Abstract: A process of coating an article includes the steps of (1) forming a layer of a ceramic based compound on an article; (2) providing a solution containing a metal as a particulate having a diameter of about 10 nanometers to about 1000 nanometers and present in an amount of about 25 percent to about 50 percent by volume of the solution; (3) contacting the ceramic based compound layer with the solution; (4) drying the article; and (5) optionally repeating steps (3) and (4).

Abstract: The invention relates to a photochemical process for the preparation of an activated polymer surface having an active fluoro group using 1-fluoro-2-nitro-4-azidobenzene to form the activated polymer surface and then immobilizing a biomolecule thereon by forming a covalent bond between the activated polymer surface and the biomolecule.

Abstract: A method of reducing unreacted monomer in a water-soluble or water swellable polymer comprising the steps, i) applying an ultraviolet initiator to the surface of the polymer and ii) irradiating the polymer with ultraviolet light, wherein the ultraviolet initiator is dissolved or dispersed in a liquid medium and in which the liquid medium comprises an organic compound. The method is useful for reducing in the amount of unreacted acrylamide in polyacrylamide. Also claimed is a liquid initiator composition comprising, i) an ultraviolet initiator, and ii) a liquid medium comprising an organic compound. The initiator system is useful for applying to the surface of a polymer, such as polyacrylamide, in the removal of unreacted monomer, such as acrylamide.

Abstract: Dielectric compositions comprising siloxane and polymeric components, as can be used in a range of transistor and related device configurations.

Abstract: Photopolymer resins ate disclosed which includes metal and/or ceramic surface chelating agents to provide strong bonding of the photopolymer resin to the inorganic surface of the first information layer of an optical disc. The resins also include a fast surface cure and glass transition temperature controlling monomers that provides easy stamper separation The disclosed photopolymer resins also include short wavelength (<405 nm) surface cure initiators. The resins may also optionally include shrinkage control oligomers and/or polymer fillers or a combination of both Use of the disclosed resins eliminates two steps from the manufacture of a multiple information layer optical disc as the formation of spacer layers and the curing of spacer layers is no longer necessary.

Abstract: A method of surface cross-linking superabsorbent polymer particles using UV irradiation is provided. The superabsorbent polymer particles for use in the method have a relatively high degree of neutralization. Brønsted acids are selectively applied onto the surface of the superabsorbent polymer particles to selectively facilitate a relatively high number of protonated carboxyl groups at the surface of the superabsorbent polymer particles while the relatively high degree of neutralization in the core of the superabsorbent polymer particles remains substantially unaffected.

Abstract: In accordance with the invention, substrate-supported linear arrays are formed by the steps of adhering a thin layer of polymer between a pair of substrates and separating the substrates perpendicular to the layer. The polymer layer separates to form substrate-supported polymer gratings on both substrates, each grating having a period proportional to the thickness of the layer. The process has been used to make gratings with periods in the sub-micron range or larger over areas covering square centimeters.

Abstract: A wood substrate is coated by spray-applying onto the substrate a 100% solids transparent coating composition containing sufficient silica-containing semithixotropic particulate having an average particle size of about 1 to about 20 micrometers to provide improved coating holdout, and curing the thus-applied coating. The coating may be applied at lower wet coating weights (thinner wet coating thicknesses) than a coating that does not employ silica-containing semithixotropic particulate. On variable grain density wood substrates such as cherry, the coating exhibits less localized soak in (better holdout) and provides a cured finish with a more uniform appearance over high and low grain density regions.

Abstract: A method of surface cross-linking superabsorbent polymer particles using UV irradiation is provided. The method is carried out in a so-called drum reactor, which comprises a hollow drum and an irradiation source. The drum has a longitudinal axis and a cross-section. Superabsorbent polymer particles are fed into the drum and are irradiated while they move within the drum, which is rotated around its longitudinal axis. The irradiation source is provided such that the radiation emitted by the irradiation source is able to reach superabsorbent polymer particles within said drum. The irradiation source for use in the method is able to emit UV radiation of a wavelength between about 100 nm and about 200 nm.

