Particle (e.g., Pigment, Etc.) Containing Layer Patents (Class 428/32.25)
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Publication number: 20130196090Abstract: A recording medium includes a base and at least one ink-receiving layer. A first ink-receiving layer that is at least one ink-receiving layer contains inorganic particles having an average primary particle size of 1 ?m or less and inorganic particles coated with a metal oxide. The inorganic particles coated with the metal oxide have an average primary particle size of 15.0 ?m or more. When the maximum of a FLOP value of the recording medium is denoted by FLOPMax and the minimum of the FLOP value is denoted by FLOPMin, the FLOPMin is 2.5 or more and a value of FLOPMin/FLOPMax is 0.80 or more and 1.00 or less.Type: ApplicationFiled: January 28, 2013Publication date: August 1, 2013Applicant: CANON KABUSHIKI KAISHAInventor: CANON KABUSHIKI KAISHA
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Patent number: 8486499Abstract: An ink jet recording medium including a substrate and two or more ink receiving layers provided on the substrate, wherein a first ink receiving layer that is an outermost ink receiving layer of the two or more ink receiving layers and a second ink receiving layer adjacent to the first ink receiving layer contain an alumina pigment, polyvinyl alcohol and boric acid. The first ink receiving layer contains polyvinyl alcohol in an amount of 7.0-10.5% by mass or less based on the alumina pigment and contains boric acid in an amount of 1.1-1.4% by mass or less based on the alumina pigment. The second ink receiving layer contains polyvinyl alcohol in an amount of 10.5-17.0% by mass or less based on the alumina pigment and contains boric acid in an amount of 1.5-2.5% by mass or less based on the alumina pigment.Type: GrantFiled: January 23, 2012Date of Patent: July 16, 2013Assignee: Canon Kabushiki KaishaInventors: Yasuhiro Nito, Hisao Kamo, Tetsuro Noguchi, Ryo Taguri, Isamu Oguri, Olivia Herlambang, Naoya Hatta, Shinya Yumoto
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Patent number: 8481131Abstract: Transparent ink-jet recording films, compositions, and methods are disclosed. These compositions and methods can impart excellent adhesion properties between film layers and the transparent support. These films are useful for medical imaging.Type: GrantFiled: September 27, 2011Date of Patent: July 9, 2013Assignee: Carestream Health, Inc.Inventors: Sharon M. Simpson, William D. Devine, William J. Ruzinsky
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Patent number: 8481132Abstract: Transparent ink-jet recording films, compositions, and methods are disclosed. These compositions and methods can impart excellent adhesion properties between film layers and the transparent support. These films are useful for medical imaging.Type: GrantFiled: September 28, 2011Date of Patent: July 9, 2013Assignee: Carestream Health, Inc.Inventors: Sharon M. Simpson, James B. Philip
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Patent number: 8470416Abstract: Transparent ink-jet recording films, compositions, and methods are disclosed. Such films do not exhibit excessive ink drying times. These films can be free of such visual effects as mud cracking. These films are useful for medical imaging.Type: GrantFiled: November 7, 2011Date of Patent: June 25, 2013Assignee: Carestream Health, Inc.Inventors: Sharon M. Simpson, James B. Philip
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Patent number: 8470415Abstract: Addition of a surfactant to either the under-layer, the image-receiving layer, or to both the under-layer and the image-receiving layer provides a quick-drying, transparent ink-jet recording film capable of achieving an optical density of at least 2.8 while still having a low haze and producing a number of grey levels.Type: GrantFiled: July 6, 2011Date of Patent: June 25, 2013Assignee: Carestream Health, Inc.Inventors: Sharon M. Simpson, James B. Philip, Jr., John D. Szafraniec
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Patent number: 8460768Abstract: A paper includes a substrate and a polymer layer disposed over at least one side of the substrate. The paper further includes an aluminous material at least partially dispersed within the polymer layer. The aluminous material has a primary aspect ratio of at least about 1.5, a secondary aspect ratio of not greater than about 3.0, and a primary particle size between about 50 nm and about 1000 nm.Type: GrantFiled: December 11, 2009Date of Patent: June 11, 2013Assignee: Saint-Gobain Ceramics & Plastics, Inc.Inventor: Doruk O. Yener
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Patent number: 8449956Abstract: Transparent ink-jet recording films, compositions, and methods are disclosed. Such films do not exhibit excessive ink drying times. These films exhibit high maximum optical densities and have low haze values. These films are useful for medical imaging.Type: GrantFiled: September 13, 2011Date of Patent: May 28, 2013Assignee: Carestream Health, Inc.Inventors: Sharon M. Simpson, William D. Devine, William J. Ruzinsky
