Next To Metal Patents (Class 428/418)
  • Patent number: 6500564
    Abstract: An epoxy resin composition comprising (A) a polyfunctional epoxy resin, (B) a phenolic resin, (C) an inorganic filler, and (D) curing catalyst-containing microcapsules having a mean particle size of 0.5-50 &mgr;m is suited for semiconductor package encapsulation since it minimizes the warpage of packages and has satisfactory catalyst latency, storage stability and cure.
    Type: Grant
    Filed: August 18, 2000
    Date of Patent: December 31, 2002
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Toshio Shiobara, Kazuhiro Arai, Hidenori Mizushima, Shigeki Ino, Yasuo Kimura, Takayuki Aoki
  • Patent number: 6500545
    Abstract: The present invention provides a crosslinking agent having reactive benzoxazine groups which is the ungelled reaction product of (a) at least one mono-hydroxy aromatic compound and (b) at least one aminotriazine compound having one or less non-alkylated NH group present in a molar ratio of reactant (a) to reactant (b) ranging from 1.0 to 3.0: 1.0, provided that where reactant (a) is a single ring monohydroxy aromatic compound, the molar ratio of reactant (a) to reactant (b) ranges from 1.0 to 1.8:1.0 and from 2.2 to 3.0:1.0. The crosslinking agent is essentially free of hydroxyl functionality and has a glass transition temperature of at least 25° C. The present invention is further directed to a method for preparing the above-described crosslinking agent.
    Type: Grant
    Filed: September 21, 2000
    Date of Patent: December 31, 2002
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Ronald R. Ambrose, Anthony M. Chasser, Shengkui Hu, John R. Schneider, Jackie L. Smith
  • Patent number: 6500546
    Abstract: Curable flame-resistant substantially halogen free epoxy resin compositions, comprising: (a) one or more bifunctional or polyfunctional epoxy resin; (b) a specific phosphorous-containing compound; (c) a curing agent consisting of oligomers of styrene and maleic acid and/or maleic anhydride and/or salts or esters of maleic acid; (d) a curing catalyst; and optionally; (e) additives; prepregs derived from said compositions and laminates derived from said prepregs.
    Type: Grant
    Filed: November 1, 2000
    Date of Patent: December 31, 2002
    Assignee: Resolution Performance Products LLC
    Inventors: Francoise Marie Louise Heine, Jean Andre Alfred Riviere, Philippe Eric Stevens, Helga Leontina Andrea De Velder
  • Publication number: 20020192460
    Abstract: A laminate is made by adhering at least one metal layer selected from the group consisting of copper and a copper alloy to a resin layer. A coating film of an azole-copper complex compound formed by a contact with an aqueous solution containing an azole compound in an range from 0.1 mass % to 15 mass % and an organic acid in a range from 1 mass % to 80 mass % is formed on the metal layer surface, and the metal layer adheres to the resin layer via the coating film of the azole-copper complex compound. Thereby, the present invention provides a laminate with improved adhesion between a surface of copper or a copper alloy and resin in a multilayered printed circuit board, and also a method of manufacturing the laminate.
    Type: Application
    Filed: April 23, 2002
    Publication date: December 19, 2002
    Applicant: MEC COMPANY LTD.
    Inventors: Mutsuyuki Kawaguchi, Jun Hisada, Toshiko Nakagawa
  • Patent number: 6494983
    Abstract: The liner provided metallic shell having an outer-facing surface and an inner-facing surface, said inner-facing surface including a cured enamel coating thereon comprising a solids mixture of an epoxy resin, a phenolic resin, carboxypolyolefin resin and polyester resin; and a shaped thermoplastic elastomer member adhered to said enamel inner surface.
    Type: Grant
    Filed: November 19, 1998
    Date of Patent: December 17, 2002
    Assignee: White Cap, Inc.
    Inventors: F. William Graue, Joyce M. Scaletta
  • Patent number: 6492027
    Abstract: The present invention provides a cationic resin composition capable of forming a cationically electrodepositable coating film which is excellent in corrosion resistance, an aptitude for the cationic electrodepositable coating of a rust preventive steel plate and in adhesion to substrate, which cationic resin composition is characterized by comprising the following components: (A) an amino group-containing epoxy resin which is prepared by adding an amino group-containing compound to an epoxy resin having an epoxy equivalent of 400 to 3000, (B) a polyol-modified amino group-containing epoxy resin which is prepared by making an epoxy resin having an epoxy equivalent of 180 to 2500 react with an amino group-containing compound and with a polyol compound obtained by adding caprolactone to a compound having plural active hydrogen groups, and (C) a blocked polyisocyanate curing agent, component (A) being 40 to 70% by weight, component (B) being 4 to 40% by weight, and component (C) being 10 to 40% by weight, base
    Type: Grant
    Filed: May 31, 2001
    Date of Patent: December 10, 2002
    Assignee: Kansai Paint Co., Ltd.
