Ester, Halide Or Nitrile Of Addition Polymer Patents (Class 428/514)
  • Patent number: 4898848
    Abstract: A thermosensitive recording label includes a thermosensitive color-forming layer disposed on one side of a substrate for creating a display of images when the temperature of selected portions of the thermosensitive color-forming layer are heated above an activated temperature. A remoistenable type adhesive is disposed in viscous form on an opposite side of the substrate and dried thereon without heating the thermosensitive color-forming layer above its activation temperature. The remoistenable adhesive does not include any organic solvents or substances which may cause bleed-through to the substrate and into the color-forming layer. Therefore, a barrier layer is not necessary therebetween. In addition, a protective, or barrier layer, may be disposed on top of the thermosensitive color-forming layer to prevent fading or discoloration by exterior contaminants.
    Type: Grant
    Filed: June 20, 1988
    Date of Patent: February 6, 1990
    Assignee: Ricoh Electronics, Inc.
    Inventor: Tomoo Shibata
  • Patent number: 4895760
    Abstract: Covering a rigid but pliable, smooth surface with a one-sided matte embossed polyethylene film, where the non-embossed smooth side of the film is in direct contact with the smooth surface being covered. Adhesion of the smooth side of the film to the smooth surface to which it is applied is effected much like a vacuum adhesion as seen when a drop of water is placed between two sheets of glass. The embossed side of the film forms microscopic air pockets when rolled upon itself which prevents blocking. This feature allows the non-embossed side to be made as smooth as possible without the need for an anti-blocking agent.
    Type: Grant
    Filed: October 9, 1987
    Date of Patent: January 23, 1990
    Assignee: Tredegar Industries, Inc.
    Inventor: Dennis D. Barger
  • Patent number: 4892787
    Abstract: Coated paper useful for ink jet printing comprises a cellulosic substrate coated with an intimate mixture of a particulate pigment with a binder comprising a mixture of an acrylic resin and polyvinyl alcohol.
    Type: Grant
    Filed: August 10, 1987
    Date of Patent: January 9, 1990
    Assignee: AM International, Inc.
    Inventors: Jurgen M. Kruse, Donald Kimball
  • Patent number: 4888250
    Abstract: A self-crosslinking polymer consisting essentially of at least 1 mole % of a halohydrin monomer, at least 1 mole % of a tertiary or secondary amine salt monomer, and 0-98 mole % of a vinyl polymerizable monomer other than the halohydrin or amine salt monomers crosslinks, in the presence of a base, at a lower temperature than a polymer without the tertiary or secondary amine salt monomer. Typical polymers contain 3-chloro-2-hydroxypropyl acrylate or methacrylate; diallylamine hydrochloride, N-isopropyl methacrylamide hydrogen sulfate, dimethylaminopropyl methacrylamide, or dimethylaminoethyl methacrylate hydrochloride or acetate; and optionally other monomers such as a vinyl ester, an acrylate, or a dialkyl diallyl ammonium chloride. When the polymers contain a conductive cationic monomer such as dimethyl diallyl ammonium chloride, they are useful as electroconductive coatings for paper substrates.
    Type: Grant
    Filed: August 31, 1988
    Date of Patent: December 19, 1989
    Assignee: National Starch and Chemical Corporation
    Inventors: Wen B. Chiao, Carmine P. Iovine, Samuel Gold
  • Patent number: 4888222
    Abstract: The present invention relates to an improved container for food and non-food products. The container utilizes a novel paperboard barrier laminate structure which maintains an isolated gas environment in the container. The laminate makes use of high strength, heat-resistant and caulking polymer layers which prevent pinholes, cuts, or cracking of the barrier layers during blank conversion, package formation, and package distribution. In addition, the novel polymer resin layers act to caulk the seams and channels present in the carton providing a sealed leak free container.
    Type: Grant
    Filed: May 9, 1988
    Date of Patent: December 19, 1989
    Assignee: International Paper Company
    Inventors: Charles E. Gibbons, Gerald A. Marano, James M. Kittrell, Allan A. Whillock, Robert L. Lanham, Donald Evans
  • Patent number: 4880696
    Abstract: The concentration of BHT in a flexible packaging material, such as a cereal liner, can be increased by incorporating the BHT into a polymer composition that is extrusion coated onto a substrate, such as PVDC-coated paper. The extrusion coating comprises a heatseal layer and an EVA tie layer containing the BHT. This method substantially prevents evaporation of the BHT. The extrusion temperature is less than the boiling point of BHT.
