Refractory Metal Salt Or Oxide Patents (Class 428/472)
-
Patent number: 7449244Abstract: The invention relates to a plate for fireplace insert or stove, or equivalent, formed from at least one substrate made of a glass material comprising at least one reflective coating on at least one of its faces. The invention also relates to the process for manufacturing the plate and to the device that includes said plate.Type: GrantFiled: September 23, 2004Date of Patent: November 11, 2008Assignee: Eurokera S.N.C.Inventors: Pablo Vilato, Mieke Nelson, Atticus Rutledge
-
Patent number: 7445851Abstract: A heat-insulating layer system for a metallic structural component, especially for a structural component of a gas turbine such as an aircraft engine, includes an adhesion promoting layer (12), an inner contact layer (14), and an outer cover layer (15) , whereby the adhesion promoting layer (12). is disposed on a surface (11) of the gas turbine structural component (10). The inner contact layer (14) is formed of a zirconium oxide partially stabilized with yttrium or yttrium oxide, and the outer cover layer (15) is formed of a material that consists of at least one component with at least one phase, which stoichiometrically comprises 1 to 80 Mol-% Mx2O3, 0.5 to 80 Mol-% MyO and Al2O3 as a remainder with incidental impurities, wherein Mx is selected from the elements chromium and barium or mixtures thereof, and wherein My is selected from the alkaline earth metals, the transition metals and the rare earths or mixtures thereof.Type: GrantFiled: May 24, 2005Date of Patent: November 4, 2008Assignees: MTU Aero Engines GmbH, Forschungszentrum Juelich GmbHInventors: Christian Friedrich, Wolfgang Wachter, Detlev Stoever, Gerhard Pracht, Robert Vassen, Bilge Saruhan-Brings, Claus-Juergen Kroeder, Uwe Schulz
-
Publication number: 20080268230Abstract: A cermet composition represented by the formula (PQ)(RS) comprising: a ceramic phase (PQ) and binder phase (RS) wherein, P is at least one metal selected from the group consisting of Group IV, Group V, Group VI elements, Q is boride, R is selected from the group consisting of Fe, Ni, Co, Mn and mixtures thereof, S comprises at least one element selected from Cr, Al, Si and Y.Type: ApplicationFiled: December 19, 2006Publication date: October 30, 2008Inventors: Narasimha-Rao Venkata Bangaru, ChangMin Chun, Neeraj Srinivas Thirumalai, Hyun-Woo Jin, Jayoung Koo, John Roger Peterson, Robert Lee Antram, Christopher John Fowler
-
Patent number: 7435468Abstract: A multi-layer structure whose volume changes when a temperature exceeds a predetermined threshold value, a microscopic structure drawing method that involves emitting a laser beam onto the multi-layer structure to create a temperature distribution within a beam spot and performing microscopic recording on a portion of the beam spot having a temperature higher than the threshold value, an optical disc master, and a mastering method using the same, where the multi-layer structure includes a substrate and a transformation layer formed on the substrate, wherein a volume of a portion of the transformation layer irradiated by a laser beam changes when the temperature of the portion exceeds a predetermined temperature. The microscopic structure drawing method includes emitting the laser beam onto a predetermined region of the transformation layer and heating the region of the transformation layer irradiated by the laser beam beyond a predetermined temperature so that the heated region can undergo a volume change.Type: GrantFiled: May 20, 2004Date of Patent: October 14, 2008Assignees: Samsung Electronics Co., Ltd., National Institute of Advanced Industrial Science and TechnologyInventors: Joo-ho Kim, In-sik Park, Masashi Kuwahara, Junji Tominaga, Takayuki Sima
-
Patent number: 7435486Abstract: A coated cutting insert for metal machining, in particular of short chipping materials, includes a tungsten carbide-based substrate with a binder phase enriched surface zone having at least one rake face and at least one clearance face intersecting to form a cutting edge. The binder phase enriched surface zone is at least partly missing on the rake face including at least a part of the surface extending from the cutting edge. As a result, an optimum combination of edge strength and wear resistance has been achieved.Type: GrantFiled: June 20, 2005Date of Patent: October 14, 2008Assignee: Seco Tools ABInventors: Silvia Dahlund, Andreas Larsson
-
Patent number: 7431998Abstract: The invention relates to a tool, especially a cutting tool, comprising a substrate member onto which at least one layer is deposited by means of CVD, and a method for the chemical vapor deposition of a two-phase layer on a sintered part. According to the invention, the single deposited layer or at least one of the layers is provided with a TiCN phase, TiOCN phase, TiOC phase, or TiC phase and an additional phase consisting of ZrO2 and/or HfO2. CH3CN, C5H5N, or C6H6 is used in the gas atmosphere for producing such a layer in addition to TiCl4, HfCl4, and/or ZrCl4 and CO2, the remainder being composed of H2 and/or Ar.Type: GrantFiled: April 23, 2004Date of Patent: October 7, 2008Assignee: Kennametal Widia Produktions GmbH & Co. KGInventors: Volkmar Sottke, Hartmut Westphal, Hendrikus Van Den Berg
-
