Abstract: A glazing panel and hollow glazing panel, the hollow glazing panel including a first pane, a second pane held in spaced-apart, face-to-face relationship with the first pane, and a plurality of localized damping members positioned between the first and second panes, adherent thereto, and distributed therebetween over the area of the opposing faces thereof, wherein the first pane comprises a pair of vitreous sheets and an intervening layer of polymeric material separating the sheets of the pair and to which the sheets adhere, wherein the first pane has a shape, an area, and a total mass of vitreous material, and may be compared to a notional monolithic vitreous sheets having a coincidence frequency (.phi..sub.m) and a critical frequency of coincidence, wherein the first pane has a coincidence frequency (.phi..sub.

Abstract: A process for producing laminated safety glass is disclosed, comprising depositing a film which comprises at least one function layer on a plastic sheet, inserting the sheet between a plurality of further layers, such as two polyvinylbutyral sheets which are in turn enclosed by glass panes, such that the plastic sheet projects beyond the edges of the other layers, clamping the plastic sheet along its projecting sections, and laminating the layers. A clamping device for performing the process and a laminated safety glass produced by the process are also disclosed.

Abstract: A wrinkle-free bilayer glazing panel comprising sequentially: a) a sheet of glass; b) a layer of plasticized partial polyvinyl butyral; c) a transparent polyester layer; and d) a layer of cross-linked, self-healing polyurethane.

Abstract: A laminating material for safety glass is disclosed wherein said material comprises a substrate of a polyester film satisfying the following conditions (1) to (4), on one side of which a heat ray shielding layer consisiting of a metal and/or a metallic compound:R.gtoreq.8000 (1)H.ltoreq.5 (2).alpha..sub.MD +.alpha..sub.TD .ltoreq.10 (3)F.sub.B .gtoreq.8 (4)wherein R stands for retardation (nm), H stands for film haze (%), .alpha..sub.MD and .alpha..sub.TD respectively stand for shrinkage of the film in the longitudinal (machine) direction and in the direction perpendicular to said direction and F.sub.B stands for the strength at break point (kg/mm.sup.2) in the longitudinal direction. The laminating material of the present invention does not generate interference fringes by polarized light, is excellent in transparency, heat resistance and strength and, therefore, suitable for heat ray reflection safety glass.

Abstract: A shaped interlayer blank adapted for use with glass in a vehicle windshield, such blank formed of plasticized polyvinyl butyral and having a quadrilateral peripheral contour with two sides of arcuate shape and a wedge-shaped thickness profile. The blank preferably has an arcuate gradient color band substantially parallel to an arcuate edge of the blank in the greater thickness region of the blank. The wedge-shaped thickness gradually increases from about 30 mils to about 35 to 40 mils across the width of the blank. The blank is tailored for safety windshields featureing head-up displays where to function effectively the glass layes must be nonparallel and canted with respect to each other.

Abstract: An optically transparent aqueous intumescent gel for use with transparent laminates comprising about 5 to 30% by weight acrylamide, about 0 to 4% by weight of a crosslinking agent, about 5 to 28% by weight of an ammonium or alkali metal salt of an alkanoic acid having 1 to 4 carbon atoms, about 0.05 to 10% by weight of a polymerization catalyst, and water, and a laminate with the gel.

Abstract: A reaction curable composition comprising, as reactive materials, a polyisocyanate component comprising a diisocyanate and a tri or higher functional polyisocyanate and having an average equivalent molecular weight of from 120 to 240, and a polyol component comprising a diol and a tri or higher functional polyol and having an average equivalent molecular weight of from 100 to 550.

Abstract: A laminate which is substantially free of distortion when used in a safety glazing comprising a transparent, thermoplastic substrate layer, optionally surface treated or coated to improve adhesion, bearing one or more functional performance layers, such as an infra-red radiation reflecting stack, and at least one layer of plasticized polyvinyl butyral bonded on one side to a functional performance layer or the substrate layer having a roughened deairing surface on its other side characterized by a roughness value, Rz, of at least 10 micrometers, such plasticized polyvinyl butyral layer, before bonding to the substrate layer or functional performance layer, possessing low surface waviness on each side characterized by a wave index value, WI, of less than 15,000 square micrometers.