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Publication number: 20130129943Abstract: A recording medium includes, in sequence, a support, a first ink-receiving layer, and a second ink-receiving layer, in which a content of a boric acid in the first ink-receiving layer is 2.0% by mass or more and 7.0% by mass or less with respect to a content of a polyvinyl alcohol in the first ink-receiving layer, a content of a boric acid in the second ink-receiving layer is 10.0% by mass or more and 30.0% by mass or less with respect to a content of a polyvinyl alcohol in the second ink-receiving layer, an outermost surface layer of the recording medium has a content of particles of 0.5% by mass or more and 5.0% by mass or less, the particles having an average secondary particle size of 1.0 ?m or more and 20.0 ?m or less with respect to a content of an inorganic pigment.Type: ApplicationFiled: November 15, 2012Publication date: May 23, 2013Applicant: CANON KABUSHIKI KAISHAInventor: CANON KABUSHIKI KAISHA
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Patent number: 8431194Abstract: The invention provides a recording medium having 2 or more ink receiving layers on a substrate, wherein an upper layer of the ink receiving layers, which is a layer most distant from the substrate, and a lower layer, which is a layer located just under the upper layer, contain at least one selected from alumina hydrate and alumina, an acid and a hydrophilic binder, the acid contained in the upper layer is a carboxylic acid represented by the general formula [I], and the acid contained in the lower layer is a sulfonic acid represented by the general formula [II] R1—COOH??General formula [I] R2—SO3H.Type: GrantFiled: September 27, 2010Date of Patent: April 30, 2013Assignee: Canon Kabushiki KaishaInventors: Tetsuro Noguchi, Hisao Kamo, Yasuhiro Nito, Ryo Taguri, Isamu Oguri, Olivia Herlambang
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Patent number: 8377522Abstract: An inkjet receiver is described which comprises a support and one or more layer coated thereon, at least one layer of which comprises one or more metal organosilicate polymer particulate materials. The metal organosilicate polymer particulate materials are obtainable by contacting a metal salt with a silicon-containing compound having an organic substituent in an organic solvent, wherein either the silicon-containing compound contains a basic group and/or the reaction is conducted in the presence of a base, wherein the metal is selected from one or more of aluminum, magnesium strontium, calcium or zinc and the silicon-containing compound comprises hydrolyzable and non-hydrolyzable substituents such as to form a metal organosilicate polymer particulate material therefrom. The described inkjet receiver is useful for forming images by inkjet printing having excellent color fastness over time.Type: GrantFiled: December 19, 2007Date of Patent: February 19, 2013Assignee: Eastman Kodak CompanyInventors: Stephanie V. Desrousseaux, Olivier J. Poncelet, Gerard A. Friour
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Patent number: 8372494Abstract: An inkjet print medium includes a base substrate, a layer of a deinking solution at least partially diffused into the base substrate, and an ink-receiving layer established on the layer of the deinking solution. The deinking solution includes a flocculant in an amount ranging from about 0.1 wt. % to about 40 wt. % of a total wt. % of the deinking solution.Type: GrantFiled: October 29, 2009Date of Patent: February 12, 2013Assignee: Hewlett-Packard Development Company, L.P.Inventors: Laurie S. Mittelstadt, Manoj K. Bhattacharyya, Hou T. Ng
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Patent number: 8357438Abstract: A recording medium includes a substrate and at least two ink receiving layers formed on the substrate. In the recording medium, an uppermost ink receiving layer of the at least two ink receiving layers has a dry coated amount of 5 g/m2 or more and 20 g/m2 or less and contains hydrated alumina which a divalent metal compound adheres to. The ratio of an element content of the divalent metal to an element content of aluminum (element content of divalent metal/element content of aluminum) in the uppermost ink receiving layer is 0.001 or more and 0.03 or less.Type: GrantFiled: May 7, 2010Date of Patent: January 22, 2013Assignee: Canon Kabushiki KaishaInventors: Masaya Asao, Hiroshi Asakawa, Yuji Kondo
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Patent number: 8354149Abstract: The compositions and methods of the present application can provide transparent ink-jet recording films that may be used by printers relying on optical detection of fed media. Such films can be useful for medical image reproduction.Type: GrantFiled: October 26, 2011Date of Patent: January 15, 2013Assignee: Carestream Health Inc.Inventors: Sharon M. Simpson, David G. Baird, Heidy M. Vosberg
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Patent number: 8313808Abstract: An inkjet receiver comprising a support and one or more layers coated on the support, at least one of which comprises a particulate material and a binder, the particulate material comprising composite particles having an inner portion and an outer portion or core-shell arrangement, wherein the inner portion comprises a negatively-charged, positively-charged or functionalized latex, and the outer portion comprises an inorganic material having enhanced keeping properties and reduced ozone-induced dye fade.Type: GrantFiled: December 19, 2007Date of Patent: November 20, 2012Assignee: Eastman Kodak CompanyInventors: Gerard A. Friour, Stephanie V. Desrousseaux, Olivier J. Poncelet
