Refractory Metal Salt Or Oxide Patents (Class 428/472)
  • Patent number: 7981520
    Abstract: A coating suitable for use as protective oxide-forming coatings on Nb-based substrates, and particularly monolithic niobium-based alloys, exposed to high temperatures and oxidative environments. The coating contains aluminum, may further contain silicon, and optionally contains niobium, titanium, hafnium, and/or chromium, which in combination form one or more intermetallic phases that promote the formation of a slow-growing oxide scale. The intermetallic phases may be M(Al,Si)3, M5(Al,Si)3, and/or M3Si5Al2 where M is niobium, titanium, hafnium, and/or chromium.
    Type: Grant
    Filed: September 26, 2008
    Date of Patent: July 19, 2011
    Assignee: General Electric Company
    Inventors: Bernard Patrick Bewlay, Pazhayannur Ramanathan Subramanian, Joseph David Rigney, Richard DiDomizio, Voramon Supatarawanich Dheeradhada
  • Patent number: 7981516
    Abstract: The invention relates to a transparent substrate provided with a thin-film multilayer comprising at least one functional metal layer, especially a silver-based layer, having reflection properties in the infrared and/or in the solar radiation range, at least one metal barrier layer in contact with the functional layer and at least one upper dielectric layer, characterized in that at least one barrier layer is based on zirconium and in that the upper dielectric layer comprises at least one ZnO-based layer in contact with the functional layer or with the barrier layer.
    Type: Grant
    Filed: August 19, 2004
    Date of Patent: July 19, 2011
    Assignee: Saint-Gobain Glass France
    Inventors: Laurent Labrousse, Nicolas Nadaud, Eric Petit Jean
  • Publication number: 20110171463
    Abstract: A wind power plant is provided including at least one component with a surface. The surface is coated at least partially with a hard material layer, preferably a vanadium-based hard material layer. Further, a wind park and a method of improving a characteristic of a surface of a component of a wind power plant are provided.
    Type: Application
    Filed: January 10, 2011
    Publication date: July 14, 2011
    Inventors: Andreas Christian Hohle, Christian Hohmann, Claudia Kummer, Helmut Kölpin, Ying Li, Brice Tchemtchoua
  • Patent number: 7968205
    Abstract: A corrosion resistant member to be exposed to a halogen-containing gas atmosphere or a halogen-containing gas plasma atmosphere, comprising a substrate and a plurality of layers deposited thereon including a layer of rare earth fluoride providing the outermost surface and a layer of rare earth oxide having a porosity of less than 5% underlying the rare earth fluoride layer.
    Type: Grant
    Filed: October 19, 2006
    Date of Patent: June 28, 2011
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Hajime Nakano, Toshihiko Tsukatani, Takao Maeda
  • Publication number: 20110151276
    Abstract: The invention relates to a coated product comprising a strip substrate comprising a conductive alloy layer comprising silver and indium provided on the surface of the substrate. The conductive alloy layer has good electrical properties and does not easily react with sulphur in the ambient air. The invention further relates to a method for producing a coated product, comprising the steps of: providing a strip substrate; ion-etching of the substrate; depositing a conductive alloy layer comprising silver and indium on the substrate. The invention also relates to a product for electrical use comprising the coated product.
    Type: Application
    Filed: July 3, 2009
    Publication date: June 23, 2011
    Applicant: Sandvik Intellectual Property AB
    Inventors: Sara Wiklund, Mikael Schuisky
  • Publication number: 20110132645
    Abstract: Embodiments described include a non-polymeric voltage switchable dielectric (VSD) material comprising substantially of a grain structure formed from only a single compound, processes for making same, and applications for using such non-polymeric VSD materials.
    Type: Application
    Filed: November 24, 2010
    Publication date: June 9, 2011
    Inventors: Ning Shi, Robert Fleming, Junjun Wu, Lex Kosowsky
  • Patent number: 7955707
    Abstract: The invention is directed to a material and method for obtaining a ceramic abradable system for high temperature applications. High purity partially stabilized zirconia and/or hafnia base material has higher sintering resistance compared to conventional 6-9 weight percent yttria stabilized zirconia systems. The benefits of these systems are higher service lifetime and low thermal conductivity to achieve high operating temperatures. System includes a superalloy substrate, oxidation resistant bond coat and a thick ceramic abradable top coat. Total coating thickness is about 0.5-5 mm. In some applications an intermediate layer of high purity partially stabilized zirconia or a partially stabilized YSZ/MCrAlY cermet is applied over the oxidation resistant bond coat. In other applications an abradable system is applied on top of a grid. Additional benefits should be reduced blade wear at high operating conditions.
    Type: Grant
    Filed: September 13, 2006
    Date of Patent: June 7, 2011
    Assignee: Sulzer Metco (US), Inc.
