Abstract: An adhesive for lamination which comprises a resin whose dynamic wettability to a film substrate is at least 0.20 mN alone or in combination with a polyisocyanate curing agent, said adhesive for lamination having a good adhesiveness to a film substrate such as a plastic film, a metal foil, a metallized film or paper.

Abstract: An applique is provided that includes a fluoropolymer backing, an adhesive on one of the surfaces of the backing and a urethane coating layer on the other surface of the backing.

Abstract: The invention relates to an imaging member comprising at least two polymer sheets joined by solvent based thermoplastic adhesive applied to at least one said at least two polymer sheets between 15 and 50° C.

Abstract: A co-mingled polyurethane-polyvinyl ester composition can be used as a coating, which has good scratch, mar and solvent resistance. The coating is derived from a waterborne polyurethane solution containing free radically polymerizable monomers such as acrylate, ultraviolet light initiators, and optionally urethane crosslinking agents. A process for forming the co-mingled polyurethane-polyvinyl ester composition comprises drying the waterborne polyurethane containing the polymerizable monomers therein and radiation polymerizing, as by ultraviolet light, the free radically polymerizable monomers on a substrate such as a plastic sheet to form a laminate. Subsequently, the laminate can be utilized to form a coating on a product as by thermoforming, where if urethane crosslinking agents are utilized, the polyurethane will be crosslinked.

Abstract: A laminated multilayer film substrate for use in the production of banknotes having an oriented polypropylene core layer and at least one high density polyethylene layer on each side of the oriented polypropylene layer. The core layer contains microcavities formed by the addition of a cavitating agent. The resultant films exhibit good embossability, dead-fold characteristics and other properties, making them highly suited for the production of bank notes and other security documents.

Abstract: The invention relates to an elastic coating system with which dry surfaces can be formed by UV curing of constituents containing (meth)acryloyl groups and by subsequent crosslinking of constituents containing NCO groups with constituents containing active hydrogen. The invention also relates to their use of this coating, system for coating, inter alia, components of plastic.

Abstract: Composites of at least two different plastics materials joined directly to one another, wherein A) is a thermoplastic polymer or a thermoplastic mixture of polymers which contain at least one polar compound of at least one of the metals of the 1st to the 5th main group or of the 1st to 8th subsidiary group of the Periodic System as an extremely finely divided powder, and B) is polyurethane.

Abstract: The present invention provides a multiple layer thermoplastic structure of a (1) skin layer selected from the group consisting of polypropylene, ethylene homopolymers having a density of from about 0.930 g/cc to about 0.960 g/cc, and ethylene homopolymers having a density of from about 0.930 g/cc to about 0.960 g/cc blended with an ethylene and a-olefin copolymers having a density less than about 0.930 g/cc, the skin layer having a thickness of greater than about 3.0 mils; (2) a radio frequency susceptible layer adhered to the skin layer, the radio frequency susceptible layer having a dielectric loss greater than 0.05 at 1-60 MHz and at temperatures of ambient to 250° C.

Abstract: The invention is a laminate structure comprising two or more layers of one or both of a) a polymeric layer containing olefinic unsaturation; and b) a polymeric layer having active hydrogen atoms; wherein, c) an adhesive layer is located between the layers derived from one or more compounds having one or more nitrile oxide moieties; wherein a portion of the nitrile oxide moieties, or derivatives thereof, is reacted with olefinic unsaturation of layer a), the active hydrogen atoms of layer b or both.

Abstract: Conductive article, for example a roller, a doctor blade or a flat or curved plate, at least comprising a conductive sleeve and a covering layer, the covering layer containing a conductive polymer and a film-forming polymer, and method for fabricating such an article, at least comprising the application of a covering layer to a conductive sleeve, wherein the covering layer is formed by the application, to the sleeve, of a mixture of a conductive polymer and a film-forming polymer.