Abstract: A method of surface cross-linking superabsorbent polymer particles using UV irradiation is provided. The method is carried out in a so-called drum reactor, which comprises a hollow drum and an irradiation source. The drum has a longitudinal axis and a cross-section. Radical former molecules are applied on the surface of superabsorbent polymer particles. These superabsorbent polymer particles are fed into the drum and are irradiated while they move within the drum, which is rotated around its longitudinal axis. The irradiation source is provided such that the radiation emitted by the irradiation source is able to reach superabsorbent polymer particles within said drum. The irradiation source for use in the method is able to emit UV radiation of a wavelength between about 201 nm and about 400 nm.

Abstract: In various aspects provided are methods for producing a nanoparticle within a cross-linked, collapsed polymeric material. In various embodiments, the methods comprise (a) providing a polymeric solution comprising a polymeric material; (b) collapsing at least a portion of the polymeric material about one or more precursor moieties; (c) cross-linking the polymeric material; (d) modifying at least a portion of said precursor moieties to form one or more nanoparticles and thereby forming a composite nanoparticle.

Abstract: A biosensor capable of detecting, for example, the index of refraction, the concentration of proteins, or antibody-antigen reactions in a sample using surface plasmon resonance are provided, as well as methods for producing the biosensor sensor measurement systems using the biosensor. A biosensor may comprise transparent rod 2; metallic reflector 40 formed on end surface 2a of one end of transparent rod 2; metallic thin film 3 formed on the outer circumferential surface of said one end of transparent rod 2; and organic substance layer 4 comprising a photo immobilizing agent containing a photo cross linking agent and a substance to be immobilized which is formed on the metallic thin film 3 on the outer circumferential surface and immobilized.

Abstract: A procedure and a mechanism for the painting/lacquering and the subsequent hardening of the paint/lacquer layer on a molded object preferably of plastic. The processes are carried out in the same tool that performs the molding of the objects, which shall be painted/lacquered and hardened. This can be realized by the molding-tool, which can both be a one- and a multi-component tool, which is supplied with at least one turnable mold part, which through stepwise turning each of e.g. 90 degrees, leads the object through four stations, where the objects respectively are molded, painted/acquered, hardened and finally ejected from the turnable mold part.

Abstract: A method of manufacturing a replica diffraction grating includes the steps of: forming a metal thin film on a grating surface of a master diffraction grating, adhering a replica substrate to the metal thin film via an adhesive, and removing the replica substrate so that the metal thin film in a reverse state is adhered on the replica substrate. In the method, before forming the metal thin film on the grating surface of the master diffraction grating, the grating surface is coated with a fluorine surface treating agent as a release agent. Then, the metal thin film is formed with vacuum vapor deposition.

Abstract: In order to provide a process for curing a coating, in particular a radiation-curable coating, on a work piece, which allows coatings even on difficult to access regions of a three-dimensional work piece to be cured in a simple manner, it is proposed that the work piece is disposed in a plasma generation area, and that in the plasma generation area a plasma is generated, by means of which the coating is at least partially cured.

Abstract: Holographic data storage media having a sandwiched construction are described in which a holographic recording material is sandwiched between two substrates. The holographic media formulation is often formed of two or more components mixed to obtain a homogeneous formulation. The holographic media formulation may include two or more components which are mixed together prior to injection between the substrates. Curing of the holographic media formulation is substantially avoided during mixing, yet accelerated after the formulation is injected between the substrates. Accordingly, the system and techniques can be used to improve the large scale manufacturability of such media by allowing for fabrication of such media within reasonable cycle times, such as less than one minute, while adhering to stringent requirements for optical clarity and parallelism.

Abstract: The invention relates to a method and coating agents used in the method which provide good adherence to and good corrosion protection of metal substrates; the coating coating agents are cross-linkable via radical polymerization. Adhesion promoting compounds are present in the conversion layer in a quantity of about 0.01 to 40 weight percent and contain, on average, one reactive unsaturated group and at least one H-active group per molecule.