    Inventors: Liangde Xie, Mitchell Dorfman, Richard Schmid, Jacobus C. Doesburg, Matthew Gold
  • Patent number: 7955709
    Abstract: An organic light emitting display device and a method of fabricating the same, in which a resonance effect is suppressed and transmittance is substantially the same in a wavelength band of visible light. The organic light emitting display device includes: a substrate; a first electrode disposed on the substrate and including a reflection layer; an organic layer disposed on the first electrode and including a white emission layer; a second electrode disposed on the organic layer; a transmittance controlled layer disposed on the second electrode; and a metal layer disposed on the transmittance controlled layer.
    Type: Grant
    Filed: November 8, 2007
    Date of Patent: June 7, 2011
    Assignee: Samsung Mobile Display Co., Ltd.
    Inventors: Hee-Seong Jeong, Sam-Il Kho, Byeong-Wook Yoo, Seong-Taek Lee, Jun-Sik Oh, Gun-Shik Kim
  • Patent number: 7955708
    Abstract: The invention is directed to high purity zirconia-based and/or hafnia-based materials and coatings for high temperature cycling applications. Thermal barrier coatings made from the invention high purity material was found to have significantly improved sintering resistance relative to coatings made from current materials of lower purity. The invention materials are high purity zirconia and/or hafnia partially or fully stabilized by one or any combinations of the following stabilizers: yttria, ytterbia, scandia, lanthanide oxide and actinide oxide. Limits for impurity oxide, oxides other than the intended ingredients, that lead to significantly improved sintering resistance were discovered. High purity coating structures suitable for high temperature cycling applications and for application onto a substrate were provided. In one structure, the coating comprises a ceramic matrix, porosity and micro cracks. In another structure, the coating comprises a ceramic matrix, porosity, macro cracks and micro cracks.
    Type: Grant
    Filed: September 13, 2006
    Date of Patent: June 7, 2011
    Assignee: Sulzer Metco (US), Inc.
    Inventors: Jacobus C. Doesburg, Liangde Xie, Richard Schmid, Matthew Gold
  • Patent number: 7955706
    Abstract: A cermet armor material for highly effective ballistic performance which is comprised of a layer of base metal in which is deposited a layer or layers of ceramic and a compatible metal such that the deposited metal in combination with the base metal forms a continuous matrix around the ceramic particles. The body has a structure which is continuously graded from a highest ceramic content at the outer surface (strike face) decreasing to zero within the base substrate, and contained no abrupt interfaces.
    Type: Grant
    Filed: June 28, 2007
    Date of Patent: June 7, 2011
    Assignee: Materials & Electrochemical Research Corp.
    Inventors: James C. Withers, Roger S. Storm, Vladimir Shapovalov, Raouf Loutfy
  • Publication number: 20110127167
    Abstract: The invention relates to a method of making a nanotubular titania substrate having a titanium dioxide surface comprised of a plurality of vertically oriented titanium dioxide nanotubes containing oxygen vacancies. The method generally comprises the steps of anodizing a titanium metal substrate in an acidified fluoride electrolyte under conditions sufficient to form a titanium oxide surface comprised of self-ordered titanium oxide nanotubes, dispersing gold nanoparticles onto the titanium oxide surface, annealing the titanium oxide surface with the gold nanoparticles thereon in a non-oxidizing atmosphere, and depositing carbon onto the annealed titanium oxide surface. The invention also relates to a hybrid gold/carbon electrode formed by the method.
    Type: Application
    Filed: December 13, 2006
    Publication date: June 2, 2011
    Applicant: UNIVERSITY OF NEVADA, RENO
    Inventors: Manoranjan Misra, Krishnan Selva Raja, Susanta Kumar Mohapatra, Vishal K. Mahajan
  • Patent number: 7951473
    Abstract: The invention discloses optical coatings with improved durability, the coating comprising a durability enhancing layer, a nucleation layer and an infrared reflecting layer. The invention also discloses methods of making thin film layers having enhanced durability.
    Type: Grant
    Filed: November 9, 2007
    Date of Patent: May 31, 2011
    Assignee: AGC Flat Glass North America, Inc.
    Inventor: Peter Maschwitz
  • Patent number: 7947363
    Abstract: A coated article that includes a substrate and a wear-resistant coating scheme. The coated article may be a cutting insert shown to improve performance in chip-forming material removal operations or a wear-resistant component used in chipless forming operations. The wear-resistant coating scheme has an underlayer and top layer containing aluminum, chromium, and nitrogen. The coating scheme also includes a mediate multi-periodicity nanolayer coating scheme containing titanium, aluminum, chromium and nitrogen. The mediate multi-periodicity nanolayer coating scheme includes a plurality of sets of alternating layer arrangements. Each one of the alternating layer arrangements has a base layer comprising titanium, aluminum and nitrogen and a nanolayer region having a plurality of sets of alternating nanolayers. Each set of alternating nanolayers has one nanolayer having aluminum, chromium, titanium and nitrogen and another nanolayer having aluminum, chromium, titanium and nitrogen.
