or cellulose esters and/or cellulose carbamates whose structures conform to the formulas ##STR1## wherein Cell is the skeleton of the unmodified cellulose molecule without hydroxyl groups; x conforms to the degree of modification, which is in the range of 0.002 to 3; R is an (optionally substituted) alkyl and/or alkenyl and/or aryl and/or arylalkyl group and the carbon chain of the group R contains 1 to 36 carbon atoms and may be interrupted by hetero atoms such as O, S, N, and contains basic and/or acidic groups such as 13 NR'.sub.2, --COOR', and/or --SO.sub.3 R' or their salts, wherein R'=H or R.Type: GrantFiled: January 5, 1993Date of Patent: November 1, 1994Assignee: Akzo NVInventors: Michael Diamantoglou, Edmund Richter, Thomas Rintelen, Gustav Duweg, Angelika Reiche, Ralf Tatas
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Patent number: 5352510Abstract: A method for the manufacture of paper faced foam which comprises (a) applying a foam-forming mixture to at least one advancing cellulosic sheet or composite thereof with an air- and/or moisture-impermeable material, the cellulosic sheet (i) being impregnated with cured polyisocyanate, (ii) being sufficiently flexible for unwinding from a roll for conveyance along a production line and (iii) having a moisture content which does not exceed about 10 percent and is evenly distributed throughout the cellulosic sheet, and (b) foaming and curing the faced foam-forming mixture.Type: GrantFiled: September 27, 1993Date of Patent: October 4, 1994Assignee: The Celotex CorporationInventors: Wayne E. Laughlin, Kenneth P. Klapper
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Patent number: 5320873Abstract: A process and apparatus for treating cellulosic fiber containing fabrics to improve durable press and shrinkage resistance includes using steam as a vehicle to supply vaporized liquid cellulosic cross-linking agent and vaporized liquid catalyst to a reaction chamber in which the fabric articles are treated by cross-linking the cellulose. Normally liquid cross-linking agent and liquid catalysts are directly injected into a stream of treating steam to cause vaporization of the cross-linking agent and catalyst. Alternatively, a steam driven ejector type pump is utilized to entrain and vaporize liquid cross-linking agent and liquid catalyst in a flowing stream of steam supplied to the reaction chamber. Gaseous ammonia may also be supplied to the reaction chamber to condition the cellulosic material containing fabric before cross-linking.Type: GrantFiled: August 29, 1991Date of Patent: June 14, 1994Assignee: American Laundry Machinery, Inc.Inventors: David R. McClain, Ewart H. Shattuck
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Patent number: 5112651Abstract: A method of forming a silver image receiving element in diffusion transfer photography by hydrolyzing a surface of an alkali-impermeable polymer layer on a continuous running web so as to convert the polymer to an alkali-permeable polymer. The method includes the steps of first applying a liquid mixture of a hydrolyzing agent and a softening agent to the surface of the alkali-impermeable polymer layer, evaporating the softening agent in the liquid mixture by blowing air on the surface to form a concentrated layer of the hydrolyzing agent; and thereafter accelerating the occurrence of hydrolysis by blowing air on the surface so as to initiate hydrolysis reaction of the surface to as to convert the alkali-impermeable polymer layer to an alkali-permeable polymer layer. The temperature of the air which is blown on the surface is in the range of 50.degree. to 120.degree. C.Type: GrantFiled: November 8, 1989Date of Patent: May 12, 1992Assignee: Fuji Photo Film Co., Ltd.Inventors: Toshihiro Watanabe, Masashi Ishiyama, Noriaki Masuda
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Patent number: 5096754Abstract: A film, preferably used as a tubular artificial sausage casing, having a base layer of a material which may be fiber-reinforced, wherein the material includes a mixture of cellulose hydrate and alginic acid and/or alginate. The alginate may be the calcium salt of alginic acid. In addition, a process for producing the film by the viscose process is also described, wherein a mixture of alkaline viscose solution and a soluble salt of alginic acid is coagulated by means of an acidic precipitating fluid.Type: GrantFiled: June 4, 1990Date of Patent: March 17, 1992Assignee: Hoechst AktiengesellschaftInventors: Klaus-Dieter Hammer, Hermann Winter
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Patent number: 5075127Abstract: A sensor comprising a sensing element capable of sensing a component in an aqueous medium and an overcoating at least partially covering the sensing element. The overcoating comprises a water insoluble, component permeable, cross-linked cellulosic material and an effective amount of an opaque agent.Type: GrantFiled: March 12, 1990Date of Patent: December 24, 1991Assignee: Minnesota Mining and Manufacturing CompanyInventors: Masao Yafuso, Henry K. Hui, Cheng F. Yan, William W. Miller
