Product With Molecular Orientation Patents (Class 428/910)
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Patent number: 6524669Abstract: Layered heat-shrinkable films disclosed herein are suitable for labels on PET bottles requiring label fitting and heat shrinkage at a high speed, which film has at least three layers, that is, both outer layers and an intermediate layer, wherein the heat shrinkability in the main shrinkage direction of the film is 20% or higher after treatment in hot water at 70° C. for 5 seconds and 35% to 55% after treatment in hot water at 75° C. for 5 seconds and 50% to 60% after treatment in hot water at 80° C. for 5 seconds, and the compressive strength of a label formed from the film meets the following formula (1): Y>X2.2 where Y is compressive strength (mN) and X is film thickness (&mgr;m).Type: GrantFiled: August 30, 2001Date of Patent: February 25, 2003Assignee: Toyo Boseki Kabushiki KaishaInventors: Hideki Ito, Norimi Tabota, Hiroshi Nagano
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Patent number: 6524720Abstract: A multiple layer film useful in moisture barrier packaging applications has at least one layer comprising a blend of propylene polymer or copolymer, and a hydrocarbon resin; and two additional layers comprising a propylene polymer or copolymer, ethylene alpha olefin copolymer, ionomer, polybutene, or blends thereof. A core layer of ethylene vinyl alcohol copolymer or other oxygen barrier material, or high density polyethylene, can be included in some embodiments. A preferred embodiment of the multi-layer film exhibits excellent moisture barrier and optical properties, and shrink properties as well if the film has been oriented. High oxygen barrier is also a feature in embodiments including EVOH or other oxygen barrier materials.Type: GrantFiled: January 23, 1997Date of Patent: February 25, 2003Assignee: Cryovac, Inc.Inventor: Gautam P. Shah
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Publication number: 20030035946Abstract: The present invention provides a cover tape for packaging electronic components, which can prevent troubles associated with the peeling strength or appearing during mounting of the electronic components, which can be produced at a low cost, and which is transparent; that is, a cover tape which has a peeling strength not too high and not too low and small in difference between the maximum value and the minimum value and which has high transparency. Specifically, the present invention provides a cover tape for packaging electronic components, which can be heat-sealed to a plastic-made carrier tape having pockets capable of storing electronic components, formed regularly therein and which comprises (A) a biaxially oriented film layer made of a polyester, a polypropylene or a nylon and (B) a thermoplastic resin layer composed of 100 parts by weight of an ethylene copolymer and 10 to 100 parts by weight of a polystyrene, laminated to one side of the layer A.Type: ApplicationFiled: June 26, 2002Publication date: February 20, 2003Inventors: Hisao Nakanishi, Masayuki Hiramatsu
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Patent number: 6521333Abstract: Biaxially oriented films having a substantially non-voided pigmented core layer of a propylene homopolymer, an intermediate layer of a voided propylene homopolymer, and two outer layers of a heat sealable olefin polymer. Such films can be heat sealed to form seals with high seal integrity.Type: GrantFiled: February 27, 2001Date of Patent: February 18, 2003Assignee: Hoechst Trespaphan GmbHInventor: Stuart Blyth
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Patent number: 6521312Abstract: Cost effective film laminates having desirable stiffness and processes for making the same are disclosed. The laminates include outer layers formed from one or more films having superior flexural modulus properties sandwiching a thicker yet less stiff polyolefin layer. The multilayered structures are suitable for use in applications which typically require a single heavy gauge film having a high degree of stiffness, such as release liners and the like.Type: GrantFiled: November 28, 2000Date of Patent: February 18, 2003Assignee: Loparex, Inc.Inventor: LeRoy Herbert Keiser
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Patent number: 6511740Abstract: A biaxially oriented polyester film with a substantially non-crosslinked polymeric coating consisting essentially of a styrene/acrylate copolymer emulsion, wherein the coating is highly thermally stable with a primary onset temperature of greater than about 350° C., having a glass transition temperature between about 0° C. and about 50° C., having a rapid solubility in a low molecular weight organic solvent, and having a surface energy of greater than about 35 dyne/cm and less than about 40 dyne/cm.Type: GrantFiled: December 6, 2000Date of Patent: January 28, 2003Assignee: Toray Plastics (America), Inc.Inventors: Steven J. Sargeant, Yasushi Takada, Masaaki Sudo, John Fitch
