Particle (e.g., Pigment, Etc.) Containing Layer Patents (Class 428/32.25)
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Publication number: 20110183087Abstract: A recording medium includes a substrate and two or more ink receiving layers on each of a first surface and a second surface of the substrate. The ink receiving layers each contain a pigment and a binder. A1, A2, B1, and B2 (nm) satisfy the relationships (1), (2), and (3), where A1 is the peak of the pore radius distribution of the outermost ink receiving layer on the first surface side, A2 is the peak of the pore radius distribution of the ink receiving layer adjacent to the outermost layer, B1 is the peak of the pore radius distribution of the outermost ink receiving layer on the second surface side, and B2 is the peak of the pore radius distribution of the ink receiving layer adjacent to the outermost layer. The arithmetic average roughness Ra specified in JIS B 0601 of each of the outermost ink receiving layers is 0.50 ?m or more.Type: ApplicationFiled: January 26, 2011Publication date: July 28, 2011Applicant: CANON KABUSHIKI KAISHAInventors: Hiroshi Asakawa, Hitoshi Nagashima, Takatoshi Tanaka
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Publication number: 20110135855Abstract: The invention provides a method for producing a recording medium, comprising a step of coating one or more ink receiving layers provided on at least one surface of a substrate with an outermost layer coating liquid to form an outermost layer, an ink receiving layer, of said one or more ink receiving layers, which is nearest to the outermost layer containing alumina hydrate and a binder. The outermost layer coating liquid contains monodispersive and spherical cationic colloidal silica particles having an average particle size of 30 nm or more and 60 nm or less, polyvinyl alcohol having a saponification degree of 75% by mol or more and 85% by mol or less and a viscosity-average polymerization degree of 1,500 or more and 2,200 or less, and cationic polyurethane emulsion particles having an average particle size of 10 nm or more and 100 nm or less.Type: ApplicationFiled: November 19, 2010Publication date: June 9, 2011Applicant: CANON KABUSHIKI KAISHAInventors: Isamu Oguri, Hisao Kamo, Yasuhiro Nito, Tetsuro Noguchi, Ryo Taguri, Olivia Herlambang
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Patent number: 7955667Abstract: An inkjet recording medium includes a substrate, a base layer, and a porous ink receiving layer. The base layer is established on at least one surface of the substrate, and the porous ink receiving layer is established on the base layer. The base layer includes calcined clay present in an amount ranging from about 25% to about 75% by dry weight.Type: GrantFiled: March 15, 2007Date of Patent: June 7, 2011Assignee: Hewlett-Packard Development Company, L.P.Inventors: Richard J Mcmanus, Silke Courtenay, Sandeep Bangaru, Steven L Webb
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Patent number: 7935398Abstract: An image recording medium has a substrate having a hot melt extruded ink-receiving layer formed on a first side of the substrate. The ink-receiving layer includes at least 50% of a hydrogel by weight. The hydrogel is capable of absorbing at least 50% of its dry weight of water.Type: GrantFiled: January 4, 2007Date of Patent: May 3, 2011Assignee: Hewlett-Packard Development Company, L.P.Inventors: Chang Park, Xulong Fu, Kelly Ronk, Ronald J Selensky, Christine E Steichen, Gail Fisher, Dilip Patel
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Patent number: 7927675Abstract: A recording sheet for ink jet printing is provided, which consists of a support having coated thereon at least one ink-receiving layer consisting of binders and at least one nanoporous inorganic compound, wherein the recording sheet contains a polynuclear aluminum hydroxo complex with 30 aluminum atoms. In a preferred embodiment, the surface of the nanoporous inorganic compound is modified by a treatment with the aluminum hydroxo complex with 30 aluminum atoms.Type: GrantFiled: August 19, 2008Date of Patent: April 19, 2011Assignee: Ilford Imaging Switzerland GmbHInventors: Robert Beer, Rolf Steiger, Vincent Ruffieux, Dipanjan Banerjee, Gerhard Furrer, Daniel Rentsch, Björn Studer
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Patent number: 7923082Abstract: The present invention relates to an inkjet recording element having outstanding dye keeping properties in time. Said recording element comprises at least one molecular imprinted polymer having sites of selective recognition of dye molecules corresponding to the dye molecules used in inks for inkjet printing.Type: GrantFiled: September 2, 2005Date of Patent: April 12, 2011Assignee: Eastman Kodak CompanyInventors: Gerard A. Friour, Olivier J. Poncelet, Karsten O. Haupt, Laurence G. Poul