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Patent number: 4960687Abstract: An improved process for the preparation of backing layers with improved coating qualities is described. These layers are designed to transmit antistatic properties from antistatic layers coated under the backing layers and provide antihalation or anticurl effects in addition thereto. The process of this invention includes in-line addition of a pre-stabilized crosslinking solution to a gelatino-conductive polymer solution just prior to the coating thereof. Smooth, skip-free coatings are obtained and the solutions are stable and can be maintained for long periods of time.Type: GrantFiled: September 29, 1989Date of Patent: October 2, 1990Assignee: E. I. Du Pont de Nemours and CompanyInventor: Thomas B. Cho
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Patent number: 4769259Abstract: The present invention relates to a method for preventing fogging or clouding of surfaces comprising glass, high molecular weight substance, and the like. The method comprises the steps of: (1) applying a dispersion liquid wherein a high molecular substance having a hydroxyl group is added to the surface to be treated (2) causing the substance on the surface to react while adding cyanuric chloride, (3) hydrolyzing the resultant mixture with a base, (4) neutralizing the treated surface, (5) rinsing and drying the above neutralized surface, (6) reacting a nonionic surface active agent having a fluorine group or a silicone group with a NH.sub.2 group or H group to react on the surface, (7) hydrolyzing the resultant surface and then, (8) neutralizing the surface with an acid.Type: GrantFiled: February 27, 1987Date of Patent: September 6, 1988Assignee: Nogawa Chemical Co., Ltd.Inventor: Minoru Ueno
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Patent number: 4695484Abstract: A moisture-permeable waterproof coating is formed by coating a fabric with a water-based coating composition containing a film forming polymer and a water-soluble polymer in a proportion of 5 to 70% based on total solids, drying or heating the fabric to form a film thereon; and then treating the resulting film with an aqueous solution of an enzyme which selectively degrades the water-soluble polymer, thereby enzymatically degrading the water-soluble polymer and extracting the degraded water soluble polymer from the film, whereby the film on the fabric is rendered microporous.Type: GrantFiled: December 6, 1985Date of Patent: September 22, 1987Assignee: Dai-Ichi Kogyo Seiyaku Co., Ltd.Inventors: Teruo Tanaka, Teruya Tanaka, Masato Kitamura
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Patent number: 4567098Abstract: Metallized paper whose metal layer has been deposited by evaporation in vacuo onto a cast-coated paper. The cast coating contains mineral pigments, latex binders and conventional additives, and at least 5 parts by weight of the pigment are a synthetic polymer pigment. The coating material has a pH value >7 and during the process of fabricating the metallized paper it is deposited in such an amount that, after the drying, 10-30 g/m.sup.2 of cast coating are present. The coating material deposited onto a paper web is dried until its moisture content is 5-15% and the web is then pressed with the coated paper surface against a drum with a highly polished surface at a temperature of 100.degree.-160.degree. C. by means of a roll with a nip >1000 N/cm.Type: GrantFiled: July 6, 1983Date of Patent: January 28, 1986Assignee: Zanders Feinpaiere AGInventors: Franz-Josef Becker, Erich Hubner, Walter Lammerich
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Patent number: 4565717Abstract: Antisoiling properties of polyamide filaments are enhanced upon melt-spinning by using a spin finish comprised of a textile lubricant, an antisoiling fluorochemical and an epoxy resin.Type: GrantFiled: October 20, 1983Date of Patent: January 21, 1986Assignee: E. I. DuPont De Nemours and CompanyInventors: Edward A. Hosegood, Ludwig E. Seufert
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Patent number: 4433120Abstract: A pre-cure resistant liquid phenol-formaldehyde resin binder composition having low viscosity and low surface tension for efficient spray application as fine droplets in waferboard manufacture comprising a highly condensed and cross-linkable phenol-formaldehyde resin of relatively high average molecular weight and a non-resinous methylolated phenol condensate having an average molecular weight of 200-300.Type: GrantFiled: September 30, 1981Date of Patent: February 21, 1984Assignee: The Borden Chemical Company (Canada) LimitedInventor: Shui-Tung Chiu
