Abstract: Process for depositing a coating for protection against oxidation and against hot corrosion on a superalloy substrate, and coating obtained The present invention relates to a process for depositing a coating for protection against oxidation and against hot corrosion on a metallic superalloy substrate (1), characterized by the fact that it comprises the deposition of the following successive layers on the substrate, a first layer of aluminium and of at least one element capable of being alloyed with sulphur, a second layer of a material that isolates said element capable of being alloyed with sulphur. The element capable of being alloyed with sulphur is chosen from the reactive elements: zirconium, hafnium, yttrium, silicon, and the rare earth elements: cerium, lanthanum, gadolinium. The invention also relates to the coating thus formed.

Abstract: Accordingly, in various embodiments, the present invention provides methods for making electrochemically active materials. Methods include making an electrochemically active material by reacting a platinum group metal salt in a organic solvent to yield a mixture, then heating the mixture to create a metal-organic solvent complex and an acid, followed by removing at least a portion of the acid, and yielding an electrochemically active material comprising the metal-organic solvent complex. In an exemplary embodiment, the resulting electrochemically active material may be used for coating an electrode.

Abstract: Photovoltaic conductive features and processes for forming photovoltaic conductive features are described. The process comprises (a) providing a substrate comprising a passivation layer disposed on a silicon layer; (b) depositing a surface modifying material onto at least a portion of the passivation layer; (c) depositing a composition comprising at least one of metallic nanoparticles comprising a metal or a metal precursor to the metal onto at least a portion of the substrate; and (d) heating the composition such that it forms at least a portion of a photovoltaic conductive feature in electrical contact with the silicon layer, wherein at least one of the composition or the surface modifying material etches a region of the passivation layer. When the surface modifying material is a UV-curable material, the process comprises the additional step of curing the UV-curable material.

Abstract: This specification describes the use of a composition comprising a nanoscale powder, a porous ceramic powder and a solvent for protecting a metallic surface against chemical attacks at high temperatures, in particular in a reducing and/or carburizing atmosphere, and also a corresponding process. Furthermore, this specification describes a plant part having a metallic surface which, in the operating state, is exposed to a reducing and/or carburizing atmosphere, wherein the surface is coated with a porous protective coating having a specific surface area of at least 20 m2/g.

Abstract: Oxidation resistant components and methods for creating an aluminum diffusion surface layer within substantially nickel- and cobalt-free components are disclosed. An aluminum-containing slurry may be applied to a component. The component may then be heated to diffuse aluminum into the component and to form an aluminum diffusion surface layer therein. The surface layer may be characterized by an intermetallic aluminum-containing phase extending below the surface of the component.

Abstract: A method including forming a first layer comprising a non-hexavalent chromium chemical conversion coating on a metal surface; and forming a second layer on the first layer through a sol gel process. An apparatus including a metal component having at least one surface; a first layer comprising a chemical conversion coating on the at least one surface; and a second layer derived from a sol gel composition on the first layer.

Abstract: Methods are provided for bonding pure rhenium to a substrate comprising a material. Non-lubricated components configured to have friction contact with another component are also provided. In an embodiment, by way of example only, a method includes disposing a eutectic alloy over the substrate to form an inter layer, the eutectic alloy comprised essentially of a base alloy and one or more melting point depressants and having a melting temperature that is lower than a melting temperature of the substrate material and a melting temperature of rhenium, placing pure rhenium over the inter layer, and heating the inter layer to a temperature that is substantially equal to or greater than the melting temperature of the eutectic alloy, but that is below the melting temperature of the substrate material and the melting temperature of the pure rhenium to bond the pure rhenium to the substrate.

Abstract: A superalloy article which comprises a substrate comprised of a superalloy, a bond coat comprised of MCrAlY wherein M is a metal selected from the group consisting of cobalt, nickel and mixtures thereof applied onto at least a portion of the substrate and a ceramic top coat applied over at least a portion of the bond coat. The bond coat is exposed to a temperature of within the range of between about 1600-1800° F. subsequent to its application onto the substrate.

Abstract: Organometallic coatings or films, substrates coated with such films and methods for applying the films to the substrates are disclosed. The organometallic film or coating is derived from a transition metal compound containing both halide ligands and alkoxide ligands. Coated articles comprising polymer substrates and adhered to the substrate surface an organometallic film in which the metal comprises halide and alkoxide ligands are also disclosed.