    Inventors: Shigeo Nishiguchi, Koji Kamikado, Tadayoshi Hiraki, Akira Tominaga
  • Patent number: 6485834
    Abstract: A thermosetting composition with a glass transition temperature of at least 100° C. comprises at least one epoxy resin formed from at least one polyepoxide containing at least two epoxy groups in its molecule and at least one aromatic polyamine containing at least two primary amino groups in its molecule, at least one alkanoyl substituent containing 1 to 12 carbon atoms located in the position alpha to one of the amino groups. The molar ratio of the amine to the epoxide is such that each amine group corresponds to 1.6 to 2.6 epoxy groups. The composition also includes a flow controller. The composition can be used as a protective coating for any metallic or non metallic surface. The invention also concerns a flexible deployable preform comprising the composition.
    Type: Grant
    Filed: November 20, 2000
    Date of Patent: November 26, 2002
    Assignee: Institut Francais du Petrole
    Inventors: Paul Mariaggi, Henri Delhomme, Dominique Audigier, Frédérique Jacquemin-Hauviller
  • Publication number: 20020168528
    Abstract: An article is coated with a multi-layer coating having improved chemical and oxidation resistance. The coating comprises a polymeric layer on the article surface, a refractory metal or refractory metal alloy strike layer on the polymeric layer and a protective layer containing a refractory metal oxide or refractory metal alloy oxide.
    Type: Application
    Filed: May 11, 2001
    Publication date: November 14, 2002
    Inventors: Patrick B. Jonte, James S. Lipe, Guocun Chen
  • Publication number: 20020168504
    Abstract: A prepreg exhibiting excellent formability and producing laminated boards and multiple layer circuit boards exhibiting high thickness precision is disclosed. The prepreg comprises an inner layer made from a glass fiber substrate, having a weight of 40 g or more and less than 115 g per square meter and an air permeability or 20 cm3/cm2/sec or less, impregnated with an epoxy resin, and an outer layer of an epoxy resin coating provided on at least one side of the inner layer, wherein the epoxy resin reaction rate in the inner layer is 85% or more and the epoxy resin reaction rate in the outer layer is 60% or less.
    Type: Application
    Filed: October 29, 2001
    Publication date: November 14, 2002
    Applicant: SUMITOMO BAKELITE COMPANY LIMITED
    Inventors: Takashi Yamaji, Mamoru Komatsu
  • Patent number: 6479585
    Abstract: A powder coating composition for heat-sensitive substrates curable at a temperature of about 300° F. or below for about 30 minutes or less comprises a) from about 10-90% by weight, relative to a) plus b), of carboxylic acid functional acrylic resin(s); b) from about 10-90% by weight, relative to a) plus b), of polyepoxy resin(s); c) a first catalyst functioning as an epoxy homopolymerization catalyst; and d) a second catalyst functioning as an epoxy/carboxylic acid reaction catalyst.
    Type: Grant
    Filed: May 26, 2000
    Date of Patent: November 12, 2002
    Assignee: H. B. Fuller Licensing & Financing Inc.
    Inventors: Stephen C. Hart, Jeffrey G. Schmierer, Brian W. Carlson, Stephen C. Larson
  • Patent number: 6479152
    Abstract: Lubricative stainless steel sheet and pipe having a chromate film on at least one of the surfaces of a stainless steel sheet or pipe substrate, the chromate film having an amount of adhered Cr of 5 to 100 mg/m2, and, on the chromate film, a lubricant film obtained by applying, on the chromate film, a water-base coating containing (a) a urethane resin of ether-ester type having a skeleton of bisphenol type, a skeleton of ester, and a carboxyl group, (b) an epoxy resin, and (c) a polyolefin wax, and baking the applied coating, the sum of the amount of the urethane resin of (a) and the epoxy resin of (b) being 70 to 95% by weight of the total solids of the coating, the amount of the polyolefin wax of (c) being 5 to 30% by weight of the total solids of the coating, and the lubricant film having a thickness of 0.5 to 5 micrometers and a Vickers hardness of at least 15. A method of producing a lubricative stainless steel pipe is also disclosed.
    Type: Grant
    Filed: November 9, 2000
    Date of Patent: November 12, 2002
    Assignee: Nippon Steel Corporation
    Inventors: Yujiro Miyauchi, Itsuro Hiroshige, Isao Anai, Katsuhiko Kato, Toshio Tanoue
  • Patent number: 6473950
    Abstract: A manufacturing method for multi-layered electronic parts which is characterized in that from a roll of a polyethylene microporous sheet which has an electrode layer forming agent formed on its surface, contains 45 to 80 volume percent of inorganic filler, and has a thickness of 25 &mgr;m or less, tensile strengths of 3 kg/mm2 or more in the longitudinal direction and of 1 kg/mm2 or more in the transverse direction, and an elongation of 30% or less in the MD direction, layered electronic parts are formed via (a) a step of unwinding the sheet, (b) a step of cutting the sheet in a predetermined length, (c) a step of stacking the cut sheets, and (d) a step of cutting the layered structure and efficient production is made possible.