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Patent number: 4419316Abstract: A process of preparing film, fibers and other shaped articles by nitrosating a polyhydroxy polymer in a reaction medium containing a solubilizing agent for the resulting polyhydroxy polymer nitrite ester and a suitable proton acceptor, bringing the reaction mixture into the desired shape and regenerating and separating the polyhydroxy polymer by contact with a protic solvent in the presence of an acid catalyst. The polyhydroxy polymer may be a polyvinyl alcohol, cellulose or other polysaccharide, and mixtures thereof. Also dissolved in the reaction medium may be an organic solvent soluble polymer substantially lacking hydroxyl groups. If mixtures of polyhydroxy polymers or of polyhydroxy polymers lacking hydroxyl groups and organic solvent soluble polymers are employed the resulting films, fibers or other shaped articles consist of homogeneous and intimate mixtures of all the polymers originally present in solution.Type: GrantFiled: October 29, 1980Date of Patent: December 6, 1983Inventor: Richard G. Schweiger
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Patent number: 4326532Abstract: A medical article having a layered antithrombogenic surface is useful as a polymeric implant. The article comprises a polymeric substrate coated with chitosan to which is appended an antithrombotic agent. A process for rendering the surface of a polymer antithrombogenic is disclosed.Type: GrantFiled: October 6, 1980Date of Patent: April 27, 1982Assignee: Minnesota Mining and Manufacturing CompanyInventor: Walton J. Hammar
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Patent number: 4289171Abstract: Disclosed is a packaging material, comprising a fibrous base web wherein at least a part of the fibers forming said base web include at least a partial coating of a mixture of chemical substances which comprise a predominant proportion of a chemical binder based on a synthetic water-soluble heat-curable cationic resin precondensate and of a minor proportion of at least one coloring chemical substance, the proportions being relative to the total weight of the mixture of substances. Also disclosed is a method of manufacturing this packaging material and a sausage casing made therefrom.Type: GrantFiled: May 29, 1979Date of Patent: September 15, 1981Assignee: Hoechst AktiengesellschaftInventor: Felix Rassbach
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Patent number: 4163816Abstract: Silver diffusion transfer image-receiving elements are formed by hydrolyzing a solution of a hydrolyzable cellulose ester, coating a support with a layer of said hydrolyzed cellulose ester and disposing silver precipitating nuclei therein.Type: GrantFiled: October 27, 1977Date of Patent: August 7, 1979Assignee: Polaroid CorporationInventors: Robert D. Eckert, Boris Levy, John B. Mahoney
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Patent number: 4138535Abstract: A polysaccharide or polyvinyl alcohol containing a mixture of nitrite ester groups with sulfate or nitrate ester groups with the mixture of ester groups being substantially uniformly distributed among the polymer units of the polysaccharide or polyvinyl alcohol.A nitrite ester of a polysaccharide alcohol having a degree of substitution of less than about 2.0. A nitrite ester of polyvinyl alcohol having a degree of substitution of 1.0 or less.Type: GrantFiled: April 18, 1977Date of Patent: February 6, 1979Inventor: Richard G. Schweiger
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Patent number: 4136218Abstract: Process for improving the water-absorbing capacity and absorptivity of fibrous materials consisting of, or containing, synthetic fibers or filaments, which comprises applying modified, highly absorbing cellulose ethers onto the fibrous materials and fixing these cellulose ethers on the fibrous material with the aid of finishing agents, resins or binders.Type: GrantFiled: August 27, 1975Date of Patent: January 23, 1979Assignee: Hoechst AktiengesellschaftInventors: Ehrenfried Nischwitz, Arno Holst, Ottokar Smerz, Michael Kostrzewa, Helmut Lask
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Patent number: 4107071Abstract: Microcapsules having a capsule core material surrounded by a relatively impermeable, densified protective wall and a method of producing such microcapsules are disclosed. To produce the microcapsules, an agitated system is provided including a liquid vehicle as a major component of the system and constituting a continuous first phase of the system. A plurality of discrete capsule core material entities are dispersed in the liquid vehicle and constitute a discontinuous second phase. A film-forming, cross-linkable, polymeric base material is also present in the liquid vehicle and, upon induction of phase separation within the agitated system, forms a sheath about the capsule core material entities. The formed sheath also contains entrapped liquid vehicle; however, a major portion of the entrapped liquid vehicle is subsequently extracted from the sheath, and the resulting densified polymeric base material in the sheath is then cross-linked to form a densified protective wall around the capsule core material.Type: GrantFiled: February 16, 1977Date of Patent: August 15, 1978Assignee: Capsulated Systems, Inc.Inventor: Robert G. Bayless
