Refractory Metal Salt Or Oxide Patents (Class 428/472)
  • Patent number: 7846549
    Abstract: Low emissivity glazing which is an assembly of thin layers including at least one metal layer reflecting infrared rays between one or more dielectric layers located between the metal layer and the glass sheet and on the metal layer, the light transmission of one clear float glass sheet 4 mm thick coated with said layers being not less than 83%, the metal layer being selected such that the emissivity is not higher than 0.042.
    Type: Grant
    Filed: October 3, 2007
    Date of Patent: December 7, 2010
    Assignee: AGC Glass Europe
    Inventors: Yvan Novis, Jean-Michel Depauw, Daniel Decroupet
  • Patent number: 7846554
    Abstract: The present invention discloses a method of making a functionally graded metal matrix composite (MMC) sheet having a central layer of particulate matter. The method includes providing a molten metal containing particulate matter to a pair of advancing casting surfaces. Solidifying the molten metal while advancing the molten metal between the advancing casting surfaces to form a product comprising a first solid outer layer, a second solid outer layer, and a semi-solid central layer having a higher concentration of particulate matter than either of the outer layers. Solidifying the central layer to form a solid metal product comprised of an inner layer sandwiched between the outer layers and withdrawing the metal product from between the casting surfaces. The method yields an MMC having a central layer enriched with particulate matter and sandwiched between metallic outer layers.
    Type: Grant
    Filed: April 11, 2007
    Date of Patent: December 7, 2010
    Assignee: Alcoa Inc.
    Inventors: David A. Tomes, Jr., Gavin F. Wyatt-Mair, David W. Timmons, Ali Unal
  • Patent number: 7846551
    Abstract: A composite article includes a first composite material and a second composite material. The first composite material and the second composite material individually comprise hard particles in a binder. A concentration of ruthenium in the binder of the first composite material is different from a concentration of ruthenium in the binder of the second composite material.
    Type: Grant
    Filed: March 16, 2007
    Date of Patent: December 7, 2010
    Assignee: TDY Industries, Inc.
    Inventors: X. Daniel Fang, Craig Morton, David J. Wills
  • Patent number: 7842403
    Abstract: A coated substrate and a process for forming the coated substrate, including a first lubricious coating layer overlying the substrate, the first lubricious coating layer including a first lubricant providing to the first lubricious coating layer a first coefficient of friction; and a second lubricious coating layer overlying the first lubricious coating layer, the second lubricious coating layer including a second lubricant providing to the second lubricious coating layer a second coefficient of friction, in which the second coefficient of friction is greater than the first coefficient of friction.
    Type: Grant
    Filed: February 23, 2006
    Date of Patent: November 30, 2010
    Assignee: Atotech Deutschland GmbH
    Inventors: William H. Meyer, Jr., Craig V. Bishop, William Bradford Staples
  • Patent number: 7842393
    Abstract: The present invention provides a vehicle antifouling element that comprises a layer comprising a p-type semiconductor and a thin film that comprises an n-type semiconductor that is laminated on the surface of the p-type semiconductor layer. The thin film comprises a photocatalytic activity and the film thickness thereof is equal to or more than 5 nm and less than 60 nm.
    Type: Grant
    Filed: December 3, 2007
    Date of Patent: November 30, 2010
    Assignee: Murakami Corporation
    Inventors: Norihiko Kuzuya, Masatoshi Nakamura
  • Publication number: 20100297410
    Abstract: There is described a Ceramic Powder, a Ceramic Layer and a Layer System of Two Pyrochlore Phases and Oxides. Besides a good thermal insulation property, thermal insulation layer systems must also have a long lifetime of the thermal insulation layer. The layer system has a ceramic layer, which comprises a mixture of two pyrochlore phases.
    Type: Application
    Filed: May 6, 2008
    Publication date: November 25, 2010
    Inventor: Ramesh Subramanian
  • Publication number: 20100297409
    Abstract: There is described a Ceramic Powder, a Ceramic Layer and a Layer System with Pyrochlore Phase and Oxides. Besides a good thermal insulation property, thermal insulation layer systems must also have a long lifetime of the thermal insulation layer. A described layer system has a layer sequence of a metallic bonding layer, an inner ceramic layer and an outer ceramic layer, which are specially matched to one another.
    Type: Application
    Filed: May 6, 2008
    Publication date: November 25, 2010
    Inventor: Ramesh Subramanian
  • Patent number: 7838120
    Abstract: An object of the present invention is to obtain an aluminum or aluminum alloy member having a uniform and dense anodic oxide film having sufficient corrosion and impact resistances. Provided is an anodic oxide film which has been formed on the surface of aluminum or aluminum alloy, the film comprising cells which have grown in random directions relative to the surface of the aluminum or aluminum alloy and thus have no orientation.