Abstract: The flexible, weatherable decorative sheet material provided by the present invention comprises a thermoformable decorative paint film having an inner surface and a weatherable, low gloss outer surface suitable for forming an exterior finish for a part, such as an automobile body part. The sheet material further includes an extensible mask layer releasably adhered to the outer surface of the paint film to form a protective film overlying the paint film. The mask layer comprises a film-forming polymer component and a particulate filler, such as silica, dispersed in the polymer component. A method of constructing the decorative sheet material, a method of controlling the gloss appearance of a paint film, and a composite shaped part including the decorative sheet material are also provided.

Abstract: A co-mingled polyurethane-polyvinyl ester composition can be used as a coating, which has good scratch, mar and solvent resistance. The coating is derived from a waterborne polyurethane solution containing free radically polymerizable monomers such as acrylate, ultraviolet light initiators, and optionally urethane crosslinking agents. A process for forming the co-mingled polyurethane-polyvinyl ester composition comprises drying the waterborne polyurethane containing the polymerizable monomers therein and radiation polymerizing, as by ultraviolet light, the free radically polymerizable monomers on a substrate such as a plastic sheet to form a laminate. Subsequently, the laminate can be utilized to form a coating on a product as by thermoforming, where if urethane crosslinking agents are utilized, the polyurethane will be crosslinked.

Abstract: Described are articles having an aminoplast resin photochromic coating prepared from an aminoplast resin, component(s) having at least two different functional groups and photochromic substances. The coatings exhibit a Fischer microhardness of from 45 to 180 Newtons per mm2 and desirable photochromic properties, i.e., the formation of darker activated colors and faster rates of photochromic activation and fade when irradiated with ultraviolet light. Also described are photochromic aminoplast resin articles.

Abstract: Curable compositions that are particularly suitable for coating plastic ophthalmic lenses includes (a) 20% to 80% of a first acrylated aliphatic urethane; (b) 5% to 50% of a monofunctional acrylate; (c) (i) 2% to 30% of a second acrylated aliphatic urethane or (ii) 2% or 25% of a multifunctional acrylate or (iii) a combination of (i) and (ii); (d) 1% to 30% of a colloidal metal oxide; (e) 1% to 20% of a photoinitiator; and (f) a solvent, with the percentages based on weight. The cured composition provides superior abrasion and impact resistance as well as protection against environmental and chemical agents. In addition, the UV curable compositions are capable of forming films on various substrates; the film has excellent compatibility and adhesion to AR coatings that are applied thereon. No primer coating is required.

Abstract: There is provided a molded product comprising: a molded substrate comprising a polyolefin resin and an ethylene-propylene rubber; a chlorinated polyolefin resin layer laminated onto the molded substrate, the chlorinated polyolefin resin layer being in contact with the molded substrate; and a surface layer of a thermoplastic resin layer laminated as an outermost layer onto the chlorinated polyolefin resin layer either directly or through other layer(s).

Abstract: A flexible lustered product used in automobiles. The flexible lustered product includes a base material made of resin. A base coat layer is formed on at least a portion of a surface of the base material by applying a coating. The base coat layer has a glass transition point that is at least −30° C. and at most 0° C. The base coat layer includes a silane coupling agent having a mercapto group. A metal film layer is applied to at least a portion of a surface of the base coat layer. The metal film layer is anticorrosive and has a thickness that is at least 150 Å and at most 800 Å. The metal film layer is formed by a plurality of metal particles disposed in contact with one another so as to define a grain boundary between adjacent metal particles. A top coat layer is formed on at least a portion of a surface of the metal film layer by applying a coating.

Abstract: A weatherseal for repeatedly and releasably contacting a panel to provide a weather resistant seal therebetween. The weatherseal includes a substrate having a contact layer on the portion of the substrate that contacts the panel. The contact layer includes a multitude of surface treated ultra high molecular weight olefinic particles, such as ultra high molecular weight polyethylene, in a thermoset material such as cross linkable urethane, wherein some of the embedded particles define the area of contact between the weatherseal and the panel.