    Type: Grant
    Filed: December 21, 1998
    Date of Patent: November 5, 2002
    Assignee: Teijin Limited
    Inventor: Shiro Kumakawa
  • Publication number: 20020160180
    Abstract: Disclosed herein is a metal sheet with anticorrosive coating which exhibits outstanding corrosion resistance, pitting corrosion resistance, and red rust resistance. It has the anticorrosive coating on at least one side thereof. The anticorrosive coating is formed from an anticorrosive paint which contains a metallic zinc powder and at least one kind of metal salt rust inhibitor. The metal salt is a salt of a metal which is more base than zinc. The metal sheet may be a steel sheet. The metal salt rust inhibitor may be a phosphate or a phosphomolybdate.
    Type: Application
    Filed: March 1, 2002
    Publication date: October 31, 2002
    Applicant: Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd)
    Inventors: Takayuki Yamamoto, Hiroo Shige, Takeshi Watase, Masafumi Shimizu
  • Publication number: 20020160202
    Abstract: Binders for aqueous corrosion protection systems, comprising products A′ABC of reaction of epoxy resins, fatty acids, and amines, having a number average molar mass Mn of at least 5000 g/mol, obtained by reacting epoxide compounds A′ containing at least two epoxide groups per molecule and reaction products ABC of epoxide compounds A, fatty acids B, and amines C, wherein, where appropriate, the epoxide compounds A′ and/or the epoxide compounds A have been modified prior to further reaction, in whole or in part, by reaction with compounds D containing at least one acid group or hydroxyl group reactive toward epoxide groups, and wherein, where appropriate, the amines C have been modified prior to further reaction, in whole or in part, by reaction with aliphatic or aromatic monoepoxide compounds A″ or mixtures thereof
    Type: Application
    Filed: January 18, 2002
    Publication date: October 31, 2002
    Inventors: Willibald Paar, Manfred Krassnitzer, Maximilian Friedl, Roland Feola, Johann Gmoser
  • Patent number: 6472472
    Abstract: Powder coating compositions for metal substrates, a method of powder coating a metal substrate, and a metal article are disclosed. The powder coating composition is a thermoplastic material and comprises: (a) a first polyester having a weight average molecular weight of about 10,000 to about 80,000 and a Tg of greater than 45° C. to about 100° C., (b) a second polyester having a weight average molecular weight of about 10,000 to about 70,000 and a Tg of about −10° C. to about 45° C., and optionally, (c) a modifying resin, such as an epoxy resin having an epoxy equivalent weight of about 500 to about 15,000, wherein the Tg of the first and second polyesters differ by about 5° C. to about 60° C. The powder coating composition is applied to a metal substrate to provide a composition film having a thickness of about 1 to about 200 microns.
    Type: Grant
    Filed: June 13, 2001
    Date of Patent: October 29, 2002
    Assignee: The Valspar Corporation
    Inventors: Rolf Jung, Christian Schmid
  • Patent number: 6472070
    Abstract: The present invention is a fire-resistant paint containing an epoxy resin, a hardener, and an inorganic filler wherein {circle around (1)} for the total of 100 weight parts of the epoxy resin and the hardener, {circle around (2)} 200-500 weight parts of the inorganic filler, chosen from a group consisting of neutralized thermally expandable graphite, metal carbonate, and a hydrated inorganic compound is contained; {circle around (3)} for the inorganic filler, at least 15-400 weight parts of neutralized thermally expandable graphite is contained; and {circle around (4)} the viscosity of the fire-resistant paint is 1-1,000 ps as measured by a B-type viscometer. The fire-resistant paint of the present invention has particularly remarkable fire resistance, and can be used in a wide range of applications.
    Type: Grant
    Filed: July 7, 2000
    Date of Patent: October 29, 2002
    Assignee: Sekisui Chemical Co., Ltd.
    Inventors: Hitomi Muraoka, Masaki Tono, Kazuhiro Okada
  • Patent number: 6468613
    Abstract: Light metal/CFRP-made structural members which are characterized in that they are structural materials in which a CFRP material is stuck to the surface of a light metal material via an adhesive agent layer of thickness at least 10 &mgr;m and up to 500 &mgr;m, and the volume resistivity of the adhesive agent layer between said metal material and said CFRP material is at least 1×1013 &OHgr;.cm and, furthermore, the adhesive strength at room temperature is at least 15 MPa. In accordance with the present invention, since conventional light metal/CFRP structural materials can be made lighter and, furthermore, since the resistance to galvanic corrosion is outstanding and it is possible to markedly enhance the strength and the impact energy absorption performance, the development of applications and large-scale expansion into new fields becomes possible. Weight reduction and enhancing the durability and reliability of structures also makes a considerable contribution in terms of environmental protection.
    Type: Grant
    Filed: April 20, 1999
    Date of Patent: October 22, 2002
    Assignee: Toray Industries, Inc.
    Inventors: Akihiko Kitano, Kenichi Yoshioka, Kenichi Noguchi, Hitoshi Nishiyama
  • Publication number: 20020150762
    Abstract: The invention describes the use of compositions containing at least one thermoplastic polymer and an epoxy resin modified by at least one aromatic polyamine to coat surfaces, especially pipes through which oil is transported. The polymer compositions used contain at least one thermoplastic polymer which is preferably amorphous selected from the group formed by polysulphones, polyetherimides and polyphenylene esters and at least one epoxy resin modified by at least one aromatic polyamine containing at least two primary amine groups in its molecule. Different layers of polymers are deposited on different types of surface, more particularly as internal and external coatings for conduits. The invention also provides a surface coating comprising such compositions. Multi-layer coatings are also produced.