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Patent number: 7910182Abstract: The use of a boric acid, borate or derivate and/or salt thereof in a subbing layer coated onto a non resin-coated support beneath an upper layer comprising a binder and an inorganic particulate material such as fumed silica and an under layer between the upper layer and the subbing layer, which under layer comprises a binder and an inorganic particulate material such as calcium carbonate, increases the gloss of an ink jet receiver formed thereby whilst maintaining good ink absorption, good image density and minimizing puddling and associated coalescence, and where the receiver otherwise suffers from surface-cracking, decreases the propensity to cracking.Type: GrantFiled: June 30, 2005Date of Patent: March 22, 2011Assignee: Eastman Kodak CompanyInventor: Julie Baker
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Patent number: 7906187Abstract: An ink jet recording sheet is provided that delivers a photoparity image when printed with ink jet printer. The recording sheet comprises a two-layer coating. The bottom layer comprises amorphous silica and the top layer comprises spherical colloidal silica. Both silicas are rendered cationic. The recording sheet provides fast dry time, excellent image quality and superior water resistance and handle ability.Type: GrantFiled: April 3, 2003Date of Patent: March 15, 2011Assignee: Hewlett-Packard Development Company, L.P.Inventors: Yubai Bi, Pierre-Alain Brugger, Martin Staiger, Rolf Steiger, Karl Peternell
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Patent number: 7901748Abstract: An ink jet recording element with a support having thereon an image-receiving layer of inorganic particles and stabilizer particles, the stabilizer particles being free of any organic solvent and containing greater than about 80% by weight of a water-insoluble antioxidant and having a mean particle size of greater than 5 nm, the inorganic particles being greater than about 50% by weight of the ink receiving layer.Type: GrantFiled: December 12, 2001Date of Patent: March 8, 2011Assignee: Eastman Kodak CompanyInventors: Yongcai Wang, Kurt M. Schroeder, Lori J. Shaw-Klein, Thomas P. Nicholas, Sridhar Sadasivan, Christine M. Vargas
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Publication number: 20110008542Abstract: An inkjet recording material which comprises a supporting substrate, a first bottom base coat applied to at least one surface of said substrate, and a second topcoat layer applied over said base coat. In said inkjet recording material, the base coat includes a combination of at least three pigments and the topcoat layer comprises pigments selected from the group consisting of fumed silica, silica gel, precipitated silica, colloidal silica, fumed alumina, boehmite, pseudo-boehmite or a mixture thereof.Type: ApplicationFiled: July 9, 2009Publication date: January 13, 2011Inventors: Xi Zeng, Jason Swei, Kali Campbell
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Patent number: 7846516Abstract: The invention provides an ink jet recording medium which attains the prevention of the bronzing of cyan ink and the prevention of the migration of magenta ink at the same time and is excellent in image characteristics. The ink jet recording medium comprises a substrate and an ink-receiving layer provided with at least an upper layer as the outermost layer and a lower layer as a layer lying just under the upper layer, both layers having a porous structure formed of an alumina hydrate and a binder, wherein both of the upper and lower layers contain an alkylsulfonic acid and only the lower layer contains a cationic polymer.Type: GrantFiled: September 9, 2008Date of Patent: December 7, 2010Assignee: Canon Kabushiki KaishaInventors: Hisao Kamo, Hiroshi Asakawa, Hiroshi Kakihira, Hirokazu Hyakuda, Tetsuro Noguchi
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Patent number: 7829160Abstract: An inkjet recording element comprising an absorbent support, a porous base layer nearest the support and comprising precipitated calcium carbonate, a porous ink-receiving intermediate layer above the base layer and comprising hydrated alumina, and a porous ink-receiving upper layer above the intermediate layer and comprising a mixture of hydrated and fumed alumina. Also disclosed is an advantageous method of making such inkjet recording materials.Type: GrantFiled: February 28, 2006Date of Patent: November 9, 2010Assignee: Eastman Kodak CompanyInventors: Terry C. Schultz, Lori J. Shaw-Klein, Thomas P. Nicholas, Kenneth J. Ruschak
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Patent number: 7815985Abstract: The invention provides a recording medium that prevents ink overflowing even when printing is conducted in an ink quantity exceeding 100%, permits forming an image high in density and bright in color tone and can settle the cause of the occurrence of curling or cockling, a production process of the recording medium, a substrate for the recording medium and a production process of the substrate. The recording medium comprising a substrate and an ink-receiving layer formed on the substrate, wherein the substrate is composed mainly of a fibrous material and has, at a position adjacent to the ink-receiving layer in the substrate, a surface coated part region in a state that the surface of the fibrous material has been coated with an alumina hydrate, and the ink-receiving layer comprises a porous inorganic pigment as a principal component, and a production process of the recording medium.Type: GrantFiled: November 18, 2005Date of Patent: October 19, 2010Assignee: Canon Kabushiki KaishaInventor: Hitoshi Yoshino