Publication number: 20080241506Abstract: A protected polymeric film comprises a polymeric film substrate having a first major surface and a second major surface opposite the first major surface, and a protective structure provided on at least the first major surface of the substrate, wherein the protective structure comprises a layer of boron oxide and an inorganic barrier layer. A protective structure may also be provided on the second major surface of the substrate. Organic electronic components may be formed on or attached to the protected polymeric films.Type: ApplicationFiled: June 11, 2008Publication date: October 2, 2008Inventors: Fred B. McCormick, Manoj Nirmal, George V. Tiers
-
Publication number: 20080241479Abstract: The subject of the invention is the use of a material composed of a substrate equipped with a coating based on titanium oxide surmounted by a thin hydrophilic layer forming at least one part of the outer surface of said material and that is not composed of titanium oxide, as a material that prevents the deposition of mineral soiling on said outer surface in the absence of water runoff.Type: ApplicationFiled: October 20, 2006Publication date: October 2, 2008Applicant: SAINT-GOBAIN GLASS FRANCEInventors: Bernard Nghiem, Georges Zagdoun, Elin Sondergard, Ronan Garrec, Eddy Royer, Andriy Kharchenko, Anne Lelarge, Etienne Barthel
-
Publication number: 20080241561Abstract: An organic light emitting display device and a method of fabricating the same, in which a resonance effect is suppressed and transmittance is substantially the same in a wavelength band of visible light. The organic light emitting display device includes: a substrate; a first electrode disposed on the substrate and including a reflection layer; an organic layer disposed on the first electrode and including a white emission layer; a second electrode disposed on the organic layer; a transmittance controlled layer disposed on the second electrode; and a metal layer disposed on the transmittance controlled layer.Type: ApplicationFiled: November 8, 2007Publication date: October 2, 2008Inventors: Hee-Seong Jeong, Sam-Il Kho, Byeong-Wook Yoo, Seong-Taek Lee, Jun-Sik Oh, Gun-Shik Kim
-
Patent number: 7429424Abstract: In accordance with an embodiment of the invention, a thermal barrier coating (TBC) for inclusion in a thermal barrier coating/environmental barrier coating system (TBC/EBC system) for use on a silicon containing material substrate is provided. The TBC comprises a compound having a primary constituent portion and a stabilizer portion stabilizing said primary constituent. The primary constituent portion of the TBC comprises hafnia present in an amount of at least about 5 mol % of the primary constituent. The stabilizer portion of said thermal barrier coating comprises at least one metal oxide comprised of cations with a +2 or +3 valence present in the amount of about 10 to about 40 mol % of the thermal barrier coating.Type: GrantFiled: December 6, 2004Date of Patent: September 30, 2008Assignee: General Electric CompanyInventors: Brett Allen Rohrer Boutwell, Irene Spitsberg, Christine Govern, Bangalore A. Nagaraj, Brian Thomas Hazel
-
Publication number: 20080220209Abstract: This invention relates to thermally sprayed coatings of a high purity yttria or ytterbia stabilized zirconia powder, said high purity yttria or ytterbia stabilized zirconia powder comprising from about 0 to about 0.15 weight percent impurity oxides, from about 0 to about 2 weight percent hafnium oxide (hafnia), from about 6 to about 25 weight percent yttrium oxide (yttria) or from about 10 to about 36 weight percent ytterbium oxide (ytterbia), and the balance zirconium oxide (zirconia). Thermal barrier coatings for protecting a component such as blades, vanes and seal surfaces of gas turbine engines, made from the high purity yttria or ytterbia stabilized zirconia powders, have a density greater than 88% of the theoretical density with a plurality of vertical macrocracks homogeneously dispersed throughout the coating to improve its thermal fatigue resistance.Type: ApplicationFiled: April 27, 2007Publication date: September 11, 2008Inventors: Thomas Alan Taylor, Danny Lee Appleby, Albert Feuerstein, Ann Bolcavage, Neil Hitchman
-
Patent number: 7416778Abstract: The present invention relates to a method of machining a metal work piece with a coated cutting tool insert having a cemented carbide body and a coating deposited as monolayer(s) or as multiple and/or alternating layers. The coating has a total thickness of from about 25 to about 75 ?m and the machining is performed at a cutting speed of greater than about 600 m/min, preferably from about 800 to about 1500 m/min. The invention also relates to a coated cutting tool useful for such machining operation.Type: GrantFiled: October 3, 2005Date of Patent: August 26, 2008Assignee: Sandvik Intellectual Property ABInventors: Kenneth Westergren, Marian Mikus, Leif Åkesson
-
