Next To Second Metal-compound-containing Layer Patents (Class 428/699)
  • Patent number: 8440327
    Abstract: A method of producing hard wear resistant layer with improved wear resistance. The method is a reactive arc-evaporation based process using a cathode including as main constituent at least one phase of a refractory compound Mn+1AXn (n=1, 2 or 3), wherein M is one or more metals selected from the groups IIIB, IVB, VB, VIB and VIIB of the periodic table of elements, A is one or more elements selected from the groups IIIA, IVA, VA and VIA of the periodic table of elements, and wherein X is carbon and/or nitrogen.
    Type: Grant
    Filed: September 17, 2008
    Date of Patent: May 14, 2013
    Assignee: Seco Tools AB
    Inventors: Jens-Petter Palmqvist, Jacob Sjolen, Lennart Karlsson
  • Patent number: 8440314
    Abstract: The present disclosure is directed to cutting tools. The disclosed cutting tools may have a wear resistant coating on a substrate. The substrate may have hard particles cemented in a binder phase. The binder may have a near-surface concentration gradient of at least one platinum group element and/or rhenium. Processes for producing cutting tools are also disclosed.
    Type: Grant
    Filed: August 25, 2009
    Date of Patent: May 14, 2013
    Assignee: TDY Industries, LLC
    Inventors: Craig W. Morton, Dewitt Dortch, John Bost, David J. Wills
  • Patent number: 8435649
    Abstract: A white film structure includes a combining layer and a color layer. The combining layer is formed on a surface of a substrate and is made of chromium nitride. The color layer is formed on the combining layer and is made of a mixture of alumina and titanium oxide. A weight percent of the aluminum in the color layer is more than that of the titanium in the color layer.
    Type: Grant
    Filed: November 19, 2010
    Date of Patent: May 7, 2013
    Assignee: Hon Hai Precision Industry Co., Ltd.
    Inventor: Hsin-Chin Hung
  • Patent number: 8435626
    Abstract: A WC—Co material or polycrystalline diamond-Co material that has a gradient in the grain size of the particles. Specifically, the material may have a top layer that has coarse grains that is designed to dissipate the heat caused by friction (and thus prevent thermal cracking). The material will then have a bulk substrate that is made up of finer grains and provide adequate hardness for the material. The top layer is positioned on top of the bulk substrate.
    Type: Grant
    Filed: March 6, 2009
    Date of Patent: May 7, 2013
    Assignee: University of Utah Research Foundation
    Inventor: Zhigang Zak Fang
  • Patent number: 8431253
    Abstract: A polymer-assisted deposition process for deposition of epitaxial cubic metal nitride films and the like is presented. The process includes solutions of one or more metal precursor and soluble polymers having binding properties for the one or more metal precursor. After a coating operation, the resultant coating is heated at high temperatures under a suitable atmosphere to yield metal nitride films and the like. Such films can be used as templates for the development of high quality cubic GaN based electronic devices.
    Type: Grant
    Filed: January 22, 2009
    Date of Patent: April 30, 2013
    Assignee: Los Alamos National Security, LLC
    Inventors: Anthony K. Burrell, Thomas Mark McCleskey, Quanxi Jia, Alexander H. Mueller, Hongmei Luo
  • Patent number: 8426043
    Abstract: The invention provides a boron suboxide composite material comprising boron suboxide and a secondary phase, wherein the secondary phase contains a boride. The boride may be selected from the borides of transition metals of the fourth to eighth groups of the periodic table. Particularly, the boride may be selected from the borides of iron, cobalt, nickel, titanium, tungsten, hafnium, tantalum, zirconium, rhenium, molybdenum or chromium. The boride also may be a platinum group metal boride, preferably palladium boride. The secondary phase also may contain one or more oxides.
    Type: Grant
    Filed: April 24, 2008
    Date of Patent: April 23, 2013
    Inventors: Anthony Andrews, David Stuart McLachlan, Iakovos Sigalas, Mathias Herrmann
  • Patent number: 8415033
    Abstract: A cutting tool is disclosed. The cutting tool comprises a substrate and a coating layer on the substrate. The coating layer consists of nitride or carbonitride containing Ti and Al, and has a thickness of 3 to 9 ?m on a flank face. A first intensity ratio I(400)/I(311) of the coating layer on an outer surface is larger than the first intensity ratio of the coating layer on the substrate side.
    Type: Grant
    Filed: January 29, 2009
    Date of Patent: April 9, 2013
    Assignee: KYOCERA Corporation
    Inventor: Masahito Matsuzawa
  • Patent number: 8415019
    Abstract: A new composition and medical implant made there from comprises a thick diffusion hardened zone, and layered ceramic surface. Orthopedic implants comprising the new composition, methods of making the new composition, and methods of making orthopedic implants comprising the new composition are disclosed.
    Type: Grant
    Filed: June 11, 2008
    Date of Patent: April 9, 2013
    Assignee: Smith & Nephew, Inc.
