Ester, Halide Or Nitrile Of Addition Polymer Patents (Class 428/514)
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Patent number: 5151331Abstract: A film comprising alternating layers of polyvinylidene chloride resin and a solvent barrier such as polyvinyl alcohol provides superior barrier properties. Barrier and mechanical properties are enhanced when formulation additives are present at customary levels only in the outermost layers.Type: GrantFiled: February 5, 1992Date of Patent: September 29, 1992Assignee: E. I. du Pont de Nemours and CompanyInventors: Charles L. Beeson, Raymond T. Cole, Gedeon I. Deak, Harbeson H. Leidolf, Jr.
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Patent number: 5147940Abstract: A core/shell polymer is capable of increasing a composition's whiteness or opacity. The core and shell polymers have either a crystalline structure or have a T.sub.g of at least about 50.degree. C. The core polymer has a different composition than the composition of the shell polymer. The core polymer comprises vinylidene halide monomers and/or vinyl halide monomers. The core and shell polymers are either homopolymers or copolymers.Type: GrantFiled: April 8, 1991Date of Patent: September 15, 1992Assignee: Union Oil Company of CaliforniaInventor: John Biale
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Patent number: 5143904Abstract: A dye image-receiving sheet for thermal transfer printing systems, comprising a substrtate sheet composed of a support paper sheet, a front coated layer comprising a thermoplastic resin, and optionally, a back coated layer comprising a thermoplastic resin; and a dye image-receiving layer comprising a resinous material capable of being dyed with a sublimating dye, and characterized in that the front coating layer has a Bekk smoothness of 100 seconds or more and the substrate sheet has a rigidity of 700 mgf or less.Type: GrantFiled: July 13, 1990Date of Patent: September 1, 1992Assignee: Oji Paper Co., LtdInventors: Toshihiro Minato, Masaru Kato, Kenji Yasuda, Norio Yamamura, Masahiro Kamiya
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Patent number: 5135297Abstract: A method of modifying surfaces of polymeric objects which comprises immersing the polymeric object in an aqueous dispersion of a polymerizable surfactant, a cross-linking agent, and a free radical initiator and exposing the immersant to ultraviolet light to form a permanent, cross-linked surface coating on the object. Also disclosed are coated objects prepared by this method, which is particularly suited for coating contact lenses.Type: GrantFiled: November 27, 1990Date of Patent: August 4, 1992Assignee: Bausch & Lomb IncorporatedInventor: Paul L. Valint, Jr.
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Patent number: 5135784Abstract: A cutting tool for use on a wrapping web container containing a roll of a web for wrapping foods or the like. The cutting tool has a member made of a piece of paper having a toothed portion with teeth in the form of saw-teeth, the toothed portion having been hardened by being immersed in a liquid containing an alkyl .alpha.-cyanoacrylate and dried.Type: GrantFiled: July 31, 1990Date of Patent: August 4, 1992Assignee: Ayako OkumuraInventor: Eitaro Okumura
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Patent number: 5132144Abstract: Paperboard packaging material for use in the manufacture of cartons for browning and crisping food in a microwave oven is prepared on a printing press using an aqueous susceptor-ink composition comprising graphite or conductive carton black dispersed in a solution of sodium silicate. The susceptor-ink composition is printed on the packaging material in a pattern corresponding to the location of the food intended to be packaged and the food contact surface is overprinted with an FDA approved food contact coating. The use of sodium silicate as the binder for the susceptor-ink composition allows the composition to be printed by gravure or flexographic printing processes and provides hereto unavailable flame retardant properties to the final packaging material.Type: GrantFiled: August 30, 1990Date of Patent: July 21, 1992Assignee: Westvaco CorporationInventor: Christopher J. Parks
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Patent number: 5126176Abstract: Lidding of a sealant layer adhered to a substrate is provided wherein the sealant layer is a blend of ethylene/unsaturated ester copolymer with ethylene/unsaturated acid/unsaturated ester terpolymer, and wherein the sealant layer provides a peel strength of 500 to 2200 g/cm.sup.2 to a wide variety of container materials, with the peel strength being substantially insensitive to operating variations in seal temperature, and the sealant layer has a higher cohesive strength than the peel strength of its seal to the container material.Type: GrantFiled: January 18, 1991Date of Patent: June 30, 1992Assignee: E. I. Du Pont de Nemours and CompanyInventors: Karen U. Blaskovitz, Stephen R. Tanny