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Publication number: 20100233391Abstract: This invention provides an ink-jet recording medium which improves balance between ink absorption and print image quality by ink-jet printing and is excellent in quick drying properties after printing and has an ink absorbing layer with high image quality. In the ink-jet recording medium, at least one ink absorbing layer including a material containing 5 to 90 wt % of a calcium carbonate pigment in terms of solid content is disposed on one side or both sides of a substrate, and this calcium carbonate pigment is one in which silica formed from soda silicate and calcium chloride is subjected to chemical or physical adsorption treatment on the surface of calcium carbonate particles so that the weight ratio of SiO2 to CaO is in a range of 2.0 to 80%, and the calcium carbonate pigment and the silica are preferably intertwined into a spherical form of 0.3 to 20 ?m.Type: ApplicationFiled: January 29, 2007Publication date: September 16, 2010Inventors: Yasuyuki Kumada, Shigeru Nawa, Hiroki Furusawa, Yasuhide Yoshida
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Patent number: 7791562Abstract: The present invention provides a method of displaying an image on a display device having first and second sides, said image including an light restricting silhouette pattern having a plurality of first transparent or translucent areas, and at least one design layer having at least one color, said at least one design layer being visible from one side of said display device and substantially less visible from the other side, said image being substantially transparent or translucent as viewed from the other side, comprising the steps: 1) providing at least a definition of said design layer to a computer; 2) generating a computerized version of said design layer with the computer; 3) outputting the computerized version of said design layer to said display device, the computerized version of said design layer being modified to subdivide said design layer into a plurality of second discrete transparent or translucent areas and other areas, and 4) displaying said modified design layer and said silhouette patternType: GrantFiled: February 9, 2007Date of Patent: September 7, 2010Assignee: 3M Innovative Properties CompanyInventors: Bruno Mueller, William E. Bird
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Patent number: 7766475Abstract: The present invention includes an image transfer sheet. The image transfer sheet comprises a release layer and a polymer layer. One or more of the release layer and the polymer layer comprise titanium oxide or other white pigment.Type: GrantFiled: August 18, 2008Date of Patent: August 3, 2010Inventors: Jodi A. Dalvey, Nabill F. Nasser
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Patent number: 7763333Abstract: This invention provides an ink jet recording medium, which is small in coverage and, at the same time, can simultaneously realize high gloss and ink absorption. The ink jet recording medium is produced by coating a lower layer comprising a water-absorptive pigment, a latex, and boric acid or its salt and an upper layer comprising a submicron pigment and polyvinyl alcohol, and conducting casting.Type: GrantFiled: September 7, 2006Date of Patent: July 27, 2010Assignee: Mitsubishi Paper Mills LimitedInventors: Makoto Kato, Masanori Nagoshi, Koji Igarashi, Yuri Watanabe, Hidetsugu Oda, Terufumi Yamaguchi
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Patent number: 7754296Abstract: An ink-jet media having an absorbent substrate with a front surface and a back surface. The front surface of the substrate is coated with an ink-vehicle permeable, preferably radiation-cured coating. A microporous ink-receptive coating is deposited on top of the ink-vehicle permeable coating. An optional protective layer may be deposited on top of the microporous ink-receptive layer. The back surface of the substrate may also be optionally coated with a polymer curl-controlling coating.Type: GrantFiled: September 27, 2005Date of Patent: July 13, 2010Assignee: Arkwright Advanced Coating, Inc.Inventors: Khizyr K. Khoultchaev, Cau T. Ho, Zhong Xu, Robert M. Conforti