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Patent number: 6511742Abstract: An adhesive tape which comprises: (1) a backing film, wherein the backing film has at least two intermeshed coextruded layers of different composition, whose interface has a nonlinear course in cross section, which continues laminarly in the machine direction and has been oriented in the machine direction, and has plane-parallel outer faces; and (2) at least one adhesive layer which is attached to the backing film.Type: GrantFiled: November 17, 2000Date of Patent: January 28, 2003Assignee: tesa AGInventors: Bernhard Müssig, Gert Schmeer
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Patent number: 6509087Abstract: A heat shrinkable, coextruded polyethylene film laminate having two surface layers, and an intermediate layer interposed therebetween, wherein each of the surface layers comprises a linear low density polyethylene having a density of 0.910-0.930 g/cm3 and a linear high density polyethylene having a density of 0.925-0.945 g/cm3 and wherein the intermediate layer comprises a linear low density polyethylene having a density of 0.910-0.930 g/cm3 and a linear very low density polyethylene having a density of 0.880-0.915 g/cm3.Type: GrantFiled: May 2, 2001Date of Patent: January 21, 2003Assignee: Okura Industrial Co., Ltd.Inventors: Hideki Uehara, Yoshio Matsuda, Kunio Sakauchi
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Patent number: 6506500Abstract: A biaxially oriented polyolefin film having more than one layer and made from a base layer and from at least one outer layer. The base layer include a fatty amide and the outer layer include at least 80% by weight of a linear olefin polymer. The film is suitable, for example, for producing a film laminate by melt extrusion of a polyethylene layer.Type: GrantFiled: May 21, 1999Date of Patent: January 14, 2003Assignee: Hoechst Trespaphan GmbHInventors: Wolfgang Rasp, Detlef Klaus Busch
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Publication number: 20030008162Abstract: An optical biaxially oriented polyester film, an adhesive film and a colored hard coat film, which can be adhered to the image display surface of a CRT or liquid crystal display device to improve the contrast and color purity of the CRT or the liquid crystal display device without deteriorating the brightness, can be provided.Type: ApplicationFiled: July 26, 2002Publication date: January 9, 2003Inventors: Taro Oya, Masayuki Fukuda, Makoto Handa
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Publication number: 20030008152Abstract: The present invention provides coextruded or laminated films having at least one layer of a fluoropolymer homopolymer or copolymer, a layer of a cyclic olefin homopolymer or copolymer and an intermediate adhesive layer. Such films have a high moisture barrier property and are substantially transparent.Type: ApplicationFiled: August 15, 2002Publication date: January 9, 2003Applicant: Honeywell International Inc.Inventors: Mingliang Lawrence Tsai, John Blum
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Publication number: 20030008163Abstract: The 4-methyl-1-pentene copolymer multi-layer film according to the present invention is a three-layer laminate or a five-layer laminate, which comprises a layer (A) comprising 4-methyl-1-pentene, a layer (B) comprising polypropylene or polyethylene, and optionally, a layer (C) comprising an adhesive resin, said layer (A) being provided on each surface of the layer (B) in the three-layer laminate or being provided on each surface of the layer (B) through the layer (C) in the five-layer laminate, and this multi-layer film is uniaxially stretched in a stretch ratio of not less than 2 times or biaxially oriented in a stretch ratio of not less than 1.5 times in each of the machine direction and the transverse direction.Type: ApplicationFiled: May 20, 2002Publication date: January 9, 2003Inventors: Takashi Nakahara, Shinichi Imuta, Hiromi Shigemoto
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Patent number: 6503588Abstract: The present invention provides a multilayered structure where an A layer made of an ethylene-vinyl alcohol copolymer resin (A) and a C layer made of a polypropylene resin (C) are laminated via a B layer made of an adhesive resin (B). The ethylene content of the ethylene-vinyl alcohol copolymer resin (A) is 20 to 60 mol %, and the saponification degree of the resin (A) is at least 90%. The melt flow rate (MFR) of the polypropylene resin (C) at 230° C. under a load of 2160 g is in the range from 0.1 to 100 g/10 min, and the stereoregularity index [M5] of the polypropylene resin (C) is at least 0.950. Such a multilayered structure has excellent gas barrier properties and moldability.Type: GrantFiled: June 9, 2000Date of Patent: January 7, 2003Assignee: Kuraray Co., Ltd.Inventors: Nahoto Hayashi, Hiroyuki Shimo, Kaoru Nemoto, Kazuhiko Negishi