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Patent number: 8298634Abstract: An inkjet printing system contains an inkjet printer loaded with a recording element comprising a support and an ink receiving layer containing: a) fusible polymeric particles; and b) a water soluble block copolymer having ethylene oxide and propylene oxide segments, the copolymer exhibiting a Draves wetting coefficient, for a 0.1 wt % solution in water at 25° C., of not more than 360 seconds. An inkjet printing method and an inkjet recording medium are also contemplated.Type: GrantFiled: September 30, 2008Date of Patent: October 30, 2012Assignee: Eastman Kodak CompanyInventors: Kurt M. Schroeder, Lawrence P. DeMejo, Gregory E. Missell
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Patent number: 8283005Abstract: An inkjet recording medium having on a substrate an ink-receiving layer containing inorganic fine particles and organic nitrogen-containing cationic polymer, with the organic nitrogen-containing cationic polymer being contained in a greater quantity in a half of the ink-receiving layer at a side nearer to the substrate (a near-substrate side) than in a half of the ink-receiving layer at a side further from the substrate (a far-substrate side) when the ink-receiving layer is divided into two equal parts by a plane parallel to the substrate.Type: GrantFiled: March 25, 2008Date of Patent: October 9, 2012Assignee: FUJIFILM CorporationInventors: Ryoichi Nakano, Hirokazu Shimada
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Publication number: 20120225223Abstract: The present invention provides an ink-jet recording material containing: a support; and at least two ink-receiving layers of an ink-receiving underlayer and an ink-receiving top layer, the ink-receiving layers containing a pigment and a binder and being disposed on the support; characterized in that the ink-receiving top layer contains: a finely agglomerated pigment with an average particle diameter of 0.008 to 0.7 ?m, selected from the group consisting of a silica, an alumina, and an alumina hydrate; and a coarse-grained pigment with an average particle diameter of 1 to 30 ?m, the coarse-grained pigment being contained in an amount of 1 to 15 parts by mass with respect to 100 parts by mass of the finely agglomerated pigment.Type: ApplicationFiled: May 15, 2012Publication date: September 6, 2012Applicant: OJI PAPER CO., LTD.Inventors: Tomomi TAKAHASHI, Ryu KITAMURA, Takehiko KISHIMOTO, Hideo MITSUI, Shigeru SUZUKI
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Patent number: 8257804Abstract: A recording medium includes a substrate and two or more ink receiving layers on each of a first surface and a second surface of the substrate. The ink receiving layers each contain a pigment and a binder. A1, A2, B1, and B2 (nm) satisfy the relationships (1), (2), and (3), where A1 is the peak of the pore radius distribution of the outermost ink receiving layer on the first surface side, A2 is the peak of the pore radius distribution of the ink receiving layer adjacent to the outermost layer, B1 is the peak of the pore radius distribution of the outermost ink receiving layer on the second surface side, and B2 is the peak of the pore radius distribution of the ink receiving layer adjacent to the outermost layer. The arithmetic average roughness Ra specified in JIS B 0601 of each of the outermost ink receiving layers is 0.50 ?m or more.Type: GrantFiled: January 26, 2011Date of Patent: September 4, 2012Assignee: Canon Kabushiki KaishaInventors: Hiroshi Asakawa, Hitoshi Nagashima, Takatoshi Tanaka
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Patent number: 8252392Abstract: The invention provides a recording medium comprising a substrate and an ink receiving layer that is provided on the substrate and contains alumina hydrate and a binder. A surface of the ink receiving layer is covered with a partial coating formed by a plurality of coatings containing a cationic polyurethane. The plurality of coatings have an average major diameter of 0.03 ?m or more and less than 1.00 ?m. The partial coating provides a coverage of 10% or more and less than 70% with respect to the surface of the ink receiving layer.Type: GrantFiled: October 8, 2010Date of Patent: August 28, 2012Assignee: Canon Kabushiki KaishaInventors: Isamu Oguri, Hisao Kamo, Yasuhiro Nito, Tetsuro Noguchi, Ryo Taguri, Olivia Herlambang
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Patent number: 8247045Abstract: An inkjet recording element is disclosed having a support and, on the support, (a) a porous base layer comprising particles of fumed silica and a hydrophilic binder and (b) an optional porous gloss layer above the base layer comprising particles of colloidal silica and a hydrophilic binder, wherein the particles of finned and colloidal silica are anionic. Also disclosed is a method of printing on such an inkjet recording element and a preferred method of making the inkjet recording element. The inkjet recording element can potentially have, in some embodiments, the advantages of improved image quality (reduced coalescence), and higher dye ink optical densities.Type: GrantFiled: November 8, 2007Date of Patent: August 21, 2012Assignee: Eastman Kodak CompanyInventors: Lori J. Shaw-Klein, Charles E. Romano, Jr.
