Product With Molecular Orientation Patents (Class 428/910)
  • Patent number: 6726998
    Abstract: A biaxially oriented polyolefin multilayer film having a skin layer made of a blend of a crystalline wax and a non-polar polymer is disclosed. The film has substantially no inorganic fillers and yet shows no visible distortion after exposure to food products such as potato chips.
    Type: Grant
    Filed: August 29, 2002
    Date of Patent: April 27, 2004
    Assignee: Toray Plastics (America), Inc.
    Inventors: Tien-Kuei Su, Leo Moreau, Kevin Kitchin
  • Patent number: 6727000
    Abstract: Multilayer heat-shrinkable films in which the skin layers A consist of a polyolefin selected from: A1) a composition containing 25-45% b.w. of a random copolymer of propylene with ethylene and 55-75% b.w. of a random terpolymer of propylene, ethylene and one or more C4-C10 alpha-olefins; and A2) random copolymer(s) of propylene and one or more C4-C10 alpha-olefins. Core layer B comprises a heterophasic composition comprising: a) 20-60% b.w. of a propylene homopolymer with an isotacticity index higher than 80 or of a propylene crystalline copolymer with ethylene and/or C4-C10 alpha-olefins containing at least 85% b.w. of propylene units and having an isotacticity index of at least 80 or of mixtures thereof and b) 40-80% b.w. of an ethylene copolymer with propylene and/or 1-butene and possibly a diene, containing 20-60% b.w. of ethylene units and completely soluble in xylene at 25° C.
    Type: Grant
    Filed: November 20, 2001
    Date of Patent: April 27, 2004
    Assignee: Basell Poliolefine Italia S.p.A.
    Inventors: Anne-Marie Joly, Enrico Beccarini
  • Patent number: 6720065
    Abstract: A laminated structure having a film composite overlying a substrate sheet, used as a decorative panel for appliances and motor vehicles. The laminated structure has high distinctness of image in both the machine direction and the transverse direction, and a ratio of these approaching 1.0.
    Type: Grant
    Filed: May 29, 2003
    Date of Patent: April 13, 2004
    Assignee: DuPont Teijin Films U.S. Limited Partnership
    Inventor: Steven R. Cosentino
  • Patent number: 6713169
    Abstract: The present invention discloses a multi-layered stretched resin film which comprises a base layer (A) containing 40 to 90 wt % of a polyolefinic resin and 10 to 60 wt % of an inorganic fine powder or an organic filler; and an amorphous resin-containing layer (B) provided on at least one side of such base layer (A), and containing 0 to 85 wt % of a polyolefinic resin and 15 to 100 wt % of an amorphous resin; where the amorphous resin-containing layer (B) has a porosity of 5% or below. Such multi-layered stretched resin film is successfully exempt from being waved or curled due to vehicle contained in offset printing ink during offset printing, and can thus ensure excellent printability.
    Type: Grant
    Filed: October 2, 2001
    Date of Patent: March 30, 2004
    Assignee: Yupo Corporation
    Inventors: Atsushi Ishige, Kazuhisa Kitamura
  • Patent number: 6713165
    Abstract: Multilayer structure based on thermoplastic polymers which is substantially devoid of vinyl chloride polymers and of plasticizers of low molecular mass and which comprises at least 3 layers: a first layer (A) comprising at least 60% by weight of at least one polyolefin of controllable crystallinity defined as comprising at least 90% of ethylene, of propylene or of butene and as having a softening temperature of less than 121° C., the thickness of the first layer being at least 20% of the total thickness of the structure and the first layer having a modulus of elasticity of less than 350 MPa; a second layer (B), positioned between the first layer (A) and the third layer (C), comprising at least 40% by weight of at least one polyolefin of controllable crystallinity, the second layer having an overall softening temperature of less than 121° C.
    Type: Grant
    Filed: July 16, 2002
    Date of Patent: March 30, 2004
    Assignee: Solvay (Societe Anonyme)
    Inventor: Petrus J. A. Karsten
  • Patent number: 6713185
    Abstract: A method of forming a reinforced polymer film structure is disclosed that includes the steps of slitting a biaxially oriented polymer film web having a top face and a bottom face into a first portion and a second portion, identifying the first portion and the second portion, and placing the first portion atop the second portion, such that the bottom face of the first portion is adjacent the top face of the second portion. This structure provides an impact and tear resistant laminate. Also disclosed is a method of forming a polymer film structure by identifying a molecular orientation direction profile of two portions of biaxially oriented polymer film and layering the two portions such that a molecular orientation direction profile of one does not coincide with a molecular orientation direction profile of the other.
    Type: Grant
    Filed: February 13, 2001
    Date of Patent: March 30, 2004
    Assignee: Mitsubishi Polyester Film, LLC
    Inventors: Charles David Carlson, Jr., Russell Scott Foxhall
  • Patent number: 6713175
    Abstract: An object is to provide a biaxially stretched film which allows tacking, is heat-stickable, is less liable to unevenness in thickness, breakage, whitening, unevenness, etc. i.e. has stretching stability and is decomposable in the natural environment. It comprises a polylactic acid-family polymer as its major component, and has a storage elastic modulus E′ at 120° C. of 100-230 MPa as measured using a test method concerning temperature dependency of the dynamic viscous elasticity under JIS K7198.