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Patent number: 5110657Abstract: An anti-skid coating composition for coating various substrates including structural panel board surfaces, comprises a binder made of urea formaldehyde resin, polyvinyl acetate, ammonium chloride and a dispersant. The binder is used in conjunction with an aggregate, such as walnut shells. A method is also provided for coating the substrates to impart slip resistance thereto.Type: GrantFiled: May 22, 1990Date of Patent: May 5, 1992Assignee: Reichhold Chemicals, Inc.Inventor: Winston C. Ainslie
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Patent number: 5089342Abstract: An improved aqueous coating agent for providing a decorative and protective coating for wood or wood products contains as a binder polyacrylate resins having chemically incorporated therein air-drying, unsaturated fatty acid moieties and quaternary ammonium moieties, and said agent is prepared by reactingA) excess polyacrylates containing epoxide groups and having an epoxide group equivalent weight of 200 to 1,300 withB) drying fatty acids, in an addition reaction with ester formation,C) reacting at least some of the remaining epoxide groups in the A)-B) reaction product with monoamine ammonium salts which contain an N-H bond in an addition reaction, anddissolving the reaction product obtained from step C) and containing quaternary ammonium groups in water.Type: GrantFiled: February 8, 1991Date of Patent: February 18, 1992Assignee: Bayer AktiengesellschaftInventors: Rolf Dhein, Thomas Scholl, Wolfgang Wellner, Lothar Backer
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Patent number: 5084348Abstract: An adhesive composition and accompanying tape wherein the adhesive is a water-soluble, pressure-sensitive adhesive mass consisting ofa) 100 parts by weight of at least one water-soluble copolymer of 55 to 90%-wt of at least one vinylcarbonic acid, 5 to 35%-wt of at least one hydroxyalkyl (meth-) acrylate, 1 to 15%-wt of at least one N-substituted (meth-)- acrylamide derivative of the formula ##STR1## in which R.sub.1 and R.sub.2 are the same or different and can represent an alkyl wherein one of R.sub.1 and R.sub.2 can also be a hydrogen atom, and R.sub.3 is a hydrogen atom or a methyl group, and 0.05 to 10%-wt of at least one vinylcarbonic acid salt,b) 50 to 200 parts by weight of at least one water-soluble softener including a polyoxyalkylene group having a molecular mass of up to 1000 andb) 0.1 to 8 parts by weight of a cross-linking agent.Type: GrantFiled: January 12, 1990Date of Patent: January 28, 1992Assignee: Lohmann GmbH & Co. KGInventors: Zbigniew Czech, Jorg Wehmann
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Patent number: 5079083Abstract: A coated sheet material is provided for wrapping, packaging or shipping food articles that are to be heated in a microwave oven. The sheet is formed from a paper or paperboard backing which is thermally and dimensionally stable when exposed to microwave energy. On at least one side is provided a smooth calendered surface or the sheet material is treated by processing as with a filler coating to fill the voids between the paper fibers and to thereby present a smooth surface. A microwave interactive layer is applied to the smoothed surface from a fluid or vapor state. The interactive coating can comprise carbon, a semiconductive metal coating or other microwave interactive material.Type: GrantFiled: February 7, 1991Date of Patent: January 7, 1992Assignee: Golden Valley Microwave Foods Inc.Inventors: James D. Watkins, David W. Andreas, David H. Cox
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Patent number: 5079097Abstract: The printing materials of the invention includes a film or sheet prepared from a chlorinated polyethylene containing 10 to 50 wt. % of chlorine and obtained by chlorinating a polyethylene having a molecular weight of 10,000 to 200,000, or from a polymer mixture containing the chlorinated polyethylene; a laminate comprising the film or sheet, and a base material; and a product prepared by impregnating or coating a base material with a solution of the chlorinated polyethylene or the polymer mixture. With the latter two printing materials, the surface of the film or sheet is used as the surface to be printed on. The image fixing method of the invention for use in producing copies by electrostatic printing comprises forming a toner image on one of these printing materials, and thereafter treating the printing material with heat at 160.degree. to 250.degree. C. for 5 to 30 seconds.Type: GrantFiled: October 14, 1988Date of Patent: January 7, 1992Assignee: Osaka Soda Co., Ltd.Inventors: Hiromi Sasaki, Masao Tojima, Satsuko Konishi, Hiroyuki Takana
