Vapor Or Gas Barrier, Polymer Derived From Vinyl Chloride Or Vinylidene Chloride, Or Polymer Containing A Vinyl Alcohol Unit Is Sandwiched Between Layers (continuous Layer) Patents (Class 428/36.7)
  • Patent number: 6420046
    Abstract: A film includes a core layer including a polymer such as nylon 6, nylon 66, nylon 6,66, and/or polyamide elastomer; first and second intermediate layers including polymeric adhesive; a first outer layer including ethylene/alpha olefin copolymer having a density of less than 0.940 grams/cubic centimeter; and a second outer layer including heat sealable polymer such as (1) ethylene/alpha olefin copolymer having a density less than 0.921 grams/cubic centimeter, (2) ethylene/vinyl acetate copolymer, (3) ethylene/alkyl (meth)acrylate copolymer, (4) ethylene/(meth)acrylic acid copolymer, and/or (5) ionomer. The film has good resistance to tear, and good resistance to impact, making it useful for packaging coins and other objects. A bag made from the film, and an article such as a sealed bag filled with coins or other objects, are also disclosed.
    Type: Grant
    Filed: January 29, 1999
    Date of Patent: July 16, 2002
    Assignee: Cryovac, Inc.
    Inventors: Gautam P. Shah, William W. Furrer
  • Patent number: 6406763
    Abstract: A multilayer, heat-shrinkable food packaging film useful for forming a post packaging pasteurization bag. The film includes at least three layers: 1) a first outer layer formed from a resin composition having a Vicat softening point of at least 100° C., 2) a second outer layer having one or more thermoplastic gloss materials of polyester, ethylene/alpha-olefin copolymer having a melt index of greater than 1 g/10 minutes, styrene/butadiene block copolymer, and ethylene/styrene random copolymer, and 3) one or more inner layers between the first and second outer layers. At least one of the inner layers includes an ethylene/alpha-olefin copolymer. The film has a total free shrink of at least 40% at 85° C. If the second outer layer includes polyester, then each of the inner layers of the multilayer film is devoid of a weight amount of polyamide or polyester greater than the weight amount of polyester in the second outer layer.
    Type: Grant
    Filed: December 23, 1999
    Date of Patent: June 18, 2002
    Assignee: Cryovac, Inc.
    Inventors: John R. Wolf, George D. Wofford, Blaine C. Childress
  • Patent number: 6406644
    Abstract: Oxygen scavenging materials incorporated into or attached to a package such as a gable-top or rectangular carton, used to package foods, beverages or other oxygen sensitive materials, and thereby increase shelf-life by decreasing oxygen in the headspace of the package, and decreasing oxidation of the packaged product.
    Type: Grant
    Filed: February 20, 2001
    Date of Patent: June 18, 2002
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Gary D. Jerdee, James P. Leonard, Ta Yen Ching, Joseph L. Goodrich, Brad D. Rodgers, Richard P. Schmidt
  • Publication number: 20020068140
    Abstract: A multi-layer closure liner for carbonated beverage containers and the like, including a gas barrier layer, a first tie layer on an upper surface of the gas barrier layer, a second tie layer on a lower surface of the gas barrier layer, a first polyolefinic resin layer on the upper surface of the first tie layer, and a second polyolefinic layer on the lower surface of the second tie layer. In the preferred embodiment, the gas barrier layer is ethylene vinyl alcohol copolymer (EVOH), the first and second tie layers are functionalized polyolefin and the first and second polyolefinic resin layers are ethylene vinyl acetate (EVA). The layers defining the closure liner are preferably simultaneously formed using a co-extrusion process to prevent the gas barrier layer from being exposed to moisture.
    Type: Application
    Filed: November 1, 2001
    Publication date: June 6, 2002
    Applicant: Tri-Seal Holdings, Inc.
    Inventors: Harvey Finkelstein, Victor Flores, Anatoly Verdel, Bruce Bums, Richard McKenna
  • Patent number: 6399171
    Abstract: The invention relates to a method of laminating two substrates by coating at least one side of a substrate with a laminating adhesive, bringing a coated side of said substrate into contact with a second substrate to form a three layer film, and treating said three layer film with a free radical initiator, wherein said laminating adhesive is formed by mixing an ethylenically unsaturated acid and a polyamine.
    Type: Grant
    Filed: July 15, 1999
    Date of Patent: June 4, 2002
    Assignees: Dow Corning Corporation, EG Technology Partners, L.P., UCB Films PLC, Star House
    Inventors: Patrick J. Merlin, Daniel Futter, John E. Wyman, Imtiaz Rangwalla, Gary Power, Karen Branch
  • Patent number: 6395358
    Abstract: Coinjection stretch blow molded containers containing thermoplastic polyester resin and an EVOH resin are obtained, which have greatly improved impact delamination resistance. The containers comprise a thermoplastic polyester layer (layer a) and an ethylene-vinyl alcohol copolymer layer (layer b), with the layer a being kept in direct contact with the both surf aces of the layer b, wherein the ethylene-vinyl alcohol copolymer satisfies the following formulae (1) and (2) and its differential scanning calorimetry (DSC) gives a single peak f or crystal fusion: 25≦ETb≦48  (1) 92≦SDb≦99  (2) wherein ETb indicates the ethylene content (mol %) of the ethylene-vinyl alcohol copolymer, and SDb indicates the degree of saponification (%) of the ethylene-vinyl alcohol copolymer.