Abstract: An optical article comprising a first layer of a transparent resin having a self-healing property; an antireflection layer consisting essentially of a non-crystalline fluorine-containing polymer disposed underneath said first layer; and a circular polarizer disposed underneath said antireflection layer. The optical article has anti-reflective and anti-glare properties and also has self-healing properties and scuff resistance imparted by a thin, multi-layered film. The optical article thus is effective in reducing reflection and glare.

Abstract: Anionic electrodeposition coating compositions for forming matte films containing acrylic resin; alkoxysilyl group containing emulsified polymer produced by a multiple stage emulsion polymerization of unsaturated monomer in the presence of water and a emulsifier, wherein the unsaturated monomer containing alkoxysilyl group-containing unsaturated monomer is present in an amount of 5 to 40% by weight based on a total amount of all the unsaturated monomers used in the multiple stage emulsion polymerization; and crosslinking agent.

Abstract: A weatherseal for repeatedly and releasably contacting a panel to provide a weather resistant seal therebetween. The weatherseal includes a substrate having a contact layer on the portion of the substrate that contacts the panel. The contact layer includes a multitude of surface treated ultra high molecular weight olefinic particles, such as ultra high molecular weight polyethylene, in a thermoset material such as cross linkable urethane, wherein some of the embedded particles define the area of contact between the weatherseal and the panel.

Abstract: A composite material is described which comprises at least two layers of different plastics materials which are directly bonded to each other, wherein

Abstract: A radiation-curable composition is disclosed. An fluorinated oligomer is combined with a diluent monomer and a photoinitiator to form the radiation-curable coating composition. The fluorinated oligomer is substantially free of isocyanate groups. The radiation-curable compositions provide a suitable coating for substrates, are resistant to penetration by water and liquid hydrocarbons, retain their physical properties over a wide temperature range and exhibit immeasurably low surface friction properties.

Abstract: A method improving paint adhesion to thermoplastic olefins. The method comprises providing a thermoplastic olefin prepared from a TPO blend comprising maleated polypropylene and amine-terminated polyether. A paint is provided comprising a base paint and a paint adhesion promoter selected from the group consisting of a chlorinated polyolefin, a hydrogenated poly(butadiene)diol, and mixtures thereof. The paint is applied to the thermoplastic olefin.

Abstract: Composites of at least two different plastics materials joined directly to one another, wherein

Abstract: The present invention provides a multilayer sheet comprising a polymeric film having on a first major side a cross-linked polyurethane layer, the major part of said cross-linked polyurethane layer comprising a polycarbonate based polyurethane containing acid groups and cross-linked with a cross-linker, the polycarbonate-based polyurethane comprising the reaction product of a polycarbonate polyol or a polycarbonate polyamine and an aliphatic polyisocyanate and the uncross-linked polycarbonate-based polyurethane having a Koenig hardness of at least 150 seconds.

Abstract: A thermoplastic skin sheet constituted by (a) a thermoplastic polyolefin or elastomer sheet; (b) a primer layer coated on the sheet, the primer being based on a modified polyolefin resin containing 2 mg-equivalent/g or less of a hydroxyl group or a carboxyl group; and (c) a topcoat layer coated on the primer layer. The topcoat layer may be mainly composed of (a) 100 parts by weight of a polycarbonate polyurethane resin having a number-average molecular weight of 8,000 or more and a 100% modulus of 20 kg/cm2 or more, and (b) 0.1-40 parts by weight of a (meth)acrylate-butadiene-styrene resin. The surface of the topcoat layer may be subjected to embossing.

Abstract: The present invention relates to membranes including an urethane including a polyester polyol, wherein the membrane has a gas transmission rate of 15.0 or less for nitrogen gas wherein the membrane has an average thickness of approximately 20.0 mils. Under certain embodiments, the membranes include blends of one or more polyester polyol based thermoplastic urethanes and one or more barrier materials. The membranes can be employed in a variety of applications and can be used as either monolayers or multi-layered laminates.

Abstract: There is provided a molded product comprising: a molded substrate comprising a polyolefin resin and an ethylene-propylene rubber; a chlorinated polyolefin resin layer laminated onto the molded substrate, the chlorinated polyolefin resin layer being in contact with the molded substrate; and a surface layer of a thermoplastic resin layer laminated as an outermost layer onto the chlorinated polyolefin resin layer either directly or through other layer(s).

