Abstract: A thermoplastic resin film (i) which has a degree of dimensional change through heating and cooling (a) in the range of from −2% to 2% as measured by thermomechanical analysis in the range of from room temperature to 135° C., or which has a degree of thermal shrinkage of 1.8% or lower upon heating at 130° C. for 30 minutes or longer; and a label paper employing the same. The label paper has suitability for heated-roll fixing type electrophotographic printers and is satisfactory in curling after printing.

Abstract: Weather stripping for use in sealing an interface between selected vehicle portions is made using a thermoplastic material such as TPV with a supercritical fluid introduced during the manufacturing process to provide a microcellular structure. The microcellular structure of one example implementation of this invention includes a cell density in a range from about 109 to about 1015 per cubic centimeter. Average cell sizes preferably are less than 2 microns. A preferred range in one example is between about 0.1 micron and about 1.0 micron. The inventive design provides superior performance with cost savings compared to rubber weather stripping.

Abstract: The invention relates to an imaging member comprising an imaging layer and a base wherein said base comprises a closed cell foam core sheet and adhered thereto an upper and lower flange sheet, wherein said foam core sheet has a modulus of between 100 and 2758 MPa and a tensile toughness between 0.344 and 35 MPa, and wherein said upper and lower flange sheet has a modulus of between and 1380 and 20000 MPa and a toughness between 1.4 and 210 MPa.

Abstract: The present invention provides a carbohydrate foam composition. The foam composition is highly wettable, resilient and has a uniform pore structure suitable for use in products such as absorbent personal products, health care products, and products suitable for fluid distribution and transfer. The foam of the present invention may also be made into sheets suitable for products such as tissue and paper towels. In one embodiment the foam is made from a carbohydrate and zinc chloride. In a further embodiment the carbohydrate is cellulose, and in a further embodiment the carbohydrate is chitin.

Abstract: The present invention is a floor mat made from a rubber composite, the composite having a foam rubber core positioned between dense rubber layers. Protrusions or cleats, which are produced during the vulcanization process, extend outwardly from the lower surface of the mat. The present mat offers mat users desirable anti-fatigue characteristics that are achieved by (a) a combination of dense rubber and foam rubber layers and (b) the spaced positioning of a plurality of cleats over one surface of the mat. Such a mat is anticipated to be useful in service environments, such as hair styling salons, retail outlets, or restaurant kitchens, for example.

Abstract: Generally flat structural panel for building construction includes an inner insulating core such as of plastic foam and a pair of opposed outer facings, or sheets, bonded to the panel's insulating core. One of the outer facings is of gypsum composite, or gypsum fiberboard, while the other outer facing is of oriented strand board (OSB) impregnated with plastic, such as a polyisocyanurate or urethane resin. The gypsum fiberboard forms the panel's inner surface, while the plastic impregnated OSB forms the panel's outer surface. The panel's outer facings provide high tensile strength, with the gypsum fiberboard facing also affording high load bearing capacity as well as resistant to fire, the environment, and insects. The plastic impregnated OSB does not expand or contract with changes in humidity to maintain a planar configuration for the panel with a smooth, uniform surface for exterior finishing.

Abstract: The invention relates to an imaging member comprising an imaging layer and a base wherein said base comprises a closed cell foam core sheet and adhered thereto an upper and lower flange sheet, wherein said foam core sheet has a modulus of between 100 and 2758 MPa and a tensile toughness between 0.344 and 35 MPa, and wherein said upper and lower flange sheet has a modulus of between and 1380 and 20000 MPa and a toughness between 1.4 and 210 MPa.

Abstract: A sealing sheet (10) assembly bondable to a construction surface comprising (a) an upper layer (14) of a first substance, the upper layer being selected fluid impermeable; and (b) a lower flexible layer (16) of a second substance, the lower flexible layer being bondable to the construction surface. The upper layer and the lower flexible layer are at least partially attached to one another, wherein a combination of the upper layer, the lower layer and the attachment or the partial attachment of the layers to one another are selected such that tensile forces resulting from constructional movements acting upon the sealing sheet result in a local detachment or relative displacement of the upper layer and the lower flexible layer, thereby the ability of the lower flexible layer of transmitting the forces onto the upper layer is remarkably reduced, resulting in improved service of the sealing cover as a whole.