Patent number: 7416788Abstract: A turbine engine component includes an electron beam-physical vapor deposition thermal barrier coating covering at least a portion of a substrate. The thermal barrier coating includes an inner layer having a columnar-grained microstructure with inter-columnar gap porosity. The inner layer includes a stabilized ceramic material. The thermal barrier coating also includes a substantially non-porous outer layer, covering the inner layer and including the stabilized ceramic material. The outer layer is deposited with continuous line-of-sight exposure to the vapor source under oxygen deficient conditions. The outer layer may further comprise a dopant oxide that is more readily reducible than the stabilized ceramic material. During deposition, the outer layer may also have an oxygen deficient stoichiometry with respect to the inner layer. Oxygen stoichiometry in the outer layer may be restored by exposure of the coated component to an oxidizing environment.Type: GrantFiled: June 30, 2005Date of Patent: August 26, 2008Assignee: Honeywell International Inc.Inventors: Margaret M. Floyd, Thomas E. Strangman, Derek Raybould, Paul J. Mravcak
-
Publication number: 20080199711Abstract: A heat resistant member includes a metal or ceramic substrate and a thermal-barrier coating layer disposed on the substrate. The thermal-barrier coating layer includes a metal layer functioning as a bonding layer and one or more ceramic layers disposed on the metal layer. At least one of the ceramic layers is mainly composed of a hafnium oxide-based ceramic layer containing 85% or more of hafnium oxide. Due to the above structure, there can be provided a heat resistant member with high heat resistance and durability which has a thermal-barrier coating layer with stable thermal conductivity at elevated temperatures, namely, not less than 1,200° C., and resistance to cracking and delamination due to sintering.Type: ApplicationFiled: February 14, 2008Publication date: August 21, 2008Applicant: KABUSHIKI KAISHA TOSHIBAInventors: Yutaka ISHIWATA, Kazuhide Matsumoto, Yoshiyasu Ito
-
Patent number: 7413798Abstract: A ceramic thermal barrier coating material (10) containing nano-sized features is predicted to exhibit improved high temperature performance than a comparable material containing fewer of such features. In a coating deposited by an APS process, the nano-sized features may be intersplat columns (32). In a coating deposited by an EB-PVD process, the nano-sized features may be a mixed oxide layer (22) formed of nano-sized mixed oxide particles, or nano-sized alumina projections (24) extending across the interface from the mixed oxide layer into the insulating material layer (20). Alternatively, the nano-sized features may be secondary columnar grains (36) extending laterally from primary columnar grains (34) in a columnar-grained ceramic material.Type: GrantFiled: April 2, 2004Date of Patent: August 19, 2008Assignee: Siemens Power Generation, Inc.Inventors: Andrew Jeremiah Burns, Ramesh Subramanian
-
Patent number: 7413808Abstract: An article has a metallic substrate having a first emissivity. A thermal barrier coating atop the substrate may have an emissivity that is a substantial fraction of the first emissivity.Type: GrantFiled: October 18, 2004Date of Patent: August 19, 2008Assignee: United Technologies CorporationInventors: Steven W. Burd, Robert M. Sonntag, Kevin W. Schlichting
-
Patent number: 7410707Abstract: The present invention provides a surface-coated cutting tool comprising a coating film on a base, while the coating film comprises a hard layer constituted of a compound selected from a nitride, a carbonitride, an oxynitride and a carboxynitride of at least one primary element selected from a group consisting of the metals belonging to the groups 4a, 5a and 6a of the periodic table as well as B, Al and Si, and the hard layer satisfies the following: (a) (hmax?hf)/hmax is at least 0.2 and not more than 0.7, assuming that hmax represents the maximum indentation depth and hf represents the indentation depth (dent depth) after unloading in a hardness test according to nanoindentation, (b) the thickness of the hard layer is at least 0.5 ?m and not more than 15 ?m, and (c) the hardness according to nanoindentation is at least 20 GPa and not more than 80 GPa.Type: GrantFiled: December 2, 2004Date of Patent: August 12, 2008Assignee: Sumitomo Electric Hardmetal Corp.Inventors: Haruyo Fukui, Naoya Omori
-
Publication number: 20080186655Abstract: A semiconductor ceramic comprising a donor element within the range of 0.8 to 2.0 mol relative to 100 mol of Ti element contained as a solid solution with crystal grains, a first acceptor element in an amount less than the amount of the donor element is contained as a solid solution with the crystal grains, a second acceptor element within the range of 0.3 to 1.0 mol relative to 100 mol of a Ti element is present in crystal grain boundaries, and the average grain size of the crystal grains is 1.0 ?m or less. A monolithic semiconductor ceramic capacitor is obtained by using this semiconductor ceramic. To form the semiconductor ceramic, in a first firing treatment to conduct reduction firing, a cooling treatment is conducted while the oxygen partial pressure at the time of starting the cooling is set at 1.0×104 times or more the oxygen partial pressure in the firing process.Type: ApplicationFiled: March 3, 2008Publication date: August 7, 2008Applicant: MURATA MANUFACTURING CO., LTD.Inventor: MITSUTOSHI KAWAMOTO
-