    Type: Grant
    Filed: June 27, 1988
    Date of Patent: November 14, 1989
    Assignee: James River II, Inc.
    Inventor: Apostol Yanidis
  • Patent number: 4880689
    Abstract: Decorative laminate having improved resistance against marring, abrasion, staining and crocking, and method for the preparation thereof, the laminate comprising a substrate and a decorative sheet, the decorative sheet having on the exposed surface a layer consisting essentially of a thermoset resin, substantially fully hydrolyzed polyvinyl alcohol, fumed amorphous silica, and particulate abrasive material having a hardness higher than that of silica. Abrasion resistance greater than 3000 cycles (NEMA Wear) by the NEMA test LD 3-3.01 is obtained in combination with improved mar resistance.
    Type: Grant
    Filed: October 18, 1985
    Date of Patent: November 14, 1989
    Assignee: Formica Corporation
    Inventors: John J. Park, Paul W. White, Calvin Richardson
  • Patent number: 4880701
    Abstract: The present invention relates to an improved container for food and non-food products. The container utilizes a novel paperboard barrier laminate structure which maintains an isolated gas environment in the container. The laminate makes use of high strength, heat-resistant and caulking polymer layers which prevent pinholes, cuts or cracking of the barrier layers during blank conversion, package formation, and package distribution. In addition, the novel polymer resin layers act to caulk the seams and channels present in the carton providing a sealed leak free container.
    Type: Grant
    Filed: May 9, 1988
    Date of Patent: November 14, 1989
    Assignee: International Paper Company
    Inventors: Charles E. Gibbons, Gerald A. Marano, James M. Kittrell, Allan A. Whillock, Robert L. Lanham, Donald Evans
  • Patent number: 4877686
    Abstract: Treated base material for recording. The recording sheet for ink-jet printing according to the invention includes, in its coating, a polyhydroxylic polymeric binder with the hydroxyl groups in the cis position, which has been gelled or coagulated with boric acid and/or its derivatives during coating, and a filler with a high absorption capacity. Application to recording paper for ink-jet printing.
    Type: Grant
    Filed: October 4, 1988
    Date of Patent: October 31, 1989
    Assignee: Societe Anonyme: Aussedat-Rey
    Inventors: Claude R. Riou, Georges M. Gidon
  • Patent number: 4876154
    Abstract: The present invention relates to water-born emulsion adhesives based on polymers or copolymers of vinyl acetate and having uniformly dispersed therein an adhesion promoter consisting essentially of an alkoxysilane and up to about 80% by weight of a plasticizer for the poly(vinyl acetate). The alkoxysilane useful herein may be selected from ##STR1## in which R is independently selected from alkyl or alkoxyalkyl radicals having 1-4 carbon atoms. The modified adhesives have improved bond strength to wood, particularly after exposure to moisture.
    Type: Grant
    Filed: September 26, 1988
    Date of Patent: October 24, 1989
    Assignee: Dow Corning Corporation
    Inventors: Gerald L. Witucki, Edwin P. Plueddemann
  • Patent number: 4868581
    Abstract: There are disclosed an ink-receiving composite polymer material wherein a nonvolatile organic compound is caused to penetrate into and diffuse through an ink-receiving polymer forming, from any one surface side thereof, and a recording medium for ink-jet recording wherein a nonvolatile organic compound is caused to penetrate into and diffuse through an ink-receiving layer, from the surface thereof.
    Type: Grant
    Filed: December 17, 1986
    Date of Patent: September 19, 1989
    Assignee: Cannon Kabushiki Kaisha
    Inventors: Hidemasa Mouri, Michiaki Tobita, Naonobu Eto, Masahiko Ishida, Shunzo Kouno, Takashi Akiya, Shigeo Toganoh, Masahiko Higuma, Mamoru Sakaki, Ryuichi Arai
  • Patent number: 4868048
    Abstract: An aqueous conductivising composition for conductivising paper or other sheet material, for example for producing a conductive base for use in dielectric paper or other electrostatic imaging material, is produced by (a) removing sodium magnesium trifluoride impurity (neighborite) from a synthetic hectorite clay conductivising agent, and (b) adding a binder. These measures reduce dust formation experienced in production or use of electrostatic imaging material incorporating a base which has been conductivised with a synthetic hectorite clay conductivising agent.