    Type: Application
    Filed: February 25, 2002
    Publication date: October 17, 2002
    Inventors: Yves Camberlin, Jacky Grenier, Stephane Poncet, Anthony Bonnet, Jean-Pierre Pascault, Henri Sautereau
  • Patent number: 6458439
    Abstract: Solid extrusion coating compositions for metal substrates, a method of extrusion coating a metal substrate, and a metal article are disclosed. The extrusion coating composition is a thermoplastic material and comprises: (a) a first polyester having a weight average molecular weight of about 10,000 to about 80,000 and a Tg of greater than 45° C. to about 100° C., (b) a second polyester having a weight average molecular weight of about 10,000 to about 70,000 and a Tg of about −10° C. to about 45° C., and optionally, (c) a modifying resin, such as an epoxy resin having an epoxy equivalent weight of about 500 to about 15,000, wherein the Tg of the first and second polyesters differ by about 5 C.° to about 60 C.°. The extrusion coating composition is applied to a metal substrate in an extrusion process to provide a composition film having a thickness of about 1 to about 40 microns.
    Type: Grant
    Filed: March 16, 1999
    Date of Patent: October 1, 2002
    Assignee: The Valspar Corporation
    Inventors: Rolf Jung, Claude Chappuis
  • Publication number: 20020132079
    Abstract: A framing device, used for displaying items such as photographs, certificates and the like, includes a translucent sheet-like material having an outward side and an inward side, both having a common continuous edge. An adhesive is applied along the inward side adjacent to the continuous edge in such a manner that a portion of such edge remains adhesive-free. A sheet of backing material has a first side and a second side and the first side of such foam is positionally secured by the adhesive and with respect to the translucent material. And a release liner is attached to the second side of the backing material. The adhesive-free portion of the edge and the sheet of backing material define a slot permitting insertion and removal of an item to be displayed.
    Type: Application
    Filed: April 12, 2002
    Publication date: September 19, 2002
    Inventor: Carey P. Woods
  • Patent number: 6447915
    Abstract: In order to provide a multilayer printed circuit board having a fine pitch circuit, the interlaminar insulating adhesive used therein must have heat resistance and low thermal expansion coefficient so that required accuracy can be obtained during circuit formation and mounting of components. Therefore, the present invention aims at providing a multilayer printed circuit board which uses an interlaminar insulating adhesive superior in heat resistance and low in thermal expansion coefficient and wherein the insulating adhesive layer has a small variation in thickness between circuit layers.
    Type: Grant
    Filed: March 3, 2000
    Date of Patent: September 10, 2002
    Assignee: Sumitomo Bakelite Company Limited
    Inventors: Toshio Komiyatani, Masao Uesaka, Masataka Arai, Hitoshi Kawaguchi
  • Patent number: 6444272
    Abstract: The present invention relates to a single-packaged epoxy resin coating composition comprising: (A) an epoxy resin having at least one epoxy group in a molecule and capable of being dissolved in the following organic solvent (D), (B) a ketimines compound having at least two primary amino groups blocked with a carbonyl compound and having no other amino groups than the above blocked amino groups, (C) a dehydrating agent and (D) an organic solvent, wherein the above organic solvent (D) comprises a hydrocarbon base solvent selected from the group consisting of an aliphatic hydrocarbon base solvent and an aromatic hydrocarbon base solvent having a boiling point of 148° C. or higher in a proportion of at least 95% by weight based on the above organic solvent (D).
    Type: Grant
    Filed: May 26, 2000
    Date of Patent: September 3, 2002
    Assignee: Kansai Paint Co., Ltd.
    Inventors: Koji Matsuda, Yoshimitsu Adachi, Tadashi Nakano, Shinji Iida
  • Patent number: 6440567
    Abstract: Fire resistant adhesive resins that include a halogen-free and bromine-free flame retardant ingredient and conductive foils coated with the halogen-free fire resistant adhesive resin coated compositions of this invention as well as printed circuit boards manufactured using the adhesive resin coated conductive foils.
    Type: Grant
    Filed: November 17, 2000
    Date of Patent: August 27, 2002
    Assignee: Isola Laminate Systems Corp.
    Inventors: Martin T. Choate, Barbara Ormond, Michael Nehls, Georg Czerny
  • Patent number: 6426147
    Abstract: The invention relates to a substrate provided with a multilayer coating. The invention additionally relates to a process for its preparation, in which the body to be coated passes via the entry 1 into the pretreatment stage 2. This is followed by electrodeposition coating 3 and the baking 4 of the electrodeposition coat. In stage 5 preparation takes place for coating with powder coating material (stage 6). In stage 7 drying is carried out with IR irradiation. This is followed by the cooling stage 7. The powder coating material is applied to the powder coat in stage 9. Following passage through the intermediate drying stage 10 a protective coat is applied in stage 11 and then is baked in stage 12. The body is transported out of the unit via the exit 11.