    Type: Grant
    Filed: August 15, 2005
    Date of Patent: November 23, 2010
    Assignee: Suzuki Motor Corporation
    Inventors: Tomoharu Yamamoto, Hiroomi Tanaka
  • Patent number: 7833628
    Abstract: A coating structure with an anti-reflection function and an anti-electromagnetic wave function, including an anti-reflection coating structure, an anti-electromagnetic wave coating structure, a third transparent substrate, and two adhesive layers respectively disposed between the anti-reflection coating structure and the third transparent substrate and between the third transparent substrate and the anti-electromagnetic wave coating structure. The anti-reflection coating structure has a first transparent substrate and an anti-reflection coating module formed on the first transparent substrate. The anti-electromagnetic wave coating structure has a second transparent substrate and an anti-electromagnetic wave coating module formed on the second transparent substrate. The third transparent substrate is disposed between the anti-reflection coating structure and the anti-electromagnetic wave coating structure.
    Type: Grant
    Filed: January 7, 2008
    Date of Patent: November 16, 2010
    Assignee: Innovation & Infinigy Global Corp.
    Inventors: Cheng-Chieh Chang, Shiu-Feng Liu, Pi-Jui Kuo
  • Patent number: 7833586
    Abstract: A thermally sprayed alumina-based coating is deposited onto a thermal barrier coating to provide an article such as a turbine engine component with both CMAS mitigation and antifouling. The alumina-based coating increases a melting point of the CMAS to a temperature greater than an operating temperature of the turbine engine component. The surface roughness of the thermally sprayed alumina based coating in less than 4.0 micrometers to 0.75 micrometers. The alumina based coatings include at least 60 weight percent alumina based on a total weight of the alumina-based coating.
    Type: Grant
    Filed: October 24, 2007
    Date of Patent: November 16, 2010
    Assignee: General Electric Company
    Inventor: Joshua L. Margolies
  • Publication number: 20100285273
    Abstract: An acrylic rubber-metal composite, which comprises an iron phosphate treated iron-based metal, and an adhesive layer comprising a phenol resin and a metal oxide, and preferably further a halogenated polymer, and an acrylic rubber layer, successively provided on the iron-based metal surface, has not only distinguished initial adhesiveness and water resistance, when the acrylic rubber is bonded to the metal owing to application of the iron phosphate treatment to the metal surface, but also can reduce the abrasion of the mating materials when brought into contact with rubber-unbaked parts of the sheet, because the surface roughness Ra[according to JIS 0601(1994)] of the surface treated steel sheet is 0.6 or less.
    Type: Application
    Filed: May 13, 2008
    Publication date: November 11, 2010
    Applicant: NOK CORPORATION
    Inventors: Katsumi ABE, Kiyofumi FUKASAWA
  • Patent number: 7829196
    Abstract: A hard tissue repairing material includes zirconia as a base material. A surface of the base material has a hydrophilic group. The hydrophilic group is bonded to zirconium atom in the base material. The base material may contain at least an ionic component that is selected from a group consisting of calcium ion, sodium ion, potassium ion, and phosphate ions within the surface. A hard tissue repairing material may include zirconia as a base material and a layer of a main component of an apatite. The layer of the apatite may be formed on a hydrophilic group bonded to zirconium atom in the base material.
    Type: Grant
    Filed: April 8, 2009
    Date of Patent: November 9, 2010
    Assignees: Panasonic Corporation Works, Ltd.
    Inventors: Tadashi Kokubo, Masahiro Nawa, Masaki Uchida
  • Publication number: 20100275875
    Abstract: A sliding component for an internal combustion engine includes a component main body made of titanium or a titanium alloy, a surface hardened layer provided on a surface of the component main body, a diamond-like carbon film provided on the surface hardened layer, and a titanium layer provided between the surface hardened layer and the diamond-like carbon film.
    Type: Application
    Filed: December 15, 2009
    Publication date: November 4, 2010
    Applicant: Yamaha Hatsudoki Kabushi Kaisha
    Inventor: Kosuke Doi
  • Publication number: 20100272982
    Abstract: This invention relates to thermal spray coatings on a metal or non-metal substrate. The thermal spray coating comprises a partially or fully stabilized ceramic coating, e.g., yttria stabilized zirconia coating, and has sufficiently high thermodynamic phase stability to provide corrosion and/or erosion resistance to the substrate. This invention also relates to methods of protecting metal and non-metal substrates by applying the thermal spray coatings. The coatings are useful, for example, in the protection of integrated circuit manufacturing equipment, internal chamber components, and electrostatic chuck manufacture.
    Type: Application
    Filed: October 20, 2009
    Publication date: October 28, 2010
    Inventors: Graeme Dickinson, John Sirman, Adil Ashary, Christopher Petorak, Neill Jean McDill
  • Patent number: 7820577
    Abstract: A biomedical member having high strength, high toughness and high hardness and an artificial joint that uses the same are provided. In addition, a biomedical member that exhibits high wear resistance even in in vivo environment and an artificial joint are provided. Such a composite ceramic is used that contains 65% by weight or more Al2O3, 4 to 34% by weight of ZrO2 and 0.1 to 4% by weight of SrO, while Sr forms a solid solution with part of the ZrO2 grains. The composite ceramics further contains TiO2, MgO and SiO2 as sintering additives, while controlling the amounts to 0.20% by weight or more SiO2, 0.22% by weight or more TiO2 and 0.12% by weight or more MgO, and the total amount of SiO2, TiO2 and MgO within a range from 0.6 to 4.5% by weight.
