Abstract: A barrier layer for a silicon containing substrate which inhibits the formation of gaseous species of silicon when exposed to a high temperature aqueous environment comprises a barium-strontium alumino silicate.

Abstract: A silicon oxide film has a ratio of A1 to A2 which is not higher than 0.21, where A1 is a first peak integrated intensity of a first peak belonging to Si—OH and appearing in the vicinity of a wave-number of 970 cm−1, and A2 is a second peak integrated intensity of a second peak belonging to O—Si—O and appearing in the vicinity of a wave-number 820 cm−1, and each of the first and second peak integrated intensities is defined as a product of peal width at half height and a peak height of a Raman spectrum obtained by a Raman scattering spectroscopic analysis of the silicon oxide film. The silicon oxide film is deposited under a condition that a ratio of a first flow rate Fo of oxygen gas to a second flow rate Fsi of a silicon source gas is not lower than 20.

Abstract: A ceramic welding process for the formation of a coherent refractory repair mass on a surface of an electrocast refractory material includes providing an electrocast refractory material having a surface to be repaired; providing a first powder mixture comprised of combustible particles, refractory particles, and at least one constituent which enhances production of a vitreous phase in the coherent refractory repair mass; and projecting the first powder mixture in a gas stream containing oxygen against the surface to be repaired so that the combustible particles react with the projected oxygen against the surface in a highly exothermic manner and release sufficient heat of combustion to form a first coherent refractory repair mass.

Abstract: A method for forming a thermal barrier coating system on a turbine engine component includes forming a bondcoat on the turbine engine component and depositing a thermal barrier coating so as to overlie the bondcoat. The bondcoat is formed by thermally co-spraying first and second distinct alloy powders on the turbine engine component forming an oxidation-resistant region, and thermally spraying a third alloy powder on the oxidation-resistant region to form a bonding region.

Abstract: A thermal spray material includes a mixture of 5-30 weight % of an AlSi alloy powder with 95-70 weight percent of a cast iron powder to provide abrasion resistance for aluminum alloy parts. The AlSi alloy powder contains 12-30 weight % Si, at least one element selected from a group consisting of 0.5-5.0 weight % Cu and 0.2-3.0 weight % Mg, 1-15% of at least one element selected from the group consisting of Fe, Mn, and Ni, and a mass balance of Al. The cast iron powder contains 2-4 weight % C, no more than 0.3 weight % Si, and 0.5-3.0 weight % P. A sliding surface of a sliding member is thermal sprayed with a coating of this thermal spray material to provide a sliding member having excellent abrasion resistance.

Abstract: A metal article which includes a protective coating system is described. The coating system includes a braze alloy layer and a plasma-sprayed bond coat. The bond coat may lie on top of the braze alloy layer, or the braze alloy layer may lie on top of the bond coat. In the case of a porous bond coat, partial or complete densification of the bond coat is sometimes carried out. Densification is achieved by heat treating the article, so that the braze alloy material migrates into the pores of the bond coat to a selected thickness. Related processes are also described.

Abstract: Multi-layer corrosion resistant polymer composite coatings are described wherein a first coating layer is applied by high velocity high temperature spray, thermal spray, plasma spray, fluidized bed, hot melt or electrostatic spray onto an unprepared, particle embedded or alternatively prepared substrate, and the outer surface of the still warm first layer is roughened by embedding particles therein or the outer surface is roughened mechanically, and a second coating layer is applied thereover. Filler powder may be added to one or both of the layers to substantially match the thermal expansion coefficients of the two layers.

Abstract: A packaging laminate (10) including a substrate film (15) coated with a carbon containing silicon oxide layer (16, 17) on both surfaces is disclosed herein. A method for producing the laminate (10), and blanks and packages fabricated from the laminate are also disclosed herein. The PECVD process of the present invention strains the substrate film (15) during deposition thereby creating a very thin oxide layer with superior durability, oxygen and aroma barrier properties. The carbon-containing silicon oxide coating (16, 17) has a stoichiometry of SiOxCy in which x is witin the range of 1.5-2.2 and y is within the range of 0.15-0.80. The substrate film (15) may include a core layer (12) of a material selected from the group consisting of paper, paperboard, a foamed core, polyethylene terephtalate, polyamide, polyethylene and polypropylene.

Abstract: A material wire for producing wear-resistant and tribologically favorable surface coatings from a supereutectic Al/Si alloy by thermal spraying. The material wire is a filling wire that has a sheath made of metallic aluminum and a filling made of one or more additional alloy components.