    Type: Grant
    Filed: April 9, 1999
    Date of Patent: May 28, 2002
    Assignee: Kuraray Co., Ltd.
    Inventors: Shinji Tai, Hiroyuki Shimo, Nahoto Hayashi, Masako Chigami
  • Patent number: 6395357
    Abstract: A fuel permeation barrier fuel tank for a vehicle includes a tank shell having a wall formed from a plurality of layers. The layers include at least an inner layer, an outer layer, a fuel permeation barrier layer disposed between the inner layer and the outer layer, and at least one adhesive layer being made of at least one of a chlorinated polyethylene and chlorosulfonated polyethylene disposed between either the inner layer and the outer layer and the fuel permeation barrier layer.
    Type: Grant
    Filed: September 1, 2000
    Date of Patent: May 28, 2002
    Assignee: Delphi Technologies, Inc.
    Inventor: Ismat Ali Abu-Isa
  • Patent number: 6391412
    Abstract: Disclosed herein is a fuel tank of multi-layer construction having good impact resistance as well as good barrier properties for gasoline, especially one containing methanol and MTBE. The fuel tank comprises (a) inner and outer layers of high-density polyethylene, (b) intermediate layers of adhesive resin, and (c) a core layer of ethylene-vinylalcohol copolymer, with said core layer (c) being shifted to the inside. For better performance, the layer (c) has a thickness which satisfies the formula below. 0.005≦A/B≦0.13  (1) where A is the thickness of the layer (c), and B is the thickness of all the layers. The fuel tank is suitable especially for oxygen-containing gasoline.
    Type: Grant
    Filed: December 30, 1999
    Date of Patent: May 21, 2002
    Assignee: Kuraray Co., Ltd.
    Inventors: Nobuhiro Hata, Taichi Negi
  • Patent number: 6391408
    Abstract: This invention relates to articles made of polyester, preferably polyethylene terephthalate (PET), having coated directly to at least one of the surfaces thereof one or more layers of thermoplastic material with good gas-barrier characteristics, and novel methods of making such articles. Preferably the barrier-coated articles take the form of preforms coated by at least one layer of barrier material and the containers blow-molded therefrom. Such barrier-coated containers are preferably of the type to hold beverages such as soft drinks, beer or juice. The preferred barrier materials have a lower permeability to oxygen and carbon dioxide than PET as well as key physical properties similar to PET. The materials and methods provide that the barrier layers have good adherence to PET, even during and after the blow molding process to form containers from preforms. Preferred barrier coating materials include poly(hydroxyamino ethers).
    Type: Grant
    Filed: October 19, 1998
    Date of Patent: May 21, 2002
    Assignee: Advanced Plastics Technologies, Ltd.
    Inventor: Gerald A. Hutchinson
  • Patent number: 6391407
    Abstract: An oxygen absorbing multi-layer film which comprises a first outer surface comprising an uncolored oxygen permeating layer 11 comprising an oxygen permeating polyolefin which does not contain a pigment; a colored concealing, oxygen permeating layer 12 disposed under the uncolored oxygen permeating layer 11, the color concealing, oxygen permeating layer 11 comprising an oxygen permeating polyolefin and a pigment; a second outer surface disposed opposite to the first outer surface, the second outer surface comprising a gas barrier layer 3; and an oxygen absorbing layer 2 disposed between the colored concealing, oxygen permeating layer 12 and the gas barrier layer 3, the oxygen absorbing layer 2 being made of an oxygen absorbing resin composition comprising an iron-containing deoxidizing agent and an oxygen permeating polyolefin. The oxygen absorbing multi-layer film can be used as a packaging material and has desirable strength, heat resistance, heat-sealing properties, hot tack properties and appearance.
    Type: Grant
    Filed: June 8, 1998
    Date of Patent: May 21, 2002
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Takashi Kashiba, Ryoji Otaki, Yoshiki Ito
  • Patent number: 6383583
    Abstract: A laminate having a layer structure of A/C/B/C/D, which is obtained by coextruding a saponified ethylene-vinyl acetate copolymer (B) and an adhesive resin (C) on one side of a polypropylene film (A) oriented at least uniaxially, to give a laminate having a layer structure of A/C/B/C, stretching this laminate in the transverse direction, and laminating a heat sealing layer (D) on a surface of the adhesive resin (C) of the laminate, and a production method thereof. The laminate of the present invention is superior in gas barrier property, moisture proof, aromatic proof and the like under particularly high humidity, and particularly when formed into a packaging bag, the packing bag shows superior sealing performance and appearance. Hence, the laminate of the present invention is useful for various packaging applications and as a packaging bag and the like for food and pharmaceutical preparations.
    Type: Grant
    Filed: September 30, 1999
    Date of Patent: May 7, 2002
    Assignees: Nippon Synthetic Chemical Industry Co., Ltd., Futamura Chemical Industries Co., Ltd.
    Inventors: Kenji Ninomiya, Tomoyuki Yamamoto, Motohiro Enokida
  • Publication number: 20020051891
    Abstract: Described are structures comprising, successively: a first layer of high density polyethylene (HDPE), a layer of binder, a second layer of EVOH or of a mixture based on EVOH, optionally a third layer of polyamide (A) or of a mixture of polyamide (A) and polyolefin (B). Also described are devices for transferring or storing fluids and more particularly tubes, tanks, chutes, bottles and containers consisting of the above structure and in which the barrier layer (the second or the combination of the second and the third layer) is in direct contact with the fluid contained or transported.