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Patent number: 5077123Abstract: A laminated film comprising(A) a base layer of a polymer based on 4-methyl-1-pentene;(B) provided on at least one side of the base layer, an interlayer of an .alpha.-olefin copolymer comprising 10-85 mole % of propylene, 3-60 mole % of 1-butene and 10-85 mole % of .alpha.-olefin having 5 or more carbon atoms, a degree of crystallininty of the copolymer as measured by X-ray diffractometry being 20% or less; and(C) provided on the interlayer, a heat-sealable layer of an .alpha.-olefin polymer material predominantly comprising an .alpha.-olefin having 2 to 4 carbon atoms.Type: GrantFiled: May 24, 1988Date of Patent: December 31, 1991Assignee: Mitsui Petrochemical Industries, Ltd.Inventor: Hiromi Shigemoto
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Patent number: 5071688Abstract: The disclosure relates to a medium density overlay plywood panel used as an exterior trim product for a residential building having a relatively high number of plies to total board thickness, and exposed edges with void free sanded surfaces having a predetermined pattern coarseness, and in which said overlay and edge surfaces are covered with an acrylic paint, whereby the trim product is characterized with the appearance of a solid wood product and the painted surfaces as highly weather resistant.Type: GrantFiled: March 17, 1989Date of Patent: December 10, 1991Assignees: Harry O. Hoffman, Kathleen A. HoffmanInventor: Harry O. Hoffman
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Patent number: 5068139Abstract: A multilayered structural article having improved resistance to delamination and having a reduced coefficient of linear thermal expansion (CLTE) relative to that of the thermoplastic resin(s) employed in its preparation comprises a core layer of a highly filled composite paper having outer layers of thermoplastic resin adhered thereto.Type: GrantFiled: November 14, 1989Date of Patent: November 26, 1991Assignee: The Dow Chemical CompanyInventor: Kent B. McReynolds
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Patent number: 5064699Abstract: A semi-rigid, heat-sealable laminate with permanent antistatic characteristics comprising a semi-rigid packaging material having a coating of heat-sealable antistatic plastic. The antistatic plastic is a film of a modified acid copolymer. The modified acid copolymer is selected from (I) a mixture of (A) a polymer containing carboxylic acid moieties and (B) an antistatically effective amount of a quaternary amine, or (II) the acid/base reaction product of (A) a polymer containing carboxylic acid moieties and (C) an antistatically effective amount of an organic or inorganic base.Type: GrantFiled: March 6, 1990Date of Patent: November 12, 1991Assignee: W. R. Grace & Co.-Conn.Inventors: Marvin R. Havens, Stephen L. Fowler, William P. Roberts, Cynthia L. Ebner
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Patent number: 5063100Abstract: A panel, and method of making the panel, useful as a water barrier including an intermediate layer of a water-swellable colloidal clay, such as bentonite, sandwiched between two layers of sheet material, such as paperboard, wherein at least one of the sheet material layers has a plurality of spaced apertures, or water channels, extending from the exterior of the panel to the intermediate water-swellable clay layer. The sheet material layer containing water channels includes a coating of a removablel material completely across the water channels in the facing sheet having controlled, predetermined water-solubility so that the intermediate water-swellable clay layer is quickly hydrated after solubilization and removal of the coating material, and to prevent clay hydration during installation, prior to removal of the coating material.Type: GrantFiled: February 15, 1990Date of Patent: November 5, 1991Assignee: American ColloidInventor: William Alexander
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Patent number: 5057366Abstract: The invention provides normally tacky and pressure-sensitive adhesive compositions comprising a polymer having an inherent viscosity greater than 0.2 and having in its backbone at least a major portion by weight of polymerized monomeric acrylic or methacrylic acid ester of a non-tertiary alcohol and, having attached to the backbone, polymeric moieties having a weight average molecular weight of above about 2,000 and a T.sub.g of above about 20.degree. C. The number and composition of the attached moieties in the polymer is such as to provide the adhesive composition with a shear holding value of at least 50 minutes. Sheet materials coated with the adhesive composition are also provided. Preferred adhesive composition comprises a copolymer monomeric acrylic or methacrylic acid ester of non-tertiary alcohol and macromolecular monomer. The copolymer may also include up to 12% by weight of a copolymerizable polar monomer such as acrylic acid.Type: GrantFiled: September 16, 1982Date of Patent: October 15, 1991Assignee: Minnesota Mining and Manufacturing CompanyInventors: James R. Husman, James N. Kellen, Rebecca E. McCluney, Michael L. Tumey