Abstract: Superabsorbent polymer particles with improved surface cross-linking for use in absorbent articles and a process for making the superabsorbent polymer particles. The superabsorbent polymer particles include a water-absorbing resin and the reaction product of a radiation activatable surface cross-linker. The reaction product of the radiation activatable surface cross-linker is present at surfaces of the superabsorbent polymer particles. The radiation activatable surface cross-linker includes at least two radiation activatable groups R, which are covalently bound to each other or to at least one spacer group S.

Abstract: A high-solid UV-curable coating composition of the present invention, comprising a low viscosity multifunctional urethane acrylate oligomer, a UV-curable monomer, 10% by weight or less of an organic solvent and a photoinitiator has good workability and environmental characteristics and provides a coating film having improved properties including thermal shock resistance.

Abstract: A resin layer formation method, resin layer formation device, disk and disk manufacturing method for making a resin layer uniform on a substrate before lamination or on a substrate to be coated by a simple procedure are provided. Adhesive A is coated at the inner circumference side while rotating a substrate P at low speed, a first adhesive layer AL1 is formed on the surface of the substrate P by rotating the substrate P at high speed, a step difference section H is formed around a rotation center of the substrate P by irradiating ultraviolet on an area in the inner circumference side of the first adhesive layer AL1 and hardening the area, the adhesive A is coated at the rotation center side from the step difference section H on the substrate P, and a second adhesive layer AL2 is formed on the first adhesive layer AL1 by rotating the substrate P at high speed. The first adhesive layer AL1 and the second adhesive layer AL2 are integrated to form a uniform adhesive layer B as a whole.

Abstract: This invention provides novel methods for the formation of biocompatible membranes around biological materials using photopolymerization of water soluble molecules. The membranes can be used as a covering to encapsulate biological materials or biomedical devices, as a “glue” to cause more than one biological substance to adhere together, or as carriers for biologically active species. Several methods for forming these membranes are provided. Each of these methods utilizes a polymerization system containing water-soluble macromers, species, which are at once polymers and macromolecules capable of further polymerization. The macromers are polymerized using a photoinitiator (such as a dye), optionally a cocatalyst, optionally an accelerator, and radiation in the form of visible or long wavelength UV light. The reaction occurs either by suspension polymerization or by interfacial polymerization.

Abstract: Refinishing an exterior automotive lens having a damaged exterior surface in situ using a continuous movement and oscillating motion, with first, a 320 grit sanding disc, next a 600 grit sanding disc and finally a 1500 grit sanding pad while flushing the surface with water to prevent melting of the surface. Buffing the surface with a polishing compound until a high gloss is achieved. Finally, coating the surface with a transparent ultraviolet hardenable coating material, and hardening it by exposure to an ultraviolet light source. This method is accomplished using an oscillating tool having a remotely located drive.

Abstract: The invention relates to a flame-retardant resin formulation comprising respectively at least one flame-retardant component, one alkali-soluble component, one polymerizable monomer, one photoinitiator, and one epoxy component, which comprises, as flame-retardant component, a phosphinic salt of the formula (I), in which R1 and R2 are identical or different and, independently of one another, are C1-C6-alkyl, linear or branched, and/or aryl; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K, and/or a protonated nitrogen base, and m is from 1 to 4. This novel flame-retardant resin formulation is preferably used as solder resist.

Abstract: A clearcoat curable by ultraviolet radiation including at least one of A) acrylate or methacrylate monomers or mixtures thereof having from one to six free-radically polymerizable groups per molecule or B) compounds containing two or more ethylenically unsaturated, free radically polymerizable groups per molecule and mixtures thereof or mixtures of A) and B). The coating may optionally include photoinitiators, volatile organic solvent(s) and customary additives. The invention further provides a process for applying the clearcoat to a substrate. In a preferred embodiment the process according to the present invention includes low energy curing of a clearcoat applied to a substrate by means of a UV light source utilizing UVA/UVV or UVA only and involves essentially no UVB or UVC radiation.