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Patent number: 7735251Abstract: A card based business communication is produced in a unique manner in which a pigmented coating is applied over one face of the card substrate so as to change the appearance of the card material and provide a based for a high resolution image. An image is applied either directly over the pigmented coating or alternatively, the image may be reverse printed on a transparent film such that when the film is applied over the pigmented coating, the image will be visible through the face of the film.Type: GrantFiled: July 17, 2006Date of Patent: June 15, 2010Assignee: Ward/Kraft, Inc.Inventor: Jesse D. Crum
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Patent number: 7718237Abstract: An inkjet recording element comprising an absorbent support, a porous base layer nearest the support, a porous ink-receiving intermediate layer above the base layer, and a porous ink-receiving upper layer above the intermediate layer. The base layer and intermediate layers are each present in an amount of at least 25 g/m2 and the total dry weight coverage of the base layer, the intermediate layer, and the upper layer is 60 to 130 g/m2 in order to handle high fluxes of ink compositions during printing and to provide high gloss upon calendering. Also disclosed is an advantageous method of making such inkjet recording materials.Type: GrantFiled: February 28, 2006Date of Patent: May 18, 2010Assignee: Eastman Kodak CompanyInventors: Terry C. Schultz, Lori J. Shaw-Klein, Thomas P. Nicholas, Kenneth J. Ruschak
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Patent number: 7713599Abstract: The object of the present invention is to provide an ink jet recording material which has no cracks on the surface of the ink-receiving layer and possesses both the color developability and the absorbability of pigment inks. According to the present invention, there is provided an ink jet recording material formed by coating a coating solution of a pigment layer and a coating solution of at least one ink-receiving layer in succession on at least one side of a paper support and drying the resulting coating layers, wherein the pigment contained in the pigment layer has an average secondary particle diameter of not less than 1 ?m and not more than 5 ?m, 50% by volume or more of the total volume of the pigment has a secondary particle diameter of not less than 1.Type: GrantFiled: August 24, 2004Date of Patent: May 11, 2010Assignee: Mitsubishi Paper Mills LimitedInventors: Hiroaki Watanabe, Katsuaki Arai, Yasuro Yokota, Suguru Kashima
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Patent number: 7704574Abstract: A printing arrangement can include an ink-receiving coating applied to a media substrate, the ink-receiving coating having a coating thickness being configured to have a concentration gradient relative to the thickness. In the concentration gradient, the concentration of a cationic agent is greater in a center region of the ink-receiving coating relative to an upper region and a lower region.Type: GrantFiled: January 4, 2008Date of Patent: April 27, 2010Assignee: Hewlett-Packard Development Company, L.P.Inventors: Eric L. Burch, Douglas E. Knight
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Patent number: 7700170Abstract: There are disclosed an ink-jet recording material having at least two ink-receptive layers mainly containing fine particulate silica on a support, which comprises an ink-receptive layer positioned farthest from the support contains a water-soluble zirconium compound, and the ink-jet recording material satisfies at least one of the following requirements (a) and (b): (a) a water-soluble zirconium compound is present with a larger amount at a portion apart from the support than a portion nearer to the support, and a cationic emulsion is contained in the ink-receptive layer farthest from the support. (b) a water-soluble aluminum compound is contained in an ink-receptive layer positioned nearer to the support, and a process for preparing the same.Type: GrantFiled: October 11, 2005Date of Patent: April 20, 2010Assignee: Mitsubishi Paper Mills LimitedInventors: Makoto Motoda, Hideto Kiyama, Izumi Akaiwa
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Publication number: 20100075042Abstract: An inkjet receiver comprising a support and one or more layers coated on the support, at least one of which comprises a particulate material and a binder, the particulate material comprising composite particles having an inner portion and an outer portion or core-shell arrangement, wherein the inner portion comprises a negatively-charged, positively-charged or functionalized latex, and the outer portion comprises an inorganic material having enhanced keeping properties and reduced ozone-induced dye fade.Type: ApplicationFiled: December 19, 2007Publication date: March 25, 2010Inventors: Gerard A. Friour, Stephanie V. Desrousseaux, Olivier J. Poncelet