    Type: Grant
    Filed: October 29, 2004
    Date of Patent: October 26, 2010
    Assignee: Kyocera Corporation
    Inventors: Kunihide Shikata, Takefumi Nakanishi, Yucong Wang
  • Patent number: 7820300
    Abstract: An article of manufacture and a process for making the article by the anodization of aluminum and aluminum alloy workpieces to provide corrosion-, heat- and abrasion-resistant ceramic coatings comprising titanium and/or zirconium oxides, and the subsequent coating of the anodized workpiece with a second coating such as polytetrafluoroethylene (“PTFE”) or silicone containing coatings. The invention is especially useful for forming longer life coatings on aluminum substrates by pre-coating the substrate with an anodized layer of titanium and/or zirconium oxide that provides excellent corrosion-, heat- and abrasion-resistance in a hard yet flexible film.
    Type: Grant
    Filed: June 20, 2005
    Date of Patent: October 26, 2010
    Assignee: Henkel AG & Co. KGaA
    Inventor: Shawn E. Dolan
  • Patent number: 7820299
    Abstract: Method to produce an element (10) subject to wear, such as a mechanical member, an abrasion or crushing tool or suchlike, comprising a metal matrix (14) and at least a core (12) of ceramic material. The method comprises a preliminary step wherein the core (12) is prepared by mixing at least a first component with a base of aluminum oxide in the form of a (a-Al2O3) with a second component comprising a eutectic compound with a base of a-Al2O3 and ZrO2, a second step wherein the core (12) is arranged in a mold, so as to define a free volume inside the mold, and a third step wherein a molten metal material is cast into the mold, to occupy the free volume so as to anchor to the core (12) and thus form a single body.
    Type: Grant
    Filed: May 6, 2004
    Date of Patent: October 26, 2010
    Assignee: F.A.R.- Fonderie Acciaierie Roiale-SpA
    Inventors: Alberto Andreussi, Guido Castenetto, Valeria Moroso, legal representative, Nella Castenetto, legal representative, Silvana Castenetto, legal representative, Primo Andreussi, Eddy Pontelli
  • Patent number: 7811683
    Abstract: A cutting tool having a substrate and a coating layer for coating the surface of the substrate, the coating layer being composed of Ti1?a?b?c?dAlaWbSicMd(CxN1?x), where M is at least one selected from Nb, Mo, Ta, Hf and Y, 0.45?a?0.55, 0.01?b?0.1, 0.01?c?0.05, 0.01?d?0.1, and 0?x?1. The cutting tool has excellent wear resistance and fracture resistance. The cutting tool may be further provided with a layer composed of at least one selected from carbides, nitrides and carbonitrides of Al and the elements of the groups 4, 5 and 6 of the periodic table.
    Type: Grant
    Filed: September 27, 2007
    Date of Patent: October 12, 2010
    Assignee: Kyocera Corporation
    Inventors: YaoCan Zhu, Hideyoshi Kinoshita, Takashi Tokunaga, Kenji Noda, Tatsuyuki Nakaoka
  • Patent number: 7811655
    Abstract: Disclosed is a metal-ceramic substrate made up of at least one ceramic layer which is provided with metallizations on both faces. In order to obtain a partial discharge resistance of less than 10 pC at a predefined measuring voltage, the thickness of the ceramic layer amounts to about one sixth of the measuring voltage.
    Type: Grant
    Filed: April 23, 2005
    Date of Patent: October 12, 2010
    Assignee: Curamic Electronics GmbH
    Inventors: Jurgen Schulz-Harder, Karl Exel
  • Publication number: 20100247323
    Abstract: A workpiece, such as a turbine engine component, comprises a substrate, a thermal barrier coating on the substrate, and a hard erosion barrier deposited over the thermal barrier coating. The erosion barrier preferably has a Vickers hardness in the range of from 1300 to 2750 kg/mm2. The erosion barrier may be formed from aluminum oxide, silicon carbide, silicon nitride, or molybdenum disilicide. The erosion barrier may be formed using either an electrophoretic deposition process or a slurry process.
    Type: Application
    Filed: May 30, 2006
    Publication date: September 30, 2010
    Inventors: Joshua Persky, David A. Litton, David L. Lambert
  • Patent number: 7803464
    Abstract: A surface-coated cutting tool comprising a substrate, and a coating formed thereon, characterized in that the coating includes a first coating containing TiCN and a second coating containing ?-type Al2O3, the first coating is interposed between the substrate and the second coating, and the second coating has compressive stress S1 on the rake face and tensile stress S2 on the flank face, with the compressive stress S1 and the tensile stress S2 being defined by the following expression; 441 MPa?|S1?S2|?3500 MPa.