Abstract: A process for forming intermediate sheeting for forming shaped interlayer blanks comprising extruding plasticized polyvinyl butyral melt into an endless straight-sided sheet having a gradient color band extending along one side, the melt forming the region of the sheet laterally of the color band extruding at a greater thickness than that forming the portion containing the color band, thereby providing a wedge-shaped thickness profile in the sheet, quenching the extruded sheet to set the polymer and winding the sheet in roll form. The intermediate sheet is at least about twenty inches wide and the wedge-shaped cross section gradually increases from about 28 to 32 mils at one edge to about 33 to 40 mils at the other edge.

Abstract: Oriented polyester films primer coated with a hydrolyzed amino silane are disclosed. These silanes in the unhydrolyzed state have the formula:XSi(R.sup.2).sub.a (R.sup.3).sub.bwherein X is a radical selected from the group consisting of H.sub.2 NR.sup.1 HNR.sup.1 --and H.sub.2 NR.sup.1 HNR.sup.1 HNR.sup.1 --; the R.sup.1 's are the same or different group selected from the group consisting of C.sub.1 to C.sub.8 alkyl or phenyl; R.sup.2 is a hydrolyzeable group selected from the group consisting of C.sub.1 to C.sub.8 alkoxy, an acetoxy group or a halide; R.sup.3 is a nonreactive, nonhydrolyzeable group selected from the group consisting of C.sub.1 to C.sub.3 alkyl or phenyl; (a) is an integer ranging from 1 to 3; (b) is an integer ranging from 0 to 2, with the sum of (a) and (b) being 3.The hydrolyzed aminosilane is applied to the film as an aqueous solution at any suitable stage during manufacture of the film, i.e., before or during the stretching operation, or it may also be applied to the finished film.

Abstract: A glazing unit comprises a substrate ply and a laminating ply laminated to a surface of the substrate ply. A coating on a laminated surface of the substrate ply is a film stack comprising a film of electrically conductive material covered by a film of dielectric material. The film of dielectric material immediately adjacent the laminating ply comprises a layer of silicon dioxide immediately adjacent the laminating ply and a layer of dielectric material of refractive index greater than 1.5 between the silicon dioxide and the conductive material. Applications include, for example, glazing units for solar load reduction and electrically heated glazing units.

Abstract: A glazing unit comprises a substrate ply and a laminating ply laminated to a surface of the substrate ply. A coating on the laminated surface of the substrate ply is a film stack comprising an electrically conductive film of silver metal covered by a tantalum pentoxide dielectric film immediately adjacent the laminating ply. Between the silver film and the tantalum pentoxide film is an adhesion film of metal selected from zinc and copper. Applications include, for example, glazing units for solar load reduction and electrically heated glazing units.

Abstract: The invention relates to a laminated glass panel incorporating therein a hologram sheet. For example, the laminated glass panel is a vehicle windshield in which the hologram sheet is used as a combiner of a head-up display. As adhesive means, the laminated glass panel uses either one sheet or two sheets of polyvinyl butyral resin (PVB) film. In the former case the hologram sheet is interposed between the PVB film and one of the glass plate and shielded from the PVB film by a transparent resin or glass film which prevents the plasticizer contained in the PVB film from transferring to the hologram sheet. In the latter case the hologram sheet is interposed between the two sheets of PBB film and shielded from each PVB film by a transparent resin or glass film having the aforementioned property. By virtue of the shielding of the hologram sheet from the PVB film, the diffraction wavelength of the hologram sheet does not significantly shift from the aimed wavelength.