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Patent number: 4076772Abstract: A method for manufacturing large, nonplanar, transparent, gelatin-coated ymer sheets is disclosed. These sheets when sensitized, exposed, and developed can record and display holograms. A poly(methyl methacrylate) sheet is coated with nitrocellulose, the nitrocellulose is denitrated, and a gelatin solution is applied, then hardened. The sheet with its gelatin film is then thermally formed to any desired three-dimensional configuration.Type: GrantFiled: March 29, 1976Date of Patent: February 28, 1978Assignee: The United States of America as represented by the Secretary of the NavyInventors: Warren J. Murbach, Arnold Adicoff
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Patent number: 4067688Abstract: The present invention relates to a durable press process for cellulosic fiber-containing fabrics which utilizes formaldehyde and an aryl sulfonic acid catalyst to impart wrinkle resistance to the fabric.Type: GrantFiled: April 14, 1976Date of Patent: January 10, 1978Assignee: The Strike CorporationInventor: George Louis Payet
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Patent number: 4035569Abstract: Preparation of partially substituted nitrate and sulfate esters of polysaccharides or polyvinylalcohol, their esters containing a mixture of nitrite with sulfate or nitrate groups, aqueous media thickened with such esters, the simultaneous preparation of such esters and alkyl nitrites or such esters and inorganic nitrites or nitrates and resulting products, useful as thickeners, films, fibers and in many other applications.Type: GrantFiled: March 23, 1976Date of Patent: July 12, 1977Inventor: Richard G. Schweiger
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Patent number: 4029726Abstract: Polymer-liquid composite materials, particularly of cellulosic polymers such as cellulose nitrate, are described, which materials are strong, transparent, ultramicroporous materials characterized by a diffusion-supporting liquid phase of about 70% or more liquid within an interpenetrating, form-retentive, solid polymer phase. The materials are prepared by precipitation from a hydrogen-bonding solvent solution by the use of a miscible nonsolvent at temperatures generally below about 45.degree. C.Type: GrantFiled: October 29, 1974Date of Patent: June 14, 1977Assignee: Moleculon Research CorporationInventor: Larry D. Nichols
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Patent number: 4025455Abstract: This invention relates to a process for forming microcapsules comprising the steps of preparing an aqueous solution containing a hydroxypropylcellulose wall forming compound, the hydroxypropylcellulose wall forming compound containing reactive hydroxyl groups and being characterized by having decreasing solubility with increasing temperature in aqueous solution. An oil solution is prepared containing an oil soluble cross-linking agent for the hydroxypropylcellulose wall forming compound in an oil to be encapsulated, the oil soluble cross-linking agent being a polyfunctional isocyanate containing more than one group capable of reacting with hydroxyl groups to provide cross-linkage with the hydroxypropylcellulose wall forming compound. The aqueous solution containing hydroxypropylcellulose is mixed with the oil solution containing the cross-linking agent in a manner such that an emulsion is formed having droplets of the oil solution dispersed in the aqueous solution.Type: GrantFiled: April 2, 1976Date of Patent: May 24, 1977Assignee: The Mead CorporationInventor: Dale Richard Shackle
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Patent number: 3999992Abstract: The adherence of a magnetic sound strip to the surface of an anti-halation layer of a multi-layer motion picture film including at least one light-sensitive emulsion layer is enhanced by using as the alkali-soluble binder of the anti-halation layer a polymer containing free carboxyl groups and including in the coating composition of the magnetic strip an organic compound which contains at least two reactive halogen atoms reactive with the polymer carboxyl groups.Type: GrantFiled: February 21, 1974Date of Patent: December 28, 1976Assignee: AGFA-GEVAERT N.V.Inventors: August Jean Van Paesschen, Joseph Antoine Herbots
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Patent number: RE30459Abstract: A polysaccharide or polyvinyl alcohol containing a mixture of nitrite ester groups with sulfate or nitrate ester groups with the mixture of ester groups being substantially uniformly distributed among the polymer units of the polysaccharide or polyvinyl alcohol.A nitrite ester of a polysaccharide alcohol having a degree of substitution of less than about 2.0. A nitrite ester of polyvinyl alcohol having a degree of substitution of 1.0 or less.Type: GrantFiled: April 26, 1979Date of Patent: December 23, 1980Inventor: Richard G. Schweiger