    Type: Grant
    Filed: April 4, 2000
    Date of Patent: July 30, 2002
    Assignee: BASF Coatings AG
    Inventors: Klaus Holzapfel, Heinrich Wonnemann
  • Patent number: 6420494
    Abstract: A curable composition having an epoxy component and an organosilane component. The epoxy component includes at least one epoxy compound having two or more epoxide functional groups. The organosilane component includes at least one organosilane compound having two or more silyl ether groups. An exemplary organosilane compound is a siloxane-modified polyol.
    Type: Grant
    Filed: September 27, 2000
    Date of Patent: July 16, 2002
    Assignee: NDSU Research Foundation
    Inventors: Mark D. Soucek, ShaoBing Wu
  • Patent number: 6413648
    Abstract: The invention relates to a can or coil coating resin system. The system contains a mixture of at least 2 polymers wherein at least one polymer has a glass transition temperature greater than 45° C. and wherein the polymers are soluble in organic solvents. The polymer with the glass transition temperature of greater than 45° C. is preferably an amorphous polyester resin. The second polymer may be a resin with a dry solids content between 30% and 100% and a Tg of less than 40° C.
    Type: Grant
    Filed: October 18, 1999
    Date of Patent: July 2, 2002
    Assignee: DSM NV
    Inventors: Albert Heyenk, Johannes Wilhelmus Besamusca
  • Patent number: 6413642
    Abstract: The present invention relates to a method of coating substrates, preferably of metal, by cleaning the substrate surface, applying, if desired, an organic and/or inorganic pretreatment composition, applying a primer, applying a coating material by spraying, dipping, knifecoating, rollercoating or brushing, the coating material comprising an amine-modified epoxy resin and a crosslinking agent suitable for crosslinking.
    Type: Grant
    Filed: August 6, 1999
    Date of Patent: July 2, 2002
    Assignee: BASF Coatings AG
    Inventors: Egon Wegner, Ulrike Clausen-Meiring, Karl-Heinz Grobe Brinkhaus, Lothar Jandel, Wolfgang Bremser, Guido Wilke, Dorothe Drescher, Rainer Bürstinghaus, Günther Ott
  • Patent number: 6410145
    Abstract: Provided are a thermosetting resin composition for build-up method which gives a cured product excellent in heat resistance, an insulating material for build-up method using thereof and a build-up print circuit board. The thermosetting resin composition for build-up method comprises (A) an epoxy resin represented by formula (I), (B) a curing agent for epoxy resin and (C) a poly(ether sulfone), an insulating material for build-up method and a build-up print circuit board using thereof. in the formula, Gly represents glycidyl group: R represents each independently, an alkyl group having 1 to 10 carbons, and the like; i represents each independently a numeral of 0 to 4; when i is 2 or more, R may be the same or different from each other; and n represents a repeating number of 1 to 10.
    Type: Grant
    Filed: June 27, 2000
    Date of Patent: June 25, 2002
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Toshiaki Hayashi, Nobuyuki Nakajima, Noriaki Saito
  • Patent number: 6410146
    Abstract: A cationic electrodeposition coating composition is provided which contains blocked isocyanate curing agent which is blocked with a substance not recognized as a HAPs (hazardous atmospheric pollutant). The cationic electrodeposition coating composition of the present invention contains a cationic group-containing epoxy modified base resin and a blocked isocyanate curing agent, wherein said blocked isocyanate curing agent is obtained by reacting a polyisocyanate compound with, as a blocking agent, a terminal primary OH-containing propylene glycol monoalkyl ether and expressed by the formula RO(CH(CH3)CH2O)nH (where R is an alkyl group having 1 to 8 carbons, which may be branched, and n is 1 to 3).
    Type: Grant
    Filed: January 5, 2001
    Date of Patent: June 25, 2002
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Shinsuke Shirakawa, Keisuke Tsutsui, Mitsuo Yamada
  • Publication number: 20020071955
    Abstract: The present invention provides a crosslinking agent which may have reactive benzoxazine groups prepared from (a) at least one aromatic compound, (b) at least one aminotriazine compound, and (c) at least one other compound having active hydrogen groups reactive with aminoplast compound (b). The crosslinking agent is essentially free of hydroxyl functionality and has a glass transition temperature of at least 25° C. The present invention is further directed to a method for preparing the above-described crosslinking agent, and a curable powder coating composition comprising a mixture of (A) a polymer having functional groups reactive with aminotriazine and/or benzoxazine groups having a glass transition temperature of at least 30° C.; and (B) the above crosslinking agent. Multilayer composite coating compositions are also provided including a basecoat deposited from a film-forming composition and a topcoat over the basecoat, deposited from the curable powder coating composition described above.
    Type: Application
    Filed: July 31, 2001
    Publication date: June 13, 2002
    Inventors: Ronald R. Ambrose, Anthony M. Chasser, Shengkui Hu, Jackie L. Smith
  • Patent number: 6403221
    Abstract: Epoxy resin compositions which comprise, as essential components, (A) an epoxy resin having two or more epoxy groups in one molecule, (B) a phenolic curing agent, (C) a phenoxy resin containing a bisphenol S skeleton and having a weight average molecular weight of 5,000 to 100,000, and (D) a curing accelerator, are useful for making adhesive films formed by coating the epoxy resin composition on a supporting base film. Such compositions are also useful for making prepregs, by coating and/or impregnating a sheet-shaped reinforced base material made of a fiber with the resin composition, as well as multilayer printed-wiring boards made with such prepregs. Such epoxy resin compositions are also useful for forming conductor layers with excellent adhesiveness without requiring, in the insulating layer, a roughening component which deteriorates performance, as well as multilayer printed-wiring boards.