    Inventors: Vivek Devidas Pawar, Shilesh C. Jani, Carolyn L. Weaver
  • Patent number: 8410355
    Abstract: This invention intends to develop a technique for forming an interlayer with excellent optical characteristics and to provide a photoelectric conversion device having high conversion efficiency. To realize this purpose, a series connection through an intermediate layer is formed in the thin-film photoelectric conversion device of the invention, and the interlayer is a transparent oxide layer in its front surface and n pairs of layers stacked therebehind (n is an integer of 1 or more), wherein each of the pair of layers is a carbon layer and a transparent oxide layer stacked in this order. Film thicknesses of each layer are optimized to improve wavelength selectivity and stress resistance while keeping the series resistance.
    Type: Grant
    Filed: October 30, 2008
    Date of Patent: April 2, 2013
    Assignee: Kaneka Corporation
    Inventors: Tomomi Meguro, Mitsuru Ichikawa, Fumiyasu Sezaki, Kunta Yoshikawa, Takashi Kuchiyama, Kenji Yamamoto
  • Patent number: 8409702
    Abstract: Coated cutting tools are disclosed which have a hard coating that includes at least one aluminum titanium nitride layer having a single phase structure of B1 cubic phase and a composition of (AlxTi1-x)N, where x is in the range of about 0.46 to about 0.52 moles. The hard coatings also have a residual stress in the range of from about ?0.4 to about ?3 GPa as measured by the XRD Sin2 ? method, and a crystallographic orientation characterized by an x-ray diffraction (200) to (111) peak intensity ratio in the range of about 1 to about 14. Preferably the aluminum titanium nitride layer has an average crystallite size in the range of about 15 to about 50 nanometers. Methods of making such coated cutting tools are also disclosed.
    Type: Grant
    Filed: February 7, 2011
    Date of Patent: April 2, 2013
    Assignee: Kennametal Inc.
    Inventors: Wangyang Ni, Zhigang Ban, Ronald M. Penich, Yixiong Liu
  • Patent number: 8409717
    Abstract: Example embodiments of this invention relate to a coated article including an infrared (IR) reflecting layer of a material such as silver or the like, for use in an insulating glass (IG) window unit for example. In certain example embodiments, the coating is a single-silver type coating, and includes an overcoat including an uppermost layer of or including silicon nitride and a layer of or including tin oxide immediately under and contacting the silicon nitride based overcoat. In certain example embodiments, the thicknesses of the silicon nitride based overcoat and the tin oxide based layer are balanced (e.g., substantially equal, or equal plus/minus about 10%). It has surprisingly been found that such balancing results in an improvement in thermal cycling performance and improved mechanical durability. In certain example embodiments, the coating may realize surprisingly good substantially neutral film side reflective coloration, and may achieve an improved visible transmission, SHGC ratio and low U-values.
    Type: Grant
    Filed: April 21, 2008
    Date of Patent: April 2, 2013
    Assignees: Guardian Industries Corp., Centre Luxembourgeois de Recherches pour le Verre et la Ceramique S.A. (C.R.V.C.)
    Inventors: Jingyu Lao, Philip J. Lingle, Brent Boyce, Bernd Disteldorf, Richard Blacker
  • Patent number: 8409696
    Abstract: A cutting tool includes a body of a hard alloy of cemented carbide, cermet, ceramics, cubic boron nitride based material or high speed steel and on which at least one of the functioning parts of the surface thereof, a hard and wear resistant coating is applied. The coating includes a polycrystalline laminar, multilayered structure of metal nitride compounds, in a repetitive form . . . MeN/(Ti1-xAlx)N/MeN/(Ti1-xAlx)N/MeN/(Ti1-xAlx)N/MeN/(Ti1-xAlx)N . . . of cubic structured (Ti1-xAlx)N layers where 0.3<x<0.95 and cubic structured MeN layers where Me is one or more of the metal element Ti, Zr, Hf, V, Nb, Ta, Mo and Al. The laminated structure has a repeat period, ?, of 5 nm??<20 nm, a layer thickness relation of 1/10<(dMeN/d(Ti,Al)N)<1/3 and a thickness dMeN?1 nm that is essentially constant throughout its total thickness up to 20 ?m.
    Type: Grant
    Filed: February 19, 2009
    Date of Patent: April 2, 2013
    Assignee: Seco Tools AB
    Inventors: Mats Johansson, Jacob Sjölén, Magnus Odén, Axel Knutsson
  • Patent number: 8409731
    Abstract: A cutting tool insert includes a body of a hard alloy of cemented carbide, cermet, ceramics, cubic boron nitride based material or high speed steel. A hard and wear resistant coating, having at least one layer, to which an (Al,Cr)2O3 layer is applied. This insert is particularly useful for machining of steel and stainless steel. The coating with a total thickness of 2-20 ?m has one or several layers, at least one of which is an (Al,Cr)2O3 layer with a thickness of 1-5 ?m having a corundum phase crystalline structure and a composition (Al1-yCry)2O3 with 0.4?y?0.6. The (Al,Cr)2O3 layer has a fiber texture with rotational symmetry in the direction of the coated surface normal to an inclination angle, ?, of the basal planes relative to the coated surface normal or the inclination angle, ?, for the highest peak in the pole plot with 70° <?<90° .