    Type: Application
    Filed: February 6, 2001
    Publication date: May 2, 2002
    Applicant: ELF ATOCHEM S.A.
    Inventors: Christophe Le Roy, Joachim Merziger, Jerome Pascal
  • Patent number: 6372317
    Abstract: A barrier laminate useful for the formation of orange juice and citrus beverage cartons is provided. The laminate provides a skin coat of a MDPE which provides a barrier to water vapor transmission through the laminate. The reduced water vapor flow decreases the bulge rate of the resulting carton.
    Type: Grant
    Filed: November 30, 1999
    Date of Patent: April 16, 2002
    Assignee: Blue Ridge Paper Products Inc.
    Inventors: Alan W. Denney, Linnea Brady Keen
  • Patent number: 6372318
    Abstract: A method of making a polyester container having an enhanced level of crystallinity in the sidewall while maintaining a low level of crystallinity in a thickened base portion. The container is particularly useful as a refillable container which can withstand higher caustic wash temperatures and exhibits reduced flavor carryover, or as a hot-fill container. According to the method, a sidewall-forming section of a preform is initially expanded, heated to contract and crystallize the same, and than reexpanded; a base-forming portion of the preform is shielded from the heat treatment and is expanded either before or after the heat treatment step.
    Type: Grant
    Filed: October 30, 1998
    Date of Patent: April 16, 2002
    Assignee: Continental Pet Technologies, Inc.
    Inventors: Wayne N. Collette, Suppayan M. Krishnakumar, Chi Ching Lin
  • Patent number: 6368686
    Abstract: A laminated material for the manufacture of packing containers with good gas and aroma barrier properties, and a method for the manufacture of the laminated material. The laminated material has a base layer (18) and a barrier layer (19) of inorganic material of a thickness of only 50-500 Å serving as a gas and aroma barrier. The barrier layer (19) is applied to the base layer (18) by means of vacuum deposition and bonded to the base layer by means of at least one intermediate layer (22) of bonding agent. To facilitate the conversion of the material to packing containers the barrier layer (19) is omitted along such areas (17a and 17b) of the material which are intended to be folded against, and combined with, one another by heat-sealing during the manufacture of the said containers.
    Type: Grant
    Filed: February 22, 1994
    Date of Patent: April 9, 2002
    Assignee: Tetra Laval Holdings & Finance S.A.
    Inventors: Lars Löfgren, Peter Frisk
  • Patent number: 6365250
    Abstract: A composition having improved fuel vapor barrier properties comprising a blend of about 20 to 80 weight percent of a first fluorointerpolymer with about 80 to 20 weight percent of a second fluorointerpolymer, the first fluorointerpolymer comprising a copolymer, terpolymer or mixture thereof formed by the copolymerization of two or more monomers selected from the group consisting of hexafluoropropylene, vinylidene fluoride and tetrafluoroethylene, and the second fluorointerpolymer comprising a copolymer, terpolymer or mixture thereof formed by the copolymerization of two or more monomers selected from the group consisting of hexafluoropropylene, vinylidene fluoride and tetrafluoroethylene, wherein the first fluorointerpolymer exhibits elastomer characteristics and the second fluorointerpolymer exhibits thermoplastic characteristics.
    Type: Grant
    Filed: January 4, 2001
    Date of Patent: April 2, 2002
    Assignee: Dayco Products, Inc.
    Inventors: Jerry Shifman, Daniel G. Shell
  • Patent number: 6365248
    Abstract: A laminated barrier film which is harmless to the environment and combines the property of being easily tearable with moderate barrier properties. The laminated film comprises: an easily tearable barrier film (19) which is made up of a first layer (23) to a third layer (25), has undergone stretching in a stretch ratio of 2.8 or higher in each of the machine and transverse directions, and has undergone thermal fixing by heat treatment at 120 to 195° C. so that it has a shrinkage of 15 to 40% through 20-minutes immersion in pressurized 120° C. water; and a sealant film (21) laminated to the film (19). The first layer (23) and the third layer (25) each contains 60 to 85 parts by weight of Ny6, 15 to 40 parts by weight of MXD6, and 0.1 to 10 parts by weight of a modifier, while the second layer (24) contains 0 to 40 parts by weight of a thermoplastic resin such as Ny6, 60 to 95 parts by weight of MXD6, and 0.1 to 10 parts by weight of a modifier.
    Type: Grant
    Filed: March 14, 2000
    Date of Patent: April 2, 2002
    Assignee: Idemitsu Petrochemical Co., Ltd.
    Inventors: Takeo Hayashi, Masao Takashige
  • Patent number: 6361299
    Abstract: A spoolable composite member having a sensor and an energy conductor embedded in the composite member. The spoolable composite member is capable of being spooled onto a reel for storage and for use in oil field applications. The spoolable tube exhibits unique anistropic characteristics that provide improved burst and collapse pressures, increased tensile strength, compression strength, and load carrying capacity, while still remaining sufficiently bendable to be spooled onto a reel in an open bore configuration. The spoolable composite tube can include an inner protective layer, an inner pressure barrier layer, an interface layer, fiber composite layers, an outer pressure barrier layer, and an outer protective layer.