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Patent number: 8247044Abstract: An inkjet recording element is disclosed having a support and, on the support, (a) a porous base layer comprising particles of fumed silica and a hydrophilic binder and (b) a porous gloss layer above the base layer comprising particles of colloidal silica and a hydrophilic binder, wherein the particles of fumed and colloidal silica are anionic. Also disclosed is a method of printing on such an inkjet recording element. The inkjet recording element can potentially have, in some embodiments, the advantages of improved image quality (reduced coalescence) and higher dye ink optical densities.Type: GrantFiled: November 8, 2007Date of Patent: August 21, 2012Assignee: Eastman Kodak CompanyInventors: Lori J. Shaw-Klein, Charles E. Romano, Jr.
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Publication number: 20120207949Abstract: A recording medium includes a support; and an ink-receiving layer, the ink-receiving layer having a lower layer and an upper layer, in which the lower layer contains fine inorganic particles, polyvinyl alcohol, and boric acid, the fine inorganic particles including at least one compound selected from alumina, hydrated alumina, and vapor-phase-process silica, in which the upper layer contains fine inorganic particles, polyvinyl alcohol, and boric acid, the fine inorganic particles including at least one compound selected from alumina and hydrated alumina, in which the lower layer has a boric acid content of 2.0% by mass to 7.0% by mass with respect to polyvinyl alcohol, and in which the upper layer has a boric acid content of 10.0% by mass to 30.0% by mass with respect to polyvinyl alcohol.Type: ApplicationFiled: February 7, 2012Publication date: August 16, 2012Applicant: CANON KABUSHIKI KAISHAInventors: Tetsuro Noguchi, Hisao Kamo, Yasuhiro Nito, Ryo Taguri, Isamu Oguri, Olivia Herlambang, Naoya Hatta, Shinya Yumoto
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Patent number: 8236394Abstract: A recording medium comprising a substrate and at least two porous ink receiving layers provided thereon of which a lower layer, second distant from the substrate, is arranged on the substrate side of an upper layer, most distant from the substrate. Pore distribution curves of the upper and lower layers respectively have one peak and two peaks. When pore radii giving the one peak and the two peaks are respectively regarded as R1 and R2, R3 where R2 is smaller than R3, R1 is 8 to 11 nm, R2 is 5 nm or more, R2 is smaller than R1, a difference between R1 and R2 is 2 nm or more, R3 is not less than R1, a difference between R3 and R1 is 3 nm or less. When pore volumes at the pore radii of R2 and R3 are respectively VR2 and VR3, a proportion VR2/VR3 is 0.8 to 2.4.Type: GrantFiled: February 9, 2011Date of Patent: August 7, 2012Assignee: Canon Kabushiki KaishaInventors: Takatoshi Tanaka, Hiroshi Asakawa, Hitoshi Nagashima
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Patent number: 8236393Abstract: An inkjet recording material which comprises a supporting substrate, a first bottom base coat applied to at least one surface of said substrate, and a second topcoat layer applied over said base coat. In said inkjet recording material, the base coat includes a combination of at least three pigments and the topcoat layer comprises pigments selected from the group consisting of fumed silica, silica gel, precipitated silica, colloidal silica, fumed alumina, boehmite, pseudo-boehmite or a mixture thereof.Type: GrantFiled: July 9, 2009Date of Patent: August 7, 2012Assignee: Hewlett-Packard Development Company, L.P.Inventors: Xi Zeng, Jason Swei, Kali Campbell
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Patent number: 8227054Abstract: A recording medium including a base paper, a first layer containing a binder, and a second layer containing a white pigment and an acid, formed in this order, wherein the base paper having the first layer provided thereon has a Cobb water absorbency of 2.0 g/m2 or below at the surface of the first layer as determined under a contact time of 120 seconds by a water absorbency test in accordance with JIS P8140, the recording medium has a water absorption amount of from 2 mL/m2 to 8 mL/m2 at the surface of the second layer as determined under a contact time of 0.5 seconds in accordance with the Bristow method, and the pH at the surface of the second layer is 5.5 or below.Type: GrantFiled: November 17, 2008Date of Patent: July 24, 2012Assignee: FUJIFILM CorporationInventors: Wataru Ono, Kiyoshi Irita, Kaoru Tojo
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Patent number: 8202586Abstract: The present invention provides an ink-jet recording material containing: a support; and at least two ink-receiving layers of an ink-receiving underlayer and an ink-receiving top layer, the ink-receiving layers containing a pigment and a binder and being disposed on the support; characterized in that the ink-receiving top layer contains: a finely agglomerated pigment with an average particle diameter of 0.008 to 0.7 ?m, selected from the group consisting of a silica, an alumina, and an alumina hydrate; and a coarse-grained pigment with an average particle diameter of 1 to 30 ?m, the coarse-grained pigment being contained in an amount of 1 to 15 parts by mass with respect to 100 parts by mass of the finely agglomerated pigment.Type: GrantFiled: January 26, 2006Date of Patent: June 19, 2012Assignee: Oji Paper Co., Ltd.Inventors: Tomomi Takahashi, Ryu Kitamura, Takehiko Kishimoto, Hideo Mitsui, Shigeru Suzuki