    Type: Grant
    Filed: November 16, 2005
    Date of Patent: September 28, 2010
    Assignee: Sumitomo Electric Hardmetal Corp.
    Inventors: Yoshio Okada, Naoya Omori, Minoru Itoh, Norihiro Takanashi, Shinya Imamura, Susumu Okuno
  • Publication number: 20100239855
    Abstract: Coated metal cutting tools with reduced adhesion weat and improved thermal resistance, processes for making the same and methods of use.
    Type: Application
    Filed: May 26, 2008
    Publication date: September 23, 2010
    Applicant: H.C. Starck GmbH
    Inventors: Benno Gries, Leo Prakash
  • Patent number: 7799420
    Abstract: A method for producing a nanostructured, in particular a ceramic-like functional coating on a substrate is described. To that end, using at least one plasma source, a pulsed plasma is produced with which a matrix phase and at least one nano-scale interstitial phase embedded in it are deposited on the substrate via a material input. Preferably a plurality of pulsed plasma sources that are time-correlated or synchronized with each other are used. Also proposed is a nanostructured functional coating, in particular one producible by this method, which is free of chlorine and/or sulfur, and which contains at least one metal and/or at least one element selected from the group oxygen, hydrogen, nitrogen, carbon, helium, argon or neon.
    Type: Grant
    Filed: August 22, 2002
    Date of Patent: September 21, 2010
    Assignees: Robert Bosch GmbH, Walter AG
    Inventors: Thomas Beck, Alexander Schattke, Sascha Henke, Veit Schier
  • Publication number: 20100233497
    Abstract: A non-conductive ceramic material contains a base ceramic material and at least one other ceramic material having a lower coefficient of thermal expansion than that of the base material so that the coefficient of thermal expansion of the non-conductive ceramic material is identical to that of a metallic material to which it will be matched. Methods of making and using same are disclosed.
    Type: Application
    Filed: April 8, 2008
    Publication date: September 16, 2010
    Inventors: Alfred Thimm, Jürgen Ruska, Johannes Ernst, Stefan Stolz
  • Publication number: 20100233388
    Abstract: A multilayer film structure for increasing transmittance includes a transparent substrate and a multifunctional film module. The multifunctional film module is formed on a front surface of the transparent substrate and composed of a plurality of dielectric layers and a plurality of metal layers. The dielectric layers and the metal layers are alternately stacked onto each other, and each metal layer is formed by mixing at least two metals. Each dielectric layer is a silicon carbide compound layer that is SiC, and each metal layer is formed by mixing Ag and Cu.
    Type: Application
    Filed: March 16, 2009
    Publication date: September 16, 2010
    Inventors: CHENG-CHIEH CHANG, HSIU-FENG LIU, PI-JUI KUO
  • Patent number: 7794846
    Abstract: A titanium part for use in an internal combustion engine includes a ceramic layer on its surface. The ceramic layer has a thickness that is greater than about 10 nm but equal to or less than about 750 nm and includes either silicon or aluminum.
    Type: Grant
    Filed: June 22, 2006
    Date of Patent: September 14, 2010
    Assignee: Yamaha Hatsudoki Kabushiki Kaisha
    Inventors: Toshihiro Itou, Naohisa Takahashi
  • Publication number: 20100220428
    Abstract: The invention relates to a method for a complex oxide film having a high relative dielectric constant formed on a substrate surface by wet-treatment method and a production process of the complex oxide film comprising a step of washing the complex oxide film with an acid solution of pH 5 or less to thereby reduce salts in the film. Further, the invention relates to a dielectric material and a piezoelectric material containing the complex oxide film, a capacitor and a piezoelectric element including the material, and a electronic device comprising the element.
    Type: Application
    Filed: July 28, 2006
    Publication date: September 2, 2010
    Applicant: SHOWA DENKO K.K.
    Inventors: Akihiko Shirakawa, Hirofumi Fukunaga, Chunfu Yu
  • Publication number: 20100221538
    Abstract: A cementitious composite material wherein glass-coated steel rods are positioned in a cementitious matrix. The glass composition for coating the steel reinforcing rods includes between about 33-45 weight percent SiO2, 13.5-19.5 weight percent B2O3, 3.5-4.6 weight percent Al2O3, 4.0-13.5 weight percent K2O, 5.5-15.5 weight percent ZrO2, 8.6-15.9 weight percent Na2O, 4.6-5.1 weight percent CaO, 0.6-0.7 weight percent MnO2, 1.0-1.0 weight percent NiO, and 1.0-1.1 weight percent CoO. The glass composition is typically in compression on the rods at ambient temperatures, has a coefficient of thermal expansion of between about 12.5 and about 13.5, and has a softening temperature of between about 585 degrees Celsius and about 600 degrees Celsius.