    Type: Grant
    Filed: November 2, 1999
    Date of Patent: March 26, 2002
    Assignee: Fiberspar Corporation
    Inventors: Peter A. Quigley, Stephen C. Nolet
  • Patent number: 6361843
    Abstract: The present invention provides a multiple layer structure (10) for fabricating medical products. The layer structure (10) has a core layer (14) of an ethylene vinyl alcohol copolymer having an ethylene content of about 25-45 mole percent, a solution contact layer of a polyolefin positioned on a first side of the core layer, an outer layer (12) positioned on a second side of the core layer opposite the solution contact layer (16), the outer layer (12) being selected from the group consisting of polyamides, polyesters and polyolefins; two tie layers (18)—one of each adhered to the first and second sides of the core layer (14) and positioned between the solution contact layer (16) and the core layer (14) and between the outer layer (12) and the core layer (14), and wherein the structure (10) is produced in a cast coextrusion process.
    Type: Grant
    Filed: June 29, 2000
    Date of Patent: March 26, 2002
    Assignee: Baxter International Inc.
    Inventors: Sidney T. Smith, Larry A. Rosenbaum, Steven Giovanetto, Bradley Buchanan, Y. Samuel Ding, Suchuan C. Fan, Gregg Nebgen
  • Patent number: 6358576
    Abstract: The specification discloses a layered composite containing a barrier layer comprising clay homogeneously dispersed in a continuous phase of polymeric material. The barrier layer is especially useful in the manufacture of liquid food containers. The clay/polymer barrier layer is formed by dispersing the clay in molten polymeric material to form a homogeneously dispersed clay in a continuous polymer phase. The barrier layer is then applied adjacent one surface of a paperboard component of the composite at a thickness ranging from about 1 to 30 microns. The paperboard may be coated or uncoated at the time the barrier layer is applied, and additional polymeric barrier layers and tie or adhesive layers may be used in combination with the barrier layer to provide reduced oxygen and water vapor transport through the composite.
    Type: Grant
    Filed: February 12, 1998
    Date of Patent: March 19, 2002
    Assignee: International Paper Company
    Inventors: Ashok M. Adur, Raymond A. Volpe, Keith S. Shih
  • Publication number: 20020028309
    Abstract: A tubular, multilayer film comprises a central barrier layer and a pair of adhesive layers on opposite sides of the central barrier layer. The adhesive layers completely cover the central barrier layer. Opposing edges of the central barrier layer overlap longitudinally along the tubular, multilayer film. The total thickness of the central barrier layers in the overlapping portion is substantially the same as the thickness of the central barrier layer in the non-overlapping portion. The tubular, multilayer film also includes inner and outer surface layers. The inner surface layer extends completely around the interior of the tubular, multilayer film, and the outer surface layer extends completely around the exterior of the tubular, multilayer film.
    Type: Application
    Filed: July 3, 2001
    Publication date: March 7, 2002
    Inventors: Joseph Dooley, Steven R. Jenkins, John A. Naumovitz
  • Publication number: 20020022144
    Abstract: Herein is disclosed a modified ethylene vinyl alcohol polymer (EVOH) comprising an oxygen scavenging functional group.
    Type: Application
    Filed: May 8, 2001
    Publication date: February 21, 2002
    Inventors: Hu Yang, Ta Yen Ching, Gangfeng Cai
  • Patent number: 6344249
    Abstract: A multi-layered article having a first portion constituted of laminated three resin layers and a second portion extending from the first portion, the first portion being constituted mainly of consecutively laminated resin layers composed of a first resin layer formed of a first resin, a second resin layer formed mainly of a second resin and a third resin layer formed of the first resin, the second portion being constituted of resin layers extending from the first resin layer and the third resin layer which constitute the first portion, the first resin layer constituting the outer surface layer of the multi-layered article, the third resin layer constituting the inner surface layer of the multi-layered article which inner surface layer is opposed to said outer surface layer, the second resin layer being encapsulated with the first resin layer and the third resin layer, the second resin layer having a thickness which decreases towards the second portion, and being discontinued, in a region of the first portion
    Type: Grant
    Filed: March 23, 1999
    Date of Patent: February 5, 2002
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Katsuya Maruyama, Takeshi Hara, Yoshihiro Terada, Takao Ota
  • Patent number: 6342282
    Abstract: The invention provides a heat-shrinkable multi-layer film comprising at least a thermoplastic resin layer as the outermost layer (A), a gas barrier resin layer as a core layer (B) and a sealing resin layer as the innermost layer (C), and optionally an adhesive layer between the individual layers, wherein (1) the sealing resin layer of the innermost layer (C) is a layer formed of a resin material (b) comprising a linear ethylene-1-octene copolymer (a) obtained by using a constrained geometry catalyst and having an 1-octene content not lower than 1 wt. % but lower than 20 wt. % and a density higher than 0.885 g/cm3 but not higher than 0.960 g/cm3, and (2) an intermediate layer (D1) formed of at least one resin (c) selected from the group consisting of polyamide resins, thermoplastic polyester resins and ethylene copolymer resins is provided between the outermost layer (A) and the core layer (B). The film has excellent sealing properties, clarity, mechanical strength, stretchability and bag-making property.