    Type: Grant
    Filed: March 3, 2009
    Date of Patent: April 2, 2013
    Assignee: Seco Tools AB
    Inventors: Mats Johansson, Tommy Larsson
  • Patent number: 8409734
    Abstract: Coated substrates having high wear resistant coatings are disclosed. The coatings include at least one layer of either titanium oxycarbonitride or titanium aluminum oxycarbonitride, such that the layer has an oxygen to titanium atomic percent ratio in the range of about 0.01 to about 0.09 and an aluminum to titanium atomic percent ratio in the range of about 0 to about 0.1. The coatings have a hardness to Young's modulus ratio of at least 0.06. The substrate may be a cutting insert. Methods of making such coated substrates are also disclosed in which layers comprising titanium oxycarbonitride or titanium aluminum oxycarbonitride are deposited by medium temperature chemical vapor deposition (MT-CVD) on substrates in the temperature range of about 750 to about 950° C. using a mixture of gases wherein the ratio of the hydrogen gas to the nitrogen gas is greater than 5.
    Type: Grant
    Filed: March 4, 2011
    Date of Patent: April 2, 2013
    Assignee: Kennametal Inc.
    Inventors: Zhigang Ban, Yixong Liu, Mark S. Greenfield
  • Patent number: 8409732
    Abstract: A cutting tool insert includes a body of a hard alloy of cemented carbide, cermet, ceramics, cubic boron nitride based material or high speed steel and a hard and wear resistant coating, including one or several layers, at least one of which is an (Al,Cr)2O3 layer. The coating, with a total thickness of 2-20 ?m includes one or several layers, at least one of which is an (Al,Cr)2O3 layer with a thickness of 1-5 ?m having a corundum phase crystalline structure and a composition (Al1-yCry)2O3 with 0.5?y?0.7. The (Al,Cr)2O3 layer has a fiber texture with rotational symmetry in the direction of the coated surface normal with an inclination angle, ?, of the basal planes relative to the coated surface normal or the inclination angle, ?, for the highest peak in the pole plot with 20°<?<55°.
    Type: Grant
    Filed: March 3, 2009
    Date of Patent: April 2, 2013
    Assignee: Seco Tools AB
    Inventors: Mats Johansson, Tommy Larsson
  • Patent number: 8409707
    Abstract: The invention relates to an iron-based soft magnetic powder for a dust core, wherein a film comprising Fe and Co, a phosphoric acid-based chemical conversion film and a silicone resin film are formed in this order on the surface of an iron-based soft magnetic powder, and to a dust core obtained by molding the iron-based soft magnetic powder for a dust core. The invention also relates to an iron-based soft magnetic powder for a dust core formed by coating the surface of an iron-based soft magnetic powder with an insulating film, wherein the powder has a particle diameter of from 45 ?m to 180 ?m, the insulating film is composed of two layers in which a lower layer composed of a phosphoric acid-based chemical conversion film and an upper layer composed of a silicone resin film, and each of the films has a thickness of from 100 nm to 280 nm, and to a dust core obtained by molding the iron-based soft magnetic powder for a dust core.
    Type: Grant
    Filed: July 2, 2008
    Date of Patent: April 2, 2013
    Assignee: Kobe Steel, Ltd.
    Inventors: Hiroyuki Mitani, Nobuaki Akagi, Hirofumi Houjou
  • Patent number: 8409491
    Abstract: A tough ultra-high temperature ceramic (UHTC) composite comprises grains of UHTC matrix material, such as HfB2, ZrB2 or other metal boride, carbide, nitride, etc., surrounded by a uniform distribution of acicular high aspect ratio reinforcement ceramic rods or whiskers, such as of SiC, is formed from uniformly mixing a powder of the UHTC material and a pre-ceramic polymer selected to form the desired reinforcement species, then thermally consolidating the mixture by hot pressing. The acicular reinforcement rods may make up from 5 to 30 vol % of the resulting microstructure.
    Type: Grant
    Filed: August 22, 2011
    Date of Patent: April 2, 2013
    Assignee: The United States of America as Represented by the Administrator of the National Aeronautics & Space Administration (NASA)
    Inventors: Margaret M Stackpoole, Matthew J Gasch, Michael W Olson, Ian W. Hamby, Sylvia M Johnson
  • Patent number: 8399110
    Abstract: The invention is directed to single crystal alkaline earth metal fluoride optical elements having an adhesive, hermetic coating thereon, the coating being chemically bonded to the surface of the metal fluoride optical element with a bonding energy ?4 eV and not merely bonded by van der Walls forces. The materials that can be used for coating the optical elements are selected from the group consisting of SiO2, F—SiO2, Al2O3, F—Al2O3, SiON, HfO2, Si3N4, TiO2 and ZrO2, and mixtures (of any composition) of the foregoing, for example, SiO2; HfO2 and F—SiO2/ZrO2. The preferred alkali earth metal fluoride used for the optical elements is CaF2. Preferred coatings are SiO2, F—SiO2, SiO2/ZrO2 and F—SiO2/ZrO2.
    Type: Grant
    Filed: May 29, 2008
    Date of Patent: March 19, 2013
    Assignee: Corning Incorporated
    Inventors: Michael J Cangemi, Horst Schreiber, Jue Wang
  • Patent number: 8394513
    Abstract: The invention relates to a body which is coated with hard material and has a plurality of layers applied by means of CVD, wherein the outer layer comprises Ti1-xAlxN, Ti1-xAlxC and/or Ti1-xAlxCN where 0.65?x?0.9, preferably 0.7?x?0.9, and this outer layer has compressive stresses in the range from 100 to 1100 MPa, preferably from 400 to 800 MPa, and a TiCN or Al2O3 layer is arranged under this outer layer.