    Type: Grant
    Filed: December 14, 2007
    Date of Patent: May 24, 2011
    Assignees: Kennametal Inc., Oerlikon Trading Ltd.
    Inventors: Fengting Xu, Wangyang Ni, Ronald M. Penich, Yixiong Liu, Volker-Hermann Derflinger, Dennis T. Quinto, Charles E. Bauer, Qian Ding
  • Patent number: 7939172
    Abstract: A low friction top coat over a multilayer metal/ceramic bondcoat provides a conductive substrate, such as a rotary tool, with wear resistance and corrosion resistance. The top coat further provides low friction and anti-stickiness as well as high compressive stress. The high compressive stress provided by the top coat protects against degradation of the tool due to abrasion and torsional and cyclic fatigue. Substrate temperature is strictly controlled during the coating process to preserve the bulk properties of the substrate and the coating. The described coating process is particularly useful when applied to shape memory alloys.
    Type: Grant
    Filed: May 17, 2007
    Date of Patent: May 10, 2011
    Assignee: G & H Technologies, LLC
    Inventors: Vladimir Gorokhovsky, Brad B. Heckerman, Yuhang Cheng
  • Publication number: 20110103961
    Abstract: A method of producing an oxide dispersion strengthened nickel-base superalloy, comprising introducing an oxide dispersoid material into a plasma gun of a plasma spray apparatus, where it is sublimed and turned to vapour; and introducing a nickel-base superalloy material into the plasma spray apparatus at a cooler location, downstream of the plasma gun, such that the oxide dispersoid material condenses on the superalloy material to produce the oxide dispersion strengthened nickel-base superalloy.
    Type: Application
    Filed: September 27, 2010
    Publication date: May 5, 2011
    Applicant: ROLLS-ROYCE PLC
    Inventors: Neil E. GLOVER, Catherine M.F. RAE, Mark C. HARDY, Robert J. MITCHELL
  • Patent number: 7935423
    Abstract: The subject of the invention is a transparent substrate, especially a glass substrate, provided with a thin-film multilayer acting on solar radiation, the multilayer being deposited by magnetron sputtering, characterized in that it includes at least a lubricating film of high optical index n, this lubricating film being associated with at least one sublayer, which is based on silicon nitride or oxynitride or carbonitride, or based on aluminum and/or zirconium nitride or oxynitride or carbonitride, or a mixture of at least two of these compounds (mixed Si—Al or Si—Zr nitrides or oxynitrides or carbonitrides).
    Type: Grant
    Filed: July 18, 2006
    Date of Patent: May 3, 2011
    Assignee: Saint-Gobain Glass France
    Inventor: Sylvain Belliot
  • Patent number: 7927709
    Abstract: A wear-resistant coating, in particular an erosion-resistant coating for a component that is exposed to fluidic loads, is disclosed. The wear-resistant coating has one or more multilayer systems applied repeatedly to the surface to be coated, where each of the applied multilayer systems has at least four different layers. A first layer of each multilayer system facing the surface to be coated is made of a metallic material adapted to the composition of the component surface to be coated. A second layer applied to the first layer of each multilayer system is made of a metal alloy material adapted to the composition of the component surface to be coated. A third layer applied to the second layer of each multilayer system is made of a gradated metal-ceramic material and a fourth layer applied to the third layer of each multilayer system is made of a nanostructured ceramic material.
    Type: Grant
    Filed: December 22, 2004
    Date of Patent: April 19, 2011
    Assignee: MTU Aero Engines GmbH
    Inventors: Wolfgang Eichmann, Rolf Gerstner, Karl-Heinz Manier, Markus Uecker, Thomas Uihlein
  • Patent number: 7923101
    Abstract: The present invention relates to a coated cutting tool insert and a texture-hardened ?-Al2O3 layer to be used in metal machining. The alumina layer is characterized by the improved toughness and it adheres to the substrate covering all functional parts thereof. The coating is composed of one or more refractory layers of which at least one layer is a texture-hardened ?-Al2O3 having a thickness ranging from 2 to 20 ?m being composed of columnar grains with a length/width ratio of 2 to 12. The ?-Al2O3 exhibits a strong (0006) diffraction peak. The improved wear resistance and toughness can be obtained when the texture coefficient (TC) for the (0006) reflection is larger than 1.33 ln h+2, where h is the ?-Al2O3 layer thickness and when the surface of the ?-Al2O3 layer is wet-blasted to an Ra-value <1 ?m. The alumina layer with a strong (0001) texture is applied on Binder phase enriched cemented carbide substrates. This combination contributes to enhanced wear resistance and toughness.