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Patent number: 5057586Abstract: There are disclosed halogenated dioxolanes of a specified formula, dioxoles made therefrom, polymers of the dioxoles, and processes for making the dioxolanes.Type: GrantFiled: August 30, 1990Date of Patent: October 15, 1991Assignee: E. I. Du Pont de Nemours and CompanyInventor: Carl G. Krespan
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Patent number: 5053265Abstract: A flexible or rigid panel, and method of making the panel, useful as a water barrier including an intermediate layer of a water-swellable colloidal clay, such as pentonite, sandwiched between two layers of sheet material, such as woven or non-woven fabric, or paperboard, wherein at least one one of the sheet material layers has a water-soluble coating material covering substantially the entire outer surface of the sheet material layer. The water-soluble coating is a material that dissolves upon a predetermined water contact period, having a controlled, predetermined water-solubility so that the intermediate water-swellable clay layer is protected against hydration during installation.Type: GrantFiled: February 15, 1990Date of Patent: October 1, 1991Assignee: American Colloid CompanyInventor: William Alexander
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Patent number: 5053268Abstract: A composite paper suitable for use as writing paper, printing paper or copying paper is disclosed which includes a synthetic resin film having a thickness of 12-30 .mu.m, and a paper sheet laminated on each side of the synthetic resin film and having a Bekk smoothness of 60-120 seconds, a density of 0.8-1.0 g/cm.sup.3, a degree of sizing of 0.5-1.5 seconds and a thickness of 20-25 .mu.m.Type: GrantFiled: November 28, 1989Date of Patent: October 1, 1991Assignee: Somar CorporationInventors: Ryohei Ehara, Masatoshi Tomiki
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Patent number: 5047286Abstract: Disclosed is a printing sheet comprising(a) a support, and(b) a surface layer provided on at least one side surface of the support, the surface layer containing at least one compound selected from the group consisting of n-butyl (meth)acrylate based polymers, phenyl (meth)acrylate based homopolymer and copolymers, benzyl (meth)acrylate based homopolymers and copolymers, styrene based homopolymers and copolymers, cinnamic acid, and cinnamic acid derivatives. The printing sheets have improved printability.Type: GrantFiled: July 25, 1989Date of Patent: September 10, 1991Assignee: Tomoegawa Paper Co.Inventors: Yoshiaki Kaburaki, Junichi Morimoto, Katumitu Tamura, Koichi Tomita
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Patent number: 5037696Abstract: A substrate for heat-sensitive recording material is disclosed, comprising a film-like substrate made mainly of a synthetic resin and a sheet-like substrate made mainly of a fibrous materials laminated each other with an electron beam-curable adhesive. A heat-sensitive recording material using the above substrate provides an image having excellent quality.Type: GrantFiled: November 10, 1988Date of Patent: August 6, 1991Assignee: Kanzaki Paper Mfg. Co., Ltd.Inventors: Junichi Miyake, Masami Kanemoto, Hironari Fujioka, Hiroo Hayashi
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Patent number: 5037702Abstract: An erasably markable article formed of a coated substrate that is markable with dry wipe inks without causing permanent discernible distortion of the substrate. The surface after marking is substantially fully erasable. The surface is provided by a smooth coating of cured lacquer preferably a radiation cured lacquer, for example, electron beam radiation cured urethane acrylate. The substrate may be flexible, for example, a biaxially oriented polypropylene multilayer film having a closed cell foam-like core wherein the substrate exhibits electrostatic cling properties. The substrate may also be adhesive coated paper or may be relatively inflexible pressboard.Type: GrantFiled: June 2, 1989Date of Patent: August 6, 1991Assignee: Dennison Manufacturing CompanyInventors: Warren R. Pitts, Peter West
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Patent number: 5026608Abstract: The adhesive properties of polyolefin products are improved by submitting said products to a surface modification process which includes the following steps:A) application to the polyolefin product surface of a layer of one or more photosensitive materials selected from:1) Chloroparaffins containing 5 to 80 wt % of chlorine and having an average molecular weight greater than 200;2) vinyl chloride homopolymers and copolymers containing 25 to 80 wt % of chlorine and having K values between 40 and 60; and3) vinylidene chloride homopolymers and copolymers; andB) exposure of the layer to ultraviolet radiation.The product treated in this manner is ready for painting or coating with various materials.Type: GrantFiled: May 31, 1989Date of Patent: June 25, 1991Assignee: Himont IncorporatedInventors: Felice Polato, Giuliano Cecchin