Abstract: Multilayer elastomer films (multilayer material) comprising at least one continuous layer, carrying an active chemical substance (such as corrosion inhibitors, lubricants or alternatively biocides for medical use), inserted between inert elastomer barrier layers, processes for the preparation and various applications of these films. The multilayer polymeric material comprises at least one layer A composed of a gel which is reversible or non-reversible, as a function of the temperature, and which carries at least one active chemical substance x, and at least two barrier layers E comprising a synthetic elastomer e, the said layers being held together by a polymeric bonding agent y incorporated in at least one of the said layers A or E and/or by an independent bonding layer Z comprising a polymer z and/or by a chemical or physical treatment of at least one of the said layers A or E.

Abstract: A resin composition comprising (a) 100 parts by weight of a thermoplastic resin containing nitrogen atom(s) in structural units thereof; and (b) 0.1 to 20 parts by weight of an iron compound catalyst comprising at least one iron oxide-based compound selected from the group consisting of iron oxide hydroxide particles or iron oxide particles, which has an average particle size of 0.05 to 2.0 &mgr;m; and has a specific oxidation activity. Such a resin composition is inhibited from generating hydrocyanic acid upon the combustion, though the composition contains nitrogen atom(s) in structural units thereof.

Abstract: The invention relates to an optionally foamed sealing composition for preformed seals which can swell when treated with water. The invention also relates to a method for the production thereof out of natural rubber and/or elastomers with a matrix comprised of natural rubber/elastomer components and particle-shaped water absorbing material stored therein. The water absorbing material is a combination of (A) polysaccharide(s) selected from cellulose, starch, starch derivatives removed from grafted starch, amylose, amylopectin, dextran, pectin, inulin, chitin, xanthan, alginic acid, alginates, carrageenan, pustulan, callose, laminarin, guluronic acid, pullulan, lichenin or mixtures of the same with (B) a highly water absorbent synthetic polymer selected from polymers based on (meth)acrylate, poly(meth)acrylic acid and the salts thereof, polyacrylamide, polyalcohols or copolymers of said synthetic polymers.

Abstract: An easily adhesive polyamide film has been created from unstretched or uniaxially stretched non-heated polyamide film coated with a water-base coating mixture, whose main constituents are (A) water polyurethane resin containing acetylene glycol in which each carbon atom immediately adjacent to the triple-bonded carbon atom is replaced with a hydroxyl group and a methyl group, and/or an ethylene oxide addition product of the acetylene glycol; (B) a water-soluble polyepoxy compound; and (C) particles with an average diameter between 0.001 and 1.0 &mgr;m, of which the solid-content weight ratio is 98-30/2-70/0.1-10, the coating amount after stretching is between 0.005 and 0.030 g/m2, and the film is stretched in at least one direction and then heated. This newly invented film possesses good blocking resistance and excellent adhesiveness with print ink, laminate, and other coating mixtures, and is especially suitable for boiling sterilization, retort sterilization, and packaging of liquids.

Abstract: A water-based coating composition suitable for preparing hydrophilic surfaces on various articles is provided which includes a supporting polymer having functional moieties capable of undergoing crosslinking reactions, said supporting polymer soluble in or emulsified in an aqueous based medium; and a hydrophilic polymer, said hydrophilic polymer associated with the supporting polymer. The composition is characterized in that, when crosslinked at the functional moieties, the supporting polymer forms a three-dimensional network which substantially minimizes disassociation of the hydrophilic polymer.

Abstract: A composite article is provided which includes a fluoropolymer intimately bonded to a component including a substantially non-fluorinated thermoplastic having pendant phenolic groups in combination with a base. Increased adhesion is observed by a greater peel strength value between the fluoropolymer component and a non-fluorinated thermoplastic having pendant phenolic groups.