    Type: Grant
    Filed: September 3, 2002
    Date of Patent: March 30, 2004
    Assignee: Mitsubishi Plastics, Inc.
    Inventors: Shigenori Terada, Jun Takagi
  • Patent number: 6709734
    Abstract: Disclosed are a resin sheet that has a resin layer which is made up of a thermoplastic resin and which has a degree of orientation of not less than 0.0002 and not more than 0.0020, and a thermoformed article and laminate structure. The resin sheet is preferably employed in a thermoforming process. Particlarly favorable application of the resin sheet is a paintless film, which is usually thermoformed and then laminated to a molten resin.
    Type: Grant
    Filed: August 20, 2002
    Date of Patent: March 23, 2004
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Kenichi Higashi, Kouichi Yanase
  • Patent number: 6709761
    Abstract: The invention provides a molded article having excellent impact, adhesive and printing properties. The invention also provides a molded article which has a low natural shrinkage percentage, a high shrinkage percentage in heating and a low density and is thus excellent in solvent resistance and hygiene. The molded article comprises as the main components an ionomer (A), which is a metal salt of a copolymer containing an &agr;-olefin unit and an unsaturated carboxylic acid unit, and a resin (B) having an alicyclic structure in its molecule. A preferred embodiment is a molded article composed of a composition comprising the ionomer (A) and the resin (B), and a still preferred embodiment is a laminate comprising a layer containing the ionomer (A) having laminated thereon a layer containing the resin (B). The invention further provides a composition comprising the ionomer (A) and the resin (B), which enables to produce the molded article.
    Type: Grant
    Filed: December 28, 2001
    Date of Patent: March 23, 2004
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Toshiyuki Hirose, Masao Maeno
  • Patent number: 6709731
    Abstract: The invention relates to a sealable, UV-resistant and flame-retardant, coextruded, biaxially oriented polyester film with one matt side and composed of at least one base layer B and of, applied to the two sides of this base layer, a sealable outer layer A and matt outer layer C. The film also comprises at least one light stabilizer which is a UV stabilizer, and comprises a flame retardant. The invention also includes the use of the film and a process for its production.
    Type: Grant
    Filed: July 26, 2002
    Date of Patent: March 23, 2004
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Ursula Murschall, Ulrich Kern, Guenther Crass, Herbert Peiffer, Hans Mahl
  • Patent number: 6706342
    Abstract: A polymeric label comprising a core layer comprising at least about 50% by weight of a linear ethylene alpha-olefin copolymer and at least about 5% by weight of a propylene copolymer; and a first skin layer comprising a propylene copolymer.
    Type: Grant
    Filed: February 21, 2001
    Date of Patent: March 16, 2004
    Assignee: ExxonMobil Oil Corporation
    Inventors: Dan-Cheng Kong, Terry Otto Jensen
  • Patent number: 6706343
    Abstract: The invention relates to heat shrinkage films having polyvinylidene chloride methyl acrylate blend as a barrier layer. Specifically, this invention relates to film structures having a first barrier layer comprising polyvinylidene chloride methyl acrylate blend wherein said barrier layer has two opposing surfaces; a second layer adhered to one of the surfaces of the first barrier layer comprising ethylene vinyl acetate copolymer blend; a third layer adhered to the other surface of the first barrier layer comprising an ethylene vinyl acetate copolymer blend; a fourth layer adhered to one of said second or said third layer comprising an ethylene acetate copolymer blend wherein the melt indexes of said blends of said second, third and fourth layers are the same; a fifth layer adhered to the other of said second or third layer comprising a blend of linear low density polyethylene and low density polyethylene. Said film structures have usefulness as shrink bags.
    Type: Grant
    Filed: June 10, 1999
    Date of Patent: March 16, 2004
    Assignee: Pechiney Emballage Flexible Europe
    Inventor: Keith D. Lind
  • Patent number: 6703134
    Abstract: A multilayer film has a core layer, such as a biaxially oriented polypropylene layer, and an adhesion promoting layer formed from a graft copolymer of syndiotactic polypropylene and a monomer, such as maleic anhydride, which has hydrophilic functionality. The adhesion promoting layer may be metallized to provide a barrier to oxygen and water vapor. The adhesion promoting layer may also render the surface of the film more receptive to printing inks, laminating adhesives, primeness overcoats and the like.
    Type: Grant
    Filed: July 31, 2000
    Date of Patent: March 9, 2004
    Assignee: ExxonMobil Oil Corporation
    Inventors: Larry A. Parr, Robert G. Peet
  • Patent number: 6703115
    Abstract: There are provided novel multilayer films comprising a layer comprising a thermoplastic polymer, such as an aliphatic-aromatic copolyester (AAPE), with or without filler, and a layer comprising a filled thermoplastic polymer. The polymers in the layers may be the same or different. The multilayer films are preferably characterized by having increased moisture vapor transmission rate (MVTR). Also provided are novel articles of manufacture comprising the novel multilayer films.