Abstract: A fabric reinforced closed cell foam composite having a textured or smooth surface which is substantially free of nodular surface irregularities. The fabric may be formed of woven fibers or of non-woven random fibers which are bonded together by resin or heat. The fabric is then coated to a suitable thickness with a foamed or unfoamed polymer formulation. The cushion has a high strength to weight ratio, is substantially impermeable to liquids, significantly dampens sound and absorbs energy. In addition, the cushion is non-slip, remaining substantially fixed in relation to the surface to which it is in contact by means of friction. Further, the surface of the cushion is relatively easily decorated with printed designs. Dyes could also be added to the foam formulation to produce a wide range of decorative colored cushions.

Abstract: The non-woven web of the present invention is comprised of recycled cellulose fiber and untreated Clarifier Sludge, and optionally, recycled glass fiber. Unlike uses of reclaimed Clarifier Sludge whereby the material has been treated in some fashion to improve its quality, the non-woven web of the present invention utilizes untreated Clarifier Sludge. The Clarifier Sludge of the present invention is dry enough to handle, and in one example varies between about 30% and about 45% solids. The Clarifier Sludge can be added to web-forming equipment (e.g., papermaking equipment) either in a waste paper disintegrator or into a recycling apparatus (e.g., broke pulper) whose output is metered into a refiner tank of the web-forming equipment. In an embodiment utilizing a broke pulper for introduction of the Clarifier Sludge, the broke pulper is filled with clarifier sludge and water to a consistency of about 3.5% solids.

Abstract: A method for making a resilient material includes providing a particulate polymer, discrete pieces of foam and a plasticizer. The polymer, foam pieces and plasticizer are mixed and disposed in a mold. The mold is heated to cause melting of the polymer without melting of the foam. After coating of the melted polymer, a heterogeneous resilient cushion is formed with gelated polymer surrounding the discrete foam pieces.

Abstract: The invention relates to an insulation element (4, 4′), at least one nonwoven layer (5) and/or a foam layer (11) being enclosed by a film layer (1), and, to achieve a solution which is adequately permeable to water vapour but nevertheless flame-retardant, proposes that the film layer (1) consists of a flame-retardant material which is preferably closed to vapour diffusion, that the film layer (1) also has through-openings (2) and that the through-openings (2) are open to vapour diffusion.

Abstract: The present invention provides a three layer laminate of (i) an outer layer comprising a filled crosslinked polyester layer, which has a stone-like appearance, (ii) an intermediate layer comprising a crosslinked acrylic resin and (iii) an inner layer comprising a rigid polyurethane foam backing.

Abstract: An insect resistant extruded or expanded polystyrene foam boards containing from 2 to 25 weight-% acicular particles such as fiberglass, stone wool, metal wool, gypsum, quartz and wollastonite, and insulation panels made from such boards. The fibers are preferably milled or chopped and range in size from 0.0156 inch (0.396 mm) inch to 0.5 inch (12.7 mm) in length and 10 to 20 micrometers in diameter.

Abstract: An injection hose for use in filling voids in concrete during installation of expansion joints is made from fibre-reinforced plastic and has four longitudinal rows of staggered slits in a side wall thereof. The hose is connected between two elbows having nipples to receive an epoxy source. Epoxy is injected into the tubular members and then into the hose at each end simultaneously. The pressure from the epoxy opens the slits and exits into the void in which the hose is located.

Abstract: The process of the invention characterized in that to 100 parts by weight of a silicate powder having 2000-8000 m2/g specific surface, 1-10 parts by weight of gas-forming material with particle size of 10-100 &mgr;m and 0.5-15 parts by weight of montmorillonite, 0.5-2 parts by weight of alkali hydrogen phosphate or alkali dihydrogen phosphate or a mixture of alkali metal phosphate and sodium silicate in form of aqueous solution, 0.01-5 parts by weight of rare earth metal oxide or a mixture of such oxides were added, then the mixture obtained is homogenized, pre-dried, coated with 1-5 parts by weight of titanium oxide and/or titanium oxide hydroxide and/or aluminum oxide hydroxide, then subjected to heat treatment at 720-1000° C., and the mixture obtained is molded. The subject of the invention: also the product of the above process.

Abstract: The invention relates to an imaging member comprising an imaging layer and a base wherein said base comprises a closed cell foam core sheet and adhered thereto an upper and lower flange sheet, and wherein said imaging member has a stiffness of between 50 and 250 millinewtons.