Abstract: Orientation degree and smoothness of a substrate surface better than those of conventional ones are provided in a textured substrate for epitaxial thin film growth. The present invention is a textured substrate for epitaxial film formation, including a crystal orientation improving layer made of a metal thin film of 1 to 5000 nm in thickness on the surface of the textured substrate for epitaxial film formation having a textured metal layer at least on one surface, wherein differences between orientation degrees (?? and ??) in the textured metal layer surface and orientation degrees (?? and ??) in the crystal orientation improving layer surface are both 0.1 to 3.0°. Further, when another metal different from the metal constituting this textured substrate crystal orientation improving layer is added equivalent to a thin film which is 30 nm or less, and subsequently is subjected to heat treatment, the smoothness of that surface can be improved.

Abstract: A method for manufacturing a superconducting wire includes the following steps. A laminate metal having a first metal layer and a Ni layer formed on the first metal layer is prepared. An intermediate layer is formed on the Ni layer of the laminate metal. A superconducting layer is formed on the intermediate layer. By subjecting the laminate metal to a heat treatment after at least either of the step of forming a intermediate layer and the step of forming a superconducting layer, a nonmagnetic Ni alloy layer is formed from the laminate metal.

Abstract: A member having a coating film capable of suppressing whisker generation is provided. The coating film (3) including a plurality of crystalline grains (3a) made of tin or tin alloy is formed above the surface of the base member (1). An intermetallic compound (3b) of tin and the first metal is being formed along the crystalline grain boundaries of the coating film.

Abstract: A method of fabricating an interconnection between a region of copper material and a conducting region is disclosed. The method includes a step of forming a region of tin material and a step of forming a region of nickel material. The method also includes a step of melting the tin material to induce formation of a nickel/tin/copper intermetallic composition at an interface between the region of copper material and the conducting region. The region of tin material and the region of nickel material define the interface between the region of copper material and the conducting region.

Abstract: The present invention provides a method for preparing an electroless nickel coating composition that includes (a) coating a substrate with an electroless nickel coating to provide a coated substrate; and (b) subjecting the coated substrate to a heating protocol comprising heating to a temperature in a range from about 550° C. to about 700° C. for a period of from about 7 to about 30 hours. An article made from the method is also provided.

Abstract: A catalyst support is made by coating a metal substrate with a solution containing a precursor for a ceramic and an amphiphilic compound, and treating the coating such that it forms a micelle structure. The coating is then treated to form a mesoporous ceramic coating on the metal substrate. The micelle structure acts as a template, so that the pores are of regular size. The active catalytic material can then be deposited in the pores. The metal substrate may for example be a corrugated foil, which can enable reaction heat to be dissipated from hot spots.

Abstract: Aluminum, magnesium, and steel can be warm formed through use of a solid, warm forming lubricant which is a metal or metal alloy, or high melting temperature polar polymer. The parts can be painted directly after warm forming.

Abstract: Disclosed is a neutral to alkaline inorganic chrome-free conversion coating composition that can be applied directly to a metal surface without a phosphatizing pre-treatment and that provides significant corrosion protection to the surface. The conversion coating composition preferably has a pH of from about 6 to 11 and more preferably from 8 to 10. The coating composition includes at least one element from group IVB of the Periodic table and at least one element from group VB of the Periodic Table. Preferably, the coating composition includes from 1 to 7% by weight of the at least one element from group IVB and from 0.20% to 2.00% by weight of the at least one element from group VB. The conversion coating composition is a dry in place coating and being chrome free it does not have the environmental issues associated with chrome-based coatings.

Abstract: The object of the present invention is to form a chromium-oxide film excellent in corrosion resistance without containing an oxide film of other metal onto the optional metallic material. The chromium-oxide passivation film excellent in corrosion resistance without containing the oxide film of other metal can be formed inexpensively and in a short time, and a fluid supplying system for supplying fluid hard in corrosivity in safety is able to be provided. This invention comprises a step of forming the passivation film consisting of a chromium oxide by giving heat treatment in an oxidizing atmosphere after coating chromium on metallic material of which surface roughness (Ra) of a coat surface is not more than 1.