    Type: Application
    Filed: November 20, 2009
    Publication date: September 2, 2010
    Inventors: Richard K. Brow, Signo T. Reis, Mike Konigstein, Genda Chen
  • Patent number: 7785714
    Abstract: An extreme low resistivity light attenuation anti-reflection coating structure with a surface protective layer includes a substrate, a coating module, and a composed protection coating layer. The coating module is formed on a front surface of the substrate. The coating module is composed of a plurality of silicon carbide compound coating layers and a plurality of metal coating layers that are alternately stacked with each other. The composed protection coating layer is formed on the coating module.
    Type: Grant
    Filed: October 5, 2007
    Date of Patent: August 31, 2010
    Assignee: Innovation & Infinity Global Corp.
    Inventors: Cheng-Chieh Chang, Shiu-Feng Liu, Pi-Jui Kuo
  • Patent number: 7785722
    Abstract: A turbine engine component is provided which has a substrate and a thermal barrier coating applied over the substrate. The thermal barrier coating comprises alternating layers of yttria-stabilized zirconia and a molten silicate resistant material. The molten silicate resistant outer layer may be formed from at least one oxide of a material selected from the group consisting of lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium, scandium, indium, zirconium, hafnium, and titanium or may be formed from a gadolinia-stabilized zirconia. If desired, a metallic bond coat may be present between the substrate and the thermal barrier coating system. A method for forming the thermal barrier coating system of the present invention is described.
    Type: Grant
    Filed: January 20, 2006
    Date of Patent: August 31, 2010
    Assignee: United Technologies Corporation
    Inventors: Melvin Freling, Kevin W. Schlichting, Michael J. Maloney, David A. Litton, John G. Smeggil, David B. Snow
  • Patent number: 7776448
    Abstract: An aqueous composition for pretreating and depositing a coating on metal substrates is provided. The coating composition includes from about 1,500 to about 55,000 ppm based on the aqueous composition of a Group IIA dissolved metal ion, from about 100 to about 200,000 ppm based on the aqueous composition of a dissolved complex metal fluoride ion wherein the metal atom is selected from Group IIIA, Group IVA, Group IVB metals, Group VA, Group VB metals; and water. The composition is free of Group IIA metal fluoride precipitate achieved by including in the composition a complex metal salt different than the salt associated with the complex metal fluoride ion, with the complex metal salt being capable of complexing free fluoride ions to prevent a precipitation reaction. A process for coating a metal substrate with such an aqueous composition is further provided.
    Type: Grant
    Filed: June 6, 2008
    Date of Patent: August 17, 2010
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Jeffrey Allen Greene, Donald Robb Vonk
  • Patent number: 7776143
    Abstract: A composition comprising a glass-forming binder component and a particulate corrosion resistant component. The particulate corrosion resistant component comprises corrosion resistant particulates having: a CTEp of at least about 4 and being solid at a temperature of about 1300° F. (704° C.) or greater; and a maximum median particle size defined by one of the following formulas: (a) for a CTEp of 8 or less, an MP equal to or less than (4.375×CTEp)?10; and (b) for a CTEp of greater than 8, an Mp equal to or less than (?4.375×CTEp)+60, wherein CTEp is the average CTE of the corrosion resistant particulates and wherein Mp is the median equivalent spherical diameter (ESD), in microns, of the corrosion resistant particulates. Also disclosed is an article comprising a turbine component comprising a metal substrate and a corrosion resistant coating overlaying the metal substrate, as well as a method for forming at least one layer of the corrosion resistant coating adjacent to the metal substrate.
    Type: Grant
    Filed: September 18, 2009
    Date of Patent: August 17, 2010
    Assignee: General Electric Company
    Inventors: Brian Thomas Hazel, Michael James Weimer
  • Patent number: 7771847
    Abstract: To provide a high cBN content ratio sintered body that improves fatigue life of the machined part and has a longer tool lifespan than conventional cBN sintered body tools by suppressing the production of the affected layer by machining formed on the machined surface of the workpiece to be cut and by promoting residual compression stress. That is a cBN sintered body according to the present invention is a cBN sintered body for high surface integrity machining having a cBN component of not less than 87% and not more than 99% by volume % and a thermal conductivity of 100 W/m·K or more; and the outermost surface of the cBN sintered body 1 is coated with a heat resistant film 2 having a thickness of 0.5 ?m to 12 ?m comprising a compound of at least one element selected from 4a, 5a, 6a group elements and Al, and at least one element selected from C, N, and O.
    Type: Grant
    Filed: May 30, 2006
    Date of Patent: August 10, 2010
    Assignee: Sumitomo Electric Hardmetal Corp.
    Inventors: Satoru Kukino, Yoshihiro Kuroda, Tomohiro Fukaya, Katsumi Okamura
  • Patent number: 7771848
    Abstract: An extreme low resistivity light attenuation anti-reflection coating with a transparent surface conductive layer includes a substrate, a coating module, and a composed protection coating layer. The coating module is formed on a front surface of the substrate. The coating module is composed of a plurality of mixture coating layers and a plurality of metal coating layers that are alternately stacked with each other. Each mixture coating layer is composed of silicon carbide compound and Ti-based oxide. The composed protection coating layer is formed on the coating module.