Abstract: Multilayer transparent, antireflex, coloured or opaline plates, with smooth or embossed surfaces, optionally thermouldable with external layers in acrylic polymers, low thickness, in the range of 1.5 up to lower thicknesses of 10 mm, by employing one or more polymeric continuous films which have the property to have elastic modulus lower than the one of PMMA of at least 30%, and/or elongation at break higher than at least 40%, measured by the test according to ISO 527 for plates or films, placed inside the panel.

Abstract: A coating material for forming an information display surface of the present invention contains a water absorbent substance and a water-soluble substance. The water absorbent substance is protein such as collagen or polysaccharide such as cellulose. A display medium has a base material for display made of polyolefin type resin and the like on which the information display surface made of the coating material is formed. Another coating material for forming the information display surface contains an ultraviolet curable resin and a natural organic substance as major components. The natural organic substance is collagen, wool, keratin and so on.

Abstract: The present invention is intended to provide aqueous resin compositions excellent in low temperature film-forming property and stability, without intentionally adding any volatile organic compound. They are double-layered aqueous resin compositions formed by copolymerising in water emulsifiable polymeric polyurethane resin and polymeric vinyl monomer, which are excellent in low temperature film-forming property and stability due to the action of the grafted polyurethane resin component in the outer layer and with hydroxyls introduced into at least either one of the polyurethane resin component and the vinyl polymer component.

Abstract: A laminate product for use as a protective and decorative sheet material for application to a substrate is described. The laminate product is comprised of: (1) a base coat layer comprising a colorant-containing thermoplastic resin system, the colorant being substantially uniformly distributed throughout the colorant-containing thermoplastic resin system; (2) a top coat layer; and (3) an adhesion promoting layer disposed between the base coat layer and the top coat layer. The colored base coat layer permits deeper draws for the formation of highly contoured components such as automotive bumpers and fascias, without the loss of color intensity or scratch resistance.

Abstract: This invention involves a composition composed of a homopolymer of vinyl ethylene carbonate or a copolymer of vinyl ethylene carbonate, which is further reacted with ammonia, a primary alkyl amine, or an amino alcohol. The resulting compound, which is a polymer containing both carbamate and hydroxyl groups is then mixed with an aminoplast, coated on a substrate and cured to form a crosslinked coating. In addition, the polymer containing both hydroxyl and carbamate functional groups can be further reacted with either an anhydride or a monofunctional isocyanate, resulting in a copolymer containing only carbamate functional groups. This copolymer is mixed with an aminoplast, coated on a substrate and cured to form a crosslinked coating.

Abstract: A thermoplastic skin sheet constituted by (a) a thermoplastic polyolefin or elastomer sheet; (b) a primer layer coated on the sheet, the primer being based on a modified polyolefin resin containing 2 mg-equivalent/g or less of a hydroxyl group or a carboxyl group; and (c) a topcoat layer coated on the primer layer. The topcoat layer may be mainly composed of (a) 100 parts by weight of a polycarbonate polyurethane resin having a number-average molecular weight of 8,000 or more and a 100% modulus of 20 kgf/cm2 or more, and (b) 0.140 parts by weight of a (meth)acrylate-butadiene-styrene resin. The surface of the topcoat layer may be subjected to embossing.

Abstract: The present invention provides a multilayer sheet comprising a polymeric film having on a first major side a cross-linked polyurethane layer, the major part of said cross-linked polyurethane layer comprising a polycarbonate based polyurethane containing acid groups and cross-linked with a cross-linker, the polycarbonate-based polyurethane comprising the reaction product of a polycarbonate polyol or a polycarbonate polyamine and an aliphatic polyisocyanate and the uncross-linked polycarbonate-based polyurethane having a Koenig hardness of at least 150 seconds.

Abstract: A process is disclosed for the manufacture of reinforced composites. This method provides a process that allows for the direct mixing of discontinuous reinforcement such as wet chopped strands of glass fiber or continuous reinforcement such as glass strands, with an aqueous suspension of a solution polymerized polymer, such as polyvinyl chloride. The process results in a cost-effective means for reinforcing polymers such as PVC while simultaneously substantially improving properties such as impact strength, stiffness, and moldability without the need for a binder.