Abstract: A method with enhanced safety characteristics of depositing a kesterite film, which includes a compound of the formula: Cu2?xZn1+ySn(S1?zSez)4+q, wherein 0?x?1; 0?y?1; 0?z?1; ?1?q?1. The method includes contacting an aqueous solvent, ammonia, a source of hydrazine, a source of Cu, a source of Sn, a source of Zn, a source of at least one of S and Se, under conditions sufficient to form an aqueous dispersion which includes solid particles; applying the dispersion onto a substrate to form a thin layer of the dispersion on the substrate; and annealing at a temperature, pressure, and length of time sufficient to form the kesterite film. An annealing composition and a photovoltaic device including the kesterite film formed by the above method are also provided.

Abstract: A composite material for an electric/electronic part, having a metal base, a resin film on at least a part of the metal base, and a layer of Sn or a Sn alloy on at least a part of the metal base at a site where the resin film is not provided, the layer of Sn or a Sn alloy including a solidified structure, and the resin film having a residual solvent quantity adjusted to 5% to 25% by mass.

Abstract: A metallic article for high temperature applications such as a turbine engine component is protected by a thermal barrier coating system on the article's metallic substrate. The thermal barrier coating system includes a bond coat layer of aluminum containing alloy on the metal substrate, an alumina layer on the bond coat layer and a ceramic thermal barrier layer on the alumina layer. The bond coat layer is doped with elemental barium that enhances the creep resistance of the alumina layer, thus, minimizing spallation of the ceramic thermal barrier layer.

Abstract: A protective coating system includes a coating having a composition that includes about 5-40 wt % of chromium, of about 5-35 wt % of aluminum, about 0.1-9 wt % of at least one of silicon, hafnium, or magnesium, about 0.05-2 wt % of a Group IIIB Periodic Table element, a non-zero amount less than 13 wt % of at least one noble metal selected from platinum, palladium, and gold, and a balance including nickel, cobalt or iron.

Abstract: Method includes providing a superalloy substrate such as a turbine disk, a turbine seal, a turbine blade, a turbine nozzle, a turbine shroud, or a turbine frame or case having an under platform or non-gas path region; and providing a predominantly gamma-prime nickel aluminide intermetallic ductile corrosion and oxidation resistant coating disposed on at least a portion of the substrate. The coating comprises from about 15 to about 30 atomic % aluminum, up to about 20 atomic % chromium, optionally, up to about 30 atomic % of at least one platinum group metal, optionally, up to about 4 atomic % of at least one reactive element, and optionally, up to about 15 atomic % of at least one strengthening element, and a balance being essentially nickel or nickel and at least one of cobalt, iron, or cobalt and iron. A coating precursor composition may be applied to the substrate before or after optional plating with one or more platinum group metals.

Abstract: A device fabrication method, according to which a tin-copper-alloy layer is formed adjacent to a copper-plated pad or pin that is used to electrically connect the device to external wiring. Advantageously, the tin-copper-alloy layer inhibits copper dissolution during a solder reflow process because that layer is substantially insoluble in liquid Sn—Ag—Cu (tin-silver-copper) solder alloys under typical solder reflow conditions and therefore shields the copper plating from direct physical contact with the liquefied solder.

Abstract: The invention relates to a contact unit and particularly a solder pin, and a method for producing a contact unit, comprising a body having a metal core and a tin layer surrounding the metal core. The tin layer is thereby designed as a duplex layer, and comprises a radially inner layer overlay of matte tin and a radially outer layer overlay of glossy tin.

Abstract: A modified coffee-stain method for producing self-organized line structures and other very fine features that involves disposing a solution puddle on a target substrate, and then controlling the peripheral boundary shape of the puddle using a control structure that contacts the puddle's upper surface. The solution is made up of a fine particle solute dispersed in a liquid solvent wets and becomes pinned to both the target substrate and the control structure. The solvent is then caused to evaporate at a predetermined rate such that a portion of the solute forms a self-organized “coffee-stain” line structure on the target substrate surface that is contacted by the peripheral puddle boundary. The target structure is optionally periodically raised to generate parallel lines that are subsequently processed to form, e.g., TFTs for large-area electronic devices.