    Type: Grant
    Filed: January 29, 2008
    Date of Patent: April 12, 2011
    Assignee: Seco Tools AB
    Inventor: Sakari Ruppi
  • Patent number: 7923130
    Abstract: A surface-coated cutting tool according to the present invention including a substrate and a coating film formed on the substrate is characterized in that the coating film includes a composite super multi-layer film obtained by alternately stacking one or more first super multi-layer film and one or more second super multi-layer film, the first super multi-layer film above is formed by alternately stacking one or more A1 layer and one or more B layer, the second super multi-layer film above is formed by alternately stacking one or more A2 layer and one or more C layer, each of the A1 layer above and the A2 layer above is composed of any of TiN, TiCN, TiAlN, and TiAlCN, the B layer above is composed of TiSiN or TiSiCN, and the C layer above is composed of AlCrN or AlCrCN.
    Type: Grant
    Filed: May 23, 2008
    Date of Patent: April 12, 2011
    Assignee: Sumitomo Electric Hardmetal Corp.
    Inventors: Akihiko Shibata, Haruyo Fukui, Shinya Imamura, Akira Kobayashi
  • Publication number: 20110076480
    Abstract: A coated article suitable for use at elevated temperature includes a metal substrate and a coating on the substrate. The coating includes a corrosion resistant particulate component having an average coefficient of thermal expansion (CTE) greater than alumina at 1200° F. (649° C.) dispersed in a binder matrix. An aspect ratio of at least a portion of the corrosion resistant particulate component is greater than about 2:1. The binder matrix includes a silicon-containing material and/or a phosphate-containing material.
    Type: Application
    Filed: September 30, 2009
    Publication date: March 31, 2011
    Inventors: Andrew Jay Skoog, Brian Thomas Hazel, Jane Ann Murphy
  • Publication number: 20110076505
    Abstract: A metallic material is provided that is superior to an iron-based metallic material in all of adhesion, heat resistance, electrical conductivity, and corrosion resistance, and a method of manufacturing the metallic material is also provided. A metallic material is provided that includes an iron-based metallic material and an oxide layer formed on the surface of the iron-based metallic material. The oxide layer includes Fe and at least one kind of metal (A) selected from a group consisting of Zr, Ti, and Hf. There is also provided a method of manufacturing the metallic material.
    Type: Application
    Filed: August 26, 2010
    Publication date: March 31, 2011
    Applicant: Henkel AG & Co., KGaA
    Inventors: Hitoshi Ishii, Yasuhiko Nagashima, Ryosuke Kawagoshi
  • Patent number: 7910221
    Abstract: Methods and compositions are disclosed for coating a biocompatible medical implant with a surface layer having antioxidant activity. In various embodiments, a surface layer described herein destroys the oxidative activity of a reactive oxygen species (ROS) upon contact. An ROS can be, for example, an ROS generated by neutrophils in vivo. In various embodiments, a surface layer comprises a titanium oxide layer that can comprise a rutile, an anatase or a perovskite crystal structure, and can include defects comprising Ti(III). In some embodiments, the oxide layer can further comprise a dopant such as niobium. In some embodiments, methods for forming a surface layer on a biocompatible medical implant having antioxidant activity are disclosed.
    Type: Grant
    Filed: February 8, 2007
    Date of Patent: March 22, 2011
    Assignee: La Jolla Bioengineering Institute
    Inventors: Ramiro Contreras, Herman Sahlin, John A. Frangos
  • Patent number: 7910219
    Abstract: A cermet armor material for highly effective ballistic performance which is comprised of a layer of base metal in which is deposited a layer or layers of ceramic and a compatible metal such that the deposited metal in combination with the base metal forms a continuous matrix around the ceramic particles. The body has a structure which is continuously graded from a highest ceramic content at the outer surface (strike face) decreasing to zero within the base substrate, and contained no abrupt interfaces.
    Type: Grant
    Filed: June 28, 2007
    Date of Patent: March 22, 2011
    Assignee: Materials & Electrochemical Research Corp.
    Inventors: James C. Withers, Roger S. Storm, Vladimir Shapovalov, Loutfy Raouf
  • Patent number: 7910220
    Abstract: Apparatus suited for removing carbon dioxide from gases are disclosed. The apparatus may employ bodies having a photocatalytic film. Associated methods and compositions are also disclosed.
    Type: Grant
    Filed: July 25, 2007
    Date of Patent: March 22, 2011
    Assignee: Alcoa Inc.