    Type: Grant
    Filed: May 11, 2000
    Date of Patent: January 29, 2002
    Assignee: Kureha Kagaku Kogyo K.K.
    Inventors: Junji Yoshii, Hajime Tsukamoto, Yoshihiro Matsukura, Hisanori Tobita
  • Publication number: 20020009565
    Abstract: A plastic container having a thin outer layer that protects against stress concentration effects arising from either surface irregularities or flexing when dropped and a method of making that container. The outer layer helps avoid bottle failure resulting from cracks that start at such areas of stress. The outer layer may incorporate both the stress inducing irregularities and the properties to minimize possible, resulting catastrophes. The surface irregularities giving birth to stress include edges of in-mold-applied labels, ridges, stippling, and grip bumps. Dropping the container gives rise to flexing which can also induce stress concentrations. The outer layer, to accomplish the protective function, should display lesser brittleness or, in some cases, lesser density than the bulk of the container wall. Making the container involves forming the bulk of the wall with a first, inner, structural plastic.
    Type: Application
    Filed: May 15, 2001
    Publication date: January 24, 2002
    Inventor: Gregory M. Fehn
  • Publication number: 20020004112
    Abstract: The present invention relates to multilayered composite films comprising a film or film combination A of plastics layers or metal layers in any arrangement, having an at least 10 &mgr;m thick, biaxially oriented heat-sealable layer C predominantly comprising polyethylene homopolymers or polyethylene copolymers, which is bonded by means of an adhesive layer or connecting layer B to the film or film combination A.
    Type: Application
    Filed: July 13, 2001
    Publication date: January 10, 2002
    Inventors: Harry Muller, Heiko Tamke
  • Patent number: 6337113
    Abstract: The invention concerns packaging container produced from a composite shaped by cold-forming, the term “packaging containers” including base of lid parts or base and lid parts shaped by cold-forming. The base or lid parts can be shaped by cold-forming, and a lid film or base film, respectively, can form the corresponding closure for the packaging container. In addition, both the base and the lid part can be shaped by cold-forming, the depressions formed in the base and lid parts advantageously lying opposite one another.
    Type: Grant
    Filed: May 20, 1998
    Date of Patent: January 8, 2002
    Assignee: Alusuisse Technology & Management AG
    Inventors: Olivier Yves A. Muggli, Erwin Pasbrig
  • Patent number: 6333087
    Abstract: Oxygen scavenging materials incorporated into or attached to a package such as a gable-top or rectangular carton, used to package foods, beverages or other oxygen sensitive materials, and thereby increase shelf-life by decreasing oxygen in the headspace of the package, and decreasing oxidation of the packaged product.
    Type: Grant
    Filed: August 27, 1998
    Date of Patent: December 25, 2001
    Assignee: Chevron Chemical Company LLC
    Inventors: Gary D. Jerdee, James P. Leonard, Ta Yen Ching, Joseph L. Goodrich, Brad D. Rodgers, Richard P. Schmidt
  • Patent number: 6333061
    Abstract: A sealed article comprising a multilayer film having at least 4 layers. The first layer is an inside layer comprising ethylene/alpha-olefin copolymer and/or polystyrene. The second layer comprises ethylene/unsaturated ester copolymer, anhydride-modified ethylene/alpha-olefin copolymer, anhydride-modified ethylene/ester copolymer, acid-modified ethylene/alpha-olefin copolymer, and/or acid-modified ethylene/acid copolymer. The third layer comprises ethylene/alpha-olefin copolymer and/or polystyrene. The fourth layer comprises ethylene homopolymer, ethylene/alpha-olefin copolymer, ethylene/vinyl alcohol copolymer, polyvinylidene chloride, polyamide, polyester, polyalkylene carbonate, polyacrylonitrile, and/or ethylene/unsaturated ester copolymer. At least 85 volume percent of the film is made up of polyolefin homopolymer, polyolefin copolymer, ethylene/ester copolymer, polystyrene, styrene/butadiene copolymer, EVOH, PVDC, and polyacrylonitirile.
    Type: Grant
    Filed: November 14, 1997
    Date of Patent: December 25, 2001
    Assignee: Cryovac, Inc.
    Inventor: Parimal M. Vadhar
  • Patent number: 6316067
    Abstract: A packaged article, especially a respiring foodstuff such as cheese which generates or releases gas during storage, and a permeable multilayer biaxially oriented film suitable for allowing escape of such gas while minimizing transfer of oxygen across the film which has a thin layer of a blend of EVOH and nylon. In a preferred embodiment the low cost film having a high permeability to CO2 and low O2 permeability is used to package cheese.
    Type: Grant
    Filed: February 3, 1994
    Date of Patent: November 13, 2001
    Assignee: Curwood, Inc.
    Inventors: David Nicholas Edwards, Stephen James Vicik
  • Patent number: 6309723
    Abstract: A protein-compatible polymer blend made from a water-soluble polymer and a matrix polymer. The glass transition temperature of either the water-soluble polymer or the matrix polymer is greater than the application temperature, i.e., the temperature at which the protein-compatible polymer blend is being used.
    Type: Grant
    Filed: August 21, 1996
    Date of Patent: October 30, 2001
    Assignee: Baxter International Inc.