    Type: Grant
    Filed: October 5, 2007
    Date of Patent: August 10, 2010
    Assignee: Innovation & Infinity Global Corp.
    Inventors: Cheng-Chieh Chang, Shiu-Feng Liu, Pi-Jui Kuo
  • Patent number: 7771836
    Abstract: A golden ornament includes a base material; a Ti coating film which is formed on a surface of the base material in an atmosphere of an inert gas other than nitrogen and whose Ti atom content is constant in the thickness direction; a TiN gradient coating film which is formed on the Ti coating film and whose N atom content has a gradient in the thickness direction; a TiN coating film which is formed on the TiN gradient coating film and whose contents of Ti atoms and N atoms are constant in the thickness direction; an Au—TiN mixture gradient coating film which is formed on the TiN coating film and whose Au atom content has a gradient in the thickness direction; and an Au—TiN mixture coating film which is formed on the Au—TiN mixture gradient coating film and whose contents of Au atoms, Ti atoms, and N atoms are constant in the thickness direction.
    Type: Grant
    Filed: March 31, 2006
    Date of Patent: August 10, 2010
    Assignee: Citizen Holdings Co., Ltd.
    Inventors: Koichi Naoi, Fumio Tase, Yukio Miya, Osamu Tanaka, Masayoshi Ushikubo
  • Patent number: 7758759
    Abstract: A process for etching a metal or alloy surface which comprises applying an etch-resist ink by ink jet printing to selected areas of the metal or alloy, solidifying the etch-resist ink without the use of actinic light and/or particle beam radiation and then removing the exposed metal or alloy by a chemical etching process wherein the etch-resist ink comprises the components: A) 60 to 100 parts carrier vehicle comprising one or more components which contain at least one metal chelating group; D) 0 to 40 parts colorant; and E) 0 to 5 parts surfactant; wherein the ink has a viscosity of not greater than 30 cPs (mPa·s) at the firing temperature, all parts are by weight and the total number of parts A)+B)+C)=100.
    Type: Grant
    Filed: October 1, 2004
    Date of Patent: July 20, 2010
    Assignee: Fujifilm Imaging Colorants Limited
    Inventors: Mark Robert James, David Cottrell
  • Patent number: 7754383
    Abstract: A negative electrode material for a non-aqueous electrolyte secondary battery comprising an alloy including silicon and a transition metal selected from the group consisting of titanium, zirconium, vanadium, molybdenum, tungsten, iron, and nickel; and a silicon oxide film and an oxide film of the transition metal formed on a surface of the alloy wherein the alloy includes an A phase including silicon and a B phase including a crystalline alloy of silicon and the transition metal. The negative electrode material has a silicon oxide film and an oxide film of the transition metal on the surface of the alloy wherein the thickness ratio of the transition metal oxide film to the silicon oxide film is at least 0.44 and smaller than 1.
    Type: Grant
    Filed: December 12, 2006
    Date of Patent: July 13, 2010
    Assignee: Panasonic Corporation
    Inventors: Teruaki Yamamoto, Masaki Hasegawa, Yasuhiko Bito
  • Patent number: 7754333
    Abstract: Thermally stable diamond constructions comprise a diamond body having a plurality of bonded diamond crystals and a plurality of interstitial regions disposed among the crystals. A metallic substrate is attached to the diamond body. A working surface is positioned along an outside portion of the diamond body, and the diamond body comprises a first region that is substantially free of a catalyst material, and a second region that includes the catalyst material. The diamond body first region extends from the working surface to depth of at least about 0.02 mm to a depth of less than about 0.09 mm. The diamond body includes diamond crystals having an average diamond grain size of greater than about 0.02 mm, and comprises at least 85 percent by volume diamond based on the total volume of the diamond body.
    Type: Grant
    Filed: September 21, 2004
    Date of Patent: July 13, 2010
    Assignee: Smith International, Inc.
    Inventors: Ronald K. Eyre, Anthony Griffo, Thomas W. Oldham
  • Publication number: 20100173106
    Abstract: The present invention relates to a method for continuously coating a substrate in motion such as a metal strip made of steel, the coating formed being an ultra-fine film of a thickness between 10 and 100 nm, deposited on the substrate: from a solution containing nanoparticles of oxides, in conditions of controlled pH, said substrate being at a temperature higher than 120° C., the total duration of the deposition being less than 5 seconds and preferably less than 1 second, characterised in that at least one chemical additive, called a “refiner”, is incorporated into said solution, said refiner having, mutatis mutandis, the effect of restricting the formation of said coating.