    Type: Grant
    Filed: October 11, 2000
    Date of Patent: June 11, 2002
    Assignee: Ajinomoto Co., Inc.
    Inventors: Shigeo Nakamura, Tadahiko Yokota
  • Patent number: 6403222
    Abstract: Waxes, particularly paraffin and microcrystalline waxes, can act as corrosion inhibitors when added at low levels to compositions based on thermosettable resins such as epoxy resins. When such wax-modified thermosettable compositions are used to coat a metallic surface, enhanced protection of the metallic surface against corrosion due to environmental exposure such as salt spray is obtained. The thermosettable compositions are particularly useful in expandable or foamable form for imparting structural reinforcement to hollow metal parts such as automotive components.
    Type: Grant
    Filed: September 22, 2000
    Date of Patent: June 11, 2002
    Assignee: Henkel Corporation
    Inventor: Bruce L. Harrison
  • Patent number: 6387508
    Abstract: An electrically insulating composition for bonding to metal and method for applying the composition in sheet form. The insulating composition comprises a polyolefin polymer adapted for elevated temperature crosslinking and a co-bonding agent mixed with the polyolefin polymer in an amount up to about 60 parts of tile co-bonding agent to 100 parts of the polyolefin polymer. Preferably, the insulating composition cures in contact with metal pre-heated to elevated temperatures in a range from about 140° C. to about 190° C. to provide a lap-shear bond strength between the electrically insulating composition and a metal substrate of from about 3.3 MPa to about 12 MPa.
    Type: Grant
    Filed: September 14, 2000
    Date of Patent: May 14, 2002
    Assignee: 3M Innovative Properties Company
    Inventors: C. Carol Guilbert, David V. Mahoney, Rafael Garcia-Ramirez
  • Patent number: 6387310
    Abstract: A thermosetting resin composition for prestressed concrete tendon, wherein the composition does not harden until the completion of the straining of the tendon, which is the inherent object in the post-tension technique, even if the heat storage temperature in the concrete structures elevates from 30° C. to 80° C. or higher due to heat of hydration reaction in setting a concrete, particularly 95° C. that is the maximum temperature in solidifying a concrete, and the composition including the site of 30° C. or lower where there is substantially no partial heat storage due to heat of hydration reaction in setting the concrete hardens within the prescribed period of time under spontaneous environmental temperature after the subsequent natural cooling, thereby achieving anti-rust and anti-corrosion of the tendon and also adhesion and integral bonding of the tendon and the concrete, a use method thereof and a prestressed concrete tendon.
    Type: Grant
    Filed: April 25, 2000
    Date of Patent: May 14, 2002
    Assignees: Mitsui Chemicals, Inc., Shinko Wire Company, Ltd.
    Inventors: Hiroshi Iizuka, Toshio Kobayashi, Mutsuhiko Ohnisi, Seiichiro Hirata
  • Patent number: 6383643
    Abstract: A coated substrate for plumbing applications in which the leaching of metals into water contacting the substrate is significantly reduced, comprises an alloy having copper has a majority constituent and also comprising tin, zinc and lead; and a coating having a thickness in a range from 0.4 to 1.2 mils upon the substrate, the coating further comprising a mixture of an cationic epoxy resin material and a curing agent for said cationic epoxy resin material. The coating is preferably applied by electrodeposition and then cured by baking in an oven at approximately 400° F. for about twenty minutes.
    Type: Grant
    Filed: August 24, 1999
    Date of Patent: May 7, 2002
    Assignee: Badger Meter, Inc.
    Inventor: George De Jarlais
  • Patent number: 6379765
    Abstract: A framing device, used for displaying items such as photographs, certificates and the like, includes a translucent sheet-like material having an outward side and an inward side, both having a common continuous edge. An adhesive is applied along the inward side adjacent to the continuous edge in such a manner that a portion of such edge remains adhesive-free. A sheet of backing material has a first side and a second side and the first side of such foam is positionally secured by the adhesive and with respect to the translucent material. And a release liner is attached to the second side of the backing material. The adhesive-free portion of the edge and the sheet of backing material define a slot permitting insertion and removal of an item to be displayed.
    Type: Grant
    Filed: September 14, 1998
    Date of Patent: April 30, 2002
    Inventor: Carey P. Woods
  • Patent number: 6376081
    Abstract: The invention provides a resin composition that is the reaction product of an epoxy resin and an anhydride. The resin composition has an epoxy equivalent weight that is substantially the same as the epoxy equivalent weight of the epoxy resin. The resin composition may be used as a coating composition, or may be mixed with water to form a water based coating composition.