    Type: Grant
    Filed: December 9, 1987
    Date of Patent: September 19, 1989
    Assignee: The Wiggins Teape Group Limited
    Inventors: William K. Barr, Doris V. Royston
  • Patent number: 4865908
    Abstract: A coated, oriented polymer film laminate is provided which comprises:(a) an oriented core layer having an upper face and a lower face, said core layer being fabricated from a polypropylene homopolymer;(b) an oriented layer applied to the lower face, and optionally, to the upper face, of core layer (a), said layer being fabricated from a member of the group consisting of copolymer or blend of copolymers, homopolymer or blend of homopolymers, a blend of at least one copolymer and at least one homopolymer, terpolymer or blend of terpolymers, and a blend of at least one terpolymer and at least one homopolymer or at least one copolymer;(c) a coating layer applied to the upper face of core layer (a), or, where layer (b) has been applied thereto, to the exposed surface of said layer (b), and;(d) an adhesively bonded substrate or a coating composition applied directly to the exposed surface of layer (b) applied to the lower face of core layer (a).
    Type: Grant
    Filed: September 21, 1987
    Date of Patent: September 12, 1989
    Assignee: Mobil Oil Corporation
    Inventors: Leland L. Liu, Robert E. Touhsaent
  • Patent number: 4861632
    Abstract: A laminated packaging material from which package type containers are fabricated for storing or transporting a variety of products ranging from dry food-stuffs to electronic equipment where maintenance of a dry environment is a requirement, comprising an outer imperforate water impervious layer, a middle layer of absorbent material and an inner perforated moisture impervious layer.
    Type: Grant
    Filed: April 19, 1988
    Date of Patent: August 29, 1989
    Inventor: Michael A. Caggiano
  • Patent number: 4859513
    Abstract: The present invention relates to an improved container for food and non-food products. The container utilizes a novel paperboard barrier laminate structure which maintains an isolated gas environment in the container. The laminate makes use of high strength, heat-resistant and caulking polymer layers which prevent pinholes, cuts, or cracking of the barrier layers during blank conversion, package formation, and package distrubution. In addition, the novel polymer resin layers act to caulk the seams and channels present in the carton providing a sealed leak free container.
    Type: Grant
    Filed: May 9, 1988
    Date of Patent: August 22, 1989
    Assignee: International Paper Company
    Inventors: Charles E. Gibbons, Gerald A. Marano, James M. Kittrell, Allan A. Whillock, Robert L. Lanham, Donald Evans
  • Patent number: 4859511
    Abstract: Release sheets formed on paper, nonwoven fabric, polymeric film, or extrusion-coated paper substrates are disclosed. The release sheets have a low polar surface energy hydrocarbon undercoating of low elastic modulus interposed between the substrate and a silicone release coating.
    Type: Grant
    Filed: August 12, 1988
    Date of Patent: August 22, 1989
    Assignee: James River Corporation of Virginia
    Inventors: Robert Patterson, Stephen M. Papez
  • Patent number: 4853276
    Abstract: There is provided a novel marble-translucent thin resilient decorative sheet 1, which comprises thin permeable pulp paper 2, fine whitish inorganic filler powder, and a substantially transparent cured resin contained by impregnation throughout the pulp paper, said filler powder being uniformly deposited onto at least the top surface of the pulp paper and being firmly fixed thereto. The decorative sheet is produced by impregnating fine whitish inorganic filler-loaded permeable pulp paper with a liquid polymerizable resinous composition for forming a substantially transparent cured resin, placing the impregnated pulp paper between molding plates, and polymerizing the resinous composition into a cured resin; or by impregnating permeable non-loaded pulp paper containing no filler powder with the liquid resinous composition containing fine whitish inorganic filler powder and carrying out the polymerization between molding plates as described above.
    Type: Grant
    Filed: July 16, 1987
    Date of Patent: August 1, 1989
    Assignee: Inax Corporation
    Inventor: Toyokazu Kurushima
  • Patent number: 4847143
    Abstract: A binder composition is disclosed, which comprises:(A) a copolymer emulsion which contains as its essential ingredients vinyl acetate, ethylene, and a monomer represented by the formula (1): ##STR1## wherein R.sub.1 is H or CH.sub.3 ; and R.sub.2 is H or an alkyl group having not more than 5 carbon atoms, the proportions of the respective ingredients being within the range of 55-96.5/3-40/0.5-5 on a weight basis;(B) a formaldehyde-free nitrogen-containing glyoxal resin;(C) a metal salt catalyst; and optionally(D) a higher alcohol sulfuric acid ester-based surfactant.Nonwoven fabrics and impregnated papers using the binder composition are also disclosed. The binder composition exhibits not only high resistance to water and solvents but also low residual free formaldehyde level, with an improvement in foamability being optionally attainable.