    Type: Grant
    Filed: January 25, 2002
    Date of Patent: March 9, 2004
    Assignee: Eastman Chemical Company
    Inventors: Wesley Raymond Hale, Ted Calvin Germroth
  • Patent number: 6703138
    Abstract: A laminated polyester film in which a coating layer whose main constituent component is a water-soluble or water-dispersible resin is provided on at least one side of a polyester film, wherein the water resistance value of the film is at least 90%, the discoloration after melt molding is no more than 10, and the haze value change after heating is no more than 20%. Adhesion, water resistance, recoverability, and whitening resistance after heating are all excellent.
    Type: Grant
    Filed: August 7, 2002
    Date of Patent: March 9, 2004
    Assignee: Toyo Boseki Kabushiki Kaisha
    Inventors: Hiroshi Taki, Chikao Morishige, Shinya Higashiura, Masayoshi Satoh
  • Patent number: 6699566
    Abstract: Process for manufacturing cold formed shaped forms of packaging having at least one recess from a metal-plastic laminate. Examples of such shaped forms of packaging are the base parts of push-through packs or blister packs. The process is such that the laminate is held between a retaining tool and a die. The die 1 exhibits at least one opening and a stamp is driven into the die opening causing the laminate to be shape-formed into a packaging, correspondingly exhibiting one or more recesses. The die and the retaining tool exhibit facing edge regions and the die, within the edge region, exhibits a shoulder region that surrounds the die opening or openings. The surface of the shoulder region lies 0.
    Type: Grant
    Filed: October 27, 1998
    Date of Patent: March 2, 2004
    Assignee: Alcan Technology & Management Ltd.
    Inventors: Patrik Zeiter, Heinz Oster
  • Patent number: 6699418
    Abstract: A method for producing a biaxially stretched film is provided, in which the method comprises, stretching a film made mainly of an ethylene-vinyl alcohol copolymer having an ethylene content of 15 to 70 mol % and a saponification degree of 80 mol % or more under heating; cooling the film; and subjecting the cooled film to a heat treatment; wherein a heating temperature during the stretching is 60 to 160° C., a cooling temperature is a temperature 30 to 100° C. lower than the heating temperature during the stretching, and a temperature for the heat treatment is 150 to 190° C. The thus obtained biaxially stretched film of the present invention has a small bowing coefficient.
    Type: Grant
    Filed: February 14, 2002
    Date of Patent: March 2, 2004
    Assignee: Kuraray Co., Ltd.
    Inventors: Kazuhisa Okada, Nariaki Fujii
  • Patent number: 6696166
    Abstract: A plastic film having a desirable balance of physical properties is prepared using a pseudohomogeneous linear low density polyethylene (lldpe) resin on a blown film extrusion line. The lldpe used in this invention must have a melt index, I2, of from 0.4 to 0.8 grams per 10 minutes, a base resin density of from 0.915 to 0.919 grams per cubic centimeter and a copolymer/homopolymer (COHO) ratio of from 3 to 9. The film must be prepared under specific extrusion conditions using a specific annular extrusion die. The film of this invention has a dart impact strength of greater than 600 grams per mil and a machine direction tear strength of greater than 350 grams per mil and is suitable for the preparation of packaging and trash bags.
    Type: Grant
    Filed: April 2, 2002
    Date of Patent: February 24, 2004
    Assignee: Nova Chemicals (International) S.A.
    Inventors: John Bayley, Peter Andrew Sipos, Nakul Ulhas Ranade
  • Patent number: 6692824
    Abstract: A light-permeable, IR-reflecting body which contains a stiff, amorphous base material comprised of light-permeable plastic and IR-reflecting particles which are oriented parallel to the surface, said light-permeable IR-reflecting body having a transmissivity (T) in the visible range of 45-75%, an overall energy permeability (g) of 30-60%, and a T/g ratio of >1.15, and the IR-reflecting particles oriented parallel to the surface are disposed in a coating layer comprised of a transparent water-insoluble binder, which layer is 5-40 micron thick and adheres to the base material, wherewith red-reflecting particles with a layer of titanium dioxide 60-120 nm thick on a platelet-shaped carrier pigment are present in the aforesaid coating layer in the amount of 20-40 wt. % of said coating layer.