Abstract: There is provided a method for applying a lower viscosity coating liquid onto a semiconductor wafer substrate so as to prevent adhesion loss and to maintain low defect level characteristics. This is achieved by priming the substrate with a bonding agent at a temperature in the range of 18° C. to 50° C. for a short amount of time. This is performed prior to the application of a liquid solvent. As a result, there is overcome the problems of poor adhesion to the substrates and high defect levels in the coated UTR films.

Abstract: A material in powder or wire form on a nickel basis for the production of a coating with a high level of resistance to corrosion and wear by means of a thermal coating process is of the following composition (in percent by weight): C 0.005-1.0;  Cr 10.0-26.0; Mo  8.0-20.0; Fe  0.1-10.0; Si 3.0-7.0; B 1.0-4.0; Cu 0.1-5.0; Ni Balance. The material in powder form can be alloyed and sprayed out of the melt or agglomerated out of different alloyed and non-alloyed metal powders. The coating material can also be used in the form of a filling wire or an alloyed and cast bar material.

Abstract: A barrier layer for a silicon containing substrate which inhibits the formation of gaseous species of silicon when exposed to a high temperature aqueous environment comprises a yttrium silicate.

Abstract: An integral, lightweight combustion chamber/nozzle assembly for a rocket engine has a refractory metal shell defining a chamber of generally frusto-conical contour. The shell communicates at its smaller end with a rocket body, and terminates at its larger end in a generally contact contour, which is open at its terminus and which serves as a nozzle for the rocket engine. The entire inner surface of the refractory metal shell has a thermal and oxidation barrier layer applied thereto. An ablative silica phenolic insert is bonded to the exposed surface of the thermal and oxidation barrier layer. The ablative phenolic insert provides a chosen inner contour for the combustion chamber and has a taper toward the open terminus of the nozzle. A process for fabricating the integral, lightweight combustion chamber/nozzle assembly is simple and efficient, and results in economy in respect of both resources and time.

Abstract: A process for depositing a mullite coating on a silicon-based material, such as those used to form articles exposed to high temperatures and including the hostile thermal environment of a gas turbine engine. The process is generally to thermally spray a mullite powder to form a mullite layer on a substrate, in which the thermal spraying process is performed so that the mullite powder absorbs a sufficient low level of energy from the thermal source to prevent evaporation of silica from the mullite powder. Processing includes deposition parameter adjustments or annealing to maintain or reestablish phase equilibrium in the mullite layer, so that through-thickness cracks in the mullite layer are avoided.

Abstract: A method for protecting a synthesis gas generator burner heat shield includes coating the burner heat shield with an overlay alloy coating composition of the formula MCrAlY wherein M is selected from the group consisting of iron, nickel, and cobalt. In a preferred embodiment, the coating includes from about 20-40 weight % Co, 5-35 weight % Cr, 5-10 weight % Ta, 0.8-10 weight % Al, 0.5-0.8 Y, 1-5 weight % Si and 5-15 weight % Al2O3.

Abstract: A barrier layer for a silicon containing substrate which inhibits the formation of gaseous species of silicon when exposed to a high temperature aqueous environment comprises a calcium alumino silicate.

Abstract: This invention relates to methods whereby nanoparticle precursor solutions are used in conventional thermal spray deposition for the fabrication of high-quality nanostructured coatings. The method allows combining nanoparticle synthesis, melting, and quenching into a single operation.

Abstract: The deposit of natural or synthetic silica comprises a preform (1) set into rotation (7) in front of a plasma torch (3) which moves back and forth substantially parallel to a longitudinal direction (L) of the preform (1), a feed duct (9) for feeding the plasma with grains of natural or synthetic silica (11), characterized in that the same feed duct (9) feeds the plasma with a fluorine or chlorine compound, preferably a fluorine compound, mixed with a carrier gas (15). Sodium or lithium contained in the grains of natural or synthetic silica reacts with the fluorine or chlorine of the fluorine or chlorine compound, making it possible to improve the optical quality of fibers built up with the natural or synthetic silica at reduced cost.

Abstract: A method of producing a nanocomposite coating without gaseous precursor reactants. A non-nanocrystalline particulate containing a polymorphic material in an atmospheric phase is introduced into a high-velocity gas jet. The projected particulate is allowed to impact a substrate at a velocity effective to cause at a least a portion of the polymorphic material to transform to a nanocrystalline, high pressure phase.