    Type: Grant
    Filed: June 4, 1986
    Date of Patent: July 11, 1989
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Katsuyoshi Watanabe, Takashi Miyaoka, Takeo Oyamada
  • Patent number: 4842927
    Abstract: A process for preparing a water absorptive composite consisting of a highly water absorptive polymer and a prefabricated fibrous substrate, which comprises applying an aqueous solution containing (a) a polymerizable monomer comprising as a main component acrylic acid, of which 20% or more of the carboxyl groups have been neutralized to its alkali metal salt or ammonium salt, (b) 2-vinylpyridine or(and) 4-vinylpyridine or(and) their salts, (c) a crosslinking agent and (d) an oxidative radical polymerization initiator to a prefabricated fibrous substrate, and then carrying out polymerization with addition of a reducing agent.
    Type: Grant
    Filed: May 26, 1988
    Date of Patent: June 27, 1989
    Assignees: Mitsubishi Petrochemical Company Limited, Uni-Charm Corporation
    Inventors: Kiichi Itoh, Takeshi Shibano
  • Patent number: 4840834
    Abstract: An electrostatic recording material which comprises a support coated in sequence with a conductive layer and a recording layer composed of a dielectric resin and a pigment, wherein at least a part of the pigment component in said recording layer is made of an aluminum hydroxide powder having an average particle size of 1-20 .mu.m is disclosed.
    Type: Grant
    Filed: March 19, 1987
    Date of Patent: June 20, 1989
    Assignee: Oji Paper Co., Ltd.
    Inventors: Yasuharu Onogi, Akinori Oka, Masakatsu Nagatomo, Takumi Kondo, Kouji Mizumoto
  • Patent number: 4839200
    Abstract: The present invention describes a pre-treated recording media capable of receiving a high resolution aqueous-based ink jet printed layer as well as a method of preparing the same, wherein the method comprises the steps of: printing a recording media with an oil-based printing ink; drying the oil-based ink layer; coating over the oil-based ink layer with a water-soluble adhesive-like substance; drying the coating of adhesive-like substance; ink jet printing an aqueous-based ink layer onto the adhesive-like substance; and, drying the aqueous-based ink jet printed layer.
    Type: Grant
    Filed: May 4, 1987
    Date of Patent: June 13, 1989
    Assignee: Webcraft Technologies, Inc.
    Inventors: William Hoffman, Marcelo Lanas, Douglas Weiss
  • Patent number: 4837087
    Abstract: A coating binder additive is prepared comprising a blocked glyoxal resin mixed with a vinyl or acrylic water soluble polymer which is reactive with free glyoxal.
    Type: Grant
    Filed: June 25, 1987
    Date of Patent: June 6, 1989
    Assignee: Sequa Chemicals Inc.
    Inventors: William C. Floyd, Sai H. Hui
  • Patent number: 4822674
    Abstract: Disclosed is an ink donor film for thermal transfer printing processes comprised of a supporting substrate with a coating of an ink composition on the top surface thereof, which ink is comprised of a blend of four hydrocarbon waxes, pigment particles, pigment dispersants, and binder polymers selected from the group consisting of (1) styrene-b-isoprene-b-dimethyl siloxane triblock copolymers; (2) blends of styrene-b-isoprene diblock copolymers with styrene-b-dimethyl siloxane diblock copolymers; (3) styrene/ethylacrylate/butylacrylate random copolymers; and (4) poly(vinylmethyl ether).
    Type: Grant
    Filed: April 27, 1987
    Date of Patent: April 18, 1989
    Assignee: Xerox Corporation
    Inventors: Shadi L. Malhotra, Maya D. Stevanovic
  • Patent number: 4803114
    Abstract: The PVC film contains a very small percentage of carbon black, which makes it possible to mark the film excellently by means of a laser beam.
    Type: Grant
    Filed: December 15, 1986
    Date of Patent: February 7, 1989
    Assignee: Internationale Octrooimaatschappij "Octropa" B.V.
    Inventor: Martin Schledorn
  • Patent number: 4801495
    Abstract: The decorative panel having an underlay or core layer and a decorative layer on one or both sides of the core. At least one of the two surfaces of at least the outermost layer of the panel comprises a synthetic resin of one or more radiation-polymerized components selected from unsaturated acrylates and methacrylates. This layer, when scratched, has a scratch resistance of at least 1.5 N and preferably 2 to 7 N (DIN 53 799, part 10). In the method for manufacturing the decorative panel, a liquid surface layer which includes the radiation-polymerizable components is applied onto an underlay and then polymerized by means of radiation. In a further step, the radiation-polymerized surface layer is pressed together with the underlay at an elevated temperature.