Abstract: To provide a makeup sponge puff of less frictional resistance and stiffness and no surface slipperiness, particles are adhered to a surface of a substrate sponge of closed-cell foam to form the makeup sponge puff. For example, the substrate sponge comprising is a natural or synthetic rubber, the particles are a thermoplastic resin, synthetic rubber or a thermosetting resin, and the particles are adhered by an adhesive layer on the surface of the substrate sponge.

Abstract: A laminate of thermoplastic over foam is well suited for making plates to be used in a protective paint-ball vest. The vest is constructed of many such plates mounted to fabric to provide good ventilation and freedom of movement with adequate protection levels against commonly encountered hazards. The vest can be made reversible to facilitate team games and is highly suitable for use in paint ball games.

Abstract: A molded article including a plastic layer and an outer film over the plastic layer forming a composite laminate with the plastic layer and a process for preparing same. The outer film has an inner surface adjacent and bonded to the plastic layer and an outer surface opposed to the inner surface. The molded article also includes a reinforcing material adhered to the inner surface of the outer film layer and preferably at least partly embedded in the inner surface of the outer film layer.

Abstract: The present invention relates to a foamlike mineral building and structural material based on a substantially uniformly foamed alkali-silicate and/or ammonium-silicate matrix encompassing an open and/or closed porous structure. In addition, the present invention relates to a method of producing a foamlike mineral building and structural material comprising the following steps: adjusting the water content of the alkali-silicate and/or ammonium-silicate starting material to a specific value, and foaming the pretreated alkali-silicate and/or ammonium-silicate material, and to an apparatus for carrying out the method which comprises: a conditioner for adjusting the water content of the alkali-silicate and/or ammonium-silicate starting material and a heating means for the foaming step.

Abstract: The invention concerns a vehicle interior trim element and process for manufacturing same.

Abstract: Lightweight, thermoplastic, vehicle headliners each having at least one integrally-formed, energy-absorbing, head-impact mechanism and injection molding methods for making same are provided. Each headliner includes a stiff, self-supporting, thermoplastic sheet adapted to be mounted adjacent a roof of the vehicle so as to underlie the roof and shield the roof from view. The sheet has an upper surface and a lower surface. Each energy-absorbing, head-impact mechanism absorbs energy of an impact with its associated headliner by a passenger of the vehicle. In one embodiment, the at least one head-impact mechanism includes a plurality of spaced-apart, energy-absorbing, thermoplastic structures, such as ribs, which are connected to and extend upwardly from the upper surface of its thermoplastic sheet.

Abstract: Provided is a porous film which is excellent in a water vapor transmission rate, a tear strength and a weatherability. This porous film can be produced by melt-extruding, for example, by a T-die method, a composition comprising 100 parts by weight of a resin blend (1) comprising 100 parts by weight of {circle around (1)} an ethylene-propylene copolymer, 3 to 40 parts by weight of {circle around (2)} a low density polyethylene and 3 to 40 parts by weight of {circle around (3)} an ethylene-vinyl acetate copolymer and 100 to 200 parts by weight of calcium carbonate (2), or a composition comprising 100 parts by weight of the above resin blend (1), 100 to 200 parts by weight of calcium carbonate (2), 0.5 to 20 parts by weight of titanium dioxide (3) coated on a surface thereof with silica and/or alumina, 0.2 to 10 parts by weight of a hindered amine light stabilizer (4) having a molecular weight of 1500 to 4500 and 0.

Abstract: The present invention provides a vibration reducing grip material that includes a closed-cell poly(vinyl chloride) foam material having a Shore durometer of about 50 to about 70. According to one embodiment of the present invention, there is provided a vibration reducing handle cover for an impact tool.

Abstract: A sprayable polymeric material and a process for preparing the material which contains a fibrous material, dispersed throughout the polymeric material. A restriction free spray nozzle is provided for mixing and spraying the polymeric material having a fibrous material, the nozzle having a restriction free check valve. A reinforced structure, and a method of making the structure are provided, the structure having layers of the polymeric material (both film and foam) containing the fibrous material. A flexible liner is provided of a porous geotextile fabric and a polyurethane composition comprising the fibrous material sprayed over the geotextile fabric.