    Inventors: Jean Ann Skiles, Paula L. Kolek, Carroll D. Davis, Albert L. Askin, Robert J. Speer, Weizong Xu, Lori A. Barrage, Luis H. Espinoza-Nava, Verne Bergstrom
  • Publication number: 20110065973
    Abstract: The invention is directed to effective means for joining materials having dissimilar coefficients of thermal expansion, such as advanced ceramics with metallic compounds. Moreover, the present invention relates to furnace tubes and methods of fabricating a joint between two different materials, which is compositionally graded to provide a substantially graded coefficient of thermal expansion between the joint materials.
    Type: Application
    Filed: September 11, 2009
    Publication date: March 17, 2011
    Applicant: STONE & WEBSTER PROCESS TECHNOLOGY, INC
    Inventors: John Andrew Fernie, Martyn David Roberts, Yong Wang, Narayanan Rajesh Kavilveedu
  • Publication number: 20110059312
    Abstract: The present invention relates to a bioactive material and to a method of producing a bioactive material which is suitable for use as an implant or for use as a bone substitute for repairing bone.
    Type: Application
    Filed: August 19, 2008
    Publication date: March 10, 2011
    Inventors: Graeme ... Howling, Paul Gunning
  • Publication number: 20110056163
    Abstract: A system for fire protection of a structural element, which system comprising one or more fire protection boards attached to the said structural element, and one or more hard plates attached to an outer surface of the fire protection boards by means of a non-combustable adhesive, said hard plates having a harder surface than the fire protection board. A method for protecting a structural element is also disclosed.
    Type: Application
    Filed: March 3, 2009
    Publication date: March 10, 2011
    Inventor: Peter Kure
  • Patent number: 7901777
    Abstract: A coated article comprising a substrate having a plastic surface and adhered thereto an organometallic film in which the metal has f electron orbitals or is niobium is disclosed. Also disclosed are methods for applying organometallic films to substrates and the organometallic films themselves.
    Type: Grant
    Filed: April 23, 2010
    Date of Patent: March 8, 2011
    Assignee: Aculon, Inc.
    Inventor: Eric L. Hanson
  • Patent number: 7897247
    Abstract: The present invention discloses coated cutting tool inserts particularly useful for turning of nodular cast iron preferably at high speeds, comprising a cemented carbide substrate comprising from about 5 to about 9 wt-% Co and from about 1 to about 5 wt % cubic carbides and balance WC of 86-94 wt-%, and a coating comprising a first layer of TiCxNyOz with equiaxed grains, a layer of TiCxNyOz with a thickness of less than about 10 to about 15 ?m with columnar grains, a layer of TiCxNyOz with a thickness of from about 0.1 to about 2 ?m and with equiaxed or plate-like grains, a layer of ?-Al2O3 with thickness from about 3 to about 8 ?m, an outer layer of a multilayered structure of TiN+TiC with TiC being the outermost layer and a total thickness of from about 0.5 to about 2 ?m and wherein the outer coating layer has been removed in the edge line and on the rake face so that the ?-Al2O3 layer is on top along the cutting edge line and on the rake face and the outer TiC layer is the top layer on the flank face.
    Type: Grant
    Filed: November 20, 2006
    Date of Patent: March 1, 2011
    Assignee: Sandvik Intellectual Property AB
    Inventors: Per Mårtensson, Per Gustafson
  • Patent number: 7897253
    Abstract: The invention relates to a piece comprised in part or in full of a pigmented ceramic in which the pigment is comprised of nanoparticles based on a metal from column IB of the periodic table of the elements or of an alkaline metal, or an alloy of both, coated with a layer of silica, the silica being crystalline silica, particularly cristobalite or tridymite. The ceramic is preferably zirconia or alumina. The nanoparticle silica is crystallized, for example, by a thermal treatment in air or under inert gas at temperatures of between 900° C. and 1400° C. The piece is made by sintering a nanoparticle/ceramic mixture in air or under inert gas at temperatures of between 900° C. and 1250° C.
    Type: Grant
    Filed: July 31, 2007
    Date of Patent: March 1, 2011
    Assignee: Rolex S.A.
    Inventors: Alke Fink-Petri, Heinrich Hofmann
  • Patent number: 7892650
    Abstract: A magnesium alloy member includes a member main body formed of a magnesium alloy containing aluminum, and an anodic oxidation coating covering at least a portion of the member main body. The anodic oxidation coating includes a porous first layer and a second layer located between the first layer and the member main body and having a higher aluminum content than that of the first layer. The ratio of the thickness of the second layer with respect to the thickness of the anodic oxidation preferably is about 5% to about 20%.