Patent number: 7399538Abstract: A solid body tribological pairing for machine parts comprising a first slide element from a first basic material and a second slide element from a second basic material is characterized in that at least one of the slide elements comprises a lubricant in the form of a hydroxide compound introduced into the basic material before its use as a machine part.Type: GrantFiled: May 8, 2003Date of Patent: July 15, 2008Assignee: AMOVIS GmbHInventor: Michael Hoetger
-
Patent number: 7396592Abstract: The invention relates to a composite target in the form of a bar made of ceramic powders and designed to be evaporated under an electron beam, the target comprising zirconia and at least one zirconia stabilizer. In characteristic manner, said target is wherein said zirconia stabilizer is at a molar content lying in the range 2% to 30% and wherein said zirconia is formed by more than 90% of a monoclinic phase. The invention is applicable to fabricating a ceramic thermal barrier of low thermal conductivity and high thermomechanical strength formed by evaporation under an electron beam.Type: GrantFiled: December 10, 2007Date of Patent: July 8, 2008Assignees: Snecma, Snecma ServicesInventors: Bertrand Saint-Ramond, Andre Malie, Christophe Chaput, Isabelle Porte, Cyrille Delage
-
Patent number: 7396371Abstract: The present invention relates to a cutting insert particularly for turning of stainless steel comprising a cemented carbide substrate and a post-treated coating with a substrate of cemented carbide having a composition of from about 5.0 to less than about 8.0 wt % Co, from about 3.0 to about 8.0 wt % cubic carbides of the metals Ti, Ta and Nb with a Ti/(Ti+Ta+Nb) ratio of from about 0.05 to about 0.3 and balance tungsten carbide (WC) having a grain size of from about 1.5 to about 3.5 ?m in the as-sintered state. Further, the substrate has a surface zone of from about 5 to about 30 ?m characterized by an enrichment of binder phase and a depletion of cubic carbides, and a coating having a first, innermost layer system of one or several layers of TiCxNyOz with x+y+z?1 with a total thickness of from about 0.7 to about 5.Type: GrantFiled: June 24, 2005Date of Patent: July 8, 2008Assignee: Sandvik Intellectual Property ABInventors: Gunilla Cedergren, Mikael Lindholm, Ann-Britt Ljungberg, Mikael Lagerquist, Frida Cullin
-
Publication number: 20080160329Abstract: Disclosed is a multilayer coating for a quasi-phase-matching (QPM) element having a substrate made of lithium metallate. The multilayer coating comprises a first layer which is in contact with the substrate and made of an oxide of a metal constituting the metallate in the lithium metallate. Specifically, when the substrate is made of lithium tantalate (LiTaO5), the first layer may be made of tantalum pentoxide (Ta2O5). When the substrate is made of lithium niobate (LiNbO3), the first layer may be made of niobium trioxide (Nb2O3). The multilayer coating of the present invention can provide a high-performance quasi-phase-matching element on the basis of consideration of a relationship between the substrate and the first layer of the multilayer coating.Type: ApplicationFiled: October 17, 2007Publication date: July 3, 2008Applicant: SHIMADZU CORPORATIONInventor: Ryo Tateno
-
Patent number: 7393589Abstract: Coatings for use in artificial joints and other implanted medical devices. The coatings comprise a dual layer structure vapor deposited atop a medical grade substrate, such as cobalt chromium. The dual layer structure comprises a first ceramic layer vapor deposited atop at least a portion of the substrate and a second ceramic layer deposited atop the first ceramic layer. The first ceramic layer is formed of a material which has particularly good adhesion to the substrate, and the second ceramic layer from a material exhibiting particularly high hardness and good wear characteristics. The vapor deposition process is controlled so as to form a graded interface between the two ceramic layers to form a dual layer coating which resists delamination, adheres well to the substrate, and exhibits good wear characteristics in situ.Type: GrantFiled: January 28, 2005Date of Patent: July 1, 2008Assignee: Ionbond, Inc.Inventors: Robert Aharonov, Raymond Fontana
-
Publication number: 20080138636Abstract: Provided is a surface processing of titanium alloy members for aerospace equipment having high wear resistance, lubricity and high fatigue strength. The method is characterized in that it comprises an oxygen diffusion step for causing oxygen to diffuse and penetrate in solid solution form into a surface of a titanium alloy member under an oxygen-containing gas atmosphere and a particle bombardment step for bombarding the surface of the titanium alloy member with an airflow containing particles. Also provided are a flap rail member and slat rail member for aircraft.Type: ApplicationFiled: February 16, 2005Publication date: June 12, 2008Inventors: Kazuyuki Oguri, Takashi Kimura, Takahiro Sekigawa, Takayuki Takahashi
-