Abstract: A method of manufacturing an optical information recording medium that has a substrate having a signal recording layer formed on one principal surface thereof; and an optically transparent layer formed on the signal recording layer and made from a radiation cure type resin. According to the method, when the optically transparent layer is formed, the radiation cure type resin is supplied onto the substrate, and the radiation cure type resin is applied over the substrate by spinning the substrate at a predetermined number of application revolutions in a spin coating method. The number of revolutions of the substrate is increased after the application of the resin, and radiation is irradiated to cure the radiation cure type resin while the number of revolutions of the substrate is increased.

Abstract: A method for the temporary protection of patinated surfaces of copper products, in which an aqueous polymer dispersion is applied to the patinated surface, so that the polymer dispersion penetrates regions of the porous patina that are close to the surface, and in which the aqueous polymer dispersion is subsequently dried, so that it forms a composite with the patina that is permeable to water vapor diffusion. The polymer dispersion binds loose dust located on prepatinated copper products and simplifies the handling of the copper products. It behaves in a hydrophobic manner, but on the other hand it permits the required access of air moisture and water to the patina layer for further weathering.

Abstract: The present invention provides a process of preparing particulate products, the process comprising the steps of printing a liquid precursor of a non-metal particulate onto or into a collecting substrate and recovering non-metal particulates.

Abstract: A paint composition comprising an aqueous resin having photo-curable functional groups in a molecule, a photoinitiator, and a crosslinker is suitable for use on golf balls since the composition is fully adherent to molded parts of ionomer resins and urethane resins commonly used in golf ball covers, eliminates a need for pre-treatment of the ball surface, and forms a cured coating having a high bond strength to the ball surface. The composition which is photo-curable ensures efficient operation in the golf ball manufacturing process. In a golf ball coated with the paint composition, the coating has abrasion durability.

Abstract: The present invention is directed to a method for producing a high gloss coating on a printed surface. In the present method, an aqueous coating composition is deposited onto a surface to be printed using a blanket roller coating face which is a low energy, non-stick, smooth surface profile. In the present method, simultaneous with the deposition of aqueous coating onto a substrate, or shortly thereafter, pressure either alone or in combination with heat may be applied to the coating in order to create a substantially tack-free surface conforming to the surface of the coating face. By using a highly polished coating face, high gloss coatings may be readily obtained using this methodology in a number of traditional printing techniques including wet trap inline sheet-fed printing, heat-set offset printing, dry trap inline flexographic printing, offset web-fed printing and gravure printing.

Abstract: The present invention discloses an ultraviolet light curable silver chloride composition and method for making such a composition that may be used to produce an silver coating on a substrate. The disclosed composition does not contain any significant amount of volatile organic solvents that do not become incorporated in the active layer after curing.

Abstract: Disclosed is a method of coating an inkjet print head using a UV curable coating composition containing a (methyl)acryloxy or vinyl functionalized silane, silica and acrylate oligomer containing at least two acrylate groups.

Abstract: The present invention provides a method of planarizing a substrate with a template spaced-apart from the substrate having a liquid disposed therebetween, the method including: contacting the liquid with the template forming a first shape therein; and impinging radiation upon the liquid causing a reduction in volume of the liquid, with the first shape compensating for the reduction in volume such that upon impinging the actinic radiation upon the liquid, the liquid forms a contoured layer having a substantially planar shape.

Abstract: An information layer for an optical information storage medium is formed in a centrifuge. A photopolymerizable composition is applied to a solid base having a relief pattern, and a flexible, transparent film layer is applied on top of the composition. The three are spun in a centrifuge to cause a thin, even distribution of the photopolymerizable composition, which is photopolymerized. The resulting replica is separated from the relief pattern and has a fluorescent material applied thereto. Alternatively, the replica has a non-fluorescent material applied thereto, and the non-fluorescent material is made fluorescent through diffusion. Multiple information layers thus formed can be glued together to form a multilayer optical information storage medium.