Abstract: Described is a preferred UV curable coating composition comprising (exclusive of any solvent present): (a) about 5% to 90% by weight of an acrylated aliphatic urethane having a molecular weight of about 500 to 2000 and comprising an aliphatic urethane based on a polymer of allyl carbomonocycle diisocyanate with alkanepolyol polyacrylates, (b) about 5% to 30% by weight of a multifunctional acrylate having a molecular weight of about 170 to 1000 and containing at least two polymerizable unsaturated groups per molecule; and (c) a photopolymerization initiator and/or sensitizer. Also described are preferred processes of coating a plastic and coated articles involving the preferred coating compositions.

Abstract: A system for protecting surfaces and facilitating the removal of unwanted substances therefrom is disclosed, the system including a polymeric coating having a low volatile organics content (VOC) which is safe for the environment, and a cleaner for application to the coating to remove material from the coating, such as graffiti. The coating may be either a water-based epoxy comprising a bisphenol A resin and polyamide resin, or an aliphatic urethane comprising a polymer having reactive sites which react with a isocyanate and an aliphatic isocyanate. The cleaner is suitable for removing all manner of epoxy and urethane based spray paints, indelible inks, industrial chemicals, and the like. The cleaner comprises N-methyl pyrrolidone in a concentration of fifty percent by weight or greater and a surfactant.

Abstract: Compositions comprising a fluorochemical agent, a copolymer extender, and a blocked isocyanate extender and substrates treated with such compositions that possess high initial water repellency and laundry durable water repellency.

Abstract: A composition and method for promoting improved adhesion between a thermoplastic resinous substrate and polyurethane foam is provided. In one aspect of this invention, the composition comprises a thermoplastic mixture of at least one polyphenylene ether and at least one poly(alkenylaromatic) compound; and at least one primary amine-containing material or secondary amine-containing material.

Abstract: A laminated multilayer film substrate for use in the production of banknotes having an oriented polypropylene core layer with print features and at least one high density polyethylene layer on each side of the oriented polypropylene layer. The resultant films exhibit good embossability, dead-fold characteristics and other properties, and are difficult to counterfeit, making them highly suited for the production of bank notes and other security documents.

Abstract: A method of bonding two substrates at least one of which is a rubbery polymeric material having carbon-carbon double bonds on the polymer backbone, the method comprising: a) applying an aqueous polyurethane dispersion adhesive composition to at least one of the substrates, the adhesive compostion further comprising an epoxy resin; b) allowing the composition to dry; and then c) joining the substrates with heating to activate the adhesive. The substrates are suitably footwear materials such as a molded rubber outer sole which has been first primed with a chlorinating primer, and a foam midsole of a material such as a lightly crosslinked ethylene vinyl acetate. The process results in bonded assemblies having improved humidity resistance.

Abstract: A multiple layer structure comprising a skin layer composed of a polypropylene copolymer with styrene ethylene-butene styrene block copolymer within a range of 0-20% by weight skin layer, and, a radio frequency (“RF”) susceptible layer adhered to the skin layer. The RF layer has a first component of a propylene based polymer, a second component of a nonpropylene polyolefin, a third component of a radio frequency susceptible polymer, and a fourth component of a polymeric compatibilizing agent wherein the radio frequency susceptible polymer is selected from the group consisting of ethylene acrylic acid copolymers, ethylene methacrylic acid copolymers, polyimides, polyurethanes, polyesters, and polyureas.

Abstract: A water-based coating composition suitable for preparing hydrophilic surfaces on various articles is provided which includes a supporting polymer having functional moieties capable of undergoing crosslinking reactions, said supporting polymer soluble in or emulsified in an aqueous based medium; and a hydrophilic polymer, said hydrophilic polymer associated with the supporting polymer. The composition is characterized in that, when crosslinked at the functional moieties, the supporting polymer forms a three-dimensional network which substantially minimizes disassociation of the hydrophilic polymer.