    Type: Grant
    Filed: October 25, 1994
    Date of Patent: February 17, 2004
    Assignee: Roehm GmbH & Co. KG
    Inventors: Volker Benz, Wolfgang Scharnke, Michael Meier-Kaiser, Michael Müller
  • Patent number: 6689436
    Abstract: “HEAT-SHRINKABLE FILMS BASED ON POLYOLEFIN COMPOSITIONS COMPRISING: (I) A LINEAR COPOLYMER OF ETHYLENE WITH ONE OR MORE &agr;-OLEFINS (LLDPE); (II) A COPOLYMER OF PROPYLENE HAVING A PARTICULAR COMPOSITION AND CHARACTERISTICS. THE FILMS ARE CHARACTERIZED BY GOOD OPTICAL AND MECHANICAL PROPERTIES, IN PARTICULAR A HIGH TEAR RESISTANCE.
    Type: Grant
    Filed: April 18, 1996
    Date of Patent: February 10, 2004
    Assignee: Basell Technology Company bv
    Inventors: Gianni Perdomi, Claudio Cometto, Enrico Beccarini
  • Patent number: 6689454
    Abstract: The invention relates to a white, flame-resistant, UV-stable, thermoformable, oriented film made from a crystallizable thermoplastic, the thickness of which lies in the range of from 10 &mgr;m to 350 &mgr;m. Said film comprises at least one white pigment, a flame-proofing agent and a UV absorber and is characterized by good stretchability and thermoformability, by good optical and mechanical properties and an economical production. The invention further relates to a method for the production of said film and the use thereof.
    Type: Grant
    Filed: July 19, 2002
    Date of Patent: February 10, 2004
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Ursula Murschall, Guenther Crass, Ulrich Kern, Klaus Oberlaender
  • Patent number: 6689857
    Abstract: A high density polyethylene (HDPE) film is provided having high-biaxial orieniation. The film includes HDPE having a density of at least about 0.940, and a melt index of from about 0.5 to about 10. The film is stretched in the machine (longitudinal) direction to a degree of from about 5:1 to about 8:1, preferably from about 6:1 to about 7:1. The film is also stretched in the transverse (lateral) direction to a degree of from about 6:1 to about 15:1, preferably from about 9:1 to about 13:1. Preferably, the film has an orientation imbalance, with a higher degree of transverse orientation than machine orientation. Skin layers such as heat seal layers can be provided. Preferably, the film contains one or more layers of a casting promoter material employed to promote casting of a high gauge HDPE sheet subsequently high biaxially oriented to provide the film. The film can also be cavitated, or otherwise modified (e.g., corona-treated, coated, metallized, etc.) to provide films suitable for special applications.
    Type: Grant
    Filed: October 3, 1996
    Date of Patent: February 10, 2004
    Assignee: ExxonMobil Oil Corporation
    Inventors: John A. Larter, Robert V. Poirier
  • Patent number: 6685865
    Abstract: The present invention is directed to a process for producing a biaxially oriented polyester film which comprises: subjecting a polyester film to simultaneous biaxial stretching in a stretching apparatus constructed to simultaneously stretch the film in the lengthwise and widthwise directions thereof; and subsequently subjecting the film to successive biaxial stretching in the lengthwise and widthwise directions thereof in the same apparatus as mentioned above. With this process, a film can be efficiently formed, without film breaking, which film is small in thickness and greatly strong in its lengthwise and widthwise directions.
    Type: Grant
    Filed: October 23, 2001
    Date of Patent: February 3, 2004
    Assignee: Toray Industries, Inc.
    Inventors: Katsuya Toyoda, Satoru Nishino, Toshiya Nishibayashi
  • Patent number: 6686055
    Abstract: The polypropylene composite film of the present invention comprises (A) a crystalline polypropylene layer and (B) a propylene-1-butene random copolymer layer which is laminated on at least one surface of the crystalline polypropylene layer (A). The propylene/1-butene random copolymer (B) has the following properties: (1) the copolymer comprises 50 to 95% by mol of constituent units derived from propylene and 50 to 5% by mol of constituent units derived from 1-butene, (2) the intrinsic viscosity is 0.1 to 5 dl/g, (3) the molecular weight distribution (Mw/Mn) is not less than 3, and (4) the parameter B value is 1.0 to 1.5. The crystalline polypropylene layer (A) of this composite film may be unstretched, monoaxially stretched or biaxially oriented. The polypropylene composite film has excellent heat-sealing properties, such as low-temperature heat-sealing properties and heat-sealing strength, and hot tack properties.
    Type: Grant
    Filed: May 17, 2002
    Date of Patent: February 3, 2004
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Yasuo Tanaka, Masahiro Sugi, Mamoru Kagami
  • Patent number: 6680104
    Abstract: A decorative wrapping film for application to a three-dimensional substrate includes a biaxially-oriented polyester layer which has a first surface for adhering to a three-dimensional substrate and a second surface. A decorative layer is coated on the second surface of the polyester layer, and a protective layer is coated on the decorative layer.
    Type: Grant
    Filed: March 27, 1998
    Date of Patent: January 20, 2004
    Assignee: Leonard Kurz GmbH & Co.