Abstract: A method of forming a layer or layers are disclosed which comprises the steps of transporting a substrate having a first surface and a second surface on the side opposite the first surface to a gap formed between a first electrode and a second electrode opposing each other, the second surface having a coefficient of kinetic friction of not more than 0.9; and subjecting the first surface of the substrate to plasma discharge treatment to form the layer at atmospheric pressure or at approximately atmospheric pressure while supplying a reactive gas to the gap.

Abstract: A process for preparing copolymer dispersions that includes subjecting A) one or more vinyl monomer mixtures containing a) OH-free (meth)acrylic esters and/or vinylaromatics, b) hydroxy-functional vinyl monomers and/or hydroxy-functional (meth)acrylic esters, c) ionic and/or potentially ionic monomers capable of free-radical copolymerization, and d)optionally further monomers, other than the compounds of components a)–c), capable of free-radical copolymerization; to free-radical polymerization in the presence of e) compounds according to formula (I) where R1 is an aliphatic, araliphatic or aromatic radical having 1 to 18 carbon atoms, R2 is H or CH3, R3, R4 are identical or different aliphatc radicals having 1 to 7 carbon atoms and n is 1 to 4; and subsequently dispersing the resultant copolymer B) before or after addition of a neutralizing agent C) in water. The resulting dispersions can be used to coat substrates.

Abstract: Self-coating or self-layering lacquer systems from at least two different resins, oligomers, or polymers, which are emulsifiable or dispersible in water, have different surface tensions, and form self-layering phases. After the application, the phases separate into the components of the formulation.

Abstract: In the condition that an acrylic transparent vessel is filled with a curable resin solution capable of being cured by a light, a plastic optical fiber is immersed in the curable resin solution. A laser beam is applied on the curable resin solution through the plastic optical fiber. The curable resin solution is cured gradually by the laser beam applied on the curable resin solution, so that an axial core is formed. Then, the transparent vessel is left at rest for predetermined time, or uncured part of the curable resin solution is removed from the transparent vessel and the transparent vessel is then filled with another curable resin solution. Then, ultraviolet rays are applied on the transparent vessel from the outside of the transparent vessel to cure the residual uncured part of the curable resin solution.

Abstract: Disclosed is a process to rapidly spin-apply an AR coating system to a backside of a prescription lens. The AR coating system comprises a polyurethane primer layer, a siloxane thermally cured scratch resistant coating layer, a two-layer sol-gel AR coating, and a hydrophobic layer. The process comprising steps of spin-applying each of the layers provides a quick way to furnish a prescription lens that is AR coated on both sides.

Abstract: A microlens is affixed in the far field of an optical fiber to spatially transform a beam either entering or exiting the fiber. In a first embodiment, a droplet of photo polymer is placed on the end of an optical fiber and the fiber is spun to create an artificial gravity. The droplet is cured by UV radiation during the spinning. In a second embodiment, nanoparticles are mixed into the droplet to increase the refractive index of the photo polymer. A third embodiment employs artificial gravity to attach a microsphere to the end of the optical fiber. A fourth embodiment chemically treats the surface of the microsphere so that the requirement of artificial gravity is either reduced or eliminated. In a fifth embodiment the droplet is cured under equlibrium or nonequilibrium conditions to obtain different final shapes for the lenslet. A sixth embodiment discloses fabrication of microlens arrays.

Abstract: Mixtures curable thermally and with actinic radiation and containing carbamate and/or allophanate groups, comprising (A) at least one of (A1) low molecular mass compounds, oligomers and polymers containing allophanate groups, carbamate groups, and carbamate and allophanate groups, and (A2) low molecular mass compounds, oligomers and polymers containing allophanate groups, carbamate groups, and carbamate and allophanate groups, and additionally allophanate- and/or carbamate-reactive functional groups, ?which are substantially or entirely free from reactive functional groups which contain at least one bond which can be activated with actinic radiation, and (C) at least one constituent containing on average per molecule at least one reactive functional group having at least one bond which can be activated with actinic radiation; with the proviso that if only (A1) is used, the mixtures further comprise (B) at least one of low molecular mass compounds, oligomers and polymers containing allophanate- and/or c

Abstract: The present invention discloses an ultraviolet light curable transparent conductive composition and method for making such a composition that may be used to produce a transparent conductive coating on a suitable substrate. These coatings may be used in such applications as touch screens, membrane switches, TV screens, and VCRs. The disclosed composition does not contain any significant amount of volatile organic solvents that do not become incorporated in the active layer after curing.