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Publication number: 20100075045Abstract: The invention provides an inkjet recording medium including at least two ink receiving layers containing inorganic fine particles and a water soluble resin on a non-water-absorptive support, wherein a mass ratio of the inorganic fine particles to the water soluble resin in an upper layer of the ink receiving layers which is the furthest away from the non-water-absorptive support is larger by 1 or more than that in a lower layer of the ink receiving layers which is located between the upper layer and the non-water-absorptive support, which is capable of forming an image with a high color density and small changes in hue; and an inkjet recording method of forming a clear and high-density recorded image with suppressed changes in hue from the hue immediately after printing.Type: ApplicationFiled: September 15, 2009Publication date: March 25, 2010Applicant: FUJIFILM CORPORATIONInventors: Hideki KAIMOTO, Wataru ONO
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Patent number: 7674401Abstract: The present invention relates to a metal oxide dispersion, which can form a metal thin film onto a substrate by heat treatment at a low temperature, wherein a metal oxide having a particle diameter of less than 200 nm is dispersed in the dispersion medium. By heat treating the dispersion after applying it onto a substrate, a metal thin film is formed.Type: GrantFiled: December 16, 2002Date of Patent: March 9, 2010Assignee: Asahi Kasei Kabushiki KaishaInventor: Mutsuhiro Maruyama
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Patent number: 7661806Abstract: An inkjet recording element comprising a support having thereon in order, from top to bottom, an upper fusible, porous layer comprising fusible polymeric particles, which particles comprise a thermoplastic polymer with reactive functional groups, the inkjet recording element further comprising a lower crosslinker-containing layer in which a polyfunctional compound has complementary reactive functional groups capable of crosslinking the reactive functional groups on the thermoplastic polymer under fusing. Optionally, an ink-carrier-liquid receptive layer is present between the fusible, porous layer and the support. Also disclosed is a method of inkjet printing on the element.Type: GrantFiled: March 11, 2005Date of Patent: February 16, 2010Assignee: Eastman Kodak CompanyInventors: Gregory E. Missell, Lawrence P. DeMejo, Xiaoru Wang
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Publication number: 20100026773Abstract: An inkjet printing system, comprises an inkjet printer, an ink composition, and an inkjet recording media comprising a support, and coated on the support in order from the support, a porous base layer, a porous intermediate layer, and a porous uppermost layer, each with particular limitations. The inkjet recording media and printer system is manufacturable using low-cost materials in an efficient process requiring only a single coating and drying step and that gives images with excellent gloss, color density and image quality.Type: ApplicationFiled: July 31, 2008Publication date: February 4, 2010Inventors: Terry C. Schultz, Bruce C. Campbell, Andrew M. Howe, Kenneth J. Ruschak, Robin D. Wesley
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Publication number: 20100028571Abstract: An inkjet printing system, comprises an inkjet printer, an ink composition, and an inkjet recording media comprising a support, and coated on the support in order from the support, a porous base layer and a porous uppermost layer, each with particular limitations The inkjet recording media and printer system is manufacturable using low-cost materials in an efficient process requiring only a single coating and drying step and that gives images with excellent gloss, color density, and image quality.Type: ApplicationFiled: July 31, 2008Publication date: February 4, 2010Inventors: Terry C. Schultz, Bruce C. Campbell, Andrew M. Howe, Kenneth J. Ruschak, Robin D. Wesley
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Patent number: 7655286Abstract: An inkjet recording element comprising a support having thereon in order, from top to bottom, a fusible, porous ink-transporting layer comprising fusible polymeric particles, which particles comprise a thermoplastic polymer with reactive functional groups, the ink-transporting layer further comprising a multifunctional compound having complementary reactive functional groups capable of crosslinking the reactive functional groups on the thermoplastic polymer. The ink-transporting layer is over a fusible dye-trapping layer that preferably comprises a mordant. Optionally, an ink-carrier-liquid receptive layer is present between the dye-trapping layer and the support.Type: GrantFiled: June 30, 2004Date of Patent: February 2, 2010Assignee: Eastman Kodak CompanyInventors: Lawrence P. DeMejo, Xiaoru Wang, Gregory E. Missell, Allan Wexler
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Patent number: 7651747Abstract: A fusible print medium for use in inkjet printing. The fusible print medium includes a substrate and a fusible layer, the fusible layer comprising at least one organic pigment and at least one solid plasticizer. A method of producing the fusible print medium and a method of producing a photographic quality image are also disclosed.Type: GrantFiled: August 23, 2004Date of Patent: January 26, 2010Assignee: Hewlett-Packard Development Company, L.P.Inventors: Tienteh Chen, Radha Sen