    Type: Application
    Filed: February 2, 2010
    Publication date: July 8, 2010
    Inventor: Sébastien LE CRAZ
  • Publication number: 20100167071
    Abstract: A coating layer prepared from an aqueous electrodeposition coating composition comprising an electrodepositable binder, the binder comprising a aromatic amine group-containing resin, and a metal oxide selected from the group consisting of bismuth oxide, vanadium oxide, manganese oxide, cobalt oxide, zinc oxide, strontium oxide, yttrium oxide, molybdenum oxide, zirconium oxide, lanthanum oxide, oxides of the lanthanide series of elements and combinations of these provides corrosion protection to a metallic substrate.
    Type: Application
    Filed: December 29, 2008
    Publication date: July 1, 2010
    Applicant: BASF CORPORATION
    Inventors: Abdellatif Chouai, Timothy S. December
  • Publication number: 20100167072
    Abstract: An aqueous coating composition comprises a metal oxide selected from the group consisting of bismuth oxide, vanadium oxide, manganese oxide, cobalt oxide, zinc oxide, strontium oxide, yttrium oxide, molybdenum oxide, zirconium oxide, lanthanum oxide, oxides of the lanthanide series of elements and combinations thereof and an electrodepositable binder, the binder comprising (a) a phosphorous-containing group in which X is a hydrogen, a monovalent hydrocarbon, an alkyl group such as an aminoalkyl group, or an oxygen atom having a single covalent bond to the phosphorous atom, and each oxygen atom has a covalent bond to a hydrogen atom, an alkyl group, an aryl group, an alkylaryl group, an arylalkyl group, or the resin, with the caveat that at least one oxygen atom has a covalent bond to resin; (b) a carboxylate group separated by from 2 to 4 carbons from an ester group; and (c) a tridentate amine ligand.
    Type: Application
    Filed: December 29, 2008
    Publication date: July 1, 2010
    Applicant: BASF CORPORATION
    Inventors: Abdellatif Chouai, Timothy S December
  • Publication number: 20100167034
    Abstract: The present invention relates to a glazing coated with an assembly of thin layers using vacuum deposition, said glazing having reflective properties for infrared radiation, while retaining a high transmission in the visible range, and retaining its properties when subjected to a thermal treatment such as bending/toughening. The glazing comprises one or more silver-based layers and dielectric layers, of which at least one underlying dielectric layer in relation to at least one silver-based layer is a titanium oxide- or oxynitride-based layer such as TiMOx or TiMOxNy, in which M is a metal or a plurality of metals or silicon, wherein these metals or silicon are contained in sufficient atomic proportions to prevent a significant transformation of the crystallographic structure of the previously deposited titanium oxide-based layer under the action of the thermal treatment.
    Type: Application
    Filed: March 17, 2008
    Publication date: July 1, 2010
    Applicant: AGC FLAT GLASS EUROPE SA.
    Inventors: Jean-Michel Depauw, Gaetan Di Stefano
  • Publication number: 20100159262
    Abstract: A composition useful as a thermal barrier coating on a superalloy substrate intended for use in hostile thermal environments. The coating comprises zirconia stabilized in a predominately tetragonal phase. The composition includes a ceramic component consisting essentially of zirconia (ZrO2) or a combination of zirconia and hafnia (HfO2) and a stabilizer component comprising, in combination, a first co-stabilizer selected from YbO1.5, HoO1.5, ErO1.5, TmO1.5, LuO1.5, and combinations thereof, and optionally YO1.5, a second co-stabilizer selected from TiO2, PdO2, VO2, GeO2, and combinations thereof, and a third co-stabilizer comprising TaO2.5. The stabilizer component is present in an amount effective to achieve the predominantly tetragonal phase in the coating.
    Type: Application
    Filed: December 18, 2008
    Publication date: June 24, 2010
    Inventors: Ming Fu, Brian Thomas Hazel, Brett Boutwell, Tobias A. Schaedler, Curtis Alan Johnson, Don M. Lipkin, Douglas G. Konitzer, Venkat S. Venkataramani
  • Patent number: 7740948
    Abstract: This disclosure addresses the issue of providing a metallic-ceramic overlay coating that potentially serves as an interface or bond coat layer to provide enhanced oxidation resistance to the underlying superalloy substrate via the formation of a diffusion barrier regime within the supporting base material. Furthermore, the metallic-ceramic coating is expected to limit the growth of a continuous thermally grown oxide (TGO) layer that has been primarily considered to be the principal cause for failure of existing TBC systems. Compositional compatibility of the metallic-ceramic with traditional yttria-stabilized zirconia (YSZ) top coats is provided to further limit debond or spallation of the coating during operational use. A metallic-ceramic architecture is disclosed wherein enhanced oxidation resistance is imparted to the surface of nickel-based superalloy or single crystal metal substrate, with simultaneous integration of the yttria stabilized zirconia (YSZ) within the metallic-ceramic overlayer.