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Patent number: 6503635Abstract: A metallized biaxially oriented film has at least one polypropylene layer and a metallized skin layer. This skin layer is formed from a blend of polymers including syndiotactic polypropylene. The polymer which is blended with the syndiotactic polypropylene may be a butylene-propylene copolymer or a graft copolymer of propylene and maleic anhydride. The film may include a separate non-metallized biaxially oriented film laminated to the metallized biaxially oriented film. The metal layer provides a barrier to oxygen and water vapor. The metallized film can be processed through package forming machines without damage to the metal barrier layer.Type: GrantFiled: November 8, 1999Date of Patent: January 7, 2003Assignee: Exxon Mobil Oil CorporationInventors: Dan-Cheng Kong, Donald F. Sexton
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Publication number: 20030004237Abstract: The invention concerns transparent, flame retardant, thermoformable, UV-stabilized, single layered or multilayered films, containing a cristallizable thermoplastic material, preferably polyethyleneterephthalate, at least one flame retarding agent and a UV stabilizer as main components. Said films are characterized by good stretchability, thermoformability and good optical and mechanical properties, which makes them and the shaped bodies made from said films suitable for both inner and outer applications.Type: ApplicationFiled: July 18, 2002Publication date: January 2, 2003Inventors: Ursula Murschall, Ulrich Kern, Andreas Stopp, Guenther Crass
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Publication number: 20030003296Abstract: The invention relates to a packaging material made of a multilayer oriented polyolefin film, which comprises a base layer and at least one first outer layer, whereby the first outer layer is placed in contact with itself or in contact with the opposing surface of the film or in contact with the surface of another film. This first outer layer contains an additive which absorbs light within the wavelength range of a laser such that when the film is locally irradiated by the laser, the area of irradiation experiences an increase in temperature that causes the polyolefin of the first outer layer to soften or melt in the irradiated area and to bond to another layer when cooled.Type: ApplicationFiled: June 19, 2002Publication date: January 2, 2003Inventors: Thomas Dries, Wolfgang Eiser
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Patent number: 6500533Abstract: A method for producing an opaque polymeric film comprises: (a) extruding a base layer comprising a polymeric matrix and at least one cavitating agent; (b) coextruding at least one additional layer on at least one side of the base layer; (c) cooling the coextruded multi-layer film; and then (d) orienting the film in at least the machine direction (MD); wherein at least said base layer contains polybutylene terephthalate (PBT) and polycarbonate.Type: GrantFiled: February 9, 2000Date of Patent: December 31, 2002Assignee: ExxonMobil Oil CorporationInventors: Dan-Cheng Kong, John A. Larter, Eldridge M. Mount, III
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Patent number: 6500563Abstract: Improved thermoplastic polymer elastic film blend compositions including a crystalline isotactic polypropylene component and a crystallizable alpha-olefin and propylene copolymer component, the copolymer having crystallizable alpha-olefin sequences. In a preferred embodiment, improved thermoplastic polymer blends are provided made up of from 0% to 95%, preferably 2% to 40 weight % of the crystalline isotactic polypropylene and from 5% to 100%, preferably 60% to 98 weight % of a crystallizable ethylene and propylene copolymer, wherein the copolymer has isotactically crystallizable propylene sequences and is predominately propylene. The resultant blends manifest unexpected compatibility characteristics, and improved resistance to elastic deformation of the crystalline isotactic polypropylene and from of a crystallizable ethylene and propylene copolymer.Type: GrantFiled: May 11, 2000Date of Patent: December 31, 2002Assignee: ExxonMobil Chemical Patents Inc.Inventors: Sudhin Datta, Jeffrey Middlesworth
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Publication number: 20020197499Abstract: The invention provides a molded article having excellent impact, adhesive and printing properties. The invention also provides a molded article which has a low natural shrinkage percentage, a high shrinkage percentage in heating and a low density and is thus excellent in solvent resistance and hygiene.Type: ApplicationFiled: December 28, 2001Publication date: December 26, 2002Inventors: Toshiyuki Hirose, Masao Maeno
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Publication number: 20020197496Abstract: A polyester film for dry film resists, which satisfies requirements for transparency, particularly transmittance of radiation having a wavelength around 365 nm, slipperiness, winding properties, resolution and recyclability. A polyester film for dry film resists which has a thickness of 10 to 25 &mgr;m, a haze value of 3% or less and a residual polycondensation metal catalyst content of less than 150 ppm, and a metal antimony content of 15 mmol % or less based on the total of all the acid components, and a laminated polyester film comprising a lubricating layer on at least one side of the above film.Type: ApplicationFiled: April 17, 2002Publication date: December 26, 2002Inventors: Kei Mizutani, Koji Kubo