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Patent number: 5024898Abstract: An erasably markable luminescent article formed of a coated substrate that is markable with dry wipe inks without causing permanent discernible distortion of the substrate. The surface after marking is substantially fully erasable. The surface is provided by a smooth coating of cured lacquer perferably a radiation cured lacquer, for example, electron beam radiation cured urethane acrylate. The luminescent appearance results from a phosphorescent layer between the substrate and an unpigmented cured lacquer coating.Type: GrantFiled: February 6, 1990Date of Patent: June 18, 1991Assignee: Dennison Manufacturing CompanyInventors: Warren R. Pitts, Hayden F. Estrada, Peter West
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Patent number: 5006405Abstract: A coating sheet material is provided for wrapping, packaging or shipping food articles that are to be heated in a microwave oven. The sheet is formed from a paper or paperboard backing which is thermally and dimensionally stable when exposed to microwave energy. On at least one surface is provided a smooth supercalendared surface or the sheet is treated by processing as with a filler coating to fill the voids between the paper fibers and to thereby present a smooth surface. A microwave interactive layer is applied to the smoothed surface from a fluid or vapor state. The interactive coating can comprise carbon, a semiconductive metal coating or other microwave interactive material.Type: GrantFiled: June 27, 1988Date of Patent: April 9, 1991Assignee: Golden Valley Microwave Foods, Inc.Inventors: James D. Watkins, David W. Andreas, David H. Cox
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Patent number: 4999239Abstract: Aqueous emulsions containing an ethylene-vinyl chloride (EVCl) copolymer and tetramethylol glycoluril are described for use as binder compositions suitable for application onto nonbonded filter paper. The emulsions are prepared by incorporating 4 to 10 wt % tetramethylol glycoluril, based on the total weight of the emulsion copolymer, into an aqueous dispersion of a copolymer consisting essentially of 65 to 90 wt % vinyl chloride, 5 to 35 wt % ethylene and optionally, up to 10 wt % of a hydroxyalkyl- or carboxylic acid-containing functional comonomer. The polymerization is conducted in the presence of a stabilizing system consisting essentially of 3 to 15 wt % polyvinyl alcohol. Filter paper impregnated with these emulsions maintain tensile strength and flexibility upon being subjected to hot oil.Type: GrantFiled: May 31, 1990Date of Patent: March 12, 1991Assignee: Air Products and Chemicals, Inc.Inventors: John G. Iacoviello, George Davidowich, Bheema R. Vijayendran, John S. Sadowski
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Patent number: 4988556Abstract: A device for mounting a transparency. The device includes back and front sheets of transparent plastic. The outer edges of the sheets are continuously bonded together. In a preferred embodiment, an opaque coating on the front sheet defines one or more generally rectangular windows. Each window is variously sized to permit the transparency to be viewed therethrough but to prevent light from leaking around the transparency. The sheets are continuously bonded together along three sides of the window to form a pocket between the sheets for mounting the transparency. A slit is formed along a fourth side of the window for inserting the transparency into the pocket.Type: GrantFiled: May 3, 1989Date of Patent: January 29, 1991Assignee: Block Drug Co., Inc.Inventors: Carl G. Nilsen, Gary L. Weisling, Arthur Sternheimer, Ralph A. Montes, Douglas R. Schoen
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Patent number: 4981739Abstract: The present invention relates to an improved container for food and non-food products. The container utilizes a novel paperboard barrier laminate structure which maintains an isolated gas environment in the container. The laminate makes use of high strength, heat-resistant and caulking polymer layers which prevent pinholes, cuts, or cracking of the barrier layers during blank conversion, package formation, and package distribution. In addition, the novel polymer resin layers act to caulk the seams and channels present in the carton providing a sealed leak free container.Type: GrantFiled: May 22, 1989Date of Patent: January 1, 1991Assignee: International Paper CompanyInventors: Charles E. Gibbons, Gerald A. Marano, James M. Kittrell, Allan A. Whillock, Robert L. Lanham, Donald Evans