    Type: Grant
    Filed: May 31, 2007
    Date of Patent: June 22, 2010
    Assignee: The United States of America as represented by the United States Department of Energy
    Inventor: Mary Anne Alvin
  • Publication number: 20100151271
    Abstract: A multilayer substrate includes a base layer, a coating layer and an intermediate layer positioned between the base layer and the coating layer. The intermediate layer contains chromium and nitrogen. A content of the chromium in the intermediate layer gradually decreases from the base layer to the coating layer.
    Type: Application
    Filed: October 27, 2009
    Publication date: June 17, 2010
    Applicant: HON HAI PRECISION INDUSTRY CO., LTD.
    Inventors: CHAO-TSANG WEI, CHUNG-PEI WANG, CHIEN-HAO HUANG, WEI-CHENG LING, CHIA-YING WU, GA-LANE CHEN
  • Patent number: 7736759
    Abstract: A turbine engine component is provided which has a substrate, a yttria-stabilized zirconia coating applied over the substrate, and a molten silicate resistant outer layer. The molten silicate resistant outer layer is formed from gadolinia or gadolinia-stabilized zirconia. A method for forming the coating system of the present invention is described.
    Type: Grant
    Filed: January 20, 2006
    Date of Patent: June 15, 2010
    Assignee: United Technologies Corporation
    Inventors: Kevin W. Schlichting, Michael J. Maloney, David A. Litton, Melvin Freling, John G. Smeggil, David B. Snow
  • Publication number: 20100136330
    Abstract: [PROBLEMS] To provide a precoated metal sheet allowing to skip postcoating after press working that realizes high whiteness degree and excels in bright reflectivity. [MEANS FOR SOLVING PROBLEMS] A white precoated metal sheet of 80 or higher postcoating whiteness degree in terms of L-value of Hunter Lab color system, comprising a metal sheet provided with two or more coating layers, wherein when the superior layer coating refers to the coating constituting the outermost surface layer and the inferior layer coating refers to the coating interposed between the superior layer coating and the metal sheet, the content of white pigment in the inferior layer coating is in the range of 40 to 60 mass % while the content of white pigment in the superior layer coating is in the range of 5 to 25 mass % so as to excel in bright reflectivity.
    Type: Application
    Filed: April 21, 2008
    Publication date: June 3, 2010
    Applicant: Honda Motors Co., Ltd.
    Inventors: Kohei Ueda, Kengo Yoshida, Hiroshi Kanai, Shiro Kamiyama, Shizuo Kimura
  • Publication number: 20100132932
    Abstract: Components having ceramic bases provided with a metalized structure on at least two opposite and/or juxtaposed faces at the same time, wherein metal in the form of pastes, films or sheets is provided for metallization and is applied to the surfaces of the ceramic base to be provided with a metalized structure.
    Type: Application
    Filed: April 17, 2008
    Publication date: June 3, 2010
    Applicant: CERAMTEC AG
    Inventor: Claus Peter Kluge
  • Patent number: 7727621
    Abstract: The present invention relates to a cutting tool, e.g. carbide insert, solid carbide drill or mill or carbide tip, particularly for milling of steels, stainless steel, HRSA, titanium or any alloyed material from any of these groups, comprising a cemented carbide substrate and an aperiodic multilayer coating with: a substrate of cemented carbide having a composition of from about 8 to about 11 wt-% Co, from about 0.1 to about 0.5 wt-% Cr and balance essentially tungsten carbide and a coating which is essentially an aperiodic multilayer consisting of layers A+B+A+B+A . . . where the sublayers A and B consist of AlxTi1-xN and TiyAl1-yN respectively. The typical average thickness of each A+B sequence is in the range from about 30 to about 300 nm and the total thickness of the coating in the range from about 0.5 to about 20 ?m. The total chemical composition averaged over the whole coating consists of TizAl1-zN where z lies in the range from about 0.40 to about 0.70.
    Type: Grant
    Filed: December 5, 2006
    Date of Patent: June 1, 2010
    Assignee: Sandvik Intellectual Property AB
    Inventors: Kjell Nordlöf, Maria Åstrand, Toril Myrtveit, Anders Lundquist, Mats Ahlgren
  • Publication number: 20100129624
    Abstract: An exemplary multi-layer film structure includes a substrate, an inmost layer clinging to the substrate, a medium layer, and a reflective-transmissive layer. The medium layer is formed on the clinging layer. The reflective-transmissive layer is formed on the medium layer. The reflective-transmissive layer is capable of reflecting a portion of incident light to be a first reflected light and allowing another portion of the incident light to transmit therethrough. The substrate is capable of reflecting the transmitted light to be a second reflected light. The medium layer is configured for controlling a light path difference between the first reflected light and the second reflected light thereby allowing the second reflected light to interfere with the first reflected light and provide the multi-layer film structure with a desired color appearance.
    Type: Application
    Filed: August 19, 2009
    Publication date: May 27, 2010
    Applicant: HON HAI PRECISION INDUSTRY CO., LTD.
    Inventors: GA-LANE CHEN, CHAO-TSANG WEI