Abstract: A double-sided self-adhesive reinforced foam tape comprising a release liner having upper and lower surfaces which are release surfaces, a first layer of pressure sensitive adhesive applied to the upper release surface, a layer of flexible polymeric film, preferably polyester film, applied to the first pressure sensitive adhesive layer, a layer of flexible foam, preferably closed cell PVC flexible foam, thermally bonded to the flexible polymeric film layer, and a second layer of pressure sensitive adhesive applied to the flexible foam layer. A length of material for use as a double-sided tape is provided, along with a method of making the length of material. An alternative embodiment, suitable for die-cutting, including a second release liner applied to the second pressure sensitive adhesive layer is provided. The tape may be used in automobiles and other applications.

Abstract: A safe room for protecting an occupant against tornado and other extremely high winds, where at least one wall member and roof member of the safe room are constructed from at least one metallic-skinned foam panels having an impact-absorbing sheathing attached to at least one side of the metallic-skinned foamed panel as a cladding layer. The safe room also includes at least one securable door, and is further fixedly anchored to a foundation. The safe room using this construction is lightweight yet strong enough to withstand killer tornado and hurricane wind loads and airborne debris impact loads. The safe room can therefore be pre-assembled and shipped to the installation site with only the need to be secured to a foundation. Or, the safe room can be easily assembled at the installation site from a kit. In either case, installation of the safe room is easy, inexpensive, and, apart from the foundation and anchorage thereto, requires no structural additions.

Abstract: A photographic element comprising a laminated base wherein said base comprises a voided polymer sheet having laminated thereto a biaxially oriented polyolefin sheet on the bottom of said polyester sheet and a biaxially oriented polyolefin sheet laminated to the top of said polyester sheet, wherein said photographic element has a bottom voided opacifying layer below at least one voided layer of said voided polymer sheet and a topside voided opacifying layer above said at least one voided layer of said voided polyester sheet.

Abstract: Core for a composite structural member comprises rigid, extruded, closed-cell polypropylene foam in which the surfaces are skived to provide adhesive bonding to structural skin layers. Panel made from core in accordance with the invention has shear strength of from about 60 to 200 psi at a density of 3 to 8 pcf and is suitable for use in marine craft, vehicles, and in building construction. The core is kerfed or “kiss cut” prior to application of adhesive for use in forming curved surfaces without a scrim layer.

Abstract: Manufacture of a polishing pad for polishing a semiconductor substrate, involves, transporting a backing layer to successive manufacturing stations, supplying a fluid phase polymer composition onto the transported backing layer, shaping the fluid phase polymer composition into a surface layer having a measured thickness, and curing the polymer composition on the transported backing layer in a curing oven to convert the liquid phase polymer composition to a solid phase polishing layer attached to the transported backing layer.

Abstract: The invention relates to a thermoformable sheeting consisting of a foam material or containing at least one layer of a foam material. The inventive sheeting is particularly applicable for thermoforming cups or trays for packaging and/or consuming food stuffs, by drawing or deep drawing the sheeting and expanding the foam material. The foam material of the inventive sheeting consists of a polypropylene blend containing between 50 and 100% of high melt strength polypropylene, has a density of 0.1 to 0.7 g/cm3, preferably between 0.25 and 0.5 g/cm3, and a cell number of from greater than 300 to 3000 cells per mm3, preferably between 800 and 2500 cells per mm3. The inventive sheeting can be drawn with a high drawing ration (e.g. 1.5) and expanded to be formed into containers even with difficult shapes, whereby no drawing problems arise and the containers produced show a homogeneous opaqueness.

Abstract: A ceramic matrix composite part having elongated cooling channels within the wall thereof is manufactured by inserting decomposable inserts within a woven ceramic fiber preform. The inserts are tows of continuous carbon fibers surrounded by a carbonaceous filler, and are inserted where the channels are desired. The preform, with the inserts in place, is disposed within a mold. A ceramic matrix material is added and the fiber preform is consolidated with the ceramic matrix material. The consolidated part is then heated to thermally decompose the inserts to create the elongated channels within the part. The inserts may be flexible and woven into the preform using an automated weaving loom, or they may have limited flexibility and be inserted by machine or by hand.