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Patent number: 8202585Abstract: An inkjet printing system, comprises an inkjet printer, an ink composition, and an inkjet recording media comprising a support, and coated on the support in order from the support, a porous base layer and a porous uppermost layer, each with particular limitations The inkjet recording media and printer system is manufacturable using low-cost materials in an efficient process requiring only a single coating and drying step and that gives images with excellent gloss, color density, and image quality.Type: GrantFiled: July 31, 2008Date of Patent: June 19, 2012Assignee: Eastman Kodak CompanyInventors: Terry C. Schultz, Bruce C. Campbell, Andrew M. Howe, Kenneth J. Ruschak, Robin D. Wesley
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Publication number: 20120148767Abstract: The present invention is to provide an ink jet recording material comprising at least two layers of ink-receptive layers mainly containing inorganic fine particles having an average secondary particle size of 500 nm or less on a resin-coated paper having a resin layer on at least one surface of a base paper, and the ink-receptive layer nearer to the support contains a pearlescent pigment.Type: ApplicationFiled: August 11, 2010Publication date: June 14, 2012Inventors: Masahiro Kawasaki, Toru Kaneko, Satoshi Kaneko, Daichi Miyake
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Patent number: 8197919Abstract: A recording material comprises a machine-finished paper which is coated with a synthetic resin on at least one side and at least one porous image recording layer, wherein the machine-finished paper is coated with a synthetic resin at least on the rear-side and this rear-side synthetic resin layer is perforated in such a way that the perforation holes reach as far as into the machine-finished paper, wherein the penetration depth is at most 1.5 to 4 times the synthetic resin layer thickness.Type: GrantFiled: October 9, 2007Date of Patent: June 12, 2012Assignee: Schoeller Technocell GmbH & Co. KGInventors: Andreas Overberg, Rainer Steinbeck
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Patent number: 8153210Abstract: A recording medium in which a base paper, a first layer including a binder and an antistatic agent, and a second layer including a white pigment are formed in this order; the content of the antistatic agent is from 0.2% by mass to 10% by mass based on an amount obtained by removing the antistatic agent from all solids in the first layer; the Cobb water absorption degree within a contact time of 120 sec at a surface of the first layer of the base paper provided with the first layer is 2.0 g/m2 or less, and the surface resistivity at 50% RH and 23° C. on the surface is 1×1012? or less; and the water absorption amount within a contact time of 0.5 sec determined by a Bristow test at a surface of the second layer is from 2 mL/m2 to 8 mL/m2.Type: GrantFiled: November 17, 2008Date of Patent: April 10, 2012Assignee: Fujifilm CorporationInventors: Hiroshi Kawakami, Ryoichi Nakano
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Patent number: 8133556Abstract: Two-layer receiver coatings particularly well adapted for use in inkjet printing comprise: A. A base layer comprising: 1. First pigment particles having (a) a number average particle size of 3-25 microns (?m), and (b) at least one of (i) an oil absorption value of at least 150 g oil/100 particles, and (ii) a pore volume of at least about 1.2 cubic meters per gram (cm3/g); and 2. Water-insoluble binder resin having a surface energy greater than 40 dyne per centimeter (dyn/cm); the first pigment particles and water-insoluble binder resin present at a weight ratio of 0.75 to 2; and B. An imaging layer comprising: 1. Second pigment particles having (a) a number average particle size of 0.01-4 (?m) aggregated to form an inter-particle region of submicron pores, and (b) a pore volume of 0.4 to 2.2 (cm3/g); and 2. Water-insoluble binder resin having a surface energy greater than 40 (dyn/cm); the second pigment particles and water-insoluble binder resin present at a weight ratio of 0.75 to 2.Type: GrantFiled: August 12, 2009Date of Patent: March 13, 2012Assignee: Brady Worldwide, Inc.Inventor: Bruce M. Klemann
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Patent number: 8114487Abstract: An inkjet printing system, comprises an inkjet printer, an ink composition, and an inkjet recording media comprising a support, and coated on the support in order from the support, a porous base layer, a porous intermediate layer, and a porous uppermost layer, each with particular limitations. The inkjet recording media and printer system is manufacturable using low-cost materials in an efficient process requiring only a single coating and drying step and that gives images with excellent gloss, color density and image quality.Type: GrantFiled: July 31, 2008Date of Patent: February 14, 2012Assignee: Eastman Kodak CompanyInventors: Terry C. Schultz, Bruce C. Campbell, Andrew M. Howe, Kenneth J. Ruschak, Robin D. Wesley