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Patent number: 7615265Abstract: A novel recording material for the inkjet printing process has a substrate and an ink receiving layer which is applied on at least one side of the substrate, the ink receiving layer containing an inorganic pigment and an ink fixative comprising at least two substances. The first substance is a polyamine epichorohydrin and the second substance is a polyvalent metal salt. This recording material is characterized in that the first substance is a medium-molecular, branched polyamine epichlorohydrin condensation product, the ratio of the first substance to the second substance is between 3:1 and 16:1, the pigment makes up at least 80 percent by weight with a D50 particle size (Malvern) ranging from 4 ?m inclusive to 12 ?m inclusive, and the ratio of ink fixative to pigment ranges from 1:2 inclusive to 1:6 inclusive. The invention is further directed to a method for recording by the discontinuous inkjet printing process which uses the novel recording material.Type: GrantFiled: August 22, 2002Date of Patent: November 10, 2009Assignee: Mitsubishi Hitec Paper Flensburg GmbHInventors: Gerhard Stork, Makato Kato, Karsten Lerius
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Patent number: 7608338Abstract: The invention provides a coating composition that provides high brightness, high gloss and superior print quality. The coated product comprises a substrate coated on at least one side with a coating composition comprising a pigment component and a binder component that is made of mixture of two binder resins. Both binder resins are capable of film forming. The first binder resin provides coating gloss and adhesion properties and the second binder resin enhances coating porosity, adhesion, and anti-static properties. The first binder resin that is used at 60-95% by weight of the total binder resin blend is selected from the group consisting of vinyl acetate acrylate, styrene acrylate and styrene butadiene acrylic copolymers. The second binder resin that is used at 5-40% by weight of the total binder resin blend is selected from the group consisting of anion type polystyrene derivatives, polyethylene glycol and polypropylene glycol.Type: GrantFiled: June 12, 2003Date of Patent: October 27, 2009Assignee: International Paper CompanyInventors: Jay Cheng Song, Sen Yang
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Publication number: 20090233016Abstract: A method for the preparation of silicium dioxide dispersions is provided, wherein the surface of the silicium dioxide is modified by a treatment with the reaction products, formed in a separate reaction step, of at least one compound of trivalent aluminum or of tetravalent zirconium or a mixture thereof with at least one aminoorganosilane; and the invention also relates to recording sheets for ink jet printing having such a dispersion incorporated in an ink-receiving layer.Type: ApplicationFiled: March 2, 2009Publication date: September 17, 2009Inventors: Urs Furholz, Vincent Ruffieux, Meinrad Schar
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Patent number: 7585553Abstract: An inkjet receiver layer is constructed of an alumina-containing layer also containing a binder with an essentially binder-free, colloidal, cationic silica top-coat. The colloidal cationic silica topcoat provides improved image quality (color gamut and gloss) and increased resistance to scratching, while maintaining a high absorption of ink.Type: GrantFiled: May 24, 2002Date of Patent: September 8, 2009Assignee: Hewlett-Packard Development Company, L.P.Inventors: Eric L Burch, Yubai Bi, Pierre-Alain Brugger, Martin Staiger
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Publication number: 20090214806Abstract: The invention provides an ink jet recording medium having at least two ink absorbing layers provided on or above a non-water-absorbing support, wherein: a first ink absorbing layer, which is provided uppermost among the at least two ink absorbing layers, contains at least silanol-modified polyvinyl alcohol, polyaluminum chloride and pseudo boehmite alumina, and a second ink absorbing layer, which is adjacent to the first ink absorbing layer, contains at least pseudo boehmite alumina having a secondary particle diameter of 80 nm or less, polyvinyl alcohol, boric acid, and a water-soluble zirconium salt. The invention further provides a method of manufacturing the ink jet recording medium.Type: ApplicationFiled: February 24, 2009Publication date: August 27, 2009Applicant: FUJIFILM CORPORATIONInventor: Masamichi Kobayashi