Publication number: 20080138658Abstract: A turbine engine component is provided which has a substrate and a thermal barrier coating applied over the substrate. The thermal barrier coating comprises at least one layer of a first material selected from the group consisting of a zirconate, a hafnate, a titanate, and mixtures thereof, which first material has been mixed with, and contains, from about 25 to 99 wt % of at least one oxide. The at least one oxide comprises at least one oxide of a material selected from the group consisting of lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium, scandium, indium, and yttrium. If desired, a metallic bond coat may be present between the substrate and the thermal barrier coating system. A method for forming the thermal barrier coating system of the present invention is described.Type: ApplicationFiled: January 20, 2006Publication date: June 12, 2008Inventors: David A. Litton, Kevin W. Schlichting, Melvin Freling, John G. Smeggil, David B. Snow, Michael J. Maloney
-
Publication number: 20080131711Abstract: A thermal barrier coating (TBC) system (450) capable of self-healing has a substrate (420), a metal-based advanced bond coat (435) overlying the substrate and a ceramic top coat (440) overlying the bond coat. The bond coat (435) comprises ceramic oxide precursor materials capable of forming a non-alumina ceramic oxide composition when exposed to a thermally conditioning oxidizing environment. Embodiments of such bond coat (435) comprise rare earth elements in a range of 1-20 weight percent, and Hf in a range of about 5 to 30 weight percent or Zr in a range of about 2 to 20 weight percent. Examples of self-healing TBC systems (400, 402, 404) are provided using such bond coat (435) or its advanced bond coat chemistries in combination with conventional bond coats (433, 437) or conventional bond coat chemistries.Type: ApplicationFiled: December 1, 2006Publication date: June 5, 2008Inventors: Anand A. Kulkarni, Ramesh Subramanian, Andrew J. Burns
-
Publication number: 20080125262Abstract: The pins of a roller chain or rollerless bushing chain for an automobile engine are subjected to chromizing treatment that forms a two part outer layer having a thick inner section composed primarily of Cr7C3 and a thinner, outermost, layer composed primarily of Cr23C6. The outer layer has convex protrusions and concave recesses. The protrusions are partially removed by barrel polishing to a level such that the depth of each recess is sufficient, but not substantially greater than necessary, for an inclusion received therein to be substantially entirely below the outer surface of the pin, thereby making the surface pressure exerted by portions of the pin on a surrounding bushing substantially as small as possible without exposure of inclusions beyond the outer surface of the pin.Type: ApplicationFiled: August 27, 2007Publication date: May 29, 2008Applicant: Tsubakimoto Chain Co.Inventor: Shota Miyanaga
-
Patent number: 7378158Abstract: Structural components that are subject to high stresses, especially caused by wear, can be protected by coating them with a hard material. For metal-cutting tools it is for example known that their wear resistance can be improved by coating them with a hard material. Different thermal expansion coefficients of the substrate material and the coating material and different layer materials in a multilayer coating may produce great stresses. The stress increases as the thickness of the coating increases, thereby increasing the danger of the coating chipping off. In order to solve this problem, the invention proposes an intermediate layer (5) to be interposed between at least two layers (4, 9) of the coating (3), said intermediate layer mainly or exclusively consisting of a material component (6, 8) of an element of the fourth to eighth subgroup of the fourth and fifth period of the periodic system.Type: GrantFiled: February 26, 2002Date of Patent: May 27, 2008Assignee: CeramTec AGInventors: Gert Richter, Michael Fripan, Daniel Von Buren
-
Patent number: 7374821Abstract: The invention relates to a ceramic thermal barrier composition of low conductivity and high high-temperature strength. In characteristic manner, the composition comprises a zirconia base, at least one trivalent oxide enabling the zirconia to be stabilized and enabling the thermal conductivity of the zirconia to be reduced in optimum manner, and at least one pentavalent oxide enabling the content of oxygen vacancies to be reduced so as to make it substantially equal to that of a partially stabilized zirconia. Preferably, said trivalent oxide is present with a molar content constituted by a first portion enabling the zirconia to be stabilized partially and a second portion which introduces point defects into the lattice said pentavalent oxide is present with a molar concentration equal to said molar concentration of said second portion of the trivalent oxide. The invention is applicable to making a superalloy machine part having a ceramic coating with said composition, and possibly also a bonding underlayer.Type: GrantFiled: August 5, 2004Date of Patent: May 20, 2008Assignees: Snecma, Snecma ServicesInventors: Bérangère Leclercq, Rémy Mevrel, Alban Azzopardi, André Malie, Bertrand Saint-Ramond
-
Patent number: 7368183Abstract: An aqueous titanium oxide-dispersed sol comprising titanium oxide particles dispersed in water, said sol comprising chloride ions in an amount of 50 to 10,000 ppm by weight as the chlorine element. Titanium tetrachloride is hydrolyzed to form an aqueous titanium oxide-dispersed sol and the chloride ion concentration thereof is controlled. Another aqueous titanium oxide-dispersed sol comprising brookite-type titanium oxide particles dispersed in water, said titanium oxide particles having an average particle size of not more than 0.5 ?m and a specific surface area of not less than 20 m2/g. Addition of titanium tetrachloride to hot water at 75 to 100° C. followed by hydrolysis at 75° C. to the boiling point of the mixture.Type: GrantFiled: January 9, 2004Date of Patent: May 6, 2008Assignee: Showa Denko K.K.Inventors: Masahiro Ohmori, Tadashi Hamanaka, Hidenori Nakamura