Abstract: Hot dip galvanized steel sheet excellent in shapeability and plateability comprised of high strength steel sheet according to the present invention can be provided containing, by mass % about, C: 0.05 to 0.25%, Si: 0.3 to 2.5%, Mn: 1.5 to 2.8%, P: 0.03% or less, S: 0.02% or less, Al: 0.005 to 0.5%, N: 0.0060% or less and the balance of Fe and unavoidable impurities. The exemplary steel sheet can have thereon a galvanized layer containing, e.g., about Al: 0.05 to 10 mass % and Fe: 0.05 to 3 mass % and the balance of Zn and unavoidable impurities. Such exemplary hot dip galvanized steel sheet can have oxides containing Si in an average content of about 0.6 to 10 mass % at the crystal grain boundaries and in the crystal grains at the sheet steel side 5 ?m or less from the interface between the high strength steel sheet and the plating layer and by the presence of Fe—Zn alloy with an average grain size of about 0.5 to 3 ?m at the plating side.

Abstract: Methods of aluminizing the surface of a metal substrate. The methods of the present invention do not require establishment of a vacuum or a reducing atmosphere, as is typically necessary. Accordingly, aluminization can occur in the presence of oxygen, which greatly simplifies and reduces processing costs by allowing deposition of the aluminum coating to be performed, for example, in air. Embodiments of the present invention can be characterized by applying a slurry that includes a binder and powder granules containing aluminum to the metal substrate surface. Then, in a combined step, a portion of the aluminum is diffused into the substrate and a portion of the aluminum is oxidized by heating the slurry to a temperature greater than the melting point of the aluminum in an oxygen-containing atmosphere.

Abstract: A rust-proof coating, which does not contain a hazardous metal such as chromium and is able to form a thin coating in which crack generation is inhibited even after a baking treatment at a high temperature, including based on the whole composition, 5 to 40% by weight of an organic silicon compound, 0.05 to 5.0% by weight of an organic titanium compound, 20 to 60% by weight of one or more metal powders selected from the group of zinc powder, zinc alloy powder, and aluminum powder, and 10 to 60% by weight of an organic solvent. A coating having excellent anticorrosive properties can be formed by coating the above-mentioned paint composition followed by heating at a temperature of from 200 to 400 degrees C.

Abstract: There is provided a zinc alloy coated steel sheet including a vacuum deposited layer capable of improving corrosion resistance and sealer adhesion that are suitable for the use in automobiles, and a process of manufacturing the same. The zinc alloy coated steel sheet includes a zinc coating layer formed on a steel sheet; and a zinc/metal alloy deposited layer formed on the zinc coating layer, wherein the zinc coating layer, and a metal diffusion layer is present in the zinc coating layer.

Abstract: A plated material 5, containing: on a conductive substrate 1, an underlayer 2 composed of nickel and the like; an intermediate layer 3 composed of Cu or a Cu alloy being provided thereon; and an outermost layer 4 composed of a Cu—Sn intermetallic compound being provided thereon; and an electric or electronic part using the same.

Abstract: Methods are provided for forming coating systems on advanced single crystal superalloy turbine airfoils. A method includes applying a layer of an additive material onto a substrate, the additive material comprising a precious metal and the substrate comprising a nickel-based superalloy, diffusion heat treating the substrate to form an intermetallic coating which comprises ?-Ni and ??-Ni3Al phases alloyed with the additive material and one or more reactive elements from the substrate including hafnium, yttrium, chromium, and silicon, and finally depositing a thermal barrier coating over the intermetallic coating to form the coating system.

Abstract: A process for protecting a thermal barrier coating (TBC) on a component used in a high-temperature environment, such as the hot section of a gas turbine engine. The process applies a protective film on the surface of the TBC to resist infiltration of contaminants such as CMAS that can melt and infiltrate the TBC to cause spallation. The process generally entails applying to the TBC surface a metal composition containing at least one metal whose oxide resists infiltration of CMAS into the TBC. The metal composition is applied so as to form a metal film on the TBC surface and optionally to infiltrate porosity within the TBC beneath its surface. The metal composition is then converted to form an oxide film, with at least a portion of the oxide film forming a surface deposit on the TBC surface.

Abstract: An aqueous phosphoric bonding solution consists essentially of phosphoric acid, a source of magnesium ions, and a leachable corrosion inhibitor. The bonding solution is stable with respect to inorganic metal particles, such as aluminum, which are admixed to the bonding solution for the preparation of a coating slurry. Metal parts coated with the coating compositions have very satisfactory properties such as heat and corrosion resistance.