    Type: Grant
    Filed: May 8, 1987
    Date of Patent: January 31, 1989
    Assignee: Hoechst Aktiengesellschaft
    Inventor: Johannes C. W. van der Hoeven
  • Patent number: 4795665
    Abstract: Containers for foods, juices and beverages containing essential oils or flavorings are comprised of a laminate structrue in which the inner surface of the container, in contact with the foods, juices or beverage, is a halopolymer, such as a vinylidene chloride polymer, which functions as a barrier layer to substantially restrict the passage or migration of the essential oils or flavorings.
    Type: Grant
    Filed: June 17, 1987
    Date of Patent: January 3, 1989
    Assignee: The Dow Chemical Company
    Inventors: Gerald M. Lancaster, Morris S. Edmondson
  • Patent number: 4792515
    Abstract: Erasable diazotype second originals on a translucent base have become very popular because they permit correcting, deletions and additions of new information to drawings without the need to redo an entire drawing. A new barrier film composition that acts simultaneously as matrix for the diazotype coating components and controls the ease of mechanical erasure is disclosed. The second originals exhibit almost film like reprographic continuity.
    Type: Grant
    Filed: January 8, 1987
    Date of Patent: December 20, 1988
    Assignee: Andrews Paper & Chemical Co., Inc.
    Inventors: Peter Muller, Henry Mustacchi, George Schmitz
  • Patent number: 4792496
    Abstract: There is disclosed a thermal transfer recording medium having a colorant layer containing a heat-fusible substance and a colorant formed on a support, the colorant comprising a copolymer obtained from an .alpha.-olefin and an acrylic acid derivative represented by the formula (I): ##STR1## wherein R.sup.1 represents a hydrogen atom or a methyl group and R.sup.2 represents a straight or branched alkyl group having 1 to 8 carbon atoms,or vinyl acetate, with the content of the above acrylic acid derivative and vinyl acetate as a monomer unit being 10% or more and of a copolymer having a melt flow index of 8 to 40 G/10 min. and a polyoxyethylene type compound.
    Type: Grant
    Filed: August 6, 1987
    Date of Patent: December 20, 1988
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Kunihiro Koshizuka, Shigehiro Kitamura, Takao Abe
  • Patent number: 4789604
    Abstract: A decorative panel and method therefor. The decorative panel includes a core layer and layers which are decorated on one or both sides of the core layer. At least the outermost layer of the panel on at least one of the two surfaces of the panel is predominantly composed of a synthetic resin which can be one or more components polymerized by radiation and includes unsaturated acrylates and methacrylates. This layer is scratch-resistant at a scratch loading of at least 1.5N, preferably 2-7N (DIN 53,799, part 10) and has a low gloss corresponding to a reflectometer value of not more than 50 at an angle of incidence of 85.degree. (DIN 67,350).
    Type: Grant
    Filed: September 22, 1986
    Date of Patent: December 6, 1988
    Assignee: Hoechst Aktiengesellschaft
    Inventor: Johannes C. W. van der Hoeven
  • Patent number: 4783376
    Abstract: A light-transmissive recording medium comprises a coating layer which has a surface electric resistance not more than 10.sup.14 .OMEGA./cm.sup.2, and has property of trapping a recording agent which is soluble and/or dispersible in an aqueous medium.
    Type: Grant
    Filed: December 17, 1986
    Date of Patent: November 8, 1988
    Assignee: Canon Kabushiki Kaisha
    Inventors: Mamoru Sakaki, Ryuichi Arai, Kenji Hasegawa, Takahiro Mori, Takashi Akiya, Hidemasa Mouri, Michiaki Tobita, Masahiko Ishida
  • Patent number: 4764420
    Abstract: A thermally insulating structural laminate comprising a core of rigid plastic foam having two major surfaces, at least one of the major surfaces of the foam being attached to a facer comprising a fribrous sheet having at least one layer of an air- and moisture-impervious polymer disposed on the inner surface thereof and interposed between the fibrous sheet and the foam, the oxygen transmission of the polymer being a value of less than about 1 cc/100 in.sup.2 -24 hrs-atm sufficient to make the facer substantially impervious to the passage of air and water vapor, resulting in the long-term preservation of insulation value.