Abstract: Oriented polyester films primer coated in-line with a hydrolyzed aminosilane are disclosed. These silanes in the unhydrolyzed state have the formula:XSi(R.sup.2).sub.a (R.sup.3).sub.bwherein X is a radical selected from the group consisting of H.sub.2 NR.sup.1 HNR.sup.1 --H.sub.2 NR.sup.1 HNR.sup.1 HNR.sup.1 --; the R.sup.1 's are the same or different groups selected from the group consisting of C.sub.1 to C.sub.8 alkyl or phenyl; R.sup.2 is a hydrolyzable group selected from the group consisting of C.sub.1 to C.sub.8 alkoxy, an acetoxy group or a halide; R.sup.3 is a nonreactive, nonhydrolyzable group selected from the group consisting of C.sub.1 to C.sub.3 alkyl or phenyl; (a) is an integer ranging from 1 to 3; (b) is an integer ranging from 0 to 2, with the sum of (a) and (b) being 3.The hydrolyzed aminosilane is applied to the film in-line as an aqueous solution at any suitable stage during manufacture of the film, i.e.

Abstract: There is disclosed automobile glass which is engraved with identifying indicia of a size whereby it can be easily viewed. Particularly, the automobile glass is of the conventional laminated type and the depth of the engraving is of sufficient depth whereby the indicia cannot be removed or obliterated. In one embodiment the engraving of the indicia is of a sufficient depth to expose a portion of the polymeric sandwiched material.

Abstract: In a solar screening assembly optionally heatable for defrosting/defogging/deicing which includes a plasticized polyvinyl butyral layer and a metal/dielectric stack comprising one or more light-reflecting metal layers and two or more antireflective layers, a cap layer Ta.sub.2 O.sub.5 or SiOx where x.ltoreq.2, in face-adhering contact with the plasticized polyvinyl butyral layer, such assembly when laminated with glass exhibiting pummel adhesion of at least 3 after at least 1000 hours exposure to UV radiation in a Fadeometer, Weatherometer or equivalent system.

Abstract: A flexible, draw-formed laminate for a safety glazing comprising a transparent, thermoplastic carrier film which is shrink-stable during laminating formation of such safety glazing bonded to at least one layer of plasticized polyvinyl butyral, such film having a greater tensile modulus than that of the layer of plasticized polyvinyl butyral. The carrier film is preferably flexible polyester such as polyethylene terephthalate having one or more functional performance coatings or layers on its surface such as a multi-layered solar radiation control stack.

Abstract: A composition of matter and an interlayer formed of such composition for a laminated glazing comprising polyvinyl butyral resin plasticized with a mixed adipate or a mixture of pure and mixed adipates made from: (a) at least one C.sub.4 to C.sub.9, preferably C.sub.6, alkyl alcohol and (b) at least one cyclo (C.sub.4 to C.sub.10), preferably C.sub.6, alcohol wherein the proportions of (a) and (b) in parts by weight per 100 parts (a) and (b) are: (a) 10-90, preferably 30-80 and (b) 90-10, preferably 70-20.

Abstract: A composition of matter and an interlayer formed of such composition for a laminated glazing comprising polyvinyl butyral resin plasticized with a mixed adipate or a mixture of pure and mixed adipates made from: (a) at least one C.sub.4 to C.sub.9, preferably C.sub.6, alkyl alcohol and (b) at least one cyclo (C.sub.4 to C.sub.10), preferably C.sub.6, alcohol wherein the proportions of (a) and (b) in parts by weight per 100 parts of (a) and (b) are: (a) 10-90, preferably 30-80 and (b) 90-10, preferably 70-20.

Abstract: A laminated transparency includes a flexible epoxy moisture seal about the periphery of the transparency. The edge of the transparency may be cleaned and primed with a silane surface treatment.

Abstract: A laminated structure composed of (A) a layer comprising a polyester resin, (B) a layer comprising a cured (meth)acrylate polymer containing an epoxy group in the molecule, and (C) a layer comprising a cured organopolysiloxane compound, the layers (A), (B) and (C) being laminated in this sequence. The laminated structure is suitable for use in a safety glass, for example.

Abstract: There are provided new articles comprising elements having surfaces bonded together with a bonding resin which is an elastomeric copolymer of about 15 to 45 mol %, preferably about 25 to 35 mol % trioxane, about 55 to 85 mol %, preferably about 65 to 75 mol % of 1,3-dioxolane, said mol percents based on the total of trioxane and 1,3-dioxolane, and about 0.005 to 0.15 wt. %, preferably about 0.05 to 0.12 wt. % of 1,4-butanediol diglycidyl ether or butadiene diepoxide as a bifunctional monomer, based on the total weight of copolymer. Preferably, at least one of said surfaces, and more preferably at least two of said surfaces bonded to each other are of a crystalline acetal polymer comprising at least 85 mol % of polymerized oxymethylene units.