    Inventors: Samuel Ding, Chuan Qin, Barrett Rabinow
  • Patent number: 6306472
    Abstract: Multilayer films and packaging structures having a delamination seal and an oxygen barrier layer are disclosed. The delamination structure adjacent to the EVOH oxygen barrier layer binds well to the EVOH layer and also retains its ability to delaminate. The multilayer films, and packages in which they are utilized, have several layers including a first, external layer; a second, tie layer comprising a mixture of polybutylene and an anhydride modified polyethylene such that a peelable bond is formed between said first, external layer and said second, tie layer; a third, core layer comprising ethylene vinyl alcohol which functions as an oxygen barrier layer; a fourth, tie layer comprising an anhydride modified polyethylene and a fifth, external layer.
    Type: Grant
    Filed: April 22, 1998
    Date of Patent: October 23, 2001
    Assignee: Pechiney Emballage Flexible Europe
    Inventor: Duane H. Buelow
  • Patent number: 6303199
    Abstract: A water-soluble polyvinyl alcohol coating agent for a film contains from 3 to 19 mol % of &agr;-olefin units, wherein each said &agr;-olefin unit contains up to 4 carbon atoms. The polyvinyl alcohol coating agent can be coated on a polyolefin, a polyester or a polyamide substrate film to form a laminate film. A method for producing the laminate film comprises applying an aqueous solution of the coating agent to the substrate film, followed by drying the coating.
    Type: Grant
    Filed: June 3, 1999
    Date of Patent: October 16, 2001
    Assignee: Kuraray Co., Ltd.
    Inventors: Shigeki Takada, Sadahiko Shiraga
  • Patent number: 6294235
    Abstract: A blow moulded automobile fuel tank having a wall defining a fuel chamber wherein the minimum wall thickness of the wall is from 2.4 mm to less than 3 mm, the tank being composed of a high density polyethylene having a density of from 0.945 to 0.955 g/cm3, a high load melt index of from 5 to 9.5 g/10 min, the high density polyethylene optionally having a carbon black content of up to 0.5 wt %, and the fuel tank having a fire resistance and an impact resistance both complying with the respective standards defined in ECE 34, ANNEX 5.
    Type: Grant
    Filed: June 19, 2000
    Date of Patent: September 25, 2001
    Assignee: Fina Research, S.A.
    Inventors: Patrick Detoumay, Claude Delahaut
  • Patent number: 6291041
    Abstract: A multi-layer heat resistant film laminate with good optical properties, extended shelflife, and memory characteristics and its method of manufacture, the laminate having the generalized structure of (outside) A/B/C/D/C/B/E (inside), where A is an outer moisture barrier layer, B is an intermediate adhesive layer, C is a polyamide layer D is an oxygen barrier layer, and E is a sealant layer.
    Type: Grant
    Filed: May 10, 1999
    Date of Patent: September 18, 2001
    Assignee: Curwood, Inc.
    Inventors: Scott Howells, Gregory Robert Pockat
  • Patent number: 6287652
    Abstract: A sampler package for fluid cosmetics, creams, gels, and the like having a liquid solvent base includes a transparent composite laminate sealed with a composite laminate having a foil barrier layer. The sealed composite laminates form a pouch in which the cosmetic sample is contained. The transparent composite laminate is preferably adhesively laminated with either a biaxially oriented PVDC film or a polychlorotrifluoroethylene film as the moisture vapor barrier layer. The moisture permeability rate of the barrier film is at most 0.065 g/100 in2/24 hrs @100° F.,90% RH. Use of such transparent films as the barrier laminate permits the sampler package to be formed with a transparent window through which the color, texture, etc. of the sampler product may be viewed.
    Type: Grant
    Filed: December 9, 1998
    Date of Patent: September 11, 2001
    Assignee: Color Prelude, Inc.
    Inventors: Kenneth H. Speckhals, Anthony J. Gunderman
  • Patent number: 6287653
    Abstract: A package for oxygen sensitive goods is made using a barrier material, an oxygen scavenging system, and a polymeric base which is reactive with the by-products of oxygen scavenging. Such packages demonstrate improved product quality.
    Type: Grant
    Filed: March 5, 1999
    Date of Patent: September 11, 2001
    Assignee: Cryovac, Inc.
    Inventors: Drew Ve Speer, Charles Robert Morgan, Thomas Andrew Blinka, Ronald Lee Cotterman
  • Patent number: 6280679
    Abstract: The multilayer plastic container comprises a neck portion, a body portion, adjacent the neck portion, forming a cylindrical wall, and a bottom portion adjacent the body portion and opposite the neck portion. The cylindrical wall comprises a first layer of PET, a layer of EVOH adjacent the first layer of PET and a second layer of PET adjacent the layer of EVOH the EVOH has an average thickness which is greater near the neck portion of the container than near the bottom portion of the container.
    Type: Grant
    Filed: November 18, 1998
    Date of Patent: August 28, 2001
    Assignee: Pechiney Emballage Flexible Europe
    Inventors: A. B. M. Bazlur Rashid, Kevin James Curie, Patrick Carl Bushman, Michael Lewis Wampler
  • Publication number: 20010012550
    Abstract: A container incorporating post-consumer recycled (“PCR”) plastic and a method of making that type of container. The container utilizes a layer of polypropylene or EVOH or a film of fluorinated polyethylene toward the interior from the recycled plastic to prevent contaminants from the latter entering the container's contents. When utilizing EVOH, the container usually has an additional layer of polyethylene or polypropylene covering the EVOH to prevent its deterioration by moisture. Making the container involves first composing a resin including the recycled plastic. Forming the various layers listed above produces a container that includes recycled plastic and a barrier to limit the migration of contaminants from the recycled material to the container's contents. This permits the use of the resulting containers for food. For a fluorinated polyethylene film, fluorination can occur either during or after the container's formation.