    Type: Grant
    Filed: January 25, 1988
    Date of Patent: August 16, 1988
    Assignee: The Celotex Corporation
    Inventors: David G. Gluck, Wayne E. Laughlin
  • Patent number: 4758547
    Abstract: A novel heat-sensitive recording material is provided comprising a support, a heat-sensitive coloring layer containing an electron donating dye precursor which is normally colorless or light-colored and an electron accepting compound which exhibits a color upon reaction with said dye precursor, a first protective layer containing a polyvinyl alcohol resin and a second protective layer containing a silicon-containing denaturated polyvinyl alcohol, a colloidal silica and/or amorphous silica, wherein either of the first or second protective layer may be coated directly on said coloring layer.
    Type: Grant
    Filed: September 2, 1986
    Date of Patent: July 19, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yuichi Itabashi, Akihiro Shimomura, Noriyuki Hosoi
  • Patent number: 4752598
    Abstract: Dye-receiving sheets for heat transfer recording comprising on a substrate, a dye-receiving layer consisting essentially of a cured product of an acrylate having two acrylic or methacrylic unsaturated bonds. The sheet is used in combination with a dye transfer sheet comprising a sublimable dye, and has a high affinity for the dye and a high heat resistance without bleeding of the dye.
    Type: Grant
    Filed: July 15, 1986
    Date of Patent: June 21, 1988
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Keiichi Yubakami, Hiromu Matsuda, Akihiro Imai, Nobuyoshi Taguchi
  • Patent number: 4752522
    Abstract: An electrostatic recording material comprising a substrate treated for low electric resistance and a dielectric layer formed on the substrate and composed of a composition comprising an insulating resin having a volume specific resistance of at least 10.sup.12 .OMEGA.cm and a powder of an acrylonitrile-type polymer having a copolymerized acrylonitrile content of at least 95% by weight and containing substantially no ionic groups, said powder having a volume average particle size of from 1.5 to 4 .mu.m and a content of particles having a size exceeding 8 .mu.m as measured by a particle size distribution measuring apparatus, being at most 0.02% by number.
    Type: Grant
    Filed: April 3, 1986
    Date of Patent: June 21, 1988
    Assignee: Mitsubishi Rayon Company Limited
    Inventors: Teruhiko Sugimori, Fumio Suzuki, Naoyuki Fukabori, Hideaki Habara
  • Patent number: 4751111
    Abstract: The improvement in the production of low sheet gloss coated papers which comprises using as the synthetic polymer latex binder for the aqueous coating composition employed to coat the papers, a carboxylated latex which substantially swells during the preparation of the aqueous coating composition and subsequently shrinks during the drying of the coated paper, whereby a microscopic surface roughness is obtained to yield a low sheet gloss coated paper while retaining high ink gloss.
    Type: Grant
    Filed: May 2, 1986
    Date of Patent: June 14, 1988
    Assignee: The Dow Chemical Company
    Inventors: Do I. Lee, Ronald E. Hendershot
  • Patent number: 4748087
    Abstract: Cured coatings on substrates especially sheet substrates like paper are produced by electron beam irradiation of curable compositions comprising organic substituted tin silicon, titanium and zirconium compounds in which the organic radicals include crotonate or, especially, acrylate residues. The inclusion of the metal compounds gives coatings which cure rapidly at low electron beam doses to give cured coatings having good solvent and abrasion resistance properties. Coated substrates produced find use in plastic laminates, furniture foils and similar products.
    Type: Grant
    Filed: September 25, 1987
    Date of Patent: May 31, 1988
    Assignee: The Wiggins Teape Group Limited
    Inventors: Robert S. Davidson, Richard J. Ellis
  • Patent number: 4746646
    Abstract: A printing paper for thermal transfer printing comprising a substrate, and a dye acceptor layer formed on one surface of the substrate to accept a sublimable dye transferred from a dye carrier ribbon in contact with the dye acceptor layer upon selective heating of the dye carrier ribbon. The dye acceptor layer has a cumulative pore volume of 0.2 to 0.6 cm.sup.3 /g and contains a pigment in the form of particles whose median particle diameter of from 0.2 to 2 .mu.m. In particular, the dye acceptor layer is made of a coating of a resinous binder uniformly dispersing a pigment therein, the coating being impregnated with a resin having good affinity for the sublimable dye.
    Type: Grant
    Filed: April 25, 1986
    Date of Patent: May 24, 1988
    Assignees: Sony Corporation, Honshu Seishi Kabushiki Kaisha
    Inventors: Toshiaki Nakanishi, Daiju Kohga, Yoshihiko Kawano, Toshiki Okazaki
  • Patent number: 4745032
    Abstract: An article of construction comprising a substrate coated with a multi-ply coating including an acrylic resin coating adhered to the surface of said substrate and underlying and adhered to an overlying acrylic resin coating, the acrylic resin of said underlying coating being a different acrylic resin than that of said underlying coating, the adhesive bond between said overlying and underlying coatings being stronger than if the bond were between two coatings formed from the same acrylic resin, and including embodiments in which fly ash is included in either the underlying or the overlying coating.