    Type: Grant
    Filed: October 2, 2000
    Date of Patent: April 23, 2002
    Assignee: Valspar Corporation
    Inventors: Girish G. Parekh, Paul Bohler, Jason M. Legleiter, Donald Wind
  • Patent number: 6372823
    Abstract: The present invention provides a cationically electrodepositable coating composition comprising: (A) a water-soluble or water-dispersible resin obtained by reacting a hydroxyl group of a bisphenol A type epoxy resin with a cyclic ester compound, (B) a vinyl resin having a solubility parameter value of less than 9.6, (C) polyalkylene glycol having a solubility parameter value of less than 9.6, and (D) a pigment component having an average particle diameter of 0.5 &mgr;m or less.
    Type: Grant
    Filed: September 27, 2000
    Date of Patent: April 16, 2002
    Assignee: Kansai Paint Co., Ltd.
    Inventors: Hidenori Furukawa, Takahisa Kasukawa
  • Patent number: 6368718
    Abstract: An anti-corrosive coating for structural steel components contains 3 to 80 wt. % of a binder including polymeric material, and 20 to 97 wt. % of a filler including semiconductive elements or compounds. A process for welding a steel component coated with such an anti-corrosive coating involves temporarily energizing the semiconductive material of the coating into its conductive state and then carrying out the welding process, e.g. electric spot welding, while the semiconductive material is in the conductive state. Thereby, the coating does not hamper the electric welding operation. The step of energizing the semiconductive material is achieved by temporarily applying an external energy such as localized heating or incident light radiation having a photon energy corresponding to an energy band gap of the semiconductive material.
    Type: Grant
    Filed: November 22, 1999
    Date of Patent: April 9, 2002
    Assignee: DaimlerChrysler AG
    Inventor: Christina Schmidt
  • Patent number: 6355351
    Abstract: The present invention provides a cationically electrodepositable coating composition capable of forming a coating film which is excellent in both of coating film physical properties such as a chipping resistance and an impact resistance and a corrosion resistance. The composition comprises an amine-modified epoxy resin (A) and a blocked polyisocyanate (B), further comprising 5 to 50 parts by weight of a cationic urethane-modified polymer emulsion (C) per 100 parts by weight of the total of the amine-modified epoxy resin (A) and the blocked polyisocyanate (B) in terms of a solid matter.
    Type: Grant
    Filed: February 16, 2001
    Date of Patent: March 12, 2002
    Assignee: Kansai Paint Co., Ltd.
    Inventors: Hidenori Sawada, Shigeo Nishiguchi, Koji Kamikado
  • Patent number: 6349747
    Abstract: The invention describes the use of compositions containing at least one thermoplastic polymer and an epoxy resin modified by at least one aromatic polyamine to coat surfaces, especially pipes through which oil is transported. The polymer compositions used contain at least one thermoplastic polymer which is preferably amorphous selected from the group formed by polysulphones, polyetherimides and polyphenylene esters and at least one epoxy resin modified by at least one aromatic polyamine containing at least two primary amine groups in its molecule. Different layers of polymers are deposited on different types of surface, more particularly as internal and external coatings for conduits. The invention also provides a surface coating comprising such compositions. Multi-layer coatings are also produced.
    Type: Grant
    Filed: January 22, 1999
    Date of Patent: February 26, 2002
    Assignee: Institut Francais du Petrole
    Inventors: Yves Camberlin, Jacky Grenier, Stéphane Poncet, Anthony Bonnet, Jean-Pierre Pascault, Henri Sautereau
  • Publication number: 20020022409
    Abstract: A coated battery terminal for protection from corrosion. A non-conductive coating is deposited on all outer surfaces of a battery terminal which prevents the terminal from being exposed to the hostile environment which lead acid batteries are subject, thus increasing battery terminal life. The coating can be color-coded to assist in polarity identification. The coating eases clean-up and decreases maintenance of the battery terminals.
    Type: Application
    Filed: September 26, 1994
    Publication date: February 21, 2002
    Inventor: ROBERT M. CARIDEI
  • Patent number: 6333369
    Abstract: The present invention relates to an epoxy-based coating resin composition which facilitates the transcription of the printed letters or photographs developed by sublimation dyes on printing paper to the surface of potteries, glasses, marbles, metals or woods only by thermal treatment and more particularly, to the epoxy-based coating resin composition with 1) long-tern storage stability due to the use of a mixture of diethanolamine and triethanolamine as a hardening accelerator, 2) uniform thickness after coated, 3) less air bubbles after dried, 4) good depth in printing, and 5) a releasing property which promotes easier separation of printing paper from its coated surface after transfer-printed.
    Type: Grant
    Filed: October 19, 2000
    Date of Patent: December 25, 2001
    Assignee: Korea Research Institute of Chemical Technology
    Inventors: In-Hwan Park, Bong Keun Song, Jong Hak Kim, Bong Soo Chung
  • Patent number: 6329045
    Abstract: A composition for substrate materials according to the present invention includes 70-95 wt. % of inorganic powder and 5-30 wt. % of thermosetting resin composition and is in a finely crushed condition. The composition for substrate materials is prepared, for example, by crushing into fine pieces and mixing the inorganic powder and the thermosetting resin composition. A heat conductive substrate is provided with an insulator body formed by heating and pressurizing said composition for substrate materials and a wiring pattern is provided in such a condition that it is exposed on the surface of the insulator body. A process for manufacturing the heat conductive substrate comprises forming said composition for substrate materials into the insulator body by casting the above mentioned composition for substrate materials into a metal mold to be heated and pressurized so that said thermosetting resin is cured.