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Publication number: 20020198307Abstract: The low intrinsic viscosity drop, low acetaldehyde, polyester composition of the invention typically produce packaging materials such as bottles. The polyester, generally PET, uses additives such as fumed silicon dioxide. The additives are added in small amounts for achieving the following benefits: (i) lower I.V. (intrinsic viscosity) drop during the injection molding process; (ii) lower levels of acetaldehyde in the resultant preforms/bottles. These properties are achieved without affecting strain-hardening properties during the stretch-blow molding operation; and without affecting anti-blemishness properties in the final bottles. These additives alone or in conjunction with carbon black provide the faster line speeds that production needs.Type: ApplicationFiled: July 29, 2002Publication date: December 26, 2002Inventor: Rajesh Jalan
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Publication number: 20020197463Abstract: Polymeric films including a layer of propylene polymer resin having microvoids therein, the microvoids having been formed by stretching a web containing the beta-form of polypropylene, have shown low static cling when being unwound from rolls in labelling operations and also during destacking of pre-formed labels. The invention provides labels formed from such films.Type: ApplicationFiled: August 6, 2002Publication date: December 26, 2002Applicant: Hoechst Trespaphan GmbHInventors: Paul Malcolm Mackenzie Davidson, Rebecca Karen Govier, Helen Ann Biddiscombe, Marc Fritz Manfred OTT
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Patent number: 6495266Abstract: The invention discloses methods of improving blocking resistant properties and reducing the coefficient of friction of a multilayer film comprising providing at least one layer of an ethylene-propylene impact copolymer having from about 3% to about 30% by weight ethylene, wherein said copolymer has no more than two peaks in the melting curve within the range from about 110° C. to about 165° C., and wherein said layer is non-heat sealable, to a multilayer film having a core layer comprising polypropylene, high density polyethylene (HDPE) or linear low density polyethylene (LLDPE), whereby anti-blocking and coefficient of friction characteristics of said film is improved without necessity of adding an antiblock or slip agent.Type: GrantFiled: December 23, 1999Date of Patent: December 17, 2002Assignee: ExxonMobil Oil CorporationInventor: Robert A. Migliorini
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Patent number: 6495246Abstract: A composite film is provided by providing a poly-propylene or other base resin layer, laminating a first covering layer of a resin composition (1) comprising the following components (A), (B), (C) and (D) to one side of the base resin layer and a second covering layer of a resin composition (2) comprising the components (A) and (D) to the other side of the base resin layer, which composite film is optionally stretched. The resin composition (2) may contain component (C). (A) a heat-sealable olefinic polymer (e.g. a propylene series copolymer such as propylene-ethylene copolymer, propylene-butene-1 copolymer or propylene-ethylene-butene-1 copolymer) (B) a diorganopolysiloxane (e.g. dimetylpolysiloxane) (C) a fine-powdered heat-resistant resin (e.g. microspheres of a thermosetting resin) (D) a higher fatty acid amide This composite film is excellent in slidability, antistaticity, releasability and clarity and compatible with a high-speed automatic overwrap packaging machine.Type: GrantFiled: October 7, 1996Date of Patent: December 17, 2002Assignee: Daicel Chemical Industries, Ltd.Inventors: Takatoshi Sakaguchi, Junichi Kimura, Teruaki Yoshida
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Patent number: 6495231Abstract: A laminated multilayer film substrate for use in the production of banknotes having an oriented polypropylene core layer and at least one high density polyethylene layer on each side of the oriented polypropylene layer. The core layer may contain microcavities formed by the addition of a cavitating agent. The outer surfaces of the multilayer film substrate are coated with one or more epoxy layers, filed or unfilled, and one or more antistatic layers. The resultant films exhibit good embossability, dead-fold characteristics and other properties, making them highly suited for the production of bank notes and other security documents.Type: GrantFiled: December 7, 2000Date of Patent: December 17, 2002Assignee: ExxonMobil Oil CorporationInventors: Gordon L. Benoit, Dennis E. McGee