Abstract: A polymeric laminate for use with a glass layer in a laminated bilayer or anti-lacerative shield application comprises a first layer of moisture tolerant plasticized polyvinyl butyral containing (a) adhesion control agent(s) and (b) residual hydroxyl content which optimize glass adhesion and optical performance over a range of moisture contents in the first layer likely to be encountered in use, i.e. 0.2 to 0.5 weight % and 2 to 2.8 weight %, such first layer being in face to face contact with a second layer of a clear polymer film or coating having a combination of performance properties desirable for these applications. Preferred second layers are biaxially stretched polyester and thermoset aliphatic polyurethane.

Abstract: An impact-resisting anti-lacerative window glass unit of laminate of a sandwich structure is disclosed, which comprises two exterior plate-like member made of a transparent organic polymer (A) and a transparent organic polymer (B) or a transparent inorganic material, respectively, and multilayer structure intermediate films made of at least two kinds of polymers (C). The multilayer structure intermediate films are interposed between two exterior plate-like members.

Abstract: A transparent polymeric laminate of plasticized polyvinyl butyral sheet chemically linked by urethane groups to a thermoset polyurethane layer formed as the reaction product of a cross-linkable mixture containing diisocyanate and polyether polyol containing primary or secondary hydroxyl groups and having a molecular weight between about 250 to about 8000.

Abstract: A laminated structure comprising a polyester film and a polyvinylbutyral sheet which are laminated through an adhesive layer obtained by curing a composition comprising an amino group-containing organosilicon compound of the following formula ##STR1## preferably its hydrolytic condensation product and a diamine of the formulaH.sub.2 N--R--NH.sub.2 (II)All symbols in these formulae are as defined in the specification. The structure is particularly useful in an automobile safety glass.

Abstract: An interlayer for a laminated glass, said interlayer being composed of a film or sheet of a thermoplastic resin, at least one surface of the film or sheet of a thermoplastic resin having numerous coarse raised and depressed portions and numerous fine raised and depressed portions existing on the surfaces of the coarse raised and depressed portions, the average distance between two adjacent coarse depressed or raised portions being about 2 to about 10 times the 10-point average roughness of the coarse raised and depressed portions measured in accordance with ISO-R468.

Abstract: Apparatus and a method for adhering a flexible soft polarizing film to a curved surface, such as the convex surface of a prescription eyeglass to be made into a polarizing lens is disclosed. The method involves glass-casting, and preformation of the film in a manner calculated to have a minimum hardening/drying effect. Air is excluded during lamination without the need for a vacuum and the attendant complications.

Abstract: A resin composition obtained by adding maleic anhydride to an unsaturated polyester resin composition comprising (I) an unsaturated polyester, (II) a styrene monomer, and (III) at least one polymerizable unsaturated compound, in limited amounts is low in viscosity, excellent in transparency and adhesiveness, able to prevent the generation of surface defects, and thus suitable for treating cathode-ray tubes.

Abstract: Method for the manufacturing of blindaged glass that detains the trajectory of projectiles shot by firearms, characterized by the formation of a transparent and limpid composition constituted by a rigid zone of impact, an intermediate elastic and adhesive zone and a mixed third zone of protection and antilacerative.The rigid zone is composed of a laminated glass; the intermediate zone is composed of a plurality of layers of PVB or of polyurethane; the final mixed zone is composed by a glass sheet laminated with a thin polycarbonate layer which is covered by a transparent film of antiabrasive material. These blindage glass can be curved so as to be used in automobiles.

Abstract: A method and apparatus of applying a polarizing film to a curved lens such as a polarizing prescription lens is disclosed. Mounting of the film on a specialized template allows for convenient drying and rewetting.

Abstract: A sandwich structure having an improved impact resistance comprises two outer plates and an intermediate layer interposed therebetween. The intermediate layer is comprised of plural films having a bonding force therebetween lower than that between intermediate layer and outer plate.