    Type: Grant
    Filed: June 11, 2008
    Date of Patent: February 22, 2011
    Assignee: Yamaha Hatsudoki Kabushiki Kaisha
    Inventors: Takaharu Suzuki, Junichi Inami, Toshikatsu Koike
  • Patent number: 7891669
    Abstract: The invention relates to a piston ring for internal combustion engines, the piston ring comprises a steel or cast iron base material with a coating of chromium nitride deposited by a physical vapor deposition process on a sliding surface of the piston ring, wherein the coating is composed of a columnar crystal structure of CrN with the following features: (a) an oxygen content in solid solution of 0.5 to 2.5 wt %; (b) a content of uniformly dispersed micro-pores of less than 10% in volume of the coating; and (c) an X-ray diffraction intensity ratio of (111) planes to (200) planes parallel to the surface in the range of 0.80 to 1.20.
    Type: Grant
    Filed: June 16, 2007
    Date of Patent: February 22, 2011
    Assignees: Mahle International GmbH, Mahle Metal Leve S.A.
    Inventors: Juliano Avelar Araujo, Gisela Ablas Marques, Jose Valentim Lima Sarabanda, Robert Richard Banfield
  • Patent number: 7887923
    Abstract: Plasma-sprayed layers of aluminium oxide on a substrate are produced by using a pyrogenically produced aluminium oxide, for example selected from the group consisting of borosilicate and steel, as starting powder.
    Type: Grant
    Filed: March 9, 2006
    Date of Patent: February 15, 2011
    Assignee: Evonik Degussa GmbH
    Inventors: Yi Deng, Monika Oswald, Klaus Deller, Rolf Clasen, Georg Fehringer
  • Patent number: 7887929
    Abstract: A method of manufacturing a gas turbine engine component includes the steps of forming a ceramic workpiece having oriented ceramic reinforcement, and severing the ceramic workpiece to produce a ceramic member having a desired orientation of the ceramic reinforcement. The ceramic member is then attached to a turbine engine component as a thermal barrier layer for the turbine engine component.
    Type: Grant
    Filed: August 28, 2007
    Date of Patent: February 15, 2011
    Assignee: United Technologies Corporation
    Inventors: Christopher W. Strock, Susan M. Tholen
  • Publication number: 20110033722
    Abstract: Provided is a wood cutting tool with improved wear resistance and corrosion resistance. A hard fundamental layer (18) of chromium nitride (CrN) is subjected to PVD to be coated on a rake face (16) of a substrate (12) formed of a cemented carbide alloy or a tool steel. The hard fundamental layer (18) has a five-layer structure having a first layer (18a) to a fifth layer (18e) disposed in order from the substrate (12) side. A hard main layer (20) of chromium oxide (Cr2O3) is coated on the outer surface of the fifth layer (18e) of the hard fundamental layer (18). The hard main layer (20), like the hard fundamental layer (18), is formed by PVD. The hard fundamental layer (18) is coated with the hard main layer (20) to suppress corrosion, thereby improving the wear resistance and corrosion resistance of a cemented carbide replaceable knife (10).
    Type: Application
    Filed: April 22, 2009
    Publication date: February 10, 2011
    Inventors: Toru Minami, Satoru Nishio
  • Patent number: 7883776
    Abstract: An optical coating on a transparent substrate is provided with a temporary layer of carbon as protection during manufacturing against scratches and corrosive environments. When the optical coating and/or substrate are tempered in an atmosphere reactive to carbon, such as air, the layer of carbon is removed as a carbon-containing gas. For an optical coating with a brittle, glassy, outermost layer furthest from the substrate, additional protection is provided by a scratch propagation blocker layer between the outermost layer and the carbon protective layer.
    Type: Grant
    Filed: May 29, 2007
    Date of Patent: February 8, 2011
    Assignee: AGC Flat Glass North America, Inc.
    Inventors: Kyle W. Hukari, Peter A. Maschwitz, Rand D. Dannenberg
  • Patent number: 7879456
    Abstract: Methods for bonding adherent phosphorous-containing coating layers to oxide surfaces on substrates wherein the substrates with oxide surfaces are selected from: (a) oxidized iron, titanium, silicon, tin and vanadium; (b) indium tin oxide; and (c) substrates with oxide layers deposited thereon, wherein the substrates on which oxide layers are deposited are selected from ceramics, semiconductors, metals, plastics and glass, and the method contacts the oxide surface with a carrier conveying an organo-phosphonic acid coating composition and heats the oxide surface and carrier at a sufficient temperature while maintaining contact for a sufficient time to bond a layer of the organophosphonic acid to the oxide surface. Coated articles prepared by the inventive method are also disclosed.
    Type: Grant
    Filed: July 8, 2008
    Date of Patent: February 1, 2011
    Inventors: Jeffrey Schwartz, Michael J. Avaltroni, Michael P. Danahy, Brett M. Silverman
  • Patent number: 7879400
    Abstract: There is provided a substrate processing apparatus equipped with a metallic component, with at least a part of its metallic surface exposed to an inside of a processing chamber and subjected to baking treatment at a pressure less than atmospheric pressure. As a result of this baking treatment, a film which does not react with various types of reactive gases, and which can block the out diffusion of metals, is formed on the surface of the above-mentioned metallic component.