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Publication number: 20020182426Abstract: The polypropylene composite film of the present invention comprises (A) a crystalline polypropylene layer and (B) a propylene-1-butene random copolymer layer which is laminated on at least one surface of the crystalline polypropylene layer (A). The propylene/1-butene random copolymer (B) has the following properties: (1) the copolymer comprises 50 to 95% by mol of constituent units derived from propylene and 50 to 5% by mol of constituent units derived from 1-butene, (2) the intrinsic viscosity is 0.1 to 5 dl/g, (3) the molecular weight distribution (Mw/Mn) is not less than 3, and (4) the parameter B value is 1.0 to 1.5. The crystalline polypropylene layer (A) of this composite film may be unstretched, monoaxially stretched or biaxially oriented. The polypropylene composite film has excellent heat-sealing properties, such as low-temperature heat-sealing properties and heat-sealing strength, and hot tack properties.Type: ApplicationFiled: May 17, 2002Publication date: December 5, 2002Inventors: Yasuo Tanaka, Masahiro Sugi, Mamoru Kagami
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Publication number: 20020182427Abstract: An oriented film of polyvinyl alcohol derived film with reduced stretch irregularity and uniform orientation in a wide range of a stretching ratio is obtained by a manufacturing method for an oriented film, comprising the steps of: contacting a non-stretched film, comprising polyvinyl alcohols or derivatives thereof, with moisture percentage adjusted to no more than 10%, to at least one heating roll currently driven and heating the film at no less than 70° C.; subsequently giving a tension and stretching using a peripheral velocity difference between the heating roll concerned and a stretch roll in a position ahead of said heating roll in a running direction of the film.Type: ApplicationFiled: April 2, 2002Publication date: December 5, 2002Inventors: Seiji Kondo, Kazuki Tsuchimoto, Akihiro Nishida, Ryouji Kinoshita
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Patent number: 6489021Abstract: The present invention provides a multi-layer resin film having excellent oxygen gas barrier properties, particularly even at high humidity, and further having no chlorine content. The multi-layer resin film of the present invention has a biaxially-stretched polypropylene resin film, an adhesive layer formed on at least one surface of the polypropylene resin film, and a polyvinyl alcohol resin layer formed on the adhesive layer, wherein the polyvinyl alcohol resin layer has a value of crystallinity parameter (CP (M//) ⊥) not less than 0.8. The multi-layer resin film of the present invention can be prepared by forming an adhesive layer on at least one surface of an unstretched polypropylene resin film; stretching the film in one direction; forming a polyvinyl alcohol resin layer on the adhesive layer; and stretching the film in another direction perpendicular to the direction of previous stretching.Type: GrantFiled: March 12, 2001Date of Patent: December 3, 2002Assignee: Toyo Boseki Kabushiki KaishaInventors: Yoshifumi Yamamoto, Ichiro Kitaura, Yutaka Matsumura, Noriko Takahashi, Takeshi Ohazama, Chikao Morishige
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Publication number: 20020176974Abstract: A heat-seal polymer film and method of forming such film is provided. The heat-seal film is formed from metallocene-catalyzed isotactic random copolymers of propylene and at least one other C2 to C8 alpha olefin, such as ethylene random. Such films show improved heat-seal characteristics, such as reduced seal initiation temperatures (SIT's) and improved heat-seal strength, as well as other improved properties.Type: ApplicationFiled: March 16, 2001Publication date: November 28, 2002Inventors: Aiko Hanyu, Scott D. Cooper, Mark Miller
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Patent number: 6485817Abstract: Oriented polyolefin composite films are disclosed comprised of core including an olefin heteropolymer core consisting essentially of an ethylene/propylene copolymer having less than 10%, by weight, ethylene and having a skin layer on at least one of its surfaces comprised of a high modulus polypropylene. These films are characterized by an oxygen and moisture vapor transmission rate greater than that of conventional polypropylene films and a tensile modulus great enough to permit their use as packaging films. This combination of properties makes these films suitable for packaging fresh produce items which continue to respire after they are harvested.Type: GrantFiled: November 28, 2000Date of Patent: November 26, 2002Assignee: Applied Extrusion Technologies, Inc.Inventor: Mark T. DeMeuse
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Patent number: 6485818Abstract: The present invention relates to a primer coated polyester film for imaging media which has a thickness of 40 to 200 &mgr;m, a haze of not more than 5%, and comprises a biaxially oriented polyester film support and at least one priming layer laminated on the support and oriented at least monoaxially. The priming layer is formed from a coating solution containing a water-soluble resin (A) having vinyl alcohol units as a main constituent and a water-soluble or water-despersible resin (B) having an aromatic polyester unit.Type: GrantFiled: April 26, 1999Date of Patent: November 26, 2002Assignee: Mitsubishi Polyester Film CorporationInventor: Masato Fujita