    Type: Grant
    Filed: January 20, 2009
    Date of Patent: March 12, 2013
    Assignee: Kennametal Inc.
    Inventors: Hendrikus Van Den Berg, Hartmut Westphal, Volkmar Sottke
  • Patent number: 8394502
    Abstract: A highly durable, environmentally and thermally stable Silver coating for mirrors, Infrared thin-film filters, or other optical coatings having very high reflection values over a large spectral and angular range where the enhanced durability and thermal stability are achieved through the selection and layer sequence of materials, which provide good chemical and environmental protection to Silver. Of particular importance are the layers directly below the Silver, and directly above the Silver (nucleation layer and barrier layer).
    Type: Grant
    Filed: August 26, 2010
    Date of Patent: March 12, 2013
    Assignee: Ocean Thin Films, Inc.
    Inventor: Grzegorz Stachowiak
  • Patent number: 8389115
    Abstract: A cutting tool insert includes a body of cemented carbide, cermet, ceramics, cubic boron nitride based material or high speed steel and a hard and wear resistant coating including at least one metal nitride layer. The coating includes at least one layer of a thermally stabilized cubic structured (Ti1?x+z)SixMez)N phase with 0.04<x<0.20 and 0<z<0.10, with a constant elemental composition throughout the layer where Me is one or more of the metal elements Y, Hf, Nb, Ta, Mo, W, Mn, Fe and Zn with a thickness of 0.5 to 10 ?m. The layer is deposited using cathodic arc evaporation and is particularly useful for machining of stainless steel and super alloys.
    Type: Grant
    Filed: March 3, 2009
    Date of Patent: March 5, 2013
    Assignee: Seco Tools AB
    Inventors: Mats Johansson, Jon Andersson, Axel Flink, Lars Hultman
  • Patent number: 8389134
    Abstract: The invention relates to a body which is coated with hard material and has a plurality of layers applied by means of CVD, in which an Al2O3 layer is arranged as outer layer on a Ti1-xAlxN layer and/or Ti1-xAlxC layer and/or Ti1-xAlxCN layer.
    Type: Grant
    Filed: January 20, 2009
    Date of Patent: March 5, 2013
    Assignee: Kennametal Inc.
    Inventors: Hendrikus Van Den Berg, Hartmut Westphal, Volkmar Sottke
  • Patent number: 8389135
    Abstract: An oxide sintered body having zinc oxide as a main component and containing magnesium, and a transparent conductive substrate are provided, and an oxide sintered body having zinc oxide and magnesium, wherein content of magnesium is from 0.02 to 0.30 as atom number ratio of Mg/(Zn+Mg); an oxide sintered body having zinc oxide, magnesium, gallium and/or aluminum, wherein content of gallium and/or aluminum is over 0 and equal to or lower than 0.09 as atom number ratio of (Ga+Al)/(Zn+Ga+Al), and content of magnesium is from 0.02 to 0.30 as atom number ratio of Mg/(Zn+Ga+Al+Mg); a target obtained by processing these oxide sintered bodies; and a transparent conductive film formed on a substrate by a sputtering method or an ion plating method, by using this target.
    Type: Grant
    Filed: May 11, 2007
    Date of Patent: March 5, 2013
    Assignee: Sumitomo Metal Mining Co., Ltd.
    Inventors: Tokuyuki Nakayama, Yoshiyuki Abe
  • Patent number: 8377567
    Abstract: A porous metal member composed of an alloy at least containing nickel and tungsten is provided. The alloy may contain 50 to 80 wt % of nickel and 20 to 50 wt % of tungsten and may further contain 10 wt % or less of phosphorus and/or 10 wt % or less of boron. Such a porous metal member can be produced by, for example, making a porous base such as a urethane foam be electrically conductive, forming an alloy film containing nickel and tungsten, then removing the porous base from the alloy film, and subsequently reducing the alloy.
    Type: Grant
    Filed: May 19, 2011
    Date of Patent: February 19, 2013
    Assignees: Sumitomo Electric Industries, Ltd., Sumitomo Electric Toyama Co., Ltd.
    Inventors: Kazuki Okuno, Masahiro Kato, Tomoyuki Awazu, Masatoshi Majima, Hidetoshi Saito, Keiji Shiraishi, Hitoshi Tsuchida, Junichi Nishimura
  • Patent number: 8377560
    Abstract: A glaze composition which makes it possible that a base material for an inorganic calcined substance containing a lot of vitreous material is glazed without having corrosion. The glaze composition comprises a plastic material, a non-plastic material, and a solvent material, wherein the plastic material comprises at least one material selected from the group consisting of Gairome clay, Kibushi clay, kaolin and talc; the non-plastic material comprises at least one material selected from the group consisting of silica, calcined kaolin, pottery stone, pyrophyllite, pottery shards, chamotte and zircon; and the solvent material comprises at least one material selected from the group consisting of feldspar, lime stone, dolomite, zinc oxide and lithium carbonate.