    Type: Grant
    Filed: October 10, 2007
    Date of Patent: February 1, 2011
    Assignee: Hitachi Kokusal Electric Inc.
    Inventors: Takahiro Maeda, Kiyohiko Maeda, Takashi Ozaki
  • Patent number: 7879443
    Abstract: A hard coating layer system comprises at least a main layer (3) on a surface of a substrate (1), a buried layer (4) and an outer surface layer (5), wherein the surface layer (5) comprises AlCrZ, where Z stands for N, C, B, CN, BN, CBN, NO, CO, BO, CNO, BNO, or CBNO In such innovative coating triplex system and corresponding coated tools and components the buried comprises any one of the following materials or their combinations: a metal nitride, carbide or carbonitride a metal silicon nitride, carbide, or carbonitride, wherein the metal is at least one transition metal of the IVB, VB or VIB group or a multilayer of the materials or a material or a combination or a multilayer of the materials comprising at least one metal or carbon, preferably a diamond like carbon layer. The main layer comprises a nitride, carbide or carbonitride or a multilayer of nitride, carbide or carbonitride material.
    Type: Grant
    Filed: February 7, 2006
    Date of Patent: February 1, 2011
    Assignee: OC Oerlikon Trading AG, Truebbach
    Inventor: Jose Endrino
  • Patent number: 7879448
    Abstract: A coated article is provided that may be heat treated in certain example embodiments. A coating of the coated article includes a zinc oxide inclusive layer located over and contacting a contact layer that is in contact with an infrared (IR) reflecting layer of a material such as silver. It has been found that the use of such a zinc oxide inclusive layer results in improved thermal stability upon heat treatment, increased visible transmission, and/or lower sheet resistance (Rs).
    Type: Grant
    Filed: March 11, 2004
    Date of Patent: February 1, 2011
    Assignees: Guardian Industires Corp., Centre Luxembourgeois de Recherches pour le Verre et la Ceramique S.A. (C.R.V.C.)
    Inventors: Anton Dietrich, Philip J. Lingle, Jens-Peter Muller, Jean-Marc Lemmer
  • Publication number: 20110020638
    Abstract: The present invention relates to essentially transparent glazings comprising a system of films deposited under vacuum by magnetron, and having antisun and/or low-emission properties, comprising as protective surface layer a layer based on titanium oxide and on at least one other metal oxide of high hardness from the group comprising: ZrO2, SiO2, Cr2O3. The glazings according to the invention are of “matchable” type.
    Type: Application
    Filed: March 20, 2009
    Publication date: January 27, 2011
    Applicant: AGC Glass Europe
    Inventor: Gaetan Di Stefano
  • Patent number: 7875360
    Abstract: A flexible metallic strip product including a ferritic chromium strip steel material having a coating of an electrically insulating layer of zirconia stabilized with yttrium, said coating being intended to receive a second coating of an electrically conducting layers is disclosed. This coating is very efficient as an electrically insulating layer in flexible solar cells and solid state thin film batteries because it has practically the same thermal expansion coefficient as the steel substrate.
    Type: Grant
    Filed: December 3, 2004
    Date of Patent: January 25, 2011
    Assignee: Sandvik Intellectual Property AB
    Inventor: Mikael Schuisky
  • Publication number: 20110008641
    Abstract: The present invention relates to essentially transparent glazings comprising a system of films deposited under vacuum by magnetron, and having antisun and/or low-emission properties, comprising as protective surface layer a layer based on titanium oxide and on at least one other metal oxide of high hardness from the group comprising: ZrO2, SiO2, Cr2O3. The glazings according to the invention are of a nature to withstand a heat treatment at 550° C. for 5 minutes without giving rise to the presence of optical effects, especially of coloration or iridescence. These glazings are termed toughenable.
    Type: Application
    Filed: March 20, 2009
    Publication date: January 13, 2011
    Applicant: AGC GLASS EUROPE
    Inventor: Gaetan Di Stefano
  • Patent number: 7867633
    Abstract: The invention provides coatings to achieve the best accommodation of chemical, physical, and mechanical properties desired in high performance and reliable glass molding and forming tools. The substrate material can be any ordinary die or tool material such as cast iron, stainless steel, platinum, tungsten carbide and silicon. A simple coating architecture consisting of a titanium adhesion layer and a Ni—Al—N or Ti—B—C—N working layer is provided. A NiAl working layer can meet the requirements of wear resistance in which abrasive and/or erosive wear is relatively low, while a Ti—B—C—N working layer is sufficient for processes operating at relatively low temperature or in vacuum or a protective environment. The coating architectures, from the coating/substrate interface to the outer most surface of the coating include an inner adhesion layer, an outer working layer and, optionally, one or more functionally graded material layers. The invention also provides methods of making these coatings.