    Type: Grant
    Filed: November 19, 1986
    Date of Patent: May 17, 1988
    Assignee: AcrySyl International Corporation
    Inventor: Bernard J. Morrison
  • Patent number: 4741969
    Abstract: An aqueous ink recording sheet is described which is prepared by coating on the surface of a substrate sheet a resin composition containing as the chief ingredient a mixture comprising (A) 10 to 90 wt % of photo polymerizable, double bonded anionic synthetic resin, and (B) 90 to 0 wt % of partially or completely saponified polyvinyl alcohol, or partially or completely saponified polymer resin composed of 20 to 100 wt % of vinyl acetate and 80 to 0 wt % of other polymerizable monomer or derivatives thereof, and/or (C) 90 to 0 wt % of homopolymer resin of N-vinylpyrrolidone or copolymer resin of other polymerizable monomer therewith, with the weight ratio of (A)/[(B)+(C)] being 90/10 to 10/90, drying the coated resin composition, and then curing the resin composition by the irradiation with actinic rays so as to form a resin coating layer on the substrate.
    Type: Grant
    Filed: October 10, 1986
    Date of Patent: May 3, 1988
    Assignee: Mitsubishi Petrochemical Co., Ltd.
    Inventors: Kazuhide Hayama, Akira Yamashita
  • Patent number: 4731285
    Abstract: There is described a water-resistant paper support for photographic purposes with at least one coating which is hardened by electron beams, wherein the resin layer forming the coating contains acrylated or methacrylated phosphoric acid with a ratio of acrylate or methacrylate groups to acid groups of 1:2 to 2:1, or itaconic acid, and wherein this acrylated or methacrylated phosphoric acid or the itaconic acid in the resin mixture forming the coating amounts to 1 to 15 weight %, and preferably 4 to 10 weight %, relative to the entire mixture, and the acrylated or methacrylated phosphoric acid possesses an average molecular weight of 400 to 600.
    Type: Grant
    Filed: September 8, 1986
    Date of Patent: March 15, 1988
    Assignee: Felix Schoeller, Jr. GmbH & Co. KG
    Inventor: Reiner Anthonsen
  • Patent number: 4729928
    Abstract: A durable high gloss water-based coating composition highly useful for multicolor printing or as printing inks, and like uses, and which is characterized by a proportioned mixture of ethylene acrylic acid and N-methylpyrrolidone, with resultant avoidance of environmental or toxicity problems, as well as formulation, application, or utilization difficulties.
    Type: Grant
    Filed: April 10, 1987
    Date of Patent: March 8, 1988
    Inventors: Attilio V. Schiappa, Wilson M. Ferrell
  • Patent number: 4728568
    Abstract: Disclosed is a masking tape suitable for use in manufacturing a printed circuit board. The masking tape comprises a water soluble paper as a tape base material, and a water soluble adhesive agent applied to one side of the paper. A method of filling through-holes employing such a water soluble masking tape in a process of manufacturing a printed circuit board is also disclosed.
    Type: Grant
    Filed: October 20, 1986
    Date of Patent: March 1, 1988
    Assignees: Dainippon Screen Mfg. Co., Ltd., Sanyo-Kokusaku Pulp Co., Ltd.
    Inventors: Shigeru Sasada, Tetsuo Ohwada, Masaru Mishima
  • Patent number: 4724186
    Abstract: A flexible weather resistant film particularly adapted for use as a weatherable surface coating by lamination to a substrate comprising a weather resistant layer of a blend of a vinyl chloride polymer, an interpolymer of ethylene and at least one carboxylic acid or ester thereof containing ethylenic unsaturation, and chlorinated polyethylene, an adhesive layer for adhesion of the film to a substrate comprising an interpolymer of ethylene and acrylic or methacrylic acid and interposed between the weatherable layer and the adhesive layer, an interlayer comprising a copolymer of ethylene and vinyl acetate.
    Type: Grant
    Filed: February 9, 1987
    Date of Patent: February 9, 1988
    Assignee: The Dow Chemical Company
    Inventor: Robert H. Kelch
  • Patent number: 4692473
    Abstract: A foam polyvinyl product prepared from a composition comprising a vinyl polymer and an alkali carbonate foaming agent.