    Inventors: Gregory J. Boris, Frank M. Yandrisevits, III
  • Patent number: 6677049
    Abstract: The invention relates to a multi-layered biaxially-oriented film, mainly made of a crystallizeable thermoplastic polyester and economically produceable with a high surface quality, i.e. without pinning bubbles and without electric arcing and film breaks, at production speeds of 340 m/min or higher. According to the invention the multi-layered polyester film has an average specific electrical melt resistance over its total thickness which lies within a range from 1.5×107 to 30×107 &OHgr;×cm. The invention also relates to a method of production of the film.
    Type: Grant
    Filed: August 24, 2001
    Date of Patent: January 13, 2004
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Harald Mueller, Ursula Murschall
  • Patent number: 6677031
    Abstract: There is provided a multilayer film which is useful as a refractive polarizer film or a semi-transparent film. The multilayer film comprises a first layer comprising of a polyester whose main recurring unit is ethylene-2,6-naphthalene dicarboxylate and a second layer comprising mainly of a thermoplastic resin which is different from the polyester of the first layer, wherein at least one of the first and second layers contains 0.001 to 0.5 wt % of inert fine particles having an average particle diameter of 0.01 to 2 &mgr;m; the first and second layers each have a thickness of 0.05 to 0.3 &mgr;m and are laminated alternately to form a laminate comprising at least 11 layers; the laminate is oriented at least in one direction; and the second layer has a lower refractive index than the first layer at least in one direction. This multilayer film has excellent handling properties such as film formability and windability and an easily adjustable reflectance.
    Type: Grant
    Filed: August 22, 2001
    Date of Patent: January 13, 2004
    Assignee: Teijin Limited
    Inventors: Hirofumi Murooka, Hiroshi Tokuda
  • Patent number: 6673424
    Abstract: Molecular electronic devices and method of making molecular electronic devices having a self-assembled ordered insulating molecular electronic film having insulating molecules attached at one end to a first electrode, and conducting device molecules inserted into the insulating molecular electronic film such that the device molecules are attached at the bottom end to a first electrode and the top end to a second electrode are provided.
    Type: Grant
    Filed: June 18, 2002
    Date of Patent: January 6, 2004
    Assignee: Arizona Board of Regents
    Inventors: Stuart Lindsay, John Devens Gust, Xiaodong Cui
  • Patent number: 6673425
    Abstract: A multilayer optical body having improved dimensional stability is disclosed. The optical body includes an optical film, such as an oriented multilayer optical film, and a dimensionally stable layer, such as a transparent polycarbonate layer. In addition, in specific implementations, the invention includes an intermediate layer between the optical film and the dimensionally stable layer. Methods of making the optical body are also disclosed.
    Type: Grant
    Filed: October 27, 2000
    Date of Patent: January 6, 2004
    Assignee: 3M Innovative Properties Company
    Inventors: Timothy J. Hebrink, Andrew J. Ouderkirk
  • Publication number: 20040001945
    Abstract: The invention is a composite foam structure comprising a first segment of an anisotropic thermoplastic foam part and a second foam shaped part comprising an isotropic foam wherein the anisotropic foam block and isotropic foam part intersect along at least one common surface.
    Type: Application
    Filed: June 27, 2002
    Publication date: January 1, 2004
    Inventors: Peter J. Cate, Myron J. Maurer, Chung P. Park, Dominicus L.A.M. Bindels, Martin H. Tusim
  • Patent number: 6670027
    Abstract: To provide a uniaxially oriented polypropylene-based film excellent in tensile elongation along the TD direction and transparence, and generating less fibers when it is torn, a film-forming material which comprises a polypropylene-based resin material consisting of 40 to 95% by weight of crystalline polypropylene, and 60 to 5% by weight of propylene-&agr;-olefin copolymer dispersed as particles in the crystalline polypropylene is uniaxially oriented to afford a uniaxially oriented polypropylene-based film, wherein the particles of the copolymer have an aspect ratio (L/D) of mean dispersed particle length (L) to mean dispersed particle diameter along the film thickness direction (D) of 100 or more in a cross section of the film along the MD direction, and the mean dispersed particle diameter of 0.10 &mgr;m or less.
    Type: Grant
    Filed: December 2, 1999
    Date of Patent: December 30, 2003
    Assignee: Chisso Corporation
    Inventors: Chikashi Okayama, Takanori Nakashima, Noriaki Saito, Hiroyuki Maehara, Yuya Ishimoto
  • Patent number: 6660397
    Abstract: An abrasion resistant coated film including a polyester film coated with a highly crosslinkable melamine coating with a crosslinking density of greater than about 50% and less than about 100%, wherein the coating is cured after transverse stretching and heat setting the film, a melamine coating having a crosslinking density between about 50% and about 100% containing between about 0.01% by weight and about 1.0% by weight of a colloidal particle selected from the group consisting of silica, TiO2, graphite and blends thereof, and a method of producing an abrasion resistant coated film including stretching a polyester film in the machine direction to form a uniaxially oriented film, applying a coating of highly crosslinkable melamine with a crosslinking density between about 50% and about 100% onto the uniaxially oriented film, heating and stretching the coated film in the transverse direction and curing the coating on the coated film.