-
Patent number: 7364806Abstract: A thermal barrier coating system comprising a metal substrate, a metal bonding layer and a ceramics thermal barrier layer wherein the ceramics thermal barrier layer has a columnar structure of a stabilized zirconia containing a stabilizer or a stabilized ZrO2—HfO2 solid solution containing a stabilizer, and comprises 0.1 to 10 mol % of lanthanum oxide.Type: GrantFiled: February 13, 2004Date of Patent: April 29, 2008Assignees: Japan Fine Ceramics Center, Ishikawajima-Harima Heavy Industries Co., Ltd.Inventors: Mineaki Matsumoto, Norio Yamaguchi, Kazushige Kimura, Hideaki Matsubara, Yasuo Matsunaga, Kouichi Matsumoto, Yasuhiro Shigegaki, Takahito Araki
-
Patent number: 7366554Abstract: The present invention selectively uses a high-impedance layer to reduce the effects of E-M scattering at metallic discontinuities. The high-impedance layer can be fabricated using a combination of metallic and resistive materials that are typically used in electro-static discharging (ESD) applications. A thin layer of metal can be deposited on the surface of a dielectric substrate such as polyethylene. This metallic layer can be on an inner, outer, or buried layer of the material. The metallic layer allows the RF induced currents to spread out over a designated surface area. A layer of resistive material can be applied to a similar dielectric layer. The resistive layer provides sufficient attenuation to decrease the RF surface waves and minimize electro-magnetic scattering on the printed circuit board (PCB). Furthermore, since the metallic and resistive materials can be applied in very thin layers, sufficient transparency can be preserved in desired areas such as the mobile phone's display region.Type: GrantFiled: August 9, 2004Date of Patent: April 29, 2008Assignee: Sony Ericsson Mobile Communications ABInventor: Gerard James Hayes
-
Patent number: 7364802Abstract: Ceramic compositions comprising at least about 91 mole % zirconia and up to about 9 mole % of a stabilizer component comprising a first metal oxide having selected from the group consisting of yttria, calcia, ceria, scandia, magnesia, india and mixtures thereof. This stabilizer component further comprises a second metal oxide of a trivalent metal atom selected from the group consisting of lanthana, gadolinia, neodymia, samaria, dysprosia, erbia, ytterbia, and mixtures thereof. These ceramic compositions are useful in preparing thermal barrier coatings having reduced thermal conductivity for the metal substrate of articles that operate at, or are exposed to, high temperatures.Type: GrantFiled: December 30, 2003Date of Patent: April 29, 2008Assignee: General Electric CompanyInventors: Irene Spitsberg, Venkat Subramanian Venkataramani, Brett Allen Boutwell, Mark Daniel Gorman, Robert William Bruce
-
Patent number: 7357068Abstract: The invention relates to a material based on an oxide ceramic for the manufacture of a surface layer (5) by means of a thermal coating process including aluminum oxide and zirconium oxide, with the material additionally containing chromium oxide for the simultaneous optimization of the hardness and toughness of the surface layer (5).Type: GrantFiled: January 6, 2006Date of Patent: April 15, 2008Assignee: Sulzer Metco AGInventor: Gérard Barbezat
-
Publication number: 20080057326Abstract: A thermal barrier coating system for use on a turbine engine component which reduces sand related distress is provided. The coating system comprises at least one first layer of a stabilized material selected from the group consisting of zirconia, hafnia, and titania and at least one second layer containing at least one of oxyapatite and garnet. Where the coating system comprises multiple first layers and multiple second layers, the layers are formed or deposited in an alternating manner.Type: ApplicationFiled: September 6, 2006Publication date: March 6, 2008Inventors: Kevin W. Schlichting, David A. Litton, Michael J. Maloney, Melvin Freling, John G. Smeggil, David B. Snow
-
Patent number: 7338714Abstract: The regionally coated noble metal element for use in glass production has an uncoated region for contacting a glass melt and a side opposite from the uncoated region is provided with an H2-impervious layer or an H2-impervious and O2-impervious layer. The H2-impervious layer or H2-impervious and O2-impervious layer has a thickness greater than or equal to 1 mm, is heat-resistant, liquid, or solid. This layer is made from at least one partly or completely crystallized glass or a glass mixture or a ceramic material. Processes for coating the noble metal element are also described.Type: GrantFiled: November 29, 2001Date of Patent: March 4, 2008Assignee: Schott AGInventors: Franz Ott, Dirk Gohlke, Joerg Witte
-