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Patent number: 4980238Abstract: An aqueous dispersion of a cationic polymer is disclosed, which is obtained by reacting an ethylene copolymer comprising from 40 to 80% by weight of ethylene and from 20 to 60% by weight of at least one aminoalkyl acrylamide comonomer represented by formula (I): ##STR1## wherein R.sub.1 represents a hydrogen atom or a methyl group; R.sub.2 and R.sub.3 each represents a hydrogen atom or an alkyl group having from 1 to 4 carbon atoms; and n represents an integer of from 2 to 4,and having a melt index, as measured in accordance with JIS K-6760, of from 10 to 1,000 g/10 min with hydrochloric acid in water to form a quaternary salt and subsequently reacting the resulting quaternary salt with an epihalohydrin compound through addition reaction. The aqueous dispersion provides a coating film having an improved electrical conductivity or produces effects to simultaneously improve degree of sizing and wet strength of paper.Type: GrantFiled: August 26, 1988Date of Patent: December 25, 1990Assignee: Sumitomo Chemical Company, Ltd.Inventors: Tadayuki Ohmae, Kentaro Mashita, Noboru Yamaguchi, Kouichiro Asao, Norio Kondo, Tadashi Sakurai
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Patent number: 4966795Abstract: Sheet structures wherein the composition of one layer comprises a first component of a polypropylene, a second component of an ethylene-based copolymer, and a third component which provides some properties representative of elastomeric polymers. The invention further contemplates packages made from the sheet structures incorporating the recited compositions.Type: GrantFiled: May 5, 1988Date of Patent: October 30, 1990Assignee: American National Can CompanyInventors: Roger P. Genske, Yong J. Kim
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Patent number: 4948664Abstract: A paper and coating composition for use in gravure printing. The paper is coated with the composition which includes a pigment containing a layer lattice silicate which has a relatively narrow range of particle size distribution compared with pigments of conventional paper coating compositions, and which includes not more than 5%, by weight, of particles which have an equivalent spherical diameter of less than 0.25 microns. Gravure printing utilizing such paper gives good results even when the coating weight of the composition is relatively low. Furthermore, good results can be achieved when the composition includes a significant proportion of relatively coarse particles.Type: GrantFiled: September 15, 1989Date of Patent: August 14, 1990Assignee: English China Clays Lovering Pochin & Company LimitedInventor: Ronald E. Brociner
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Patent number: 4946728Abstract: In an adhesive paper for copying prepared by laminating an overlying sheet with a release sheet so that an adhesive layer coated on the bottom surface of said overlying sheet is in contact with the releasing surface of said release sheet, the improvement comprising a radiation-induced polymer layer having a glass transition temperature ranging from 50.degree. to 200.degree. C., applied to at least one edge face of said adhesive paper for copying, said radiation-induced polymer layer being formed by applying a solvent free radiation polymerizable composition to said edge face followed by irradiation curing. The presence of the radiation-induced polymer layer prevents an adhesive from squeezing out. The polymer layer, because of its specific glass transition temperature, will not break and fall off. Thus a copying machine will not be contaminated with squeezed adhesive or broken and fallen polymer layer during copying.Type: GrantFiled: June 28, 1988Date of Patent: August 7, 1990Assignee: FSK Kabushiki KaishaInventors: Takeshi Ikeda, Akira Nozaki, Kazuyoshi Ebe
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Patent number: 4944997Abstract: A coated paper for use in electrostatogrpahic processes for receiving a toner image formed by a liquid developer comprises a substrate having bound thereto on at least one side generally smooth surface, spherical, bearing spacer particles having a particle size of from about 5 to about 15 micrometers.Type: GrantFiled: November 18, 1988Date of Patent: July 31, 1990Assignee: Xerox CorporationInventor: Norman A. Nielsen
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Patent number: 4942086Abstract: Heat resistance binders for flexible polyester webs may be prepared using an emulsion polymer,the polymer being prepared by a two-stage polymerization procedure wherein a first stage is prepared based on a relatively low Tg ethylene vinyl acetate polymer and a second stage higher Tg polymer thereby combining the advantageous flexibility and film forming properties of the ethylene vinyl acetate copolymer with the stiffness and heat resistance of the higher Tg copolymer.Type: GrantFiled: September 9, 1988Date of Patent: July 17, 1990Assignee: National Starch and Chemical Investment Holding CorporationInventors: Paul R. Mudge, James J. Walker, Ronald Pangrazi