    Type: Grant
    Filed: February 21, 2002
    Date of Patent: December 9, 2003
    Assignee: Toray Plastics (America), Inc.
    Inventors: John Fitch, Steven J. Sargeant
  • Patent number: 6652984
    Abstract: A paper-plastic laminate sheeting capable of being converted by conventional equipment into envelopes, grocery bags and other dilatable container products that initially are in a flat state and are normally made of paper. The sheeting is composed of a paper facing sheet cold-laminated by means of a water-based adhesive to a reinforcing film of synthetic plastic material, such as polypropylene. The film is oriented to impart exceptional tear and burst strength characteristics to the resultant waterproof product. The product, whose exterior surface is formed by the paper facing sheet, is readily printable. For some applications, a second paper facing sheet is cold-laminated to the other side of the film to produce a three-ply laminate sheeting whose exposed surfaces are readily printable and can accept conventional adhesives.
    Type: Grant
    Filed: June 10, 2002
    Date of Patent: November 25, 2003
    Inventors: Arnold B. Finestone, Gilbert Bloch
  • Patent number: 6652979
    Abstract: Biaxially-drawn polyester film for fabrication which is characterized in that it is a film comprising polyester in which ethylene terephthalate units and/or ethylene naphthalate units are the chief structural component and containing 0.1-2 wt % of a carnauba wax and 1 to 200 ppm of germanium, and the melting point of said film is 180-270° C., the angle of contact to water is 70°-120°, and the planar orientation coefficient is 0.08-0.15. This film shows outstanding release properties following repeated use, use after fabrication and use in an aqueous environment and, furthermore, it exhibits stable properties with little variation and, in particular, following lamination to metal sheet such as steel or aluminium, when used as the inner face of a fabricated metal can, it is outstanding in its non-stick properties to the contents, and provides a combination of heat resistance and processability.
    Type: Grant
    Filed: August 2, 2001
    Date of Patent: November 25, 2003
    Assignee: Toray Industries, Inc.
    Inventors: Kohzo Takahashi, Ryosuke Matsui, Masahiro Kimura
  • Patent number: 6652961
    Abstract: A biaxially oriented polyester film with a substantially non-crosslinked polymeric coating containing styrene and acrylate, wherein the coating is highly thermally stable with a primary onset temperature of greater than about 350C, having a glass transition temperature between about 0C and about 50C, having a solubility in a low molecular weight organic solvent, and having a surface energy of greater than about 35 dyne/cm and less than about 40 dyne/cm.
    Type: Grant
    Filed: November 7, 2002
    Date of Patent: November 25, 2003
    Assignee: Toray Plastics (America), Inc.
    Inventors: Steven J. Sargeant, Yasushi Takada, Masaaki Sudo, John Fitch
  • Patent number: 6649732
    Abstract: A film of the present invention includes, as its main component, an aliphatic polyester whose primary repeating unit is represented by a general formula —O—CHR—CO— (where R denotes H or an alkyl group having a carbon number of 1-3). A three-dimensional surface roughness SRa of at least one side of the film is about 0.01 &mgr;m to about 0.1 &mgr;m. PCC value denoting the number of projections on the film per a unit of area along a mean roughness plane and the three-dimensional surface roughness SRa satisfy the following relationship: PCC value≦7000-45000×SRa.
    Type: Grant
    Filed: October 30, 2002
    Date of Patent: November 18, 2003
    Assignee: Toyo Boseki Kabushiki Kaisha
    Inventors: Hisato Kobayashi, Keiji Mori, Naonobu Oda, Tadashi Okudaira
  • Patent number: 6649247
    Abstract: The invention relates to a sealable, flame-retardant, coextruded, biaxially oriented polyester film with one matt side, and composed of at least one base layer B and of, applied to the two sides of this base layer, a sealable outer layer A and a matt outer layer C. The film also comprises at least one flame retardant. The invention further relates to the use of the film and to a process for its production.
    Type: Grant
    Filed: July 26, 2002
    Date of Patent: November 18, 2003
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Ursula Murschall, Ulrich Kern, Guenther Crass, Herbert Peiffer, Hans Mahl
  • Patent number: 6645609
    Abstract: Described is a stretched multilayered film comprising: (a) a polyolefin layer; and (b) at least one peelable outer layer. Each peelable outer layer (b) independently is 0.5 to 5 &mgr;m thick, comprises a copolymer of vinyl acetate and ethylene, and has a vinyl acetate proportion of from 3 to 30 wt. %, based on the weight of the peelable outer layer (b). Also described is a method of using the multilayered film as a packaging film.