    Type: Grant
    Filed: February 17, 2000
    Date of Patent: December 11, 2001
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Koichi Hirano, Seiichi Nakatani, Hiroyuki Handa
  • Patent number: 6322892
    Abstract: There is disclosed a cation-polymerizable coating composition characterized by containing (A) a cation-polymerizable binder component consisting of (a) an epoxy group-containing compound and, as necessary, (b) an oxetane compound, (B) a modified dimethylsilicone oil with a number average molecular weight of 500-1,000,000 having a hydroxyl group(s) bonded directly to a silicon atom, a hydrolyzable functional group(s) bonded directly to a silicon atom and capable of forming a hydroxyl group(s) bonded directly to a silicon atom by hydrolysis, or a carboxyl group(s), and (C) a cation-polymerization initiator which forms a cation by irradiation or by heating. Said coating composition is suitable particularly for coating cans capable of forming a coating film having excellent adhesivity, processibility, hardness, initial lubricity and lubricity after the retort treatment.
    Type: Grant
    Filed: June 8, 1999
    Date of Patent: November 27, 2001
    Assignee: Kansai Paint Co., Ltd.
    Inventor: Seiji Takami
  • Patent number: 6323131
    Abstract: A ULSI circuit chip comprising copper interconnects is provided with a corrosion protection passivating layer on the surface of the copper which layer is comprised of a self assembled organic monolayer formed from treating the copper surface with a dilute solution of, for example a thio-bisalkyl acetoacetonate. A similar layer can be formed under the copper to provide a barrier layer against copper migration.
    Type: Grant
    Filed: June 13, 1998
    Date of Patent: November 27, 2001
    Assignee: Agere Systems Guardian Corp.
    Inventors: Yaw Samuel Obeng, Jennifer S. Obeng
  • Patent number: 6319619
    Abstract: The present invention relates to a semiconductor encapsulating resin composition which is safe and superior in moisture resistance, flame retardance and moldability, and to a highly reliable semiconductor device which is fabricated by encapsulating a semiconductor element with such a semiconductor encapsulating resin composition. The resin composition according to the present invention comprises a thermosetting resin, a hardening agent and a compound metal hydroxide of polyhedral crystal form represented by the following general formula (1): m(MaOb).n(QdOe).cH2O  (1) [wherein M and Q are different metal elements; Q is a metal element which belongs to a group selected from IVa, Va, VIa, VIIa, VIII, Ib and IIb groups in the periodic table; m, n, a, b, c, d and e, which may be the same or different, each represents a positive number].
    Type: Grant
    Filed: October 20, 1999
    Date of Patent: November 20, 2001
    Assignee: Nitto Denko Corporation
    Inventors: Yuko Yamamoto, Miho Yamaguchi, Hitomi Shigyo
  • Patent number: 6312813
    Abstract: The present invention provides a cationic electrodeposition paint capable of forming a coating film with uniform coating surface and small film thickness difference and excellent in gloss and levelling property, characterized by containing a cationizable resin having crosslinkable functional group (A), a blocked polyisocyanate compound (B) and benzoic acid and/or salicylic acid (C).
    Type: Grant
    Filed: March 10, 2000
    Date of Patent: November 6, 2001
    Assignee: Kansai Paint Co., Ltd.
    Inventors: Shinji Miyatake, Hidehiko Haneishi
  • Patent number: 6309751
    Abstract: To a substrate such as brass is applied a powder coating comprising a) at least one non-crystalline epoxy resin, b) at least one crystalline epoxy resin such as tetramethylbisphenol diglycidyl ether in an amount sufficient to reduce or eliminate bubble entrapment within the cured coating when cured at a temperature of below about 350° F. (about 177° C.), and c) a curing agent such as dicyandiamide.
    Type: Grant
    Filed: June 28, 2000
    Date of Patent: October 30, 2001
    Assignee: Rohm and Haas Company
    Inventors: William G. Ruth, Stacy L. Greth, Carryll A. Seelig, Dean A. Schreffler
  • Patent number: 6310147
    Abstract: An epoxy-resin composition comprising (A) an at least bifunctional epoxy compound and/or an at least bifunctional epoxy resin, (B) an at least bifunctional ester-containing compound and/or an at least bifunctional ester-containing resin as a curing agent, 10 to 100% of whose hydroxy groups are esterified with aliphatic or aromatic acyl groups, and (C) an accelerating agent, the accelerating agent essentially containing a phosphine oxide represented by general formula (1): where R1 to R6 all of which may be the same or not are hydrogen, straight, branched or cyclic alkyl having 1 to 10 carbons or aryl or aralkyl having 6 to 10 carbons.
    Type: Grant
    Filed: May 17, 1999
    Date of Patent: October 30, 2001
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Tatsuhiro Urakami, Kenichi Sugimoto, Takuo Tajima, Koutaro Suzuki, Keisuke Takuma, Tadahito Nobori, Usaji Takaki