Abstract: A method for depositing a platinum-group-containing layer on a substrate includes furnishing the substrate, and preparing a water-base paint containing metallic platinum-group powder, water, and a binder. The method further includes spraying the water-base paint overlying the substrate to form a platinum-group-containing layer, and thereafter heating the platinum-group-containing layer to interdiffuse the platinum-group-containing layer.

Abstract: In order to simply produce a microstructured body in which metal particles are arranged so as to be fixed to depressions of a metal substrate having at a surface a structure of protrusions and the depressions, a process for producing the microstructured body includes the steps of: (A) preparing a metal substrate 11 with a surface having a structure of protrusions and depressions; (B) forming a metal film 21 on the surface of the metal substrate 11, where the metal film 21 contains as the main component a metal different from the constituent metal of the metal substrate 11; and (C) annealing the metal film so that the constituent metal of the metal film is coagulated into particles.

Abstract: Conventionally, cavities and cracks are filled with a solder metal which forms brittle phases with a subsequently applied coating, which have a negative effect on the mechanical properties. According to the invention, the components which form brittle phases are removed from the solder metal. The above is achieved, whereby a second material is applied which reacts with said component and which is removed again with the brittle phases, before the coating.

Abstract: In one embodiment, a method for forming an aluminide coated article comprises: applying an aluminum composition to the article to form a precursor coating, heating the article to a migration temperature sufficient to diffuse a metal from the article into the precursor coating, and gasifying aluminum in the aluminum composition at a gasification temperature that is greater than or equal to the migration temperature. An outward grown aluminide coating forms on the article. In another embodiment, a method for forming an aluminide coated article, comprises: applying an aluminide composition an article to form a precursor coating, heating the article to a migration temperature of greater than or equal to 1,065° C., gasifying the aluminum at a gasification temperature of greater than or equal to 1,065° C., and forming an outward grown aluminide coating on less than 100% of a surface of the article.

Abstract: A nickel-base superalloy substrate includes a surface region having an integrated aluminum content of from about 18 to about 24 percent by weight and an integrated platinum content of from about 18 to about 45 percent by weight, with the balance components of the substrate. The substrate is preferably a single-crystal advanced superalloy selected for use at high temperatures. The substrate may optionally have a ceramic layer deposited over the platinum-aluminide region, to produce a thermal barrier coating system. The platinum-aluminide region is produced by diffusing platinum into the substrate surface, and thereafter diffusing aluminum into the substrate surface.

Abstract: A metallic article for high temperature applications such as a turbine engine component is protected by a thermal barrier coating system on the article's metallic substrate. The thermal barrier coating system includes a bond coat layer of aluminum containing alloy on the metal substrate, an alumina layer on the bond coat layer and a ceramic thermal barrier layer on the alumina layer. The bond coat layer is doped with elemental barium that enhances the creep resistance of the alumina layer, thus, minimizing spallation of the ceramic thermal barrier layer.

Abstract: A component such as a gas turbine engine component has an oxidation protective layer formed as a substrate surface region in a substrate of the component. The substrate has a nickel-based composition including nickel and an aluminum proportion of greater than 4.5 weight %. The surface region is formed by diffusion of at least platinum into the substrate surface region to provide an integrated platinum proportion of 5 to 40 weight percent over the integration depth range in the surface region.

Abstract: A belt-type continuously variable transmission (15) includes a primary sheave (29) having a pair of first clamp surfaces (37a, 37b), a secondary sheave (30) having a pair of second clamp surfaces (51a, 51b), and a belt (31) endlessly wound between both the sheaves (29, 30). The belt (31) has contact surfaces (58a, 58b) clamped between the first clamp surfaces (37a, 37b) and between the second clamp surfaces (51a, 51b). Powder (64) having infusibility as a friction enhancing material is held on at least one of the first clamp surfaces (37a, 37b) of the primary sheave (29), the second clamp surfaces (51a, 51b) of the secondary sheave (30), and the contact surfaces (58a, 58b) of the belt (31).