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Publication number: 20090213151Abstract: A manufacturing an ink-receiving medium comprising the steps of providing a support, treating the support with a salt of a multivalent metal cation, and coating upon one or each side of the support at least one porous ink-receiving top layer from an aqueous coating composition consisting of non-cationic components, wherein the non-cationic components comprise a binder and anionic particles of average particle size less than 2.5 microns, wherein the ink-receiving top layer comprises at least 50% of the total solids by weight, such that the water-soluble salt of a multivalent metal cation is able to diffuse into the ink-receiving top layer, the method further comprising drying the coating and optionally calendering the coating. Also disclosed is inkjet media made from such method and a method of printing using such inkjet media.Type: ApplicationFiled: May 7, 2009Publication date: August 27, 2009Inventors: Thomas J. Dannhauser, Douglas E. Bugner, Sharon R. Girolmo
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Patent number: 7563494Abstract: There is disclosed an ink-jet recording material which comprises a light transmitting support, at least one ink-receptive layer provided on one surface of the support and at least one back-coating layer provided on the opposite surface of the support, wherein at least one of the back-coating layers contains inorganic fine particles having an average particle size of a primary particle of 5 to 50 nm and a binder, and a void ratio of the layer is 70% by volume or less.Type: GrantFiled: February 13, 2002Date of Patent: July 21, 2009Assignee: Mitsubishi Paper Mills LimitedInventors: Takeshi Nagashima, Satoshi Kaneko
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Publication number: 20090136692Abstract: The present invention provides an ink-jet recording material containing: a support; and at least two ink-receiving layers of an ink-receiving underlayer and an ink-receiving top layer, the ink-receiving layers containing a pigment and a binder and being disposed on the support; characterized in that the ink-receiving top layer contains: a finely agglomerated pigment with an average particle diameter of 0.008 to 0.7 ?m, selected from the group consisting of a silica, an alumina, and an alumina hydrate; and a coarse-grained pigment with an average particle diameter of 1 to 30 ?m, the coarse-grained pigment being contained in an amount of 1 to 15 parts by mass with respect to 100 parts by mass of the finely agglomerated pigment.Type: ApplicationFiled: January 26, 2006Publication date: May 28, 2009Applicant: Oji Paper C., Ltd.Inventors: Tomomi Takahashi, Ryu Kitamura, Takehiko Kishimoto, Hideo Mitsui, Shigeru Suzuki
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Publication number: 20090123675Abstract: An inkjet recording element is disclosed having a support and, on the support, (a) a porous base layer comprising particles of fumed silica and a hydrophilic binder and (b) an optional porous gloss layer above the base layer comprising particles of colloidal silica and a hydrophilic binder, wherein the particles of finned and colloidal silica are anionic. Also disclosed is a method of printing on such an inkjet recording element and a preferred method of making the inkjet recording element. The inkjet recording element can potentially have, in some embodiments, the advantages of improved image quality (reduced coalescence), and higher dye ink optical densities.Type: ApplicationFiled: November 8, 2007Publication date: May 14, 2009Inventors: Lori J. Shaw-Klein, Charles E. Romano, JR.
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Publication number: 20090123676Abstract: This invention provides an ink jet recording medium, which is small in coverage and, at the same time, can simultaneously realize high gloss and ink absorption. The ink jet recording medium is produced by coating a lower layer comprising a water-absorptive pigment, a latex, and boric acid or its salt and an upper layer comprising a submicron pigment and polyvinyl alcohol, and conducting casting.Type: ApplicationFiled: September 7, 2006Publication date: May 14, 2009Applicant: Mitsubishi Paper Mills LimitedInventors: Makoto Kato, Masanori Nagoshi, Koji Igarashi, Yuri Watanabe, Hidetsugu Oda, Terufumi Yamaguchi
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Publication number: 20090123674Abstract: An inkjet recording element is disclosed having a support and, on the support, (a) a porous base layer comprising particles of fumed silica and a hydrophilic binder and (b) a porous gloss layer above the base layer comprising particles of colloidal silica and a hydrophilic binder, wherein the particles of fumed and colloidal silica are anionic. Also disclosed is a method of printing on such an inkjet recording element. The inkjet recording element can potentially have, in some embodiments, the advantages of improved image quality (reduced coalescence) and higher dye ink optical densities.Type: ApplicationFiled: November 8, 2007Publication date: May 14, 2009Inventors: Lori J. Shaw-Klein, Charles E. Romano, JR.