Abstract: A method for applying a porous coating incorporating a tricomponent powder mixture deposited on a hard substrate (i.e. metallic or ceramic) by plasma spraying. The coating has high adhesion strength to the substrate, with outstanding thermo-mechanical characteristics and with good resistane to thermal or mechanical action. The mixure includes aluminum oxide and/or titanium oxide powder and glass powder as the coating's microstructure forming materials; aluminum and/or titanium power metal binder and aluminum hyroxide and/or titanium hydroxide powder as a material assuring the formation of coating's microstructure. Plasma spraying includes passing the powder through the plasma beam, simultaneously melting of the metal oxide, partially alloying components into separate plasma beam zones—the hydroxide to the colder zone, and the metal to the hotter zone. The aluminum particles reach the substrate first and develop the adhesion of the sprayed layer to the substrate.

Abstract: A method for applying a barrier layer which comprises a barium-strontium aluminosilicate to a silicon containing substrate which inhibits the formation of cracks.

Abstract: A method of preparing a planographic printing member is disclosed. In one embodiment, the method comprises forming a hydrophilic layer by thermally spraying a hydrophilic particulate material onto an ablatable layer. Typical hydrophilic materials are SiO2, Al2O3, Cr2O3, TiO2 and ZrO2. Spraying a plasma containing the hydrophilic material in an inert gas atmosphere is preferred method for forming the hydrophilic layer.

Abstract: Natural or synthetic silica is deposited on a preform set into rotation in front of a plasma torch which moves back and forth substantially parallel to a longitudinal direction of the preform, a first feed duct feeds the plasma with grains of natural or synthetic silica while a second feed duct feeds the plasma with a fluorine or chlorine compound, preferably a fluorine compound, mixed with a carrier gas Any sodium or lithium contained in the grains of natural or synthetic silica react with the fluorine or chlorine of the fluorine or chlorine compound, thereby making it possible to improve the optical quality of fibers drawn from a preform built up with natural or synthetic silica, and to do so at reduced cost.

Abstract: A coating of whisker shaped beta silicon nitride grains are formed upon a silicon nitride substrate by sintering over a period of several hours, and the resulting product has a porous reaction bond coating strongly adhered to the silicon nitride substrate.

Abstract: A hard carbon film is formed over an inner surface of a guide bush by fixing an auxiliary electrode support member for supporting an auxiliary electrode of a jig for forming a film in a center bore of the guide bush by an auxiliary electrode insulation member, disposing an auxiliary electrode in alignment with the axis of the center bore so as to face the inner surface, disposing legs, and a first electrode plate, a second electrode plate, and the insulation member which are fixed to the legs are placed on the bottom of a vacuum vessel placing the guide bush on the first electrode plate contacted electrically with a power source, while the projection of the auxiliary electrode support member projecting out of the auxiliary electrode insulation member is contacted electrically with the second electrode plate.

Abstract: A process for depositing a mullite coating on a silicon-based material, such as those used to form articles exposed to high temperatures and including the hostile thermal environment of a gas turbine engine. The process is generally to thermally spray a mullite powder to form a mullite layer on a substrate, in which the thermal spraying process is performed so that the mullite powder absorbs a sufficient low level of energy from the thermal source to prevent evaporation of silica from the mullite powder. Processing includes deposition parameter adjustments or annealing to maintain or reestablish phase equilibrium in the mullite layer, so that through-thickness cracks in the mullite layer are avoided.

Abstract: A method for preparing a scratch and abrasion resistant surface on unroughened aluminum or stainless steel cookware, for subsequent coating with a nonstick polymer resin, such as a fluoropolymer, in a liquid and/or powder medium. The scratch and abrasion resistant surface consists of a thermally sprayed aluminum or stainless steel, respectively. A metal coated substrate produced by this method and an article subsequently coated with a fluoropolymer surface by this method are also described.

Abstract: A mass of molybdenum disilicide-silicon carbide composite material is prepared by providing a mixture of molybdenum disilicide-silicon carbide precomposited powder, and plasma spraying the precomposited powder onto a substrate using argon-shrouded plasma spray deposition, to form a plasma-sprayed mass. The plasma-sprayed mass may be subsequently heat treated.

Abstract: In a method of coating easily oxidisable materials by plasma powder build-up welding of additive materials in powder form using alternating current or direct current with superimposed alternating current to produce a plasma transferred arc for powder build-up welding in accordance with patent application No 196 26 941.5 a CuNi-alloy is used as an additive welding material with additions (in % by weight) of:______________________________________ Fe below about 10; Cr below about 5; B below about 4; Si below about 4; C with about 1.5; ______________________________________with a degree of mixing of more than 40% by volume.