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Patent number: 4940612Abstract: The present invention relates to an improved container for food and non-food products. The container utilizes a novel paperboard barrier laminate structure which maintains an isolated gas environment in the container. The laminate makes use of high strength, heat-resistant and caulking polymer layers which prevent pinholes, cuts, or cracking of the barrier layers during blank conversion, package formation, and package distribution. In addition, the novel polymer resin layers act to caulk the seams and channels present in the carton providing a sealed leak free container.Type: GrantFiled: May 9, 1988Date of Patent: July 10, 1990Assignee: International Paper CompanyInventors: Charles E. Gibbons, Gerald A. Marano, James M. Kittrell, Allan A. Whillock, Robert L. Lanham, Donald Evans
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Patent number: 4937145Abstract: A three layer structural sheet material having improved resistance to delamination comprising a core layer of a composite paper having outer surface layers of thermoplastic resin adhered to both major surfaces thereof.Type: GrantFiled: November 21, 1988Date of Patent: June 26, 1990Assignee: The Dow Chemical CompanyInventor: Kent B. McReynolds
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Patent number: 4935273Abstract: Closure liner, i.e., innerseal, comprising a pressure-activated adhesive that is a copolymer of butadiene and acrylonitrile or methacrylonitrile. The copolymer has a single glass transition temperature of no higher than about -25.degree. C., a nitrile content of no greater than about 31% by weight, preferably of from about 18% by weight to about 30% by weight, a Mooney viscosity of at least 95 (measured according to ASTM D1646-87 at 100.degree. C. for 4 minutes), preferably from about 120 to about 150. The copolymer is not cross-linked, and the amount of vinyl groups in the copolymer should not exceed 10% by weight.Type: GrantFiled: February 1, 1989Date of Patent: June 19, 1990Assignee: Minnesota Mining and Manufacturing CompanyInventor: David T. Ou-Yang
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Patent number: 4931422Abstract: A no-carbon pressure-sensitive copying paper obtained by coating a composition containing an alkali thickening type copolymer latex as a binder on a support is excellent in color forming properties, resistance to smudge and high concentration coating suitability.Type: GrantFiled: August 17, 1988Date of Patent: June 5, 1990Assignee: Mitsubishi Paper Mills LimitedInventors: Mamoru Ishiguro, Akira Kawai
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Patent number: 4929495Abstract: Fibers in non-woven fibrous goods are bonded together by a crosslinked carboxylated acrylate polymer which forms a network of coalesced latex particles bonding contiguous fibers. This network exists as a non-continuous, porous film supported upon the fibers of the non-woven goods. The particles are of polymer derived from a crosslinked carboxylate latex containing from 1-20 phr of itaconic acid (IA) and at least 70 phr of one or more copolymerizable monomers one of which is an acrylate having the structure ##STR1## wherein R.sub.1 is hydrogen or methyl;R.sub.2 represents C.sub.1 -C.sub.20 alkyl, C.sub.2 -C.sub.7 alkoxyalkyl, C.sub.2 -C.sub.7 alkylthioalkyl, or C.sub.2 -C.sub.7 cyanoalkyl; andat least 40 phr of said acrylate in said film is present as an alkyl acrylate in which alkyl is C.sub.4 -C.sub.8.Type: GrantFiled: April 13, 1989Date of Patent: May 29, 1990Assignee: The B.F. Goodrich CompanyInventor: Vic Stanislawczyk
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Patent number: 4929494Abstract: A laminate is disclosed, comprising substrates which are impregnated with a curable composition, laminated and cured, wherein the curable composition comprises (i) a curable prepolymer having a main chain consisting essentially of a random copolymer of a vinyl monomer and an acrylic or methacrylic monomer, and a side chain containing an acryloyl or methacryloyl group at the terminal, as a main component, and (ii) a crosslinkable vinyl monomer.Type: GrantFiled: November 6, 1987Date of Patent: May 29, 1990Assignee: Showa Denko Kabushiki KaishaInventors: Fumio Matsui, Noboru Suzuki, Minoru Takaishi, Ryushi Ogura, Noriaki Harigai, Tadayoshi Hashimoto, Tomoe Uematu
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Patent number: 4921733Abstract: The present invention relates to an improved container for food and non-food products. The container utilizes a novel paperboard barrier laminate structure which maintains an isolated gas environment in the container. The laminate makes use of high strength, heat-resistant and caulking polymer layers which prevent pinholes, cuts, or cracking of the barrier layers during blank conversion, package formation, and package distribution. In addition, the novel polymer resin layers act to caulk the seams and channels present in the carton providing a sealed leak free container.Type: GrantFiled: May 9, 1988Date of Patent: May 1, 1990Assignee: International Paper CompanyInventors: Charles E. Gibbons, Gerald A. Marano, James M. Kittrell, Allan A. Whillock, Robert L. Lanham, Donald Evans