Patent number: 7332228Abstract: A setter used in sintering and having an oxide coating layer is configured such that oxide powder of at least one of, or a mixture of oxide powders of two or more of alumina, silica, zirconia, yttria, titania, magnesia, and calcia is deposited to at least one surface of a metal composed of molybdenum, tungsten, or an alloy of a molybdenum group and a tungsten group, and a deposition surface thereof allows no exposure of the base material.Type: GrantFiled: February 24, 2004Date of Patent: February 19, 2008Assignee: A.L.M.T. CorporationInventors: Yoshitake Fukaya, Hiroshi Yoshida, Masahiro Katoh
-
Patent number: 7332021Abstract: A coating composition comprising an aqueous mixture containing acid-stable particles and one or more fluoroacids. The amount of the acid-stable particles in the coating composition is from 0.005% to 8% by weight on a dry weight basis. The acid-stable particles can be selected from aluminum-modified silica particles, nonaluminum-modified silica particles, and organic particles selected from anionically stabilized polymer dispersion particles. The invention is also directed to a coating on a metal substrate. The coating contains acid-stable particles attached to the metal substrate through a metal-oxide matrix. The metal-oxide matrix comprises a metal selected from titanium, zirconium, silicon, hafnium, boron, aluminum, germanium, or tin.Type: GrantFiled: July 22, 2003Date of Patent: February 19, 2008Assignee: Henkel Kommanditgesellschaft auf AktienInventors: William E. Fristad, Jeng-Li Liang, David C. Montrose
-
Patent number: 7326470Abstract: A spallation resistant metallic article comprising a metallic substrate, at least one ceramic thermal barrier coating comprising a zirconia base and at least one other element selected from the group consisting of La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Sc, In, Y, Mo and C, rare earth oxides, scandium, and indium, and a ceramic bond coat located on at least a portion of the substrate and between the metallic substrate and the at least one ceramic thermal barrier coating wherein the ceramic bond coat is composed of yttria stabilized zirconia (YSZ).Type: GrantFiled: April 28, 2004Date of Patent: February 5, 2008Assignee: United Technologies CorporationInventors: Nicholas E. Ulion, Mladen Trubelja, Michael J. Maloney, David A. Litton
-
Patent number: 7309528Abstract: A protective coating composition comprising a silicate, such as an organosilicate, an organosilicate polymer and colloidal silica and an organic titanate, preferably a titanate chelate or a titanate ester in a suitable organic solvent. The composition is free from metal particles.Type: GrantFiled: April 23, 2002Date of Patent: December 18, 2007Assignee: Dow Corning GmbHInventors: Vittorio Clerici, Alexandra Wilhelmi
-
Publication number: 20070259173Abstract: Using this method, a coating (1) is manufactured on a substrate (2), which forms a surface of a base body. In this method a layer (3) with ceramic coating material is applied to the substrate in a process chamber (6) using a plasma beam (30) and using an LPPS or LPPS-TF process. The substrate contains at least one metal Me. At a set reaction temperature of the substrate and in the presence of oxygen an oxide, which results reactively with metal M diffused on the surface, is generated as a ceramic intermediate layer (4). The ceramic layer (3) is deposited on this intermediate layer.Type: ApplicationFiled: April 30, 2007Publication date: November 8, 2007Applicant: Sulzer Metco AGInventors: Arno Refke, Wolfram Beele
-
Patent number: 7288328Abstract: An article for use in hostile thermal environments, such as a component of a gas turbine engine. The article includes a nickel-base superalloy substrate that is prone to formation of a deleterious secondary reaction zone (SRZ), and an overlay coating having a predominantly gamma prime-phase nickel aluminide (Ni3Al) composition suitable for use as an environmental coating, including a bond coat for a thermal barrier coating. The coating comprises a chromium-containing nickel aluminide intermetallic overlay coating of predominantly the gamma prime phase, in which aluminum is present in the coating in an amount approximately equal to the aluminum content of the superalloy substrate so as to inhibit diffusion of aluminum from the overlay coating into the superalloy substrate.Type: GrantFiled: October 29, 2004Date of Patent: October 30, 2007Assignee: General Electric CompanyInventors: Ramgopal Darolia, William Scott Walston
-
Patent number: 7288324Abstract: Novel, monodispersed, spherical ZrO2 particles in the size range of approximately 10 to approximately 600 nm exhibiting metastable tetragonal crystal structure at room temperature and novel methods of preparation. The ZrO2 particles are approximately 100% in the tetragonal phase at room temperature and can be pure and free of foreign oxides. The novel method can include mixing zirconium-alkoxide and an alcohol, forming preparation one, followed by separately dissolving completely de-ionized water and a polymeric steric stabilizer in an alcohol forming preparation two. Next the preparations can be mixed with vigorous stirring while subjecting the materials to hydrolysis and condensation reactions with very slow stirring. Next, there is waiting for the formation of a sol from the mixture, followed by drying at approximately 80 degrees C. to form resultant material followed by crushing the resultant material.Type: GrantFiled: September 5, 2003Date of Patent: October 30, 2007Assignee: University of Central Florida Research Foundation, Inc.Inventors: Sudipta Seal, Satyajit Shukla