    Type: Grant
    Filed: April 26, 1985
    Date of Patent: September 8, 1987
    Assignee: Orin Chemical Company
    Inventors: Thomas C. Wright, Grover L. Johnson
  • Patent number: 4689282
    Abstract: A method for printing by magnetography under atmospheric conditions of relative humidity exceeding 65 or even 75% consists in transferring to a sheet of paper a fusible magnetic ink in powdered form which is distributed on a temporary magnetizable support in accordance with the configuration to be produced, whereupon the ink is fixed by fusion on the sheet of paper. The paper has a surface resistivity of at least 10.sup.10 ohms square and a relative smoothness of at least 20 Bekk.
    Type: Grant
    Filed: January 3, 1986
    Date of Patent: August 25, 1987
    Assignee: Aussedat Rey
    Inventors: Georges Gidon, Claude Richard
  • Patent number: 4680234
    Abstract: A flexible weather resistant film comprising a weather resistant layer of a blend of a vinyl chloride polymer and chlorinated polyethylene and a second layer comprising a normally solid thermoplastic adhesive. Improved performance is obtained when the first layer additionally comprises an interpolymer of ethylene and at least one carboxylic acid or ester thereof containing ethylenic unsaturation.
    Type: Grant
    Filed: May 13, 1985
    Date of Patent: July 14, 1987
    Assignee: The Dow Chemical Company
    Inventor: Robert H. Kelch
  • Patent number: 4673601
    Abstract: A cold- or heat-sealable composite film comprises a permanently adhesive layer which is applied to a carrier film and which, on the side facing away from the carrier film, has a covering layer of a material having a low elongation at break and low tear propagation strengths. If the covering layer is not itself cold- or heat-sealable, it is provided with an appropriate cold- or hot-sealing layer. The composite film can be used as a closing membrane for preformed containers or can itself be formed as a container.
    Type: Grant
    Filed: May 6, 1985
    Date of Patent: June 16, 1987
    Assignee: Nyffeler, Corti AG
    Inventors: Alfons Lamping, Beat Karth, Werner Hiltbrunner
  • Patent number: 4668730
    Abstract: Latex adhesives having a Tg of -60.degree. to 0.degree. C. characterized by superior rheological properties, are prepared without the use of additional thickeners from a colloid stabilized latex comprising: 65-90% by weight of the latex polymer solids of an acrylate or methacrylate ester monomer polymerized in 10-35% by weight of the latex solids of a polymeric colloid, the polymeric colloid having a Tg of -40.degree. to 0.degree. C., a number average molecular weight of 2,000 to 10,000 and comprising(a) 50 to 85% by weight of a monomer of the formula: ##STR1## where R' is hydrogen or methyl and R" is a C.sub.1 -C.sub.12 straight or branched chain alkyl group;(b) 10 to 50% by weight of an ethylenically unsaturated mono- or dicarboxylic acid;(c) 5 to 30% by weight of an acrylic or methacrylic ester of a polyalkylene oxide, and(d) 0 to 30% by weight of another ethylenically unsaturated copolymerizable monomer.
    Type: Grant
    Filed: August 5, 1985
    Date of Patent: May 26, 1987
    Assignee: National Starch and Chemical Corp.
    Inventors: Carmine P. Iovine, Yen-Jer Shih, Paul B. Foreman
  • Patent number: 4668565
    Abstract: A structure for a synthetic resin-made molding for a bodies, bumpers, etc. of automobiles is adhered via a double-coated adhesive tape. Adhesives comprising chloroprene rubbers, isobutylene-isoprene rubbers and phenolic resins and primers comprising a mixture of at least one polymer selected from polyacrylic acid derivatives and polymethacrylic acid derivatives and chloroprene rubbers are coated and formed between the molding and the tape.
    Type: Grant
    Filed: March 3, 1986
    Date of Patent: May 26, 1987
    Assignee: Toyoda Gosei Co., Ltd.
    Inventor: Tatsuya Murachi
  • Patent number: 4659607
    Abstract: A retouchable mat film comprising a hydrophobic support which has formed thereon a mat layer containing silicon dioxide as a matting agent is disclosed. The mat layer further includes a mixture of poly(methyl methacrylate) or a copolymer containing at least 80 wt % of methyl methacrylate and a hydrophilic polymer as a binder. This mat film withstands several retouching operations in ink.
    Type: Grant
    Filed: December 2, 1985
    Date of Patent: April 21, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shinzi Kataoka, Yukio Shinagawa, Shinji Sakaguchi