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Patent number: 6482526Abstract: The present invention relates to a polyester resin-covered metal sheet exhibiting superior formability and particularly suitable to withstand the stresses of drawing, drawing and ironing, drawing and stretch forming, or drawing and stretch forming followed by ironing. The resin-covered metal sheet is produced by contacting a biaxially oriented polyester resin film to a metal sheet heated above the melting temperature of the resin, covering the metal sheet with the polyester resin, pinching and press laminating the film-metal sheet composite, and cooling the laminate at a rate of 600° C./second immediately thereafter. It is essential that the resulting resin-covered metal sheets exhibit a true stress of 3.0 to 15.0 kg/mm2, corresponding to a true strain of 1.0 at 75° C. These laminates also exhibits a gradation of retention of the polyester resin's original biaxial orientation.Type: GrantFiled: June 15, 1999Date of Patent: November 19, 2002Assignee: Toyo Kohan Co., LTDInventors: Hiroyuki Iwashita, Fumiko Gotoh, Atsuo Tanaka
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Patent number: 6482532Abstract: Easy-tear, non-halogenated, high-clarity ethylene polymer films are described that do not contain migratory additives and that are useful as a domestic food wrap. These films also exhibit high inherent cling values. In one embodiment, the film is multilayered in which the outer layers comprise a very low density heterogeneously linear polyethylene or a homogeneously branched polyethylene, preferably a substantially linear ethylene polymer, and the inner layer(s) comprise a low density polyethylene. In another embodiment, the film is a monolayer, or multiple layers of the same formula, in which the film comprises a mixture of a very low density heterogeneous linear polyethylene or a homogeneously branched polyethylene, preferably a SLEP, and a LDPE.Type: GrantFiled: June 7, 2000Date of Patent: November 19, 2002Assignee: Dow Global Technologies Inc.Inventors: Peter C. C. Yap, Shih-Yaw Lai
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Patent number: 6482501Abstract: An optical-use adhesive film includes a substrate film formed of a biaxially oriented polyester film; and a polymeric adhesive layer provided on at least one surface of the substrate film. The optical-use adhesive film has a haze of 1.0% of less, and the substrate film contains foreign substance particles having a maximum size of about 20 &mgr;m or more at a ratio of about 10/m2 or less.Type: GrantFiled: May 18, 1999Date of Patent: November 19, 2002Assignee: Toyo Boseki Kabushiki KaishaInventors: Naoki Mizuno, Mikio Matsuoka
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Patent number: 6481476Abstract: The present invention provides the method of manufacturing the artificially figured veneer or artificially figured board at high productivity with the expression of the grain and figure of natural wood in very similar form observed in natural woods, in addition to normal grain of natural wood.Type: GrantFiled: May 31, 2001Date of Patent: November 19, 2002Assignee: Hokusan Ltd.Inventor: Susumu Okamoto
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Patent number: 6479162Abstract: A composition includes greater than 50% by weight such as between 51% and 99% by weight, of a first PVdC copolymer having a weight average molecular weight of between 80,000 and 125,000, and less than 50% by weight, such as between 1% and 49%, by weight of a second PVdC copolymer having a weight average molecular weight of between 126,000 and 180,000, the weight percent of each of the first and second polymers based on the combined weight of the first and second polymers. A film includes at least one layer having the above composition. A film can have at least one layer including a blend of a first vinylidene chloride polymer and a second vinylidene chloride polymer, the film having a free shrink ratio of between 0.6 and 2.2 at a shrink temperature of 180° F., or a free shrink ratio of between 0.8 and 1.4 at a shrink temperature of 200° F. Methods of making the film of the invention are also disclosed.Type: GrantFiled: September 29, 2000Date of Patent: November 12, 2002Assignee: Cryovac, Inc.Inventor: Solomon Bekele
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Patent number: 6479138Abstract: A film includes a core layer including a linear random alpha-olefin/vinyl aromatic copolymer; and first and second outer layers including an olefinic polymer; the film having Young's modulus between 50,000 and 200,000 psi, free shrink between 40 and 80% at 240° F., and shrink tension of between 50 and 400 psi, or a shrink force of between 20 and 180 grams, at 240° F. First and second intermediate layers including an ethylene copolymer having a melt index less than 2.0 can be optionally included. Alternatively, a film includes a core layer including an ethylene copolymer having melt index less than 2.0; first and second intermediate layers including a linear random alpha-olefin/vinyl aromatic copolymer; and first and second outer layers including an olefinic polymer; the film having properties as disclosed above.Type: GrantFiled: February 27, 2001Date of Patent: November 12, 2002Assignee: Cryovac, Inc.Inventor: Blaine Childress