    Type: Grant
    Filed: February 12, 2008
    Date of Patent: February 19, 2013
    Assignee: Nichiha Corporation
    Inventor: Takashige Akie
  • Patent number: 8377577
    Abstract: Coated articles comprising a decorative metal substrate and a transparent cured coating thereon containing inorganic particles in which the concentration of particles in the exposed surface region of the cured coating is greater than the bulk region of the coating. Preferably, the transparent coating is applied by electrodeposition.
    Type: Grant
    Filed: August 4, 2010
    Date of Patent: February 19, 2013
    Assignee: PPG Industries Ohio, Inc.
    Inventors: James E. Poole, Anthony D. Kulfan, Raphael O. Kollah
  • Patent number: 8377578
    Abstract: An infrared radiation reflecting transparent layer system on a transparent substrate and a method for producing same is provided. The infrared radiation reflecting layer system comprises an infrared radiation reflecting layer sequence which includes a selective function usually consisting of a noble metal, mostly silver, or an alloy thereof and having a good selective reflectivity in the infrared range. The layer sequence is supplemented by at least one transparent dielectric layer of an oxynitride of a metal, a semiconductor or a semiconductor alloy having a low to moderate refractive index arranged directly on the substrate or above the infrared radiation reflecting layer sequence.
    Type: Grant
    Filed: January 12, 2012
    Date of Patent: February 19, 2013
    Assignee: Von Ardenne Anlagentechnik GmbH
    Inventors: Christoph Koeckert, Holger Proehl, Falk Milde
  • Patent number: 8367225
    Abstract: A coating includes a deposited layer. The deposited layer is a nickel-titanium carbonitride layer.
    Type: Grant
    Filed: December 15, 2010
    Date of Patent: February 5, 2013
    Assignees: Hong Fu Jin Precision Industry (ShenZhen) Co., Ltd., Hon Hai Precision Industry Co., Ltd.
    Inventors: Hsin-Pei Chang, Wen-Rong Chen, Huan-Wu Chiang, Cheng-Shi Chen, Chuang Ma
  • Patent number: 8361639
    Abstract: A coating includes a nano-composite base comprising a number of films, the films stacked together one after another. Each film includes a nickel-titanium carbonitride layer and a titanium carbonitride layer.
    Type: Grant
    Filed: December 15, 2010
    Date of Patent: January 29, 2013
    Assignees: Hong Fu Jin Precision Industry (ShenZhen) Co., Ltd., Hon Hai Precision Industry Co., Ltd.
    Inventors: Hsin-Pei Chang, Wen-Rong Chen, Huan-Wu Chiang, Cheng-Shi Chen, Chuang Ma
  • Patent number: 8357454
    Abstract: A ceramic thermal barrier coating (TBC) (18) having first and second layers (20, 22), the second layer (22) having a lower thermal conductivity than the first layer for a given density. The second layer may be formed of a material with anisotropic crystal lattice structure. Voids (24) in at least the first layer (20) make the first layer less dense than the second layer. Grooves (28) are formed in the TBC (18) for thermal strain relief. The grooves may align with fluid streamlines over the TBC. Multiple layers (84, 86, 88) may have respective sets of grooves (90), Preferred failure planes parallel to the coating surface (30) may be formed at different depths (A1, A2, A3) in the thickness of the TBC to stimulate generation of a fresh surface when a portion of the coating fails by spalling. A dense top layer (92) may provide environmental and erosion resistance.
    Type: Grant
    Filed: September 26, 2008
    Date of Patent: January 22, 2013
    Assignee: Siemens Energy, Inc.
    Inventors: Anand A. Kulkarni, David J. Mitchell, Ramesh Subramanian, Andrew J. Burns
  • Patent number: 8354177
    Abstract: This invention provides a surface-coated cutting tool which exhibits excellent fracture resistance and wear resistance in high-speed cutting, such as high-speed gear cutting, high-speed milling, and high-speed drilling. The surface-coated cutting tool includes a hard coating layer composed of an alternately laminated layer structure of at least a thin layer A and a thin layer B formed on the surface of a tool substrate, such as a cemented carbide substrate, a cermet substrate, and a high-speed tool steel substrate. The thin layer A is an (Al, Cr, Si)N layer which satisfies a compositional formula: [AlXCrYSiZ]N (0.2?X?0.45, 0.4?Y?0.75, 0.01?Z?0.2, and X+Y+Z=1 in terms of atomic ratio). The thin layer B is an (Al, Ti, Si)N layer which satisfies a compositional formula: [AlUTiVSiW]N (0.05?U?0.75, 0.15?V?0.94, 0.01?W?0.1, and U+V+W=1 in terms of atomic ratio).
    Type: Grant
    Filed: August 1, 2008
    Date of Patent: January 15, 2013
    Assignee: Mitsubishi Materials Corporation
    Inventors: Koichi Maeda, Masanori Morikawa, Yuki Matsuoka, Natsuki Ichimiya
  • Patent number: 8354178
    Abstract: There is provided a method of making a heat treated (HT) coated article to be used in shower door applications, window applications, or any other suitable applications where transparent coated articles are desired. For example, certain embodiments of this invention relate to a method of making a coated article including a step of heat treating a glass substrate coated with at least a layer of or including diamond-like carbon (DLC) and an overlying protective film thereon. In certain example embodiments, the protective film may be of or include an oxide of zinc. Following and/or during heat treatment (e.g., thermal tempering, or the like) the protective film may be removed. Other embodiments of this invention relate to the pre-HT coated article, or the post-HT coated article.