Abstract: A multi-layer article which may be provided in the form of a tape comprises a conformable, compressible, melt flow-resistant core layer having first and second major surfaces, a sealant layer on the first major surface of the core layer, and optionally a bonding layer on the second major surface of the core layer. The sealant layer and the bonding layer each have a surface available for contacting a separate substrate. Various thermoset and foam core layers are disclosed as are thermosettable and thermoplastic sealant layers. The articles are useful for sealing two substrates together, particularly where one of the substrates is glass. Thus, the articles are especially adapted for sealing motor vehicle windshields to a frame. Various assemblies and methods for producing the same are also described.

Abstract: This invention pertains to a composition and a process for preparing a closed cell alkenyl aromatic polymer foam having enlarged cell size, comprising one or more alkenyl aromatic polymers, one or more substantially random interpolymers, one or more blowing agents having zero ozone depletion potential and optionally one or more co-blowing agents, and optionally, one or more nucleating agents and optionally, one or more other additives. This combination allows the manufacture of closed cell, low density alkenyl aromatic polymer foams of enlarged cell size, when blowing agents of relatively high nucleation potential are employed. When such blowing agents are used with alkenyl aromatic polymers in the absence of the substantially random interpolymers, small cell foams result.

Abstract: A water-based chipping-resistant paint which comprises 30 to 65 weight percent of solid matter and 0.1 to 10 weight percent of low-temperature volatility solvent as a water-based dispersion substance and wherein the solid matter contains 15 to 75 weight percent of film-formable resin, 0.2 to 25 weight percent of thermoexpandable microspheres, and 20 to 80 weight percent of chipping-resistant material, facilitates vaporization of water at the time of film formation owing to mixing of the low-temperature volatility solvent, can prevent cracking and blistering of a film due to water remaining in the film and vaporization of water remaining after the film formation, and readily form a thick film owing to an expansion effect of the thermoexpandable microspheres at the stage of baking after coating, and therefore is suitable for a chipping resistant underbody coating for automobiles.

Abstract: An apparatus is disclosed for injecting an expandable or foaming material in a closed sectional structure of a body. The apparatus is suitable for mass-producing vehicles, such as automobiles efficiently. This apparatus is provided with a manipulator (38) movable to a desired position, a injector (50) fixed to the manipulator, a device (56) for supplying the expandable or foaming material to the injector, and a controller (40) adapted to control the position of the manipulator (10) so that the injector is set in a position in which the foaming material can be supplied to the closed sectional structure of the vehicle body through an injection port of the same closed sectional structure, and also adapted to control the supply device so that the foaming material can be injected and filled in the closed sectional structure thereof by only such an amount that was set in accordance with the volume of the inside of the sectional structure.

Abstract: A multi-layer article which may be provided in the form of a tape comprises a conformable, compressible, melt flow-resistant core layer having first and second major surfaces, a sealant layer on the first major surface of the core layer, and optionally a bonding layer on the second major surface of the core layer. The sealant layer and the bonding layer each have a surface available for contacting a separate substrate. Various thermoset and foam core layers are disclosed as are thermosettable and thermoplastic sealant layers. The articles are useful for sealing two substrates together, particularly where one of the substrates is glass. Thus, the articles are especially adapted for sealing motor vehicle windshields to a frame. Various assemblies and methods for producing the same are also described.

Abstract: The invention relates to a thermoformable sheeting consisting of a foam material or containing at least one layer of a foam material. The inventive sheeting is particularly applicable for thermoforming cups or trays for packaging and/or consuming food stuffs, by drawing or deep drawing the sheeting and expanding the foam material. The foam material of the inventive sheeting consists of a polypropylene blend containing between 50 and 100% of high melt strength polypropylene, has a density of 0.1 to 0.7 g/cm3, preferably between 0.25 and 0.5 g/cm3, and a cell number of from greater than 300 to 3000 cells per mm3, preferably between 800 and 2500 cells per mm3. The inventive sheeting can be drawn with a high drawing ration (e.g. 1.5) and expanded to be formed into containers even with difficult shapes, whereby no drawing problems arise and the containers produced show a homogeneous opaqueness.

Abstract: A low dielectric constant, multiphase material which can be used as an interconnect dielectric in IC chips is disclosed. Also disclosed is a method for fabricating a multiphase low dielectric constant film utilizing a plasma enhanced chemical vapor deposition technique. Electronic devices containing insulating layers of the multiphase low dielectric constant materials that are prepared by the method are further disclosed.