    Type: Application
    Filed: January 24, 2001
    Publication date: August 9, 2001
    Inventor: Gregory M. Fehn
  • Patent number: 6270869
    Abstract: Cold-formable laminate film, for example, for manufacturing push-through or blister packs or the base parts and for forms of packaging or shaped parts for packaging medical instruments and applicators, containing a barrier layer that is impermeable to water vapor and gases and a plastic layer on both sides of the barrier layer. The laminate film exhibits a layered structure containing in the following order: (a) a plastic layer in the form of a film of the following type, namely, polychloride, polyester, polypropylene, cycloolefin-copolymer or a cast film of polyvinyl-chloride or polypropylene; (b) a metal foil such as an aluminium foil; and (c) an oriented polyamide film having a thickness of 25 to 2 &mgr;m. The free sides of the first and/or the second plastic film may feature a sealing layer or the first and/or the second plastic films may be sealable. The laminate films may, for example, be processed into forms of packaging by a deepening process such as stretch drawing, i.e.
    Type: Grant
    Filed: November 24, 1999
    Date of Patent: August 7, 2001
    Assignee: Alusuisse Technology & Management Ltd.
    Inventors: Patrik Zeiter, Erwin Pasbrig, Hans Peter Breitler
  • Patent number: 6265037
    Abstract: An improved composite structural member comprising a complex profile structural member, made of a composite comprising a polypropylene polymer and a wood fiber. The material is useful in conventional construction applications. The complex profile, in the form of an extruded thermoplastic composite member can be used in residential and commercial structures as described. Preferably, the structural member is used in the manufacture of the fenestration components such as windows and doors. Such linear members are designed with specifically configured cross-sectional shapes to form structural elements in the fenestration units. Structural elements must possess sufficient strength, thermal stability and weatherability to permit the manufacture of a structurally sound window unit that can be easily installed into a rough opening but can maintain its attractive appearance and structural integrity over the life of the window unit often twenty years or more.
    Type: Grant
    Filed: April 16, 1999
    Date of Patent: July 24, 2001
    Assignee: Andersen Corporation
    Inventors: Shankar Godavarti, Rodney K. Williams, Michael J. Deaner
  • Publication number: 20010008686
    Abstract: A multilayer sealant film for use in the medical field at least comprises as its innermost layer a first layer comprising at least one resin selected from the group consisting of linear low-density polyethylene, low-density polyethylene, polypropylene and polybutene-1, and a third layer comprising an ethylene-vinyl alcohol copolymer and laminated to the outer side of the first layer with a second layer serving as an adhesive layer and comprising a resin containing, as a main component, at least one of an amorphous polyolefin, adherent polyolefin and ethylene-vinyl acetate copolymer. The ethylene-vinyl alcohol copolymer forming the third layer functions as a barrier for preventing contaminants from migrating from outside of the third layer toward the first layer (innermost layer). Further, it is possible to improve the formability of the multilayer film since the difference in density between the resin for forming the first layer and the resin for forming the second layer is set to be 0.02 g/cm3 or less.
    Type: Application
    Filed: February 6, 1997
    Publication date: July 19, 2001
    Inventors: FUJIO INOUE, MASAMITSU IZUMI, SHIGETOSHI KASHIYAMA
  • Patent number: 6261655
    Abstract: A multiple layer structure comprising a skin layer composed of a polypropylene copolymer with styrene ethylene-butene styrene block copolymer within a range of 0-20% by weight skin layer, and, a radio frequency (“RF”) susceptible layer adhered to the skin layer. The RF layer has a first component of a propylene based polymer, a second component of a nonpropylene polyolefin, a third component of a radio frequency susceptible polymer, and a fourth component of a polymeric compatibilizing agent wherein the radio frequency susceptible polymer is selected from the group consisting of ethylene acrylic acid copolymers, ethylene methacrylic acid copolymers, polyimides, polyurethanes, polyesters, and polyureas.
    Type: Grant
    Filed: June 17, 1999
    Date of Patent: July 17, 2001
    Assignee: Baxter International Inc.
    Inventors: Larry A. Rosenbaum, William Anderson, Lecon Woo, Dean Laurin, Angeles Lillian Buan, Michael T. K. Ling, Yuan Pang Samuel Ding, Denise S. Hayward, Joseph P. Hoppesch, Gregg Nebgen, Stanley Westphal
  • Patent number: 6258423
    Abstract: A multilayer heat-sealable chlorine-free film of relatively low modulus, high interlaminar strength, and low noise upon flexing is provided. The film comprises an odor barrier layer of polyester resin and at least one heat-sealable skin layer, preferably two such skin layers on opposite sides of said odor barrier layer, composed of a homopolymer of ethylene or a copolymer of ethylene and an alpha-olefin or an ester-containing monomer. In a preferred embodiment, the odor barrier layer is formed of polyethylene terephthalate and adhesive tie layers are interposed between the odor barrier layer and the skin layers, resulting in a multilayer film of five layers. Pouches formed of such multilayer films are also disclosed.