Abstract: A bonding or superfine wire is provided made of copper, with a gold enrichment on the surface thereof, in particular in an amount corresponding to a coating of at most 50 nm. The wire may be bonded by the ball/wedge method, has a copper-colored appearance, and the ball thereof after flame-off has a hardness of less than 95 according to HV0.002. In order to produce the bonding or superfine wire, a copper wire is coated with gold or a copper-gold alloy or gold is introduced into the surface of the copper wire. The wires are bonded to a semiconductor silicon chip.

Abstract: In a method for coating a substrate, and a coated object, in a first step, in an external current-less or electrolytic manner, nickel and/or cobalt and/or platinum are deposited on a substrate in a deposition bath. In the deposition bath, particles are additionally suspended which contain at least one metal selected from Mg, Al, Ti, Zn and no Cr, the particles becoming occluded in the coating. In a second step, the actual protective layer is produced by heat treatment. The coating of component parts may be used for aircraft turbines or gas turbines or for garbage incineration systems having temperature-resistant protective layers against high temperature corrosion.

Abstract: A rust inhibitor which ensures the simplicity of application typical for a coating process and can demonstrate excellent characteristics similar to those obtained with a metal spraying method. The rust inhibitor is manufactured by admixing zinc and aluminum as fine powders of inorganic metals, which are manufactured with a stamping mill to have a flaky shape, to a modified silicone resin solution. A silane-type silicone resin is used for the modified silicone resin solution. For example, a mixed solution of an organosilane-type silicone resin and an oligomer-type silane coupling agent and the like is used.

Abstract: Methods and articles are disclosed. The methods are directed to depositing nickel duplex layers on substrates to inhibit tin and tin alloy surface oxidation and improve solderability of the substrates.

Abstract: A method for making a gas turbine engine turbine blade comprising an airfoil section a platform section, an under platform section, and a dovetail section, the exterior surface of the dovetail section comprising a shank exterior surface and a serrated exterior surface. The blade further includes a silicon-modified diffusion aluminide layer a surface of a turbine blade section selected from the group consisting of the exterior surface of the under platform section, the exterior surface of the dovetail section, and combinations thereof, the aluminide layer having a concentration of silicon at a surface of the aluminide layer in the range of about 1 weight percent to about 10 weight percent and a concentration of aluminum at the surface of the aluminide layer in the range of about 5 weight percent to about 25 weight percent.

Abstract: Methods are provided for bonding pure rhenium to a substrate comprising a material. Non-lubricated components configured to have friction contact with another component are also provided. In an embodiment, by way of example only, a method includes disposing a eutectic alloy over the substrate to form an inter layer, the eutectic alloy comprised essentially of a base alloy and one or more melting point depressants and having a melting temperature that is lower than a melting temperature of the substrate material and a melting temperature of rhenium, placing pure rhenium over the inter layer, and heating the inter layer to a temperature that is substantially equal to or greater than the melting temperature of the eutectic alloy, but that is below the melting temperature of the substrate material and the melting temperature of the pure rhenium to bond the pure rhenium to the substrate.

Abstract: Exemplary embodiments of the present invention can provide a hot dip galvannealed steel sheet which has excellent corrosion resistance, workability, coatability and appearance. The exemplary galvannealed sheet can include an ultra-low carbon steel sheet having a plating layer which includes about 8 to 13% Fe, about 0.05 to 1.0% Ni, about 0.15 to 1.5% Al, and a balance of Zn and unavoidable impurities. An exemplary method for producing a hot dip galvannealed steel sheet is also provided which can include cleaning an annealed ultra-low carbon steel sheet, preplating it with Ni, rapidly heating the sheet in a nonoxidizing or reducing atmosphere, plating the sheet in a galvanization bath containing Al, wiping it, then rapidly reheating it and either cooling the sheet without any soaking time or soaking and holding it for less than 15 seconds and then cooling it.

Abstract: A quasi-single phase or single phase thick platinum nickel aluminide coating and methods for forming the coating over a nickel-based superalloy substrate are provided. The method includes the steps of forming a metal layer over a surface of the nickel-based superalloy substrate, the metal layer comprising platinum, growing a diffusion zone comprising a platinum nickel alloy layer from the metal layer and the nickel-based superalloy substrate, and subjecting the platinum nickel alloy to one or more aluminization cycles to transform the platinum nickel alloy into a platinum nickel aluminide coating having a platinum aluminide phase formed therein.