Abstract: A motor vehicle glass pane including a sheet of glass and in which in sequence from the side facing the inside of the vehicle in the fitted state includes a plastic-deformable lamination film and an adjoining splinter protection film, and a frame gasket extending around the peripheral edge of the sheet of glass, enclosing its narrow peripheral surfaces as well as an area of the side surfaces close to the peripheral edge on the one hand of the sheet of glass and on the other of the splinter protection film, whereby the lamination film is force-lockingly connected to the frame gasket.

Abstract: An anti-blurring optical member for window panes, reflecting mirrors, etc. for use in automobiles, ships and boats, buildings, and so forth, which secures good viewing field by the formation of hydrophilic regions and hydrophobic regions on a visible light transmitting substrate. Both regions are arranged in patterns with a size and interval corresponding to that of water drops.

Abstract: A coated plastic film 5 possessing high transmittance for visible light and high reflectance for heat radiation is disclosed which comprises a carrier film 1 of a transparent polymer and a reflection metal layer 3 embedded between two dielectric layers 2 and 4. The reflection metal layer 3 is formed from a metal selected from the group comprising silver, gold, and copper, whereas dielectric layers 2 and 4 are metal nitride layers.This coated plastic film may be coated on each side with a polyvinyl butyral film to form a plastic laminate which is itself a constituent of a laminated safety glass pane.

Abstract: An impact-resistant laminate has a front glass sheet which receives an impact such as a bullet, and a rear polycarbonate sheet. A thin polycarbonate sheet up to about 1 mm thick is adhered to the rear polycarbonate sheet, and carries a self-healing polyurethane coating.

Abstract: A process for forming a multi-layer ceramic substrate. The process includes the steps of obtaining a plurality of ceramic sheets in the green state, depositing a conductive metal pattern on at least one of the green ceramic sheets, heating the at least one green ceramic sheet so as to soften it, pressing the conductive metal pattern into the at least one green ceramic sheet, stacking and laminating the green ceramic sheets so as to form a substrate and then sintering the substrate. There is also disclosed a multi-layer ceramic substrate having a conductive metal pattern pressed into the at least one green ceramic sheet.

Abstract: Article comprising a substrate bearing an optically clear, non-crosslinked coating formed from a blend comprising at least one polymer containing carbonylamido functional groups and at least one hydrophobic polymer substantially free of acidic functional groups.The coating is useful for promoting adhesion, increasing the hydrophilicity of the surface of the article, and increasing receptivity of the substrate for aqueous based inks.

Abstract: A protective superposed layer composite glass structure includes at least one glass plate, a polyurethane film, and a polyvinyl butyral sheet between the glass plate and the polyurethane film for attaching the polyurethane sheet to the glass plate. A polycarbonate plate is superposed against the polyurethane film. Alternatively, a polyester sheet can be superposed against the polyurethane film. A process for making a superposed layer composite glass structure includes surrounding the various layer elements with bands formed of a thermo-retractable material, calendering the layered elements surrounded by the bands at a temperature approximately in the range of 120.degree. to 200.degree. C. and subsequently subjecting the layered elements surrounded by the bands to the action of an autoclave at a temperature approximately in the range of 120.degree. to 200.degree. C. under a pressure approximately in the range of 10 to 15 bars.

Abstract: A fire-resistant thermoplastic composition comprising polyvinyl butyral resin and a compatible mixture in an amount sufficient to provide fire-resistant properties to such composition which includes (a) a plasticizer blend of a char-forming component, such as an organic phosphate, and an oxygen sequestering agent, such as an organic phosphite, wherein the char-forming component is the major constituent; (b) a nucleating agent such as fumed silica for dispersing the fire decomposition products of the composition; and (c) a heat reactive bonding resin.

Abstract: Safety or impact resistant laminates which avoid the application of heat and excessive pressure in their construction comprising a plurality of laminae, at least one interlayer interposed between any two of the laminae, and a sufficient number of adhesive layers, at least one a contact or pressure sensitive adhesive, to bond all the laminae and interlayers.