    Type: Grant
    Filed: June 13, 2001
    Date of Patent: November 11, 2003
    Assignee: Wolff Walsrode AG
    Inventors: Bernd Sperlich, Helmut Wagner, Willi Schwarz, Hans Wunderlich
  • Patent number: 6645589
    Abstract: The present invention provides a white biaxially oriented polyester film having a two-layer structure of layer A/layer B, wherein the layer A contains a polyester having a melting point of 240° C.-260° C. and containing titanium dioxide in a proportion of 5-30 wt %, the layer B contains a polyester having a melting point of 210° C.-235° C., and the film shows a dimensional change of not more than 2%, which is obtained by thermally adhering a layer B side of the film to a metal plate to give a laminate, which is heat-treated at 210° C. for 2 minutes, and subjecting the film after the treatment to the measurement, a film-laminated metal plate using the polyester film and a metal container obtained by forming this film-laminated metal plate. The polyester film of the present invention has superior heat resistance and is capable of stably covering the surface of a metal plate even after a heat treatment during a can forming process and the like.
    Type: Grant
    Filed: September 12, 2001
    Date of Patent: November 11, 2003
    Assignee: Toyo Boseki Kabushiki Kaisha
    Inventors: Shingo Fujii, Hideki Igushi, Hiroshi Nagano
  • Patent number: 6641900
    Abstract: A multilayered polymer film includes a first set of optical layers and a second set of optical layers. The first set of optical layers is made from a polyester which is often birefringent. The polyesters of the first set of optical layers typically have a composition in which 70-100 mol % of the carboxylate subunits are first carboxylate subunits and 0-30 mol % are comonomer carboxylate subunits and 70 to 100 mol % of the glycol subunits are first glycol subunits and 0 to 30 mol % of the glycol subunits are comonomer glycol subunits, where at least 0.5 mol % of the combined carboxylate and glycol subunits are comonomer carboxylate or comonomer glycol subunits. The multilayered polymer film may be used to form, for example, a reflective polarizer or a mirror.
    Type: Grant
    Filed: November 28, 2001
    Date of Patent: November 4, 2003
    Assignee: 3M Innovative Properties Company
    Inventors: Timothy J. Hebrink, William W. Merrill, Carl A. Stover
  • Patent number: 6641924
    Abstract: The present invention relates to a white, biaxially oriented polyester film having at least a base layer, the characterizing features of which are that at least this base layer comprises a cycloolefin copolymer (COC) at a concentration of from 4 to 60% by weight, based on the base layer, where the glass transition temperature of cycloolefin copolymer (COC) is within the range from 70 to 270° C.
    Type: Grant
    Filed: October 19, 1999
    Date of Patent: November 4, 2003
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Herbert Peiffer, Gottfried Hilkert
  • Patent number: 6638636
    Abstract: A breathable multilayer film having a breathable core layer and at least one skin layer is disclosed. The core layer prepared by from a mixture containing a thermoplastic polymer and a particulate filler and the skin layer or layers are prepared from a mixture of at least two incompatible polymers and a polymer which compatiblizes the incompatible polymers. The addition of the compatiblizer in the skin layer improves the film forming consistency. In addition, the core layer contains voids around the particulate filler and the skin layer or layer has cracks or voids, which provides breathability to the multilayer film. Stretching of the film after the layers are coextruded together forms the voids and/or cracks.
    Type: Grant
    Filed: August 28, 2001
    Date of Patent: October 28, 2003
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventor: John David Tucker
  • Patent number: 6638637
    Abstract: A multi-layered biaxially oriented film comprising at least one primary layer and at least one secondary layer, wherein the primary layer comprises a propylene copolymer having a first melting point and the secondary layer comprises a polypropylene homopolymer or copolymer having a second melting point, such that the second melting point is greater than the first melting point and the multi-layered construction is biaxially stretched. The multi-layered film further includes a surface finishing layer, to provide a writable multi-layered film. This stretched film exhibits a refractive index in the machine direction (MD) that is greater than the refractive index measured in the transverse direction (TD).
    Type: Grant
    Filed: January 22, 2001
    Date of Patent: October 28, 2003
    Assignee: 3M Innovative Properties Company
    Inventors: Patrick J. Hager, Joseph T. Bartusiak, Kevin M. Hamer, Randall E. Kozulla, Martin E. Denker
  • Patent number: 6635337
    Abstract: Birefringent optical films have a Brewster angle (the angle at which reflectance of p-polarized light goes to zero) which is very large or is nonexistent. This allows for the construction of multilayer mirrors and polarizers whose reflectivity for p-polarized light decreases slowly with angle of incidence, are independent of angle of incidence, or increase with angle of incidence away from the normal. As a result, multilayer films having high reflectivity (for both planes of polarization for any incident direction in the case of mirrors, and for the selected direction in the case of polarizers) over a wide bandwidth, can be achieved.
    Type: Grant
    Filed: August 10, 2001
    Date of Patent: October 21, 2003
    Assignee: 3M Innovative Properties Company
    Inventors: James M. Jonza, Michael F. Weber, Andrew J. Ouderkirk, Carl A. Stover
  • Patent number: 6632538
    Abstract: A battery packet (50) comprises a battery case (51) formed by processing a battery case forming laminated sheet (10), a battery 50a contained in the battery case (51), and tabs (59, 60) extending outside from the battery case (51). The battery case forming laminated sheet (10) is formed by laminating a first base film layer (1a), i.e., an outermost layer, a metal foil layer (2), and a heat-adhesive resin layer (3) in that order. The first base film layer (1a) is a biaxially oriented polyethylene terephthalate resin film or a biaxially oriented nylon resin film. The metal foil layer (2) is an aluminum or copper foil. The heat-adhesive resin layer (3) is formed of a polyolefin resin, more preferably, of an acid-denatured polyolefin resin.