Abstract: A method of forming a polycrystalline silicon thin layer, which comprises the steps of forming a silicon thin film on a surface of a heat resistant substrate by making use of polycrystalline silicon fine particles as a raw material, and heating the silicon thin film thereby to recrystallize the silicon thin film and hence to enlarge an average particle diameter of the polycrystalline silicon fine particles. The silicon thin film is formed by depositing the polycrystalline silicon fine particles directly on the surface of the substrate, and meets a relationship represented by the following formula (1)W.sub.A /(V.sub.S .multidot.d.sub.S).gtoreq.0.95 (1)wherein W.sub.A is the weight of the polycrystalline silicon fine particles which is actually deposited on the surface of the substrate, V.sub.S is a volume of the silicon thin film which is deposited on the surface of the substrate, and d.sub.S is a density of silicon (Si).

Abstract: A coating for a cylinder bore of a reciprocating engine with an iron, aluminum, or magnesium base comprises a hypereutectic aluminum/silicon alloy. The alloy is applied to a cylinder wall by thermal spraying.

Abstract: The present invention provides a method of making sheet articles, for example, abrasive articles, retroreflective articles (such as traffic signs), pavement marking articles, or traction or non-skid articles. The method includes passing particles through a thermal sprayer to heat the particles and impinging the heated particles into a polymeric sheet so that the particles are at least partially embedded in the polymeric sheet. Preferably, the polymeric sheet is heated before impingement of the heated particles. One preferred method of softening the sheet is by a thermal sprayer that is used to heat the particles. A preferred thermal sprayer is a flame sprayer having a nozzle for emitting a flame, where the nozzle has a cross-web width and a downweb thickness, the width being substantially greater than the thickness.

Abstract: An apparatus for forming a film on a substrate includes a gas inlet and an insert attached to the gas inlet, the insert including a deposition source material such as lithium. To form the film on the substrate, the substrate is mounted in a vacuum chamber. After the vacuum chamber is pumped clown to a subatmospheric pressure, a first process gas such as argon is provided through the gas inlet and insert and into a plasma region proximate the substrate. Power is then coupled to generate a plasma inside of the insert which heats the insert and causes the deposition source material to vaporize. The deposition source material vapor is mixed with a plasma polymerizable material in the plasma region proximate the substrate causing a plasma enhanced chemical vapor deposition (PECVD) thin film such as silicon oxide including the deposition source material (e.g. lithium) to be deposited on the substrate.

Abstract: A method for fabricating a tool used in cutting, grinding and machining operations, is provided. The method is used to deposit a mixture comprising an abrasive material and a bonding material on a tool surface. The materials are propelled toward the receiving surface of the tool substrate using a thermal spray process. The thermal spray process melts the bonding material portion of the mixture, but not the abrasive material. Upon impacting the tool surface, the mixture or composition solidifies to form a hard abrasive tool coating.

Abstract: A granular composition is applied to tips of rotor blades utilized in a gas turbine engine wherein the blade tips rub against an abradable ceramic layer. Individual grains each have a core of silicon carbide and a layer of aluminum nitride on the core. A layer of a cladding metal may be bonded to the aluminum nitride. The composition also may include particles of cubic boron nitride and/or particles of metal alloy blended with the grains of silicon carbide.

Abstract: A process for the deposition of thick coatings with a thickness >1 mm on products made of copper or alloys thereof, wherein said products are subjected to the following operations: surface activation of the product made of copper or alloys thereof; optional heat stabilization to a temperature below the ones causing deterioration of the chemical and physical properties of the copper or alloys thereof; deposition of a first layer, for example of Ni or alloys thereof; optional interdiffusion heat treatment; optional activation of the surface of the first layer; thermal stabilization of said product at a temperature of between 20.degree. and 400.degree. C.

Abstract: A method of fusing a thermal spray coating to a base material employs infrared heating. The thermal spray coating is applied to the base material in a conventional manner. The infrared heater applies unidirectional heat in a first time-temperature relation to the coating during a fusing phase to melt individual coating platelets into a dense layer and to metallurgically bond the coating to the base material. In a base material that is heat treatable, the base material can be heat treated subsequent to the fusing phase. Initial heat treating of the base material occurs during the fusing phase. Continued heat treating of the base material is achieved after the thermal spray coating fusing phase by a second application of time-temperature from the infrared heater. A cold wall process can be used to aid in the quenching phase of the heat treating process.

Abstract: Structural ceramic matrix composite material to be employed as automotive engine parts and the like is provided with erosion-resistant qualities in several ways. For one, an erosion-resistant material is applied to the surface as by plasma spraying. The erosion-resistant material can also be mixed with the fibers of the material, particularly near the surface.

Abstract: All-ceramic retroreflective elements which may be used in pavement markings comprising an opacified ceramic core and ceramic optical elements partially embedded into the core.