Abstract: An interlayer of polyvinyl butyral resin containing a compatible mixture of additives dispersed therein providing fire-resistant properties thereto, said mixture comprising a plasticizer blend of (a) a char-forming component, such as an organic phosphate, and an oxygen sequestering agent, such as an organic phosphite, wherein the char-forming agent is the major constituent; (b) a nucleating agent such as fumed silica for dispersing the fire decomposition products of the interlayer; and (c) a heat reactive bonding resin such as silicone resin.

Abstract: Reduction in the adhesion to glass of thermoplastic, plasticized polyvinylbutyral molding compositions, in particular sheeting, by the addition of a metal salt and/or metal chelate of an enolizable .beta.-diketone, or mixtures of these compounds, as an non-stick agent, preferably in amounts of 0.003 to 0.3% by weight, relative to the plasticized polyvinylbutyral. It is preferable to employ the non-stick agent in the form of a solution in the plasticizer. The use of the sheeting having an adhesion to glass reduced in accordance with the invention as a laminating layer for the production of glass laminates.

Abstract: Thermoplastic laminae are given scratch and mar resistance on an external face as well as protection from incompatible additives of adjacent adhesive layers on an internal face by a single cross-linked protective coating.

Abstract: A composite facing slab comprises a sheet of natural stone, such as marble, and a protective layer constituted by a sheet of transparent glass. The latter is fixed to the face of the stone sheet intended to remain visible with the interpositioning of an interlayer of transparent thermoplastics material which can adhere to both the sheets and fills the surface defects (pores, cavities, cracks and the like) of the stone sheet.

Abstract: Reduction in the adhesion to glass of thermoplastic, plasticized polyvinylbutyral molding compositions, in particular sheeting, by adding the magnesium salt of sulfonic acids or sulfuric acid half-esters or mixtures of these compounds as an non-stick agent, preferably in amounts of 0.003 to 0.3% by weight, relative to the plasticized polyvinylbutyral. The non-stick agent is preferably employed in the form of a solution in the plasticizer. The use of the sheeting having an adhesion to glass reduced in accordance with the invention as the laminating layer for the production of glass laminates.

Abstract: A security glass which possesses substantial resistance to penetration by impact by a heavy implement and which exhibits only a small amount of spall formation is a glass flexible bonding material, e.g. polyvinylbutyral, laminate in which the layer of flexible bonding material positioned other than at the forwardmost flexible bonding material layer position possesses increased thickness. The rearmost glass layer is generally relatively thin and is preferably chemically toughened.

Abstract: In a polyvinyl butyral (PVB) sheet plasticized with a multiester of an alcohol having 2 to 4 hydroxyl groups and a C.sub.16 to C.sub.20 unsaturated fatty acid having a hydroxyl group attached to the acid molecule, which sheet does not craze polycarbonate or polyacrylate when in contact therewith, the addition of a synergistically effective amount of a monoester of a glycol and such C.sub.16 to C.sub.20 acid improves the low temperature penetration resistance and adhesion properties of such sheet without significant loss in its resistance to stress cracking polycarbonate or polyacrylate in a laminated glass assembly.

Abstract: A plasticizer blend for polyvinyl butyral (PVB) comprising a monoester of a glycol and a C.sub.16 to C.sub.20 unsaturated fatty acid having a hydroxyl group attached to the acid molecule and a multiester of an alcohol having 2 to 4 hydroxyl groups and said unsaturated fatty acid, the monoester being present in the blend on a weight basis in an amount equal to or greater than the multiester. The low temperature penetration resistance and adhesion properties of PVB sheet plasticized with such blend is improved without significant loss in its resistance to stress cracking polycarbonate or polyacrylate in contact therewith in a laminated glass assembly.

Abstract: A plastic adhesive layer used as an insert layer in laminated glasses and the laminated glasses containing the insert layer, the adhesive layer comprising a polyfunctional polyol component and a polyfunctional isocyanate component, wherein the polyol component is present in considerable excess and the numerical ratio of the isocyanate groups to the hydroxyl groups is between 0.2 and 0.6. The adhesive layer is particularly useful in soundproofing glasses and in safety glasses such as bulletproofing glasses.