    Type: Grant
    Filed: December 13, 1999
    Date of Patent: October 14, 2003
    Assignee: Dai Nippon Printing Co., Ltd.
    Inventors: Takuya Yamazaki, Kiyoshi Oguchi, Koji Shimizu, Kenichiro Suto, Tsutomu Yoshinaka, Hideki Kurokawa, Hitoshi Sekino, Masahiro Yoshikawa, Hiroshi Miyama, Katsuhiko Hayashi, Jun Fukuda
  • Patent number: 6630224
    Abstract: The invention relates to a matt, biaxially oriented polyester film having at least one matt base layer (B) which comprises at least 70% by weight of thermoplastic polyester, and also a pigment system with narrow grain size distribution. The invention further relates to the use of the film and to a process for its production. The film of the invention has characteristic matt surfaces and has good suitability for use as a packaging film or for industrial applications.
    Type: Grant
    Filed: September 10, 2001
    Date of Patent: October 7, 2003
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Herbert Peiffer, Guenther Crass, Gottfried Hilkert
  • Patent number: 6630216
    Abstract: Described is a molded plastic article which includes a barrier film. The molded plastic article is prepared by a process which involves: (a) providing a barrier film comprising at least one polymeric layer, the barrier film having a first surface and a second surface; (b) placing the barrier film in a mold such that the first surface of the barrier film is in contact with at least a portion of the interior surfaces of the mold; (c) injecting a polymer (e.g., a molten thermoplastic polymer) into the mold, the injected polymer contacting the second surface of the barrier film; and (d) removing the molded plastic article from the mold. Also described are molded articles according to the present invention, which include, for example, plastic containers, plastic fuel tanks, plastic storage units, plastic fascias and plastic motor vehicle interior cladding materials.
    Type: Grant
    Filed: July 26, 2001
    Date of Patent: October 7, 2003
    Assignee: Bayer Aktiengesellschaft
    Inventors: Dirk Pophusen, Gerhard Opelka, Detlev Joachimi, Helmut Schulte, Karsten-Josef Idel
  • Patent number: 6627295
    Abstract: The invention relates to a biaxially oriented polyester film having at least one matt side and composed of at least one base layer (B) and of, applied to this base layer, at least one matt outer layer (A) which comprises at least 70% by weight of thermoplastic polyester and also to a pigment system with narrow grain size distribution. The invention further relates to the use of the film and to a process for its production. The film of the invention with the outer layer (A) has a characteristic matt surface and characteristic optical properties and has good suitability for use as a packaging film or for industrial applications.
    Type: Grant
    Filed: September 10, 2001
    Date of Patent: September 30, 2003
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Herbert Peiffer, Stefan Bartsch
  • Patent number: 6627308
    Abstract: The present invention relates to a release film comprising: a polyester film; a coating layer formed on one surface of said polyester film; and a release layer formed on a surface of said coating layer which exhibits a residual adhesion rate of not less than 80%, said release film satisfying all of the conditions represented by the following formulae (1) to (3): OL≦0.6 (1) TL≧80 (2) TL(H)≦8 (3)  wherein OL is an amount (mg/m2) of oligomers extracted with dimethylformamide from a surface of said release layer after the release film is heat-treated at a temperature of 180° C. for 10 minutes; TL is a total light transmittance (%) of said release film; and TL(H) is a total light transmittance (%) of a laminate prepared by interposing said release film between two polarizing plates disposed in a perpendicular relation to each other.
    Type: Grant
    Filed: April 3, 2001
    Date of Patent: September 30, 2003
    Assignee: Mitsubishi Polyester Films Corporation
    Inventors: Kimihiro Isaki, Masashi Inagaki
  • Patent number: 6627695
    Abstract: The present application relates to a white, biaxially oriented, UV-resistant polyester film with at least one base layer which comprises, based on the weight of the base layer, from 2 to 60% by weight of a cycloolefin copolymer (COC), where the glass transition temperature of the COC is within the range from 70 to 270° C. The film also comprises from 0.01 to 5.0% by weight of a UV stabilizer as light stabilizer, based on the weight of the base layer. The film of the invention is suitable for packing foods or other consumable items which are sensitive to light and/or to air, or for use in industry, e.g. in the production of hot-stamping foils or as a label film, or for image-recording papers, printed sheets or magnetic recording cards.
    Type: Grant
    Filed: February 12, 2001
    Date of Patent: September 30, 2003
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Ursula Murschall, Herbert Peiffer, Gottfried Hilkert, Richard Lee Davis