    Type: Grant
    Filed: August 23, 1999
    Date of Patent: July 10, 2001
    Assignee: Hollister Incorporated
    Inventor: Claudio Giori
  • Patent number: 6245437
    Abstract: A composite gas barrier film having a layer structure comprises a thermoplastic resin film laminated on at least one side of a film formed from polyglycolic acid containing at least 60 wt. % of a repeating unit represented by the following formula (1): wherein the polyglycolic acid film is a film formed from polyglycolic acid having a melt viscosity, &eegr;* of 500 to 100,000 Pa•s as measured at a temperature of the melting point of the polymer +20° C. and a shear rate of 100/sec, a melting point Tm of at least 150° C., and a melt enthalpy, &Dgr;Hm of at least 20 J/g. An adhesive layer is provided between the polyglycolic acid film and the thermoplastic resin film. The film has excellent oxygen gas barrier property and/or carbon dioxide gas barrier property.
    Type: Grant
    Filed: January 19, 1999
    Date of Patent: June 12, 2001
    Assignee: Kureha Kagaku Kogyo K.K.
    Inventors: Zenya Shiiki, Yukichika Kawakami, Nobuo Sato, Mitsuru Hoshino, Toshitaka Kouyama
  • Patent number: 6239046
    Abstract: The invention is directed to coating a knit, woven, or non-woven textile substrate with adhesive polyurethane layer and then with an elastomeric polysiloxane layer and to then form an air curtain or air bag therefrom with superior air-holding and superior heat resistance.
    Type: Grant
    Filed: June 7, 1999
    Date of Patent: May 29, 2001
    Assignee: Bradford Industries, Inc.
    Inventors: Manuel J. Veiga, Richard J. Satin
  • Patent number: 6224956
    Abstract: A polymeric film is provided which comprises a core layer of polyamide and two outer layers of ethylene propylene copolymer, polypropylene, and blends thereof. Coextruded embodiments include intermediate adhesive layers. A preferred embodiment of the multilayer film exhibits a combination of good abuse resistance and oxygen barrier properties, as well as excellent optical properties and shrink properties. The differential in CO2 transmission and O2 transmission rates makes these films especially useful in cheese packaging applications.
    Type: Grant
    Filed: November 16, 1993
    Date of Patent: May 1, 2001
    Assignee: Cryovac, Inc.
    Inventor: Gautam P. Shah
  • Patent number: 6221410
    Abstract: A heat-shrinkable backseamed casing film comprises a first layer, a second layer, and a third layer, with the first and third layers being outer layers and the second layer being between the first layer and the third layer. The first outer layer serves as an inside casing layer, and comprises polyolefin; the second layer comprises polyester and/or polyamide; the third layer serves as an outside casing layer and comprises polyolefin, polystyrene, and/or polyamide. The second layer has a thickness of at least about 5% of a total thickness of the heat-shrinkable casing film. Alternatively, the first layer comprises polyolefin and has a surface energy level of less than about 34 dynes/cm; the second layer comprises a polyamide having a melting point of at least 300° F.; and the third layer comprises polyolefin, polystyrene and/or polyamide. A package comprises a cooked meat product within the backseamed casing.
    Type: Grant
    Filed: November 12, 1997
    Date of Patent: April 24, 2001
    Assignee: Cryovac, Inc.
    Inventors: Ram K. Ramesh, Michael J. Rosinski
  • Patent number: 6218024
    Abstract: A multilayer plastic film has a series of component layers and bonding layers bonding said component layers together, the component layers including an inner hydrolysed ethylene vinyl acetate copolymer (EVOH) layer, an adjacent polyvinylidene chloride (PVDC) layer, and outer layers comprising a polyolefin homopolymer, copolymer or ionomer.
    Type: Grant
    Filed: June 4, 1999
    Date of Patent: April 17, 2001
    Assignee: Macro Engineering & Technology Inc.
    Inventors: Harinder Tamber, Mirek Planeta
  • Patent number: RE37699
    Abstract: Film and sheet materials, and articles made therefrom, such as bags, pouches, trays, etc., comprise one or more layers of a thermoplastic, homogeneous alpha-olefin/vinyl aromatic copolymer, preferably an ethylene/styrene copolymer. The alpha-olefin/vinyl aromatic copolymer has properties which can can provide a desired performance characteristics such as impact resistance, printability, RF sealability, free shrink, optics, as well as many others. The homogeneous alpha-olefin-vinyl aromatic copolymer may be present in a mono-layer film, either alone or in a blend, or may be included in one or more layers of a multilayer film. Also included is a multilayer thermoformable article comprising a web having a film of such alpha-olefin/vinyl aromatic copolymers thereto. Finally, also included is an RF-sealable film comprising such copolymers.
    Type: Grant
    Filed: July 19, 1999
    Date of Patent: May 14, 2002
    Assignee: Cryovac, Inc.
    Inventors: John G. Bradfute, Blaine Clemons Childress, Marvin Havens, Cedric Michael Lulham, Ronald D. Moffitt, Martindale Nelson, Lawrence R. Norpoth, William Peyton Roberts, Gloria Garcia Toney, George Dean Wofford