Abstract: A method of applying a silica having fluorine therein by spraying silica simultaneously with a fluorine-containing gas by a POD method plasma torch.

Abstract: A method and apparatus for the controlled synthesis and assembly of nanoparticles into nanostructured materials, including nanocomposites, includes a source of nanoparticles and a hypersonic impaction apparatus. The nanoparticles are impacted on a substrate through hypersonic impaction to thereby provide nanostructured materials as well as nanophase materials.

Abstract: Coatings containing at least 85% by volume crystalline mullite with less than 15% by volume of amorphous material and mullite dissociation phases are plasma sprayed onto the surface of a silicon based ceramic substrate by closely controlling the plasma spray parameters including the mullite feed stock and its particle size, the nozzle outlet stand-off distance, movement of the substrate past the plasma flow, back side heating of the substrate and the powder feed rate through the plasma spray gun.

Abstract: This invention is relating to a sputter cathode (1) with a layer of material that is applied to a substrate by sputtering, wherein this layer (3) contains low electrical conductivity particles (3a) of which a certain quantity are at least coated by a film (3b) of electrically conductive material, or which form an aggregate with a conductive material, so as to give this layer (3) sufficient electrical conductivity to be able to be applied to the substrate by means of sputtering.

Abstract: A method and apparatus for reactive plasma surfacing includes at least two electrodes between which reactive gases are passed. The reactive gases are ionized by the arc between the electrodes, creating a plasma of heated, ionized, reactive gases. The plasma is then applied to a surface to be treated, causing a chemical reaction between the plasma and the surface and resulting in a new diffusional substrate surface on the treated object. The process occurs at substantially atmospheric pressure, and may include an inert gas to shield the process from the surrounding environment.

Abstract: In order to produce lightweight mirror structures or other reflecting components, preformed silicon elements of sufficient wall thickness are applied to a CFC or CMC substrate structure with the dimensions of the component to be produced, at a temperature in the range 1300.degree. C. and 1600.degree. C. either in vacuum or in a protective atmosphere. In this way a mirror structure or reflector is formed directly. It is possible to work at temperatures in the range of 300.degree. C. to 600.degree. C. when the silicon is applied in the form of a preform such as a wafer, which is joined to the substrate by way of a zone of a melt eutectic incorporating a nonferrous metal, which is preferably gold. The surfaces are subsequently coated.

Abstract: A high quality shaped article of silicon carbide is efficiently produced by using a carbon substrate suitable for the production of a silicon carbide film without generating cracking or breakage. In a method of producing a shaped article of silicon carbide while using a carbonaceous material as a deposition substrate by decomposing halogenated organic silicone compound by a reduction pyrolysis at a high temperature, forming a silicon carbide film layer on a surface of the substrate by CVD and removing the carbon substrate, the carbon substrate is formed of a composite of graphite and amorphous carbon obtained by shaping and firing a mixture of a powdery graphite and an organic substance.

Abstract: The invention relates to an oxidation inhibitor coating for high-melting metals selected from the group of molybdenum, tungsten, tantalum and niobium and/or alloys thereof. The oxidation inhibitor coating comprises 1 to 14% by weight boron, 0.1 to 4% by weight carbon and the balance silicon.

Abstract: The invention is to a method for producing a high surface substrate. A mask is positioned (31) over a substrate to define a deposition area. Thereafter at least two dissimilar materials are simultaneously deposited (32) through the mask onto the deposition area. Then one of the deposited materials is selectively removed (33) to provide a high surface area deposited substrate.

Abstract: A dielectric image receiving member is disclosed which comprises a substrate layer, a porous plasma-sprayed dielectric layer formed on the surface of the substrate layer, and a dielectric polymeric coating material filling at least those pores opening at the surface of the oxide layer. Most preferably, the plasma-sprayed layer is a metal oxide and the coating material is a glass resin.

Abstract: A method of repairing an oxide-based refractory body by projecting a powder mixture against a hot surface of the body and in the presence of oxygen to provide a refractory repair mass includes providing a powder mixture composed of particles of at least one refractory oxide; fuel particles which react in an exothermic manner with the oxygen to form a refractory oxide and which are particles composed of at least one element selected from the group consisting of magnesium, aluminum, silicon, and mixtures thereof; and particles of silicon carbide present in an amount which is effective to provide a reduced porosity of the refractory repair mass and which does not exceed 10% by weight based on the weight of the powder mixture; and projecting the powder mixture against a hot surface of the oxide-based refractory body and in the presence of oxygen. Preferably, the powder mixture contains at least 1%, most preferably from 1 to 5%, by weight of the particles of silicon carbide.