Abstract: A process is described for producing molding compounds and coatings on substrates by curing radiation-curable compositions under inert gas by exposure to light wherein said inert gas comprises a gas heavier than air, and lateral escape of the inert gas in the course of radiation curing is prevented by means of appropriate apparatus or other measures.

Abstract: A liquid material is applied by spin coating it onto a first main surface of a flat plate to form a coating of the liquid material thereon. The flat plate includes a second main surface which is opposite to the first main surface and a hole which passes through the flat plate. The application of the liquid material is carried out using an inner guide member, which is placed in the hole, and the spin coating is carried out while the flat plate is placed on a stage such that the inner guide member is placed generally adjacent to an inner peripheral side surface of the flat plate and an upper surface of the inner guide member and the first main surface are located at generally the same level. Thereby, a coating is obtained which extends on the upper surface of the inner guide member and the first main surface of the flat plate.

Abstract: Three-dimensional structures are fabricated by a process in which a 3D solid model is designed by software at a PC and sliced into a series of 2D layers. Each 2D layer is displayed at a dynamic mask via micro-mirror deflections projected onto a photoresist to form a layer, which is lowered and the process is repeated to build the object layer by layer.

Abstract: A method for reducing the scattered light emitted through an optical element is provided that protects adhesive used to hold the optical element in place from light induced deterioration. In one embodiment, the method includes applying a thin coating of an organoxy metallic compound to a region on an optical element where adhesive will be applied and exposing the organoxy metallic compound to ultra-violet light. Exposure to ultra-violet light converts the organoxy metallic compound to its corresponding metal oxide forming an optically inert, light absorbing coating that protects adhesive used to hold the optical element in place from light induced deterioration.

Abstract: The invention relates to primer coating compositions exhibiting very good adhesion properties on a large variety of substrates, in particular plastic substrates such as ophthalmic lenses made of organic glasses and which also impart good impact resistance properties to the thus coated substrates. The invention also concerns substrates coated with these primer coating compositions as well as a method for making such coated substrates.

Abstract: The method for hardening electro-insulating materials is characterised by the utilization and/or co-utilization of near-infrared radiation (NIR) having a wavelength of 500 nm to 1400 nm. NIR also enables very fast hardening of the component surface even with pure thermally hardenable impregnating material and further provides good hardening of thick layers located deep inside said layers. Combined hardening, for example, NIR and UV light, is also possible.

Abstract: A radiation curable powder coating composition is disclosed, which comprises a blend of (meth)acryloyl group containing polyphenoxy resin, a (meth)acryloyl group containing resin other than the polyphenoxy resin and other than a (meth)acryloyl group containing amorphous polyester and, eventually, a (meth)acryloyl group containing monomer or oligomer. These powders give coatings with improved chemical resistance and flexibility.

Abstract: The present invention discloses ultraviolet light curable paint compositions to be used in a multilayer paint coating and method for applying such a compositions to a substrate. Suitable substrates include glass, metals, and various plastics such as polycarbonates. The disclosed compositions do not contain any significant amount of volatile organic solvents that do not become incorporated in the coating or released to ambient after curing.

Abstract: A paint and method are divulged for protecting the silver film of mirrors. The paint in its preferred embodiment includes a metal carboxylate which will contribute metal ions, namely stannous octoate for the contribution of stannous(II) ions in an amount of 0.5% or greater by weight. Alternate methods of the invention utilize an additional coating over the paint, such as an acrylic, epoxy or blend thereof which is UV curable. In another form of the paint, copper octoate is utilized in a minimum amount of 0.5% by weight for contribution of copper(II) ions.