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Publication number: 20120021147Abstract: An inkjet print medium with a glossy ink-receiving surface, which includes a substrate, an undercoat layer containing acrylic-polyurethane hybrid polymer and polyoxazoline; and at least one ink-receiving layer containing inorganic pigment particles and a binder, wherein the undercoat is formed between the substrate and the at least one ink-receiving layer.Type: ApplicationFiled: October 23, 2009Publication date: January 26, 2012Inventor: Jessica Liao
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Publication number: 20120019587Abstract: An article in the form of a paper substrate having a water-swellable substrate coating on at least one of the first and second surfaces at a thickness of less than about 10 microns and. The substrate coating has an amount of a coating pigment sufficient to impart a Parker Print Smoothness value of at least about 4 to the at least one surface and is dispersed in a water-swellable coating pigment binder matrix in a coating pigment to binder matrix weight ratio of at least about 2:1. The coating pigment has larger porous coating pigment particles, and smaller coating pigment particles in a weight ratio of at least about 0.2:1. The substrate coating provides an ink-receptive porous surface. Also, a method for preparing such coated paper substrates, as well as a method for printing an image on the coated paper substrate with an inkjet printer using a lower ink usage level.Type: ApplicationFiled: July 22, 2011Publication date: January 26, 2012Applicant: INTERNATIONAL PAPER COMPANYInventor: MICHAEL F. KOENIG
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Patent number: 8084106Abstract: There are provided an inkjet recording medium having on a substrate an ink-receiving layer containing inorganic fine particles and a sulfur compound, with the sulfur compound being contained in a greater quantity in half of the ink-receiving layer at a side nearer to the substrate than in half of the ink-receiving layer at a side further from the substrate when the ink-receiving layer is divided into two equal parts by a plane parallel to the substrate, and a manufacturing method thereof.Type: GrantFiled: March 25, 2008Date of Patent: December 27, 2011Assignee: Fujifilm CorporationInventors: Ryoichi Nakano, Hirokazu Shimada
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Patent number: 8084107Abstract: The present invention is drawn to a print medium and a method of preparing the same. The print medium can include a media substrate, a porous ink-absorbing layer coated on the media substrate, and a porous ink-receiving layer coated on the porous ink-absorbing layer. The porous ink-absorbing layer can include semi-metal oxide or metal oxide particulates and a first binder, and the porous ink-receiving layer can include organosilane-functionalized semi-metal oxide or metal oxide particulates and a second binder.Type: GrantFiled: February 7, 2005Date of Patent: December 27, 2011Assignee: Hewlett-Packard Development Company, L.P.Inventor: Tienteh Chen
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Patent number: 8080291Abstract: An ink jet recording medium having a gas-permeable substrate, and an ink receiving layer and a surface layer provided in that order on the gas-permeable substrate, wherein the surface layer is formed through the steps of (1) applying a coating liquid comprising a first inorganic pigment and a binder onto the ink receiving layer, and (2) applying a coagulating liquid comprising a coagulant and a second inorganic pigment having a refractive index higher by 0.30 or more than that of the above first inorganic pigment and an average particle size of 100 nm or less onto the applied coating liquid to subject the coating liquid to a coagulating treatment followed by pressing a coating layer including the coating liquid and the coagulating liquid against a heated casting drum while the coating layer is in a wet condition to subject the coating layer to a cast treatment.Type: GrantFiled: April 28, 2010Date of Patent: December 20, 2011Assignee: Canon Kabushiki KaishaInventors: Takatoshi Tanaka, Hiroshi Asakawa, Hitoshi Nagashima, Takeshi Tsurusaki, Saki Suzuki
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Patent number: 8075963Abstract: The present invention relates to a material intended for forming images by inkjet printing having good stability to ozone and to light as well as a uniform surface, to obtain a high-quality printed image. The material comprises a support and at least one ink-receiving layer, wherein the ink-receiving layer comprises at least one polysaccharide, such as carrageenan, and at least one hydriphillic polymer having hydroxyl groups, such as polyvinyl alcohol and guar gum, and inorganic particles having a neutral or positive surface charge.Type: GrantFiled: February 7, 2006Date of Patent: December 13, 2011Assignee: Eastman Kodak CompanyInventor: Didier J. Martin