    Type: Grant
    Filed: October 7, 2010
    Date of Patent: January 15, 2013
    Assignees: Guardian Industries Corp., Centre Luxembourg de Recherches pour le Verre et la Ceramique S.A. (C.R.V.C.)
    Inventors: Nestor P. Murphy, Maximo Frati, Rudolph Hugo Petrmichl, Jiangping Wang, Jens-Peter Muller, Herbert Lage
  • Patent number: 8349474
    Abstract: The invention relates to a hob cutter tool with a coating, wherein the coating is produced by a physical vapor deposition method, in which in a coating chamber in an atmosphere containing nitrogen, an arc discharge is generated in each case between at least one anode and at least one pure Al cathode on the one hand, and at least one pure Cr cathode on the other hand, and in this way, Al and Cr are vaporized from the cathode, in which the hob cutter tool to be coated is rotated in the coating chamber, wherein the tool is subsequently guided past the at least two cathodes, and in which the vaporized Al and Cr is deposited in atomic or ionized form together with nitrogen from the atmosphere containing nitrogen onto the hob cutter tool led rotating past the cathodes.
    Type: Grant
    Filed: August 18, 2009
    Date of Patent: January 8, 2013
    Assignee: Fette GmbH
    Inventors: Marcus Morstein, Tibor Cselle, Andreas Lumkemann, Jorn Kohlscheen
  • Patent number: 8343617
    Abstract: A Ceramic substrate is provided. The ceramic substrate includes a ceramic main body and a planar buffer layer on the ceramic main body. Further, the coefficient of thermal expansion of the ceramic main body CTEm and the coefficient of thermal expansion of the planar buffer layer CTEp satisfy the following mathematical relationship: |CTEm?CTEp|?3×10?6/° C.
    Type: Grant
    Filed: January 21, 2010
    Date of Patent: January 1, 2013
    Assignee: Industrial Technology Research Institute
    Inventors: Yu-Hsin Yeh, Tzer-Shen Lin, Ren-Der Jean
  • Patent number: 8338002
    Abstract: A sputtering composite target includes: an oxide based component containing indium oxide; and a carbon based component.
    Type: Grant
    Filed: June 4, 2009
    Date of Patent: December 25, 2012
    Assignee: Dexerials Corporation
    Inventors: Hayato Hommura, Kenji Katori, Go Sudo
  • Patent number: 8337988
    Abstract: A coated article is provided, having a coating supported by a glass substrate where the coating includes at least one color and/or reflectivity-adjusting absorber layer. The absorber layer(s) allows color tuning, and reduces the glass side reflection of the coated article and/or allows sheet resistance of the coating to be reduced without degrading glass side reflection. In certain example embodiments the absorber layer is provided between first and second dielectric layers which may be of substantially the same material and/or composition. In certain example embodiments, the coated article is capable of achieving desirable transmission, together with desired color, low reflectivity, and low selectivity, when having only one infrared (IR) reflecting layer of silver and/or gold. Coated articles according to certain example embodiments of this invention may be used in the context of insulating glass (IG) window units, monolithic windows, or the like.
    Type: Grant
    Filed: April 22, 2010
    Date of Patent: December 25, 2012
    Assignees: Centre Luxembourgeois de Recherches pour le Verre et la Ceramique S.A. (C.R.V.C.), Guardian Industries Corp.
    Inventors: Hartmut Knoll, Jochen Butz, Uwe Kriltz, Bernd Disteldorf, Jose Ferreira, Pierrot Pallotta
  • Patent number: 8334062
    Abstract: The present invention relates generally to a multi-layered article suitable for service in severe environments. The article may be formed of a substrate, such as silicon carbide and/or silicon nitride. The substrate may have a first layer of a mixture of a rare earth silicate and Cordierite. The substrate may also have a second layer of a rare earth silicate or a mixture of a rare earth silicate and cordierite.
    Type: Grant
    Filed: February 1, 2008
    Date of Patent: December 18, 2012
    Assignee: Saint-Gobain Ceramics & Plastics, Inc.
    Inventors: Vimal K. Pujari, Ara Vartabedian, William T. Collins, David Woolley, Charles Bateman
  • Patent number: 8329318
    Abstract: A coated substrate is disclosed. The coated substrate includes a substrate and a coating composition over the substrate comprising at least one metal based layer selected from tungsten, chromium, tantalum, molybdenum, aluminum, niobium, and mixtures and alloys thereof; and mixtures and alloys of cobalt and chromium; and at least one dielectric layer including SixNy, where x/y ranges from 0.75 to 1.5, over the metal based layer. The ?Ecmc (1.5:1) (T), ?Ecmc (1.5:1) (R1) and ?Ecmc (1.5:1) (R2) of a non-heat treated, coated substrate as compared to a heat treated, coated substrate according to the present invention are no greater than 8 units.