    Type: Grant
    Filed: June 6, 2005
    Date of Patent: January 11, 2011
    Assignee: Colorado School of Mines
    Inventors: John Moore, Dalong Zhong, Jianliang Lin
  • Publication number: 20110003119
    Abstract: The invention is directed to high purity zirconia-based and/or hafnia-based materials and coatings for high temperature cycling applications. Thermal barrier coatings made from the invention high purity material was found to have significantly improved sintering resistance relative to coatings made from current materials of lower purity. The invention materials are high purity zirconia and/or hafnia partially or fully stabilized by one or any combinations of the following stabilizers: yttria, ytterbia, scandia, lanthanide oxide and actinide oxide. Limits for impurity oxide, oxides other than the intended ingredients, that lead to significantly improved sintering resistance were discovered. High purity coating structures suitable for high temperature cycling applications and for application onto a substrate were provided. In one structure, the coating comprises a ceramic matrix, porosity and micro cracks. In another structure, the coating comprises a ceramic matrix, porosity, macro cracks and micro cracks.
    Type: Application
    Filed: September 13, 2006
    Publication date: January 6, 2011
    Inventors: Jacobus C. Doesburg, Liangde Xie, Richard Schmid, Matthew Gold
  • Patent number: 7862911
    Abstract: A thermal spray coating is made of cermet and provided on the surface of a base. The value that is gained by further dividing the value, which is gained by dividing the coefficient of thermal expansion of the thermal spray coating by the thickness of the thermal spray coating (unit: ?m), by the coefficient of thermal expansion of the base is set to a value no less than 0.15×10?2. Accordingly, peeling and cracking of the thermal spray coating can be prevented from being caused by the difference in the coefficient of thermal expansion between the thermal spray coating and the base.
    Type: Grant
    Filed: February 2, 2007
    Date of Patent: January 4, 2011
    Assignee: Fujimi Incorporated
    Inventors: Hiroaki Mizuno, Junya Kitamura
  • Patent number: 7858194
    Abstract: An extreme low resistivity light attenuation anti-reflection coating structure in order to increase transmittance of blue light, includes a substrate and a coating module. The coating module is formed on a front surface of the substrate and composed of a plurality of silicon carbide compound coating layers, a plurality of Al-based oxide coating layers and a plurality of metal coating layers that are alternately stacked onto each other.
    Type: Grant
    Filed: May 27, 2008
    Date of Patent: December 28, 2010
    Assignee: Innovation & Infinity Global Corp.
    Inventors: Cheng-Chieh Chang, Hsiu-Feng Liu, Pi-Jui Kuo
  • Patent number: 7851402
    Abstract: The invention relates to soluble metal oxides and mixed metal oxides and to solutions comprising metal oxides and mixed metal oxides. The invention further relates to a process for preparing a soluble metal oxide and a soluble mixed metal oxide and additionally relates to a process for modifying the solubility of a soluble metal oxide. The metal oxides, mixed metal oxides and solutions thereof have a number of applications and in particular are suitable for use as catalysts and also as precursors for the formation of metal films.
    Type: Grant
    Filed: November 22, 2004
    Date of Patent: December 14, 2010
    Assignee: National University of Ireland, Galway
    Inventors: Patrick Desmond Cunningham, James McManus
  • Patent number: 7851065
    Abstract: An extreme low resistivity light attenuation anti-reflection coating structure in order to increase transmittance of blue light. The coating structure includes a substrate and a coating module. The coating module is formed on a front surface of the substrate and composed of a plurality of mixture coating layers, a plurality of Al-based oxide coating layers and a plurality of metal coating layers that are alternately stacked onto each other. Each mixture coating layer is composed of silicon carbide compound and Ti-based oxide.
    Type: Grant
    Filed: May 27, 2008
    Date of Patent: December 14, 2010
    Assignee: Innovation & Infinity Global Corp.
    Inventors: Cheng-Chieh Chang, Hsiu-Feng Liu, Pi-Jui Kuo
  • Patent number: 7846549
    Abstract: Low emissivity glazing which is an assembly of thin layers including at least one metal layer reflecting infrared rays between one or more dielectric layers located between the metal layer and the glass sheet and on the metal layer, the light transmission of one clear float glass sheet 4 mm thick coated with said layers being not less than 83%, the metal layer being selected such that the emissivity is not higher than 0.042.
    Type: Grant
    Filed: October 3, 2007
    Date of Patent: December 7, 2010
    Assignee: AGC Glass Europe
    Inventors: Yvan Novis, Jean-Michel Depauw, Daniel Decroupet