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Patent number: 8071185Abstract: A method for the preparation of silicon dioxide dispersions is described, wherein the surface of the silicon dioxide is modified by a treatment with the reaction products of a compound of trivalent aluminum with least one aminoorganosilane. These reaction products are formed in a separate reaction step. The present invention also relates to recording sheets for ink jet printing having such a dispersion incorporated in an ink-receiving layer.Type: GrantFiled: October 12, 2005Date of Patent: December 6, 2011Assignee: Ilford Imaging Switzerland GmbHInventors: Urs Fürholz, Vincent Ruffieux, Meinrad Schär
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Publication number: 20110293860Abstract: The invention provides a recording medium having excellent ink absorbency and capable of forming a sharp image thereon. The recording medium has a substrate, and a first layer and an outermost layer provided on the substrate in this order, wherein the first layer contains at least one of alumina and alumina hydrate, the outermost layer contains a pigment and is lower in refractive index than the first layer, and the absolute dry coating amount of the outermost layer is 0.1 g/m2 or more and 0.5 g/m2 or less.Type: ApplicationFiled: April 20, 2011Publication date: December 1, 2011Applicant: CANON KABUSHIKI KAISHAInventors: Isamu Oguri, Hisao Kamo, Yasuhiro Nito, Tetsuro Noguchi, Ryo Taguri, Olivia Herlambang, Naoya Hatta
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Patent number: 8062719Abstract: The present invention relates to a material intended for forming or printing images, comprising a support and at least one hydrophilic binder-based layer, and its manufacturing method, said method enabling the gelation process of the hydrophilic binder to be controlled. The material according to the invention is characterized in that in at least one of said hydrophilic binder-based layers, said hydrophilic binder is gelated by complexation with a complexing agent present on a heat-sensitive polymer or copolymer, that is hydrophobic at temperatures higher than its lower critical solution temperature LCST to protect the complexing agent, and water-soluble at temperatures less than its LCST to make the complexing agent accessible, the LCST of the heat-sensitive (co)polymer being higher than the setting temperature of said hydrophilic binder. The material according to the invention can be used as photographic material or as material taking aqueous ink compositions applied by the inkjet printing technique.Type: GrantFiled: June 13, 2007Date of Patent: November 22, 2011Assignee: Eastman Kodak CompanyInventors: Olivier J. Poncelet, Gérard A. Friour, Ilias Iliopoulos
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Publication number: 20110279554Abstract: An inkjet receiving medium including a substrate and having a topmost layer coated thereon at solid content of from 0.1 to 25 g/m2, wherein the topmost layer comprises from 30-70 wt % of one or more aqueous soluble salts of multivalent metal cations and at least 0.05 g/m2 of a cross-linked hydrophilic polymer binder. Improved optical density, reduced mottle and improved wet abrasion resistance are provided when the receiver is printed with an aqueous pigment-based ink. In further embodiments, the topmost layer may further comprise a latex dispersion for improved image durability.Type: ApplicationFiled: May 17, 2010Publication date: November 17, 2011Inventors: Thomas J. Dannhauser, Gerald A. Campbell
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Patent number: 8057031Abstract: A method of creating an image on a recording medium including a support having thereon a porous fusible layer, using an ink composition that is solid at room temperature and liquid at elevated temperature including the steps of generating droplets of the ink composition with an ink jet print head, transferring the droplets of the ink composition to the surface of the fusible layer, thermally treating the recording medium such that the ink transferred to fusible layer passes into the medium away from the surface of the fusible layer while the fusible layer remains substantially unfused, and when the ink has passed into the medium, treating the recording medium to fuse the fusible layer to become a protective overcoat. The present invention also pertains to a system for creating an image on a recording medium.Type: GrantFiled: August 20, 2007Date of Patent: November 15, 2011Assignee: OCE-Technologies B.V.Inventors: Guido G. Willems, Johannes P. J. C. Rooijakkers, Rudolf A. H. M. Sturme
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Patent number: 8053043Abstract: A recording sheet for ink jet printing is described, which consists of a support having coated onto said support at least two ink-receiving layers, wherein the ink-receiving layer situated next to the support contains nanoporous silicon dioxide with a positively charged surface and at least one binder and the ink-receiving layer situated further away from the support contains nanocrystalline, nanoporous aluminium oxide or aluminium oxide/hydroxide and at least one binder and, optionally, nanoporous silicon dioxide with a positively charged surface.Type: GrantFiled: February 21, 2007Date of Patent: November 8, 2011Assignee: ILFORD Imaging Switzerland GmbHInventors: Robert Beer, Pierre-Alain Brugger, Vincent Ruffieux, Martin Staiger, Rolf Steiger