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Patent number: 7507451Abstract: An inkjet recording element comprises a support having thereon in order, from top to bottom, a fusible, porous layer comprising fusible multifunctional polymer particles derived from an aqueous dispersion that comprise a thermoplastic polymer with at least two reactive functional groups capable of crosslinking with each other. Optionally, an ink-carrier-liquid receptive layer is present between the fusible, porous layer and the support. Also disclosed is a method of inkjet printing on the element.Type: GrantFiled: March 11, 2005Date of Patent: March 24, 2009Assignee: Eastman Kodak CompanyInventors: Gregory E. Missell, Lawrence P. DeMejo, Xiaoru Wang
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Publication number: 20090074995Abstract: A method of manufacturing an ink-receiving medium comprising the steps of providing a support, treating the support with a salt of a multivalent metal cation, and coating upon one or each side of the support at least one porous ink-receiving top layer from an aqueous coating composition consisting of non-cationic components, wherein the non-cationic components comprise a binder and anionic particles of average particle size less than 2.5 microns, wherein the ink-receiving top layer comprises at least 50% of the total solids by weight, such that the water-soluble salt of a multivalent metal cation is able to diffuse into the ink-receiving top layer, the method further comprising drying the coating and optionally calendering the coating. Also disclosed is inkjet media made from such method and a method of printing using such inkjet media.Type: ApplicationFiled: September 14, 2007Publication date: March 19, 2009Inventors: Thomas J. Dannhauser, Douglas E. Bugner, Sharon R. Girolmo
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Publication number: 20090011155Abstract: The invention provides an ink jet recording medium which attains the prevention of the bronzing of cyan ink and the prevention of the migration of magenta ink at the same time and is excellent in image characteristics. The ink jet recording medium comprises a substrate and an ink-receiving layer provided with at least an upper layer as the outermost layer and a lower layer as a layer lying just under the upper layer, both layers having a porous structure formed of an alumina hydrate and a binder, wherein both of the upper and lower layers contain an alkylsulfonic acid and only the lower layer contains a cationic polymer.Type: ApplicationFiled: September 9, 2008Publication date: January 8, 2009Applicant: CANON KABUSHIKI KAISHAInventors: Hisao Kamo, Hiroshi Asakawa, Hiroshi Kakihira, Hirokazu Hyakuda, Tetsuro Noguchi
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Publication number: 20080254240Abstract: Printable articles having a single coating/ink receiving layer are disclosed. In addition, printable articles having a single coating/ink receiving layer disposed on the printable article and a second coating layer disposed on the coating/ink receiving layer are disclosed.Type: ApplicationFiled: April 10, 2007Publication date: October 16, 2008Inventors: Bor-Jiunn Niu, Dheya Alfekri
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Publication number: 20080241437Abstract: There are provided an inkjet recording medium having on a substrate an ink-receiving layer containing inorganic fine particles and a sulfur compound, with the sulfur compound being contained in a greater quantity in half of the ink-receiving layer at a side nearer to the substrate than in half of the ink-receiving layer at a side further from the substrate when the ink-receiving layer is divided into two equal parts by a plane parallel to the substrate, and a manufacturing method thereof.Type: ApplicationFiled: March 25, 2008Publication date: October 2, 2008Applicant: FUJIFILM CORPORATIONInventors: Ryoichi NAKANO, Hirokazu SHIMADA
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Publication number: 20080160230Abstract: This invention provides an ink jet recording medium comprising a support and at least two layers on one side of the support, wherein the uppermost layer placed farthest from the support comprises a porous colloidal silica and a binder, at least one of the layer(s) that is not the uppermost layer comprises inorganic fine particles having an average primary particle diameter of less than 20 nm and a binder, the content of the inorganic fine particles is 10 g/m2 or more, the ratio (A/B) by mass between the inorganic fine particles (A) and the binder (B) is from 3 to 15, and at least the uppermost layer and/or a layer other than the uppermost layer comprises a sulfoxide compound and/or a thioether compound.Type: ApplicationFiled: December 17, 2007Publication date: July 3, 2008Applicant: FUJIFILM CORPORATIONInventor: Masamichi Kobayashi
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Patent number: 7374800Abstract: A printing arrangement can include an ink-receiving coating applied to a media substrate, the ink-receiving coating having a coating thickness being configured to have a concentration gradient relative to the thickness. In the concentration gradient, the concentration of a cationic agent is greater in a center region of the ink-receiving coating relative to an upper region and a lower region.Type: GrantFiled: February 9, 2005Date of Patent: May 20, 2008Inventors: Eric L. Burch, Douglas E. Knight
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Publication number: 20080085384Abstract: An ink receptive article including a substrate having on at least a portion of a major surface thereof an antistatic layer, and wherein the antistatic layer has on at least a portion of a major surface thereof an ink receptive layer, wherein the ink receptive layer includes a crosslinked polymer selected from the group consisting of polyurethanes, polyethers, polyesters, polyacrlylics, polyureas, copolymers thereof, and blends thereof.Type: ApplicationFiled: October 4, 2006Publication date: April 10, 2008Inventors: Caroline M. Ylitalo, Scott A. Boyd, Joseph C. Carls, Eugene H. Carlson, Christopher K. Haas, James M. Jonza, Mark J. Pellerite, Robert F. Watkins