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Patent number: 6479137Abstract: The present invention relates to multilayer laminates having controlled directional tearing in both the machine direction (MD) and the transverse direction (TD). It is desirable to have controlled tearing for use in connection with pouches or other packages having a reclose device. The laminate is made up of a biaxially oriented inner layer containing linear low density polyethylene (LLDPE) and having a tensile elongation to break of less than 200% in the MD and less than 150% in the TD, an outer layer having a heat distortion temperature of at least 10° C. higher than the inner layer and a tensile longation to break of less than 200% in the MD and less than 150% in the TD, and an adhesive layer containing an adhesive polymer sandwiched between the inner and outer layers and adhering the two layers to each other.Type: GrantFiled: May 9, 2000Date of Patent: November 12, 2002Assignee: Exxon Mobil Oil CorporationInventors: Patrick K. Joyner, Dan-Cheng Kong
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Publication number: 20020164470Abstract: A thermoplastic multi-layer film for forming hermetic seals on packages comprising layer B comprising polypropylene and a softening additive; and layer C comprising a copolymer.Type: ApplicationFiled: February 20, 2002Publication date: November 7, 2002Inventor: Michael J. Bader
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Publication number: 20020160170Abstract: A multi-layered stretched resin film comprises a base layer (A) comprising more than 90 wt % of a polyolefinic resin and less than 10 wt % of an inorganic fine powder and/or an organic filler; and an amorphous resin-containing layer (B), comprising 0 to 85 wt % of a second polyolefinic resin, which may be the same or different than the first polyolefinic resin, and 15 to 100 wt % of an amorphous resin. The amorphous resin-containing layer (B) is disposed on at least one side of the base layer (A), and has a porosity of 5% or less. Such multi-layered stretched resin films are resistant to waving or curling caused by exposure to the vehicle component of offset printing inks during offset printing, and therefore have excellent printing properties.Type: ApplicationFiled: February 4, 2002Publication date: October 31, 2002Applicant: YUPO CORPORATIONInventors: Atsushi Ishige, Kazuhisa Kitamura
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Publication number: 20020160169Abstract: A thermoplastic multi-layer film for forming hermetic seals on packages comprising layer A comprising polyethylene, layer B comprising polypropylene, layer C comprising a copolymer, and an adhesion promoting coating applied to layer C.Type: ApplicationFiled: February 20, 2002Publication date: October 31, 2002Inventor: Michael J. Bader
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Publication number: 20020160167Abstract: A thermoplastic multi-layer film for forming hermetic seals on packages comprising layer A comprising polyethylene, layer B comprising polypropylene, layer C comprising a copolymer, and an adhesion promoting coating applied to layer C.Type: ApplicationFiled: February 23, 2001Publication date: October 31, 2002Inventor: Michael J. Bader
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Publication number: 20020160215Abstract: The present invention relates to a high-whiteness, biaxially oriented polyester film with at least a base layer made from polyester. The base layer of the polyester film of the invention also comprises from 2 to 60% by weight of a cycloolefin copolymer (COC), from 0.1 to 25% by weight of a white pigment, and, if desired, from 0 to 5% by weight of an optical brightener, based on the weight of the base layer. The glass transition temperature of the COC here is to be within the range from 70 to 270° C. The film is particularly suitable for packing foods or other consumable items which are sensitive to light and/or to air, or for use in industry, e.g. for producing hot-stamping foils or as a label film, or for image-recording papers, printed sheets, or magnetic recording cards, or for processing on high-speed machinery for winding, metallizing, printing or laminating.Type: ApplicationFiled: February 23, 2001Publication date: October 31, 2002Inventors: Herbert Peiffer, Gottfried Hilkert, Bart Janssens
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Publication number: 20020160217Abstract: A method for producing a biaxially stretched film is provided, in which the method comprises, stretching a film made mainly of an ethylene-vinyl alcohol copolymer having an ethylene content of 15 to 70 mol % and a saponification degree of 80 mol % or more under heating; cooling the film; and subjecting the cooled film to a heat treatment; wherein a heating temperature during the stretching is 60 to 160° C., a cooling temperature is a temperature 30 to 100° C. lower than the heating temperature during the stretching, and a temperature for the heat treatment is 150 to 190° C. The thus obtained biaxially stretched film of the present invention has a small bowing coefficient.Type: ApplicationFiled: February 14, 2002Publication date: October 31, 2002Applicant: KURARAY CO. LTD.Inventors: Kazuhisa Okada, Nariaki Fujii