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Patent number: 4916044Abstract: A color photographic element for use in color diffusion transfer photography comprised of a lightsensitive dye release and receiving sheet and a cover sheet, wherein development, dye release and dye transfer occur in the presence of an alkaline processing solution, and wherein the cover sheet is provided with a neutralizing system which causes neutralization by an alkaline processing solution to proceed by at least a first and a second stage, wherein the first stage is characterized in that neutralization (lowering) of the pH of an alkaline processing solution occurs to the extent to interrupt development and dye release reactions but at which the transfer of a dye for forming a transfer image can continue, and a second stage at which the pH of the processing solution is gradually lowered to a final value which is stably maintained over prolonged storage, the photographic element characterized in that the neutralizing system comprises at least a neutralizing layer, a 2nd neutralization timing layer, an auxiliType: GrantFiled: December 29, 1987Date of Patent: April 10, 1990Assignee: Fuji Photo Film Co., Ltd.Inventor: Hideki Tomiyama
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Patent number: 4911960Abstract: Wet laminating adhesives capable of withstanding the stresses encountered during heat sealing operations are prepared from emulsion copolymers consisting essentially of 45 to 80% by weight of a vinyl ester of an alkanoic acid, 10 to 30% ethylene, 5 to 30% of dialkyl maleate, 0.5 to 2% of an N-methylol containing comonomer and 0.5 to 4% of an ethylenically unsaturated mono- or di-carboxylic acid. These specific emulsion copolymers are prepared utilizing standard emulsion polymerization procedures with hydroxyethylcellulose or polyvinyl alcohol as a protective colloid. The emulsion polymers thus produced provide superior wet laminating adhesive properties for use in substrates which are to be formed into microwavable packages or bags.Type: GrantFiled: January 19, 1988Date of Patent: March 27, 1990Assignee: National Starch and Chemical CorporationInventors: Paul R. Mudge, James L. Walker, Terence M. Barnhart
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Patent number: 4908240Abstract: The printability of paper is improved by applying an aqueous coating agent consisting of(a) 100 parts by weight of a finely divided pigment,(b) from 5 to 70 parts by weight, based on solids, of a cationic aqueous polymer dispersion of a paper size and(c) from 0.01 to 10 parts by weight of a surfactant which interferes with the formation of the surface size and/or of a polymeric dispersantin an amount of from 0.5 to 4 g/m.sup.2 to one or both surfaces of the paper and drying the coated paper.Type: GrantFiled: September 15, 1988Date of Patent: March 13, 1990Assignee: BASF AktiengesellschaftInventors: Werner Auhorn, Hans-Juergen Degen, Lothar Hoehr, Ulrich Riebeling
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Patent number: 4906317Abstract: Cyanoacrylate adhesive compositions which employ silacrown compounds as additives give substantially reduced fixture and cure times on de-activating substrates such as wood. The silacrown compounds are preferably employed at levels of about 0.1-5% by weight of the composition.Type: GrantFiled: June 27, 1985Date of Patent: March 6, 1990Assignee: Loctite CorporationInventor: Ju-Chao Liu
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Patent number: 4902568Abstract: There are disclosed a recording medium which comprising spherical silica contained in the surface to be recorded or in the inside thereof.Type: GrantFiled: January 30, 1987Date of Patent: February 20, 1990Assignee: Canon Kabushiki KaishaInventor: Naoya Morohoshi
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Patent number: 4900765Abstract: A deodorant and mildewproof sheet comprises a vinyl chloride resin, a deodorant which is hardly soluble in water or insoluble in water, and an antifugnal agent which is hardly soluble in water or insoluble in water.Type: GrantFiled: September 10, 1987Date of Patent: February 13, 1990Assignee: Daicel Chemical Industries, Ltd.Inventors: Katsuyoshi Murabayashi, Motoharu Kotani, Keishi Sato
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Patent number: 4900620Abstract: An ink jet recording sheet includes a sheet-like substrate composed mainly of 70 to 100 wt % of wood pulp and 0 to 30 wt % of precipitated calcium carbonate and having a Stockigt sizing degree of not less than 2 seconds and not more than 25 seconds when formed into a sheet having a basis weight of 64 g/m.sup.2, and a coating layer composed mainly of white pigment, with the coating layer being formed on at least one side of the substrate at a weight of 1 to 10 g/m.sup.2. This sheet has a high ink absorption rate and is able to develop bright colors and sharp images.Type: GrantFiled: October 6, 1988Date of Patent: February 13, 1990Assignee: OJI Paper Co., Ltd.Inventors: Makiko Tokita, Masahiro Nakagawa, Akira Kobayashi, Kenji Yasuda