    Type: Grant
    Filed: March 22, 2011
    Date of Patent: December 11, 2012
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Dennis J. O'Shaughnessy, James J. Finley
  • Patent number: 8329304
    Abstract: A plasma display panel (PDP) includes an EMI filter supported by a glass substrate for blocking/shielding substantial amounts of electromagnetic waves, with the filter being supported by a side of the substrate opposite a viewer. In certain example embodiments, a black frit and a silver frit comprise a filter frame and are supported by the filter such that the filter is closer to the glass substrate than either or both of the frits. Alternatively, in certain example embodiments, a conductive black frit comprises a filter frame and is supported by the filter such that the filter is closer to the glass substrate than the frit. The filter has high visible transmission, and is capable of blocking/shielding electromagnetic waves. Advantageously, a transparent conductive coating (TCC) can be coated on a stock, non-cut glass sheet.
    Type: Grant
    Filed: August 21, 2008
    Date of Patent: December 11, 2012
    Assignee: Guardian Industries Corp.
    Inventors: Yei-Ping (Mimi) H. Wang, Brandon Bolt
  • Publication number: 20120308844
    Abstract: The present invention relates generally to methods for producing a coated jewelry article or a coated component of a jewelry article, comprising a jewelry article or a component of a jewelry article, a first metallic coating, and a second metallic coating.
    Type: Application
    Filed: June 1, 2012
    Publication date: December 6, 2012
    Applicant: FREDERICK GOLDMAN INC.
    Inventor: Andrew Derrig
  • Patent number: 8323783
    Abstract: A coated cutting insert for removing material from a workpiece that includes a substrate is disclosed. A wear-resistant coating on the substrate that includes an ?-alumina layer and a Zr— or Hf— carbonitride outer layer deposited on the ?-alumina layer. The Zr— or Hf— carbonitride outer layer is subjected to a post-coat wet blasting treatment. The wet blasting changes the stress condition of the exposed alumina coating layer from an initial tensile stress condition to a compressive stress condition.
    Type: Grant
    Filed: November 10, 2009
    Date of Patent: December 4, 2012
    Assignee: Kennametal Inc.
    Inventors: Volkmar Sottke, Zhigang Ban, Hartmut Westphal, Yixiong Liu, Michael Frank Beblo
  • Patent number: 8318329
    Abstract: The radiation-selective absorber coating (20) has two barrier layers (24a, 24b), an IR-reflecting layer (21) arranged thereon, an absorption layer (22) arranged above the IR-reflecting (21) and an antireflection layer (23) over the absorption layer (22). The absorber tube (13) is a steel tube (1) with the radiation-selective absorber coating (20) applied to the outside thereof. In the process of coating the absorber tube (13) a first oxide barrier layer (24a) is applied to a steel tube by thermal oxidation; a second barrier layer (24b) is then applied by physical gas phase deposition of silicon with supply of oxygen; the IR-reflecting layer (21) is then applied by gas phase deposition of gold, silver, platinum or copper; the absorption layer (22) is then applied by deposition of aluminum and molybdenum; and a final antireflection layer (23) is applied by deposition of silicon with supply of oxygen.
    Type: Grant
    Filed: February 17, 2009
    Date of Patent: November 27, 2012
    Assignee: Schott AG
    Inventors: Kamel Silmy, Jan Schulte-Fischedick, Thomas Kuckelkorn, Christina Hildebrandt, Wolfgang Graf, Andreas Georg
  • Patent number: 8318328
    Abstract: An inventive workpiece features on at least parts of its surface a wear resistant hard coating comprising the following composition Al1-a-b-c-dCraXbSicBdZ, where x is at least one element from Nb, Mo, W or Ta; Z is one element or compound from N, C, CN, NO, CO, CNO; and 0.2<=a<=0.5; 0.01<=b<=0.2; 0<=c<=0.1; 0<=d<=0.1. Further a PVD process for depositing such a wear resistant coating is disclosed whereby at least one workpiece is installed in a vacuum coating system and said system is operated in a low pressure argon atmosphere utilizing at least two metal or metal alloy targets with at least temporarily addition of a reactive gas.
    Type: Grant
    Filed: July 14, 2005
    Date of Patent: November 27, 2012
    Assignee: Oerlikon Trading AG, Trubbach
    Inventors: Jose Endrino, Volker Derflinger, Christoph Gey
  • Patent number: 8309235
    Abstract: A multilayer film-coated member is fabricated by coating the surface of a substrate with at least two hard coating films having different compositions, wherein the first composition hard film of the outermost layer is represented by SiaBbNcCdOe with a+b+c+d+e=1, 0.1?a?0.5, 0.01?b?0.2, 0.05?c?0.6, 0.1?d ?0.7 and 0<e?0.2, the second composition hard coating film having at least two selected from Al. Ti, Cr, Ni, Ce. Mg, Nb, W, Si, V, Zr and Mo and N and at least one selected from B, C, O and S and the oxygen content of the film at least 25 nm from the interface of the first composition hard coating film that is in contact with the underlying layer toward the surface of the first composition hard coating film is limited to a range of less than 3.5 atm. %.