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Publication number: 20020160171Abstract: The invention relates to a transparent, biaxially oriented polyester film which comprises at least 80% by weight of thermoplastic polyester and also comprises an amount in the range from 0.05 to 0.5% by weight of a specific pigment system. The invention further relates to a process for producing the film. The film can be used as a packaging film, or for metalizing or ceramic coating, and in applications in the industrial sector, as a substrate for stamping foils.Type: ApplicationFiled: February 15, 2002Publication date: October 31, 2002Inventors: Herbert Peiffer, Martin Mueller-Roosen, Gottfried Hilkert
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Patent number: 6472046Abstract: A biaxially oriented polyester film to be laminated onto a metal plate and molded, (A) which comprises a copolyester comprising (a) terephthalic acid in an amount of 82 to 100 mol % and 2,6-naphthalenedicarboxylic acid or a combination of 2,6-naphthalenedicarboxylic acid and other dicarboxylic acid in an amount of 0 to 18 mol % of the total of all dicarboxylic acid components and (b) ethylene glycol in an amount of 82 to 100 mol % and cyclohexanedimethanol or a combination of cyclohexanedimethanol and other diol in an amount of 0 to 18 mol % of the total of all diol components, having (c) a glass transition temperature of 78° C. or more and (d) a melting point of 210 to 250° C., and containing (e) porous silica particles with a pore volume of 0.5 to 2.0 ml/g which are agglomerates of primary particles having an average particle diameter of 0.001 to 0.1 &mgr;m; and (B) which has the following relationship between the highest peak temperature (Te, °C.Type: GrantFiled: August 18, 1999Date of Patent: October 29, 2002Assignee: Teijin LimitedInventors: Koji Kubo, Hirofumi Murooka, Masahiko Kosuge, Hideshi Kurihara
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Publication number: 20020155267Abstract: A thermoplastic multi-layer film for forming hermetic seals on packages comprising layer B comprising polypropylene and a softening additive; and layer C comprising a copolymer.Type: ApplicationFiled: February 22, 2001Publication date: October 24, 2002Inventor: Michael John Bader
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Publication number: 20020155277Abstract: The present invention discloses a multi-layered stretched resin film which comprises a base layer (A) containing 40 to 90 wt % of a polyolefinic resin and 10 to 60 wt % of an inorganic fine powder or an organic filler; and an amorphous resin-containing layer (B) provided on at least one side of such base layer (A), and containing 0 to 85 wt % of a polyolefinic resin and 15 to 100 wt % of an amorphous resin; where the amorphous resin-containing layer (B) has a porosity of 5% or below. Such multi-layered stretched resin film is successfully exempt from being waved or curled due to vehicle contained in offset printing ink during offset printing, and can thus ensure excellent printability.Type: ApplicationFiled: October 2, 2001Publication date: October 24, 2002Applicant: YUPO CORPORATIONInventors: Atsushi Ishige, Kazuhisa Kitamura
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Publication number: 20020156167Abstract: To provide a polyolefin based resin film of high elastic modulus and a composition for producing a polyolefin based resin film of high elastic modulus. The polyolefin based resin film is characterized in that a polyolefin [A] having a weight average molecular chain length of 2850 nm or more and a polyolefin wax [B] having a weight average molecular weight of 700 to 6000 have been compounded in a ratio of [A]/[B]=90/10 to 50/50 (by weight) as the resin component, and 10 to 300 parts by weight of inorganic fillers have been added to 100 parts by weight of the resin component.Type: ApplicationFiled: March 25, 2002Publication date: October 24, 2002Applicant: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Atsuhiro Takata, Ryuma Kuroda, Satoshi Hanada, Takeshi Yamada
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Publication number: 20020155308Abstract: The present invention is directed to a biaxially oriented multi-layer film which comprises: (a) a core layer comprising a syndiotactic propylene homopolymer; and (b) at least one additional layer adjacent to the core layer comprising a polymer which is an ethylene or a propylene homopolymer, ethylene copolymer or terpolymer containing comonomers of propylene and/or butene-1. Optionally, there can be a skin layer applied to the exposed surface of the outer layer. The skin layer and/or the at least one additional layer is a polyolefin selected from the group consisting of isotactic polypropylene, polyethylene, ethylene-propylene random copolymer, ethylene-propylene block copolymer or ethylene-propylene -butene-1 terpolymer.Type: ApplicationFiled: December 21, 2001Publication date: October 24, 2002Inventors: Michael T. Heffelfinger, Jay K. Keung, Robert G. Peet