-
Patent number: 7288332Abstract: A conductive layer for biaxially oriented semiconductor film growth and a thin film semiconductor structure such as, for example, a photodetector, a photovoltaic cell, or a light emitting diode (LED) that includes a crystallographically oriented semiconducting film disposed on the conductive layer. The thin film semiconductor structure includes: a substrate; a first electrode deposited on the substrate; and a semiconducting layer epitaxially deposited on the first electrode. The first electrode includes a template layer deposited on the substrate and a buffer layer epitaxially deposited on the template layer. The template layer includes a first metal nitride that is electrically conductive and has a rock salt crystal structure, and the buffer layer includes a second metal nitride that is electrically conductive. The semiconducting layer is epitaxially deposited on the buffer layer. A method of making such a thin film semiconductor structure is also described.Type: GrantFiled: October 6, 2005Date of Patent: October 30, 2007Assignee: Los Almos National Security, LLCInventors: Alp T. Findikoglu, Vladimir Matias
-
Patent number: RE39912Abstract: Coated milling insert has a WC-Co cemented carbide with a low content of cubic carbides and a highly W-alloyed binder phase and a coating including an inner layer of TiCxNy with columnar grains followed by a layer of ?-Al2O3 and a top layer of TiN. The coated milling insert is particularly useful for milling of grey cast iron with or without cast skin under wet conditions at low and moderate cutting speeds and milling of nodular cast iron and compacted graphite iron with or without cast skin under wet conditions at moderate cutting speeds.Type: GrantFiled: June 9, 2006Date of Patent: November 6, 2007Assignee: Sandvik Intellectual Property ABInventors: Anders Nordgren, Ingemar Hessman, Marian Mikus
-
Patent number: RE39986Abstract: The present invention relates to a coated cutting tool insert useful for grooving or severing steel components such as steel or stainless steel tubes and bars. The insert is characterized by WC—Co-based cemented carbide substrate having a highly W-alloyed Co-binder phase and a relatively thin coating including an inner layer of TiCxNyOz with columnar grains followed by a layer of fine grained ?—Al2O3 and a top layer of TiN.Type: GrantFiled: June 8, 2006Date of Patent: January 1, 2008Assignee: Sandvik Intellectual Property ABInventors: Ingrid Reineck, Torbjorn Selinder, Anders Piirhonen, Gregor Kullander
-
Patent number: RE39998Abstract: Composite wear component produced by casting and consisting of a metal matrix whose working face or faces includes inserts which have a very high wear resistance, characterized in that the inserts consist of a ceramic pad, this ceramic pad consisting of a homogeneous solid solution of 20 to 80% of Al2O3 and 80 to 20% of ZrO2, the percentages being expressed by weights of the constituents, and the pad then being impregnated with a liquid metal during the casting.Type: GrantFiled: August 27, 1997Date of Patent: January 8, 2008Assignee: Magotteaux International S.A.Inventor: Hubert Francois
-
Patent number: RE39999Abstract: A coated turning insert particularly useful for turning in stainless steel is disclosed. The insert is characterized by a WC—Co-based cemented carbide substrate having a highly W-alloyed Co-binder phase and a coating including an inner layer of TiCxNyOz with columnar grains followed by a layer of fine-grained, ?-Al2O3 and a top layer of TiN. The layers are deposited by using CVD methods.Type: GrantFiled: November 29, 1996Date of Patent: January 8, 2008Assignee: Sandvik Intellectual Property ABInventors: Per Lindskog, Per Gustafson, Björn Ljungberg, Åke Östlund
-
Patent number: RE40005Abstract: There is disclosed a coated cutting insert particularly useful for cutting in cast iron materials. The insert is characterized by a straight WC-Co cemented carbide body having a highly W-alloyed Co binder phase, a well-defined surface content of Co and a coating including an innermost layer of TiCxNyOz with columnar grains, a layer of a fine-grained, textured Al2O3 layer and a top layer of TiCxNyOz that has been removed along the cutting edge line.Type: GrantFiled: June 9, 2006Date of Patent: January 15, 2008Assignee: Sandvik Intellectual Property ABInventors: Asa Kutscher, Kenneth Westergren, Björn Ljungberg, Anders Lenander
-
Patent number: RE40025Abstract: The present invention relates to a coated cutting tool (e.g.—cemented carbide insert) useful for grooving or parting of steel or stainless steel components such as tubes and bars. The insert is characterised by a WC-Co-based cemented carbide substrate having a highly W-alloyed Co-binder phase and a hard and wear resistant coating including a multilayered structure of sublayers of the composition (TixAl1-x)N with a periodic and repeated variation of the Ti/Al ratio.Type: GrantFiled: June 8, 2006Date of Patent: January 22, 2008Assignee: Sandvik Intellectual Property ABInventors: Anders Jonsson, Anders Piirhonen, Torbjörn Selinder, Gregor Kullander