    Type: Grant
    Filed: July 29, 2009
    Date of Patent: November 13, 2012
    Assignee: Sulzer Metaplas GmbH
    Inventor: Jörg Vetter
  • Patent number: 8309165
    Abstract: The present invention discloses a color filter by copper and silver film, comprising: a lower copper layer; a lower silver layer formed on the lower copper layer; a medium formed on the lower silver layer; an upper copper layer formed on the medium; and an upper silver layer formed on the upper copper layer.
    Type: Grant
    Filed: December 15, 2011
    Date of Patent: November 13, 2012
    Assignee: Pixart Imaging Inc.
    Inventors: Sen-Huang Huang, Chin-Poh Pang, Hsin-Hui Hsu
  • Patent number: 8309234
    Abstract: The invention provides a multilayer film-coated member having sufficient heat resistance and abrasion resistance and capable of exhibiting an effect of preventing adhesion even in cutting work of steel materials that may readily cause adhesion to cutting tools, and therefore capable of prolonging tools, and provides a method for producing it. The multilayer film-coated member is fabricated by coating the surface of a substrate with at least two hard coating films having different compositions, in which the first composition hard coating film of the outermost layer of the hard coating films represented by SiaBbNcCdOe with a+b+c+d+e=1, 0.1?a?0.5, 0.01?b?0.2, 0.05?c?0.6, 0.1?d?0.7 and 0<e?0.
    Type: Grant
    Filed: July 29, 2009
    Date of Patent: November 13, 2012
    Assignee: Sulzer Metaplas GmbH
    Inventor: Jörg Vetter
  • Patent number: 8304072
    Abstract: Certain example embodiments relate to robust semi-transparent coatings that are suitable for use in a wide variety of display-on-demand mirror applications, and methods of making the same. In certain example embodiments, a coated article includes a coating supported by a glass substrate. A reflective metal-inclusive layer is formed, directly or indirectly, on the glass substrate. A silicon oxide inclusive layer is formed, directly or indirectly, on the reflective metallic layer. A titanium oxide inclusive layer is formed, directly or indirectly, on the silicon oxide inclusive layer. The metal-inclusive layer is formed so as to reflect incoming light away from the glass substrate such that substantially less incoming light would be reflected away from the glass substrate if lighting were provided on a side of the glass substrate opposite the coating than if no lighting were provided. The surface of the coated article need not necessarily be conductive.
    Type: Grant
    Filed: October 7, 2008
    Date of Patent: November 6, 2012
    Assignee: Guardian Industries Corp.
    Inventors: Desaraju V. Varaprasad, Yiwei Lu
  • Patent number: 8304045
    Abstract: Certain example embodiments of this invention relate to articles including anticondensation coatings that are exposed to an external environment, and/or methods of making the same. In certain example embodiments, the anticondensation coatings may be survivable in an outside environment. The coatings also may have a sufficiently low sheet resistance and hemispherical emissivity such that the glass surface is more likely to retain heat from the interior area, thereby reducing (and sometimes completely eliminating) the presence condensation thereon. The articles of certain example embodiments may be, for example, skylights, vehicle windows or windshields, IG units, VIG units, refrigerator/freezer doors, and/or the like.
    Type: Grant
    Filed: May 10, 2010
    Date of Patent: November 6, 2012
    Assignee: Guardian Industries Corp.
    Inventors: Jean-Marc Lemmer, Nestor P. Murphy
  • Patent number: 8304098
    Abstract: The hard-coated member of the present invention having a compression-stress-loaded hard coating having a thickness of 5 ?m or more, the hard coating having a face-centered cubic structure having a composition represented by (Me1-aXa)?(N1-x-yCxOy), wherein Me is at least one element selected from Groups 4a, 5a and 6a, X is at least one element selected from the group consisting of Al, Si, B and S, a, x and y are respectively the contents (atomic ratios) of X, C and O, and ? is a ratio of (Me1-aXa) to (N1-x-yCxOy), meeting 0.1?a?0.65, 0?x?0.1, 0?y?0.1, and 0.85???1.25; and the X-ray diffraction of the hard coating having a peak intensity Ir of a (111) plane, a peak intensity Is of a (200) plane, and a peak intensity It of a (220) plane, meeting 2?Is/Ir, and 0.2?It/Ir?1, and the (200) plane having a half-value W(°)?0.7.
    Type: Grant
    Filed: October 12, 2007
    Date of Patent: November 6, 2012
    Assignee: Hitachi Tool Engineering, Ltd.
    Inventors: Kazuyuki Kubota, Hitoshi Ohnuma
  • Patent number: 8303856
    Abstract: Disclosed is a conductive laminated body, and a method for preparing the same, wherein the conductive laminated body including: a substrate; a zinc oxide-based thin film doped with an element M; and an interlayer including an oxide M?2O3, which is interposed between the substrate and the zinc oxide-based thin film. The disclosed conductive laminated body includes a metal oxide interlayer of an oxidation number +3, between a substrate and a zinc oxide layer. Therefore, it is possible to improve electrical properties of a transparent conductive thin film, especially, a resistivity property, and to minimize the unevenness in electrical properties between a middle portion and a circumferential portion on the surface of the thin film in sputtering deposition.
    Type: Grant
    Filed: February 26, 2008
    Date of Patent: November 6, 2012
    Assignee: LG Chem, Ltd.
    Inventors: Hyeon Woo Jang, Jungsik Bang