Abstract: A shopping cart having a foam pad designed to reduce bruising and other damage to fruits and vegetables as well as provide additional comfort to young children sitting on the pad is provided. The pad should be formed of closed-cell FDA approved foam, having a protective water impermeable skin substantially surrounding exposed surfaces of the foam. The skin should also be FDA approved.

Abstract: The present invention is directed to materials that assist respiration of living cells contained in cell-containing systems. The materials form air-filled conduits or channels through which gases, such as oxygen and carbon dioxide, can readily exchange by diffusional means between regions of different gas partial pressures. When the present invention is placed within an aqueous environment, such as cell-culture media or host tissue, the invention provides aid to cellular respiration in cell-containing systems.

Abstract: A biodegradable, water dispersible shaped core product useful in winding or rolling and storage of paper goods is provided by extruding starch which has a particle size of 800 to 1200 microns into an expanded, closed cell starch product.

Abstract: A multi-layer article which may be provided in the form of a tape comprises a conformable, compressible, melt flow-resistant core layer having first and second major surfaces, a sealant layer on the first major surface of the core layer, and optionally a bonding layer on the second major surface of the core layer. The sealant layer and the bonding layer each have a surface available for contacting a separate substrate. Various thermoset and foam core layers are disclosed as are thermosettable and thermoplastic sealant layers. The articles are useful for sealing two substrates together, particularly where one of the substrates is glass. Thus, the articles are especially adapted for sealing motor vehicle windshields to a frame. Various assemblies and methods for producing the same are also described.

Abstract: A rigid polyurethane foam is described which is preferably, while not exclusively, used for manufacturing composite building elements used in buildings or for manufacturing industrial constructions. The foam has a structure consisting of closed cells substantially free therein of optionally halogenated hydrocarbon foaming agents, having an adhesion strength to a supporting substrate, measured according to standards EN 1607, equal to or higher than 0.7 kg/cm2. The polyurethane foam may be obtained starting from at least one polyol and at least one isocyanate compound by using a water-based foaming agent entirely compatible with the strictest environmental requirements, and has good mechanical characteristics, characteristics of dimensional stability, characteristics of adhesion to a supporting substrate and, possibly, characteristics of fire resistance.

Abstract: The present invention is polyurethane dispersion composition that can be mechanically frothed to yield a foam that has good resiliency. Frothed foams of the present invention can be useful in cushioned flooring applications such as attached cushion broadloom, carpet tiles, carpet underlay, or vinyl flooring. Frothed foams of the present invention can also be useful as coatings for various textiles and for diapers.

Abstract: The invention provides gel-coated materials that provide enhanced flame-, physical- and chemical-resistance to the foamed materials. The gel coatings can be created with a sol-gel process. Such treated materials can be used, for example, in the manufacture of articles of clothing that are to be used in environments in which fire and exposure to acids, bases or other chemicals which tend to corrode foamed materials is a potential hazard.

Abstract: A ceramic composite includes (a) 30 to 60% by volume of C-fibers; (b) 10 to 55% by volume of a matrix made of SiC and C, wherein the weight ratio SiC:C is in the range of between 20:1 and 2:1; (c) 5 to 40% by volume porosity that may be open or closed. A base material is formed from a)+b)+c).

Abstract: Articles including material laminated to a surface of a microcellular substrate are disclosed, as well as methods of making these articles. Microcellular polymeric material in sheet form can be extruded and continuously fed from the extruded to a lamination system, or microcellular sheet can be produced and stored, and then fed into a lamination system.

Abstract: A layered structure that includes a product mixture of numerous particles, a foamable substance, such as including a liquid binder, and a reacted dry binder is provided. The particles preferably are comprised of cellulosic, fibrous materials. The dry binder reacts with the liquid binder to create a strong bond among separated particles. The particles are separated during transport, together with the dry binder, before the dry binder is reacted with the foamed liquid binder. Upon contact with the liquid binder, the dry binder reacts to cause desired adhesion among the separated particles. The reacted dry binder is disposed relatively inwardly of the product mixture, while the liquid binder is located outwardly thereof, with at least some of the liquid binder, after curing, being disposed on outer portions of the product mixture. The layered structure also includes one or more outer members or panels that are laminated or otherwise joined to the outer surface portions of the product mixture.