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Patent number: 8048497Abstract: The present invention is drawn to a composition for cast-coating on ink-jet media. The composition includes a liquid vehicle, silica particulates, and an internal release agent. The composition is substantially free of polymeric binder and can improve the glossiness of a porous particulate-coated ink-receiving media by at least 2 gloss units at 20 degrees. The silica particulates can be suspended in the liquid vehicle at about 1-35 wt %, and can have a particle size of less than about 150 nm. The internal release agent can be present at about 0.5-10 wt %.Type: GrantFiled: April 27, 2007Date of Patent: November 1, 2011Assignee: Hewlett-Packard Development Company, L.P.Inventors: Eric L Burch, Douglas E Knight, Christopher Toles, David Rossing
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Patent number: 8034422Abstract: A manufacturing an ink-receiving medium comprising the steps of providing a support, treating the support with a salt of a multivalent metal cation, and coating upon one or each side of the support at least one porous ink-receiving top layer from an aqueous coating composition consisting of non-cationic components, wherein the non-cationic components comprise a binder and anionic particles of average particle size less than 2.5 microns, wherein the ink-receiving top layer comprises at least 50% of the total solids by weight, such that the water-soluble salt of a multivalent metal cation is able to diffuse into the ink-receiving top layer, the method further comprising drying the coating and optionally calendering the coating. Also disclosed is inkjet media made from such method and a method of printing using such inkjet media.Type: GrantFiled: May 7, 2009Date of Patent: October 11, 2011Assignee: Eastman Kodak CompanyInventors: Thomas J. Dannhauser, Douglas E. Bugner, Sharon R. Girolmo
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Patent number: 8034423Abstract: A recording medium in which a base paper, a first layer including a binder, and a second layer including kaolin and at least one pigment selected from calcined kaolin, delaminated kaolin, and amorphous silica are laminated in that order. A total content of at least one pigment selected from the group of pigments is 10% or more of the total amount of pigments in the second layer. A Cobb water absorption degree within a contact time of 120 sec in a water absorption test at a surface of the first layer of the base paper provided with the first layer is than 2.0 g/m2 or less, and a water absorption amount within a contact time of 0.5 sec determined by a Bristow test at a surface of the second layer is from 2 mL/m2 to 8 mL/m2.Type: GrantFiled: November 13, 2008Date of Patent: October 11, 2011Assignee: Fujifilm CorporationInventors: Hiroshi Kawakami, Ryoichi Nakano
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Patent number: 8007879Abstract: The invention provides a recording medium excellent in the water resistance and image fixability and a producing method thereof and an inkjet recording method using the recording medium, comprising: sequentially laminated, a base paper; a first layer containing a binder; and a second layer containing a white pigment and at least one selected from the group consisting of a urethane resin and an acrylic resin, each having a glass transition temperature of 50° C. or less, wherein a Cobb water absorption degree during a contact time of 120 sec in a water absorption test in accordance with JIS P8140 on a surface of the first layer disposed on the base paper is 2.0 g/m2 or less and an amount of water absorption during a contact time of 0.5 sec in the Bristow method on a surface of the second layer is 2 to 8 mL/m2.Type: GrantFiled: November 17, 2008Date of Patent: August 30, 2011Assignee: FUJIFILM CorporationInventor: Ryoichi Nakano
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Patent number: 8007920Abstract: The invention provides a coating composition that provides high brightness, high gloss and superior print quality. The coated product comprises a substrate coated on at least one side with a coating composition comprising a pigment component and a binder component that is made of mixture of two binder resins. Both binder resins are capable of film forming. The first binder resin provides coating gloss and adhesion properties and the second binder resin enhances coating porosity, adhesion, and anti-static properties. The first binder resin that is used at 60-95% by weight of the total binder resin blend is selected from the group consisting of vinyl acetate acrylate, styrene acrylate and styrene butadiene acrylic copolymers. The second binder resin that is used at 5-40% by weight of the total binder resin blend is selected from the group consisting of anion type polystyrene derivatives, polyethylene glycol and polypropylene glycol.Type: GrantFiled: May 29, 2009Date of Patent: August 30, 2011Assignee: International Paper CompanyInventors: Jay C. Song, Sen Yang